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Environmental and Economic Assessment of Management of Plastic Packaging Waste Master Thesis 30 ECTS Author: Aikaterini-Nafsika Softa s111129 Supervisors: Thomas Fruergaard Astrup Veronica Martinez Sanchez Kostyantyn Pivnenko September 2013

Environmental and Economic Assessment of … · Environmental and Economic Assessment of Management of Plastic Packaging Waste Master Thesis 30 ECTS Author: Aikaterini-Nafsika Softa

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Page 1: Environmental and Economic Assessment of … · Environmental and Economic Assessment of Management of Plastic Packaging Waste Master Thesis 30 ECTS Author: Aikaterini-Nafsika Softa

Environmental and Economic Assessment of

Management of Plastic Packaging Waste

Master Thesis

30 ECTS

Author:

Aikaterini-Nafsika Softa

s111129

Supervisors:

Thomas Fruergaard Astrup

Veronica Martinez Sanchez

Kostyantyn Pivnenko

September 2013

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DTU Environment

Department of Environmental Engineering

Technical University of Denmark

Miljoevej, Building 113

DK-2800 Kgs. Lyngby

Tlf: 4525 1600

Fax: 4593 2850

E-post: [email protected]

www.env.dtu.dk

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Preface

The present document is a Master thesis report counting for 30 ECTS and completing

the master program in Environmental Engineering at the Technical University of

Denmark (DTU). The study carried out from the middle of March until the end of

September 2013 at DTU Environment, under the supervision of the Associate

professor Thomas Fruergaard Astrup and the PhD students Veronica Martinez

Sanchez and Kostyantyn Pivnenko.

The project provides an environmental and economic assessment of waste

management options of take-away food plastic packaging and it was performed in

collaboration with the Municipality of Copenhagen under the frame of Plastic ZERO

project. The project’s case study is the Sticks’ n Sushi restaurants in Copenhagen.

The report is divided into 10 main chapters. Chapter 1 introduces the problem

assessed in the project while Chapter 2 provides background information. Chapter 3

introduces the project and key parts of it. Chapter 4 and 5 describe the inventory of

the environmental and economic part of the study respectively. Chapter 6 presents the

results of the study while Chapter 7 presents the sensitivity analysis performed in

crucial points of the environmental part of the project. Chapter 8 includes the

discussion of the different parts of the report while Chapter 9 gathers the conclusions

of the study. Chapter 10 proposes ideas and suggestions for future studies.

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Acknowledgement

I would like to deeply thank my supervisors Thomas Fruergaard Astrup, Veronica

Martinez Sanchez and Kostyantyn Pivnenko for their precious guidance in the course

of the project and for the time they spend on our long discussions and meetings. In

addition, I would like to express my particular thanksgiving to Mette Skovraard who

trusted me for the performance of the present project, as well as Marianne Kristine

Kjærgaard Bigum for being my contact person in the Municipality of Copenhagen and

providing me with guidance and relevant information when needed. I would also like

to thank Jacob Gaard for providing me with starting information in the beginning of

my research and Sticks’ n Sushi restaurants for being my case study.

A special thanks goes to very helpful Niels Nielsen from Donplast A/S, who gave me

the opportunity to visit his packaging production facility and provided me with a large

volume of information concerning not only his facility but generally the followed

route of the production process. An equally strong thanks goes to my contact person

from the foil’s production industry whose name is not mentioned, respecting his

willingness. I would like to sincerely thank him for all the important data he gave me

as well as for his patience and the time he spend to answer all my questions and

explain to me the difference of crucial points of the processes. Moreover, I would like

to thank Danskretursystem for the provided information concerning the transportation

of the sorted plastic.

It would be an omission not to express my thanks to Valentina Bisinella and Anders

Damgaard for their significant advice and help in order to face the software’s issues.

Additionally, I would like to thank Alessio Boldrin for his input in a crucial point of

the thesis.

Last but not least, I would like to thank my friends for their support especially during

the last months of the thesis’s implementation and mainly my family for providing me

all kinds of support during the whole period of my master studies.

Aikaterini-Nafsika Softa

DTU Environment

September 2013

[email protected]

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Abstract

The large volume of plastic packaging ending to the municipal waste is a challenge

concerning the most beneficial way of treatment. Plastic ZERO project corporates

with public and private sector for the reduction, prevention and recycling of plastic

waste. Under this framework, the present project focused on the disposal alternatives

of take-away plastic food packaging. The type of assessed plastic is PET applying to

the packaging used in the Sticks’ n Sushi case study.

The study is a combined life cycle assessment (LCA) and life cycle costing (LCC)

study aiming to assess and compare the performance of four waste management

alternatives of the plastic take-away packaging of 1000 equally amounted meals. An

additional goal was the gathering of representative, state-of-the-art data for the set-up

of the environmental model, sourcing directly from the involved industries.

The first three scenarios referred to the currently used one-use packaging while the

forth scenario referred to the option of 20 timed-reusable packaging. The first

scenario depicted today’s applicable situation in Copenhagen, where the waste is

collected and taken for incineration with energy recovery. The second scenario

represented a separated collection of the used packaging and its transportation to UK

for conventional recycling. The output of the scenario was intended to be used in

electronic packaging applications. Scenario 3 followed the same route as Scenario 2

with an additional supercleaning step after the conventional recycling. The output of

the process was intended to be used for food packaging applications. Scenario 4

referred to packaging used for 20 times followed by disposal to incineration with

energy recovery. Due to comparative reasons the upstream phase of the additional

kilos of packaging used in the first three scenarios, had to be included in the modeling

of Scenario 1,2,3.

The environmental modeling was realized by using the EASETECH, LCA tool. The

environmental impacts were calculated with the ‘’ILCD Recommended‘’ method and

were assessed for 12 impact categories. Most of the data used in the environmental

part of the study were obtained directly from the involved industries, the Municipality

of Copenhagen or from scientific papers. EASETECH, EASEWASTE and Ecoinvent

databases were also used as sources for the background processes of the project.

The economic assessment was performed in Excel spread shits. The data were

obtained from a variety of sources including the involved industries, reports, personal

market research and websites.

The environmental assessment showed that Scenario 4 is by far the most beneficial

option, followed by Scenario 3, Scenario 1 and finally Scenario 2. The ranking stayed

the same in two implemented sensitivity analysis which assessed the system’s

performance after reducing the times of reuse to the half and after modeling a

different, more loading upstream phase.

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Under the economic point of view, Scenario 4 was still appeared to be the less costly

option while Scenario 2 appeared to be the most expensive solution.

The combined LCA and LCC showed that Scenario 4 and reuse are the most

beneficial approaches contrary to Scenario 2 which is the least preferable option.

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Abbreviations

CC Climate change

CFCs Chlorofluorocarbons

CO2 Carbon oxide

DAR Depletion of abiotic resources

DARF Depletion of abiotic resources, fossil

DK Denmark

DKK Danish krona

EFSA European Food Safety Authority

EP Eutrophication potential

ET Ecotoxicity, total

EU European Union

F.U. Functional Unit

FDA Food and Drug Administration

FE Freshwater eutrophication

GB Great Britain

HCFCs Hydrochlorofluorocarbons

HTC Human toxicity, carcinogenic

HTNC Human toxicity, non-carcinogenic

IV Intrinsic Viscosity

Kg kilos

l liters

NIR Near Infra-Red

NOx Nitrogen Oxides

PCR-PET Post Consumer PET

PET Polyethylene terephthalate

PIRP Postindustrial recycle PET

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PM Particulate matter

POF Photochemical oxidant formation

RER Europe

SC Supercleaned

SCR Supercleaned recycled

SOD Stratospheric ozone depletion

SOx Sulfur Oxides

TA Terrestrial acidification

UK United Kingdom

US United States

VOCs Volatile Organic Compounds

y years

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Table of contents Preface ........................................................................................................................................ v

Acknowledgement .................................................................................................................... vii

Abstract ..................................................................................................................................... ix

Abbreviations ............................................................................................................................ xi

1. Introduction and objectives .............................................................................................. 1

2. Background ........................................................................................................................ 3

2.1. Plastic Packaging ............................................................................................................. 3

2.2. Plastic food packaging .................................................................................................... 7

2.2.1. PET in food packaging .............................................................................................. 7

2.2.2. Legislation for food contact applications ................................................................ 7

2.3 Management of plastic packaging waste ........................................................................ 8

2.3.1. Legislation ................................................................................................................ 8

2.3.2. Management in Europe ........................................................................................... 9

2.3.3. Management in Denmark ...................................................................................... 13

2.3.4. Management in Copenhagen ................................................................................ 14

2.3.5. Recycling of PET ..................................................................................................... 15

2.4. Life Cycle Assessment (LCA) ......................................................................................... 19

2.4.1. LCA phases ............................................................................................................. 20

2.4.2. EASETECH .............................................................................................................. 21

2.5. Life Cycle Costing (LCC) ................................................................................................. 22

2.6. Literature review of LCA and LCC on plastic packaging ................................................ 23

2.6.1. Food packaging ...................................................................................................... 23

2.6.2. Single and reusable food packaging ...................................................................... 23

2.6.3. Waste management of plastic and plastic food packaging ................................... 23

2.7. The Sticks’ n sushi case study ....................................................................................... 25

3. Goal and Scope definition ............................................................................................... 26

3.1.Goal ............................................................................................................................... 26

3.2.Scope ............................................................................................................................. 26

3.2.1. Functional unit ....................................................................................................... 26

3.2.2. Description of Scenarios ........................................................................................ 27

3.2.3. Modeling framework ............................................................................................. 33

3.2.4. System boundaries ................................................................................................ 33

3.2.5. General assumptions ............................................................................................. 35

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3.2.6. Impact Assessment criteria ................................................................................... 36

3.2.7. Data source and technological scope .................................................................... 37

3.2.8. Time and geographical scope ................................................................................ 38

3.2.9. Critical review ........................................................................................................ 39

4. Life cycle Inventory analysis (LCIA) .................................................................................. 40

4.1. Studied packaging......................................................................................................... 40

4.2. Upstream processes ..................................................................................................... 41

4.2.1. Virgin PET flow ....................................................................................................... 43

4.2.2. Foil production ...................................................................................................... 43

4.2.3. Transportation from the foil production facility in UK to the packaging production

facility in DK and vice versa ............................................................................................. 44

4.2.4. Packaging production ............................................................................................ 45

4.3. Disposal phase .............................................................................................................. 46

4.3.1. Waste packaging flow ............................................................................................ 46

4.3.2. Scenario 1 .............................................................................................................. 47

4.3.3. Scenario 2 .............................................................................................................. 49

4.3.4. Scenario 3 .............................................................................................................. 55

4.3.5. Scenario 4 .............................................................................................................. 58

5. Life Cycle Costing Inventory analysis ................................................................................... 62

5.1. Upstream processes ..................................................................................................... 63

5.2 Disposal processes ......................................................................................................... 63

5.2.1. Collection ............................................................................................................... 63

5.2.2. Transportation ....................................................................................................... 64

5.2.3. Mechanical Recycling ............................................................................................ 65

5.2.4. Mechanical Recycling followed by the supercleaning process and partly pelletizing

......................................................................................................................................... 66

5.2.5. Incineration in Vestforbrænding ........................................................................... 67

5.2.6. Landfilling in UK ..................................................................................................... 67

5.2.7. Manual Dishwashing ............................................................................................. 67

5.2.8. Automatic Dishwashing ......................................................................................... 68

5.3. Assessed Scenarios ....................................................................................................... 68

6. Results ................................................................................................................................. 70

6.1 Environmental assessment ............................................................................................ 70

6.1.1. Non-toxic potential impact categories .................................................................. 70

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6.1.2. Toxic potential impact categories ......................................................................... 74

6.1.3. Resource depletion ................................................................................................ 76

6.2. Cost assessment ........................................................................................................... 77

7. Sensitivity analysis ............................................................................................................... 79

7.1. Times of packaging reuse ............................................................................................. 79

7.2. Upstream processes ..................................................................................................... 81

8. Discussion ............................................................................................................................ 83

9. Conclusions .......................................................................................................................... 87

10. Future work suggestions and study improvement ............................................................ 89

References ............................................................................................................................... 90

ANNEXES .................................................................................................................................. 98

Annex A : Background information ......................................................................................... 98

A1 Graphs ............................................................................................................................ 98

A2 Applied PET supercleaning processes ............................................................................ 99

A3 Impact categories and waste management ................................................................. 101

Annex B: Upstream Processes ............................................................................................... 102

B1 EASETECH’s snapshots.................................................................................................. 102

B1.1 Virgin PET flow ....................................................................................................... 102

B1.2 Foil production ...................................................................................................... 102

B1.3 Transportation from UK to DK and vice versa ....................................................... 102

B1.4 Packaging production ............................................................................................ 103

B2 Data and calculations ................................................................................................... 103

B2.1 Differences between the different types of PET ................................................... 103

B2.2 Foil production ...................................................................................................... 103

B2.3 Packaging production ............................................................................................ 104

B2.4 Actual amounts of upstream processes ............................................................... 106

Annex C: Disposal Processes ................................................................................................. 107

C1 EASETECH’s snapshots .................................................................................................. 107

C1.1 Waste flow ............................................................................................................. 107

C1.2 Scenario 1 .............................................................................................................. 107

C1.3 Scenario 2 .............................................................................................................. 109

C1.4 Scenario 3 .............................................................................................................. 111

C1.5 Scenario 4 .............................................................................................................. 112

C2 Data and calculations ................................................................................................... 113

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C2.1 Waste flow ............................................................................................................. 113

C 2.2 Manual dishwashing ............................................................................................. 113

C 2.3 Automatic dishwashing ........................................................................................ 114

Annex D: Life Cycle Costing , Detailed Calculations .............................................................. 115

D1 General Data ................................................................................................................ 115

D1.1 Materials and Energy ............................................................................................ 115

D1.2 Salaries .................................................................................................................. 116

D1.3 Truck ...................................................................................................................... 116

D1.4 Washing Equipment .............................................................................................. 116

D2 Virgin Foil production ................................................................................................... 118

D3 Packaging Production ................................................................................................... 119

D4 Collection ..................................................................................................................... 121

D5 Transportation ............................................................................................................. 122

D6 Sorting Facility .............................................................................................................. 124

D7 Mechanical Recycling ................................................................................................... 127

D8 Mechanical Recycling followed by the supercleaning process and pelletizing ........... 128

D9 Landfill in UK ................................................................................................................ 129

D10 Manual Dishwashing .................................................................................................. 130

D11 Automatic Dishwashing ............................................................................................. 131

Annex E: Environmental Results ............................................................................................ 132

E1 Characterized Results ................................................................................................... 132

E2 Normalized Results ....................................................................................................... 138

E3 Main process and substance contributors ................................................................... 143

E3.1 Main substance-contributors ................................................................................ 143

E3.2 Main contribution and saving sources in each process ........................................ 144

E4 Stratospheric ozone depletion graph ........................................................................... 146

Annex F: Economic Results .................................................................................................... 147

F1 Scenario 1 ..................................................................................................................... 147

F2 Scenario 2 ..................................................................................................................... 147

F3 Scenario 3 ..................................................................................................................... 147

F4 Scenario 4 ..................................................................................................................... 148

F5 Total .............................................................................................................................. 148

Annex G: Sensitivity analysis ................................................................................................. 149

G1 Sensitivity 1 .................................................................................................................. 149

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G1.1 Adjusted modeling data ........................................................................................ 149

G1.2 Composition comparisons .................................................................................... 149

G2 Sensitivity 2 .................................................................................................................. 151

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1. Introduction and objectives

The increased consumption of plastics in products and packaging has led to an

increasing presence of plastics in the municipal waste streams (Plastic ZERO). The

growth of the global population combined with the increasing need for food and the

quick pace of life have led to an increasing production of take-away food which is

mostly sold in plastic packaging as it keeps the food fresh and protected. This type of

packaging ends up relatively soon in the waste bin due to its single use design,

concept that enhances the production of plastic waste. In Copenhagen’s region, 12%

of the incinerated residual waste is plastic (Plastic ZERO).

Until now, a number of Life Cycle Assessment (LCA) studies have taken place in

order to investigate the environmental impacts sourcing of different plastic waste

disposal options and technologies. A deep emphasis has been given on the waste

management options of Polyethylene terephthalate (PET) bottles due to the easy

separation of the fraction and the variety of applied recycling methods which can

convert the waste PET to a source of raw material for many different applications,

including applications for direct food contact. The studies focusing on the reuse of

food packaging, in many cases compare different packaging materials for the same

product. The economic dimension is added in many LCA waste management studies

in order to give a more representative perspective.

According to the waste hierarchy and the results of the majority of the LCA studies of

the waste management field, reuse is the most environmental friendly approach,

followed by the recycling. Incineration with energy recovery is also competitive in

many cases. Landfilling is the option which is the least favorable as it is considered a

complete waste of sources. The fundamental difference between the alternatives of

incineration and recycling is that the incineration of the waste leads to a loss of

materials while the recycling keeps them in the cycle. In the same time, recycling

contributes to the savings of energy and raw materials the production of which is

linked to the emissions of greenhouse gases. The production of virgin plastic comes

from oil and accounts for almost 8% of the worldly oil production ( EUROPEAN

COMMISSION, 2013).

The present study is an integrated environmental and economic assessment of

restaurants’ take-away packaging waste. The main aim of the project is to assess and

compare the environmental and economic impacts coming from the life cycle of PET

plastic take-away food packaging from restaurants, focusing on the alternative

disposal options. The study includes four different scenarios. The first three scenarios

refer to an one-use packaging while the forth scenario refers to a reusable packaging.

The waste treatment options which are involved are the incineration with energy

recovery and two different types of recycling. Life Cycle Costing (LCC) of the

scenarios enhances the decision supporting nature of the study. A further aim of the

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study is the gathering of representative data concerning the currently used

technologies and the recycled material’s applications, coming directly from the side.

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2. Background

The present chapter illustrates the waste management policies and technologies

applied to the plastic packaging, focusing on the food plastic packaging and on

polyethylene terephthalate (PET) plastic. Additionally, it introduces the terms of Life

Cycle Assessment (LCA) and Life Cycle Costing (LCC).

2.1. Plastic Packaging

The sector of plastic packaging represents 39% of the European plastics market

(PlasticsEurope(a), 2012) and accounts for the largest European and global share of

plastic production (Figure 1) (bio Intelligence Servise, 2011). The plastic packaging’s

growth rate is the highest among all the packaging materials for the period 2005-2010

(Eurostat, 2013) The resistance, the flexibility, the low cost and the lightness of the

plastics are some of the characteristics that make the plastic packaging useful, popular

and practical ( EUROPEAN COMMISSION, 2013) as it contributes to a safer use,

transport and storage and keeps the product fresh and protected (PlasticsEurope(b),

2012).

There are many different types of rigid1plastic packaging in the market intended for

different applications. The type of polymer used is chosen according to its properties

and features (i.e. resistance, transparency, thermal stability etc.) in accordance with

the products’ characteristics, use and storage conditions (Delgado et al., 2007).

Polymers can be used in packaging combined with other polymers or materials and

they can also be coloured, labored and decorated in many ways (Delgado et al., 2007;

Kirwan & Strawbridge, 2011). Glass clear, transparent, coloured, opaque, with glossy

or matte surface are some of the variations applied in the design of plastic packaging

(Kirwan & Strawbridge, 2011).

All types of plastic packaging in Europe (EU) and in United States (US) are identified

by a code and symbol concerning their plastic type, in order to facilitate the recycling

(Christensen and Fruergaard, 2011). In EU, the marking of the plastic products (both

packaging and no packaging) is recommended but volunteering (Christensen and

Fruergaard, 2011). Types of plastic used for packaging together with their various

uses, code and abbreviation are presented in Table 1.

1 Rigid plastic packaging refers to any plastic packaging application such as bottles, closures, cups,

pots

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Figure 1: European plastic demand by segment and resin type, 2011, source: PlasticsEurope(a), 2012

Table 1: Type, use and code of plastics, Source: Christensen and Fruergaard, 2011; bio Intelligence Servise, 2011

Plastic type Abbreviation Use Code

Polyethylene

terephthalate

PET Bottles for carbonated soft

drinks, textile fibers, film food

packaging, trays, medical

products

1

High density

polyethylene

HDPE Containers, toys, house wares,

industrial wrappings, gas pipes

2

Polyvinyl-chloride PVC Bottles, containers of medical

products window frames, pipes,

flooring, wallpaper, toys, cable

insulation, credit cards,

3

Low density

polyethylene

LDPE Pallets, agricultural films, bags,

toys, coatings, containers, pipes,

wrappings, films

4

Polypropylene PP Film, battery cases, containers,

crates, vegetable trays, electrical

components

5

Polystyrene PS Cups, plates,thermal insulation,

tape cassettes, electrical

appliances, toys

6

Expanded

polystyrene

EPS Packaging of foodstuffs,

medical supplies, foam

insulation, building material,

cycle helmet, electrical

consumer goods

7

Polyamide PA Films for packaging of food

waste, fibers, high-temperature

engineering applications, textile

7

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Polyolefins (LDPE, HDPE, PP) and PET are the polymers which are most commonly

used in plastic packaging in EU/15, Norway and Switzerland (bio Intelligence

Servise, 2011). LDPE which is the dominant polymer used in plastic packaging, is

used mainly in plastic bags and shrink/ stretch wrap while HDPE is used for bags and

sacks when high rigidity is needed for commercial or industrial applications (Delgado

et al., 2007). PP is the most representative plastic material for rigid type food

packaging (e.g. rigid containers, pots, tubes) if excluding the beverage bottle case

where PET is the leading type of plastic (Delgado et al., 2007). PP trays correspond to

28% of the total production of the trays used for frozen/ready food as its high melting

point permits the microwave use (Delgado et al., 2007). HDPE and mainly PET are

basically used in bottles (bio Intelligence Servise, 2011) although PET is also applied

in food trays, frozen meals and salads (Delgado et al., 2007). PS is applied in

protective packaging with EPS used for the protection of the food in the packaging

(Delgado et al., 2007; bio Intelligence Servise, 2011). Crystal polystyrene is

commonly used as a barrier layer between the plastic and the packaged food (Delgado

et al., 2007). PVC is widely used for medical and non-food applications (Delgado et

al., 2007). The largest portion of plastic packaging ends up in household while the rest

is used in the industry for distribution reasons (e.g. crates, pallets, wrapping)

(ARGUS, et al., 2001). In Table 2 is given a detailed overview of the type of plastics

used in main household packaging.

Bioplastics are the new types of plastics which entered to the market in 2005, in

specific applications including packaging and waste collection bags (bio Intelligence

Servise, 2011; Christensen and Fruergaard, 2011). Renewable biomass (e.g. corn

starch and cane sugar) is the base for the bioplastics’ production, and that aims to the

reduction of fossil fuels consumed in the production phase (Christensen and

Fruergaard, 2011). Bioblastics are not completely CO2 neutral thought, as fossil fuels

are still used for the cultivation and reprocessing of the biomass. Polylactic acid

plastic (PLA), the most commercially applicable bioplastic until now, is used in the

production of packaging, bags and bottles replacing PE or PET plastic (bio

Intelligence Servise, 2011). Not all bioplastics thought, can be currently used in food

packaging, since they do not meet the resistance requirements (bio Intelligence

Servise, 2011). In Europe, bioplastics represent 0.1-0.2% of the total European plastic

consumption (bio Intelligence Servise, 2011).

The present report focuses on PET since it is one of the most popularly used polymers

in the plastic packaging industry and since it is also commonly applied in packaging

of meals and in trays, which is the report’s examined application.

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Table 2: Main household packaging applications, source: bio Intelligence Servise, 2011

Applications Most common polymers

used

Bottles

Dairy products HDPE

Juices, sauces HDPE, barrier PET, PP

Water, soft drinks PET, barrier PET

Beer and alcoholic beverages Barrier PET

Oil, vinegar PET, PVC

Non-food products (cleaning

products, toiletries, lubricants,

etc.)

HDPE, PET,PVC

Medical products PET

Closures Caps and closures of bottles, jars,

pots, cartons etc.

PP, LDPE, HDPE, PVC

Bags and sacks

Carrier bags LDPE, HDPE

Garbage bags HDPE, LDPE, LLDPE

Other bags and sacks LDPE, LLDPE, HDPE, PP,

woven PP

Films

Pouches (

(sauces, dried soups, cooked

meals)

PP, PET

Overwrapping (food trays and

cartons)

OPP, bi-OPS

Wrapping, packets, sachets, etc. PP, OPP

Wrapping (meat, cheese) PVDC

Collection shrinks film (grouping

package for beverages, cartons,

etc.)

LLDPE, LDPE

Cling stretch rap film (food) LLDPE, LDPE, PVC, PVDC

Lidding (heat sealing) PET, OPA, OPP

Lidding (MAP and CAP foods) Barrier PET2, barrier layered

PET/PE and OPP/PE

Lidding (dairy) PET

Trays

Microwaveable ready meals,

puddings

PP,C-PET

Ovenable ready meals C-PET

Salads, desserts A-PET, PVC

Vegetables PP, EPS

Fish PP, PVC, A-PET, EPS

Confectionery PVC, PS

Dairy products PP,PS

Meat, poultry A-PET, PVC, EPS

Soup PP, A-PET

Others

Blisters PET, PVC

Pots, cups and tubs PP, PS

Service packaging (vending cups,

etc.)

PS

Protective packaging (“clam”

containers, fish crates, loose

filling, etc.)

EPS

2 Barrier materials applied as mono or multi-layers, limit the gas exchange and prolong the life of the

product (Delgado et al., 2007)

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2.2. Plastic food packaging

Food packaging sector accounts for more than the half of the total plastic packaging

production (Delgado et al., 2007). The main properties that make plastics so popular

in food packaging are the food protection from spoilage, the lack of interaction with

the food, the lightweight, the resistant in breakage, the low cost and the availability in

a wide range of shapes and designs which contributes to an attractive and convenient

product (Kirwan & Strawbridge, 2011). The main volume of packaging met in

household sector, comes from food packaging as can be observed from Table 2.

Food packaging can be composed from more than one polymer or from different

materials (bio Intelligence Servise, 2011). Representative example is the PET bottles

case that despite the fact that their main component is PET plastic, their caps can be

made of PE and the labels can be made of PS, PVC, PP or even paper (bio

Intelligence Servise, 2011).

2.2.1. PET in food packaging

PET has become the most favorable packaging material for beverages due to its

unbreakability, lightweight compared to the glass bottles and its easy processes ability

(PlasticsEurope, 2008; Welle, 2011). PET bottles are used for soft drinks, energy

drinks, ice teas, mineral water, juices even for beer and wine (Welle, 2011). Soft

drinks and juices representing the 42% of the total use of PET in packaging (Delgado

et al., 2007; Welle, 2011). In addition, a remarkable application of PET concerns the

packaging of chilled/frozen food, salads, food trays for vegetables, snack foods,

sweets and long life confectionery (Delgado et al., 2007; PlasticsEurope, 2008).

Especially the applications in the packaging of pre-cooked food show a large rise

which is representative of the evolution in the European food consumption habits

(Welle, 2011).

Used PET is an attractive material for recycling which unlike other polymers can be

recycled back to food contact applications (bio Intelligence Servise, 2011). It is

important to be mentioned thought, that the product’s designing phase plays a key role

for its sustainability, since the recycling depends up to a large extent, on the

composition of the used materials ( EUROPEAN COMMISSION, 2013).

2.2.2. Legislation for food contact applications

Council Regulation (EC) 1935/2004 of 27 October 2004 includes all the materials and

articles, including plastics, which intend to come into contact with food and poses the

requirements on which the materials must comply with (European Commission (a)).

The requirements include the ‘’good manufacturing practice’’ established by the

Commission Regulation (EC) 2023/2006 of 22 December 2006 for all the stages of

production. By this regulation the manufacturers are obliged to adopt a quality

assurance and a quality control system. In the Commission Regulation (EU) 10/2011

of 14 January 2011, specific requirements concerning the manufacture and marketing

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of plastic materials for food contact use, are additionally established to the ones of

Council Regulation (EC) 1935/2004 of 27 October 2004. In addition, migration limits

for the materials and articles in question consisting in the plastic materials coming in

to food contact, are established due to the toxic substances that can be transferred

from the plastic articles to the food (Europa, 2012).

According to the Commission Regulation (EC) 282/2008 of 27 March 2008 on

recycled plastic materials and articles intended to come into contact with food, the

plastic input in the recycling process must have been manufactured in EU or US and

comply with the relevant regulations for plastic food contact materials (EFSA, 2011)

even if they are used for non-food applications such as shampoos and household

cleaning products (Franz et al., 2004). In the opposite case, it has to be proved that the

input applies to the Commission Regulation (EC) 282/2008 of 27 March 2008

(EFSA, 2011). All plastic packaging resins sold in EU and US which apply

respectively to Commission Directive (EC) 2002/72 of 6 August 2002 and to 21 CFR3

177.1630 and 21 CFR 177.1315 are food contact graded (EFSA, 2011).

2.3 Management of plastic packaging waste

2.3.1. Legislation

Europe

Despite the high environmental impacts caused by the disposal of plastic waste, there

is no actual legislation about the waste treatment of plastic in Europe (EUROPEAN

COMMISSION, 2013). There are only EU directives framing the policy that country-

members have to adopt (Biener et al., 2013).

The first EU Directive on the management of packaging waste is the Council

Directive (EEC) 85/339 of 27 June 1985, which covers the waste packaging of liquid

beverage containers intended for human consumption (European Commission , 2010).

Due to the vague of the directive, only some of the EU members adopted measures on

packaging waste management (European Commission, 2010).

Following, the Council Directive (EC) 94/62 of 20 December 1994 on packaging

waste, promotes the prevention of packaging and packaging waste, contains

provisions on the recycling, recovery and reuse of packaging waste and sets recycling

and recovery targets for plastic packaging. The revision of the directive in 2004

included the increase of recycling targets (European Commission, 2010). The

Council Directive (EC) 2008/98 of 19 November 2008 on waste, sets recycling and

recovery targets for certain materials originated from households, including plastic,

which should be reached by 2020, by waste management and waste prevention plans,

adopted separately by every EU-member country (European Commission, 2012). The

Directive also introduces the concept of ‘’extended producer’s responsibility’’ in the

waste management, which aims to encourage the plastic product producers in

3 CFR is the acronymic of Code of Federal Regulations which refers to regulations of United States

(U.S.)

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designing more sustainable products with less environmental impacts (Biener et al.,

2013). Finally, the directive emphasizes the priority order that should be applied in

the waste management, starting from the prevention of the waste, followed by the

reuse, recycling, recovery and ending in the disposal. Waste management hierarchy is

depicted in Figure 2.

Figure 2: Waste management hierarchy, source: European Commission, 2012

In most of the EU countries, waste taxes have been introduced as a measure aiming in

the reduction of the waste (Merrild & Christensen, 2011). Additionally, the waste tax

imposed to different disposal ways can be an indirect way to lead the waste to the

most desirable disposal option (Merrild & Christensen, 2011).

Denmark

Danish parliament issued its own legislation concerning the waste management of

packaging and established a deposit and return system (Biener et al., 2013) explained

in Section 2.3.3. Supplementary to that, the Council Directive (EC) 94/62 of 20

December 1994 was also implemented in order to minimize the environmental

impacts caused by waste packaging production (Biener et al., 2013).

Denmark is one of the countries which imposed taxes in the different waste

management options. Landfilling is the option with the highest taxes, followed by the

taxes imposed on incineration process (Merrild & Christensen, 2011). Recycling and

reuse are excluded from the taxes (Merrild & Christensen, 2011).

The ‘’extended producer responsibility’’ introduced in Council Directive (EC)

2008/98 of 19 November 2008 thought, is not yet included in the Danish waste

management system (Biener et al., 2013).

