KRAJOWE CENTRUM INWENTARYZACJI EMISJI NATIONAL EMISSION CENTRE

UN ECE - EMEP/Poland-Report

Emission Inventory of SO2, NO2, NH3, CO, PM, NMVOCs, HMs, and POPs in Poland in 2001

Krzysztof Olendrzyński, Bogusław Dębski, Iwona Kargulewicz, Jacek Skośkiewicz,

Janina Fudała*, Stanisław Hławiczka*, Marian Cenowski*

* Institute of Ecology of Industrialized Areas, Katowice

This work has been financed by the National Fund for Environmental Protection and Water Management at the request of the Ministry of Environment

June 2003

Contents

1. Introduction 3

2. Specific comments concerning individual pollutants 4

2.1 SO2, NO2, NH3 and CO emissions 4

2.1.1 Sulphur dioxide emissions 4

2.1.2 Nitrogen oxides and carbon oxide emissions 6

2.1.3 Ammonia emissions 9

2.2 Particulate matter emissions 10

2.3 Non-methane volatile organic compound emissions 20

2.4 Heavy metal emissions 25

2.5 Persistent organic pollutant emissions 34

Appendix 52

Tables with national totals 53

NFR Tables 56

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1. Introduction

The report presents summary of atmospheric emission estimates of sulphur dioxide, nitrogen dioxide, ammonia, carbon monoxide, particulate matter (PM2.5, PM10 and total suspended particulates - TSP), non-methane volatile organic compounds (NMVOCs), heavy metals (HMs), and persistent organic pollutants (POPs) and in Poland in the year 2001. By means of this report and accompanying computer files, Poland fulfils its obligation for reporting emission data to UN ECE and EMEP. Collected data for the year 2001 are presented for each pollutant or group of pollutants as: detailed tables with activity data emission factors and emission estimates disaggregated

according to SNAP'97 classification at level 2 and 3 (wherever possible) national emissions disaggregated according to NFR (Nomenclature For Reporting) national totals (trends) in form of former standardized EMEP aggregated tables (see

appendix) summary NFR tables (appendix)

In order to increase transparency of reporting this report includes all important data on activities, emission factors and emission estimates at lowest possible level of aggregation. For each pollutant or group of pollutants (e.g. polychlorinated dibenzo-dioxins and furans - PCDD/F or polychlorinated biphenyls - PCBs), there are tables according to SNAP'97 with corresponding sector of NFR. Then there are separate tables with summation carried out according to NFR codes. In this way possible errors in assigning SNAP'97 sectors to NFR sectors or errors in summation can be easily traced down and corrected if necessary. It should be noted that in all tables in the following the comma character denotes the decimal point and not the separation character between thousands and lower numbers. The main results of the inventory are discussed in the following chapters. The differences between results for the year 2001 compared to 2000 are briefly explained separately for each pollutant or group. The major differences in emission estimates concern POPs and particularly HCB and dioxin and furans. National emission measurement for these pollutants lead to the development of new emission factors for key sources. Also some new categories were added (e.g. landfill, household and automobile fires) which appear to have significant share in the respective national totals. More details are given in the sub-sector dealing with POPs.

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2. Specific comments concerning individual pollutants

2.1 Main pollutants: SO2, CO, NO2 and NH3 emissions Estimation of main (including SO2, NO2, NH3 and CO) and other pollutant emissions is based on various activity data obtained mainly from the Central Statistical Office. They are as follows: - national fuel consumption balance, - data on air pollutants emissions from large app. 1600 enterprises particularly hazardous for environment; the data on emission concerning SNAP 01 - combustion in energy and transformation industries are adopted as reported by individual plants, - data on production of goods and products and fuel consumption for their production, - data on number of husbandry animal heads and consumption of fertilizers in agriculture, as well as

plant production, - data on industrial and municipal waste water and accumulated and generated solid wastes. - other statistical data concerning industry, agriculture or forestry The estimated values of emissions for main pollutants have been obtained from calculations based on national, CORINAIR, RADIAN and IPCC/OECD emission factors. The same emission factors were used as in several past national inventories. Estimation of SO2 emission from mobile sources was based on standard concentration value for sulphur in liquid fuels. 2.1.1 Sulphur dioxide emissions In 2001 emission of SO2 increased by 3,5% compared to the respective figure for the year 2000. The most significant change was in the residential sector (category 0202) 22,9% increase, public power sector (0101) - 33% increase, district heating plants (0102) - 19,9% increase and commercial and institutional plants (0201) - 10,2% increase. Emission grew in road transport - 11% (increased consumption of diesel oil), while in sector (08) - Other mobile sources and machinery emission decreased by 43,3% (lower diesel oil consumption). Table 1a. Sulphur dioxide emissions in Poland in 2001.

Emission source Activity [Gg]

Emission factor

Emission Gg

NFR code

Total 1564 01. Combustion in energy and transformation industries 823,5 0101 Public power 769,3 1 A 1 a 0102 District heating plants 16,4 1 A 1 a Coke 2,6 0,75% 0,0 Hard coal 1041,2 0,75% 15,6 Fuel oils 128,8 0,30% 0,8 0103 Petroleum refining plants 27,2 1 A 1 b 0104 Solid fuel transformation plants 3,1 1 A 1 c 0104 Coal mining, oil/gas extraction, pipeline compressors 7,5 1 A 1 c 02. Non-industrial combustion plants 342,8 0201 Commercial and institutional plants 95,8 1 A 4 a Hard coal 6371,1 0,75% 95,6 Fuel oils 36,2 0,30% 0,2 0202 Residential plants 203,6 1 A 4 b i Hard coal 9112 1,00% 182,2 Coke 558 1,00% 11,2 Brown coal 159 0,30% 1,0 Fuel oils 1540 0,30% 9,2 0203 Plants in agriculture, forestry and aquaculture 43,4 1 A 4 c i Hard coal 1701 1,00% 34,0

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Coke 130 1,00% 2,6 Fuel oils 1131 0,30% 6,8 03. Combustion in manufacturing industry 327,6 0301 Combustion in boilers, gas turbines and stationary engines 282,8 1 A 2 Hard coal 11290,8 1% 225,8 Brown coal 38,6 0,30% 0,2 Coke 2839,6 1% 56,8 Fuel oils 1236,8 0,30% 7,4 0303 Processes with contact 44,8 1 A 2 04. Production processes 29,8 040202 Blast furnace charging 9,3 2 C 1 0403 Processes in non-ferrous metal industry 5,2 2 C 5 0404 Processes in inorganic chemical industry 1,9 2 B 5 040407 NPK Fertilizers 11,7 2 B 5 0405 Processes in organic chemical industry 1,7 2 B 5 040605-08 Bread, wine, beer, spirits 0,1 2 D 2 07. Road transport 35,5 1 A 3 b Motor gasoline 4617,8 0,10% 9,2 Diesel oil 4380,2 0,30% 26,3

0701 Passenger cars 11,0 1 A 3 b i Motor gasoline 3835,4 0,10% 7,7 Diesel oil 551,6 0,30% 3,3

0702 Light duty vehicles < 3.5 t 5,6 1 A 3 b ii Motor gasoline 719,1 0,10% 1,4 Diesel oil 700,9 0,30% 4,2

0703 Heavy duty vehicles > 3.5 t 0,30% 17,0 1 A 3 b iii Motor gasoline 7,2 0,10% 0,0 Diesel oil 2359,5 0,30% 14,2 Buses, diesel oil 478,2 0,30% 2,9

0704-5 Mopeds and motorcycles 0,1 1 A 3 b iv Motorcycles, gasoline 34,7 0,10% 0,1 Mopeds, gasoline 21,4 0,10% 0,0 tractors, diesel oil 290 0,30% 1,7 1 A 3 b iii 08. Other mobile sources and machinery 5,1 Motor gasoline 11 0,10% 0,0 Diesel oil (excluding national sea traffic and fishing) 741,8 0,30% 4,5 0802 Railways, diesel 76,2 0,30% 0,5 1 A 3 c 0,2 1 A 3 d ii 080301-04 Inland waterways, diesel oil 10,9 0,30% 0,1 080402 National sea traffic, diesel oil 14 0,30% 0,1 080402 National sea traffic, fuel oil 5 1,00% 0,1 0,4 1 A 4 c iii 080403 fishing, diesel oil 21,8 0,30% 0,1 080403 fishing, fuel oil 52 0,30% 0,3 3,6 1 A 4 c ii 0806 Agriculture, tractors 541,5 0,30% 3,2 0806 Agriculture, machinery 58,4 0,30% 0,4 0,4 1 A 3 e ii 0808 Industry, machinery diesel oil 31,9 0,30% 0,2 0810 Other off-road, gasoline 11,2 0,10% 0,0 0810 Other off-road, diesel oil 23,1 0,30% 0,1

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Table 1b. Sulphur dioxide emissions in Poland in 2001 according to NFR.

NFR code Emission in Gg

Total 15641 A 1 a 785,71 A 1 b 27,21 A 1 c 10,61 A 2 327,61 A 3 b i 11,01 A 3 b ii 5,61 A 3 b iii 18,81 A 3 b iv 0,11 A 3 c 0,51 A 3 d ii 0,21 A 3 e ii 0,41 A 4 a 95,81 A 4 b i 203,61 A 4 c i 43,41 A 4 c ii 3,61 A 4 c iii 0,42 B 5 15,22 C 1 9,32 C 5 5,22 D 2 0,1

2.1.2 Carbon oxide and nitrogen oxides (as NO2) emissions Compared to the year 2000, in 2001 emission of CO increased by o 3,6%, while NO2 emissions grew by 8,1%. For CO the change was caused by increase in category SNAP'97 0202 by 22,8%, category 0201 by 10,2% and in category 01 by 12,3%. The reason for these increases was elevated demand for heat and electricity due to colder winter. At the same time emissions decreased for small sources in category 0203 (by 30,8%), combustion in industry 0301 and 0302 (by 85,4% - lower consumption of fuel wood), processes 0303 (by 27,7%) and in transport 08 (by 63,3% - lower consumption of diesel oil). For NO2 the emission increases were noted in the residential sector (category 0202 by 47,2%), municipal heating plants (0201 by 10,5%) and in road transport (07 by 6,5%). The decreases were - similarly to CO - in small sources (0203 by 32,1%), combustion in industry (0301 and 0302 by 17,2%), processes (03 by 33,7%), and in off-road transport (08 by 44,7%). The decreases in those sectors were caused mainly by lower consumption of fuels and scrapping old high emission vehicles. For both pollutants a new category was added compared to 2000, namely domestic sea traffic and fishing. The influence of the sector on national emission total is very small however. The detailed disaggregation of CO and NO2 emissions both in SNAP'97 and NFR are given in Tables 1c. and 1d.

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Table 1c. Carbon oxide and nitrogen dioxide emissions in Poland in 2001. Emission

factor [Mg/TJ]Emission [Mg]

NFR Emission source Activity [Gg]

CO NO2 CO NO2 code Total 3 527 900 805 383 01. Combustion in energy and transformation industries 49985,5 264528,6 0101 Public power 37131 242339 1 A 1 a 0102 District heating plants Hard coal 23261,3 0,0325 0,27 756,0 6280,6 1 A 1 a Fuel oils 5316,9 0,015 0,2 79,8 1063,4 1 A 1 a Natural gas 989,1 0,019 0,125 18,8 123,6 1 A 1 a 0103 Petroleum refining plants 1500 9234 1 A 1 b 0104 Solid fuel transformation plants 8700 2396 1 A 1 c 0104 Coal mining, oil/gas extraction, pipeline compressors 1800 3092 1 A 1 c 02. Non-industrial combustion plants 1 863 187,7 117 222,4 0201 Commercial and institutional plants Hard coal 142432,1 0,12 0,15 17091,9 21364,8 1 A 4 a Brown coal 442,5 0,12 0,15 53,1 66,4 1 A 4 a Coke 1395 0,12 0,15 167,4 209,3 1 A 4 a Fuel oils 1579,6 0,015 0,18 23,7 284,3 1 A 4 a Natural gas 8598,1 0,02 0,1 172,0 859,8 1 A 4 a Industrial gases 421,1 0,02 0,1 8,4 42,1 1 A 4 a Fuel wood 125,3 1,5 0,2 188,0 25,1 1 A 4 a 0202 Residential plants Hard coal 243146 3,095 0,155 752536,9 37687,6 1 A 4 b i Other solid fuels 16912 5 0,015 84560,0 253,7 1 A 4 b i Fuel wood 110232 6,615 0,07 729184,7 7716,2 1 A 4 b i Fuel oil 66465 0,015 0,18 997,0 11963,7 1 A 4 b i LPG 24381 0,05 0,1 1219,1 2438,1 1 A 4 b i Natural gas 184987 0,05 0,1 9249,4 18498,7 1 A 4 b i 0203 Plants in agriculture, forestry and aquaculture Hard coal 37074 3,095 0,155 114744,0 5746,5 1 A 4 c i Other solid fuels 4939 5 0,015 24695,0 74,1 1 A 4 c i Fuel wood 19000 6,615 0,07 125685,0 1330,0 1 A 4 c i Natural gas 777 0,05 0,1 38,9 77,7 1 A 4 c i LPG 2365 0,05 0,1 118,3 236,5 1 A 4 c i Fuel oils 49105 0,05 0,17 2455,3 8347,9 1 A 4 c i 03. Combustion in manufacturing industry 17971,0 118027,7 0301-02 Combustion in boilers, gas turbines and stationary engines Hard coal 200814,9 0,0058 0,2174 1164,7 43657,2 1 A 2 f Brown coal 328,6 0,0058 0,2174 1,9 71,4 1 A 2 f Coke 5359,8 0,0058 0,2174 31,1 1165,2 1 A 2 f Fuel oils 44655,1 0,0156 0,2244 696,6 10020,6 1 A 2 f Natural gas 57937,4 0,02 0,1368 1158,7 7925,8 1 A 2 f Industrial gases 18044,2 0,02 0,09 360,9 1624,0 1 A 2 f Fuel wood 2184,6 1,5 0,2 3276,9 436,9 1 A 2 f 0303 Processes with contact

