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Experiment 1: Characteristics of Matter Apolega, Melissa Ann Kim Dizon, Diane Marie Group 1

Expt 1-Characteristics of Matter

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Chemistry 14.1 - General Chemistry Laboratory I

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Page 1: Expt 1-Characteristics of Matter

Experiment 1: Characteristics of Matter

Apolega, Melissa Ann Kim

Dizon, Diane Marie

Group 1

Page 2: Expt 1-Characteristics of Matter

Characteristics of Materials Used in the Experiment

Iron (Fe) filings Magnetic, malleable, with silver/grey coloring Most familiar element to display corrosion

Mothballs Non-polar organic solids Aromatic compound that sublimes easily

Table Salt (NaCl) A well-known ionic compound Brittle, and known to conduct electricity in the

molten state in an aquaeous solution

Page 3: Expt 1-Characteristics of Matter

Magnesium (Mg) ribbon White ash=result of burning Mg ribbon Mg combines with oxygen to form magnesium oxide When water is added forms magnesium hydroxide, a

base Food Color

Substance added to change food/beverage color Also used for educational purposed and laboratories

Iodine (I2) crystals Lustrous, grey-black substance When heated gently, it vaporizes into a purple gas,

exhibiting sublimation

Page 4: Expt 1-Characteristics of Matter

Hydrochloric Acid (HCl) Magnesium and iron corrode easily in acid

solutions such as this Dissolves metals to form oxidized metal chlorides

and hydrogen gas (formation of bubbles)

Ferric Chloride (FeCl3) Mild oxidizing agent that dissolves metals (ex.

Copper and iron) A moderately strong Lewis acid, highly corrosive

and toxic Sulfur (S) powder

If heated, forms sulfur dioxide

Page 5: Expt 1-Characteristics of Matter

Hexane (C6H14) Alkane hydrocarbon, frequently used as inert

solvent in organic reactions due to its being non-polar

Does not dissolve in water

Page 6: Expt 1-Characteristics of Matter

Methods of Physical Separation: As Applied in Ex. 1

Filtration Solid and liquid separated by a porous

medium (filter paper) Sublimation

Solid transformed into gaseous state without passing through the liquid phase (vaporization of iodine and naphthalene)

Page 7: Expt 1-Characteristics of Matter

Solvent Extraction Method of separation where two immiscible

solvents form two layers in the solution, making it easy to pour each separately

Adsorption Means to adhere to a surface Occurs as atoms or ions at the surface of a

solid are extremely reactive

Page 8: Expt 1-Characteristics of Matter

Chemical Properties of Metals Metals are lustrous in appearance. Most of them are solid at room temperature, good

conductors of heat and electricity exhibit malleability and ductility. generally have low electronegativities, having the

tendency to form cations and have positive oxidation numbers

The reaction of a metal with either an acid or metal salt is called a displacement reaction. This occurs because the ion in the solution is displaced or replaced through oxidation of an element..

Page 9: Expt 1-Characteristics of Matter

Chemical Properties of Nonmetals

Nonmetallic elements are poor conductors of heat and electricity, unlike metals.

exhibit both positive and negative oxidation numbers.

more electronegative than metals; they can readily accept electrons when they are subjected to reactions.

Page 10: Expt 1-Characteristics of Matter

Physical and Chemical Changes in Matter

In a physical change, no new substance is formed after the process but only phase changes occur; melting, freezing, vaporization and sublimation are some examples of a physical change.

At the occurrence of a chemical change, a new substance is formed. Indications that a chemical reaction has taken place include: emission of light or heat, change in color, gas production, odor, or sound.

Page 11: Expt 1-Characteristics of Matter

Results and Discussion Reaction of Metallic and Non metallic

substances with HCl Iron evolution of gas (chemical) Magnesium evolution of gas (chemical) Mothballs no reaction Iodine no reaction

Evolution of gas is an indicator that a chemical reaction has occurred. As this had been observed in the experiment evidently in iron and magnesium as they reacted with HCl, the changes have been identified as chemical in nature

Page 12: Expt 1-Characteristics of Matter

Classification

Iron metallic Magnesium metallic Mothballs nonmetallic Iodine nonmetallic

Page 13: Expt 1-Characteristics of Matter

Reaction with FeCl3 Iron no change Magnesium showed chemical change

Page 14: Expt 1-Characteristics of Matter

Reaction of Oxides with Water Magnesium Oxide almost not dissolved Sulfur Dioxide partly dissolved

Basic/Acidity Magnesium Oxide Basic Sulfur Dioxide Acid

Page 15: Expt 1-Characteristics of Matter

Metal Oxides Most are ionic compounds Those that dissolve in water react to form

hydroxides and are called basic anhydrides or basic oxides

Nonmetal Oxides Oxyacids result from most nonmetal oxides

combining with water Oxides that react with water to form acids are

caled acidic anhydrides or acidic oxides

Page 16: Expt 1-Characteristics of Matter

Chemical Properties of Metals and Nonmetals based on the Experiment Metals

Evolution of Gas upon reactionReactive with Acids

NonmetalsNo evolution of gas observed in substances

tested non-reactive with acids

Page 17: Expt 1-Characteristics of Matter

Oxidation occurs as metals react with the acidic solutions. Acids are combinations of nonmetals combined with hydrogen and oxygen, thereby oxidizing metals which are known to lose electrons in reactions like these.

A Comparison between Iron and Magnesium

In the activity series, magnesium is located higher than iron; magnesium is more easily oxidized compared to iron and can therefore react more readily to form compounds. With this fact, it can be said that magnesium is more reactive than iron as it undergoes various reactions.

Page 18: Expt 1-Characteristics of Matter

Changes of Matter upon heating and type Iron burns (P) Food Color burns (C) Iodine purple vapor formed (P) Naphthalene particles move away from

flame (P) NaCl burns (P) Mg Ribbon white ash formed (C)

Page 19: Expt 1-Characteristics of Matter

Significant Observations Change in iodine crystals

When heated, crystals were directly changed into the gas state in the form of purple vapor (sublimation)

Formation of white ash on the mg ribbonEvidence of the formation of magnesium

oxide as fumes form. If combined with water, this forms magnesium hydroxide (basic)

Most substances heated underwent physical changes only as phase changes were observed in the experiment

Page 20: Expt 1-Characteristics of Matter

Balanced Reactions

MgO (s) +H2O Mg (OH)2

SO2 (g) +H2O H2SO3

2Fe + 6 HCl 2FeCl3 +3H2

Mg + 2HCl MgCl2 + H2

3 Mg + 2FeCl3 3MgCl2 +2Fe

Page 21: Expt 1-Characteristics of Matter

Conclusion

It can therefore be concluded that properties of matter are crucially considered when substances are subjected to reactions. As substances are subjected to reactions, their properties also manifest during the reaction

Page 22: Expt 1-Characteristics of Matter

Sources

Chang, Raymond. Chemistry. International Edition (5th). McGraw-Hill, Inc., New Jersey, USA. 1994

Brown, Theodore, Lemay, H. Eugene, Bursten, Bruce and Burdge, Julia. Chemistry the Central Science. 9th Edition (Philippine ed). Pearson Education South Asia. 2004

en.wikipedia.org