2.3.2. Management in Europe

The annual packaging production is commonly equalized with the packaging waste

generation due to the limited life of the packaging products (Delgado et al., 2007). As

already mentioned, packaging sector represents the largest plastic consumer in most

European countries (bio Intelligence Servise, 2011). The average EU-27 annual

production of plastic packaging waste in 2007, reached the 30.6 kg/capita (bio

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Intelligence Servise, 2011). Figure 3 depicts the plastic packaging waste production

by EU member generated in 2007. The variation of the plastic waste generation

between the countries seems big, but it is the lowest of all the materials (Eurostat,

2013).

Recycling, landfilling and incineration combined or not with energy recovery are

possible treatment options for plastic waste (bio Intelligence Servise, 2011). In 2008,

the European generation of plastic packaging waste reached the 15.6 Mt from which

41.8 % was disposed to landfills (6.5 Mt) and the rest 58.2% (9.1 Mt) was recovered

by recycling or energy recovery (bio Intelligence Servise, 2011). More precisely, 4.4

Mt of the recovered fraction of 9.1 Mt comes from mechanical recycling, 0.074 Mt

comes from feedstock recycling and 4.6 Mt comes from energy recovery. The above

mentioned amounts are illustrated in Figure 4 in order to give a clearer overview.

Table 3, presents the plastic packaging waste treatment by member state for 2007

while Figure 25 in Annex A1 visualizes the respective rates. The amounts of the table

refer to both commercial and household plastic packaging waste.

Denmark is the European country with the highest recovery rate4 (98%) originating

mainly from its high incineration rate (76%). Germany follows Denmark with an

almost equally high recovery rate of 95%. In Germany, 1Mt of plastic packaging

waste (the largest amount in Europe) is being mechanically recycled and 0.054Mt of

plastic packaging waste is being chemically recycled (bio Intelligence Servise, 2011).

Germany is one of the two countries applying chemical recycling for plastic

packaging waste (bio Intelligence Servise, 2011).

Figure 3: Plastic packaging waste generation by EU-27, 2007 (Mt), source: bio Intelligence Servise, 2011

4 Recovery here refers to recycling and energy recovery

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Figure 4: Treatment of total plastic packaging waste generated in EU-27, Norway and Switzerland in 2008 (Mt), source: bio Intelligence Servise, 2011

Bulgaria, Cyprus and Greece are countries with low recovery rates as they do not

possess infrastructures for incineration or energy recovery. Bulgaria’s recycling rate

for example is slightly lower than Denmark’s but its recovery rate is much lower since

the majority of the plastic packaging waste is disposed in landfills, contrary to

Denmark where the remaining fraction is send for incineration with energy recovery

(bio Intelligence Servise, 2011)

Legislation and mainly Council Directive (EC) 94/62 of 20 December 1994 has

contribute to a remarkable increase in recycling of the packaging (bio Intelligence

Servise, 2011). Thus, the European recycling rate is annually increasing by an average

percentage of 2% (PlasticsEurope(b), 2012).

PET bottles and PE containers are one of the dominant driving forces in the waste

plastic recycling industry (bio Intelligence Servise, 2011). Recycling amounts of

plastic packaging for the European countries in total are higher than incineration’s or

energy recovery’s (see Table 3). Plastic packaging is widely mechanically recycled

with recycling rates varying depending on the type of plastic (bio Intelligence Servise,

2011). Distribution packaging such as crates, drums, pallets, wrapping, films, EPS

packaging, are met in commercial and industrial sectors while PET and HDPE bottles

are mainly recovered from the household flow (Delgado et al., 2007). Plastic

packaging existing in the household waste flow is estimated to be 65-75% by weight

of total plastic packaging while the remaining percentage is met in the industrial and

commercial fraction (Delgado et al., 2007). More than 90% of crates and boxes and

40% of bottles and industrial films are recycled in the EU (bio Intelligence Servise,

2011). The recycling of plastic is more difficult and costly, compared to the recycling

of other packaging materials (Eurostat, 2013).

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Table 3: Plastic packaging waste treatment by member state, 2007 (Mt), source: bio Intelligence Servise, 2011

Mechanical

recycling

Other forms

of recycling

Energy

recovery

Incineration

with energy

recovery

Germany 1.075 0.054 0.516 0.874

Italy 0.642 - 0.687

UK 0.477 0.024 0.167

France 0.446 - 0.683

Spain 0.392 0.010 0.238

Netherlands 0.157 0.079 0.318

Poland 0.144 0.0005 0.084 0.011

Belgium 0.119 0.003 0.144

Czech

Republic

0.099 0.001 0.025

Austria 0.080 0.059 0.094

Sweden 0.080 - 0.070

Portugal 0.058 - 0.028

Romania 0.057 0.022 -

Ireland 0.053 - -

Norway 0.042 0.031 0.046

Denmark 0.042 - 0.146

Greece 0.041 - -

Hungary 0.037 0.023 0.036

Slovakia 0.031 0.0001 0.0001

Bulgaria 0.020 <0.00001 -

Lithuania 0.018 - -

Finland 0.018 0.024 -

Estonia 0.014 0.00004 -

Luxemburg 0.010 0.001 0.012

Latvia 0.009 - -

Cyprus 0.002 - -

Total 4.162 0.055 0.875 3.580

The recycling rate of 22.5% which represents the 2008-target has been met by all

country-members that agreed to reach the target by now. The plastic recycling rate of

each country compared to the 2008-target can be seen in Annex A1.

It has to be mentioned that a remarkable amount of plastic packaging waste is

exported from European countries, mainly to Asian Countries, due to economic and

technological reasons (bio Intelligence Servise, 2011). China and Hong Kong import

most of the European waste plastic, which reached the amount of 1.85 Mt in 2006

(bio Intelligence Servise, 2011). Netherlands, Belgium, Italy and Germany are the

main ‘’internal-EU traders’’ of plastic waste (bio Intelligence Servise, 2011). In 2004,

0.85 Mt of plastic waste was traded between the European countries (bio Intelligence

Servise, 2011).

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2.3.3. Management in Denmark

The Danish waste management system is based on the curbside and drop-off

collection schemes (Biener et al., 2013). Curbside collection refers to the disposal of

the waste and recyclables by the citizens into a container, bag or bins outside their

homes. Drop off collection refers to the disposal of waste and recyclables by the

citizens to a recycling or collection center (Biener et al., 2013). The first type of

collection seems to be more effective for recyclables between those two options due

to its convenience from the citizen’s perspective (Biener et al., 2013). The

responsibility for the collection scheme’s decision is taken by the local authorities and

that is the reason why waste management strategy can vary among the Danish

municipalities (Biener et al., 2013).

Deposit-and-return system, is a type of drop-off collection, which was introduced to

the Danish waste system for the management of beverage packaging waste as already

mentioned in Chapter 2.3.1. This system consists of reverse vending machines which

accept used beverage containers and return a fee to the user (Biener et al., 2013).

Almost 3000 reverse vending machines have been installed in 2700 stores all over

Denmark where the consumer returns the used bottle and gets back a deposit (Franz et

al., 2004; Biener et al., 2013). Dansk Returnsystem A/S, founded in 2000, is a private

non-profit organization, which operates the Danish deposit and return system,

supported by the Danish Environmental Protection Agency (Danskretursystem (a))

Dansk Retursystem A/S deposits and refunds refillable bottles (refillables) and one

way packaging (Danskretursystem (b)). The refillables are plastic or glass bottles

washed and refilled by the producer while one-use packaging is single-use products

(Danskretursystem (b)) ;bottles and cans of beer, carbonated soft drinks, energy

drinks, mineral water, iced tea, ready-to-drink beverage and cider products

(Danskretursystem (b) ; Danskretursystem (c)). The collected one way packaging is

sorted by material type (glass, plastic, aluminum, steel) and send for recycling

(Danskretursystem (c)). In 2011, the return percentage 5for one-use packaging was

89% and for refillable packaging 103% (Danskretursystem (d)). In 2010, Denmark’s

reverse vending machines accepted 800 million packaging from which 326 million

were plastic bottles (Biener et al., 2013).

Drink products’ importers and producers, wishing to be covered by the system, have

to register their products in the Dansk Returnsystem A/S and label them according to

the system’s guidelines (Danskretursystem (e)). The one-use packaging registered in

the system, are categorized in three types (A,B,C) with different deposit value

(Danskretursystem (b)). Refundable deposits are presented in Table 4.

5 The return percentage is calculated from the number of returned refundable packaging in proportion

to the total number of sold packaging (Danskretursystem (c))

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Table 4: Refundable deposits, Source: Danskretursystem (b)

Type of packaging Deposit (DKK)

Refillable bottles

Glass bottles (≤0.5 l) 1.00

Glass bottles (>0.5l) 3.00

Plastic bottles (<1 l) 1.5

Plastic bottles (≥1l) 3.00

One-use packaging

Type A

All cans and bottles under 1 l, except plastic bottles

1.00

Type B

Plastic bottles under 1 l

1.50

Type C

Cans, glass and plastic bottles of 1 l and over

3.00

As packaging is the dominant type of waste in Denmark, packaging taxes are imposed

on a number of products (Warberg Larsen and Skovgaard, 2012). A volume-based

tax on beverages was firstly introduced in 1978, aiming to enhance the use of

refillable packaging (Warberg Larsen and Skovgaard, 2012). In 1999, a weight-based

tax was imposed on a number of products such as detergents, soaps, perfumes,

margarine, non-carbonated soft drinks, edible oils and vinegar (Warberg Larsen and

Skovgaard, 2012). The purpose of this tax is the reduction of the waste through the

reduced consumption of packaging (Warberg Larsen and Skovgaard, 2012). The

weight-based tax was also applied on PVC film foodstuff packaging in order to be

promoted the use of more environmental friendly packaging foils (Warberg Larsen

and Skovgaard, 2012).

2.3.4. Management in Copenhagen

A central point in Copenhagen’s waste management system is the source separation of

the recyclable waste fractions included in the municipal waste, which are collected by

a combination of a curbside and bring-back system (Warberg Larsen and Skovgaard,

2012). Until now though, little was the attention given to the plastic fraction with the

exception of PVC (Warberg Larsen and Skovgaard, 2012). PVC and insolation

materials are taken for landfilling while the residual waste fraction is taken for

incineration (Warberg Larsen and Skovgaard, 2012).

Concerning the packaging waste, no separation takes place, with only exception the

deposit-and-return system as explained in Chapter 2.3.3 (Warberg Larsen and

Skovgaard, 2012). Bottle’s recovery reached a percentage of more than 95%

(Warberg Larsen and Skovgaard, 2012) due to the application of this system. The

advantage of this collection system is that PET does not get contaminated by other

materials during the collecting process (Franz et al., 2004).

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Until late 2012, other plastic beverage containers, glass and metal cans have been

collected together in the bring banks6, when a new curbside collection scheme started

being implemented (Warberg Larsen and Skovgaard, 2012). The new source-

separation scheme, started in the autumn of 2012, applies to multi-story buildings and

collects the rigid plastic packaging (Warberg Larsen and Skovgaard, 2012). The

disadvantage of this type of collection is the almost impossible separation between the

plastic packaging for food and non-food applications (Franz et al., 2004). The gradual

implementation of the new system is expected to be fully completed in 2016

(Warberg Larsen and Skovgaard, 2012). Supplementary with the new system’s

establishment, the citizens’ introduction to the system is planned to takes place in

2012-2014, by a relevant information campaign (Warberg Larsen and Skovgaard,

2012).

Bulky, non-food plastic packaging consisting of rigid or flexible recyclable plastic or

PVC is separately collected in the four recycling stations for bulky waste in

Copenhagen (Warberg Larsen and Skovgaard, 2012).

Beverage containers and rigid PVC are collected in order to be recycled (Warberg

Larsen and Skovgaard, 2012). According to survey’s estimations, the potential

recyclable rigid plastic packaging in Copenhagen’s annual household waste is 6600

tons (Warberg Larsen and Skovgaard, 2012).

Table 5, presents the application and the treatment methods of plastic packaging

waste in Copenhagen as reported in 2009 (Warberg Larsen and Skovgaard, 2012).

The landfilled plastic packaging, it is assumed to be PVC (Warberg Larsen and

Skovgaard, 2012).

Table 5: Application and plastic packaging waste in Copenhagen, 2009 , source: Warberg Larsen and Skovgaard, 2012

Application Generated

(tones)

Treatment (tones) Incineration

and landfill

(tones)

% of the

waste

which is

incinerated

and

landfilled

Mechanic

al

recycling

Incineration Landfill

Household

packaging

13,173 1,223 11,761 188 11,949 90.7

Industrial

packaging

10,854 6,642 4,212 0 4,212 38.8

2.3.5. Recycling of PET

During the last decade, EU supported two major projects concerning the recyclability

and re-usability of recycled plastic for new food packaging applications (Welle,

2005). The first project (AIR2-CT93- 1014) dealt with reuse and recycling of waste

plastic packaging materials and concluded that PET is the most promising plastic for

6 Recycling site facilities

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reuse in food contact applications (NARCIS). The second project FAIR CT98- 4318

‘’Recyclability’’, based on the results of the first project, focused on PET and its

reprocessing into new food contact applications (Welle, 2005).

The input of a PET recycling process can be classified into four categories based on

its quality, according to (Franz et al., 2004). The four classes are the following:

Class 1: Includes scrap PET materials coming from the manufacturing or

converting industry, where their past life is known and controlled. This

material defined as ‘’postindustrial recycle PET’’ (PIRP) and ‘’pre-consumer

industrial scrap’’ can be used in applications with direct food contact, with the

fundamental precondition that the ’good manufacturing practice’’ has been

followed as mentioned in Chapter 2.3.1.

Class 2: Includes post-consumer PET (PCR PET) which was used for food

packaging purposes. This type of material cannot be used directly for food

contact applications since the history of its use phase is not known. This

stream is usually collected via a deposit system or material collection.

Class 3: Includes non-pure PCR PET, possibly mixed with other plastics and

PCR PET coming also from non-food packaging applications. This fraction is

usually collected by a mix plastic collection system.

Class 4: Includes the materials of classes 1,2,3 after depolymerisation

(conversion of polymers to monomers by a chemical process) which ends up

to the regeneration of a new polymer.

Feedstock7 coming from Class 1 and 4 can be directly used to direct food contact

applications without any further process (Franz et al., 2004). Contrary, materials

coming from class 2 and 3 can only be directly used for not direct food contact

purposes while they must be further processed in order to be used for applications

with direct contact (Franz et al., 2004).

According to the European Food Safety Authority (EFSA), the PET used for non-food

contact containers such as shampoos and detergents must not exceed the percentage of

5% of the recycling feedstock (EFSA, 2011) due to the potential risks which are

mentioned in Chapter 2.2.2..

The four processes used to recycle plastic packaging material are the primary, the

mechanical, the chemical recycling and the energy recovery which are described as

follows.

1.Primary recycling: Refers to a commonly used approach in industry, where

feedstock of class 1 is used for the production of new packaging (FDA, 2006).

2.Physical reprocessing: Secondary/mechanical/conventional recycling: It

includes a combination of steps like sorting, grinding, shredding, melting, granulating,

7 Feedstock or feed stream refers to PCR PET used as recycling’s input (Franz et al., 2004)

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washing and drying without changing the chemical structure of the plastic (Franz et

al., 2004, (Christensen and Fruergaard, 2011). Dirt and foodstuffs are removed in the

washing and gridding steps (Franz et al., 2004). The smaller the particles/flakes are,

the more effective the washing will be (FDA, 2006). Common additives in the

washing phase are caustic soda and detergents which contribute to the surface

cleaning of the PCR-PET (Welle, 2011). Usually separation step of non-PET

materials like polyolefins is combined with the washing step, by taking advantage of

the different densities (Welle, 2011). An extra cleaning effect can be applied by re-

melting the already washed flakes (Welle, 2011). The purity of the output is affected

by the type of washing (hot or cold water), washing additives, and duration of

washing (Welle, 2011).

PET from class 2 and 3 is the input of this type of recycling which, in the end of the

process, become flakes or pellets after an additional extrusion step (Franz et al.,

2004). The produced PET flakes can be used for: 1) non-food packaging applications,

2) the core layer of multilayer containers or 3) as feedstock for a super clean recycling

process in order to be suitable for food-contact applications (Franz et al., 2004).

Multilayer containers: PET flakes coming from the conventional recycling can be

used in packaging applications as a core layer between of two virgin layers (Delgado

et al., 2007). In the food packaging industry thought, this is not always the case, as the

PCR-PET can contaminate the virgin layer during the film production (Welle, 2011);

personal contact with the industry). Thus, in those cases, it must be proved that the

barrier layer is efficient under the worst case conditions and safe for food contact

applications (see legislation).

Super clean process: Is an extra decontamination step, applied to the output flakes of

the secondary recycling process, in order to produce recycled PET plastic, with

contamination level similar to the one of virgin PET pellets, suitable for direct food

contact applications (Franz et al., 2004). This special deep cleansing step usually

includes high temperature, vacuum or inert gas treatment and surface treatment with

non-hazardous chemicals (e.g. caustic soda) (Welle, 2011).

The solid state of polycondensation (SSP), usually used as decontamination step in

supercleaning processes based on pellets 8, is the first process that entered the market

and is also used as the last step in the processes of the virgin PET (Delgado et al.,

2007). The SSP process can take place either in a standalone system such as a solid

state batch or in continuous working units in the line production, where a continuous

treatment of PET takes place under appropriate temperature and vacuum for a

determined residence time (personal contact with the industry). When PET is

supercleaned through solid stating, a desired (IV) can be achieved according to the

PET’s future application -different applications require different IVs (personal contact

8 PET superclean recycling processes based on pellets uses as input the washed PET flakes which are re

extruded to pellets before the SSP step

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with the industry). Different types of supercleaning already applied in the industry are

presented In Annex A2.

3.Chemical reprocessing: Tertiary/Feedstock recycling: It uses the feedstock of

class 1 to 3 as input and by the process of depolymerisation followed by purification

generates new polymers (Franz et al., 2004). The latters are used for the production of

new packaging (FDA, 2006). Hydrolysis or methanolysis are used for the

depolymerization of PCR-PET to its monomers9 while distillation or crysrallization

usually consist the purification step (Welle, 2011). The purificathion step removes

efficiently every post-consumer compound and the output of the process does not

need to be tested as it is considered safe for food contact applications (Welle, 2011).

The main advantage of the chemical process is its low quality requirements for the

input as it can successfully treat contaminated or heterogeneous plastic feedstock and

produce output of high quality (Ren, 2012). The amounts coming of this recycling

method are not significant in the market, despite the safeness of the process (Welle,

2011).

4.Quaternary recycling: Energy recovery: Refers to the use of the waste as a fuel in

order to generate energy (bio Intelligence Servise, 2011).This process is not

considered as recycling in EU (Ren, 2012).

As it is already mentioned, mechanical recycling is the dominant type of plastic waste

of recycling in Europe. The limited application of the chemical recycling is justified

due to technical and economic reasons (Ren, 2012).

The recycled PET flakes can be used for fibres, sheets, bottles, containers as end

market applications, with packaging gaining more and more place during the last

decade (in 2009, 49% of PCR-PET used in packaging sector the majority of which in

food applications) (Welle, 2011). Germany, UK, France and Italy are the European

countries with the highest recollection rate of PET bottles and are also the countries

with the main super clean facilities installed (Welle, 2011).

2.3.5.1. Risks and limitations in the recycling of plastic materials

The main issue in mechanical recycling process is the heterogeneity of plastic input

which needs to be controlled (Perugini et al., 2005). Food packaging consists

frequently of different types of materials or plastics with different properties and

characteristics as mentioned in Chapter 2.2.1. In order to produce high quality

recycled product, with strength and flexibility, the input material must be cleaned and

separated in types of plastic (Christensen and Fruergaard, 2011). In the opposite case,

the produced plastic is of low quality and needs to be proceeded to a feedstock

recycling process (Christensen and Fruergaard, 2011).

Even if the recycling input comes only from the food packaging sector, the mixing of

different packaging designed for special food types and conditions of use, may lead to

9 PET’s monomers are ethylene glycol and terephthalic acid or terephthalic acid methyl ester

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an undesirable quality of plastic (FDA, 2006). An example of this case may be the

additives used in aqueous type of foods or for refrigerated use which may end up in

packaging for high-temperature use with fatty foods (FDA, 2006). This concept can

be limited by the collection of only a single characteristic container as for instance

PET soda bottles (FDA, 2006).

A limiting factor in using recycled plastics is the big amount of post-consumer plastic

which is required for the production of the recycled material in combination with the

price which has to be competitive compared to the price of the virgin plastic (bio

Intelligence Servise, 2011).

In addition, the fact that recycling cannot eliminate the colors from the reprocessed

plastics, denies their application in transparent or light colored end uses (bio

Intelligence Servise, 2011).

For the food packaging industry, the risks related to the use of recycled plastic comes

from the possible migration of contaminants of the recycled material into the

packaged food (EFSA, 2011). Thus, a ‘’challenge test’’ with a highly contaminated

input is required by the EFSA, in order to be proved that the decontamination during

the recycling process is efficient enough and no risk is posed to human health (see

Chapter 2.2.2.) (EFSA, 2011). For the PET plastic containers, the contaminants

considered by EFSA (2011) come from:

possible storage of chemicals

possible contact with non-food products such as cosmetics and cleaning

products that may lead to an absorption of chemicals

the use of non-authorized plastics as recycling input, the way of production

and quality of which may not apply to the European legislation concerning the

production of plastic for food contact purposes

chemicals coming from multilayer of other than PET materials which may

enter the recycling input due to insufficient separation

chemicals such as detergents which are used in the recycling process

‘’degradation products of the plastic’’ which can be produced as a result of the

high temperature which is applied in many steps in the recycling procedure

and which may convert the polymer chain into new compounds

components of the food which may be absorbed by the PET packaging and

contaminate the plastic which is to be recycled

2.4. Life Cycle Assessment (LCA)

Life cycle assessment (LCA) is used for the evaluation of potential environmental

impacts coming from the life cycle of a product system. Extraction of resources,

production, use and disposal are the stages of a product system’s entire life (from

cradle to grave) that can be accounted under the LCA approach. Its holistic point of

view contributes to the solution of one environmental problem while avoiding the

creation of others, concept that makes LCA a powerful decision supporting tool.

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The ISO 14040 and 14044 illustrate the framework for LCAs while the International

Reference Life Cycle Data Systems (ILCD) provides further guidance. The present

study tries to be as close as possible to the above framework but it does not follow it

strictly.

LCA studies can be approached under two different perspectives: attributional or

consequential. The approach is fundamentally important to be defined in the

beginning of the study since the choice strongly affects the processes and the

modeling of the study. Attributional approach considers an independent of its

surroundings system opposite to consequential approach which takes under

consideration the exchanges between the system and its surroundings systems and

economy. The present study follows a consequential approach.

For the consequential modeling of foreground systems, generic10

or average 11

background datasets may be used, in case of specific data’s unavailability (European

Commission, Joint Research Centre, Institute for Environment and Sustainability,

2010). The required data for the consequential modeling of the background system is

the marginal mixes unless the average mix represents better the superseded process

(European Commission, Joint Research Centre, Institute for Environment and

Sustainability, 2010).

System expansion with substitution is the second option for avoiding allocation

according to the ISO hierarchy and is the applied method approach for solving

multifunctionality in consequential modeling. This method can be applied either by

adding functions in order to make the systems comparable or by subtracting the not

required functions which are substituted by the modeled processes (substitution by

system expansion).

In waste management LCAs, the primary focus is given to the end-of life of products,

opposite to the LCA of products where production and use phase gather the primary

attention (Hauschild & Barlaz, 2011). In many LCA studies of waste management the

starting point of the study is the moment when the product becomes waste and in that

way the production and use phase are excluded from the study (Bjorklund et al.,

2011). However, this is not always the case as in some comparative studies the

production or use phase of the product need to be included. Additionally, not all flows

reach the ‘’grave phase’’ as for example in cases of material and energy recovery

from waste (Bjorklund et al., 2011).

2.4.1. LCA phases

According to ISO 14040, the main phases consisting an LCA study are four: goal and

scope definition, inventory analysis, impact assessment and interpretation of results.

10

Generic datasets refer to data partly developed based on patents, stoichiometric or other calculation

models, expert judgment etc. 11

Average data set refers to average data, technologies or processes

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1. The goal and scope definition describes the study’s parameters including the

purpose and the intended use of the study.

2. The inventory analysis (LCI) introduces and quantifies the inputs and outputs

(materials, energy, emissions) of the product system’s life cycle. It also

includes the collection of data.

3. The impact assessment (LCIA) uses the results of the second phase in order

to provide potential environmental impacts and resource consumption for the

studied system. This phase can be divided in four stages, of which the first two

are mandatory according to the ISO 14040.

Classification: the grouping of LCI results into impact categories

based on the different caused environmental damages

Characterization: quantifying of the contribution caused in each

impact category and resource consumption

Normalization: characterized results expressed to a common unit

Weighting: using numerical factors to express the enhanced

importance of some impact categories

4. The interpretation phase discusses and evaluates the obtained LCIA results,

combined with conclusions and recommendations. Sensitivity and uncertainty

analysis can also be included for key points of the assessment.

2.4.2. EASETECH

The present study was modeled in EASETECH which is a waste management LCA

program, developed by the Residual Resources Research and LCA Research Group of

Technical University of Denmark. The name of the software is an acronym of

‘’Environmental Assessment System for Environmental Technologies’’ and is the

evolution model of the former model EASEWASTE.

EASETECH provides a database of waste generation and waste management

processes together with a number of different LCIA methods. It is also possible for

the user to create its own processes additionally to the processes and flows that can be

imported from the Ecoinvent database. The model quantifies loads and savings of

potential environmental impacts coming from waste management scenarios as well as

mass flows (Sankey diagram).

The software is expected to be a powerful tool although it is not yet fully developed.

The responsible research group is currently working for the optimization of the

program’s processes, bugs and malfunctions. Additionally, new functions are

supposed to be implemented to EASETECH. The preliminary stage of program’s

development was an extra difficulty for the implementation of the present study

basically due to frequent crashes, slow speed of reaction and lack of processes which

had to be inserted manually from EASEWASTE.

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2.5. Life Cycle Costing (LCC)

Life Cycle Costing (LCC) is applied for the estimation of economic costs of products

and systems under a life cycle perspective and it is traditionally used by decision

makers (Hauschild & Barlaz, 2011). The LCC method is basically used for the

comparison of cost-effectiveness of different scenarios (Merrild & Christensen,

2011). This analysis does not consider environmental impacts but it is usually

combined with an LCA study preferably applied to the same system boundaries, in

order to supplement each other in the procedure of decision (Carlsoon Reich).

According to Merrild and Christensen (2011), the private costs 12

in waste

management systems, accounted for LCC, include four different types of costs which

are presented as follows:

1. The capital/fixed costs: Are the costs invested in land, buildings and equipment.

The costs related to the planning of the system are often included in the capital costs.

As the majority of this type of costs is invested during the first years of the system’s

life, the costs are annualized in order to convert them to a yearly cost.

2. The variable/running costs: Refer to the system’s operational and maintenance

costs. Wages, electricity, raw materials, vehicles, replacement of worn equipment are

representative costs of this category.

3. Revenues: Refer to the income coming from the sale of recovered from the waste

products. Examples of recovered products are energy, metals, plastics, paper, and

compost.

4. Taxes: This category includes both general taxes such as VAT (value added tax)

and specific waste taxes imposed on landfilling and incineration.

All the economic data originating from different years needs to be converted to the

present value by a discounting rate or inflation correction (Reich, 2005; Merrild &

Christensen, 2011). The costs of waste management systems can vary significantly

mainly due to factors related to the technological, service and wage level applied to

different collection, transportation and treatment options (Merrild & Christensen,

2011).

LCC does not follow any ISO standards and thus a number of definitions can be

found in literature. The present study adopts the definition of Financial LCC found in

Carlsson Reich (2005), where financial costs depict the present value of all monetary

costs (positive or negative) of the studied system. The calculations of the present LCC

were realized in an excel spread shit, where the costs are depicted with a negative

while the revenues with a positive value. The net revenue, coming from the addition

of the above mentioned values was calculated for all the facilities and processes of the

studied systems.

12

Monetary costs needed for the waste system’s management (Merrild & Christensen, 2011)

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2.6. Literature review of LCA and LCC on plastic packaging

2.6.1. Food packaging

A number of LCA studies have been published comparing food plastic packaging

with other types of packaging or comparing and assessing different types of plastic.

Zabaniotou and Kassidi (2002) compared two egg packaging made from polystyrene

and recycled paper concluding that PS packaging has more impacts than the paper

one. Humbert et al. (2009) compared glass jars and plastic pots as two baby food

packaging alternatives and reached the conclusion that for the same transportation

distances the plastic pot system contributes less than the glass jar system mentioning

the importance of the transportation in the examined systems.

2.6.2. Single and reusable food packaging

Singh et al. (2006) compared reusable plastic containers with single use paper

corrugated trays used for the packaging of fruit and vegetables, focusing on North

American market, with the reusable containers appearing to have a better

environmental profile. Levi et al. (2011) also compared the packaging and distribution

system of re-usable plastic containers with one way paper corrugated boxes for fruit

and vegetables in Italy. Wrap (2010) presents the factors that need to be taken under

consideration when assessing the single use and reusable packaging systems’

performance.

2.6.3. Waste management of plastic and plastic food packaging

Numerous studies have also taken place trying to investigate which is the optimal

disposal method for plastic waste, by comparing different disposal scenarios of

landfilling, incineration, recycling or a combination of the above by using the LCA

tool. Claus Mølgaard (1995) compared the environmental impacts coming from the

disposal of plastic found in the municipal solid waste by investigating six different

disposal ways: two different recycling processes with plastic separation, recycling

without separation, pyrolysis, Danish incineration with heat recovery and landfill,

coming to the conclusion that recycling with plastic separation is the most

environmental friendly approach. Merrild et al. (2012) assessed the environmental

impacts coming from recycling and incineration of six household material fractions

including plastic. For plastic and cardboard fractions the results were more unclear

compared to the rest of the fractions (paper, glass, steel, aluminum) as it was shown

that incineration can be more environmental friendly than recycling, in some cases.

Those cases depended on the examined system boundaries, the incineration’s energy

recovery and the focused impact category.

Arena et al. (2003) assessed an Italian plastic packaging recycling system which

collected and mechanically recycled used PE and PET liquid containers, providing

data coming from the industry. Different alternatives of plastic disposal were also

included in the study which concludes that recycling is the most environmentally

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preferable option, underling the advantages coming from the processed scraps’ energy

recovery. Perugini et al. (2005) studied the recycling of household plastic packaging

waste in Italy comparing it with landfilling, incineration and two other types of

feedstock recycling, pointing that recycling scenarios are environmentally preferable.

Santosh et al. (2009) realized a cradle to grave LCA comparing the environmental

profiles of polylatic acid (PLA), polyethylene terephthalate (PET) and polystyrene

(PS) clamshell containers for strawberries emphasizing the different end of life

scenarios (landfill, incineration, a combination of the above). PET showed the largest

burden contributions to the environment mainly due to the higher weight of the

container. Kruger et al. (2009) compared clamshells made of polylactide (Ingeo) with

clamshells made of virgin and recycled PET. Lazarevic et al. (2010) summarized that

most of the investigated LCAs on plastic waste management seem to follow the waste

hierarchy and confirm mechanical recycling as the preferable environmental option

compared to feedstock recycling and incineration, with the assumption that the plastic

is clean with limited contamination and the substitution rate of recycled plastic with

virgin is close to 1:1. The study also underlines some sensitive key points of plastic

waste management.