030301 Sinter and pelletizing plants (agglomeration) 8959,7 0,016 0,003 143,4 26,9 1 A 2 a 030301 Sinter and pelletizing plants (blast furnace pig iron) 95159,1 0,0003 0,0 28,5 1 A 2 a

030301 Sintered zinc oxide 219,4 1,6 0,003 351,0 0,7 1 A 2 a 030302 Iron cast 2132,0 0,15 0,06 319,8 127,9 1 A 2 a 030302 Steel cast 317,3 0,15 0,06 47,6 19,0 1 A 2 a

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030304 Primary lead production 610,9 0,05 0,062 30,5 37,9 1 A 2 b 030306 Primary copper production 437,7 0,05 0,125 21,9 54,7 1 A 2 b 030308 Secondary zinc production 3435,5 0,012 0,062 41,2 213,0 1 A 2 b

030311 Cement* (clinker wet method) 13465,7 0,3 2,38 4039,7 32048,4 1 A 2 f 030311 Cement* (clinker dry method) 20891,2 0,3 0,98 6267,4 20473,4 1 A 2 f 030314 Flat glass 497,6 0,006 0,045 3,0 22,4 1 A 2 f 030315 Container glass 1249,2 0,006 0,045 7,5 56,2 1 A 2 f

030321 Paper 79,8 0,09 0,22 7,2 17,6 1 A 2 d 04. Production processes 21145,1 14835,9 040205 Open heart furnace steel plants 1172,3 0,7 0,0 820,6 2 C 040206 Basic oxygen furnace steel plants 1600,7 0,837 0,045 1339,8 72,0 2 C 040207 Electric furnace steel plants 1268,6 0,09 0,152 114,2 192,8 2 C 040208 Rolling mills (cold rolling) 19066,5 0,015 0,06 286,0 1144,0 2 C 040208 Rolling mills (hot rolling) 1327,2 0,009 0,06 11,9 79,6 2 C 040208 Rolling mills (seamless steel pipes) 737,2 0,017 0,06 12,5 44,2 2 C 040208 Rolling mills (other steel pipes) 653,1 0,017 0,06 11,1 39,2 2 C 040302 Ferrosilicon 967,8 1,65 0,4 1596,9 387,1 2 C 2 040407 NPK fertilizers 177,1 0,015 1,52 2,7 269,2 2 B 5 040407 Fertilizers 873,0 0,015 1,52 13,1 1327,0 2 B 5 040409 Carbon black 113,7 0,015 0,05 1,7 5,7 2 B 5 040410 Titanium dioxide 606,3 1,5 0,89 909,4 539,6 2 B 5 040412 Calcium carbide production 539,3 0,015 0,89 8,1 480,0 2 B 4 040501 Ethylene and propylene 49791,2 0,16 0,0 7966,6 2 B 5 040501 Caprolactam 653,5 0,16 0,0 104,6 2 B 5 040512 Styrene butadiene 3424,0 0,16 0,0 547,8 2 B 5 040602 Paper pulp (kraft process) 1322,3 0,18 0,043 238,0 56,9 2 D 1 040612 Cement (decarbonizing) 445,0 0,015 0,043 6,7 19,1 2 A 1 040614 Lime (decarbonizing) 10303,4 1,57 0,07 16176,3 721,2 2 A 2 040614 Lime (binders) 265,4 1,57 0,07 416,7 18,6 2 A 2 07. Road transport Gg Mg/Gg Mg/Gg 659886,4 244577,1 0701 Passenger cars Motor gasoline, no catalytic converter 1111,5 215 34,1 238972,5 37902,2 1 A 3 b i Motor gasoline, with catalytic converter 2710,9 56,1 9,5 152081,5 25753,6 1 A 3 b i Motor gasoline, 2-stroke engine 13 246,5 9,7 3204,5 126,1 1 A 3 b i LPG 97 120 38 11640,0 3686,0 1 A 3 b i LPG, low emission 309,1 102,8 11,4 31775,5 3523,7 1 A 3 b i Diesel oil 220,6 15 11,1 3309,0 2448,7 1 A 3 b i Diesel oil, low emission 331 14,2 8,3 4700,2 2747,3 1 A 3 b i 0702 Light duty vehicles < 3.5 t Motor gasoline, no catalytic converter 286 210 31,7 60060,0 9066,2 1 A 3 b iiMotor gasoline, with catalytic converter 433,1 43,7 7,1 18926,5 3075,0 1 A 3 b iiDiesel oil, old 241,3 18 12,6 4343,4 3040,4 1 A 3 b iiDiesel oil, new 459,6 7,4 17,2 3401,0 7905,1 1 A 3 b iiLPG, old 29,7 120 38 3564,0 1128,6 1 A 3 b iiLPG, new 64,2 99,8 11,9 6407,2 764,0 1 A 3 b ii 0703 Heavy duty vehicles > 3.5 t Motor gasoline 7,2 337 35,9 2426,4 258,5 1 A 3 b iiiDiesel oil, old 1552,5 32,5 53 50456,3 82282,5 1 A 3 b iiiDiesel oil, new 807 5 28 4035,0 22596,0 1 A 3 b iiiBuses, diesel oil, old 326,5 55,7 57,1 18186,1 18643,2 1 A 3 b iiiBuses, diesel oil, new 151,7 5 28 758,5 4247,6 1 A 3 b iiiTractors, diesel oil 290 46,3 52 13427,0 15080,0 1 A 3 b iii

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0704 Mopeds and motorcycles < 50cm3 21,4 540 3,6 11556,0 77,0 1 A 3 b iv 0705 Motorcycles > 50cm3 34,7 480 6,5 16656,0 225,6 1 A 3 b iv 08. Other mobile sources and machinery 43123,3 46191,0

080201 Shunting locs 76,2 29,5 54 2247,9 4114,8 1 A 3 c 0803 Inland waterways 10,9 29,5 54 321,6 588,6 1 A 3 d ii080402 National sea traffic 14 8 58,4 112,0 817,6 1 A 3 d ii080403 National fishing 21,8 8 58,4 174,4 1273,1 1 A 4 c iii

0805 Air traffic, jet kerosene 340 5,2 12,5 1768,0 4250,0 1 A 3 a ii 0805 Air traffic, aviation gasoline 3 1034 3,52 3102,0 10,6 1 A 3 a ii 0806 Agriculture, tractors 541,8 46 52 24922,8 28173,6 1 A 4 c ii 0806 Agriculture, machinery 58,4 50 63 2920,0 3679,2 1 A 4 c ii 0808 Industry, machinery diesel oil 31,9 40 60 1276,0 1914,0 1 A 3 e ii 0810 Other off-road, diesel oil 22,9 34 55 778,6 1259,5 1 A 4 b ii 0810 Other off-road, gasoline 11 500 10 5500,0 110,0 1 A 4 b ii09. Waste treatment and disposal 872600,5 0907 Open burning of agricultural wastes 872,6 6 C Table 1d. Carbon oxide and nitrogen dioxide emissions in Poland in 2001 according to NFR.

Emission in Gg NFR code NO2 CO

Total 805 3 5281 A 1 a 249,8 38,01 A 1 b 9,2 1,51 A 1 c 5,5 10,51 A 2 a 0,2 0,91 A 2 b 0,3 0,11 A 2 d 0,0 0,01 A 2 f 117,5 17,01 A 3 a 4,3 4,91 A 3 b i 76,2 445,71 A 3 b ii 25,0 96,71 A 3 b iii 143,1 89,31 A 3 b iv 0,3 28,21 A 3 c 4,1 2,21 A 3 d ii 1,4 0,41 A 3 e ii 1,9 1,31 A 4 a 22,9 17,71 A 4 b i 78,6 1577,71 A 4 b ii 1,4 6,31 A 4 c i 15,8 267,71 A 4 c ii 31,9 27,81 A 4 c iii 1,3 0,22 A 1 0,0 0,02 A 2 0,7 16,62 B 4 0,5 0,02 B 5 10,8 0,92 C 2,8 3,42 D 1 0,1 0,26 C 0,0 872,6

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2.1.3 Ammonia emissions A slight increase of NH3 emissions in 2001 compared to the year 2000 was caused by the increase of fertilizers use (3,9% increase) and by the increase of the number of laying hens (by 15,8%). The estimated NH3 emissions from latrines were however lower because of the lower population figure that use latrines. Table 1e. Ammonia emissions in Poland in 2001.

Emission source Activity mln of heads

Emission factor Unit Emission

[Gg] NFR

code Total 328

04. Production processes* 3,2 2 B 0404-0405 Processes in inorganic and organic chemistry 3,2 2 B 09. Waste treatment and disposal 8,0 0901007 Latrines 5 1,6 [kg/capita] 8,0 6 B 10. Agriculture 317,23 1001 Cultures with fertilizers 895 9,8 % 87,71 4 D 1 100501 Dairy cows 3,005 27,8 kg/head 83,54 4 B 1 a 100502 Other cattle 2,729 12,5 kg/head 34,11 4 B 1 b 100503 Pigs 17,105 5,1 kg/head 87,24 4 B 8 100503 Ovines 0,343 1,9 kg/head 0,65 4 B 8 100506 Horses 0,546 12,5 kg/head 6,83 4 B 6 100507 Laying hens 45,075 0,32 kg/head 14,42 4 B 9 100509 Other poultry 10,507 0,26 kg/head 2,73 4 B 9

* Data from questionnaires OS-1 for large industrial plants referring mainly to the chemical industry (fertilizers production)

Table 1f. Ammonia emissions in Poland in 2001 according to NFR. NFR code Emission in GgTotal 328,4

2 B 3,24 B 1 a 83,544 B 1 b 34,114 B 6 6,834 B 8 87,894 B 9 17,164 D 1 87,716 B 8,0

2.2 Particulate matter emissions Following the increased scope of reporting requirements, Poland as Party to the Convention on Long-range Transboundary Air Pollution, has developed the inventory of particulate matter emissions, including fine fractions PM10 and PM2.5. The emission estimates are based on various activity data obtained mainly from the Central Statistical Office, including national fuel consumption balance, data on manufacturing of products and fuel consumption for their production, data on number of husbandry animal heads, data on industrial wastes utilization. The estimated values of emissions are a result of calculations based on national activity data and emission factors derived from TNO and IIASA PM inventories. Several emission factors have been verified and adapted to Polish conditions based on Polish studies and surveys. The main source for these changes were the results of research done by the Institute for Ecology of Industrial Areas in Katowice in co-operation with the Institute for Chemical Processing of Coal in Zabrze.

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Emission estimates (Tables 2b and 2c.) have been calculated on the second (and third where possible) level of SNAP 97. The national total emission of TSP, PM10 and PM2.5 in Poland in 2001 was 491 361 Mg, 303 151 Mg and 142 071 Mg respectively. The main source of TSP emissions in Poland are the combustion processes (SNAP 01, 02, 03) with the share of more than 60% in the national totals. Compared to estimates for the year 2000, emission of TSP in 2001 grew by 5,9%. Significant increase was noted in residential sector (0202 by 26%), while the entire category 02 grew by 21%. The main reason was the increased demand for fuels was colder winter compared to the year 2000. At the same time national emission decreased in several sectors: in industry (03 and 04) by 11,4%, off-road transport (08) by 45,5%. These decreases were the result of lower fuel consumption in those sectors. Total TSP emission were lowered also due to lower number of forest fires and diminishing cigarette smoking. In 2001 inventory two subcategories were added: national sea traffic and fishing but their share in national total is rather small. Table 2a includes activity data and emission factors that were applied in the 2001 inventory, while Tables 2b and 2c show the respective emission estimates in both SNAP and NFR classifications. Table 2a. Activity data and emission factors for particulate matter emissions in Poland in 2001.

