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„Energy from Chemical Fuels “ EEC 2012, Katowice. Prof. Dr.-Ing. Thomas Kolb, KITCC Germany. What are Chemical Fuels ?. C hemical F uels / C hemical E nergy Carriers, CEC : substances with chemical enthaly content produced for transport , storage - PowerPoint PPT Presentation
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„Energy from Chemical Fuels“EEC 2012, KatowiceProf. Dr.-Ing. Thomas Kolb, KIT CC Germany
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
What are Chemical Fuels?
2
Chemical Fuels / Chemical Energy Carriers, CEC:
substances with chemical enthaly content
• produced for transport, storage and use in energy conversion systems
• produced from fossil and biogenic energy resourcesi.e. low rank / quality fuels
• or synthesysed from chemical substances
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Energy from Chemical Fuels - field of operation
utilization
power
heat
mobility
chemical fuel
conversion
upgrading
electr. therm. energy
conversionchem. subst.
chemical fuel
storage furnace
engine
turbine
power plant
fuel cell
trans-port
energyresources
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
utilization
power
heat
mobility
chemical fuel
electr. therm. energy
conversion
chemical fuel
storage furnace
engine
turbine
power plant
fuel cell
crude oilnat gas
coalbiomass
dieselDMESNG
pellets
examples
trans-port
energyresources
chem. subst.
conversion
upgrading
Energy from Chemical Fuels - field of operation
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb 5
Challenges
• CO2-reduction !
• fuel resources ?• RES integration
supply / demand gap !
Answers Chemical Fuels
• process efficiency• fuel / load / product flexibility• storage• biomass
Energy from Chemical Fuels - Strategy
SET Plan
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Potential of Gasification
Quelle: IPCC Special Report on Carbon Dioxide Capture and Storage, 2005
Expanded technology initiative areas. All important but with varying time for implementation and winning business case
The initial areas
1. Wind2. PV/CSP3. Bioenergy4. Smart Grids5. Energy Storage6. Smart energy efficient
buildings and cities7. Advanced Nuclear8. Clean Coal
Further promising areas
9. Hydro10.Geothermal11.Marine12.Combined heat and power13.Advanced Fossil14.Energy efficiency in
industrial applications15.Fusion16.Fuel Cells and hydrogen
EEC, 2012-05-15 | Dr. M Callavik
by Magnus Callavik, KIC
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Innovation ProjectsEnergy from Chemical Fuels
8
Akronym Title
1 DeBugger Demonstration of efficient Biomass Use for Generation of Green Energy and Recovery of Nutrients
2 Demitar Development and market implementation of PID and FID tar analyzers
3 SNG Demonstration of improved catalysts and reactor designs for the production of SNG from biomass via gasification + SNG for smart gas grids
4 Fuel Flex Fuel flexible combustion systems for liquid and gaseous bio fuels
5 Syncon Novel synthesis process concepts for efficient chemicals / fuel production from biomass
6 Upgrad Upgrading of low-rank biogenic feedstock for heat and power production via combustion and gasification
7 xGaTe Extended Gasifier Technologies
Status 2012-04-24
Engler-Bunte Institute , Fuel TechnologyInstitute for Technical Chemistry, Gasification TechnologyDVGW Research Station , Gas Technology
9 Prof. Dr.-Ing. Thomas Kolb | INFUB - 9, Estoril, Portugal, April 2011Prof. Dr.-Ing. Thomas Kolb │ INFUB 2011, Estoril, Portugal, April 2011
„Chemical Storage“EEC 2012, KatowiceProf. Dr.-Ing. Thomas Kolb, KIT CC Germany
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
What are Chemical Fuels good for?
11
Chemical Fuels / Chemical Energy Carriers, CEC:
are produced / designed for:
• energy storage
• energy transport
• energy conversion
in systems with high energy efficiency
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Power Storage – Energy Density
12
10-1 101100 102 103 104
10-2
10-1
100
101
102
MJ/kg
MJ/
l
Hydrogen
Methane
TNT
Air (300 bar, isothern)
Blei-Säure-Akku
Lithium-Ionen-Akku
Alkali-Mangan-BatteryNiMH Akku
Zink-Air-Battery
Ethanol
CNG(200 bar)
LNGGasolineCrudeDiesel
Graphite
Hydrogen (liquid)
Hydrogen (700 bar)
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
1ltr gasoline
109 m³n NG
Power Storage - Options
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Storage of Gaseous Chemical Energy Carriers
Storage Capacity SNG from RES• demand 2050: 16TWh
• NG infra: 330 TWhchem
PHS 0.04 - 0.06 TWh
Germany
KIC InnoEnergy / Energy from Chemical Fuels / Speaker: Prof. Dr.-Ing. Thomas Kolb
Transport of Gaseous Chemical Energy Carriers
Transport Capacity120 bars / 1400 mm50*109 mn³/a
70 GWchem
1 high voltage AC power cable
<1 GW
16 Engler-Bunte-Institut, EBI-cebInstitut für Technische Chemie, Vergasungstechnologie
DVGW Forschungsstelle am EBI, GastechnologieI
Prof. Dr.-Ing. Thomas Kolb
bioliq® BtL process at KIT
17 Engler-Bunte-Institut, EBI-cebInstitut für Technische Chemie, Vergasungstechnologie
DVGW Forschungsstelle am EBI, GastechnologieI
Prof. Dr.-Ing. Thomas Kolb
bioliq® BtL process at KIT