2.6.3.1. PET bottles

During the last years, PET was in the focus of many LCA studies due to the separate

collection of PET bottles and its recycling applications. Some of the most recent ones

are briefly presented below. Chilton et al. (2010) realized an LCA in order to compare

the closed-loop recycling of PET bottles with the incineration in an energy recovery

plant. Under an overall perspective, the recycling option had a better environmental

performance. Shen et al. (2010) investigated the open loop of PET bottles-to-fibre

recycling for four different recycling cases (mechanical, semi-mechanical, back to

oligomer and back to monomer recycling) applying different allocation approaches. It

was concluded that mechanical recycling performed better than the chemical

recycling, noting thought that chemically recycled fibres have a wider range of

applications. Shen et al. (2011) get further the previous research by assessing the

effects caused on the cradle to grave system of recycling PET bottles back to bottles

and fibres, by the number of recycling trips, the production of PET from bio-based

feedstock and the shares of recycled PET used for fibres and bottles.

2.6.3.2. Combined LCA and LCC

Carlsson Reich (2005) examined Uppsala’s waste management system under an

environmental and economic point of view. The economic approach was realized

under a financial and environmental LCC. The case study revealed that landfilling is

the least preferred option from an economic perspective as the energy included in the

waste is wasted to the greater extent. In 2005, Schmidt et al. applied an experiment in

the city of Copenhagen in order to define, under an economic and environmental point

of view, the city’s waste scheme concerning plastic and metal single use beverage

containers. This study proved that combined LCA and LCC is a useful tool for waste

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systems’ evaluation. Emery et al. (2006) applied an LCA and LCC approach to a

number of waste management scenario in a typical location in Wales. The LCA

resulted in incineration being as the preferred option compared to landfilling and

recycling/composting method. Oppositely, the LCC showed that incineration needs

higher running costs and provides fewer jobs. It is concluded that an integrated waste

management system is the approach combining many environmental and economic

benefits. Larsen et al. (2009) investigated the potential rise of the recycling rate

through improvements in the collection schemes for recyclables in Aarhus and how

this was reflected in the economic part. The study concluded that the enhancement of

recycling and avoiding of incineration had a positive performance both under an

environmental and economic perspectives. Wrap (2009) realized a study financially

assessing the separation and reprocessing of mixed plastics in UK. The Foolmaun and

Ramleeawon (2012) studied the environmental impacts together with the cost

effectiveness of four alternatives for the disposal of used PET bottles in Mauritius.

The examined alternatives included a combination of landfilling, incineration with

energy recovery and flake production. The combined result of LCA an LCC indicated

the scenario of “75% flake production and 25% landfilling” as the better option.

Foolmaun and Ramleeawon (2012b) took further their previous research by adding

the social paramenter (S-LCA) showing the previously mentioned scenario as the

most sustainable option between the examined scenarios.

2.7. The Sticks’ n sushi case study

Plastic ZERO (2011-2014) is an international waste project which corporates with

public and private sector for the reduction, prevention and recycling of plastic waste

(70). Under this framework, Sticks’ n sushi restaurants chain in Copenhagen,

expressed interest in participating in the project and assessing the possibility of

adopting a ‘’bring back system’’ of their take-away packaging. Sticks’ n sushi

restaurants’ take-away packaging is the case study of the present report.

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3. Goal and Scope definition

3.1.Goal

The present study aims at assessing and comparing the environmental and economic

impacts caused by the end of life treatment of the plastic take-away food packaging.

The study analyses different alternatives concerning the technology and the strategy

approach. The technological variations include incineration with energy recovery and

different types of recycling while the strategic alternatives include one-use and

reusable packaging solutions. An additional goal is the gathering of foreground

processes’ data from state of the art industries in order to reassure the reliability of the

results. The economic reflection of the different scenarios combined with the

environmental results aims at providing an overview of the sustainability of the

different alternatives.

The target audience of the study are decision makers and main stakeholders of the

plastic packaging waste production and waste management sectors in Copenhagen’s

area (in the present case: all take-away food restaurants in Copenhagen including the

Sticks’ n sushi restaurants, the Plastic ZERO project and the Municipality of

Copenhagen). The results of the study are intended to inform Sticks’ n Sushi

restaurants about the potential impacts caused from the waste management

alternatives of their take away packaging in order to evaluate the possibility of

adopting a ‘’bring back system’’ and possibly change the current way of their

packaging’s disposal. In addition, the results of the study could propose a broad

solution and support a decision for a future plastic packaging waste management

system including all the take-away food restaurants in Copenhagen, under the Plastic

ZERO’s framework and the Municipality’s support.

The present report is a comparative study, planned to be disclosed to the public and

thus all the considered assumptions, methods and the applied data are analytically

presented in the following chapters. The project is not funded.

3.2.Scope

3.2.1. Functional unit

The functional unit (F.U.) of the present study is the waste management of the plastic

packaging containers/boxes that serve the distribution of 1000 equal amounted meals

of takeaway food in the chain from restaurant to the private household.

The study assesses two types of packaging: one-use packaging for Scenario 1,2,3 and

reusable packaging for Scenario 4. The reusable packaging is assessed for 20 times of

use and is thicker than the one-use packaging. The qualitative and quantitative

compositions of the two kinds of packaging are presented in Table 6.

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Table 6: Qualitative and quantitative composition of boxes

Type of

box

Times

of use

Number of boxes that

serve the distribution

of 1000 meals

Weight of

plastic (kg),

used for the

distribution of

1000 meals

Composition

of PET plastic

One way 1 1000 69 10% Virgin

90% Recycled

Reusable 20 50 6.9 50% Virgin

50% Recycled

3.2.2. Description of Scenarios

The report’s studied scenarios are four and consist of two phases: the upstream

production phase and the disposal phase. The upstream phase includes the processes

related to the packaging production while the disposal phase encloses the processes

after the packaging’s disposal. Despite the fact that this is a waste management LCA

the upstream phase is considered due to the different weight composition of the one-

use and reusable packaging which are assessed in the study. Thus, the addition of the

upstream phase make the systems comparable. The analytical flowcharts of the

scenarios are depicted in Figure 5-Figure 8.

The upstream phase includes the same processes for all the scenarios but applies to

different quantities. More precisely the upstream phase for Scenario 1,2,3 is exactly

the same since the above scenarios assess the same amount and type of packaging.

Contrary the upstream phase of Scenario 4 is quantitative different since the scenario

assesses a different type of packaging applying to different number of pieces.

The processes included in the studied upstream phase of the production are: the

production of virgin PET, the production of foil, the production of the packaging

including also the relevant transportation and the profits of the recycling of

postindustrial scraps.

The waste management alternatives assessed in the scenarios are described below:

Scenario 1 depicts the current waste management situation where the waste food

packaging is collected together with the rest of municipal waste and transported to the

waste to energy plant where it is incinerated with the parallel production of electricity

and heat. The bottom ash is taken to the mineral landfill.

Scenario 2 refers to a monomaterial collection system where the used boxes are

gathered to the restaurants’ sites under the frame of a deposit-and-return system

system, after they have been manually washed. The gathered packaging is collected

from all the participating restaurants and transported to the sorting facility where it

gets sorted, compacted and baled. The compacted bales are transported to United

Kingdom (UK) in a mechanical recycling facility. The output of the facility is hot

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washed R-flakes which is intended to be used for the production of electronic

packaging. The residuals of the recycling process are taken to the Sanitary landfill

while the residuals of the sorting facility follow the incineration’s route.

Scenario 3 depicts a situation similar to scenario 2 with the addition of some extra

steps after the production of the R-PET flakes aiming to the production of R-flakes

suitable for food contact applications. Thus, the hot washed R-flakes are

decontaminated with the super cleaning process which results to super cleaned flakes.

A part of those flakes is pelletized while another part stays as flakes. The output of the

supercleaned R-flakes and R-pellets is going to be used for the production of new

take-away food packaging. The residuals of the recycling process are taken to the

Sanitary landfill while the residuals of the sorting facility are taken for incineration.

Scenario 4 represents a situation of reusable take-away boxes participating in a

deposit-and-return system. The used boxes after being manually washed are taken

back to the restaurants in order to get reused for a future use. The system is assumed

to work with a refund as driving force. The returned boxes are washed in the

restaurants by a dishwashing machine. The packaging can be reused 20 times,

meaning that the manual and automatic dishwashing takes place 19 times. After the

20 uses, the reusable boxes are collected and transported to the waste to energy

incineration facility in Copenhagen. The incineration’s bottom ash is taken to the

mineral landfill.

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Incineration

Foil production

Packaging production

Electricity

Electricity

Diesel T

Virgin PET

Use phase

C+T

Scraps

Cut foil

T

Virgin PET

Electricity and heat

Diesel

Diesel

Waste packaging with foodstuffs

Scenario 1

Inputs from the background processes

T

C+T

Foreground processes

Substitutions

Transportation

Collection and transportation

Inputs from the background processes

Output

Heat and electricity

Virgin PET

Figure 5: Analytical flowchart of scenario 1

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Sorting and compacting

PET Recycling Incineration

Residuals

Residuals

TT

Wastewater treatment

Bales

Manual dishwashing

Landfilling

Foil production

Packaging production

Electricity

Electricity

Diesel T

Virgin PET

Use phase

C+T

Scraps

Cut foil

T

Virgin PET

Diesel

Diesel

Water

Diesel

Electricity Diesel

Diesel

Electricity and heat

T

Wastewater treatment

Water

Natural gas, electricity,

NaOH, water

Diesel

Mineral landfill

TDiesel

Bottom ash

Virgin PP

Waste packaging with

foodstuffs

T

C+T

Foreground processes

Substitutions

Waste treatment of foreground processes’

byproducts

Transportation

Collection and transportation

Inputs from the background processes

Scenario 2

Output

R-PET flakes and pellets (food grade)

Virgin PET

Figure 6: Analytical flowchart of scenario 2

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Sorting and compacting

PET Reprocessing (recycling,

supercleaning, pelletizing)

Incineration

Residuals

Residuals

TT

Wastewater treatment

Bales

Manual dishwashing

Landfilling

Foil production

Packaging production

Electricity

Electricity

Diesel T

Virgin PET

Use phase

C+T

Scraps

Cut foil

T

Virgin PET

Diesel

Diesel

Water

Diesel

Electricity Diesel

Diesel

Electricity and heat

T

Wastewater treatment

Water

Natural gas, electricity,

NaOH, water

Diesel

Mineral landfill

TDiesel

Bottom ash

Virgin PET

Waste packaging with

foodstuffs

T

C+T

Foreground processes

Substitutions

Waste treatment of foreground processes’

byproducts

Transportation

Collection and transportation

Inputs from the background processes

Scenario 3

Output

R-PET flakes and pellets (food grade)

Virgin PET

Figure 7: Analytical flowchart for scenario 3

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Automatic dishwashing

(19 times)

Incineration

C+T

Manual dishwashing

(19 times)

Foil production

Packaging production

Electricity

Electricity

Diesel T

Virgin PET

Use phase

Scraps

Cut foil

T

Virgin PET

Diesel

Water

Diesel

Electricity,Water,

detergent, rinsing agent

Wastewater treatment

Mineral landfill

T

Diesel

Bottom ash

Electricity and heat

Waste packaging with

foodstuffs

T

C+T

Foreground processes

Substitutions

Waste treatment of foreground processes’

byproducts

Transportation

Collection and transportation

Inputs from the background processes

Scenario 4

Use phase’s output

Wastewater treatment

Electricity and heat

Virgin PET

Figure 8: Analytical flowchart for scenario 4

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3.2.3. Modeling framework

The present is a consequential LCA study since it evaluates the environmental and

economic impacts due to a change occurring in the waste management system of the

packaging material.

The modeling of the study was implemented by applying the method of system

expansion with substitution. That means that the emissions of the avoided production

of byproducts/co-products are subtracted from the emissions of the analyzed system.

The subtraction takes place since the above byproducts/co-products do not have to be

produced from marginal resources. This approach usually leads to negative net

impacts which means that the savings are higher than the loads.

The quantitative substitution of the study’s plastic recycling downstream processes

was modeled based on the technical and market substitution. The technical

substitution refers to the material loss coming from the process while the market

substitution refers to the market acceptance of the secondary product 13

(Christensen et

al., 2011). The technical substitution in the study is around 76% and the market

substitution 90% in both types of recycling. The qualitative part was selected based on

the process of virgin plastic production which was substituted. The reuse of water in

the plastic recycling process was substituted with the avoided production of fresh

water from the waterworks.

Under the consequential way of thinking, the processes used for the electric and heat

production in Denmark were the marginal ones, since their production can change

quickly based on the different demands. The coal based energy is considered to be the

marginal energy in many European countries (Christensen et al., 2011). More

information about the exact processes used in the modeling of the technologies are

included in Chapter 4.

The upstream phase which is included in order to make the systems comparable, was

modeled with virgin PET as raw material. This occurred by considering a

consequential point of view and an unsaturated PET recycled market. For unsaturated

markets, when virgin plastic consumption is prevented (in the present case due to the

recycled content of the packaging) virgin PET that would otherwise be used in the

production packaging industry is available for other applications. Thus, under a

consequential point of view, it is expected that the excess of virgin PET will be used

in other applications.

3.2.4. System boundaries

The system boundaries define the processes which are included in the studied system

and separate them of the outer environment. The system boundaries of the present

study are depicted in Figure 9 while the analytical flowcharts for each scenario

separately are presented respectively in Figure 5-Figure 8. 13

Product (fully or partly) made with recycled material

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34

Vir

gin

PET

Pack

agin

g pr

oduc

tion

Man

ual d

ishw

ashi

ng WaterWastewater treatment So

rtin

g

Colle

ctio

n &

Tr

ansp

orta

tion Diesel

Tran

spor

tati

onDiesel

Mec

hani

cal R

ecyc

ling Electricity

Landfilling of residuals

Natural gas

Transport of residuals

NaOHWater

Wastewater treatment

Vir

gin

PET

Tran

spor

tati

on

Foil

prod

ucti

on

Vir

gin

PETDiesel Electricity

Tran

spor

tati

on Diesel

Recycling of scraps

Pack

agin

g pr

oduc

tion Electricity

Recycling of cut foil

Transport of cut foil U

se p

hase

Man

ual d

ishw

ashi

ng (1

9 ti

mes

)

Water

Wastewater treatment

Colle

ctio

n &

Tr

ansp

orta

tion

Aut

omat

ic d

ishw

ashi

ng

(19

tim

es)

Electricity Diesel

Was

te to

ene

rgy

inci

ners

atio

n

Transport of bottom ashWater

Detergent

Rinsing agent

Wastewater treatment

Bottom ash landfilling

Electricity

Incineration of residuals

Diesel

Transport of residuals

Transport of bottom ash

Bottom ash landfilling

Colle

ctio

n &

Tr

ansp

orta

tion Diesel

Was

te to

ene

rgy

inci

ners

atio

n Transport of bottom

ash

Bottom ash

landfillingV

irgi

n PE

T

Tran

spor

tati

on

Foil

prod

ucti

onDiesel Electricity

Tran

spor

tati

on Diesel

Recycling of scraps

Pack

agin

g pr

oduc

tion Electricity

Recycling of cut foil

Transport of cut foil U

se p

hase

Vir

gin

PET

Pack

agin

g pr

oduc

tion

Man

ual d

ishw

ashi

ng Water

Wastewater treatment

Sort

ing

Colle

ctio

n &

Tr

ansp

orta

tion Diesel

Tran

spor

tati

onDiesel

Mec

hani

cal R

ecyc

ling

&

Supe

rcle

anin

g

Electricity

Landfilling of residuals

Natural gas

Transport of residuals

NaOH

WaterWastewater treatment

Electricity

Incineration of residuals

Diesel

Transport of residuals

Transport of bottom ash

Bottom ash landfilling

Vir

gin

PET

Tran

spor

tati

on

Foil

prod

ucti

onDiesel Electricity

Tran

spor

tati

on Diesel

Recycling of scraps

Pack

agin

g pr

oduc

tion Electricity

Recycling of cut foil

Transport of cut foil U

se p

hase

Vir

gin

PET

Pack

agin

g pr

oduc

tion

Vir

gin

PET

Tran

spor

tati

on

Foil

prod

ucti

onDiesel Electricity

Tran

spor

tati

on Diesel

Recycling of scraps

Pack

agin

g pr

oduc

tion Electricity

Recycling of cut foil

Transport of cut foil U

se p

hase

Scenario 1

Scenario 3

Scenario 2

Scenario 4

Figure 9: System boundaries for the four scenarios of the study

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35

In the present study the system boundaries include the processes of plastic

packaging’s production, the relevant transportation and all the processes following

after the point that packages become waste until the final disposal to incineration or

recycling from where the output is flows.

Upstream productions i.e. energy and raw materials needed in the waste management

are also included in the boundaries of the study. In addition, downstream products

(e.g. wastewater and residuals waste) from the assessed waste management system are

accounted as well.

The construction and the end of life of the technologies and facilities are excluded

from the boundaries. The use phase is also excluded since it is equal for all the

scenarios.

The starting flow of the system boundaries is the production of virgin PET needed for

the production of the examined packaging (different amounts for the production of

reusable and one-use packaging).

The system boundaries of the LCC are identical with the LCA’s in order the two

analyses to supplement each other in the decision process.

3.2.5. General assumptions

The specific assumptions used in the modeling of the study are explained in detail in

Chapter 4. Some of the main assumptions thought are the following:

The studied packaging is made of transparent PET

The bottle grade PET, is used for the modeling of the virgin PET

For the modeling of the production of packages it is assumed that all the

scenarios have the production of 6.9kg (weight of 50 reusable packaging) and

only the upstream of the extra amounts is modeled for scenarios 1, 2, 3.

It is assumed that the recycled PET plastic market is unsaturated; meaning that

the current demand for plastic cannot be fulfilled with recycled plastic thus,

virgin PET needs to complete the demand.

It is also assumed that the transportation of the packaging from households to

the restaurants for the disposal of the one-use packages and the reuse of

reusable packages is combined on the way to work/supermarket etc. and thus

it is not modeled. In addition, it is assumed that the above transportation can

also take place by the delivery boy on his way back to the restaurant after the

delivery of a new order.

It is assumed that all the users of the packaging in scenario 2,3 and 4 follow

the step of washing the waste product before to send it back for recycling or

reuse. The followed type of washing is manual, including only the use of

water (without detergent), as it is a rough washing aiming to the removal of

the foodstuff.

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In the scenario of reuse, it is considered that there are no material losses due to

damages and all the boxes are returned back to the restaurant for reuse. For the

rest of the scenario it is respectively assumed that all the used packaging is

send for incineration or recycling respectively.

3.2.6. Impact Assessment criteria

In the present report, the impact method used for the calculation of the results is the

ILCD Recommended method and the modeling tool is EASETECH. The assessment

of the environmental performance was analyzed for all the impact categories of the

chosen method. The normalization of the results was performed with the

normalization factors of the method, as found in EASETECH in July 2013. The study

does not include weighting of the impact categories since it is a comparative study

intended to be publically disclosed (International Standardization Organization,

2006).

The chosen method is a combination of other existing impact methods and

environmental models which are considered to be the most suitable for the evaluation

of each impact category separately (European Commission-Joint Research Centre -

Institute for Environment and Sustainability, 2011). Based on that concept, the

particular method was decided to be applied for the calculation of the project’s results.

Table 7 presents the analyzed impact categories with the abbreviations used in the

present study, the respective normalization factors and the originating method.

The impact categories can be divided in three larger groups: non-toxic, toxic and

resource depletion group. The non-toxic group is consisted from the first 7 categories,

according to the Table’s order of appearance, the toxic group is consisted of the next

three impact categories and the last group is consisted of the last two categories.

A short description of the main contributors of each category sourcing from the waste

management systems is given in Annex A3 for the better interpretation of the results.

Concerning the economic part of the report, the assessment took place by converting

all the assessed costs and revenues to the present monetary value and by calculating

the net cost. The net cost of each process is calculated by summing up the costs and

the revenues of each process under the consumer’s or the payer’s perspective. The

final net cost of each scenario comes from the addition of the net costs of all the

processes included in the scenario. The currency of the study is Danish kroners

(DKK).

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Table 7: Impact categories with their normalization factors used in EASETECH in July 2013 and with the origin of the recommended impact category

Impact category Abbreviation in

current study

Normalization

factor

Origin/

description

1.Climate change CC 7.73E+03 IPCC 2007

2.Stratospheric ozone

depletion

SOD 2.05E-02 EDIP

3.Photochemical

oxidant formation

POF 5.29E+01 ReCiPe Midpoint

4.Terrestrial

acidification

TA 4.99E+01 ReCiPe Midpoint

5.Eutrophication

potential

EP 3.56E+02 CML 2001

6.Freshwater

eutrophication

FE 9.60E-01 ReCiPe Midpoint

7.Particulate matter PM 4.71E+00 Updated from

Humbert 2009 by

Laurent 2012

8.Human toxicity,

carcinogenic

HTC 3.25E-05 USEtox, DTU

updated version

9.Human toxicity,

non-carcinogenic

HTNC 8.14E-04 USEtox, DTU

updated version

10.Ecotoxicity, total ET 5.06E+03 USEtox, DTU

updated version

11.Depletion of

abiotic resources,

fossil

DARF 8.06E+04

CML 2012

12.Depletion of

abiotic resources

DAR 2.17E-01 CML 2013

3.2.7. Data source and technological scope

As already mentioned, one of the goals of the study was the acquisition of

representative data directly from the industry, for the modeling of the foreground

processes.

To begin with, the weight of the one- packaging was obtained by personal contact

with the Stick’s n Sushi manager (Gaard, 2013).

The data used for building up the packaging production process were obtained by

visiting the Donplast industry in Søro, in Denmark where the studied plastic

packaging is produced (Nielsen, 2013). The visit in the site except of the technical and

economic data, gave a visualization of the production process combined with useful

information about the different types of packaging made of recycled PET, the

transportation route of the produced packaging and the processes which need to take

place before the final production of the box.

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Following, the data used for the modeling of the production of the foil and the super

cleaning process were obtained after a multiple and continuous personal contact with

the relevant industry (Foil's Production Industry, 2013). A large volume of crucial

information concerning the composition of the different foils, technical parameters of

the super cleaning process, the specificity of the recycled plastic for food contact

applications as well as economic data were also provided by the same source. The

industry providing these data prefers to be kept unanimous.

The volume, the type of engine and the consumption of the trucks used for the

collection and transportation of the municipal waste to the incinerator are data

obtained directly from the Municipality of Copenhagen (Municipality of Copenhagen,

2013). The cost of the waste’s collection and transportation, the energy tax and the

gate fee paid to the incineration of Vestforbrænding were also obtained from the same

source (Municipality of Copenhagen, 2013).

Data concerning the truck used for the collection and transportation of the recyclable

material was obtained by personal contact with the Danskretursystem. Unfortunately

data concerning the applied processes in Danskereturnsystem as well as operational

costs were information denied to be given (Danskreturnsystem, 2013). Thus, the data

for sorting facility’s modeling was obtained by Perugini et al. (2005). The cost of the

process was estimated.

The transportation of the raw material to the foil’s production faciliy was based on the

consumption given by personal contact with the Foil's Production Industry (2013).

The transportation of the foil from U.K. to Donplast in Denmark was modeled

following the route indicated by Nielsen N. (2013).

The data for the modeling of the mechanical recycling process were obtained from

Perugini et al. (2005). The process of converting the flakes to pellets were modeled

with data obtained from Shen et al. (2010).

Processes applied to the background system were basically obtained from the

Ecoinvent, EASEWASTE’S or EASETECH’s database. The distances were estimated

from Google Maps (Google Maps, 2013).

The prices of the materials, as well as the capital costs and the gate fees were based on

many different sources including personal contact with the industry and the

Municipality of Copenhagen, various relevant reports, industries’ websites and

brochures, personal research in the Danish market and assumptions.

3.2.8. Time and geographical scope

The reference year for the comparison of the scenarios as well as for the costing of the

systems is 2013. Concerning the LCA part, when no data were available for this year

the used data tried to be as up-to-dated as possible without exciding the last decade.

Most of the data used for the setup of the foreground processes are collected during

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39

the reference year 2013 (e.g. packaging production process, foil production process,

transportation, and waste to energy process).

The geographical scope of the study focuses on two countries: Denmark (DK) and

United Kingdom (U.K). DK is the starting point for the assessed packaging waste

production. The choice of involving UK in the scenarios sources from the

representation of the actual studied processes. When no processes could be found for

two those countries European data were applied.

3.2.9. Critical review

The evaluation of the present thesis report by the external examiner can be considered

as critical review since the above person has not been involved in the implementation

of the project.

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4. Life cycle Inventory analysis (LCIA)

The present chapter focuses on the project’s data collection and the modeling of the

studied system according to the goal and scopes’ framework. The considered

assumptions are also included and explained. The inventory phase is the most effort

requiring and time consuming part of an LCA.

The quality of the used data, which is related to its representativeness, completeness

and precision, is of crucial importance. Technological, temporal and geographical

aspects must be taken under consideration for the appropriate selection of the data.

Obtaining specific data 14

is the best possible choice which is not thought always

feasible. The alternative is to use data or processes from other sources. The data used

in the modeling of the present study aimed to apply as much as possible to the above

parameters.

In the present study, EASETECH’s and EASEWASTE’s databases as well as

Ecoinvent database were used for the modeling of the background processes.

4.1. Studied packaging

The studied packaging is a one-use PET plastic box composed of a black bottom part

and a transparent cover used by the Sticks’n Sushi restaurants for the packaging of the

take-away orders. The restaurant uses a variety of packages differing on the shape and

the enclosed amount of food. The present study focuses to the most popularly used

box which weights 69g; 35g the bottom part and 34 the cover (Gaard, 2013). The

width of the above packaging is 5.5mm.

The reusable packaging is not used in the reality. It was assumed that the reusable

packaging weights double as one-use packaging does, according to the situation

occurring for the refillable bottles (Christensen & Fruergaard, 2011). It was also

assumed that the box can be reused 20 times according to the same source

(Christensen & Fruergaard, 2011). Thus, the reusable box’s weight was assumed to be

138g; 70g the bottom part and 68g the cover.

The black color used in the packaging could be major issue even in a closed loop

recycling15

(Foil's Production Industry, 2013). This problem occurs due to the Near

Infra-Red (NIR) sorting technology which is currently applied in the recycling plants

for sorting the PET (Foil's Production Industry, 2013). Carbon black which is the

main colorant for food contact packaging absorbs the NIR and cannot be sorted by the

above mentioned technology (Dvorak et al., 2011). That is the reason why some

companies are working on a masterbatch for black that overcomes the problem (Foil's

Production Industry, 2013). For all the above technical reasons, it is assumed that the

whole box is consisted of transparent PET plastic.

14

Specific data set refers to measured data representing the specific process/system 15

Closed loop recycling: The secondary good is used in the same application from where it case from

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4.2. Upstream processes

The upstream processes of all the scenarios include the foil production in UK, the

transportation of the produced foil to the packaging production facility in DK, the

transportation of the cut foils back to the foil’s production facility in UK for recycling

and the recycling of the scraps and the cut foil coming of the foil and packaging

production respectively. The virgin PET, the electricity and the diesel used as flows in

the foreground processes are produced by the background processes. Figure 10

depicts the upstream processes quantitatively and qualitatively.

The recycling is depicted through the avoided production of virgin PET. The process

was substituted with virgin PET and not of a lower quality of plastic, since both the

scraps and the cut foil are postindustrial plastics coming from virgin input and virgin

foil respectively. In the present report, the bottle grade PET, was used for the

modeling of the virgin PET. Differences between the types of PET can be found in

Annex B2.1. The credits for the recycling were counted in the different processes (foil

production, packaging production) according to the amount which was saved in each

facility.

The steps followed for the upstream production of the packaging were the same for all

the scenarios. However, the quantitative processes were not the same as Scenario

1,2,3 use a larger input amount of virgin PET than Scenario 4. As can be seen from

Table 6, the produced amount of one-use packaging for the first three scenarios was

69 kg while for the reusable packaging used in fourth scenario was only 6.9 kg.

Considering that both types of packaging are made of virgin PET it was assumed that

the production of 6,9kg took place for all the scenarios, thus only the extra amount

(62.1kg) needed to be modeled for Scenarios 1,2,3. The description of every used

process and flow together with the reason of its choice is analyzed in the following

sections of the chapter while Table 8 , summarizes the main characteristics of the

processes used in the upstream phase.

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Table 8: Characteristics of the processes used in the modeling of the upstream phase

Process Place Name of used process Numerical

info

Type of use Database

Virgin PET

flow

Polyethylene terephthalate, granulate, bottle grade, at plant, RER Ecoinvent

Foil

production

UK Electricity, production mix GB, GB 0.406kWh/kg Consumption Ecoinvent

Polyethylene terephthalate, granulate, bottle grade, at plant, RER 0.153kg/kg

input

Substitution Ecoinvent

Transportation

UK-DK

UK Transport Vehicle, 25t EURO5, motorway, 1 liter diesel, 2006 0.00001

l/km/kg

Consumption EASEWASTE

DK Transport Vehicle, 25t EURO5, motorway, 1 liter diesel, 2006 0.00003

l/km/kg

Consumption EASEWASTE

UK-

DK

Transport, transoceanic freight ship, OCE Ecoinvent

Packaging

production

DK Marginal Electricity Consumption incl. Fuel Production, Coal,

Energy Quality, DK, kWh, 2006

1kWh/kg Consumption EASETECH

Polyethylene terephthalate, granulate, bottle grade, at plant, RER 0.324kg/kg

input

Substitution Ecoinvent

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Foil production(Efficiency: 83%)

Packaging production

(Efficiency: 64%)

Electricity39.4kwh

Electricity 97.6 KWh

Diesel

Virgin PET117kg

Scraps

Cut foil

T

Virgin PET17.9kg

Diesel

Scenario 1,2,3

Transportation

Packaging 62.1kg

Inputs from the background processes

T

Foreground processes

Substitutions

Transportation

Inputs from the background processes

Output

Virgin PET31.5kg

Figure 10: Upstream processes as modeled in scenarios 1,2,3.

4.2.1. Virgin PET flow

The modeling of the upstream processes started with the creation of a flow

representing the Virgin PET pellets. As the EASETECH is software for the

assessment of waste management scenarios, the existing flows refer only to different

waste fractions. Thus, the virgin PET flow including the upstream impacts of its

production had to be created. The upstream impacts were modeled by using the

process: ‘’polyethylene terephthalate, granulate, bottle grade, at plant, RER’’ exported

from Ecoinvent database. The virgin PET pellets are bottle graded and constitute the

clearest and purest form of PET plastic; that is the reason why the above process was

chosen for the representation of their extraction. The data of the process refer to

European scope. Snapshots of the flow’s modeling in EASETECH can be found in

Annex B1.1.

4.2.2. Foil production

The represented facility of foil production is situated in UK and is involved in the

production chain of the studied packaging. The foil production process converts the

input plastic resins to roles of foil by melting and reforming the plastic.

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In the present case, the input material was virgin PET pellets which was converted to

virgin PET foil with an efficiency of 83%. Except from the plastic input, energy and

anti-block additives were needed to be added in the process. The presence of anti-

block additive prevents the blocking16

of the plastics while the electricity is used for

the melting and forming stage. In the present study the anti-block additive was not

modeled due to the negligible used amount per kilo of input. Data for the modeling of

foil production process were obtained directly from the industry (Foil's Production

Industry, 2013). Annex B2.2contains the detailed data.

The virgin PET flow was linked to the actual process of foil production, representing

the input of virgin PET pellets. The process used for the modeling of the electricity

was imported from Ecoinvent database and corresponds to the geographical scope of

the process. The modeled consumption was 0.406kWh/kg of input (Foil's Production

Industry, 2013).