Emission factors Emission source Activity EF unit

TSP PM10 PM2.5 01. Combustion in energy and transformation industries 0101 Public power Hard coal 888723,0 Mg/TJ 0,0432 0,0216 0,0060 Brown coal 511731,1 Mg/TJ 0,0369 0,0189 0,0047 Fuel oils 7404,0 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 14263,7 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 9330,7 Mg/TJ 0,0050 0,0050 0,0050 0102 District heating plants Hard coal 23261,3 Mg/TJ 0,0432 0,0216 0,0060 coke 68,9 Mg/TJ 0,0432 0,0216 0,0060 Fuel oils 5316,9 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 989,1 Mg/TJ 0,0002 0,0002 0,0002 0103 Petroleum refining plants Hard coal 76,0 Mg/TJ 0,1400 0,0700 0,0170 Coke 3,0 Mg/TJ 0,1400 0,0700 0,0170 Fuel oils 35075,0 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 1216,0 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 39630,0 Mg/TJ 0,0050 0,0050 0,0050 0104 Solid fuel transformation plants Hard coal 3094,0 Mg/TJ 0,1400 0,0700 0,0170 Fuel oils 0,0 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 113,0 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 27556,0 Mg/TJ 0,0050 0,0050 0,0050 0105 Coal mining, oil/gas extraction, pipeline compressors Hard coal 38274,0 Mg/TJ 0,1400 0,0700 0,0170 Brown coal 305,0 Mg/TJ 0,1600 0,0800 0,0200 Coke 24,0 Mg/TJ 0,1400 0,0700 0,0170

Fuel oils 219,0 Mg/TJ 0,0400 0,0200 0,0100

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Natural gas 16584,0 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 2985,0 Mg/TJ 0,0050 0,0050 0,0050 Crude oil Mg/TJ 0,0400 0,0200 0,0100 02. Non-industrial combustion plants 0201 Commercial and institutional plants Hard coal 142432,1 Mg/TJ 0,1400 0,0700 0,0170 Brown coal 442,5 Mg/TJ 0,1600 0,0800 0,0200 Coke 1395,0 Mg/TJ 0,1400 0,0700 0,0170 Fuel wood 125,3 Mg/TJ 0,1600 0,0800 0,0200 Fuel oils 1579,6 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 8598,1 Mg/TJ 0,0002 0,0002 0,0002 LPG 168,3 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 421,1 Mg/TJ 0,0050 0,0050 0,0050 0202 Residential plants Hard coal 243146,0 Mg/TJ 0,5000 0,3750 0,1250 Brown coal 1440,0 Mg/TJ 0,5000 0,3750 0,1250 Coke 15472,0 Mg/TJ 0,1000 0,0400 0,0200 Fuel wood 110232,0 Mg/TJ 0,2000 0,1900 0,1800 Fuel oils 66465,0 Mg/TJ 0,0600 0,0500 0,0400 Natural gas 184987,0 Mg/TJ 0,0002 0,0002 0,0002 LPG 24381,0 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 38,0 Mg/TJ 0,0002 0,0002 0,0002 0203 Plants in agriculture, forestry and aquaculture Hard coal 37074,0 Mg/TJ 0,5000 0,3750 0,1250 Brown coal 1299,0 Mg/TJ 0,5000 0,3750 0,1250 Coke 3640,0 Mg/TJ 0,1000 0,0400 0,0200 Fuel wood 19000,0 Mg/TJ 0,2000 0,1900 0,1800 Fuel oils 49105,0 Mg/TJ 0,0600 0,0500 0,0400 Natural gas 777,0 Mg/TJ 0,0002 0,0002 0,0002 LPG 2365,0 Mg/TJ 0,0002 0,0002 0,0002 03. Combustion in manufacturing industry 0301 Combustion in boilers, gas turbines and stationary engines Hard coal 67589,9 Mg/TJ 0,1400 0,0700 0,0170 Brown coal 24,6 Mg/TJ 0,1600 0,0800 0,0200 Coke 149,8 Mg/TJ 0,1400 0,0700 0,0170 Fuel wood 30,6 Mg/TJ 0,1600 0,0800 0,0200 Fuel oils 15781,1 Mg/TJ 0,0400 0,0200 0,0100 Natural gas 4391,4 Mg/TJ 0,0002 0,0002 0,0002 LPG Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 14642,2 Mg/TJ 0,0050 0,0050 0,0050 0302-03 Processes with or without contact Hard coal 193874,0 Mg/TJ 0,1000 0,0600 0,0350 Brown coal 341,0 Mg/TJ 0,1000 0,0600 0,0350 Coke 76820,0 Mg/TJ 0,1000 0,0600 0,0350 Fuel wood 2173,0 Mg/TJ 0,1000 0,0600 0,0350 Fuel oils 36039,0 Mg/TJ 0,0500 0,0400 0,0350 Natural gas 108496,0 Mg/TJ 0,0002 0,0002 0,0002 Industrial gases 53511,0 Mg/TJ 0,0050 0,0050 0,0050 030204 Plaster furnaces 1034500 kg/Mg 0,1000 0,0400 0,0100

030301 Sinter and pelletizing plants 6769967 kg/Mg 0,8500 0,4000 0,3000

030302 Iron cast 424002 kg/Mg 2,0000 0,6000 0,0900

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030304 Primary lead production 28823 kg/Mg 0,6000 0,5000 0,3000 030305 Primary zinc production 160147 kg/Mg 0,5000 0,4000 0,3000 030306 Primary copper production 485869 kg/Mg 0,5000 0,4000 0,3000 030307 Secondary lead production 32261 kg/Mg 0,1000 0,0800 0,0400 030308 Secondary zinc production 8140 kg/Mg 0,1000 0,0800 0,0400 030308 Secondary copper production 498451 kg/Mg 1,0000 0,8000 0,6000

030311 Cement 12074300 kg/Mg 0,6000 0,5100 0,1800 030312 Lime 2049700 0,5000 0,2000 0,0400 030314 Flat glass 480511 kg/Mg 0,5000 0,4500 0,4000 030315 Container glass 993400 kg/Mg 0,5000 0,4500 0,4000 030316 Glass wool 60922 kg/Mg 1,0000 0,9000 0,7000

04. Production processes 0402 Processes in iron and steel industries 040201 Coke oven 8954325 kg/Mg product 0,2000 0,2000 0,1000 040203 Sulphur recovery plants 5440047 kg/Mg product 1,1000 0,8000 0,5500 040205 Open heart furnace steel plants 177615 kg/Mg product 1,0000 0,7500 0,6500 040206 Basic oxygen furnace steel plants 5822518 kg/Mg product 0,1500 0,1700 0,1500 040207 Electric furnace steel plants 2809078 kg/Mg product 0,7800 0,6900 0,3400 0403 Processes in non-ferrous metal industries 040301 Aluminium production 54606 kg/Mg product 8,0000 6,4000 2,8000 0404 Processes in inorganic chemistry 040407 NPK fertilizers 4280696 kg/Mg product 1,0000 0,8000 0,6000 040409 Carbon black 14713 kg/Mg product 0,5600 0,5000 0,4500 040414 Phosphate fertilizers 348997 kg/Mg product 0,3000 0,2400 0,1800 0405 Processes in organic chemistry 040508 PVC production 225608 kg/Mg product 0,0900 0,0300 0,0030 05. Extraction and distribution of fossil fuels and geothermal energy 0501 Extraction and 1st treatment of solid fossil fuels 050101 Extraction of brown coal 59552000 kg/Mg product 0,10 0,0500 0,0050 050102 Extraction of hard coal 103991700 kg/Mg product 0,10 0,0500 0,0050 050102 Extraction of copper ores 30227300 kg/Mg product 0,10 0,0500 0,0050 050102 Extraction of zinc-lead ores 4665761 kg/Mg product 0,10 0,0500 0,0050 050103 Storage and transport of cement 12074300 kg/Mg product 0,01 0,0050 0,0005 050103 Storage and transport of coal 103991700 kg/Mg product 0,15 0,0600 0,0060 050103 Storage and transport of coke 8954325 kg/Mg product 0,11 0,0440 0,0044 050103 Storage and transport of nitrogen fertilizers 4280696 kg/Mg product 0,10 0,0320 0,0040 050103 Storage and transport of potassic fertilizers 9346 kg/Mg product 0,10 0,0320 0,0040 050103 Storage and transport of phosphate fertilizers 348997 kg/Mg product 0,10 0,0320 0,0040 07. Road transport 0701 Passenger cars Motor gasoline, no catalytic converter 1112 Mg/Gg fuel 0,0110 0,0110 0,0110 Motor gasoline, with catalytic converter 2711 Mg/Gg fuel 0,0072 0,0072 0,0072 Motor gasoline, 2-stroke engine 13 Mg/Gg fuel 0,0110 0,0110 0,0110 Diesel oil, old 221 Mg/Gg fuel 6,0000 6,0000 6,0000 Diesel oil, new - low emission 331 Mg/Gg fuel 1,9000 1,9000 1,9000

0702 Light duty vehicles < 3.5 t Motor gasoline, with catalytic converter 286 Mg/Gg fuel 0,0110 0,0110 0,0110 Motor gasoline, no catalytic converter 433 Mg/Gg fuel 0,0071 0,0071 0,0071 Diesel oil, old 241 Mg/Gg fuel 6,0000 6,0000 6,0000 Diesel oil, new 460 Mg/Gg fuel 1,1000 1,1000 1,1000

0703 Heavy duty vehicles > 3.5 t

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Motor gasoline 7 Mg/Gg fuel 0,0110 0,0110 0,0110 Diesel oil, old 1553 Mg/Gg fuel 6,0000 6,0000 6,0000 Diesel oil, new 807 Mg/Gg fuel 1,0000 1,0000 1,0000 Buses, diesel oil, old 327 Mg/Gg fuel 6,0000 6,0000 6,0000 Buses, diesel oil, new 152 Mg/Gg fuel 1,0000 1,0000 1,0000 Tractors, diesel oil 290 Mg/Gg fuel 5,2000 5,2000 5,2000

0704 Mopeds and motorcycles < 50cm3 21 Mg/Gg fuel 0,0110 0,0110 0,0110 0705 Motorcycles > 50cm3 35 Mg/Gg fuel 0,0110 0,0110 0,0110

0707 Automobile tyre and brake wear Passenger cars

Tyre wear 79894,0 Mg/mln km 0,069000 0,003450 0,000000 Brake wear 79894,0 Mg/mln km 0,006000 0,006000 0,006000 Road wear 79894,0 Mg/mln km 0,145000 0,007250 0,000000

Light duty vehicles < 3.5 t Tyre wear 17716,0 Mg/mln km 0,090000 0,004500 0,000000 Brake wear 17716,0 Mg/mln km 0,007500 0,007500 0,007500 Road wear 17716,0 Mg/mln km 0,190000 0,009500 0,000000

Heavy duty vehicles > 3.5 t Tyre wear 13114,0 Mg/mln km 0,371250 0,018563 0,000000 Brake wear 13114,0 Mg/mln km 0,032250 0,032250 0,032250 Road wear 13114,0 Mg/mln km 0,738000 0,026900 0,000000 Mopeds and motorcycles Tyre wear 1285,0 Mg/mln km 0,034500 0,001725 0,000000 Brake wear 1285,0 Mg/mln km 0,003000 0,003000 0,003000 Road wear 1285,0 Mg/mln km 0,073000 0,003650 0,000000 08. Other mobile sources and machinery 0802 Railways

080201 Shunting locs 76,2 Mg/Gg fuel 4,7000 4,7000 4,7000 National navigation

0803 Inland waterways 10,9 Mg/Gg fuel 4,7000 4,7000 4,7000 080402 National sea traffic 14,0 Mg/Gg fuel 4,0000 4,0000 4,0000 080403 National fishing 21,8 Mg/Gg fuel 4,0000 4,0000 4,0000

0805 Air traffic, aviation fuel Jet kerosene 340,0 Mg/Gg fuel 0,0000 0,0000 0,0000 Aviation gasoline 3,0 Mg/Gg fuel 0,0300 0,0300 0,0300

0806 Agriculture Tractors 541,8 Mg/Gg fuel 5,2000 5,2000 5,2000 Machinery 58,4 Mg/Gg fuel 5,2000 5,2000 5,2000 0808 Industry Machinery, diesel oil 31,6 Mg/Gg fuel 5,2000 5,2000 5,2000 0810 Other off-road Diesel oil 22,9 Mg/Gg fuel 5,2000 5,2000 5,2000 Gasoline 11,0 Mg/Gg fuel 0,0110 0,0110 0,0110 LPG 50,0 Mg/Gg fuel 0,0000 0,0000 0,0000 09. Waste treatment and disposal 0902 Waste incineration 090201 Municipal waste incineration 14200,0 Mg/Mg 0,0001 0,0001 0,0001 090202 Industrial waste incineration 302500,0 Mg/Mg 0,1000 0,0600 0,0350 0907 Open burning of agricultural wastes 352380,4 Mg/Mg 0,0047 0,0033 0,00282 10. Agriculture 1003 On-field burning of stubble, straw 122245,2 Mg/Mg 0,0047 0,0033 0,00282

1005 Manure management regarding organic compounds

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100501 Dairy cows 3005,0 Mg/thou. 0,888000 0,400000 0,008880 100502 Other cattle 2729,0 Mg/thou. 0,888000 0,400000 0,008880 100503 Fattening pigs 15479,0 Mg/thou. 0,867000 0,390000 0,008670 100504 Sows 1626,0 Mg/thou. 0,867000 0,390000 0,008670 100506 Horses 546,0 Mg/thou. 0,867000 0,390000 0,008670 100507 Laying hens 45075,0 Mg/thou. 0,008310 0,003740 0,000831 100508 Boilers 5619,0 Mg/thou. 0,554000 0,250000 0,005540 100509 Other poultry 4888,0 Mg/thou. 0,008310 0,003740 0,000831 11. Other sources and sinks 1103 Forest fires 124987,5 Mg/Mg 0,0047 0,0033 0,00282 1126 Cigarette smoking 72200,0 Mg/Mg 0,0400 0,0400 0,0400 Table 2b. Particulate matter emissions in Poland in 2001.