The recycling of scraps, coming from the foil production process was modeled as the

avoided production of virgin PET. The process used for the substitution was the one

previously used for the production of virgin PET. The choice of the process was based

on the quality of the substitution (bottle graded PET) and the process’ European

scope. No transportation was needed to be considered here, since the scraps are the

postindustrial PET which is internally recycled in the industry (see Chapter 2.3.5.).

The market substitution for the recycled material in the foil production process is 90%

and the substituted amount is 0.153kg/kg 17

of input.

4.2.3. Transportation from the foil production facility in UK to the packaging

production facility in DK and vice versa

The foil’s transportation from the foil’s production facility in UK to the packaging

production facility in DK involves two changes and two different types of means:

truck and ship. According to information obtained of personal contact with the

involved facilities (Foil's Production Industry, 2013 ; Nielsen, 2013) the followed

route is: foil production facility (FPF) - Immingham port - Esbjerg port - packaging

production facility (PPF). The modeled distances were estimated from Google Maps.

Table 9 presents the starting and the ending destination, the used means of

transportation and the distances used for the modeling part.

Table 9: Transportation route, mean of transport and length of transported distance

Transportation route Mean of transport Length of distance (km)

FPF- Immingham Truck 229

Immingham- Esbjerg Ship 585

Esbjerg-PPF Truck 220

16

Blocking is a common problem met in plastic foil’s manufacturing and refers to the adhesion of two

adjacent layers of film 17

0.17*0.90=0.153

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The transportation of long distances is affected up to a great extent from the

transported distance and that is the reason why it was modeled based on fuel

consumption per kilo transported per kilometer (l/kg/km). The consumption used for

the transportation with truck in UK was 0.00001 l/km/kg (Foil's Production Industry,

2013) while for DK was 0.00003 l/km/kg (Sanchez Martinez & Møller, 2011).The

transportation with truck for both countries was modeled with EURO 5 engine trucks

applying to the real situation. The emissions of the process were transferred manually

from EASEWASTE’s database.

The process used for the modeling of the water transportation was a choice of

assumption since no relevant data was available. The process was imported from

Ecoinvent database and it was considered the most suitable for the suspended process,

among the few available ones. The environmental impacts of the above process are

dependent on the inserted transportation distance.

The same combination of means, technologies and distances was used for the

modeling of the transportation of the cut foil from DK to UK.

4.2.4. Packaging production

The represented packaging production facility is Donplast A/S, situated in Søro,

Denmark and is the site where the studied packaging is produced. The data needed for

the modeling of the process was obtained during the visit to the facility and by

personal contact with the company’s manager for additional information (Nielsen,

2013).

The process of production takes place in a thermoforming machine that can be

divided in different ‘’parts’’. Firstly, the foil passes by the heaters where it becomes

totally soft in order to be easily formed. In the second part, the desired forming tool 18

has been placed so as to form the foil in the desired shape of packaging. After this

step, the formed packaging is passed through the next part where a knife cuts the rest

of the foil. Then the packaging goes out of the machine where it is manually packed

in boxes. In the ending of the machine, the cut foil is turned through a cylinder in

order to be disposed in the container of its color, get granulated and send back to UK

for recycling as industrial post material. Cuttings are separated and granulated in

colors. Pictures of the visit in the facility and the different steps of the described

procedure can be found in Annex B2.3.1 together with some additional information

coming from the site.

The material inputs of the process are the foil and electricity. The efficiency of the

process19

was calculated to be 64% based on the average monthly foil’s consumption

and average monthly packaging production. Thus, the rest 36% is the cut foil which is

recycled in the foil’s production facility.

18

Forming tools are molds, used in order to give to the foil the desired shape (see Appendix B1.3.1.) 19

Efficiency of the packaging production refers to the packaging produced per kilo of used foil

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The process used for the modeling of the electricity consumption reflected the

geographical scope of the suspended process applying to Danish reality and it was

found in EASETECH’s database. The modeled consumption was 1kWh/kg (Foil's

Production Industry, 2013).

The recycling of cut foil was modeled as the avoided production of virgin PET. The

process used for the substitution was the one previously used for the recycling of

scraps in the foil’s production industry. The recycling of the cut foil was substituted

with bottle grade PET, since it is postindustrial material coming from virgin PET and

without having been mixed with other types of plastics. The market substitution for

the recycled material is 90%. Thus, the substituted amount was 0.324kg/kg 20

of input.

The transportation of the cut foil from DK back to UK was modeled with the way

described in Chapter 4.2.3. Snapshots of packaging production’s modeling in

EASETECH can be found in Annex B1.4.

4.3. Disposal phase

Opposite to the upstream production, the disposal phase contained different steps for

each scenario. Some of the processes however, were met in more than one scenario

and they were modeled with the same way, based on the same data and assumptions.

The following sections analytically describe all the modeled processes as they were

met in the course of the scenarios while Tables summarizing the modeled processes

included in each Scenario in order to give a clearer and quicker overview.

4.3.1. Waste packaging flow

The input of the disposal phase for all the scenarios was the used packaging together

with the stack foodstuffs on it, after the removal of the leftovers. The quantity input

thought, was different among the fourth and the rest of the scenarios, due to the

different type of packaging. Table 10 gives an overview of the qualitative and

quantitative description of the input flow.

The amount of foodstuff used for the study’s purposes was found in (Gilleßen et al.,

2013) and it corresponds to the amount of food used in standard EN 50242 21

for

scientific investigations for manual dishwashing. It was assumed an equal amount of

meat and vegetables in a total amount of 1.44 g of foodstuff per used packaging.

Additional information concerning the calculation of the amount and the type of

soiling, can be found in Annex C2.1.

20

0.36*0.90=0.324 21

The scientific investigations for manual dishwashing follow the standard EN 50242 in order to obtain

comparable results. The standard determines how the food has to be distributed on the studied dishes

and specifies the assessment of the study’s cleaning results (Gilleßen et al., 2013)

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Table 10: Characteristics of waste flow

Waste flow Number of

boxes

Plastic (kg) Foodstuff

(kg)

Total input

kg %

Scenario

1,2,3

1000 69 1.44 70.44 100

Plastic 69 98

Vegetables 0.72 1

Meat 0.72 1

Scenario 4 50 6.9 0.072 6.97 100

Plastic 6.9 99

Vegetables 0.036 0.5

Meat 0.036 0.5

The modeling of the waste flow included three fractions: plastic bottles representing

the virgin amount of plastic contained in the packaging, vegetable food waste and

animal food waste fractions representing the stack foodstuff. The last column of Table

10 depicts the values inserted in EASEWASTE, while the snapshots of the program

are presented in Annex C1.1.

4.3.2. Scenario 1

The disposal phase of Scenario 1 consisted of the collection and transportation of the

used packaging to the Vestforbrænding incineration plant. The bottom ash coming out

as a byproduct of the incineration process was transported to the mineral landfill

where it was landfilled. The visualization of the process is presented in Figure 5. The

EASETECH’S snapshot depicting the modeled scenario is presented in Annex C1.2,

while Table 11 summarizes the processes used for the modeling of the Scenario 1.

The enclosed processes of Incineration and Bottom landfilling processes can be seen

by the relevant program’s snapshots.

Table 11: Summary of the processes used in the disposal phase’s modeling of Scenario 1, together with basic characteristics

Process -Location Name of used

process

Numerical

info

Type of use Database

Collection and

transportation

DK Collection

vehicle, 10t

EURO5, urban

traffic, 1lt diesel,

2006

0.003 l/kg Consumption EASEWASTE

Waste

incineration

DK Waste

Incineration,

generic, DK, 2012

Includes

substitution

EASETECH

Transportation

to mineral

landfill

DK Transportation

Vehicle, 25t

Euro5, motorway,

1 liter diesel,

2006’’

0.00003 l

diesel/kg/km

Consumption EASEWASTE

Bottom ash

landfill

DK Bottom ash

landfill

EASETECH

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4.3.2.1. Collection and transportation of the waste to the Vestforbrænding plant

The collection of the packaging and its transportation to the Vestforbrænding

Incineration facility was modeled as one process and contrary to the transportation of

long distances, the collection’s modeling is based on the fuel consumption per

collected kilo (l/kg). The above consumption represents the amount of diesel used for

the waste collection from the first bin till the last bin and is basically depending on the

type of truck, the type of waste and the type of housing area covered (EASETECH

course 7-25 January 2013, 2013). The number of stops, the length of the covered

distance and the collection frequency are parameters included in the definition of

‘’housing area’’ and ‘’type of waste’’. Thus, it is not needed to know the exact length

of the collection route (EASETECH course 7-25 January 2013, 2013).

The diesel consumption for the present collection and transportation route together

with the volume and the type of truck used was information given by the Municipality

of Copenhagen 22

(2013). The collection vehicle used for the modeling of the process

was chosen to correspond as much as possible to the volume and the type of truck of

the real situation. The truck’s process was imported manually from EASEWASTE’s

database. The consumption used was 0.003 l/kg (Municipality of Copenhagen, 2013).

The snapshot of the modeling of the process in EASEWASTE can be found in

Appendix C.1.2.

4.3.2.2. Incineration with energy recovery in Vestforbrænding plant

The process used for the modeling of Vestforbrænding incineration plant was found in

EASETECH’s database. The process describes a Danish Incineration plant in 2012

whose flue-gas cleaning system is based on Vestforbrænding’s. The modeled plant

combines the production of heat and electricity with an efficiency of 22% and 73%

respectively. The substitution of the produced energy is included in the process. The

environmental impacts of the process are calculated by subtracting the emissions of

the substituted processes from the thermal plant’s emissions (EASETECH course 7-

25 January 2013, 2013). The EASEWASTE’s snapshot depicting the process’

included processes can be found in Annex C.1.2.

4.3.2.3. Transportation to the mineral landfill

The transportation of the bottom ash to the mineral landfill was modeled for a

transportation distance of 70 km and a diesel consumption of 0.00003 l diesel/kg/km

based on Danish data used in Sanchez Martinez & Møller (2011). The truck used was

the same as in Chapter 4.2.3 as it was assumed to apply to the same minimum engine

type’s demand of EYRO5 as the collection trucks do. Annex C1.2 includes the

EASETECH’s snapshot depicting the modeled process. 22

All of the currently used tucks are diesel powered, applying to a minimum demand of EURO5

engine. On average, a truck collects and delivers to incineration 5,5 tons of waste (Municipality of

Copenhagen, 2013)

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4.3.2.4. Bottom ash landfill

The process used for the modeling of mineral landfill was found in EASETECH’s

database and includes the modeling of leachate generation. The EASEWASTE’s

snapshot depicting the enclosed processes of the process can be found in Annex C1.2.

4.3.3. Scenario 2

The disposal phase of Scenario 2 includes the manual washing of the used packaging

at home, the collection of all the packaging from the restaurants and their

transportation to the sorting facility, the sorting and the compunction of the

packaging, the transportation of the bales to UK for recycling, the recycling process

and the waste treatment of the byproducts coming out of the sorting and the recycling

facility. The waste management of the residuals coming out of the sorting facility

include: the transportation of the residuals to the Vestforbrænding incineration plant,

the incineration of the waste in Vestforbrænding with the combined production of

electricity and heat, the transportation of the bottom ash to the mineral landfill and the

landfilling of the bottom ash. The present waste route concerning the waste

management of residuals was chosen based on the current Danish management

system which applies incineration with energy recovery. The waste management of

the residuals coming out of the recycling facility includes: the transportation of the

residuals to the sanitary landfill and the process of landfilling. The landfilling of the

residuals was chosen as waste management option since the recycling process takes

place in UK where landfilling is the dominant waste management option (The

environment Agency, 2013). The visualization of the process is depicted in Figure 6,

while the overview of the modeled processes together with basic information are

presented in Table 12. EASETECH’s snapshots depicting all the modeled processes

of the scenario can be seen in Annex C1.3.

4.3.3.1. Transportation to the restaurant

The transportation of the packaging waste to the restaurant was excluded of the

modeling process assuming that it was combined with a different route that had to be

done any way (e.g. on the way to work, supermarket, gym etc.). It was also assumed

that the packaging could be taken back to the collection point by the delivery-boy to

his way back to the restaurant, after the delivery of the new order. Therefore it was

assumed that the present transportation could be excluded from the study’s modeling.

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Table 12: Summary of processes used in the modeling of Scenario 2, Scenario 3, together with basic information

Process – Location Name of used process Numerical info Type of use Database

Manual

dishwashing

(Sc1,2,3)

DK Water from waterworks, Sweden, 2008 121.9 kg/kg

input

Consumption EASETECH

Treatment, sewage, to wastewater treatment, class 2, CH 0.1219 m3/kg

input

Consumption Ecoinvent

Collection and

transportation

DK Collection vehicle, 10t EURO5, urban traffic, 1lt diesel, 2006 0.003 l/kg Consumption EASEWASTE

Sorting facility DK Marginal Electricity Consumption incl. Fuel Production, Coal,

Energy Quality, DK, kWh, 2006

0.02488kWh/kg

input

Consumption EASETECH

Marginal Electricity Consumption incl. Fuel Production, Coal,

Energy Quality, DK, kWh, 2006

0.034kWh/kg

input

Consumption EASETECH

Forklift, combustion 1L of diesel, 2003/2011 0.002l/kg input Consumption EASETECH

Recycling * UK See Chapter 4.3.3.6 (Scenario 2) or Chapter 4.3.4.1.(Scenario3)

Transportation

UK-DK

UK Transport Vehicle, 25t EURO5, motorway, 1 liter diesel, 2006 0.00001 l/km/kg Consumption EASEWASTE

DK Transport Vehicle, 25t EURO5, motorway, 1 liter diesel, 2006 0.00003 l/km/kg Consumption EASEWASTE

UK-

DK

Transport, transoceanic freight ship, OCE Ecoinvent

Transportation to

the Sanitary landfill

UK Transportation Vehicle, 25t Euro5, motorway, 1 liter diesel, 2006’’ 0.00001 l

diesel/kg/km

Consumption EASEWASTE

Sanitary landfill UK Process-specific burdens, sanitary landfill, CH Ecoinvent

Transportation to

Incineration plant

DK Transportation Vehicle, 25t Euro5, motorway, 1 liter diesel, 2006’’ 0.00003 l

diesel/kg/km

Consumption EASEWASTE

Waste incineration DK Waste Incineration, generic, DK, 2012 Includes

substitution

EASETECH

Transportation to

mineral landfill

DK Transportation Vehicle, 25t Euro5, motorway, 1 liter diesel, 2006’’ 0.00003 l

diesel/kg/km

Consumption EASEWASTE

Bottom ash landfill DK Bottom ash landfill EASETECH

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4.3.3.2. Manual dishwashing

It was assumed that all the studied packaging was manually washed before to be

brought back to the restaurant. It was also assumed that the washing was more like a

flushing without including the use of soap or heated water. The modeled water

consumption was set to be 8.6 l/packaging according to Stamminger et al. (2007). The

used water-process was chosen based on its geographical scope since there was no

relevant process available depicting the Danish reality.

In addition to the water consumption, the modeling of the manual dishwashing

process included the wastewater treatment of the used water. No relevant process

could be found coresponding to the actual danish technology. Thus it was chosen a

relevant process of the Ecoinvent datbase which according to the description, refers to

a wastewater treatment technology for municipal wastewater applied in modern

plants in Europe. The choise of the secondary treatment plant (class 2) was made

based on Doka G. (2003) where 85% of the population in Denmark is connected to a

secondary or/and tertiary treatment plant. Thus an assumption was made that

Copenhagen is connected to a treatment plant of class2.

The removal of foodstaff during the washing process was modeled to be 66% based

on the cleaning efficiency of the study’s results of Stamminger et al. (2007).

The inserted numbers in the model were calculated based on the number of dirty

packaging consisting 1kg of input since EASETECH’s calculations are performed per

kilo of input. For the case of the single-use packaging, 1kg of input contains 14.2

packages. The analytical calculations of the cleaning efficiency and the model’s input

can be found in Annex C2.2 together with the obtained data from Stamminger et al.

(2007). Snapshots of the modeling of the process in EASETECH can be found in

Annex C1.3.

4.3.3.3. Collection and transportation of the packaging from the restaurants to the

Sorting facility

The collection of the waste packaging from the different restaurants and its

transportation to the sorting facility was modeled in the same way and based on the

same consumptions described in Chapter 4.3.2.1 for the collection and transportation

of the waste to the incineration plant.

4.3.3.4. Sorting facility

The Sorting facility of the study is placed in Denmark and it is considered to be the

Danskretursystem’ facility in Copenhagen which is responsible for the deposit and

return system (see Chapter 2.3.3).

Due to the fact that the real data was denied to be given, the modeling of the sorting

process was based on data obtained from Perugini et al. (2005). The modeled data

refer to a combination of manual and automatic operations coming directly from three

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52

Italian sorting companies (Perugini et al., 2005). Since the above mentioned data refer

to a collection process of PE and PET containers, their sorting efficiencies were added

assuming that both refer to PET. Therefore, the modeled sorting efficiency was 75%.

The Sorting facility’s modeling consisted of the electric energy needed for the sorting

of the plastic (0.02488 kWh/kg input), the electric energy needed for the compaction

of the plastic (0.034 kWh/kg input) and the diesel used as a fuel for the forklifts used

in the facility (0.002 l/kg input). The EASETECH’s snapshot depicting the modeling

of the process is included in Annex C1.3.

The consumptions used for the modeling of the process were given in MJ by Perugini

et al. (2005). Thus, the conversion of the MJ of diesel to l/kg input was occurred

based of the energy content of the diesel oil automotive23

.

4.3.3.5. Transportation from the Sorting facility in DK to the Recycling plant in UK

The transportation of the sorted PET waste from the Sorting facility in DK to the

Recycling plant in UK was modeled in the same way as described in Chapter 4.2.3,

with only difference the transported distances. The following route was assumed to

take place in the present transportation: Sorting facility to Esbjerg port- Esbjerg port

to Immingham port- Immingham port to Recycling plant by using the following

means respectively: truck, ship , truck. The modeled distances were estimated from

Google Maps. Table 13 presents the relevant transporting data.

Table 13: Transportation route, mean of transport and length of transported distance

Transportation route Mean of transport Length of distance (km)

Sorting facility-Esbjerg Truck 290

Esbjerg-Immingham port Ship 585

Immingham-Recycling plant Truck 230

According to information obtained by personal contact with the Danskretursystem

(Danskreturnsystem, 2013) the sorted plastic is transported with large trucks up to

48tn or small trucks up to 7.5tn of EURO4 or EURO5 engine. Thus, it was assumed

as average the same type of truck and the same consumption as described in Chapter

4.2.3. The part of the English transportation was based on assumption as previously

done (Chapter 4.2.3).

4.3.3.6. Mechanical Recycling process

The Recycling facility considered in the study is situated in UK and is one of the

companies which supply the Foil production facility with recycled PET. The data

used for the modeling of the recycling process were taken from Arena et al. (2003)

and Perugini et al. (2005), coming from on-side investigations. The efficiency of the

23

Diesel oil automotive contains 38.6 MJ/l, source: (Glenn Elert and his students, 2006, 2008)

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process was 76% and the same efficiency was also assumed for the removal of the

stack foodstuff.

The represented recycling process included a prewashing step, a magnetic separation

step in order to separate the ferrous material, a X-ray separation for the removal of

PVC, the washing step of the sorted PET, a flotation step for the separation of the

HDPE plastic, the drying of the cleaned PET and a final fine screening in order to

remove the very thin parts (Arena et al., 2003; Perugini et al., 2005). The prewashing

and the washing steps were realized by the use of water and NaOH solusion while the

flotation step by the use of water and chemicals. The chemicals used in the flotation

step were considered a cut off due to their negiglible amount. The wastewater coming

out from the washing, prewashing and flotation step was partly treated while part of

the treated water was reused in the washing and prewashing step. Figure 11, depicts

the modeled process while Table 14 summarizes the modeled processes consting the

recycling process.

PET-Reprocessing (Efficiency 76%)

Mechanical Recycling process

Wastewater treatment

3.75 kg

Fresh water 1.5 kg

1kg PETFresh water 4.5 kg

NaOH 0.002 kg

Methane energy 1.9MJ

Electric energy 0.8

MJ

0.76 kg R-PET flakes

Scraps 0.24kg

Wastewater 4.5 kg

Treated water taken for

reuse 1.5kg

Untreated wastewater

0.75kg

Treated wastewater

3.75kg

No reused treated

wastewater 2.25kg

Flows (input and output)

Processes

Substitution

Reuse

Virgin PP0.684kg

Figure 11: Mechanical Recycling process

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Table 14: Modeled processes consisting the Mechanical Recycling process

Name of used process Numerical info Type of use Database

Sodium hydroxide (NaOH), RER,

ELCD, 1996

0.002kg/kg input Consumption EASETECH

Water from Waterworks,

Sweden,2008

4.5kg/kg in put Consumption EASETECH

Water from Waterworks,

Sweden,2008

1.5kg/kg in put Substitution EASETECH

Electricity, production mix GB,

GB

0.224kWh/kg Consumption Ecoinvent

Natural gas in Industry Burner

(prod+comb), >100Kq, 1996

1.9 MJ/kg Consumption EASETECH

Waste water treatment, EU-27,

ELCD, 2003

3.75 kg/kg input Consumption EASETECH

Polypropylene, granulate, at plant,

RER

0.684kg/kg input Substitution Ecoinvent

The NaOH solusion used in the process contains 30% of NaOH. Thus, the amount of

modeled NaOH was calculated based on that consistency. The process chosen for the

treatment of the effluent water applies to industrial wastewater treatment in Europe

and as a matter of fact it is different than the one used in the dishwashing process.

Concerning the methane gas consumption, it was modeled as natural gas since methan

is the primary component of natural gas (EPA United States Environmental Protection

Agency, Last updated 9/9/13).

As explained in Chapter 3.2.3, the quantitative part of the recycling process’

substitution was modeled in the present study according to the technial and market

substitution. The output R-PET flakes were intended to be used for the production of

a recycled foil for electronic packaging. The foil consists of 90% recycled material

and 10% virgin 24

(Foil's Production Industry, 2013). Thus, the market substitution in

the present case is 90% and the technical substitution which depicts the recycling

process’ efficiency is 76%. Based on that, the quantitative substitution is 0.684kg/kg

of input while the qualitative substitution is the polypropylene (PP) production since

the electronic packaging would have been produced by PP if there was no recycled

PET available (Christensen & Fruergaard, 2011). The snapcoshot of the recycling’s

modeling is presented in Annex C1.3.

4.3.3.7. Transportation of residuals to the Sanitary landfill

The transportation of residual waste from the Recycling facility to the Sanitary

landfill was assumed to take place with the type of truck (25t, EURO5) and the diesel

consumption (0.00001 l/kg) described in Chapter 4.2.3 for the English road

transportation. The distance of the transportation to the Sanitary landfill, it was

24

The virgin part in this type of foil is used due to reprocessing reasons (Foil's Production Industry,

2013)

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assumed to be the same as the one used in Chapter 4.3.2.3 for the Bottom ash landfill

in DK. Snapshot of the modeling in EASETECH can be found in Annex C1.3.

4.3.3.8. Sanitary landfill

The process used for the representation of the Sanitary landfill’s emissions was

exported from Ecoinvent database. The process refers to Swiss technology which

according to the description applies to modern landfills in Europe for untreated

municipal solid waste. In Annex C1.3 can be found the model’s snapshot for the

process.

4.3.3.9. Transportation of residuals from the Sorting facility to Vestforbrænding

Incineration plant

The transportation of the residuals coming out as byproduct from the Sorting facility

were assumed to be transported to the Incineration plant with the same type of truck

and the same consumption as used for the transportation of the sorted plastic (see

Chapter 4.3.3.5.). The length of the distance was set to be 20km according to Google

Map’s estimations. Snapshot of the transportation’s modeling is included in Annex

C1.3.

4.3.3.10. Rest of the processes

The description of the rest of the processes included in the Scenario 2 (‘’ Incineration

with energy recovery in Vestforbrænding plant’’, ‘’Transportation to the mineral

landfill’’ and ‘’Bottom ash landfill’’) can be found in the Chapters 4.3.2.2, 4.3.2.3,

4.3.2.4 respectively.

4.3.4. Scenario 3

The processes included in Scenario 3 were the same as in Scenario 2 with the only

exception of the Recycling process which in the present scenario, was enhanced with

additional steps of decontamination. The description of the rest of the processes and

the way they were modeled can be found in Chapter 4.3.3 in the respective

subchapters. The overview of the modeled processes is presented in Table 12 while

the depiction of scenario can be seen in Figure 7.

4.3.4.1. Reprocessing of PET

The PET Reprocessing process includes the mechanical recycling process, followed

by the supercleaning of the recycled flakes and the partly pelletizing of the

supercleaned flakes. The overview of the process is depicted in Figure 12 while the

actual processes used for the modeling are presented in Table 15 and Table 16.

Snapshots of the modeling of the process in EASETECH, are included in Annex C1.4.

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PET-Reprocessing (Efficiency 76%)

PET Reprocessing process

Wastewater treatment

3.75 kg

Fresh water 1.5 kg

1kg PETFresh water 4.5 kg

NaOH 0.002 kg

Methane energy 1.9MJ

Electric energy 0.8

MJ

0.76 kg R-PET flakes

Scraps 0.24kg

Wastewater 4.5 kg

Treated water taken for

reuse 1.5kg

Untreated wastewater

0.75kg

Treated wastewater

3.75kg

No reused treated

wastewater 2.25kg

Flows (input and output)

Processes

Substitution

Reuse

Virgin PET0.67kg

Supercleaning (Efficiency 98%)

0.75 kg SCR-PET

flakes

Peletizing (Efficiency 96%)

0.166 kg SCR-PET pellets

0.72 kg SCR-PET

flakes

Figure 12: Flowchart of the ‘’PET Reprocessing’’ process

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The modeling of the Mechanical Recycling process was performed as described in

Chapter 4.3.3.6 by using the same data with only exception the quality and quantity of

the substituted process (see Table 15).

The hot washed R-PET flakes consisting the output of the mechanical recycling

process were fed to the Supercleaning Unit for further decontamination. The data used

for the modeling of the Supercleaning process represent a current applied technology 25

since it was obtained by personal contact with the industry (Foil's Production

Industry, 2013). The output of the Supercleaning process is supercleaned flakes ready

to be used for food contact applications. However, for the production of the SC-foil

for food contact applications, a combination of supercleaned flakes (SCR-flakes) and

supercleaned pellets (SCR-pellets) needs to be inserted due to reprocessing reasons

(Foil's Production Industry, 2013). Thus, a part of the supercleaned flakes was taken

for pelletizing. The amount of flakes which was modeled to be pelletized (23%) was

calculated according to the foil production’s consistency requirements. The data used

for the pelletizing process were obtained from Shen et al. (2010).

Table 15: Recycling in Scenario 3

Name of used process Numerical info Type of use Database

Sodium hydroxide

(NaOH), RER, ELCD,

1996

0.002kg/kg input Consumption EASETECH

Water from

Waterworks,

Sweden,2008

4.5kg/kg in put Consumption EASETECH

Water from

Waterworks,

Sweden,2008

1.5kg/kg in put Substitution EASETECH

Electricity, production

mix GB, GB

0.224kWh/kg Consumption Ecoinvent

Natural gas in Industry

Burner (prod+comb),

>100Kq, 1996

1.9 MJ/kg Consumption EASETECH

Waste water treatment,

EU-27, ELCD, 2003

3.75 kg/kg input Consumption EASETECH

Polyethylene

terephthalate,

granulate, bottle grade,

at plant, RER

0.67kg/kg input Substitution Ecoinvent

Pelletizing 0.165 kg/kg input Consumption See Table 16

Super Cleaning of PET

flakes

0.76kg/kg input Consumption See Table 16

25

The studied foil’s production facility owns a Supercleaning reactor which is used for the conversion

of the non-food grade R-PET flakes to food grade material. The modeled data refer to the performance

of the above mentioned reactor.

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Table 16: Modeling of Supercleaning and pelletizing process

Process Place Name of used process Numerical info Type of use

Super

Cleaning of

PET flakes

UK Electricity, production

mix GB, GB

0.12 kWh/kg

input

Consumption

Pelletizing UK Electricity, production

mix GB, GB

0.43kWh/kg Consumption

Natural gas in Industry

Burner (prod+comb),

>100Kq, 1996

0.24MJ/kg input Consumption

The efficiency of the supercleaning process is 98% (Foil's Production Industry, 2013).

Thus, the amount of R-PET which is send for supercleaning is 0.76kg/kg 26

of input.

The efficiency of the pelletizing process is 96% (Foil's Production Industry, 2013).

The modeled amount of pelletizing was 0.175kg/kg 27

input.

The substitution concerning the reprocessed PET of the present reprocessing process

differ both qualitatively and quantitatively compared to the one applied in the second

Scenario’s recycling. The output of the present process is a combination of

supercleaned flakes and pellets which are intended to be used for the production of

foil for food contact applications and following converted to new food packaging.

Thus, the process used for the virgin PET substitution was the same as used in the

upstream phase for substituting the virgin PET production.

The market substitution of the supercleaned recycled material is 90% as the

supercleaned foil consists of 10% virgin PET pellets and 90% supercleaned R-PET.

From the used R-PET, the 23% is coming from SCR-pellets and the 77% of SCR-

flakes (Foil's Production Industry, 2013). Thus, the technical substitution is 16.6% 28

for SCR-pellets and 58%29

for SCR-flakes ending to a total technical substitution of

74.6%. Taking all the above under consideration the substituted amount of virgin PET

for the process was 0.67 kg/kg 30

of input.

The substitution of the reused treated water was also modeled, in the present case,

following the same quality and quantity characteristics used in Chapter 4.3.3.6.

4.3.5. Scenario 4

The modeling of the scenario applies to the modeling of the reuse according to the

ILCD Handbook. The avoided production of plastic that occurs due to the reuse of the

packaging was taken under consideration during the modeling of the upstream

processes. Thus, in this part of the modeling no avoided production was needed to be

26

Since 0.76kg/kg of input is the output of the mechanical recycling process 27

0.76*0.98*0.23*0.96=0.165 28

0.23*0.96*0.75=0.166 29

0.75*0.77=0.58 30

0.90*0.746=0.67

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credited. The modeling of the scenario’s washing processes included the

consumptions corresponding to 19 washes in order to reuse the packaging 20 times.

The following subchapters describe the washing processes met in Scenario 4. The rest

of the processes are the same as the ones met in Scenario 1, described in Chapter

4.3.2, since the reusable packaging is taken for incineration after the reuse of 20

times. Table 17 summarizes the processes used in the modeling of the scenario

combined with some basic information.

4.3.5.1. Manual dishwashing

The manual dishwashing of the reusable packaging was modeled in the same way as

described for the one-use packaging (see Chapter 4.3.3.2). The only difference

between the two processes is that in the present case, the consumption of water

applied for 19 of cleaning. The way of modeling was also the same, by referring to the

consumptions of 1kg of input; in the present case 1kg of input includes 7.2 reusable

packaging (see Annex C2.2). The snapshot of the process can be seen in Annex C1.5.

4.3.5.2. Automatic dishwashing

All the packaging which is brought back to the restaurant were washed in a

dishwasher, in order to be ready for the next use. It was assumed that one reusable

packaging was reused for 20 times based to the fact that a reusable bottle can be

returned and refilled for approximately 20 times according to Christensen &

Fruergaard (2011). Thus, the modeling of all the processes included in the Automatic

dishwashing process referred to the consumptions for 19 washes. More information

about the process’ modeling can be found in Annex C2.3 while the snapshots of

EASETECH depicting the different parts of the modeling can be seen in Annex C1.5.