Emission in Mg NFR Emission source TSP PM10 PM2.5 code

Total 491 361 303 151 142 071 01. Combustion in energy and transformation industries 66500,7 33693,7 9522,9 0101 Public power 57658,4 29095,3 7910,0 1 A 1 a Hard coal 38415,0 19207,5 5370,2 Brown coal 18897,8 9690,2 2416,3 Fuel oils 296,2 148,1 74,0 Natural gas 2,9 2,9 2,9 Industrial gases 46,7 46,7 46,7 0102 District heating plants 1221,3 610,8 194,3 1 A 1 a Hard coal 1005,5 502,7 140,6 coke 3,0 1,5 0,4 Fuel oils 212,7 106,3 53,2 Natural gas 0,2 0,2 0,2 0103 Petroleum refining plants 1612,5 905,4 550,5 1 A 1 b Hard coal 10,6 5,3 1,3 Coke 0,4 0,2 0,1 Fuel oils 1403,0 701,5 350,8 Natural gas 0,2 0,2 0,2 Industrial gases 198,2 198,2 198,2 0104 Solid fuel transformation plants 571,0 354,4 190,4 1 A 1 c Hard coal 433,2 216,6 52,6 Fuel oils 0,0 0,0 0,0 Natural gas 0,0 0,0 0,0 Industrial gases 137,8 137,8 137,8 0105 Coal mining, oil/gas extraction, pipeline compressors 5437,5 2727,9 677,6 1 A 1 c Hard coal 5358,4 2679,2 650,7 Brown coal 48,8 24,4 6,1 Coke 3,4 1,7 0,4 Fuel oils 8,8 4,4 2,2 Natural gas 3,3 3,3 3,3 Industrial gases 14,9 14,9 14,9 02. Non-industrial combustion plants 196507,5 147398,0 66155,3 0201 Commercial and institutional plants 20293,7 10148,8 2476,1 1 A 4 a

Hard coal 19940,5 9970,2 2421,3

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Brown coal 70,8 35,4 8,9 Coke 195,3 97,7 23,7 Fuel wood 20,0 10,0 2,5 Fuel oils 63,2 31,6 15,8 Natural gas 1,7 1,7 1,7 LPG 0,0 0,0 0,0 Industrial gases 2,1 2,1 2,1 0202 Residential plants 149916,4 116647,8 53424,9 1 A 4 b i Hard coal 121573,0 91179,8 30393,3 Brown coal 720,0 540,0 180,0 Coke 1547,2 618,9 309,4 Fuel wood 22046,4 20944,1 19841,8 Fuel oils 3987,9 3323,3 2658,6 Natural gas 37,0 37,0 37,0 LPG 4,9 4,9 4,9 Industrial gases 0,0 0,0 0,0 0203 Plants in agriculture, forestry and aquaculture 26297,4 20601,4 10254,3 1 A 4 c i Hard coal 18537,0 13902,8 4634,3 Brown coal 649,5 487,1 162,4 Coke 364,0 145,6 72,8 Fuel wood 3800,0 3610,0 3420,0 Fuel oils 2946,3 2455,3 1964,2 Natural gas 0,2 0,2 0,2 LPG 0,5 0,5 0,5 03. Combustion in manufacturing industry 56225,8 34223,7 17967,7 0301 Combustion in boilers, gas turbines and stationary engines 10197,7 5135,9 1384,6 1 A 2 Hard coal 9462,6 4731,3 1149,0 Brown coal 3,9 2,0 0,5 Coke 21,0 10,5 2,5 Fuel wood 4,9 2,4 0,6 Fuel oils 631,2 315,6 157,8 Natural gas 0,9 0,9 0,9 LPG 0,0 0,0 0,0 Industrial gases 73,2 73,2 73,2 0302-03 Processes with or without contact 29412,0 18123,3 11112,9 1 A 2 Hard coal 19387,4 11632,4 6785,6 Brown coal 34,1 20,5 11,9 Coke 7682,0 4609,2 2688,7 Fuel wood 217,3 130,4 76,1 Fuel oils 1802,0 1441,6 1261,4 Natural gas 21,7 21,7 21,7 Industrial gases 267,6 267,6 267,6 16616,0 10964,5 5470,2 1 A 2 030204 Plaster furnaces 103,5 41,4 10,3 1 A 2

030301 Sinter and pelletizing plants 5754,5 2708,0 2031,0 1 A 2 030302 Iron cast 848,0 254,4 38,2 1 A 2 030304 Primary lead production 17,3 14,4 8,6 1 A 2 030305 Primary zinc production 80,1 64,1 48,0 1 A 2 030306 Primary copper production 242,9 194,3 145,8 1 A 2 030307 Secondary lead production 3,2 2,6 1,3 1 A 2 030308 Secondary zinc production 0,8 0,7 0,3 1 A 2 030309 Secondary copper production 498,5 398,8 299,1 1 A 2

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030311 Cement 7244,6 6157,9 2173,4 1 A 2 030312 Lime 1024,9 409,9 82,0 1 A 2 030314 Flat glass 240,3 216,2 192,2 1 A 2 030315 Container glass 496,7 447,0 397,4 1 A 2 030316 Glass wool 60,9 54,8 42,6 1 A 2

04. Production processes 15867,8 13076,1 8622,8 0402 Processes in iron and steel industries 11017,0 9204,2 5831,4 040201 Coke oven 1790,9 1790,9 895,4 1 B 1 b 040203 Sulphur recovery plants 5984,1 4352,0 2992,0 2 C 1 040205 Open heart furnace steel plants 177,6 133,2 115,4 2 C 2 040206 Basic oxygen furnace steel plants 873,4 989,8 873,4 2 C 2 040207 Electric furnace steel plants 2191,1 1938,3 955,1 2 C 2 0403 Processes in non-ferrous metal industries 436,8 349,5 152,9 040301 Aluminium production 436,8 349,5 152,9 2 C 3 0404 Processes in inorganic chemistry 4393,6 3515,7 2637,9 040407 NPK fertilizers 4280,7 3424,6 2568,4 2 B 5 040409 Carbon black 8,2 7,4 6,6 2 B 5 040414 Phosphate fertilizers 104,7 83,8 62,8 2 B 5 0405 Processes in organic chemistry 040508 PVC production 20,3 6,8 0,7 2 B 5 05. Extraction and distribution of fossil fuels and geothermal energy 37353,4 16764,2 1680,1 0501 Extraction and 1st treatment of solid fossil fuels 1 B 1 a 050101 Extraction of brown coal 6057,6 2977,6 297,8 050102 Extraction of hard coal 10578,0 5199,6 520,0 050102 Extraction of copper ores 3074,7 1511,4 151,1 050102 Extraction of zinc-lead ores 474,6 233,3 23,3 050103 Storage and transport of cement 120,7 60,4 6,0 050103 Storage and transport of coal 15598,8 6239,5 624,0 050103 Storage and transport of coke 985,0 394,0 39,4 050103 Storage and transport of nitrogen fertilizers 428,1 137,0 17,1 050103 Storage and transport of potassic fertilizers 0,9 0,3 0,0 050103 Storage and transport of phosphate fertilizers 34,9 11,2 1,4 07. Road transport 55467,0 20430,4 18724,4 0701 Passenger cars 1984,4 1984,4 1984,4 1 A 3 b i Motor gasoline, no catalytic converter 12,2 12,2 12,2 Motor gasoline, with catalytic converter 19,5 19,5 19,5 Motor gasoline, 2-stroke engine 0,1 0,1 0,1 Diesel oil, old 1323,6 1323,6 1323,6 Diesel oil, new - low emission 628,9 628,9 628,9

0702 Light duty vehicles < 3.5 t 1959,6 1959,6 1959,6 1 A 3 b ii Motor gasoline, with catalytic converter 3,1 3,1 3,1 Motor gasoline, no catalytic converter 3,1 3,1 3,1 Diesel oil, old 1447,8 1447,8 1447,8 Diesel oil, new 505,6 505,6 505,6

0703 Heavy duty vehicles > 3.5 t 13741,4 13741,4 13741,4 1 A 3 b iii Motor gasoline 0,1 0,1 0,1 Diesel oil, old 9315,0 9315,0 9315,0 Diesel oil, new 807,0 807,0 807,0 Buses, diesel oil, old 1959,0 1959,0 1959,0

Buses, diesel oil, new 151,7 151,7 151,7 Tractors, diesel oil 1508,0 1508,0 1508,0

0704 Mopeds and motorcycles < 50cm3 0,2 0,2 0,2 1 A 3 b iv

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0705 Motorcycles > 50cm3 0,4 0,4 0,4 1 A 3 b iv 0707 Automobile tyre and brake wear 37781,7 2745,0 1039,0 1 A 3 b iv

Passenger cars Tyre wear 5512,7 275,6 0,0 Brake wear 479,4 479,4 479,4 Road wear 11584,6 579,2 0,0

Light duty vehicles < 3.5 t Tyre wear 1594,4 79,7 0,0 Brake wear 132,9 132,9 132,9 Road wear 3366,0 168,3 0,0

Heavy duty vehicles > 3.5 t Tyre wear 4868,6 243,4 0,0 Brake wear 422,9 422,9 422,9 Road wear 9678,1 352,8 0,0

Mopeds and motorcycles Tyre wear 44,3 2,2 0,0 Brake wear 3,9 3,9 3,9 Road wear 93,8 4,7 0,0 08. Other mobile sources and machinery 3957,2 3957,2 3957,2 0802 Railways 358,1 358,1 358,1

080201 Shunting locs 358,1 358,1 358,1 1 A 3 c National navigation 194,4 194,4 194,4

0803 Inland waterways 51,2 51,2 51,2 1 A 3 d ii 080402 National sea traffic 56,0 56,0 56,0 1 A 3 d ii 080403 National fishing 87,2 87,2 87,2 1 A 4 c iii

0805 Air traffic, aviation fuel 0,1 0,1 0,1 1 A 3 a ii Jet kerosene 0,0 0,0 0,0 Aviation gasoline 0,1 0,1 0,1

0806 Agriculture 3121,0 3121,0 3121,0 1 A 4 c ii Tractors 2817,4 2817,4 2817,4 Machinery 303,7 303,7 303,7 0808 Industry 164,3 164,3 164,3 1 A 3 e ii Machinery, diesel oil 164,3 164,3 164,3 0810 Other off-road 119,2 119,2 119,2 1 A 3 e ii Diesel oil 119,1 119,1 119,1 Gasoline 0,1 0,1 0,1 LPG 0,0 0,0 0,0 09. Waste treatment and disposal 31907,6 19314,3 11582,6 0902 Waste incineration 30251,4 18151,4 10588,9 6 C 090201 Municipal waste incineration 1,4 1,4 1,4 090202 Industrial waste incineration 30250,0 18150,0 10587,5 0907 Open burning of agricultural wastes 1656,2 1162,9 993,7 6 C 10. Agriculture 24099,0 10992,5 617,9 1003 On-field burning of stubble, straw 574,6 403,4 344,7 4 F 1005 Manure management regarding organic compounds 23524,4 10589,1 273,2 100501 Dairy cows 2668,4 12020,0 26,7 4 B 1 a 100502 Other cattle 2423,4 1091,6 24,2 4 B 1 b 100503 Fattening pigs 13420,3 6036,8 134,2 4 B 8 100504 Sows 1409,7 634,1 14,1 4 B 8