The Automatic dishwashing process included the consumption of water, detergent,

cleanser, rinsing agent, electricity and the treatment of the effluent water. All the data

for the above consumptions were obtained from Stamminger et al. (2007) and

Presutto et al. (2007). The consistancy of the detergent and the rinsing agent used in

dishwashers was modeled according to Presutto et al. (2007) and is presented in Table

18 and Table 19 together with the modeled processes which were exported from

Ecoinvent database.

The removal of foodstaff during the washing process was modeled to be 76% based

on the cleaning efficiency of the Stamminger reference study’s results (Stamminger et

al., 2007) (see Annex C2.2.).

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Table 17: Summary of processes used in the modeling of Scenario 4, together with basic information

Process -Location Name of used process Numerical info Type of use Database

Manual

dishwashing (Sc4)

DK Water from waterworks, Sweden, 2008 1170 kg/kg input Consumption EASETECH

Treatment, sewage, to wastewater treatment, class 2, CH 1.17 m3/kg input Consumption Ecoinvent

Automatic

dishwashing

DK Marginal Electricity Consumption incl. Fuel Production,

Coal, Energy Quality, DK, kWh, 2006

17 kWh/kg input Consumption EASETECH

Water from Waterworks, Sweden,2008 210 kg/kg in put Consumption EASETECH

Treatment, sewage, to wastewater treatment, class 2, CH 0.21 m3/kg input Consumption Ecoinvent

Detergent for dishwasher 0.34kg/kg input Consumption See Table 18

Rinsing agent for dishwashers 0.004kg/kg input Consumption See Table 19

Collection and

transportation

DK Collection vehicle, 10t EURO5, urban traffic, 1lt diesel,

2006

0.003 l/kg input Consumption EASEWASTE

Waste incineration DK Waste Incineration, generic, DK, 2012 Includes

substitution

EASETECH

Transportation to

mineral landfill

DK Transportation Vehicle, 25t Euro5, motorway, 1 liter

diesel, 2006’’

0.00003 l

diesel/kg/km

Consumption EASEWASTE

Bottom ash landfill DK Bottom ash landfill EASETECH

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Table 18: Input data and processes used for the modeling of 1kg of detergent for dishwasher, source: Presutto et al., 2007

Name of process Numerical info Database

Sodium tripolyphosphate, at plant/RER 0.55kg/kg input Ecoinvent

Sodium perborate, monohydrate, powder, at plant/RER 0.06 kg/kg input Ecoinvent

EDTA, ethylenediaminetraacetic, at plant/RER 0.02 kg/kg input Ecoinvent

Sodium silicate, spray powder 80%, at plant/RER 0.05 kg/kg input Ecoinvent

Ethoxylated alcohols,unspecified, at plant/RER 0.02 kg/kg input Ecoinvent

Sodium percarbonate, powder, at plant/RER 0.3 kg/kg input Ecoinvent

Table 19: Input data and processes used for the modeling of 1kg of rinsing agent for dishwasher, source: Presutto et al., 2007

Name of process Numerical info Database

Ethoxylated alcohols,unspecified, at plant, RER 0.15 kg/kg input Ecoinvent

Cumene, at plant/RER 0.115 kg/kg input Ecoinvent

Acetic acid, 98% in H20, at plant/RER 0.03 kg/kg input Ecoinvent

Water,dionised, at plant/CH 0.705 kg/kg input Ecoinvent

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5. Life Cycle Costing Inventory analysis

This Chapter presents the sources used for the implementation of the project’s

economic analysis and explains the calculations and the assumptions which led to the

final results. All the calculations were realized in Excel spread shits. Annex D2-D11

presents the detailed costing as estimated under the facilities’ point of view, while in

the following sections is mentioned the cost as considered under the present LCC’s

perspective. This LCC accounts all the costs through the product’s lifecycle from the

perspective of the consumer in the upstream phase and the perspective of the one who

pays the costs for the waste treatment.

When it comes to the economics, it is always difficult to obtain the precise data from

the industry mainly due to competitive reasons. The results of the present economic

study are an approximation of the real costs since the calculations were based on

prices from various sources. The above sources include personal contact with the

industry, personal contact with the Municipality of Copenhagen, various relevant

reports, industries’ websites and brochures, personal research in the Danish market

and assumptions.

For the evaluation of the capital costs, the payback time for the equipment and

vehicles was set to be 7 years with a rate of 7% according to Presutto et al. (2007).

Only exception to that is the life time of the collection truck which set to be 5 years

according to specific information obtained from the Municipally of Copenhagen

(2013). The respective time for the buildings set to be 15 years with the same rate

(Presutto et al., 2007).

According to Presutto et al. (2007) the maintenance and repairs of the equipment and

the trucks was set to be 5% of the respective annual capital cost, in case no specific

numbers could be found. The economic data broadly applied in the operational

costing of most of the processes (e.g. water, electricity, diesel, gas, salaries etc.) are

presented in Annex D1. The operational costs were mainly calculated according to the

consumptions of the LCA part of the study.

The end of life cost was assumed to be negligible compared to the other costs so it

was excluded from the study. The only exception concerns the life cycle costing of

the sanitary landfill. For this side it was considered that the end of life costs is

important to be considered since it is enclosed on the charged landfilling fee.

When no reference year was mentioned in the source of the data, it was assumed that

the information are also valid for the present year. It was also assumed that since

2009, the prices in the building sector and equipment’s prices stayed the same.

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5.1. Upstream processes

The costing applying to the upstream processes was calculated for the actual

quantities used in each scenarios and not for the modeled ones31

. All the costs of the

upstream phase are enclosed in the costing of packaging production. This occurs

since the cost of the used foil which is included in the operational cost of the

packaging production, encloses the costs of the transportation and the foil production.

The cost of the production of the PET and its transportation to the foil production

facility is respectively already included in the cost of the foil. Thus, the cost that the

consumer pays in this phase is the one for buying the packaging.

The cost considered in the LCC is the revenues from packaging production facility’s

sales (31.4 DKK/kg packaging) since it depicts the price that the consumer has to pay.

Table 20 presents the costs considered in the LCC study for the upstream processses.

The costs depict the reality as they were obtained by the visiting to the industry’s

facility.

The estimated life cycle costing of the foil production and packaging production

facility’s together with the relevant assumptions can be found in Annex D2 and D3

respectively.

Table 20: Life cycle costing for packaging production under the consumer’s perspective, presented in an synoptic way

Costs DKK/kg of packaging produced

Costs 31.4

Revenue 0

Net cost 31.4

5.2 Disposal processes

The LCC estimations in the present phase, were implemented under the waste

treatment’s perspective, meaning that represent the money that have to be spend by

the municipality/consumer/waste management operator for the treatment of the waste.

The costs and the revenues of the recycling facility are also included in the LCC

althougt, there is not a gate fee to the facility in order to consider the economical

benefit of the process.

5.2.1. Collection

The combined collection and transportation process is met in all the scenarios and can

be divided in two different routes. In Scenario 2 and 3 the plastic waste is collected

from the restaurants and transported to the sorting facility while in Scenario 1 and 4 it

is transported to the incineration plant. Both routes take place in DK and are modeled

31

It is reminded, that in the modeling part, it was assessed the difference of the upstream processes

between the first three scenarios and scenario 4

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with the same diesel consumption and the same type of truck (see Chapter 4.3.2.1.).

Based on the above, it was assumed that both routes cost the same.

The fee paied to the company which collects and transports the waste to the facilities

was considered revenue for the company but cost for the LCC study. The cost of the

fee paied for the collection and transportation of the waste to the incineration facility

is 1032 DKK/tn according to Municipality of Copenhagen (2013).

Table 21 depicts the costs and the revenues of the process under the LCC’s

perspective while the detailed calculation applied to the transportation company’s life

cycle costing are included in Annex D4.

Table 21: Life Cycle costing for waste collection, under the payers’ point of view

Costs DKK/kg transported

Costs 1.0

Revenues 0

Net cost 1.0

5.2.2. Transportation

As already described in Chapter 4, many different types of transportation take place

for the different scenarios. The transportation cost can vary according to the

distance’s length of the transportation distance and the types of mean used. The costs

are also different between the countries. Thus, in the present case three different type

of transportation were estimated: the transportation of the residuals of the recycling

process to landfill (UK), the residuals of the sorting facility to the incineration plant

(DK) and the combined transportation of the three means between the two countries

(UK-DK). The transportation of the bottom ash to the mineral landfill was assumed to

be included in the incineration fee, thus was not separately estimated.

Due to lack of information concerning the fee paid to the transportation company, it

was assumed that the paid fee for each transportation route is 2.4 times larger than the

transportation’s actual cost (under the company’s point of view) according to the

situation applied for the collection of the waste (Annex D4). Thus, this estimated fee

which is the company’s revenue, it represents the cost in the LCC, under the payer’s

perspective.

Concerning the life cycle costing of the road transportation companies, it was

estimated based on the assumptions and costs described in Annex D5. Concerning the

combined transportation of the three means (truck-ship-truck) between the two

countries, the calculation of its cost was estimated based on the difference between

the selling and buying foil's price from the studied companies, since it was assumed

that this difference occurs due to the enclosed transportation from UK to DK. It was

also assumed that the cost of transporting the foils from the FPF in UK to PPF in DK

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is the same with transporting the sorted plastic from the Sorting facility in DK to the

Recycling facility in UK.

Table 22- Table 24 depicts the costs and the revenues of the transportation under the

LCC’s perspective while the detailed calculation applied to the transportation

company’s life cycle costing are included in Annex D5.

Table 22: Life cycle costing for Transportation of the residuals (coming from the Sorting facility) to the Incineration plant (DK) under the payers’ point of view

Costs DKK/kg

Total costs 0.56

Revenue 0

Net cost 0.56

Table 23: Life cycle costing for Transportation of the residuals (coming from the Recycling plant) to the landfill (UK) under the payers’ point of view

Costs DKK/kg

Total costs 0.56

Revenue 0

Net cost 0.56

Table 24: Transportation from UK to DK and vice versa under the payers’ point of view

Costs DKK/kg

Total costs 0.55

Revenue 0

Net revenue 0.55

5.2.3. Mechanical Recycling

The cost of sorted plastic, which actually includes the costs of the Sorting facility, is

enclosed in the costing of mechanical recycling process since it is included in the

operational cost of the recycling. The cost of the transportation of the sorted plastic to

the recycling facility was calculated separately as already explained in Chapter 5.2.2.

and it was not considered to be included in the purchase price of the sorted plastic,

paid by the recycling to the sorting facility. The estimated life cycle costing of the

Sorting facility together with the relevant assumptions can be found in Annex D6. In

the present case the facility’s LCC is identical with the waste management operator’s

perspective, assessed in the present study.

The cost estimation for the function of the Mechanical Recycling facility was based

on the assumptions and the investment costs of Axion Consulting (2009) refering to

the English reality. In the present analysis were considered only the machines and the

equipment beeing used for the recycling of PET and not for the rest types of plastic,

assessed in the reference report. The geographical scope of the data source fits which

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the studied facility (UK). The capacity of the represented plant is the process of

80000t/y.

For the operational and maintenance costs it was assumed that all the sections of the

plant run on a 24 hour basis, for 7 days per week, manned with 3 shifts of operators.

The revenue of the recycling facility sources from the hot washed flakes sold to the

industries. The price used in the calculations was given by the Foil's Production

Industry (2013) and it is represenbtative for the English reality.

Table 25, presents the overview of the costs and revenues of the facility, while the

detailed calculations can be found in Annex D7. The minous in the net cost shows that

the facility makes profit.

Table 25: Life cycle costing for Recycling facility, presented in an synoptic way

Costs DKK/kg produced

1.Capital cost 0.2

2.Operational and maintenance costs 2.6

Revenues -7.5

Total costs 2.8

Net cost/ Net revenue -4.6

5.2.4. Mechanical Recycling followed by the supercleaning process and partly

pelletizing

The life cycle costing of this type of enhanced recycling process was calculated based

on the same data and the same assumptions considered in Chapter 5.2.3. Therefore,

the capital cost in the present process were the same as before, with the addition of the

Supercleaning reactor’s cost. The reactor’s cost was assumed to be the same as the

cost of ‘’Bale breaking and NIR/colour sorting section’’ due to lack of data.

Moreover, there are some differences in the operational and maintenance costs, since

they were calculated based on the input used for the modeling of the LCA part. Thus,

more energy is consumed in the present case due to the supercleaning and pelletizing

process. The repair and maintenance costs are also different since they are calculated

based on the capital cost.

The revenues come from the SCR-pellets and the SCR-flakes. The price used in the

revenue’s calculation was the one given by the Foil's Production Industry (2013),

corresponding to the SCR-pellets.

The detailed life cycle costing calculations of the process can be found in Annex D8.

Table 26, presents the overview of the estimated facility’ costing which is the same

with the waste management operator’s perspective, as in the previously mentioned

case (Chapter 5.2.3). The minous in the net/revenue cost shows that the facility makes

profit.

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Table 26: Life cycle costing for the Recycling facility including supercleaning and pelletizing, presented in an synoptic way

Costs DKK/kg produced

1.Capital Costs 0.3

2.Operational and maintenance costs 2.6

Total costs 2.9

Revenues -8.4

Net cost/net revenue -5.5

5.2.5. Incineration in Vestforbrænding

Based on the fact that the Danish state-owned waste management companies are not

allowed to make profits, it was assumed that the net cost of the studied facility is the

incineration gate fee. The revenues in the present case come from the gate fee paid

and the energy production (heat and electricity). The incineration gate fee for the

Vestforbrænding Incineration is 90 DKK/ton (Municipality of Copenhagen, 2013).

The cost of the transportation of the bottom ash to the mineral landfill and the cost of

the bottom ash landfilling were assumed to be included in the paid incineration fee.

According to Dominic Hogg & Eunomia Research & Consulting, the bottom ash

landfilling in DK costs 0.25DKK/kg.

5.2.6. Landfilling in UK

The gate fee including the relevant taxes considered as net cost for the facility was set

to be 741.9DKK/ton according to the English data of WRAP (2012). The landfill tax

was set to be 560DKK/kg according to the same source (WRAP, 2012). The detailed

life cycle costing estimations for the facility can be found Annex D9.

5.2.7. Manual Dishwashing

The cost of the manual dishwashing was calculated based on the consumption of the

water modeled in the LCA part of the study. Additionally to that the estimation of the

life cycle costing of the process contained the used brush/sponge as a capital cost. The

price for the brush/sponge was estimated based on personal research on the Danish

market in July 2013 (see Annex D1.4.). It was assumed that one brush/sponge can

wash 200 items.

The cost of manual dishwashing is the same for both types of studied packaging;

reusable and one-use and it is presented in Table 27. There are no revenues in the

process and thus there is a net cost.

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Table 27: Life cycle costing for the manual dishwashing washing process, presented in an synoptic way

Costs DKK/packaging DKK/1000

packaging

DKK/50

packaging

1.Capital cost 0.087 87 4.4

2.Operation costs 0.34 336 16.8

Total 0.42 423 21.2

Revenues 0 0 0

Net cost/Net Revenue 0.42 423 21.2

5.2.8. Automatic Dishwashing

The operational cost of the dishwasher was calculated based on the consumptions

used in the modeling of the respective process (Chapter 4.2.5.2). The cost of the

detergent and the rinsing agent was estimated based on personal research of the prices

applied in the Danish supermarkets in July 2013. The result of the research was

0.17DKK/washing and 1.15 DKK/washing for the rinsing agent and the detergent

respectively (see Annex D1.4).

The investment cost of the washing machine was estimated to be 4294DKK, based on

personal research to the Danish market in July 2013, concerning dishwashers of class

A+ (see Annex D1.4). The maintenance cost was assumed to be 37DKK/year

according to Presutto et al. (2007). For the estimation of the maintenance cost per

washing cycle, it was assumed that a machine performs 280 cycles/y (Presutto et al.,

2007). The present process considers no revenues. Table 28, presents the overview of

the costs.

Table 28: Life cycle Costing for the automatic washing process, presented in an synoptic way

Costs DKK/ packaging DKK/50packaging

1.Investment costs 0.12 6.2

2.Operational and maintenance costs 0.42 21.1

Total costs 0.54 27.3

Revenues 0 0

Net Revenues 0.54 27.3

5.3. Assessed Scenarios

The monetary costs of the scenarios were calculated based on the estimated costs of

the previously mentioned sections of the Chapter. The economic analysis of the study

followed as far as possible the same boundaries with the LCA part. Table 25 presents

the costing overview of the assessed scenarios.

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Table 29: Life Cycle Costing of scenarios presented in a synoptic way

Costs (DKK) Revenues (DKK) Net cost/ net revenue (DKK)

Scenario 1 2241 0 2169

Scenario 2 2820 -294 2537

Scenario 3 2820 -328 -2504

Scenario 4 272 0 273

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6. Results

The present chapter presents and discusses the environmental and economic

performances of the assessed scenarios. The characterized and normalized results are

presented in Annex E1 and E2 respectively while the costs included in each scenario

can be found in Annex F1-F5.

6.1 Environmental assessment

The environmental results were obtained by applying the ILCD Recommended

method in EASETECH software, 2.0.0 Internal Institute Version (July 2013). The

negative values represent savings while the positive ones represent loads.

The analysis of the environmental results begins with the presentation of the total

potential impacts in order to find out the general performance of the scenarios.

Following, the contributors of the impacts are presented in order to find out the

sources of the burdens and the savings in each impact category, in each scenario.

The composition of the impacts is consisted of 11 different source-contributors:

Bottom ash landfill, Manual dishwashing, PET reprocessing, Sanitary landfill, Sorting

facility, Waste incineration, Automatic dishwashing, Packaging production,

Production of virgin foil and Virgin PET pellets. The categories represent the

processes as described in Chapter 4 with only difference the ‘’Collection and

transportation’’ category which in the present Chapter includes the collection of waste

and all the types of transportation involving in the scenario. The PET Reprocessing

process refers to the two different types of recycling applied in scenario 2 and 3.

A deeper sight in the contributing sources is presented in Annex E3.2. where the most

loading and most saving process included in each source-contributor are mentioned.

For the source-contributors which contained only emissions, the main loading

substance contributor was spotted and presented in in Annex E3.1

In order to have a clearer and more precise overview of the results, they are divided

and presented in three groups: non-toxic impact categories, toxic impact categories

and depletion of abiotic resources. The results are reported in milli personal

equivalent per functional unit (mPE/ F.U.). The results presented in the main part of

the report are the normalized results for comparative reasons.

6.1.1. Non-toxic potential impact categories

Figure 13 depicts the net environmental impacts in non-toxic categories for all four

scenarios. It can be seen that all the scenarios contribute net burdens in all the

categories. Climate change is the impact category with the highest contributions while

Stratospheric ozone depletion is the category with the lowest. A more clear figure of

SOD can be seen in Annex E4.

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Figure 13: Total net impacts in non-toxic impact categories

As a general outcome, it can be said that Scenario 4 is the least burdening scenario for

all but one impact category (FE), opposite to Scenario 2 which appears with the

largest burdens in four out of seven categories. Scenario 2 is followed by scenario 1

which burdens the most in two out of seven categories.

Between the two recycling scenario, Scenario 3 which combines the conventional

recycling with the supercleaning process appears to be the most environmental

friendly, in all the categories.

In Figure 14 is depicted the origin of the savings and the burdens met in each scenario

in the different impact categories. As a first conclusion from the graph it can be

mentioned that in most impact categories the largest burdens sourcing from the

‘’Virgin PET pellets’’ for Scenarios 1,2,3 and from ‘’Automatic dishwashing’’ for

Scenario 4. The main source of savings appears larger quantity variations depending

on the scenario and the assessed impact category. The savings origin from

‘’Packaging production’’, ‘’PET Reprocessing’’, ‘’Production of virgin foil’’ due to

the recycling of plastic linked to the avoided production of virgin plastic and from

‘’Waste Incineration’’ due to the production of electricity and heat.

Since the upstream production processes (production of foil, packaging production,

Virgin PET pellets) is common for scenario 1,2 and 3, every impact category that

appears contributions (savings or loads) sourcing from the above processes are

numerically equal for all three scenarios.

The difference between the savings of the ‘’PET Reprocess’’ between the two

recycling scenarios (Scenario 2 and 3), shows that the Virgin PET production

contributes with more loads to the environment than the production of virgin PP and

thus the substitution of virgin PET leads to more savings.

0

5

10

15

20

25

30

35

40

CC SOD POF TA EP FE PM

mP

E/ F

.U.

Non-toxic impact categories

scenario 1scenario 2scenario 3scenario 4

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Figure 14: Composition of impacts in non-toxic impact categories

-20

-10

0

10

20

30

40

50

sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4

Climate change Stratospheric ozonedepletion

Photochemicaloxidant formation

Terrestrialacidification

Eutrophicationpotential

Freshwatereutrophication

Particulate matter

mP

E/F.

U.

Composition of impacts in non-toxic impact categories

Automatic dishwashing Virgin PET pellets Production of virgin foil Packaging production

Waste Incineration, DK Sorting facility Sanitary landfill PET Reprocessing

Manual dish washing Collection and transportation Bottom ash landfill Total

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6.1.1.1.Climate change

In the present impact category, Scenario 1 is the most loading contributive scenario

contrary to Scenario 4 which contributes with the least burdens. The main burdens for

the first three scenarios originate from the production of the Virgin PET pellets where

the carbon dioxide is the dominant substance-contributor. In Scenario 4 the automatic

dishwashing is the process with the largest burdens mainly due to the electricity

consumption.

Scenario 3 is the scenario which saves the most in the category. The greatest benefit

for Scenario 2 and 3 sources from the PET Reprocessing process due to the recycling

of plastic which is linked to the avoided production of virgin PP and PET

respectively. Scenario 3 has larger savings than Scenario 2 due to the different type of

plastic which substitutes. All the scenarios and especially Scenario 1, get benefited by

the incineration process mainly due to the electricity production. Savings in Scenarios

1,2,3 are also equally enhanced by the production of virgin foil due to the recycling of

postindustrial PET which is included in the process.

6.1.1.2. Stratospheric ozone depletion

The present category has negligible contributions compared with the rest of the non-

toxic categories. A more clear Figure of the category can be found in Annex E4, from

where it can be seen that Scenario 2 is the most loading scenario, opposite to Scenario

4 which is the least burdening scenario in the present impact category.

The dominant loading contributor for Scenarios 1, 2 and 3 is the Virgin PET pellets

production mainly due to air emission of methane, bromochlorodifluoro, Halon1211.

For Scenario 4 the main burden sources from automatic dishwashing due to the

detergent’s use.

Concerning the largest saving of the category, it appears to Scenario 3 sourcing

mainly from the PET Reprocessing process due to the avoided production of virgin

PET. For Scenario 1 and 2 the main saving-process is the production of virgin foil due

to the included recycling. Scenario 4 saves only from the incineration process mainly

due to the electricity production (Annex E3.2.1).

6.1.1.3.Freshwater eutrophication

Scenario 4 has a protagonist role in the present category as it includes emissions both

from manual and automatic dishwashing processes. Oppositely, Scenario 1 has the

least impacts in the category since no manual or automatic dishwashing is involved.

The main load-source in Scenario 4 is the automatic dishwashing mainly due to the

use of detergent (Annex E3.2.1). Contrary, Scenario 1 has the least contributions

among the scenarios, with Virgin PET production being the most loading process due

to the phosphide emitted in water compartments. The most burdening process for

scenario 2 and 3 is the manual dishwashing due to the wastewater treatment process

(Annex E3.2.1).

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The category appears savings in the first three scenarios, with Scenario 2 saving the

most due to the Reprocessing process and the avoided production of virgin PP.

6.1.1.4.Other non-toxic categories

Since the rest of the categories are affected by the same sources, the trend of their

impacts is almost the same and thus they are discussed together.

In POF category the first scenario is the most burdening one, while in the rest three

categories Scenario 2 is the respective most loading scenario. For all the impact

categories, Scenario 4 is the most environmental friendly scenario.

In all four categories, the main source of impacts for the first three scenarios is the

production of virgin PET. NOx is the main substance-contributor of the extraction

process burdening in the EP and POF categories while the respective dominant

contributor in TA and PM categories is the SOx substance (Annex E3.1.). For

Scenario 4 the largest load in all the impact categories, comes from the automatic

dishwashing due to the electricity consumption.

For POF, TA and EP categories, the main saving-source process for Scenario 1 and 4

is the waste incineration due to electricity production in the first category and due to

heat production in the following two categories (Annex E3.2). For scenario 2 and 3

the processes of packaging production and PET Reprocessing respectively is the main

saving process, due to the avoided production of virgin PET in both cases.

The PM category follows the same saving course with the exception of Scenario 1

where the main saving process is the packaging production.

6.1.2. Toxic potential impact categories

Figure 15 depicts the net environmental impacts in toxic categories for all four

scenarios. It can be seen that all the scenarios contribute in total net burdens in all the

categories, as in the non-toxic impact cases.

Human toxicity, carcinogenic (HNC) is the category with the highest loads opposite

to Ecotoxicity, total category (ET). Scenario 2 burdens the most in all three categories

while Scenario 4 contributes the least in two out of three categories, followed by

Scenario 1. As can be seen from the graph, the impact categories where Scenario 4 is

the most environmental friendly scenario are the HTC and ET categories.

Figure 16 depicts the source-processes of savings and loads for each scenario for all

the toxic categories.

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Figure 15: Total net impacts in toxic impact categories

As it can be observed from the graph, the dominant burdening process for Scenario 1,

2 and 3 is the production of virgin PET pellet process. Based on Annex E3.1 the main

contributive substance of the above process is Chromium released in water for HTC

category, emission of Zinc in air for HTNC category and Vanadium released in air for

ET category. For Scenario 4, the respective main loading process is either the

automatic dishwashing or the manual dishwashing depending on the assessed impact

category. For the HTC category the automatic dishwashing is the most contributive

process due to the use of detergent and mainly due to the released chromium in water.

For the other two toxic categories the manual dishwashing is the most burdening

process because of the wastewater treatment effects and mainly due to the Zinc which

is released in soil and in water respectively.

Figure 16: Composition of impacts in toxic impact categories

0

10

20

30

40

50

60

70

80

90

HTC HTNC ET

mP

E/ F

.U.

Toxic impact categories

scenario 1

scenario 2

scenario 3

scenario 4

-100

-50

0

50

100

150

200

sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4

HTC HTNC ET

mP

E/F.

U.

Composition of impacts in toxic impact categories

Automatic dishwashing Virgin PET pellets Production of virgin foilPackaging production Waste Incineration, DK Sorting facilitySanitary landfill PET Reprocessing Manual dish washingCollection and transportation Bottom ash landfill Total

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Concerning the savings, all the above impact categories get mostly benefited by the

same processes. The basic saving-process in Scenario 1 and 2 is the packaging

production and in Scenario 3 is the PET Reprocessing process, where the benefits

come from the avoided emissions of virgin PET’s production. More precisely,

Scenario 1 and 2 gets mainly benefited in HTC category by the avoided releasing of

Chromium in the water, in HTNC by the avoided emission of Zinc to the air and in

ET by the avoided emission of Vanadium in air. Scenario 3 mainly saves in HTC and

ET categories grace to the avoided releasing of Chromium in water and in HTNC

grace to the avoided releasing of arsenic ion in water. Scenario 4 saves due to waste

incineration, sourcing mainly from the electricity production.

6.1.3. Resource depletion

Figure 17 depicts the net impacts of the resource depletion categories. Scenario 2 is

the most loading scenario in DAR category while Scenario 1 is the most burdening in

DARF category. Scenario 4 is the least burdening scenario in both categories.

Figure 18 represents the composition of the impacts of depletion resource categories.

In the DAR category, the main contributive process for the first three scenarios is the

Virgin PET pellets production especially due to the gold depletion which is related

with the process (Annex E3.1.). For Scenario 4 the main burdening source is the

Automatic dishwashing process mainly due to the use of detergent (see Annex

E3.2.3). The largest saving of the category comes from Scenario 3 mainly due to

‘’PET Reprocessing’’ sourcing from the avoided PET production. Scenario 4 has no

savings.

Figure 17: Total net impacts of depletion of abiotic resources

0

10

20

30

40

50

60

70

80

Depletion of abiotic resources Depletion of abiotic resources, fossil

mP

E/ F

.U.

Depletion of abiotic resources scenario 1

scenario 2

scenario 3

scenario 4

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Figure 18: Composition of impacts in depletion of resources

In the DARF category the most burdening scenario is the first one due to the Virgin

PET pellets’ production and basically due to the crude oil’s consumption. Scenario 2

and 3 have the same dominantly loiading process as Scenario1. Scenario 4’s most

burdening process is Automatic dishwashing, due to the electricity consumption. The

largest savings in the category come from Scenario 3, mainly due to avoided

production of Virgin PET pellets and the avoided consumption of crude oil.

6.2. Cost assessment

In accordance with the LCA part the positive values represent the costs while the

negative ones the revenues. The exact values of each scenario’s costing can be found

respectively in Annex F1-Annex F4.

Figure 19 depicts the net cost of each scenario. It can be observed that Scenario 2 is

the most costly scenario opposite to Scenario 4. Scenario 2 and 3 have a similar cost,

with Scenario 2 being 1.3% more expensive than Scenario 3. A large monetary

difference can be observed between Scenario 4 and the rest of the scenarios.

The composition of the net cost is visualized in Figure 20 separately for each scenario

in order to give a better overview of the origin of the costs. The composition of the

costs and the revenues is consisted of 7 different categories: Automatic dishwashing,

Manual dishwashing, PET reprocessing, Sanitary landfill, Waste incineration,

Packaging production, and Collection and transportation. The categories represent the

costing of the processes as described in Chapter 5, applying the same considerations

as in Chapter 6.1.

-100

-50

0

50

100

150

sc1 sc2 sc3 sc4 sc1 sc2 sc3 sc4

Depletion of abiotic resources Depletion of abiotic resources, fossil

mP

E/F.

U.

Composition of impacts in depletion of sources

Automatic dishwashing Virgin PET pellets Production of virgin foilPackaging production Waste Incineration, DK Sorting facilitySanitary landfill PET Reprocessing Manual dish washingCollection and transportation Bottom ash landfill Total

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Figure 19: Net cost of the different scenarios

Based on the graph, it can be mentioned that the packaging production process is the

most costly process for all the Scenarios. Comparing the upstream (packaging

production) with the disposal phase it can be concluded that the first is much more

expensive phase. This conclusion also explains the large monetary difference between

the forth and the rest of the scenarios since the scenario of reuse needs less kilos of

produced packaging.

The slight monetary difference between Scenario 2 and 3 occurs mainly due to the

fact that the revenues from the recycling process are higher for Scenario 3 (Annex

F5). Comparing the cost of Scenario 1, Scenario 2 and Scenario 3 which apply to the

same amount of plastic waste, it can be concluded that incineration process is more

expensive than recycling, since the later gives back more revenues.

Figure 20: Life Cycle Costing of scenarios

2248

2537 2504

273

0

500

1000

1500

2000

2500

3000

sc1 sc2 sc3 sc4

DK

K

Net cost of the Scenarios

2248 2537 2504

273

-500

0

500

1000

1500

2000

2500

3000

sc1 sc2 sc3 sc4

DK

K

Life Cycle Costing of Scenarios

Automatic dishwashing Sanitary LandfillPackaging production PET ReprocessingWaste Incineration Transportation and waste collectionManual dish washing Net cost

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7. Sensitivity analysis

This part of the report assess the robustness of the study by spotting sensitive points

and evaluating the influence caused in the results by the change of these parameters.

The assumptions are changed one at a time. According to Clavreul et al. (2012) the

uncertainties met in LCA studies can refer to model uncertainties, scenario

uncertainties and parameter uncertainties.