100506 Horses 473,4 212,9 4,7 4 B 3 100507 Laying hens 374,6 168,6 37,5 4 B 9 100508 Boilers 46,7 21,0 4,7 4 B 9

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100509 Other poultry 2708,0 1222,0 27,1 4 B 9 11. Other sources and sinks 3475,4 3300,5 3240,5 1103 Forest fires 587,4 412,5 352,5 6 D 1126 Cigarette smoking 2888,0 2888,0 2888,0 6 D

Table 2c. Particulate matter emissions in Poland in 2001 according to NFR. Emission in Mg NFR

code TSP PM10 PM2.5

TOTAL 491 361 303 150 142 071

1 A 1 a 58879,7 29706,0 8104,41 A 1 b 1612,5 905,4 550,51 A 1 c 6008,5 3082,3 868,01 A 2 56225,8 34223,7 17967,7

1 A 3 a ii 0,1 0,1 0,11 A 3 b i 1984,4 1984,4 1984,41 A 3 b ii 1959,6 1959,6 1959,61 A 3 b iii 13740,8 13740,8 13740,81 A 3 b iv 0,6 0,6 0,61 A 3 b vi 37781,7 2745,0 1039,01 A 3 c 358,1 358,1 358,1

1 A 3 d ii 107,2 107,2 107,21 A 3 e ii 283,5 283,5 283,51 A 4 a 20293,7 10148,8 2476,11 A 4 b i 149916,4 116647,8 53424,91 A 4 c i 26297,4 20601,4 10254,31 A 4 c ii 3121,0 3121,0 3121,01 A 4 c iii 87,2 87,2 87,21 B 1 a 37353,4 16764,2 1680,11 B 1 b 1790,9 1790,9 895,42 B 5 4413,9 3522,4 2638,52 C 9663,0 7762,8 5088,8

4 B 1 a 2668,4 1202,0 26,74 B 1 b 2423,4 1091,6 24,24 B 3 473,4 212,9 4,74 B 8 14830,0 6671,0 148,34 B 9 3129,2 1411,6 69,24 F 574,6 403,4 344,76 C 31907,6 19314,3 11582,66 D 3475,4 3300,5 3240,5

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2.3 NMVOCs emissions Statistical data on production of the stocks, consumption of fuels and raw materials worked out by the Central Statistic Office were used for national NMVOCs emission assessment. Use of advanced methods for statistical analyses allows acquiring more precise input data for national emission inventory for subsequent years. Additionally, the emission factors were used for calculating the NMVOCs emission estimate from the sources covered by SNAP’97. Emission factors for fossil fuels combustion in energy sector and industrial processes (SNAP 01-04) were applied to calculate the NMVOCs emission in the year 2000. No changes in emission factors were done in emission calculations for 2001. For some emission sources, default emission factors published in EMEP/CORINAIR Atmospheric Emission Inventory Guidebook, Second Edition, September 1999 were applied. Higher emission factors have been used for NMVOCs emission calculation from solvent use in households (SNAP 060408 – 1.2 Mg/thou. of inhabitants instead of 1.0) and a lower emission factor was applied to oil extraction (SNAP 060404 – 14,0 Mg/Gg instead of 18,0) and forest fires (SNAP 1103 – 0,5 Mg/ha instead of 1,6 ). These changes were made based on the results of verification of emission factors done by Institute for Ecology of Industrial Areas in 2001 and presented in the technical report Fudala J., Cenowski M., 2001 "The analysis of NMVOCs emission factors used in Poland due to other European countries and the assessment of the effects of fulfillment the requirements with regard to NMVOCs emission resulting from protocols to the LRTAP Convention”. According to calculations, the national total emission of NMVOCs in Poland in 2001 was 873 385 Mg. The assessed amount is lower by 31 thousand Mg compared to the respective figure for the year 2000. Such decrease of the emission resulted from the reduction of emissions from SNAP'97 03-05, and 07-11 source categories. Category 06 (18.8 %) has the highest share in the emission of NMVOCs within the group of stationary sources (categories 01-06 + 09 + 10). 164 667 Mg of NMVOCs were emitted from processes included in this category in 2001. The share of this category in the national emission increased slightly in comparison to previous year, mainly because of higher consumption of paints and significant increase of use of water soluble paint as well as the change of emission factor for solvent use in households. The second category in national emissions includes combustion processes in municipal and housing sectors (category 02 - 13.0 %). These processes emitted 113 841Mg of NMVOCs to the air i.e. 16 000 Mg more than in 2000. The increase in hard coal consumption in municipal sector was the main reason of emission increase in this sector. The share of specific categories in the national emission has been presented in the table below. The total emission of non-methane volatile organic compounds from the stationary sources in 2001 was 429 219 Mg. Means of transport and machines with combustion engines classified as categories 07 and 08 in SNAP’97 emitted 147 309 Mg of NMVOCs, i.e., 16,9 % of the total national emission. Decrease of emission from the transport sector compared to 2000, is caused by taking an updated and more accurate numbers for various road vehicles with a bigger share of low-emitting vehicles, lower number of cars without catalytic converters and those using LPG. Finally, the natural sources, classified category as 11, which are also a type of sources referred to as nature, emitted 296 856 Mg of NMVOCs, which is 34 % of the national emission of NMVOCs. This load is only slightly lower than in 2000, which is a result of reduction of

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emissions from forests fires and emissions from other categories. The total emission from anthropogenic sources was 576 528 Mg of NMVOCs, i.e., 66,0 % of the total national emission. Approximately 17 thousand Mg of NMVOCs have been emitted from high emitters > 100m and 856 thousand of Mg from other emitters < 100m. The emission of NMVOCs from high sources constitutes only about 2% of the total national emission. Table 3a. NMVOCs emissions in Poland in 2001.

Activity Emission UNIT Emission NFR Emission source factor [Mg] code

Total 873 385,4

01. Combustion in energy and transformation industries 12 555,1 0101 Public power 11263,4 Hard coal 888723,0 0,0080 Mg/TJ 7109,8 1 A 1 a Brown coal 511731,1 0,0080 Mg/TJ 4093,8 1 A 1 a Residual oil 7404,0 0,0030 Mg/TJ 22,2 1 A 1 a Natural gas 14263,7 0,0010 Mg/TJ 14,3 1 A 1 a Industrial gases 9330,7 0,0025 Mg/TJ 23,3 1 A 1 a 0102 District heating plants 157,2 Hard coal 23261,3 0,0060 Mg/TJ 139,6 1 A 1 a Coke 68,9 0,0100 Mg/TJ 0,7 1 A 1 a Residual oil 5316,9 0,0030 Mg/TJ 16,0 1 A 1 a Natural gas 989,1 0,0010 Mg/TJ 1,0 1 A 1 a 0103 Petroleum refining plants 207,1

Hard coal 76,0 0,0200 Mg/TJ 1,5 1 A 1 b Coke 3,0 0,0100 Mg/TJ 0,0 1 A 1 b Residual oil 35075,0 0,0030 Mg/TJ 105,2 1 A 1 b Natural gas 1216,0 0,0010 Mg/TJ 1,2 1 A 1 b Industrial gases 39630,0 0,0025 Mg/TJ 99,1 1 A 1 b 0104 Solid fuel transformation plants 130,9 Hard coal 3094,0 0,0200 Mg/TJ 61,9 1 A 1 c Residual oil 0,0 0,0030 Mg/TJ 0,0 1 A 1 c Natural gas 113,0 0,0010 Mg/TJ 0,1 1 A 1 c Industrial gases 27556,0 0,0025 Mg/TJ 68,9 1 A 1 c 0105 Coal mining, oil/gas extraction 796,5 Hard coal 38274,0 0,0200 Mg/TJ 765,5 1 A 1 c Brown coal 305,0 0,0200 Mg/TJ 6,1 1 A 1 c Coke 24,0 0,0100 Mg/TJ 0,2 1 A 1 c Residual oil 219,0 0,0030 Mg/TJ 0,7 1 A 1 c Natural gas 16584,0 0,0010 Mg/TJ 16,6 1 A 1 c Industrial gases 2985,0 0,0025 Mg/TJ 7,5 1 A 1 c Crude oil 0,0 0,0030 0,0 1 A 1 c 02. Non-industrial combustion plants 113 841,2 0201 Commercial and institutional plants 2898,4 Hard coal 142432,1 0,0200 Mg/TJ 2848,6 1 A 4 a Brown coal 442,5 0,0200 Mg/TJ 8,9 1 A 4 a Coke 1395,0 0,0100 Mg/TJ 14,0 1 A 4 a Wood 125,3 0,1000 Mg/TJ 12,5 1 A 4 a Residual oil 1579,6 0,0030 Mg/TJ 4,7 1 A 4 a Natural gas 8598,1 0,0010 Mg/TJ 8,6 1 A 4 a LPG 0,0 0,0035 Mg/TJ 0,0 1 A 4 a Industrial gases 421,1 0,0025 Mg/TJ 1,1 1 A 4 a

22

0202 Residential plants 94526,7 Hard coal 243146,0 0,2000 Mg/TJ 48629,2 1 A 4 b i Brown coal 1440,0 0,2000 Mg/TJ 288,0 1 A 4 b i Coke 15472,0 0,0200 Mg/TJ 309,4 1 A 4 b i Wood 110232,0 0,4000 Mg/TJ 44092,8 1 A 4 b i Residual oil 66465,0 0,0030 Mg/TJ 199,4 1 A 4 b i Natural gas 184487,0 0,0050 Mg/TJ 922,4 1 A 4 b i LPG 24381,0 0,0035 Mg/TJ 85,3 1 A 4 b i Industrial gases 38,0 0,0025 Mg/TJ 0,1 1 A 4 b i 0203 Plants in agriculture, forestry and aquaculture 16416,2 Hard coal 37074,0 0,2000 Mg/TJ 7414,8 1 A 4 c i Brown coal 1299,0 0,2000 Mg/TJ 259,8 1 A 4 c i Coke 49105,0 0,0200 Mg/TJ 982,1 1 A 4 c i Wood 19000,0 0,4000 Mg/TJ 7600,0 1 A 4 c i Residual oil 49105,0 0,0030 Mg/TJ 147,3 1 A 4 c i Natural gas 777,0 0,0050 Mg/TJ 3,9 1 A 4 c i LPG 2365,0 0,0035 Mg/TJ 8,3 1 A 4 c i 03. Combustion in manufacturing industry 6 716,0 0301 Combustion in boilers, gas turbines and stationary engines 1495,8 Hard coal 67589,9 0,0200 Mg/TJ 1351,8 1 A 2 Brown coal 24,6 0,0200 Mg/TJ 0,5 1 A 2 Coke 5210,0 0,0100 Mg/TJ 52,1 1 A 2 Wood 30,6 0,1000 Mg/TJ 3,1 1 A 2 Residual oil 15781,1 0,0030 Mg/TJ 47,3 1 A 2 Natural gas 4391,4 0,0010 Mg/TJ 4,4 1 A 2 LPG 0,0 0,0035 Mg/TJ 0,0 1 A 2 Industrial gases 14642,2 0,0025 Mg/TJ 36,6 1 A 2 0302-03 Processes with or without contact 5220,2 Hard coal 193874,0 0,0200 Mg/TJ 3877,5 1 A 2 Brown coal 341,0 0,0200 Mg/TJ 6,8 1 A 2 Coke 76820,0 0,0100 Mg/TJ 768,2 1 A 2 Wood 2173,0 0,1000 Mg/TJ 217,3 1 A 2 Residual oil 36039,0 0,0030 Mg/TJ 108,1 1 A 2 Natural gas 108496,0 0,0010 Mg/TJ 108,5 1 A 2 LPG 0,0 0,0035 Mg/TJ 0,0 1 A 2 Industrial gases 53511,0 0,0025 Mg/TJ 133,8 1 A 2 04. Production processes 57 377,3

0401 Processes in petroleum industries 16301,7 1 B 2 a iv

040101 Petroleum products processing 18113,0 0,9000 Mg/Gg 16301,7 0402 Processes in iron and steel industries and collieries 8461,2 040201 Coke oven 8954325,0 0,0005 Mg/Mg 4477,2 1 B 1 b 040202 Blast furnace charging 5440047,0 0,000237 Mg/Mg 1289,3 2 C 040205 Open hearth furnace steel plant 177615,0 0,000015 Mg/Mg 2,7 2 C 040206 Basic oxygen furnace steel plant 5822518,0 0,000038 Mg/Mg 221,3 2 C 040207 Electric furnace steel plant 2809078,0 0,000740 Mg/Mg 2078,7 2 C 040208 Rolling mills - hot 692840,0 0,000126 Mg/Mg 87,3 2 C 040208 Rolling mills - cold 10161226,0 0,000030 Mg/Mg 304,8 2 C

0404 Processes in inorganic chemical industries 6317,2 040403 Ammonia 1169124,0 0,0049 Mg/Mg 5728,7 2 B 1 040409 Carbon black 14713,0 0,0400 Mg/Mg 588,5 2 B 5 0405 Processes in organic chemical industries (bulk production) 11578,3