In the present case two different points are assessed. The first sensitivity analysis

focuses on the forth scenario and how the environmental results are influenced by

reducing the times of packaging reuse to the half. The second analysis focuses on the

processes of the upstream phase and how the results get affected if it is considered

only the extraction of virgin raw material as upstream process.

7.1. Times of packaging reuse

As mentioned in Chapter 4.1 the assumption of the times that a packaging can be

reused was based on the situation applying for refillable bottles. In this part of the

report it is assessed the environmental performance of the scenario by reducing the

number of reuses to the half (10 times).

The change of the times of reuse depicts affects not only to the disposal phase of the

scenarios but also to the upstream phase. In the present situation, in order to serve

1000 meals in boxes that can be reused 10 times, 100 packages are needed and not 50

as in the main report’s case. Thus, the upstream phase, must include the production of

the extra amount of packaging used. In addition the washing processes of the assessed

scenario must apply to 9 times of washing leading to the 10 reuses. The amount of

plastic which is taken for incineration is correspondently larger. The modeling of the

upstream processes corresponding to the new scenario named Sens1.Sc4 applies to the

difference of used kilos between the two assessed scenarios, method which was

followed for the evaluation of the main scenarios. Thus the upstream processes of the

Sens1.Sc4 scenario correspond to the production of 6.9kg of packaging. The adjusted

consumption data used for the modeling of the washing phases can be found in Annex

G1.1.

Figure 21 depicts the difference of the environmental impacts between Sens1.Sc4 and

Scenario 4. As it can be observed in all the impact categories, Sens1.Sc4 contributes

more loads than Scenario 4 with only exception the FE category. In FE category,

Sens1.Sc4 burdens less than Scenario 4 mainly due to the smaller amount of detergent

used in the automatic dishwashing phase, since it corresponds to 9 washes and not to

19 as in the case of Scenario4. Concerning the rest of the impact categories,

Sens1.Sc4 has larger net burdens since it includes the extra loading impacts sourcing

of its enhanced upstream phase. It has to be remarked thought, that the washing

phases of Scenario 4 are more contributive than Sens1.Sc4’s, fact which is expected

due to the almost double amount of washes that occur.

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Figure 21: Difference of the environmental impacts between Sens1.Sc4 and Scenario 4

The composition of the impacts for the two compared Scenarios, is illustrated in

Annex G1.2, separately for each group of impacts categories (non-toxic, toxic,

recourse depletion).

Figure 22 depicts the new scenario compared with the rest of the scenarios. As it can

be observed the reuse scenario remains the least contributive in most of the categories,

as performed in the previous case. The only difference in the performance of the

scenarios is spotted in HTC category where Scenario3 and Sens1Sc4 have a slight

difference favoring Scenario 3. Although, the ranking of the scenarios concerning

their environmental performance stays the same even if the times of reuse are reduced

to the half.

Figure 22: Comparison of the main scenarios with the Sens1.Sc4

-2.00

-1.00

0.00

1.00

2.00

3.00

4.00

5.00

6.00

7.00

8.00

CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mP

E

Difference of the environmental impacts between Sens1.Sc4 and Scenario4

0

10

20

30

40

50

60

70

80

90

CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mP

E/Sc

en

ario

Comparison of main scenarios with Sens1.Sc4 scenario 1

scenario 2

scenario 3

sens1.sc4

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7.2. Upstream processes

The upstream phase of the study included a number of processes starting from the

extraction of oil for the production of PET until the production of the assessed

packaging, considering also the transportation and the recycling of the postindustrial

PET (see Chapter 4.2).

The present sensitivity analysis assesses the alternative of modeling only the

production of virgin PET needed for the manufacturing of the assessed packaging

excluding the rest of the processes. Figure 23 depicts the numerical difference

between the environmental impacts sourcing of the pure extraction of virgin PET

(single-processed upstream phase (S-P)) and the group of processes (multiple-

processed upstream phase(M-P)). The comparison of the two phases and their

composition is visualized in Annex G2.

According to the graph multiple-processed upstream phase is more environmental

friendly in all the categories despite the fact that includes a number of extra processes.

The recycling of postindustrial PET which corresponds to the avoided production of

virgin PET is the saving parameter of the phase. This concept reassures that the virgin

extraction process is contributive for the environment and when avoided the credits

for the environment are considerable.

Figure 24 depicts the environmental performance of the scenarios in Sensitivity

analysis 2 in all the impact categories, in order to give an overview of the change’s

affects. The analytical visualization for each type of impact categories (toxic, non-

toxic, recourses) is included in Annex G2. It can be observed that the change of the

upstream processes did not affect the trend of the scenarios’ performance neither their

ranking. The same scenarios contribute the highest loads and savings in the same

impact categories as before. Thus, Scenario 4 remains the least burdening scenario,

followed by Scenario 3. The contributive performance of the other two scenarios

depends on the assessed impact category.

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Figure 23: Difference of environmental impacts between the single and multiple processed upstream phases

Figure 24: Performance of the scenarios in all the impact categories under the change of Sensitivity 2

0

10

20

30

40

50

60

CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mP

E

Diference of impacts between the single and multiple processed upstream phases

0

20

40

60

80

100

120

140

CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mP

E/Se

ns.

Sce

nar

io

Environmental performance of Scenarios in Sensitivity 2

Sens2.Sc1Sens2.Sc2Sens2.Sc3Sens2.Sc4

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8. Discussion

Uncertainties of the inventory

The importance of the accuracy of the data used in the set-up of the model is crucial

and fundamental for the results of an LCA. The inventory of the present study can be

divided in two parts; the inventory of the upstream packaging production and the

inventory of the waste management system.

The inventory of the upstream processes of the packaging production has few

uncertainties since the system was well defined by using site specific data obtained

directly from the involved facilities, applying to the reference year of the project.

However some critical parameters considered in the inventory of the reusable

packaging production are uncertain because it was not possible to find specific data

for reusable take-away food-packaging since it is not a presently applicable situation.

These parameters concern the times of reuse and the thickness of the packaging which

were based on the respective data applying for refillable bottles. Concerning the

uncertainty referring to the times of reuse, a sensitivity analysis was performed in

order to assess the robustness of the assumption. The analysis showed that the ranking

of the scenarios is not influenced even after reducing the times of reuse to the half.

Concerning the inventory of the waste management systems, the degree of uncertainty

is a bit higher for the scenarios where sorting and conventional recycling technology

is involved. The uncertainty refers to the data used for the modeling of these two

processes since they represent the Italian reality of 2003 and source from facilities

dealing with PET bottles. For the rest of the processes used in the waste management

scenarios the uncertainties are lower.

When it comes to the inventory of the economic part of the study, the uncertainty is

quite high due to the involved approximations and assumptions. The estimated costs

of recycling facility as well as the gate fee of landfill in UK do not apply to the actual

studied facilities but they were based on general data. The capital cost of the recycling

facility was based on costs found in other studies of relevant facilities and the

operational cost was estimated according to the input used in the environmental part

of the study, fact that includes uncertainties. On the other hand, the prices used for the

selling and purchasing materials were based on industries’ information or on personal

research in multiple type of sources.

Environmental results

The evaluation of the net environmental impacts showed that Scenario 4 performs in

the most environmental friendly way in all the impact categories with the exceptions

of FE and HTNC categories where Scenario 1 reacts in a better way. The above

results are in accordance with the waste hierarchy reassuring that reuse is the most

beneficial approach for the environment. The results of the first sensitivity analysis

also reassured that Scenario 4 is the less burdening scenario even if the times of reuse

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are reduced to the half. The fact that Scenario 4 loads the most in FE category was

expected since it is the only scenario including the automatic washing process

involving detergent which is the main contributor in the category.

The worst environmental performance was realized mainly by Scenario 2 followed by

Scenario 1. More precisely, Scenario 2 contributes the most loads in 8 out of 12

impact categories (SOD, TA, EP, DAR, HTC, HTNC, ET, PM), Scenario 1 to three

out of 12 (CC, POF, DARF) and Scenario 4 to one impact category (FE).

Comparing the two scenarios which are related with the recycling process in the waste

treatment phase, Scenario 3 was assessed to be the most saving scenario. That has to

do with the type of virgin plastic which was substituted in the recycling process of the

waste treatment phase. In Scenario 2 the substituted plastic is PP while in Scenario 3

is bottle graded PET. That leads to the conclusion that virgin PET production is more

resource consuming than virgin PP production. In addition the fact that bottle graded

PET is used for the substitution and not amorphous PET enhances the numerically

obtained benefits, since the first mentioned type of PET is used for food contact

applications and depicts the clearest and purest form of PET.

The main contributor-process in Scenarios 1,2,3 for all the impact categories apart

from FE, is the production of virgin PET pellets originating from the upstream phase.

This relation reassures the resource demanding nature of the virgin PET production

process and reveals the important environmental benefits obtained due to avoided

production of virgin PET linked to the recycling process. The second sensitivity

analysis also focused on the importance of the recycling process leading to the above

conclusion concerning the loading nature of virgin process. For Scenario 4 the main

contributor process is the automatic dishwashing.

The savings of the scenarios originated from the ‘’PET reprocessing’’, ‘’packaging

production’’, ‘’foil production’’ and ‘’waste incineration’’ processes. In the first three

processes the savings source from the avoided production of virgin plastic which

substitutes the recycling process. In the waste incineration process the substitutions of

marginal electricity and heating are the reasons of the beneficial contribution.

The second sensitivity analysis showed that the multiple-processed upstream phase

which includes the benefits of the recycling is more environmental friendly in all the

categories compared with the single-processed phase that does not consider the

recycling’s benefits, despite the fact that includes a number of extra processes.

It has to be mentioned and reminded thought, that even in Scenario 4 there are actual

benefits and loads sourcing from the upstream processes. The reason for not being

depicted in the results of the study is the fact that it was considered the difference of

the upstream impacts between one-use and reusable packaging.

The results of the studied scenarios in total cannot be compared with literature

sources, since each scenario includes a combination of processes and phases. It can be

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splitted thought in smaller parts in order to reassure the accuracy of the results

compared to the literature.

The overall conclusion of the study that the reuse approach is the most

environmentally beneficial approach is in accordance with a number of studies which

prove the importance of prevention and reuse (Singh et al., 2006; Levi et al., 2011;

Sanchez Martinez & Møller, 2011).

According to many literature studies such as Claus Mølgaard (1995), Arena et al.

(2003), Perugini et al. (2005), Lazarevic et al. (2010) the recycling process is favored

over incineration or other disposal methods. The present study showed that recycling

scenario is less loading than incineration scenario when the virgin substitution refers

to virgin PET plastic. In the case that the substitution refers to virgin PP plastic, in

most of the categories it is the incineration with energy recovery scenario which

burdens less. Thus the results of the present study are in accordance with Merrild et

al. (2012) where it was concluded that in some cases, incineration of plastic in

Denmark may be more beneficial than recycling.

Economic results

The evaluation of the economic results showed that the second scenario is the most

costly opposite to the forth one which is the less expensive. Scenario 2 and 3 were

assessed to have an almost identical estimated cost, with Scenario 2 costing 1.3%

more due to the lower revenues of the process. The large difference between the forth

and the rest of the scenarios is linked up to a great extent with the less amount of

plastic which is included in Scenario 4. It was also observed that the upstream costs of

all the scenarios are much higher than the disposal ones.

Comparing the cost of Scenario 1 and Scenario 2 and 3 which apply to the same

amount of plastic waste, it can be concluded that incineration process is more

expensive than recycling, since the latter contributes more economical savings. This

conclusion is in accordance with Emery et al. (2006) and Larsen et al. (2009). The

process that mainly enhanced the cost of the recycling scenarios compared to the

incineration scenario is the manual dishwashing.

Combined LCA and LCC

The aim of combining the results of LCA and LCC studies applying to the same

system boundaries, is to obtain a more complete and realistic evaluation of the studied

system. The combination of those two approaches can be used as a useful supporting

decision tool. Table 30 presents the LCA and the LCC ranking starting from the most

beneficial option.

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Table 30: Ranking of scenarios under the environmental (LCA) and the economic (LCC) perspective

LCA LCC

Most beneficial scenario

↓ ↓

Least beneficial scenario

Scenario 4 Scenario 4

Scenario 3 Scenario 1

Scenario 1 Scenario 3

Scenario 2 Scenario 2

In the present study, Scenario 4 appeared to be the best option combining by far the

most beneficial environmental and economic performance compared to all the

assessed scenarios.

Contrary, Scenario 2 appeared to be last in the ranking as it is the most

environmentally loading for most of the impact categories and at the same time the

most expensive scenario. The decision of ranking Scenario 2 in the last place of

preference is also enhanced by the market demand. According to Nielsen (2013), the

type of foil produced in Scenario 2 is not very commonly asked for packaging

applications due to the impurities that may contain32

, giving a non-appealing

appearance to the packaged product.

Concerning the rest two scenarios, Scenario 3 appeared to be environmentally less

burdening than Scenario 1 in all of the impact categories, but in the same time

Scenario 1 was assessed to be 10% less costly than Scenario 3.

32

The potential impurities that may be contained in the recycled material are correlated with the

cleaning steps followed in the recycling process applying in each facility

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9. Conclusions

The present report aimed to evaluate the environmental and economic performance of

four waste management scenarios of take-away PET plastic food packaging. The first

three scenarios refer to an one-use packaging while the forth scenario refers to a

twenty timed reusable packaging. Due to the different quantitative composition of the

assessed packaging, the upstream phase of the packaging production had to be

modeled additionally to the disposal phase. The assessed waste management

alternatives of the packaging were the following: 1) incineration with energy recovery

in Denmark 2) conventional recycling in UK with the output applying to electronic

packaging 3) conventional recycling in UK followed by a super cleaning process with

the output applying to food packaging applications 4) reuse of the packaging 20 times

and disposal to incineration with energy recovery.

The environmental assessment was performed by using the EASETECH modeling

tool and refers to the evaluation of twelve impact categories. The environmental

impacts were expressed in milli person equivalent per functional unit (mPE/F.U.)

Most of the data used in the environmental assessment was obtained directly from the

relevant industrial facilities or from scientific articles. The processes used for the

modeling of the background processes were imported from Ecoinvent database,

EASEWASTE’s database or were included in EASETECH’s database.

The data used in the economic assessment was obtained directly from the above

mentioned industries, personal market reasearch and relevant reports and websides.

The evaluation of the potential environmental impacts reassured that reuse is by far

the most beneficial approach under an environmental perspective.

The environmental ranking of the scenarios starts with Scenario 4 as the most

beneficial option, followed by Scenario 3, Scenario 1 and finally Scenario 2. The

implementation of two sensitivity analysis showed that the scenario’s environmental

ranking stays the same a) in the case that the times of packaging’s reuse in the

Scenario 4 are reduced to the half and b) in the case that the upstream phase includes

only the virgin PET production.

The second sensitivity analysis also showed that the multiple-processed upstream

phase which includes the benefits of the recycling is more environmental friendly in

all the categories compared with the single-processed phase that does not consider the

recycling’s benefits, despite the fact that includes a number of extra processes.

Comparing the two scenarios involving the recycling process in their disposal phase,

Scenario 3 appeared to be the most beneficial scenario. The above outcome also led to

an additional verification that virgin PET production is more resource consuming than

virgin PP extraction.

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The process of virgin PET production originating from the upstream phase was the

main burdening process for Scenarios 1,2,3 for all the impact categories apart from

FE category. For scenario 4 the main loading process was the automatic dishwashing.

The evaluation of the economic results showed that Scenario 2 is the most expensive

option opposite to Scenario 4 which is the least costly option. Scenario 2 and 3 were

assessed to cost approximately the same. It was also concluded that incineration

process is more expensive than recycling process.

The combination of LCA and LCC results, showed that Scenario 4 represents the best

option among all the assessed scenarios while Scenario 2 is the least preferable

option. The most costly process for all the Scenarios appeared to be the packaging

production process, fact that explains the large monetary difference between the

Scenario 4 and the rest of the scenarios. It was also concluded that the production

phase costs much more than the disposal phase.

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10. Future work suggestions and study improvement

The current report represents a first approach of the environmental and economic

assessment of take-way PET food packaging. In accordance with the discussion

phase, the present Chapter proposes suggestions for the improvement of the present

study, as well as recommendations and ideas for future LCA studies.

To begin with, the assumptions which were considered in the course of the project

could be spotted and reexamined based on more accurate data, in order to obtain more

powerful and updated results.

The first spotted points for further assessment can be considered the thickness of the

reusable packaging as well as the times of reuse. Tests can be realized in order to

evaluate the performance of different thicknesses. In addition, tests can take place, in

order to assess the resistance of the packaging under different conditions of treatment.

These types of tests can be used supplementary to each other in order to find the

desired correlation of resistance and thickness. The other simpler option for assessing

the different packaging thicknesses would be to apply additional sensitivity analysis

concerning that factor. The sensitivity referring to the times of reuse is already

existent in the project.

A second uncertain point of the project which could be reevaluated is the recycling

technology applied in the current project. The acquisition of more recent data,

applying to the English reality would give a more representative perspective of the

modeled situation.

Additionally, a potential economic assessment performed with data coming directly of

the involved recycling facility would give a more robust and reliable economic

approach.

A more representative perspective of the reusable scenario could be obtained if losses

were taken under consideration. The material losses can source either from damages

occurring in the reusable products or from products that were not returned to the

restaurant and stayed out of the loop.

It would also be interesting to compare respective scenarios using as raw material bio

plastics in order to evaluate the different performance of the plastics.

Finally, a socio-perspective research concerning the willingness and the openness of

the people to enhance and participate to a bringing back system of reusable take-away

food packaging, could complete the present study. This is a crucial point since the

functionality and the success of the report’s project is based on the people’s

participation. Thus, a potential deny of participation to the system could lead to the

opposite of the plastic waste prevention result and accumulate more plastic in the

dustbins considering that the reusable packaging weights more.

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ANNEXES

Annex A : Background information

A1 Graphs

Figure 25: Rate of plastic packaging waste treatment by country-member, 2007 (%), source: bio Intelligence Servise, 2011

Figure 26: Recycling rate for plastic packaging, 2010, Source: Eurostat, 2013

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A2 Applied PET supercleaning processes

Figure 27: PET supercleaning processes based on pellets, source: (Welle, 2011)

Figure 28: Two schemes of Supercleaning recycling process based on decondamination of PET flakes, source: Welle, 2011

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Figure 29: PET supercleaning based on partial depolymerisation to oligomers, source: Welle, 2011

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A3 Impact categories and waste management

Non-toxic categories

In the waste management field, photochemical oxidation (POF) is mainly affected

from the emissions of nitrogen oxides (NOx) caused by the incineration and the waste

collection and transportation processes and by the volatile organic compounds

(VOCs) emitted from the landfills (Hauschild & Barlaz, 2011). Eutrophication-

potential (EP) category referring to solid waste treatment, is affected by ammonia and

NOx which are also emitted by the above relevant sources (Hauschild & Barlaz,

2011). In addition, emissions of NOx, ammonia and sulfur oxides (SOx) which

contribute to the terrestrial acidification (TA) are emitted by transport processes and

generally processes where diesel combustion is involved. Particulate matter 33

(PM) is

also formed by the combustion of fossil fuels in vehicles and engines. Climate change

is affected by the greenhouse gases where carbon oxide (CO2) which is the most

popular of the greenhouse gases, is formed by the combustion of fossil fuels.

Chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs) and bromine-

containing halons are the most common manmade gases which contribute to

stratospheric ozone depletion (Hauschild & Barlaz, 2011).Freshwater eutrophication

category refers to the impacts caused by phosphorous emissions. A common source of

phosphorous which is met in waste studies, is the waste water treatment plants.

Toxic categories

Human beings are exposed to thousands of substances which potentially can exert

human toxicity. In the field of waste treatment, the most important exposures come

from the waste incineration’s and transportation’s emitted particles as well as from the

exposure to toxic metals and persistent organic pollutants (e.g. dioxins, furans)

(Hauschild & Barlaz, 2011). Ecosystems can also be toxically damaged by the toxic

metals and persistent organic pollutants. Thus, the toxic categories assess the

ecotoxicity in total (including effects on both ecosystems and human health) and also

focuses in two different types of human toxicity (carcinogenic and non).

Recourse depletion

The recourse depletion category, refers to the impacts that occur to the abiotic

resources, divided in two categories; fossil and non. The depletion of abiotic

resources, fossil category (DARF) refers to the consumption of fossil fuels while the

other category includes the rest of the abiotic resources (e.g. minerals).

33

Particulate matter is a synthesis of very small solid and liquid particles polluting the atmosphere

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Annex B: Upstream Processes

B1 EASETECH’s snapshots

Figure 30: Snapshot of EASETECH depicting the upstream processes

B1.1 Virgin PET flow

Figure 31: Snapshot of EASETECH, depicting the modeling of the virgin PET flow

B1.2 Foil production

Figure 32: Snapshot of EASETECH, depicting the modeling of the foil production process

B1.3 Transportation from UK to DK and vice versa

Figure 33: Snapshot of EASETECH, depicting the modeling of the transportation process from UK to DK and vice versa

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B1.4 Packaging production

Figure 34: Snapshot of EASETECH, depicting the modeling of the packaging production process

B2 Data and calculations

B2.1 Differences between the different types of PET

Table 31: Differences between the different types of PET, source: (Foil's Production Industry, 2013)

Type of PET Grade Intrinsic Viscosity (IV)

Virgin pellets Bottle grade 0.8

R- PET flakes Hot washed

(no food grade)

0.70-0.74

Super cleaned flakes Food grade

R-PET pellets Food grade 0.82 (as virgin)

B2.2 Foil production Table 32: Data concerning the production of 1kg of virgin foil (Foil's Production Industry, 2013)

General information

Application: food contact Type of input: 100% virgin pellets

Grade: bottle grade Thickness: 0.3-0.6 mm

IV: 0.8IV Process’ efficiency: 83%

Input

Electricity consumption per kilo of produced foil 0.406 KWh/kg

Input of virgin pellets per kilo of produced foil 1.2 kg/kg

Input of anti-block additives per kilo of produced foil 0.0024 kg/kg

Output

Scraps taken for recycling per kilo of produced foil 0.2 kg

Virgin PET foil 1 kg

Economic data

Selling price 1.96 €/kg

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B2.3 Packaging production

B2.3.1 Visit to the packaging production facility (Donplast A/S)

Pictures of the facility and the followed processes

Figure 35: Roles of foil used for the production of the packaging

Figure 36: Forming tools

A B

Figure 37: A: Production line of the facility B: Product coming out of the thermoforming machine

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A B

Figure 38: A: The produced packaging placed in boxes B: The cut foil turned around a cylinder

Figure 39: Cut foils separated by color in containers in order to be shipped back to UK for recycling

Figure 40: Grinding the cut foil separately for each color, before to transport them back to UK

Forming tools and Workshop

‘’Forming tools’’ are used in order to give to the foil the desired shape. The company

has 500 forming tools half of which are formed in the company’s workshop.

Workshop they call the part of the company where they create new forming tools and

maintain the existing ones. Figure 36 depicts some of them.

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It is possible for the company to make changes to the forming tools that have been

created by them, since they have the drawings. It takes weeks to build one forming

tool considering that the steps before the final production are: design - pilot scale - try.

Most of the times, the design of the product is designed by the Donplast itself

involving the client’s wishes. In the Sticks’n sushi case, the design of the packaging

did not involve Donplast and that is the reason why an agreement was signed,

forbidding the company to produce the particular packaging for any other application.

B2.4 Actual amounts of upstream processes

Table 33: Amounts applying to the upstream processes

Scenario 1,2,3 (kg) Scenario 4 (kg)

Virgin PET input 130 13.0

Amount of produced foil 107.8 10.8

Amount of transported foil 107.8 10.8

Amount of produced packaging 69 6.9

Amount of cut foil 38.8 3.9

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Annex C: Disposal Processes

C1 EASETECH’s snapshots

C1.1 Waste flow

Figure 41: EASETECH’s snapshot depicting the modeling of the input waste flow for scenario 1,2,3.

Figure 42: EASETECH’s snapshot depicting the modeling of the input waste flow for scenario 4.

C1.2 Scenario 1

Figure 43: Snapshot of EASETECH depicting the modeling of Scenario 1

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Figure 44: Snapshot of EASETECH, depicting the modeling of the collection and transportation process

Figure 45: Snapshot of EASETECH, depicting the processes included in the ‘’ Waste to energy , generic, Denmark, 2012’’ process

Figure 46: Snapshot of EASETECH, depicting the process used for the transportation of the Bottom ash to the landfill

Figure 47: Snapshot of EASETECH, depicting the processes included in the ‘’Bottom ash landfill’’ process

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C1.3 Scenario 2

Figure 48: Snapshot of EASETECH depicting the modeled processes of Scenario 2

Figure 49: Snapshot of EASETECH, depicting the processes used for the modeling of the manual dishwashing

Figure 50: Snapshot of EASETECH, depicting the modeling of the collection and transportation process

Figure 51: Snapshot of EASETECH, depicting the modeling of the Sorting facility

Figure 52: Snapshot of EASETECH, depicting the modeling of the transportation of the Sorting facility in DK to the Recycling plant in DK

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Figure 53: Snapshot of EASETECH, depicting the modeling of the Recycling process

Figure 54: Snapshot of EASETECH, depicting the modeling of the transportation of the Recycling facility to the Sanitary landfill

Figure 55: Snapshot of EASETECH, depicting the modeling of the Sanitary landfill

Figure 56: Snapshot of EASETECH, depicting the modeling of the transportation of the residuals coming out of the Sorting facility to the Incineration plant

The snapshots of the processes: ‘’Incineration with energy recovery in

Vestforbrænding’’, ‘’Transportation of bottom ash to mineral landfill’’ and ‘’Bottom

ash landfill’’ are the same as in Annex B2.

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C1.4 Scenario 3

Figure 57: Snapshot of EASETECH depicting the modeled processes of Scenario 3

Figure 58: Snapshot of EASETECH depicting the modeled Reprocessing process

Figure 59: Snapshot of EASETECH depicting the modeled super cleaning process, included in the modeling of the ‘’PET Reprocessing’’ process

Figure 60: Snapshot of EASETECH depicting the modeled pelletizing process, included in the modeling of the ‘’PET Reprocessing’’ process

The snapshots of the rest processes of the scenario are depicted in Annex C1.3.

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C1.5 Scenario 4

Figure 61: Snapshot of EASETECH depicting the modeled processes of Scenario 4

Figure 62: Snapshot of EASETECH depicting the modeling of Manual dishwashing in scenario 4

Figure 63: Snapshot of EASETECH depicting the modeling of Automatic dishwashing

Figure 64: Snapshot of EASETECH depicting the modeling of the detergent for dishwashers

Figure 65: Snapshot of EASETECH depicting the modeling of the rinsing agent for dishwashers

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The snapshots of the rest of the processes used in the Scenario can be seen in Annex

C 1.2.

C2 Data and calculations

C2.1 Waste flow

Table 34: Origin of the modeled amount of foodstuff, source: Gilleßen et al., 2013

Type of soiling Amount Unit

Tea 6 g

Milk 10 ml*

Egg 4 g

Meat 4.5 g

Spinach 6.5 g

Oat flakes 3 g

margarine 2 g

sum 36 g

Soil per item 1.44 g *assuming a density of 1

C 2.2 Manual dishwashing

Table 35: Data used for the manual dishwashing, source: Stamminger et al., 2007

Water (l) Energy (kWh) Cleanser (kg) Evaluation of

cleaning (/5)

Average* /12

items washed 63 1.6 0.026 3.3

Average* /item

washed

8.6

0.2

0.0029

3.3

*The average refers to all 113 manual washers of the study

Based on the assumption that the manual dishwashing of the packaging is more like a

flushing, the data concerning the warming up of the water (energy) and the amount of

cleanser used in the study, were not included in the modeling of the present study.

Removal of foodstuff

Taking under consideration that the average evaluated cleaning efficiency was 3.3/5,

it was assumed that the efficiency of the manual dishwashing is 66%. Thus, 34% of

the foodstuff remains on the packaging after the manual dishwashing.

Inputs in the modeling of manual dishwashing

Table 36: inputs in the modeling of manual dishwashing

Scenario Type of washing Number of dirty packages

(1kg of input)

Water (l)

2,3 Manually 14.2 122

4 Manually 7.2 1170*

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*The amount of water in the fourth scenario is calculated for the water consumption of 19 times of

cleaning (20 uses of packaging).

C 2.3 Automatic dishwashing

The inserted numbers in the model refer to the number of dirty packaging consisting

1kg of input since EASETECH’s calculations are performed per kilo of input. For the

case of the reusable packaging, 1kg of input contains 7.2 packages. The inserted

values, the ralevant calculations and the reference data can be found in the following

Tables.

Table 37: Data used for the Automatic dishwashing, source: (Stamminger et al., 2007; Presutto et al., 2007)

Automatic

dishwashing

Water (l) Energy

(kWh)

Cleanser

(kg)

Evaluation

of cleaning

(/5)

Rinsing

agent (kg)

Consumption/place 1.5 0.13 0.0025 3.8 0.00029

Removal of foodstuff

Taking under consideration that the average evaluated cleaning efficiency was 3.8/5,

it was assumed that the efficiency of the automatic dishwashing is 76%.

Inputs in the modeling of Automatic dishwashing Table 38: Inputs in the modeling of Automatic dishwashing

Scenario Type of

washing

Number of

dirty packages

(1kg of input)

Water

(l)

Energy

(kWh)

Cleanser

(kg)

Rinsing

agent

(kg)

4 Automatic 7.2 210.1 17 0.34 0.04

The calculations of the inputs correspond to the consumptions of 19 times of cleaning

referring to 20 uses of packaging.

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Annex D: Life Cycle Costing , Detailed Calculations

D1 General Data

The following Subchapters depict data used for the basic calculation of the study. All

the monetary changes were made based on the currency of July 2013, depicted in

Table 39.

Table 39: Currency considered in the project, July 2013

Euro (€) 7.46 DKK

GBP 1.17 €

For the capital costs it was considered an interest rate of 7% (Dominic Hogg,

Eunomia Research & Consulting, n.d.).