23

040501 Ethylene 308272,0 0,0110 Mg/Mg 3391,0 2 B 5 040502 Propylene 227902,0 0,0050 Mg/Mg 1139,5 2 B 5

040506 Polyethylene low density 159347,0 0,0260 Mg/Mg 4143,0 2 B 5 040508 Polyvinylchloride 225608,0 0,0080 Mg/Mg 1804,9 2 B 5 040509 Polypropylene 122915,0 0,0080 Mg/Mg 983,3 2 B 5 040511 Polystyrene 92540,0 0,001260 Mg/Mg 116,6 2 B 5

0406 Proc.in wood, paper pulp, food, drink and other industries 14718,9 040601 Chipboard 2937000,0 0,0002 Mg/m3 587,4 2 D 1 040602 Paper pulp 753100,0 0,0010 Mg/Mg 753,1 2 D 1 040605 Bread 1653,3 4,5000 Mg/Gg 7439,9 2 D 2

040606 Wine 3315476,0 0,000034 Mg/hl 112,7 2 D 2 040607 Beer 25162900,0 0,00002 Mg/hl 503,3 2 D 2 040608 Spirits 679289,0 0,0024 Mg/hl100% 1630,3 2 D 2

040610 Roof covering with asphalt materials 73845,0 0,0500 Mg/1000m2 3692,3 2 A 5 05. Extraction and distribution of fossil fuels and geothermal energy 37 503,9 0501 Extraction and 1st treatment of solid fossil fuels 10399,2 050102 Underground mining 103991,7 0,1 Mg/Gg 10399,2 1 B 1 a

0502 Extraction and 1st treatment and loading of liquid fossil fuels 76,7

050201 Land-based activities 767000,0 0,0001 Mg/Mg 76,7 1 B 2 a i 0503 Extraction, 1st treatment and loading of gaseous 336,7

Land-based activities (high-methane natural gas) 2088,0 0,068 Mg/hm3 142,0 1 B 2 b Land-based activities (nitrified natural gas) 3090,0 0,063 Mg/hm3 194,7 1 B 2 b

0504 Liquid fuel distribution (except gasoline distribution) 2514,9 050401 Marine terminals (tankers, handling and storage) 8039,0 0,3 Mg/Gg 2411,7 1 B 2 a i 050402 Other handling and storage (including pipeline) 5158,0 0,020000 Mg/Gg 103,2 1 B 2 a i 0505 Gasoline distribution 17625,2 050501 Refinery dispatch station 4294,0 0,31 Mg/Gg 1331,1 1 B 2 a v 050502 Transport and depots 4629,0 0,72 Mg/Gg 3332,9 1 B 2 a v

050503 Service stations (including refueling of cars) 4629,0 2,8 Mg/Gg 12961,2 1 B 2 a v 0506 Gas distribution networks 6551,3

Natural gas (high-methane) 9195,0 0,338 Mg/hm3 3107,9 1 B 2 b Natural gas (nitrified) 1651,0 0,784 Mg/hm3 1294,4 1 B 2 b Coke oven gas 2956,0 0,727 Mg/hm3 2149,0 1 B 2 b 06. Solvent and other product use 164 667,0 0601 Paint application 79580,9

060101 Waterborne paints 233680,0 0,03 Mg/Mg 7010,4 3 A

060102 Conventional solvent paint 145141,0 0,5 Mg/Mg 72570,5 3 A

0602 Degreasing, dry cleaning and electronics 17504,8

060201 Metal degreasing 11710,0 1,0 Mg/Mg 11710,0 3 B

060202 Dry cleaning 38632,0 0,15 Mg/Gg 5794,8 3 B

0603 Chemical products manufacturing or processing 14759,1

060302 Polivinylchloride processing 225608,0 0,0078 Mg/Mg 1759,7 3 C

060304 Polystyrene foam processing 92540,0 0,0508 Mg/Mg 4701,0 3 C

060305 Rubber processing 383251,0 0,016 Mg/Mg 6132,0 3 C

060306 Pharmaceutical products manufacturing 38632,0 0,014 Mg/Gg 540,8 3 C

060307 Paints manufacturing 325,1 5,0 Mg/Gg 1625,5 3 C

0604 Other use of solvents and related activities 52822,2

24

060404 Fat, edible and non edible oil extraction 461,7 14,0 Mg/Gg 6463,8 3 D

060408 Domestic solvent use (other then paint application) 38632,0 1,20 Mg/Gg 46358,4 3 D 07. Road transport 135 567,8 0701 Passenger cars 72484,3

Diesel passenger cars - old 220,6 3,50 Mg/Gg 772,1 1 A 3 b i

Diesel passenger cars - new 331,0 3,30 Mg/Gg 1092,3 1 A 3 b i

Two-stroke passenger cars 13,0 191,80 Mg/Gg 2493,4 1 A 3 b i Gasoline passenger cars without catal. 1111,5 44,00 Mg/Gg 48906,0 1 A 3 b i Gasoline passenger cars with catal. 2710,9 5,50 Mg/Gg 14910,0 1 A 3 b i LPG passenger cars 97,0 25,00 Mg/Gg 2425,0 1 A 3 b i LPG passenger cars - low emission 309,1 6,10 Mg/Gg 1885,5 1 A 3 b i 0702 Light duty vehicles <3.5 t 18120,5 Diesel light - duty cars - old 241,3 6,90 Mg/Gg 1665,0 1 A 3 b ii Diesel light - duty cars - new 459,6 1,10 Mg/Gg 505,6 1 A 3 b ii Gasoline light - duty cars without catal. 286,0 38,50 Mg/Gg 11011,0 1 A 3 b ii Gasoline light - duty cars with catal. 433,1 8,80 Mg/Gg 3811,3 1 A 3 b ii LPG light - duty cars 29,7 25,00 Mg/Gg 742,5 1 A 3 b ii LPG light - duty cars - low emission 64,2 6,00 Mg/Gg 385,2 1 A 3 b ii 0703 Heavy duty vehicles >3.5 t 29145,1 Diesel heavy - duty cars - old 1552,5 12,50 Mg/Gg 19406,3 1 A 3 b iii Diesel heavy - duty cars - new 807,0 2,00 Mg/Gg 1614,0 1 A 3 b iii Gasoline heavy duty vehicles 7,2 47,60 Mg/Gg 342,7 1 A 3 b iii Buses - old 326,5 15,80 Mg/Gg 5158,7 1 A 3 b iii Buses - new 151,7 2,00 Mg/Gg 303,4 1 A 3 b iii Tractors 290,0 8,00 Mg/Gg 2320,0 1 A 3 b iii 0704 Mopeds and motorcycles < 50 cm3 21,4 350,00 Mg/Gg 7490,0 1 A 3 b iv 0705 Motorcycles > 50 cm3 34,7 240,00 Mg/Gg 8328,0 1 A 3 b iv 08. Other mobile sources and machinery 11 741,6 0802 Railways 967,7 080201 Shunting locomotives, diesel oil 76,2 12,70 Mg/Gg 967,7 1 A 3 c 0803 Inland waterways 10,9 12,70 Mg/Gg 138,4 1 A 3 d ii 0805 Air traffic 337,2 Jet fuel 340,0 0,78 Mg/Gg 265,2 1 A 3 ii (ii) Aviation gasoline 3,0 24,00 Mg/Gg 72,0 1 A 3 ii (ii) 0806 Agriculture 5081,9 Tractors 541,8 8,00 Mg/Gg 4334,4 1 A 4 c ii Machinery 58,4 12,80 Mg/Gg 747,5 1 A 4 c ii 0808 Industry 382,4 Industry - oil engine powered machinery 31,6 12,10 Mg/Gg 382,4 1 A 2 0809 Household and gardening 4834,0 Other machinery (gasoline engines) 22,9 12,40 Mg/Gg 284,0 1 A 4 b ii Other machinery (oil engines) 11,0 300,00 Mg/Gg 3300,0 1 A 4 b ii Other machinery (LPG) 50,0 25,00 Mg/Gg 1250,0 1 A 4 b ii 09. Waste treatment and disposal 2 569,6 0902 Waste incineration 1864,8

090201 Municipal waste incineration 14200,0 0,00740 Mg/Mg 105,1 6 C 090202 Industrial waste incineration 186900,0 0,00740 Mg/Mg 1383,1 6 C 090205 Hospital waste incineration 50900,0 0,00740 376,7 6 C 0907 Open burning of agricultural wastes 352380,0 0,0020 Mg/Mg 704,8 6 C 10. Agriculture 33 989,3 1001 Cultures with fertilizers 33650,3

25

Permanent crops 14095,2 1,15 Mg/1000ha 16209,5 4 D 1 Meadows and pasture 4056,0 4,3 Mg/1000ha 17440,8 4 D 1 1003 Stubble burning 33,9 10,0 Mg/1000ha 339,0 4 F 11. Other sources and sinks 296 856,5 1101 Broadleaf forests 2019,0 10 Mg/1000ha 20190,0 7 1102 Coniferous forests 6875,0 40 Mg/1000ha 275000,0 7 1103 Forest and other vegetation fires 3333,0 0,5 Mg/ha 1666,5 7 Table 3b. NMVOCs emissions in Poland in 2001 according to NFR.

NFR code Emission in GgTOTAL 8731 A 1 a 11,4211 A 1 b 0,2071 A 1 c 0,9271 A 2 7,0981 A 3 a ii(ii) 0,3371 A 3 b i 72,4841 A 3 b ii 18,1211 A 3 b iii 29,1451 A 3 b iv 15,8181 A 3 c 0,9681 A 3 d ii 0,1381 A 4 a 2,8981 A 4 b i 94,5271 A 4 b ii 4,8341 A 4 c i 16,4161 A 4 c ii 5,0821 B 1 a 10,3991 B 1 b 4,4771 B 2 a i 2,5921 B 2 a iv 16,3021 B 2 a v 17,6251 B 2 b 6,8882 A 5 3,6922 B 1 5,7292 B 5 12,1672 C 3,9842 D 1 1,342 D 2 9,6863 A 79,5813 D 17,5053 C 14,7593 D 52,8224 D 1 33,654 F 0,3396 C 2,577 296,857

26

2.4. Heavy metal emissions The presented heavy metal (HM) emission assessments for 2001 were made on the basis of the Polish Central Statistical Office (GUS) data on goods and materials production as well as on raw materials consumption in Poland. For the HM emission assessments the emission factors used in the report were based on: - data presented in the EMEP/CORINAIR "Atmospheric Emission Inventory Guidebook" and - the emission factors characteristic for processes in Poland. No natural HM emission sources were considered in the emission inventory. Several emission factors have been verified and adapted to Polish conditions based on Polish studies and surveys. The main source for these changes were the results of research done by the Institute for Ecology of Industrial Areas in Katowice in co-operation with institutes representing iron and steel metallurgy sector, non-ferrous metals production sector as well as with laboratories in refineries and chemical enterprises. Emission estimates (Tables 4a, 4b, 4c and 4d.) have been calculated on the second (and third where possible) level of SNAP 97. The assessed national emission totals in 2001 for: arsenic (As), cadmium (Cd), copper (Cu), nickel (Ni) are higher than the values calculated for the previous year, while totals for chromium (Cr), mercury (Hg), lead (Pb) and zinc (Zn) are lower. The main reason of that is higher consumption of solid fuels in Poland due to colder weather and increased demand for heat and electricity. Emissions of lead were lower due to inter alia complete elimination of leaded gasoline in 2001. Among the seven SNAP source categories considered in the inventory, combustion processes for energy production purposes have the biggest share in the emission of HM in Poland within the 1, 2, 3, 4, 7, 8 and 9 SNAP groups. The share of this processes in the national emission is similar in comparison to the previous year. The second category group which the share in the national emissions of HM is the highest are technological processes (SNAP 4). From the activities within the SNAP 4 group, processes in iron and steel industry as well as processes in non-ferrous metal industries dominate as the source of the heavy metals, except mercury. In case of mercury cement production is the main industrial source of the metal emission to the air in Poland. Table 4a. Emission factors for: Cd, Hg and Pb in Poland in 2001.