D1.1 Materials and Energy

Table 40: Prices of raw materials used in the production of the foil, source: Foil's Production Industry, 2013

Raw material Price (DKK/kg)

Hot washed R-PET flakes 7.46

Virgin Pellets 9.24

R-PET Pellets 8.36

Table 41: Prices of the foil, source: Foil's Production Industry, 2013

Transparent Foil Price (DKK/kg)

Virgin 14.6

V-R-V 10.7

V-SCR-V 11.0

Thicker foil (for the reusable) 12.8

Table 42: Prices of the packaging, source: Table 43 (Nielsen, 2013)

Price (DKK/kg)

Packaging 31* *Referring to the price of the studied packaging. The price of the final product varies

according to the order’s size (Nielsen, 2013)

Table 44: Price of diesel, source1: (Fuel-prices-europe.info, 2013), source 2: (Department of Energy and Climate Change, 2012) , source 3: (Axion Consulting, 2009) source4: (Marvin J., 2012), source 5: (HOFOR, 2013), source 6: (Mollenborg, 2008)

Country Dieselsource1

(DKK/ l)

Electricity

(DKK/ kWh)

Water

(DKK/kg)

Industrial gas

(DKK/kWh)

Denmark 11.72 1.9 source 6

*0.039source 5

United

Kingdom

11.99 0.091 source 2

0.0023 source 3

0.17source 4

*The analytical calculations of the price are presented in Table 45

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Table 45: Analytical calculations of the water price and drainage in Copenhagen (2013), source: (HOFOR, 2013)

Elements Price for 1l of water (DKK/l)

Water tariff 0.0065

Groundwater Protection 0.00050

Water tax 0.0055

State tax mapping of groundwater

resources 0.00067

Drainage Contributions, transport 0.0064

Drainage Contributions, cleaning 0.012

Moms 0.0078

Total 0.039

D1.2 Salaries

Table 46: Salaries in UK, source: (Reed, 2013)

Job Salary (DKK/y)

Administrative position 266245

Worker in industry 193094

Salary (DKK/h)

Driver 105

Table 47: Salaries in DK, source: (Statistics Denmark, 2013)

Job Salary (DKK/h)

Administrative position 249.56

Worker 177.84

Driver 163

D1.3 Truck

Table 48: Different volume trucks and their respective capital and operational costs

Volume of

truck (ton)

Capital cost

(DKK)

Repair-

Maintenance

(DKK/y)

License

(DKK/y)

Insurance

(DKK/y)

5 1199993 49997 4998 24998

10 2399986 99994 9996 49997

25 5999966 249985 24991 124992

D1.4 Washing Equipment

Table 49: Cost of ringing agent in the Danish market in July 2013, source: personal research

Ringing agent Cost (DKK/lt)

Product A 92.38

Product B 19

Average price 55.69

DKK/washing 0.17

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Table 50: Cost of brushes and sponges in the Danish market in July 2013, source: personal research

Bruches and sponges Costs (DKK/item)

Product A 22.95

Product B 19.95

Product C 39.95

Product D 19.95

Product E 0.70

Product F 1

Average cost 17.42

DKK/wash* 0.09

*It was assumed that one brush/item can wash 200 packages

Table 51: Cost of detergent for dishwashers in the Danish market in July 2013, source: personal research

Normal detergent powder Cost

(DKK/kg)

DKK/washing

Product A 46.3 0.82

Product B 35.98 0.64

Product C 38.98 0.62

Product D 134 2.5

Average cost 63.82 1.15

Table 52: Data of consumptions, source: Presutto et al., 2007

Use of detergent (g/cycle) 30

Softener (salt) (g/cycle) 20

Rinsing agent (g/cycle) 4

125ml of rinsing agent is(loads)* 40

Rinsing agent in 1lt (loads) 320

*Information found in product’s webpage

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Table 53: Cost of dishwashers of Class A+ in the Danish market in July 2013, source: personal research

Dishwashers A+ Cost (DKK)

Dishwasher 1 3999

Dishwasher 2 6999

Dishwasher 3 5999

Dishwasher 4 4999

Dishwasher 5 3989

Dishwasher 6 3450

Dishwasher 7 4140

Dishwasher 8 4346

Dishwasher 9 3499

Dishwasher 10 2399

Dishwasher 11 6999

Dishwasher 12 3650

Dishwasher 13 2989

Dishwasher 14 4606

Dishwasher 15 2346

Average price 4294

D2 Virgin Foil production

The economic calculations of the virgin foil production were based on the operational

data presented in Annex D1, referring to UK. Additional data, however, and a number

of assumptions needed to be considered for the implementation of the costing.

According to Foil Production Industry’s brochure, the facility produces annually

6000000kg of foil and occupies 20 people working in the manufacturing production

line. It was assumed that the production line works 6 days/week, for 2 shifts/day and

every person works 8h/d. It was also assumed that 8 more people are occupied in

administrative positions. The capital cost used for the present calculations was

representative for 2010 (Foil Production Industry’s brochure); however it was

assumed that the cost for constructions did not change until now. The following

Tables represent the life cycle costing calculations for the facility’s function.

Table 54: Annulation of Capital costs for foil production facility

Years Rate Present cost

(DKK)

DKK/year DKK/kg of

foil produced

1. Capital cost 15 7% 17,456,400 1,916,619 0.32

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Table 55: Operational and maintenance costs for foil production facility

2. Operational and

maintenance costs

DKK/year DKK/kg of

foil produced

2.1. Repairs-

maintenance

5% of investment cost 95,830.94 0.016

2.2. Salaries 5,991,839 1.00

2.2.1. Workers 20 persons 3,861,879

2.2.2.Administration

staff

8 persons 2,129,960

2.3. Materials/Energy 11.13

2.3.1. Virgin pellets 1.2 kg/kg foil 11.09

2.3.2. Energy

consumption

0.406 kwh/kg input 0.037

Total 12.1

Table 56: Revenues, Total costs and Net Revenue for the foil production

DKK/kg of

foil produced

Total costs 12.4

Revenues 14.6

Net Revenue 2.19

D3 Packaging Production

Based on the information obtained by the visiting to the industry’s facility, the

company’s human resources consists of 4 persons working in the administrative part

and of 14 persons working in the production line and the company’s ‘’workshop’’34

(Nielsen, 2013). The facility is functional for 18 hours per day and operates 11

thermoforming machines (Nielsen, 2013).

Based on the above mentioned data, it was assumed that the production line functions

with 4.7 35

persons per shift, with 3 shifts/day while the administration part functions

with 1 person/shift for 2 shifts /day.

The company’s monthly packaging production is 35.000kg with a monthly foil

consumption of 55000kg (Nielsen, 2013). The hourly packaging production was

calculated to be 97kg/h assuming that the working days per month are 20 and the

daily working hours 18.

The total area of the facility is extended in 3200m2 (Donplast A/S). The investment

cost includes the building’s construction costs and the equipment’s cost. The surface

area (m2) of the excavations, the paved area and the buildings were based on

34

‘’Workshop’’ is named the part of the facility where new forming tools are designed and produced

(Nielsen, 2013). 35

4.7=14 persons divided with the 3 shifts per day.

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assumptions while the costs for each one of the civil works was calculated based on

Danish data (Dominic Hogg & Eunomia Research & Consulting). The equipment’s

cost estimation was based on internet research.

The following Tables present the analytical estimated costs for the packaging

production facility.

Table 57: Capital costs of the packaging production facility

1. Capital costs Unit Unit price

(DKK)

Sum

(DKK)

1.1.Civil works 92615

land acquisition 3200 m2 149 8579

surface preparation 3200 m2 22 1287

excavations 2000 m2 52 1877

paved area 1200 m2 403 8686

supply systems 500 m 1000 8981

lighting incl. cables 5 9996 898

buildings 2000 m2 1499 53887

miscellaneous (including

design etc)

10% of civil

costs

8420

1.2.Equipment 59316

thermoforming machines 11 58981

industrial water cooler 1 335

Total 151932

Table 58: Annulation of the capital costs for packaging production

1.Capital costs Years Rate Present cost

(DKK)

Annual cost

(DKK)

DKK/kg

produced

1.1.Civil works 15 7% 690910 565902 1.3

1.2.Equipment 7 7% 442500

612520 1.5

Total 2.8

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Table 59: Operational and maintenance costs for packaging production

2.Operational and maintenance

costs

DKK/y DKK/kg

produced

2.1.Repairs-maintenance

15853 0.038

maintenance of thermoforming

machines

5% of investment cost 14920

maintenance of cooling unit 5% of investment cost 932.5

DKK/h DKK/kg

produced

2.2. Salaries

1079 11.10

workers per shift 4.7

830

administration staff/shift 1 250

2.3. Materials/Energy

Electric energy 3.0

Foils 11.98

Total 26.1

Table 60: Revenues, Total costs and Net Revenue for the packaging production

DKK/ kg of packaging

Revenues 31.43

Total costs 28.93

Net revenue 2.50

D4 Collection

The cost calculations took place for a truck of 10t with a diesel consumption of

0.03l/kg. The collection’s truck price, the maintenance cost, the license and the

insurance fee were found in the report of Hogg & Eunomia Research & Consulting,

corresponding to a 5tn collection vehicle applying to the danish economic reality. In

order to adjust the availabe data to the study’s truck carasteristics, the cost of the 5tn

truck was devided with 5.000 kg so as to find the cost per kg, which was following

multiplied with the kilos of the studied truck (10000kg) (see Annex D1). The

respective way of thinking was also applied in the estimation of repair-maintenance

cost, licence fee and insurance fee. For the calculation of the repair-maintenance costs

it was also assumed that the truck performs 1 route per day, while for the calculation

of the licence and insurance fee it was additionaly assumed that the truck is

functional for 5d/week., 52 weeks/year.

According to Municipality of Copenhagen (2013), the truck is staffed with two

persons (1 driver, 1 helper) and the average route lasts for 3.5 hours. Based on that, it

was calculated the labour’s cost of the collection. The truck’s life time for collection

purposes lasts approximately 5 years (Municipality of Copenhagen, 2013).

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The fee paied to the company which collects and transports the waste to icineration

was considered revenue. The cost of the fee is 1032 DKK/tn Municipality of

Copenhagen, 2013).

The Table 61 present the analytical estimated life cycle costing for the transportation

company.

Table 61: Life Cycle costing for waste collection

Costs Years Rate DKK/year DKK/kg

1. Capital cost 0.225

Vehicle 5 7% 585,334 0.225

2.Operational and maintenance costs 0.21

Repair-maintenance 0.038

Labour (2 persons) 0.11

Diesel 0.036

Licence 0.0038

Insurance 0.019

Total costs DKK 0.4

Revenues from fee DKK 1.0

Net revenue DKK 0.6

D5 Transportation

The volume of the truck used in the road transportation for all the scenarios was the

same (25t) for both countries. The capital cost was calculated with the same way and

based on the same data as described in Annex D4. The price of the truck was assumed

to be the same for both countries.

The estimation of the truck’s license and insurance were also based on the

assumptions and the calculation approach presented in Annex D4, assuming the same

costs for both countries. The calculated numbers can be found in Annex D1.

The diesel consumption thought, was different for the two countries based on the data

sources mentioned in Chapter 4. Thus, the diesel expenses were calculated to be

different for the two countries. It is reminded that in UK the consumption is 0.00001

l/kg/km and in DK 0.00003 l/kg/km. Due to the link of the cost with the driven

kilometers, the different transportation routes were calculated in the same way but

assuming different distances. The transported distances were estimated based on

Google Maps and are the ones presented in the LCA part of the study.

The estimation of the labor expenses for the two countries, were also different, based

on the hourly salary of each country (see Annex D1). The time per transported route

was estimated based on Google Map’s estimations. It was also assumed that each

truck is staffed with two drivers.

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Due to lack of information concerning the fee paid to the transportation company, it

was assumed that the paid fee for each transportation route is 2.4 times larger than the

transportation’s total cost according to the situation applied for the collection of the

waste (Annex D4).

Tables below depict the estimated life cycle costing applying to the transportation

company.

Table 62: Transportation of the residuals (coming from the Sorting facility) to the Incineration plant (DK)

Costs Years Rate Present cost

(DKK)

DKK/year DKK/kg

1.Capital costs 0.17

Vehicle 7 7% 5999966 1,113,313 0.17

2.Operational and

maintenance costs

0.067

Repair-maintenance 249985 0.039

Licence 24991 0.0038

Insurance 124992 0.019

Labour (2 persons) 0.0050

Diesel 0.00000037

Total costs 0.24

Revenue 0.56

Net revenue 0.32

Table 63: Transportation of the residuals (coming from the Recycling plant) to the landfill (UK)

Costs Years Rate Present

cost

(DKK)

DKK/year DKK/kg

1.Capital cost 0.17

Vehicle 7 7% 5999966 1,113,313 0.17

2.Operational and

maintenance costs

0.064

Repair-maintenance 249985 0.039

Labour (2 persons) 0.0084

Diesel 0.00000034

Licence 24991 0.0038

Insurance 124992 0.013

Total costs 0.24

Revenue 0.56

Net revenue 0.32

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Table 64: Transportation from UK to DK and vice versa

DKK/kg

Total costs 0.16

Revenue 0.55

Net revenue 0.38

D6 Sorting Facility

In the present study, the sorting facility was assumed to be the Danskreturn system

which is a non-profit organization. That means that the total costs should be equal to

the revenues, ending to zero net revenue (Danskretursystem (f)). According to

Danskretursystem (2013) the deposit fees are adjusted on an annual basis based on the

past volumes of sales and the future predictions. The importers and producers pay the

respective fee for the sales of their products. According to the speciality of the studied

facility, the present economic analysis included only the capital costs of the facility,

the operational costs excluding the paied deposit fee and the revenue of the purchased

sorted PET excluding the paied fee coming of the importers and producer participants.

Since it was not possible to find economic information for plastic sorting facilities in

DK, information concerning the civil works was obtained from transfer stations in DK

(Dominic Hogg & Eunomia Research & Consulting) assuming that the civil

constructions are similar. The capacity of the assessed sorting facility is 15000t/y.

In addition, the prices for the forklifts and the wheeled loading shove used in the

facility were obtained from the respective equipment used in sorting facilities in UK,

assuming to be representative for DK too. The English prices were found in Dominic

Hogg & Eunomia Research & Consulting .

According to Slater (2009), the purchase price of the sorted PET in UK, in 2006 was

1.53 DKK/kg. Assuming an incising price rate of 7% during the last eight years, the

purchase price for the study was set to be 1.63DKK/kg. It is assumed that all the

sorted material is sold to UK with the above price, corresponding to the material flow

followed in the scenarios of the LCA study.

The number of people occupied in the facility and the type of their position was based

on assumptions.

Tables below presents the life cycle costing of the sorting facility excluding the fee

paid by the system’s participants and the deposit fees.

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Table 65: Capital costs for the Sorting facility

1.Capital costs Unit Unit price

(DKK)

Sum

(DKK)

1.1.Civil works 3028835

land acquisition 3000 m2 149 447600

surface preparation 3000 m2 22 67140

excavations 1000 m2 52 52220

paved area 2400 m2 403 966816

unpaved area 200 m2 97 19396

supply systems 500 m 1000 499820

lighting incl. cables 5 9996 49982

fencing 200 m2 254 50728

buildings 400 m2 1499 599784

miscellaneous (including design

etc)

10% of civil

costs 275349

1.2.Equipment 5004675

compactor 2 700002 1400003

forklift 2 358080 716160

wheeled loading shovel 1 954880 954880

baler 1 1933632 1933632

Total capital cost 6099878

Table 66: Annulation of the capital costs of the sorting facility

1.Capital costs Years Rate Present cost DKK/y DKK/kg

1.1.Civil works 15 7% 3028835 332,550 0.022

1.2.Equipment 7 7% 5004675 928,634 0.062

Total annualized capital costs 0.084

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Table 67: Operational and maintenance costs for the Sorting facility, *excluding the deposit fees paid

2.Operational and maintenance costs DKK/y DKK/kg

2.1. Repairs-maintenance 197330 0.013

maintenance compactor 5% of investment 35000

maintenance transport equipment 5% of investment 17904

maintenance loading shover 5% of investment 47744

maintenance baler 5% of investment

96682

DKK/h DKK/kg

2.2. Salaries 1536 0.90

workers 4 711

forklift's drivers 2 326

administration staff 2 499

DKK/kg

2.3. Energy

0.14

diesel 0.0020 l/kg 0.023

electric energy (sorting) 0.034 kWh/kg 0.065

electric energy (compactor) 0.025 kWh/kg 0.048

Total 1.05

Table 68: Revenues, Total costs and Net Revenue for the Sorting facility

DKK/ kg of packaging

Revenues* =Total costs=1.05

Net revenue 0

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D7 Mechanical Recycling

Table 69: Capital costs for the Recycling Facility

1.Capital cost Ye

ars

Ra

te

Present cost

(DKK)

DKK/y

DKK/kg

produced

1.1.Civil works 15 7

%

10,473,840

1.2.Project management and

design costs

15 7

%

6,982,560

1.3.Equipment 15 7

%

154,550,237

Bale breaking and NIR/colour

sorting section

39,241,987

Bale breaking and sorting

conveyors and installation

9,810,497

Hot flake washing 65,941,551

Hot flake washing conveyors and

installation

16,487,570

PET extrusion 18,451,415

PET extrusion conveyors and

installation

4,617,218

Total 15 7

%

172,006,637 18,885,

404

0.24

Table 70: Operational and maintenance costs for the Recycling facility

2.Operational and maintenance costs DKK/y DKK/kg

produced

2.1.Insurance 1047384 0.013

2.2.Communications 174,564 0.0022

2.3.Repairs-maintenance 5% of investment 8,600,332 0.11

2.4.Salaries number 6,085,423 0.076

Bale breaking and sorting 3 operators/shift 2,317,128

Flake washing 2 operators/shift 1,544,752

Maintenance staff 4 operators/shift 772,376

Lab staff 2 operators/shift 386,188

Other staff 4 operators/shift 1,064,980

2.5. Materials 2.2

PET bale 2.1

Fresh water 0.10

2.6.Energy 0.15

Natural ga energy 0.12

Electric Energy 0.027

Total 2.6

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Table 71: Revenues, Total costs and Net Revenue for the Recycling facility

DKK/kg produced

Revenues 7.5

Total costs 2.8

Net revenue 4.6

D8 Mechanical Recycling followed by the supercleaning process and

pelletizing

Table 72: Capital costs for the Recycling Facility including supercleaning and pelletizing

1.Capital cost Years Rate Present cost

(DKK)

DKK/y DKK/kg

produced

1.1.Civil works 15 7% 10,473,840 1,149,971 0.01

1.2.Project management

and design costs

15 7% 6,982,560

766,648 0.01

1.3.Equipment 15 7% 193,792,225 21,277,345 0.27

Bale breaking and

NIR/colour sorting section

39,241,987

Bale breaking and sorting

conveyors and installation

9,810,497

Hot flake washing 65,941,551

Hot flake washing

conveyors and installation

16,487,570

PET extrusion 18,451,415

PET extrusion conveyors

and installation

4,617,218

Supercleaning reactor 39,241,987

Total 15 7% 211,248,625 23,193,963 0.29

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Table 73: Operational and maintenance costs for the Recycling Facility including supercleaning and pelletizing

2.Operational and maintenance

costs

DKK/y DKK/kg

produced

2.1. Insurance 0.013

2.2. Communications 174,564 0.0022

2.3. Repairs-maintenance 5% of the

investment cost

8,600,332 0.11

2.4. Salaries 6,085,423 0.076

Bale breaking and sorting 3 operators/shift 2,317,128

Flake washing 2 operators/shift 1,544,752

maintenance staff 4 operators/shift 772,376

lab staff 2 operators/shift 386,188

Other staff 4 operators/shift 1,064,980

2.5.Materials (for 1kg output) 2.2

PET bale 1.31 2.1

Fresh water 5.92 0.1

2.6. Energy 0.2

Natural gas energy for recycling 0.695 0.1

Electric Energy for recycling 0.2919 0.0

Heat (from natural gas) for

pelletizing

0.068 0.012 0.0027

Pellet extrusion 447 0.018

Energy consumption for

supercleaning

0.12 0.021 0.0048

Total 2.6

Table 74: Revenues from the Recycling Facility including supercleaning and pelletizing

Revenues DKK/y DKK/kg produced

SCR-PET flakes 8.36266 6.5

SCR-PET Pellets 8.36 1.9

Total 8.4

Table 75: Revenues, Total costs and Net Revenue for the Recycling facility including supercleaning and pelletizing

DKK/kg produced

Total costs 2.9

Revenues 8.4

Net revenue 5.46

D9 Landfill in UK

The life cycle costing of the present landfill refers to a new extension of an existing

site in UK according to Dominic Hogg & Eunomia Research & Consulting. The

calculations corespond a fill volume of 175000tons of waste and the expected life of

the facility is 10 years.

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Table 76: Capital costs for the Landfilling in UK

1.Capital costs Present cost

(DKK)

Life

(y)

Rate Annual costs

(DKK/y)

DKK/kg

1.1.Site assessment 2387200 10 7% 339884 0.0019

1.2.Acquisition 11936000 10 7% 1699418 0.010

1.3.Capex and

development

105101923 10 7% 14964149 0.086

1.4.Restoration 7161600 10 7% 1019651 0.0058

Total 0.10

Table 77: Operational for the Landfilling in UK

2.Operational costs Annual costs (DKK/y) DKK/kg

Operation 14323200 0.082

Landfill tax 0.56

Total 0.64

Table 78: End of life costs for the Landfilling in UK

3. End of life costs Present cost

(DKK)

Life (y) Rate Annual costs

(DKK/y)

DKK/kg

Aftercare 36737385 10 7% 5230577 0.030

Total 0.030

Table 79: Revenues for the Landfilling in UK

4.Revenues DKK/kg

4.1. Gate fee 741.90 DKK/ton 0.74

Total 0.74

Table 80: Revenues, Total costs and Net Revenue for the Landfilling in UK

DKK/kg

Total costs 0.77

Revenues -0.74

Net cost/ net revenue 0.031

D10 Manual Dishwashing

Table 81: Life cycle costing for the manual dishwashing washing process

Costs DKK/packaging DKK/1000

packaging

DKK/50

packaging

1.Capital cost 0.087 87 4.4

brush/sponge 0.087 87 4.4

2.Operation costs 0.34 336 16.8

water and drainage 0.34 336 16.8

Total 0.42 423 21.1

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D11 Automatic Dishwashing

Table 82: Animalization of the dishwasher’s capital cost

Capital costs Years Rate Present cost (DKK) DKK/y DKK/cycle

Dishwasher A+ 15 5% 4294 413.69 1.48

Table 83: Life cycle costing for the automatic washing process

Costs DKK/ packaging DKK/50packaging

1.Capital costs 0.12 6.16

2.Operational and maintenance costs 0.42 21.1

Maintenance costs 0.012 0.61

Detergent 0.10 4.8

Rinsing agent 0.015 0.73

Electricity 0.24 12.0

Water and drainage 0.060 3.0

Total costs 0.54 27.2

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Annex E: Environmental Results

E1 Characterized Results Table 84: Characterized results for scenario1

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM kg CO2-Eq kg CFC-11-

Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-Eq

CTU CTU CTU MJ kgPM2.5-

eq

Bottom ash

landfill

2.67E-02 1.87E-11 9.86E-05 7.16E-05 1.12E-04 3.58E-07 1.95E-16 3.07E-09 6.50E-10 1.71E-01 2.32E+00 2.93E-06

Collection and transportation

6.10E-01 5.96E-10 2.87E-03 1.74E-03 3.02E-03 0.00E+00 2.97E-16 1.92E-11 4.04E-09 1.59E-02 8.27E+01 1.55E-05

Transportation

to mineral landfill

2.34E-02 2.29E-11 9.56E-05 5.79E-05 9.84E-05 0.00E+00 1.14E-17 7.37E-13 1.55E-10 6.09E-04 3.17E+00 5.50E-07

Waste

Incineration,

DK

-2.95E+01 -3.31E-08 -2.41E-01 -3.20E-01 -2.61E-01 4.92E-08 1.25E-08 -9.78E-09 -1.24E-06 -2.90E-01 -1.58E+03 -1.17E-02

Packaging

production

2.27E+00 -3.76E-06 -1.84E-01 -2.16E-01 -1.07E-01 -5.15E-05 -3.41E-04 -1.05E-06 -4.58E-06 -3.07E+01 -1.32E+03 -2.64E-02

Production of

virgin foil

-2.35E+01 -1.68E-06 -8.95E-02 -8.32E-02 -4.41E-02 -2.76E-05 -1.93E-04 -5.54E-07 -2.02E-06 -1.60E+01 -9.32E+02 -8.82E-03

Transport of cut

foil (from DK

to foil production

facility in UK )

1.12E+00 2.43E-08 7.05E-03 6.67E-03 7.37E-03 1.20E-07 2.00E-08 1.42E-09 1.44E-08 6.33E-02 1.25E+02 4.59E-04

Transportation of foil (from

UK to

packaging production

facility in DK)

3.10E+00 6.74E-08 1.96E-02 1.85E-02 2.05E-02 3.33E-07 5.57E-08 3.95E-09 4.01E-08 1.76E-01 3.47E+02 1.28E-03

Virgin PET

pellets

3.39E+02 1.41E-05 9.58E-01 1.12E+00 6.87E-01 1.91E-04 1.27E-03 3.92E-06 2.03E-05 1.15E+02 9.09E+03 1.25E-01

sum 2.93E+02 8.71E-06 4.74E-01 5.29E-01 3.06E-01 1.13E-04 7.35E-04 2.32E-06 1.26E-05 6.84E+01 5.81E+03 7.95E-02

savings -5.30E+01 -5.47E-06 -5.15E-01 -6.19E-01 -4.12E-01 -7.90E-05 -5.34E-04 -1.61E-06 -7.84E-06 -4.70E+01 -3.84E+03 -4.69E-02

burdens 3.46E+02 1.42E-05 9.88E-01 1.15E+00 7.18E-01 1.92E-04 1.27E-03 3.93E-06 2.04E-05 1.15E+02 9.65E+03 1.26E-01

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Table 85: Characterized results for scenario2

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

kg CO2-

Eq

kg CFC-

11-Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-

Eq

CTU CTU CTU MJ kgPM2.5-

eq

Bottom ash

landfill

6.63E-03 4.64E-12 2.45E-05 1.78E-05 2.79E-05 8.90E-08 4.84E-17 7.64E-10 1.62E-10 4.25E-02 5.77E-01 7.29E-07

Collection and

transportation

6.02E-01 5.88E-10 2.83E-03 1.72E-03 2.98E-03 0.00E+00 2.94E-16 1.89E-11 3.99E-09 1.57E-02 8.16E+01 1.53E-05

Manual dish

washing

3.50E+00 3.18E-07 1.53E-02 2.81E-02 2.80E-02 7.66E-03 1.20E-05 7.30E-07 1.41E-05 3.25E+01 3.25E+01 2.38E-03

PET Recycling

(sc2)

-5.04E+01 1.19E-07 -2.51E-01 -1.67E-01 -1.21E-01 -1.52E-03 -1.45E-06 -4.02E-07 -2.13E-08 -4.81E+00 -2.28E+03 -9.44E-03

Sanitary

landfill

5.87E-02 6.80E-09 7.59E-04 4.53E-04 7.77E-04 3.83E-08 1.17E-08 4.02E-10 1.95E-09 1.03E-02 8.28E-01 7.06E-05

Sorting facility 4.34E+00 1.70E-09 6.19E-03 5.47E-03 6.83E-03 0.00E+00 4.28E-16 3.15E-10 3.80E-08 1.65E-02 1.02E+02 3.96E-04

Transportation

(bottom ash-

mineral

landfill)

5.82E-03 5.69E-12 2.37E-05 1.44E-05 2.45E-05 0.00E+00 2.84E-18 1.83E-13 3.85E-11 1.51E-04 7.89E-01 1.37E-07

Transportation

(DK-UK)

1.80E+00 3.63E-08 1.11E-02 1.03E-02 1.16E-02 1.79E-07 2.99E-08 2.12E-09 2.24E-08 9.79E-02 2.05E+02 6.88E-04

Transportation

(residues-

sanitary

landfill)

2.57E-02 2.51E-11 1.05E-04 6.34E-05 1.08E-04 0.00E+00 1.25E-17 8.07E-13 1.70E-10 6.68E-04 3.48E+00 6.02E-07

Transportation

(sorting

facility-

Vestforbrændin

g)

3.01E-02 2.94E-11 1.23E-04 7.44E-05 1.26E-04 0.00E+00 1.47E-17 9.47E-13 1.99E-10 7.83E-04 4.08E+00 7.06E-07

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Table 86: Characterized results for scenario2 (continue)

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

kg CO2-

Eq

kg CFC-

11-Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-

Eq

CTU CTU CTU MJ kgPM2.5-

eq

Waste

Incineration,

DK

-7.25E+00 -8.28E-09 -6.02E-02 -7.98E-02 -6.52E-02 1.22E-08 3.08E-09 -2.44E-09 -3.10E-07 -7.23E-02 -3.95E+02 -2.92E-03

Packaging

production

2.27E+00 -3.76E-06 -1.84E-01 -2.16E-01 -1.07E-01 -5.15E-05 -3.41E-04 -1.05E-06 -4.58E-06 -3.07E+01 -1.32E+03 -2.64E-02

Production of

virgin foil

-2.35E+01 -1.68E-06 -8.95E-02 -8.32E-02 -4.41E-02 -2.76E-05 -1.93E-04 -5.54E-07 -2.02E-06 -1.60E+01 -9.32E+02 -8.82E-03

Transport of

cut foil (from

DK to foil

production

facility in UK )

1.12E+00 2.43E-08 7.05E-03 6.67E-03 7.37E-03 1.20E-07 2.00E-08 1.42E-09 1.44E-08 6.33E-02 1.25E+02 4.59E-04

Transportation

of foil (from

UK to

packaging

production

facility in DK)

3.10E+00 6.74E-08 1.96E-02 1.85E-02 2.05E-02 3.33E-07 5.57E-08 3.95E-09 4.01E-08 1.76E-01 3.47E+02 1.28E-03

Virgin PET

pellets

3.39E+02 1.41E-05 9.58E-01 1.12E+00 6.87E-01 1.91E-04 1.27E-03 3.92E-06 2.03E-05 1.15E+02 9.09E+03 1.25E-01

sum 2.75E+02 9.21E-06 4.37E-01 6.46E-01 4.28E-01 6.26E-03 7.46E-04 2.65E-06 2.76E-05 9.63E+01 5.06E+03 8.24E-02

savings -8.11E+01 -5.44E-06 -5.85E-01 -5.46E-01 -3.37E-01 -1.60E-03 -5.36E-04 -2.00E-06 -6.93E-06 -5.16E+01 -4.93E+03 -4.76E-02

burdens 3.56E+02 1.47E-05 1.02E+00 1.19E+00 7.65E-01 7.85E-03 1.28E-03 4.66E-06 3.46E-05 1.48E+02 9.99E+03 1.30E-01

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Table 87: Characterized results for scenario 3

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM kg CO2-

Eq

kg CFC-11-

Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-

Eq

CTU CTU CTU MJ kgPM2.5-

eq

Bottom ash

landfill

6.63E-03 4.64E-12 2.45E-05 1.78E-05 2.79E-05 8.90E-08 4.84E-17 7.64E-10 1.62E-10 4.25E-02 5.77E-01 7.29E-07

Collection and

transportation

6.02E-01 5.88E-10 2.83E-03 1.72E-03 2.98E-03 0.00E+00 2.94E-16 1.89E-11 3.99E-09 1.57E-02 8.16E+01 1.53E-05

Manual dish

washing

3.50E+00 3.18E-07 1.53E-02 2.81E-02 2.80E-02 7.66E-03 1.20E-05 7.30E-07 1.41E-05 3.25E+01 3.25E+01 2.38E-03

PET

Reprocessing

-

7.57E+01

-3.98E-06 -2.55E-01 -2.85E-01 -1.74E-01 -5.64E-05 -3.78E-04 -1.12E-06 -5.57E-06 -3.35E+01 -2.51E+03 -3.26E-02

Sanitary landfill 6.39E-02 7.40E-09 8.26E-04 4.93E-04 8.46E-04 4.16E-08 1.27E-08 4.37E-10 2.12E-09 1.13E-02 9.02E-01 7.69E-05

Sorting facility 4.34E+00 1.70E-09 6.19E-03 5.47E-03 6.83E-03 0.00E+00 4.28E-16 3.15E-10 3.80E-08 1.65E-02 1.02E+02 3.96E-04

Transportation

(bottom ash-

mineral landfill,

DK)

5.82E-03 5.69E-12 2.37E-05 1.44E-05 2.45E-05 0.00E+00 2.84E-18 1.83E-13 3.85E-11 1.51E-04 7.89E-01 1.37E-07

Transportation

(DK-UK)

1.80E+00 3.63E-08 1.11E-02 1.03E-02 1.16E-02 1.79E-07 2.99E-08 2.12E-09 2.24E-08 9.79E-02 2.05E+02 6.88E-04

Transportation

(residues-landfill,

UK)

8.38E-02 8.19E-11 3.42E-04 2.07E-04 3.52E-04 0.00E+00 4.09E-17 2.64E-12 5.55E-10 2.18E-03 1.14E+01 1.97E-06

Transportation

(sorting facility-

Vestforbrænding)

3.01E-02 2.94E-11 1.23E-04 7.44E-05 1.26E-04 0.00E+00 1.47E-17 9.47E-13 1.99E-10 7.83E-04 4.08E+00 7.06E-07

Waste

Incineration, DK

-7.25E+00 -8.28E-09 -6.02E-02 -7.98E-02 -6.52E-02 1.22E-08 3.08E-09 -2.44E-09 -3.10E-07 -7.23E-02 -3.95E+02 -2.92E-03

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Table 88: Characterized results for scenario 3 (continue)

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM kg CO2-

Eq

kg CFC-11-

Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-

Eq

CTU CTU CTU MJ kgPM2.5-

eq

Packaging

production

2.27E+00 -3.76E-06 -1.84E-01 -2.16E-01 -1.07E-01 -5.15E-05 -3.41E-04 -1.05E-06 -4.58E-06 -3.07E+01 -1.32E+03 -2.64E-02

Production of

virgin foil

-2.35E+01 -1.68E-06 -8.95E-02 -8.32E-02 -4.41E-02 -2.76E-05 -1.93E-04 -5.54E-07 -2.02E-06 -1.60E+01 -9.32E+02 -8.82E-03

Transport of cut

foil (from DK to

foil production

facility in UK )

1.12E+00 2.43E-08 7.05E-03 6.67E-03 7.37E-03 1.20E-07 2.00E-08 1.42E-09 1.44E-08 6.33E-02 1.25E+02 4.59E-04

Transportation of

foil (from UK to

packaging

production

facility in DK)

3.10E+00 6.74E-08 1.96E-02 1.85E-02 2.05E-02 3.33E-07 5.57E-08 3.95E-09 4.01E-08 1.76E-01 3.47E+02 1.28E-03

Virgin PET

pellets

3.39E+02 1.41E-05 9.58E-01 1.12E+00 6.87E-01 1.91E-04 1.27E-03 3.92E-06 2.03E-05 1.15E+02 9.09E+03 1.25E-01

sum 2.49E+02 5.11E-06 4.33E-01 5.28E-01 3.76E-01 7.72E-03 3.69E-04 1.93E-06 2.21E-05 6.76E+01 4.84E+03 5.93E-02

savings -1.06E+02 -9.42E-06 -5.89E-01 -6.64E-01 -3.90E-01 -1.35E-04 -9.12E-04 -2.72E-06 -1.25E-05 -8.02E+01 -5.16E+03 -7.07E-02

burdens 3.56E+02 1.45E-05 1.02E+00 1.19E+00 7.66E-01 7.85E-03 1.28E-03 4.66E-06 3.46E-05 1.48E+02 1.00E+04 1.30E-01

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Table 89: Characterized results for scenario 4

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

kg CO2-

Eq

kg CFC-11-

Eq

kg NMVOC kg SO2-Eq kg NOx-Eq kg P-Eq kg

antimony-

Eq

CTU CTU CTU MJ kgPM2.5-

eq

Automatic

dishwashing

1.24E+02 6.69E-07 1.20E-01 2.07E-01 1.27E-01 1.30E-02 5.53E-05 1.08E-06 5.58E-06 1.88E+01 1.49E+03 1.58E-02

Bottom ash

landfill

2.65E-03 1.85E-12 9.78E-06 7.10E-06 1.11E-05 3.55E-08 1.93E-17 3.05E-10 6.45E-11 1.70E-02 2.30E-01 2.91E-07

Collection and

transportation

5.99E-02 5.85E-11 2.82E-04 1.71E-04 2.97E-04 0.00E+00 2.92E-17 1.89E-12 3.97E-10 1.56E-03 8.12E+00 1.52E-06

Manual dish

washing

3.32E+00 3.02E-07 1.45E-02 2.67E-02 2.66E-02 7.28E-03 1.14E-05 6.93E-07 1.34E-05 3.08E+01 3.08E+01 2.26E-03

Transportation

(bottom ash-

landfill)

2.32E-03 2.27E-12 9.48E-06 5.74E-06 9.76E-06 0.00E+00 1.13E-18 7.31E-14 1.54E-11 6.04E-05 3.15E-01 5.45E-08

Waste

Incineration,

DK

-2.88E+00 -3.31E-09 -2.41E-02 -3.19E-02 -2.61E-02 4.84E-09 1.23E-09 -9.75E-10 -1.24E-07 -2.89E-02 -1.58E+02 -1.17E-03

sum 1.24E+02 9.68E-07 1.11E-01 2.02E-01 1.28E-01 2.02E-02 6.66E-05 1.77E-06 1.89E-05 4.96E+01 1.37E+03 1.69E-02

savings -2.88E+00 -3.31E-09 -2.41E-02 -3.19E-02 -2.61E-02 4.84E-09 1.23E-09 -9.75E-10 -1.24E-07 -2.89E-02 -1.58E+02 -1.17E-03

burdens 1.27E+02 9.71E-07 1.35E-01 2.34E-01 1.54E-01 2.02E-02 6.66E-05 1.77E-06 1.90E-05 4.97E+01 1.53E+03 1.80E-02

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E2 Normalized Results Table 90: Normalized results for scenario1

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE

Bottom ash

landfill

3.45E-03 9.11E-07 1.86E-03 1.44E-03 3.15E-04 3.73E-04 8.98E-13 9.46E-02 7.99E-04 3.38E-02 2.88E-02 6.23E-04

Collection and

transportation

7.90E-02 2.91E-05 5.43E-02 3.49E-02 8.48E-03 0.00E+00 1.37E-12 5.90E-04 4.96E-03 3.14E-03 1.03E+00 3.29E-03

Transportation

to mineral

landfill

3.03E-03 1.12E-06 1.81E-03 1.16E-03 2.76E-04 0.00E+00 5.26E-14 2.27E-05 1.91E-04 1.20E-04 3.94E-02 1.17E-04

Waste

Incineration,

DK

-3.81E+00 -1.61E-03 -4.55E+00 -6.41E+00 -7.32E-01 5.13E-05 5.76E-05 -3.01E-01 -1.53E+00 -5.72E-02 -1.97E+01 -2.48E+00

Packaging

production

2.93E-01 -1.83E-01 -3.48E+00 -4.33E+00 -3.01E-01 -5.36E-02 -1.57E+00 -3.22E+01 -5.63E+00 -6.07E+00 -1.64E+01 -5.61E+00

Production of

virgin foil

-3.04E+00 -8.19E-02 -1.69E+00 -1.67E+00 -1.24E-01 -2.87E-02 -8.88E-01 -1.70E+01 -2.48E+00 -3.16E+00 -1.16E+01 -1.87E+00

Transport of

cut foil (from

DK to foil

production

facility in UK

1.45E-01 1.18E-03 1.33E-01 1.34E-01 2.07E-02 1.25E-04 9.24E-05 4.37E-02 1.77E-02 1.25E-02 1.55E+00 9.75E-02

Transportation

of foil (from

UK to

packaging

production

facility in DK)

4.02E-01 3.29E-03 3.70E-01 3.72E-01 5.75E-02 3.46E-04 2.57E-04 1.21E-01 4.92E-02 3.47E-02 4.30E+00 2.71E-01

Virgin PET

pellets

4.38E+01 6.87E-01 1.81E+01 2.25E+01 1.93E+00 1.99E-01 5.85E+00 1.21E+02 2.50E+01 2.27E+01 1.13E+02 2.65E+01

sum 3.79E+01 4.25E-01 8.95E+00 1.06E+01 8.60E-01 1.18E-01 3.39E+00 7.13E+01 1.54E+01 1.35E+01 7.21E+01 1.69E+01

savings -6.85E+00 -2.67E-01 -9.73E+00 -1.24E+01 -1.16E+00 -8.23E-02 -2.46E+00 -4.95E+01 -9.63E+00 -9.29E+00 -4.76E+01 -9.96E+00

burdens 4.48E+01 6.91E-01 1.87E+01 2.30E+01 2.02E+00 2.00E-01 5.85E+00 1.21E+02 2.50E+01 2.28E+01 1.20E+02 2.68E+01

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Table 91: Normalized results for scenario 2

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE

Bottom ash landfill 8.58E-04 2.26E-07 4.63E-04 3.57E-04 7.83E-05 9.27E-05 2.23E-13 2.35E-02 1.98E-04 8.39E-03 7.16E-03 1.55E-04

Collection and

transportation

7.79E-02 2.87E-05 5.35E-02 3.44E-02 8.37E-03 0.00E+00 1.35E-12 5.83E-04 4.90E-03 3.09E-03 1.01E+00 3.25E-03

Manual dish washing

4.53E-01 1.55E-02 2.88E-01 5.63E-01 7.88E-02 7.98E+00 5.51E-02 2.25E+01 1.73E+01 6.41E+00 4.03E-01 5.04E-01

PET Recycling

(sc2)

-6.52E+00 5.80E-03 -4.74E+00 -3.35E+00 -3.39E-01 -1.58E+00 -6.69E-03 -1.24E+01 -2.62E-02 -9.51E-01 -2.83E+01 -2.00E+00

Sanitary landfill 7.59E-03 3.32E-04 1.43E-02 9.07E-03 2.18E-03 3.99E-05 5.38E-05 1.24E-02 2.39E-03 2.04E-03 1.03E-02 1.50E-02

Sorting facility 5.61E-01 8.31E-05 1.17E-01 1.10E-01 1.92E-02 0.00E+00 1.97E-12 9.69E-03 4.67E-02 3.26E-03 1.26E+00 8.42E-02

Transportation

(bottom ash-mineral

landfill)

7.53E-04 2.77E-07 4.49E-04 2.88E-04 6.87E-05 0.00E+00 1.31E-14 5.63E-06 4.73E-05 2.99E-05 9.78E-03 2.90E-05

Transportation (DK-UK)

2.33E-01 1.77E-03 2.09E-01 2.06E-01 3.25E-02 1.86E-04 1.38E-04 6.53E-02 2.75E-02 1.93E-02 2.54E+00 1.46E-01

Transportation

(residues-sanitary landfill)

3.32E-03 1.22E-06 1.98E-03 1.27E-03 3.03E-04 0.00E+00 5.76E-14 2.48E-05 2.09E-04 1.32E-04 4.31E-02 1.28E-04

Transportation

(sorting facility-

Vestforbrænding)

3.90E-03 1.43E-06 2.32E-03 1.49E-03 3.55E-04 0.00E+00 6.76E-14 2.91E-05 2.45E-04 1.55E-04 5.06E-02 1.50E-04

Waste Incineration -9.38E-01 -4.04E-04 -1.14E+00 -1.60E+00 -1.83E-01 1.27E-05 1.42E-05 -7.51E-02 -3.81E-01 -1.43E-02 -4.90E+00 -6.19E-01

Packaging

production

2.93E-01 -1.83E-01 -3.48E+00 -4.33E+00 -3.01E-01 -5.36E-02 -1.57E+00 -3.22E+01 -5.63E+00 -6.07E+00 -1.64E+01 -5.61E+00

Production of virgin foil

-3.04E+00 -8.19E-02 -1.69E+00 -1.67E+00 -1.24E-01 -2.87E-02 -8.88E-01 -1.70E+01 -2.48E+00 -3.16E+00 -1.16E+01 -1.87E+00

Transport of cut foil

(from DK to foil production facility

in UK )

1.45E-01 1.18E-03 1.33E-01 1.34E-01 2.07E-02 1.25E-04 9.24E-05 4.37E-02 1.77E-02 1.25E-02 1.55E+00 9.75E-02

Transportation of

foil (from UK to packaging

production facility

in DK)

4.02E-01 3.29E-03 3.70E-01 3.72E-01 5.75E-02 3.46E-04 2.57E-04 1.21E-01 4.92E-02 3.47E-02 4.30E+00 2.71E-01

Virgin PET pellets 4.38E+01 6.87E-01 1.81E+01 2.25E+01 1.93E+00 1.99E-01 5.85E+00 1.21E+02 2.50E+01 2.27E+01 1.13E+02 2.65E+01

sum 3.55E+01 4.49E-01 8.25E+00 1.30E+01 1.20E+00 6.52E+00 3.44E+00 8.16E+01 3.39E+01 1.90E+01 6.28E+01 1.75E+01

savings -1.02E+01 -2.65E-01 -1.11E+01 -1.10E+01 -9.47E-01 -1.66E+00 -2.47E+00 -6.17E+01 -8.51E+00 -1.02E+01 -6.12E+01 -1.01E+01

burdens 4.57E+01 7.15E-01 1.93E+01 2.39E+01 2.15E+00 8.18E+00 5.90E+00 1.43E+02 4.25E+01 2.92E+01 1.24E+02 2.76E+01

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Table 92: Normalized results for scenario 3

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE

Bottom ash

landfill

8.58E-04 2.26E-07 4.63E-04 3.57E-04 7.83E-05 9.27E-05 2.23E-13 2.35E-02 1.98E-04 8.39E-03 7.16E-03 1.55E-04

Collection and

transportation

7.79E-02 2.87E-05 5.35E-02 3.44E-02 8.37E-03 0.00E+00 1.35E-12 5.83E-04 4.90E-03 3.09E-03 1.01E+00 3.25E-03

Manual dish

washing

4.53E-01 1.55E-02 2.88E-01 5.63E-01 7.88E-02 7.98E+00 5.51E-02 2.25E+01 1.73E+01 6.41E+00 4.03E-01 5.04E-01

PET

Reprocessing

-9.80E+00 -1.94E-01 -4.82E+00 -5.71E+00 -4.87E-01 -5.88E-02 -1.74E+00 -3.44E+01 -6.84E+00 -6.61E+00 -3.11E+01 -6.92E+00

Sanitary landfill 8.26E-03 3.61E-04 1.56E-02 9.88E-03 2.38E-03 4.34E-05 5.85E-05 1.35E-02 2.60E-03 2.22E-03 1.12E-02 1.63E-02

Sorting facility 5.61E-01 8.31E-05 1.17E-01 1.10E-01 1.92E-02 0.00E+00 1.97E-12 9.69E-03 4.67E-02 3.26E-03 1.26E+00 8.42E-02

Transportation

(bottom ash-

mineral landfill,

DK)

7.53E-04 2.77E-07 4.49E-04 2.88E-04 6.87E-05 0.00E+00 1.31E-14 5.63E-06 4.73E-05 2.99E-05 9.78E-03 2.90E-05

Transportation

(DK-UK)

2.33E-01 1.77E-03 2.09E-01 2.06E-01 3.25E-02 1.86E-04 1.38E-04 6.53E-02 2.75E-02 1.93E-02 2.54E+00 1.46E-01

Transportation

(residues-

landfill, UK)

1.08E-02 3.99E-06 6.46E-03 4.15E-03 9.89E-04 0.00E+00 1.88E-13 8.11E-05 6.81E-04 4.31E-04 1.41E-01 4.17E-04

Transportation

(sorting facility-

Vestforbrændin

g)

3.90E-03 1.43E-06 2.32E-03 1.49E-03 3.55E-04 0.00E+00 6.76E-14 2.91E-05 2.45E-04 1.55E-04 5.06E-02 1.50E-04

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Table 93: Normalized results for scenario 3 (continue)

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE

Waste

Incineration,

DK

-9.38E-01 -4.04E-04 -1.14E+00 -1.60E+00 -1.83E-01 1.27E-05 1.42E-05 -7.51E-02 -3.81E-01 -1.43E-02 -4.90E+00 -6.19E-01

Packaging

production

2.93E-01 -1.83E-01 -3.48E+00 -4.33E+00 -3.01E-01 -5.36E-02 -1.57E+00 -3.22E+01 -5.63E+00 -6.07E+00 -1.64E+01 -5.61E+00

Production of

virgin foil

-3.04E+00 -8.19E-02 -1.69E+00 -1.67E+00 -1.24E-01 -2.87E-02 -8.88E-01 -1.70E+01 -2.48E+00 -3.16E+00 -1.16E+01 -1.87E+00

Transport of

cut foil (from

DK to foil

production

facility in UK )

1.45E-01 1.18E-03 1.33E-01 1.34E-01 2.07E-02 1.25E-04 9.24E-05 4.37E-02 1.77E-02 1.25E-02 1.55E+00 9.75E-02

Transportation

of foil (from

UK to

packaging

production

facility in DK)

4.02E-01 3.29E-03 3.70E-01 3.72E-01 5.75E-02 3.46E-04 2.57E-04 1.21E-01 4.92E-02 3.47E-02 4.30E+00 2.71E-01

Virgin PET

pellets

4.38E+01 6.87E-01 1.81E+01 2.25E+01 1.93E+00 1.99E-01 5.85E+00 1.21E+02 2.50E+01 2.27E+01 1.13E+02 2.65E+01

sum 3.23E+01 2.49E-01 8.18E+00 1.06E+01 1.06E+00 8.04E+00 1.70E+00 5.95E+01 2.71E+01 1.34E+01 6.00E+01 1.26E+01

savings -1.38E+01 -4.60E-01 -

1.11E+01

-

1.33E+01

-

1.10E+00

-1.41E-

01

-

4.20E+00

-

8.37E+01

-

1.53E+01

-

1.59E+01

-

6.40E+01

-

1.50E+01

burdens 4.60E+01 7.09E-01 1.93E+01 2.39E+01 2.15E+00 8.18E+00 5.90E+00 1.43E+02 4.25E+01 2.92E+01 1.24E+02 2.76E+01

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142

Table 94: Normalized results for scenario 4

Name CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE mPE

Automatic

dishwashing

1.60E+01 3.26E-02 2.27E+00 4.15E+00 3.57E-01 1.35E+01 2.55E-01 3.32E+01 6.85E+00 3.72E+00 1.84E+01 3.35E+00

Bottom ash

landfill

3.42E-04 9.04E-08 1.85E-04 1.42E-04 3.12E-05 3.70E-05 8.91E-14 9.38E-03 7.92E-05 3.35E-03 2.85E-03 6.18E-05

Collection and

transportation

7.75E-03 2.86E-06 5.33E-03 3.42E-03 8.33E-04 0.00E+00 1.35E-13 5.80E-05 4.87E-04 3.08E-04 1.01E-01 3.24E-04

Manual dish

washing

4.30E-01 1.47E-02 2.74E-01 5.35E-01 7.48E-02 7.58E+00 5.23E-02 2.13E+01 1.65E+01 6.09E+00 3.83E-01 4.79E-01

Transportation

(bottom ash-

landfill)

3.01E-04 1.11E-07 1.79E-04 1.15E-04 2.74E-05 0.00E+00 5.22E-15 2.25E-06 1.89E-05 1.19E-05 3.90E-03 1.16E-05

Waste

Incineration,

DK

-3.73E-01 -1.62E-04 -4.55E-01 -6.39E-01 -7.32E-02 5.04E-06 5.65E-06 -3.00E-02 -1.52E-01 -5.71E-03 -1.96E+00 -2.47E-01

sum 1.61E+01 4.72E-02 2.10E+00 4.05E+00 3.60E-01 2.11E+01 3.07E-01 5.45E+01 2.32E+01 9.81E+00 1.70E+01 3.58E+00

savings -3.73E-01 -1.62E-04 -4.55E-01 -6.39E-01 -7.32E-02 -3.00E-02 -1.52E-01 -5.71E-03 -1.96E+00 -2.47E-01

burdens 1.65E+01 4.74E-02 2.55E+00 4.69E+00 4.33E-01 2.11E+01 3.07E-01 5.46E+01 2.33E+01 9.82E+00 1.89E+01 3.83E+00

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143

E3 Main process and substance contributors

E3.1 Main substance-contributors

Table 95: Main substance-contributors for each impact category, for the ‘’Virgin PET pellet’’, ‘’Sanitary landfill’’, ‘’Bottom ash landfill’’ processes.

Virgin PET pellets'

extraction

Sanitary landfill Bottom ash landfill

Largest burden Substance Compart

ment

Substance Compart

ment

Substance Compart

ment

Climate change Carbon

dioxide

Air Carbon

dioxide

fossil, air

Air Carbon

dioxide,

fossil

Air

Stratospheric

ozone

depletion

Methane,

bromochlo

rodifluoro,

Halon

1211

Air

Methane,

Bromotrifluo

ro, Halon

1301

Air Methane

trichloroflu

oro, HCF

11

Air

Photochemical

oxidant

formation

Nitrogen

oxides

Air Nitrogen

oxides

Air Nitrogen

oxides

Air

Terrestrial

acidification

Sulfur

dioxide

Air Nitrogen

oxides

Air Nitrogen

oxides

Air

Eutrophication

potential

Nitrogen

oxides

Air Nitrogen

oxides

Air Nitrogen

oxides

Air

Freshwater

eutrophication

Phosphate Water Phosphorous Soil Phosphorus Water

Depletion of

abiotic

resources

Gold Natural

resource,

ground

Chromium Natural

resource

Ground

Aluminum Natural

resource

Ground

Human

toxicity,

carcinogenic

Chromium Water Chromium Water Chromium Water

Human

toxicity, non-

carcinogenic

Zinc Air Mercury Air Arsenic,

ion

Water

Ecotoxicity,

total

Vanadium Air Chromium Water Copper, ion Water

Depletion of

abiotic

resources,

fossil

Crude oil Natural

resource,

ground

Crude oil Natural

resource

Ground

Crude oil Natural

resource

Ground

Particulate

matter

Sulfur

dioxide

Air Particulates

<2.5 um

Air Particulates

<2.5 um

Air

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E3.2 Main contribution and saving sources in each process

E3.2.1 Non-toxic impact categories

Table 96: Main contribution and saving source in each process for each non-toxic impact category

Climate change Stratospheric

ozone depletion

Photochemical

oxidant

formation

Terrestrial

acidification

Eutrophication

potential

Freshwater

eutrophication

Particulate

matter

Largest Burden Saving Burden Saving Burden Saving Burden Saving Burden Saving Burden Saving Burden Saving

Manual

dishwashing

WWT - WWT - WWT - WWT - WWT - WWT - WWT -

PET

reprocessing

WWT Virgin

PET/PP

E Virgin

PET/PP

E Virgin

PET/PP

E Virgin

PET/PP

E Virgin

PET/PP

E Virgin

PET/PP

E Virgin

PET/PP

Sorting

facility

E - E - DF - E - DF - 0 - E -

Waste

incineration

E E WP E WP E PSE H PSE H PSE H PSE E

Automatic

dishwashing

E - DD - E

- E - E - DD - E -

Packaging

production

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

E - E Virgin

PET

Production

of virgin

foil

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

E Virgin

PET

WWT: Wastewater treatment WP: Water process DD: Detergent for dishwashers H: Heat

PSE: Process specific emissions E: Electricity DF: Diesel (forklifts)

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E3.2.2 Toxic impact categories

Table 97: Main contribution source of burdens and savings for each toxic category

Human toxicity,

carcinogenic

Human toxicity, non-

carcinogenic Ecotoxicity, total

Largest Burdens Savings Burdens Savings Burdens Savings

Manual

dishwashing

Wastewater

treatment

- Wastewater

treatment

- Wastewater

treatment

-

PET

reprocessing

Electricity Virgin

PET/PP

Electricity Virgin

PET/PP

Electricity Virgin

PET/PP

Sorting

facility

Electricity - Electricity - Diesel

(forklift)

Waste

incineration

Water

process

Electricity Specific

emissions

Electricity Limestone,

milled

Electricity

Automatic

dishwashing

Detergent

for

dishwasher

- Wastewater

treatment

- Detergent

for

dishwasher

-

Packaging

production

Electricity Virgin

PET

Electricity Virgin

PET

Electricity Virgin

PET

Production

of virgin

foil

Electricity Virgin

PET

Electricity Virgin

PET

Electricity Virgin

PET

E3.2.3 Resource depletion categories

Table 98: Main contribution source of burdens and savings for each Resource depletion category

Depletion of abiotic resources

Depletion of abiotic resources,

fossil

Largest Burdens Savings Burdens Savings

Manual

dishwashing

Wastewater

treatment

- Wastewater

treatment

-

PET

reprocessing

Electricity Avoided

production of

virgin PET/PP

Electricity Avoided

production of

virgin PET/PP

Sorting facility Diesel

(forklift)

- Diesel

(forklift)

-

Waste

incineration

Limestone,

milled

Electricity Water process Electricity

Automatic

dishwashing

Detergent for

dishwasher

- Electricity -

Packaging

production

Electricity Virgin PET Electricity Virgin PET

Production of

virgin foil

Electricity Virgin PET Electricity Virgin PET

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146

E4 Stratospheric ozone depletion graph

Figure 66: Performance of the scenarios in Stratospheric ozone depletion category

Figure 67: Composition of stratospheric ozone depletion impacts

0.00

0.05

0.10

0.15

0.20

0.25

0.30

0.35

0.40

0.45

0.50

scenario 1 scenario 2 scenario 3 scenario 4

mP

E/f.

u.

Stratospheric ozone depletion

-6.0E-01

-4.0E-01

-2.0E-01

0.0E+00

2.0E-01

4.0E-01

6.0E-01

8.0E-01

sc1 sc2 sc3 sc4

Stratospheric ozone depletion

mP

E/f.

u.

Composition of impacts in Stratospheric ozone deplition

Automatic dishwashing Virgin PET pellets Production of virgin foil

Packaging production Waste Incineration, DK Sorting facility

Sanitary landfill PET Reprocessing Manual dish washing

Collection and transportation Bottom ash landfill Total

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147

Annex F: Economic Results

F1 Scenario 1

Figure 68: Life cycle costing for scenario 1

Cost Country Cost

(DKK)

Revenues

(DKK)

Net revenue

(DKK)

Foil production UK 1340 -1576 -236

Collection and

Transportation

UK,DK 55 -153 -98

Packaging production DK 1996 -2169 -172

Incineration DK 6340 -6340 0

Total 9731 -10238 -507

F2 Scenario 2

Figure 69: Life cycle costing for scenario 2

Costs Country Cost

(DKK)

Revenues

(DKK)

Net Revenues

(DKK)

Manual dish washing DK 423 0 423

Transportation and waste

collection

DK,UK 73 -206 -132

Sorting facility DK 50 -50 0

Waste Incineration DK 1563 -1563 0

PET reprocessing UK 111 -294 -183

Foil production UK 1340 -1576 -236

Packaging production DK 1996 -2169 -172

Sanitary Landfill UK 2.72 -9.51 -6.78

Total 5560 -5868 -307

F3 Scenario 3

Figure 70: Life cycle costing for scenario 3

Costs Country Cost

(DKK)

Revenues

(DKK)

Net Revenues

(DKK)

Manual dish washing DK 423 0 423

Transportation and waste

collection

DK,UK 73 -207 -132

Sorting facility DK 50 -50 0

Waste Incineration DK 1563 -1563 0

PET reprocessing UK 111 -320 -209

Foil production UK 1340 -1576 -236

Packaging production DK 1996 -2169 -172

Sanitary Landfill UK 2.97 -10.35 -7.38

Total 5560 -5896 -335

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F4 Scenario 4

Figure 71: Life cycle costing for scenario 4

Costs Country Costs

(DKK)

Revenue

(DKK)

Net revenue

(DKK)

Foil production UK 134 -158 -24

Waste collection and

transportation

UK,DK 5 -15 -10

Packaging production DK 200 -217 -17

Manual dish washing DK 21 0 -21

Automatic dishwashing DK 27 0 -27

Waste incineration DK 622 -622 0

Total sc4 1010 -1012 -2

F5 Total

Table 99: Summarizing table for Life cycle net costing for all the Scenarios

Net cost sc1 sc2 sc3 sc4

Manual dish washing 0 423 423 21

Transportation and waste collection 73 117 110 7

Waste Incineration 6 2 2 1

PET Reprocessing 0 -183 -209 0

Packaging production 2169 2169 2169 217

Sanitary Landfill 0 9.41 10.25 0

Automatic dishwashing 0 0 0 27

Net cost total 2248 2537 2504 273

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Annex G: Sensitivity analysis

G1 Sensitivity 1

G1.1 Adjusted modeling data

Table 100: Adjusted consumption amounts used for the modeling of the washing processes for 10 times of reuse

Scenario Type of

washing

Dirty

packaging

(1kg of

input)

Water (l) Energy

(kwh)

Cleanser

(kg)

Rinsing

agent

(kg)

Sens1.Sc4 manual 7.2 554.0

Sens1.Sc4 automatic 7.2 99.5 8.07 0.161 0.0184

G1.2 Composition comparisons

Aiming to a simpler comparison between the scenarios, the impacts were divided to

five contribution-sources: Upstream phase, Automatic dishwashing, Manual

dishwashing, Bottom ash landfill, Collection and transportation. The ‘’Upstream

processes’’ category includes all the processes mentioned in Chapter 4.2. In the

present case, ‘’Collection and transportation’’ category, represents only the waste

collection occurring in the disposal phase of the scenarios.

Figure 72: Comparison of the composition of Scenario 4 and Sesns1.Sc4, for the non-toxic categories

-5

0

5

10

15

20

25

sc4

sen

s1.s

c4 sc4

sen

s1.s

c4 sc4

sen

s1.s

c4 sc4

sen

s1.s

c4 sc4

sen

s1.s

c4 sc4

sen

s1.s

c4 sc4

sen

s1.s

c4

CC SOD POF TA EP FE PM

mP

E/ S

cen

ario

Comparison of the non-toxic categories of Scenario 4 and Sens1.Sc4

Upstream processes Waste Incineration Manual dish washing

Collection and transportation Bottom ash landfill Automatic dishwashing

sum

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Figure 73: Comparison of the composition of Scenario 4 and Sesns1.Sc4, for the toxic categories

Figure 74: Comparison of the composition of Scenario 4 and Sesns1.Sc4, for the resource depletion categories

-10

0

10

20

30

40

50

60

70

sc4 sens1.sc4 sc4 sens1.sc4 sc4 sens1.sc4

Human toxicity, carcinogenic Human toxicity, non-carcinogenic

Ecotoxicity, total

mP

E/Sc

en

ario

Comparison of toxic categories of Scenario 4 and

Sens1.Sc4

Upstream processes Waste Incineration Manual dish washing

Collection and transportation Bottom ash landfill Automatic dishwashing

sum

-10

-5

0

5

10

15

20

25

30

sc4 sens1.sc4 sc4 sens1.sc4

` Depletion of abiotic resources

mP

E/Sc

en

ario

Comparison of recourse deplition categories of Scenario 4 and Sens1.Sc4

Upstream processes Waste Incineration Manual dish washing

Collection and transportation Bottom ash landfill Automatic dishwashing

sum

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G2 Sensitivity 2

Figure 75: Composition of the single and multiple processed upstream phase

Figure 76: Impacts of Sensitivity 2 in non-toxic categories

-60

-40

-20

0

20

40

60

80

100

120

140M

-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

M-P S-P

CC SOD POF TA EP FE DAR HTC HTNC ET DARF PM

mP

E/U

pst

ream

ph

ase

Composition of the single and multiple processed upstream phase

Virgin PET pellets Transportation of foil Transportation of cut foil

Production of virgin foil Packaging production sum

0

5

10

15

20

25

30

35

40

45

CC SOD POF TA EP FE PM

mP

E/Sc

en

ario

Impacts of Sensitivity 2 in non-toxic categories

Sens2.Sc1

Sens2.Sc2

Sens2.Sc3

Sens2.Sc4

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Figure 77: Impacts of Sensitivity 2 in toxic categories

Figure 78: Impacts of Sensitivity 2 in resource depletion categories

0

20

40

60

80

100

120

140

HTC HTNC ET

mP

E/Sc

en

ario

Impacts of Sensitivity 2 in toxic categories

Sens2.Sc1

Sens2.Sc2

Sens2.Sc3

Sens2.Sc4

0

10

20

30

40

50

60

70

80

90

100

DAR DARF

mP

E./S

cen

ario

Impacts of Sensitivity 2 in Recourse depletion caterory

Sens2.Sc1

Sens2.Sc2

Sens2.Sc3

Sens2.Sc4