Emission factors Emission source Activity

unit Activity EF unit

Cd Hg Pb 01. Combustion in energy and transformation industries 0101 Public power Hard coal TJ 888723 kg/TJ 0,00018 0,008 0,014 Brown coal TJ 511731,1 kg/TJ 0,00021 0,005 0,006 Fuel oil TJ 7404 kg/TJ 0,0024 0,003 0102 District heating plants Hard coal TJ 23261,3 kg/TJ 0,0256 0,008 0,16 Brown coal TJ 0 kg/TJ 0,00021 0,005 0,006 Coke TJ 68,9 kg/TJ Fuel oil TJ 5316,9 kg/TJ 0,024 0,03

27

0103 Petroleum refining plants TJ Hard coal 76 kg/TJ 0,027 0,008 0,17 Brown coal TJ kg/TJ 0,0007 0,005 0,022

Coke TJ 3 kg/TJ 0,023 0,0006 0,13 Fuel oil TJ 35075 kg/TJ 0,024 0,03 0104 Solid fuel transformation plants Hard coal TJ 30940 kg/TJ 0,027 0,008 0,17 Brown coal TJ kg/TJ 0,0007 0,005 0,022 Coke TJ kg/TJ 0,023 0,0006 0,13 Fuel oil TJ kg/TJ 0,024 0,03 0105 Coal mining, oil/gas extraction Hard coal TJ 38274 kg/TJ 0,027 0,008 0,17 Brown coal TJ 305 kg/TJ 0,0007 0,005 0,022 Coke TJ 24 kg/TJ 0,023 0,0006 0,13 Fuel oil TJ 219 kg/TJ 0,024 0,03

02. Non-industrial combustion plants 0201 Commercial and institutional plants Hard coal TJ 142432,1 kg/TJ 0,052 0,008 0,33 Brown coal TJ 442,5 kg/TJ 0,0007 0,005 0,022 Coke TJ 1395 kg/TJ 0,023 0,0006 0,13 Fuel oil TJ 1579,6 kg/TJ 0202 Residential plants Hard coal TJ 243146 kg/TJ 0,073 0,004 0,46 Brown coal TJ 1440 kg/TJ 0,71 0,005 0,217 Coke TJ 15472 kg/TJ 0,066 0,0006 0,359 Fuel oil TJ 66465 kg/TJ 0,024 0,03 0203 Plants in agriculture, forestry and aquaculture Hard coal TJ 37074 kg/TJ 0,073 0,004 0,46 Brown coal TJ 1299 kg/TJ 0,71 0,005 0,217 Coke TJ 3640 kg/TJ 0,066 0,0006 0,359 Fuel oil TJ 49105 kg/TJ 0,024 0,03 03. Combustion in manufacturing industry 0301 Combustion in boilers, gas turbines and stationary engines TJ Hard coal TJ 67589,9 kg/TJ 0,027 0,008 0,17 Brown coal TJ 24,6 kg/TJ 0,0007 0,005 0,022 Coke TJ 149,8 kg/TJ 0,023 0,0006 0,13 Fuel oil TJ 15781,1 kg/TJ 0,024 0,03 0302 Process furnaces without contact Hard coal TJ 193874 kg/TJ 0,027 0,008 0,17 Brown coal TJ 341 kg/TJ 0,0007 0,005 0,022 Coke TJ 76820 kg/TJ 0,023 0,0006 0,13 Fuel oil TJ 36039 kg/TJ 0,024 0,03 0303 Processes with contact 030304 Primary lead production Mg 28823 kg/Gg 9,8 3 560 030305 Primary zinc production Mg 160147 kg/Gg 2,5 113 030306 Primary copper production Mg 485869 kg/Gg 0,42 0,1 230 030307 Secondary lead production Mg 32261 kg/Gg 0,3 40 030308 Secondary zinc production Mg 8140 kg/Gg 14 0,02 85 030309 Secondary copper production Mg 585123 kg/Gg 2 110

030311 Cement Mg 12074300 kg/Gg 0,008 0,49 0,216 030317 Other glass Mg 1473911 kg/Gg 0,15* 0,05 10

28

04. Production processes 0402 Processes in iron and steel industries and collieries 040201 Coke oven Mg 8954325 kg/Gg 0,05 0,03 0,22 040202 Blast furnace charging Mg 5440047 kg/Gg 0,287 040203 Sulphur recovery plants Mg 5440047 kg/Gg 4,5 040205 Open hearth furnace steel plant Mg 177615 kg/Gg 0,2 1,4 040206 Basic oxygen furnace steel plant Mg 5822518 kg/Gg 0,025 0,003 0,1 040207 Electric furnace steel plant Mg 2809078 kg/Gg 0,25 0,15 5,5 040209 Sinter and pelletizing plants (excluding 030301) Mg 6769967 kg/Gg 0,1 0,02 5,4 0403 Processes in non-ferrous metal industries Mg 040301 Aluminium production Mg 54606 kg/Gg 0,1 040302 Ferro alloys Mg 55969 kg/Gg 0,24 040309 Other (production of batteries) Mg 50269 kg/Gg 5 0404 Processes in inorganic chemical industries Mg 040413 Chlorine production Mg 267695 kg/Gg 3,66 040414 Phosphate fertilizers Mg 348997 kg/Gg 0,6 07. Road transport Unleaded gasoline Gg 4617,8 kg/Gg 4,3 Diesel oil Gg 4380,2 kg/Gg 0,05 08. Other mobile sources and machinery Unleaded gasoline Gg 354 kg/Gg 4,3 Diesel oil Gg 741,8 kg/Gg 0,05 09. Waste treatment and disposal 0902 Waste incineration Mg 201100 kg/Gg 3 3 35 *new and updated emission factors compared to the inventory for the year 2000 are marked in bold font

Table 4b. Emissions of Cd, Hg and Pb in Poland in 2001. Emission in kg

Emission source Cd Hg Pb

NFR Code

Total 52 504 23 167 609 778

01. Combustion in energy and transformation industries 2 975,2 10 187,6 27 530,6

0101 Public power 285,2 9 668,4 15 534,7 1 A 1 a

Hard coal 160,0 7 109,8 12 442,1

Brown coal 107,5 2 558,7 3 070,4

Fuel oil 17,8 0,0 22,2

0102 District heating plants 723,1 186,1 3 881,3 1 A 1 a

Hard coal 595,5 186,1 3 721,8

Brown coal 0,0 0,0 0,0

Coke 0,0 0,0 0,0

Fuel oil 127,6 0,0 159,5

0103 Petroleum refining plants 843,9 0,6 1 065,6 1 A 1 b

Hard coal 2,1 0,6 12,9

Brown coal 0,0 0,0 0,0

Coke 0,1 0,0 0,4

Fuel oil 841,8 0,0 1 052,3

0104 Solid fuel transformation plants 83,5 24,8 526,0 1 A 1 c

Hard coal 83,5 24,8 526,0

Brown coal 0,0 0,0 0,0

29

Coke 0,0 0,0 0,0

Fuel oil 0,0 0,0 0,0

0105 Coal mining, oil/gas extraction 1 039,4 307,7 6 523,0 1 A 1 c

Hard coal 1 033,4 306,2 6 506,6

Brown coal 0,2 1,5 6,7

Coke 0,6 0,0 3,1

Fuel oil 5,3 0,0 6,6

02. Non-industrial combustion plants 33 874,7 2 288,5 187 017,5

0201 Commercial and institutional plants 7 438,9 1 142,5 47 193,7 1 A 4 a

Hard coal 7 406,5 1 139,5 47 002,6

Brown coal 0,3 2,2 9,7

Coke 32,1 0,8 181,4

Fuel oil 0,0 0,0 0,0

0202 Residential plants 21 388,4 989,1 119 708,0 1 A 4 b i

Hard coal 17 749,7 972,6 111 847,2

Brown coal 1 022,4 7,2 312,5

Coke 1 021,2 9,3 5 554,4

Fuel oil 1 595,2 0,0 1 994,0

0203 Plants in agriculture, forestry and aquaculture 5 047,5 157,0 20 115,8 1 A 4 c i

Hard coal 2 706,4 148,3 17 054,0

Brown coal 922,3 6,5 281,9

Coke 240,2 2,2 1 306,8

Fuel oil 1 178,5 0,0 1 473,2

03. Combustion in manufacturing industry 12 572,2 8 265,0 285 698,0

0301 Combustion in boilers, gas turbines and stationary engines 2 207,1 540,9 11 983,7 1 A 2 f

Hard coal 1 824,9 540,7 11 490,3

Brown coal 0,0 0,1 0,5

Coke 3,4 0,1 19,5

Fuel oil 378,7 0,0 473,4

0302 Process furnaces without contact 7 866,6 1 598,8 44 033,9 1 A 2 f

Hard coal 5 234,6 1 551,0 32 958,6

Brown coal 0,2 1,7 7,5

Coke 1 766,9 46,1 9 986,6

Fuel oil 864,9 0,0 1 081,2

0303 Processes with contact 2 498,5 6 125,3 229 680,4

030304 Primary lead production 282,5 86,5 16 140,9 1 A 2 b

030305 Primary zinc production 400,4 0,0 18 096,6 1 A 2 b

030306 Primary copper production 204,1 48,6 111 749,9 1 A 2 b

030307 Secondary lead production 9,7 0,0 1 290,4 1 A 2 b

030308 Secondary zinc production 114,0 0,2 691,9 1 A 2 b

030309 Secondary copper production 1 170,2 0,0 64 363,5 1 A 2 b

030311 Cement 96,6 5 916,4 2 608,0 1 A 2 f

030317 Other glass 221,1 73,7 14 739,1 1 A 2 f

30

04. Production processes 2 222,9 1 822,6 81 114,9

0402 Processes in iron and steel industries and collieries 2 008,1 842,9 80 850,1

040201 Coke oven 447,7 268,6 1 970,0 1 B 1 b

040202 Blast furnace charging 0,0 0,0 1 561,3 2 C

040203 Sulphur recovery plants 0,0 0,0 24 480,2 2 C

040205 Open hearth furnace steel plant 35,5 0,0 248,7 2 C

040206 Basic oxygen furnace steel plant 145,6 17,5 582,3 2 C

040207 Electric furnace steel plant 702,3 421,4 15 449,9 2 C

040209 Sinter and pelletizing plants (excluding 030301) 677,0 135,4 36 557,8 2 C

0403 Processes in non-ferrous metal industries 5,5 0,0 264,8 2 C

040301 Aluminium production 5,5 0,0 0,0

040302 Ferro alloys 0,0 0,0 13,4

040309 Other (production of batteries) 0,0 0,0 251,3

0404 Processes in inorganic chemical industries 209,4 979,8 0,0 2 B 5

040413 Chlorine production 0,0 979,8 0,0

040414 Phosphate fertilizers 209,4 0,0 0,0

07. Road transport 219,0 0,0 19 856,5 1 A 3 b

Unleaded gasoline 0,0 0,0 19 856,5

Diesel oil 219,0 0,0 0,0

08. Other mobile sources and machinery 37,1 0,0 1 522,2 1 A 3 e ii

Unleaded gasoline 0,0 0,0 1 522,2

Diesel oil 37,1 0,0 0,0

09. Waste treatment and disposal 603,3 603,3 7 038,5 6 C

0902 Waste incineration 603,3 603,3 7 038,5 Table 4c. Emission factors for: As, Cr, Cu, Ni and Zn in Poland in 2001.

Emission factors Emission source Unit

As Cr Cu Ni Zn 01. Combustion in energy and transformation industries 0101 Public power Hard coal kg/TJ 0,0021 0,0039 0,011 0,009 0,028 Brown coal kg/TJ 0,0044 0,003 0,006 0,0014 0,026 Coke kg/TJ Fuel oil kg/TJ 0,0024 0,0029 0,0068 0,0654 0,0024 0102 District heating plants Hard coal kg/TJ 0,016 0,022 0,09 0,08 0,65 Brown coal kg/TJ 0,0044 0,003 0,006 0,0014 0,026 Coke kg/TJ Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 0103 Petroleum refining plants Hard coal kg/TJ 0,017 0,022 0,095 0,085 0,69 Brown coal kg/TJ 0,018 0,011 0,024 0,005 0,11 Coke kg/TJ 0,002 0,017 0,086 0,076 0,53 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 0104 Solid fuel transformation plants Hard coal kg/TJ 0,017 0,022 0,095 0,085 0,69

31

Brown coal kg/TJ 0,018 0,011 0,024 0,005 0,11 Coke kg/TJ 0,002 0,017 0,086 0,076 0,53 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 0105 Coal mining, oil/gas extraction Hard coal kg/TJ 0,017 0,022 0,095 0,085 0,69 Brown coal kg/TJ 0,018 0,011 0,024 0,005 0,11 Coke kg/TJ 0,002 0,017 0,086 0,076 0,53 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 02. Non-industrial combustion plants 0201 Commercial and institutional plants Hard coal kg/TJ 0,034 0,043 0,19 0,17 1,32 Brown coal kg/TJ 0,018 0,011 0,024 0,005 0,11 Coke kg/TJ 0,002 0,017 0,086 0,076 0,53 0202 Residential plants Hard coal kg/TJ 0,05 0,06 0,27 0,23 1,85 Brown coal kg/TJ 0,168 0,11 0,22 0,048 1,07 Coke kg/TJ 0,005 0,045 0,237 0,209 1,45 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 0203 Plants in agriculture, forestry and aquaculture Hard coal kg/TJ 0,05 0,06 0,27 0,23 1,85 Brown coal kg/TJ 0,168 0,11 0,22 0,048 1,07 Coke kg/TJ 0,005 0,045 0,237 0,209 1,45 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 03. Combustion in manufacturing industry 0301 Combustion in boilers, gas turbines and stationary engines Hard coal kg/TJ 0,017 0,022 0,095 0,085 0,69 Brown coal kg/TJ 0,018 0,011 0,024 0,005 0,11 Coke kg/TJ 0,002 0,017 0,086 0,076 0,53 Fuel oil kg/TJ 0,024 0,029 0,068 0,654 0,024 0302 Process furnaces without contact Hard coal kg/TJ 0,017 0,022 0,095 0,085 0,69 Brown coal kg/TJ 0,018 0,011 0,086 0,005 0,11 Coke kg/TJ 0,002 0,017 0,068 0,076 0,53 Fuel oil kg/TJ 0,024 0,029 0,024 0,654 0,024 0303 Processes with contact 030304 Primary lead production kg/Gg 10,0 7,5 100,0 030305 Primary zinc production kg/Gg 294,0 030306 Primary copper production kg/Gg 32,0 334,0 300,0 030307 Secondary lead production kg/Gg 0,2 6,0 030308 Secondary zinc production kg/Gg 10,0 1089,0 030309 Secondary copper production kg/Gg 2,0 75,0 500,0

030311 Cement kg/Gg 0,012 0,105 0,111 0,293 030317 Other glass kg/Gg 0,1 2,5 0,5 2,0 10,0

04. Production processes 0402 Processes in iron and steel industries and collieries 040201 Coke oven kg/Gg 0,02 0,17 0,09 0,065 0,22 040202 Blast furnace charging kg/Gg 0,58 040203 Sulphur recovery plants kg/Gg 0,003 0,021 040205 Open hearth furnace steel plant kg/Gg 0,75 9,8 1,18 40,15 040206 Basic oxygen furnace steel plant kg/Gg 0,015 0,06 0,03 0,05 0,6 040207 Electric furnace steel plant kg/Gg 0,1 1,0 3,1 0,25 23,9

32

040209 Sinter and pelletizing plants (excluding 030301) kg/Gg 0,04 0,3 0,6 0,7 8,9 0403 Processes in non-ferrous metal industries 040301 Aluminium production kg/Gg 0,1 0,15 040302 Ferro alloys kg/Gg 80,0 040309 Other (production of batteries) kg/Gg 0404 Processes in inorganic chemical industries 040413 Chlorine production kg/Gg 040414 Phosphate fertilizers kg/Gg 07. Road transport Unleaded gasoline kg/Gg 0,5 0,3 0.5 Diesel oil kg/Gg 0,3 0,5 08. Other mobile sources and machinery Unleaded gasoline kg/Gg 0,5 0,3 0,5 Diesel oil kg/Gg 0,3 0,5 09. Waste treatment and disposal 0902 Waste incineration kg/Gg 0,05 0,3 3,0 0.1 21,0

*new and updated emission factors compared to the inventory for the year 2000 are marked in bold font Table 4d. Emissions of As, Cr, Cu, Ni and Zn in Poland in 2001.

Emission in kg Emission source

As Cr Cu Ni Zn

NFR Code

Total 52 583 64 103 394 311 287 268 1 709 164

01. Combustion in energy and transformation industries 6 192,6 7 627,7 21 698,6 41 145,9 82 945,7

0101 Public power 4 135,7 5 022,7 12 896,7 9 199,2 38 207,0 1 A 1 a

Hard coal 1 866,3 3 466,0 9 776,0 7 998,5 24 884,2

Brown coal 2 251,6 1 535,2 3 070,4 716,4 13 305,0

Fuel oil 17,8 21,5 50,3 484,2 17,8

0102 District heating plants 499,8 665,9 2 455,1 5 338,2 15 247,5 1 A 1 a

Hard coal 372,2 511,7 2 093,5 1 860,9 15 119,8

Brown coal 0,0 0,0 0,0 0,0 0,0

Coke 0,0 0,0 0,0 0,0 0,0

Fuel oil 127,6 154,2 361,5 3 477,3 127,6

0103 Petroleum refining plants 843,1 1 018,9 2 392,6 22 945,7 895,8 1 A 1 b

Hard coal 1,3 1,7 7,2 6,5 52,4

Brown coal 0,0 0,0 0,0 0,0 0,0

Coke 0,0 0,1 0,3 0,2 1,6

Fuel oil 841,8 1 017,2 2 385,1 22 939,1 841,8

0104 Solid fuel transformation plants 52,6 68,1 293,9 263,0 2 134,9 1 A 1 c

Hard coal 52,6 68,1 293,9 263,0 2 134,9

Brown coal 0,0 0,0 0,0 0,0 0,0

Coke 0,0 0,0 0,0 0,0 0,0

Fuel oil 0,0 0,0 0,0 0,0 0,0

0105 Coal mining, oil/gas extraction 661,5 852,1 3 660,3 3 399,9 26 460,6 1 A 1 c

Hard coal 650,7 842,0 3 636,0 3 253,3 26 409,1

Brown coal 5,5 3,4 7,3 1,5 33,6

Coke 0,0 0,4 2,1 1,8 12,7

33

Fuel oil 5,3 6,4 14,9 143,2 5,3

02. Non-industrial combustion plants 22 193,8 27 479,2 115 843,0 168 480,9 740 622,2

0201 Commercial and institutional plants 4 853,4 6 153,2 27 192,7 24 321,7 188 798,4 1 A 4 a

Hard coal 4 842,7 6 124,6 27 062,1 24 213,5 188 010,4

Brown coal 8,0 4,9 10,6 2,2 48,7

Coke 2,8 23,7 120,0 106,0 739,4

Fuel oil 0,0 0,0 0,0 0,0 0,0

0202 Residential plants 14 071,7 17 370,9 74 152,7 102 694,5 475 390,5 1 A 4 b i

Hard coal 12 157,3 14 588,8 65 649,4 55 923,6 449 820,1

Brown coal 241,9 158,4 316,8 69,1 1 540,8

Coke 77,4 696,2 3 666,9 3 233,6 22 434,4

Fuel oil 1 595,2 1 927,5 4 519,6 43 468,1 1 595,2

0203 Plants in agriculture, forestry and aquaculture 3 268,7 3 955,2 14 497,6 41 464,8 76 433,4 1 A 4 c i

Hard coal 1 853,7 2 224,4 10 010,0 8 527,0 68 586,9

Brown coal 218,2 142,9 285,8 62,4 1 389,9

Coke 18,2 163,8 862,7 760,8 5 278,0

Fuel oil 1 178,5 1 424,0 3 339,1 32 114,7 1 178,5

03. Combustion in manufacturing industry 23 235,5 13 520,1 239 161,3 66 254,4 738 110,6 0301 Combustion in boilers, gas turbines and stationary engines 1 528,5 1 947,4 7 507,6 16 077,5 47 097,9 1 A 2 f

Hard coal 1 149,0 1 487,0 6 421,0 5 745,1 46 637,0

Brown coal 0,4 0,3 0,6 0,1 2,7

Coke 0,3 2,5 12,9 11,4 79,4

Fuel oil 378,7 457,7 1 073,1 10 320,8 378,7

0302 Process furnaces without contact 4 320,6 6 620,1 24 536,1 45 888,8 175 390,1 1 A 2 f

Hard coal 3 295,9 4 265,2 18 418,0 16 479,3 133 773,1

Brown coal 6,1 3,8 29,3 1,7 37,5

Coke 153,6 1 305,9 5 223,8 5 838,3 40 714,6

Fuel oil 864,9 1 045,1 864,9 23 569,5 864,9

0303 Processes with contact 17 386,4 4 952,6 207 117,6 4 288,1 515 622,6

030304 Primary lead production 288,2 0,0 216,2 0,0 2 882,3 1 A 2 b

030305 Primary zinc production 0,0 0,0 0,0 0,0 47 083,2 1 A 2 b

030306 Primary copper production 15 547,8 0,0 162 280,2 0,0 145 760,7 1 A 2 b

030307 Secondary lead production 6,5 0,0 0,0 0,0 193,6 1 A 2 b

030308 Secondary zinc production 81,4 0,0 0,0 0,0 8 864,5 1 A 2 b

030309 Secondary copper production 1 170,2 0,0 43 884,2 0,0 292 561,5 1 A 2 b

030311 Cement 144,9 1 267,8 0,0 1 340,2 3 537,8 1 A 2 f

030317 Other glass 147,4 3 684,8 737,0 2 947,8 14 739,1 1 A 2 f

04. Production processes 951,3 12 929,8 13 976,6 6 319,9 143 262,0

0402 Processes in iron and steel industries and collieries 951,3 8 452,3 13 976,6 6 314,4 143 253,8

040201 Coke oven 179,1 1 522,2 805,9 582,0 1 970,0 1 B 1 b

040202 Blast furnace charging 0,0 0,0 0,0 0,0 3 155,2 2 C

040203 Sulphur recovery plants 0,0 0,0 16,3 0,0 114,2 2 C

040205 Open hearth furnace steel plant 133,2 1 740,6 209,6 0,0 7 131,2 2 C

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040206 Basic oxygen furnace steel plant 87,3 349,4 174,7 291,1 3 493,5 2 C

040207 Electric furnace steel plant 280,9 2 809,1 8 708,1 702,3 67 137,0 2 C

040209 Sinter and pelletizing plants (excluding 030301) 270,8 2 031,0 4 062,0 4 739,0 60 252,7 2 C

0403 Processes in non-ferrous metal industries 0,0 4 477,5 0,0 5,5 8,2 2 C

040301 Aluminium production 0,0 0,0 0,0 5,5 8,2

040302 Ferro alloys 0,0 4 477,5 0,0 0,0 0,0

040309 Other (production of batteries) 0,0 0,0 0,0 0,0 0,0

0404 Processes in inorganic chemical industries 0,0 0,0 0,0 0,0 0,0 2 B 5

040413 Chlorine production 0,0 0,0 0,0 0,0 0,0

040414 Phosphate fertilizers 0,0 0,0 0,0 0,0 0,0

07. Road transport 0,0 2 308,9 2 699,4 4 499,0 0,0 1 A 3 b

Unleaded gasoline 0,0 2 308,9 1 385,3 2 308,9 0,0

Diesel oil 0,0 0,0 1 314,1 2 190,1 0,0

08. Other mobile sources and machinery 0,0 177,0 328,7 547,9 0,0 1 A 3 e ii

Unleaded gasoline 0,0 177,0 106,2 177,0 0,0

Diesel oil 0,0 0,0 222,5 370,9 0,0

09. Waste treatment and disposal 10,1 60,3 603,3 20,1 4 223,1 6 C

0902 Waste incineration 10,1 60,3 603,3 20,1 4 223,1 Table 4e. Emissions of Cd, Hg, PB, As, Cr, Cu, Ni and Zn in Poland in 2001 according to NFR.

Emission in Mg NFR code

Cd Hg Pb As Cr Cu Ni Zn

Total 52,5 23,2 609,8 52,6 64,1 394,3 287,3 1 709,2

1 A 1 a 1,008 9,855 19,416 4,635 5,689 15,352 14,537 53,454

1 A 1 b 0,844 0,001 1,066 0,843 1,019 2,393 22,946 0,896

1 A 1 c 1,123 0,332 7,049 0,714 0,920 3,954 3,663 28,595

1 A 2 b 2,181 0,135 212,333 17,094 0,000 206,381 0,000 497,346

1 A 2 f 10,391 8,130 73,365 6,141 13,520 32,781 66,254 240,765

1 A 3 b 0,219 0,000 19,857 0,000 2,309 2,699 4,499 0,000

1 A 3 e ii 0,037 0,000 1,522 0,000 0,177 0,329 0,548 0,000

1 A 4 a 7,439 1,143 47,194 4,853 6,153 27,193 24,322 188,798

1 A 4 b i 21,388 0,989 119,708 14,072 17,371 74,153 102,694 475,390

1 A 4 c i 5,047 0,157 20,116 3,269 3,955 14,498 41,465 76,433

1 B 1 b 0,448 0,269 1,970 0,179 1,522 0,806 0,582 1,970

2 B 5 0,209 0,980 0,000 0,000 0,000 0,000 0,000 0,000

2 C 1,566 0,574 79,145 0,772 11,408 13,171 5,738 141,292

6 C 0,603 0,603 7,039 0,010 0,060 0,603 0,020 4,223 2.5 Persistent organic pollutants Verification of the emission factors has been carried out based on quite a few results of Polish POPs emission measurements in 2002, expert’s opinions, information from industrial plants and comparative analysis of the factors used in Poland and other countries. For the first time estimates for Polish emission factors for HCB are presented. Tables 5a, 5b and 5c include all previously used and currently used emission factors for PCDD/F, HCP and PCBs respectively.

35

Numbers in bold and italic have been calculated on the basis of most recent domestic measurements. The main source of PCDD/F (68% of national total) and PAHs emission (87%) in Poland are non-industrial combustion plants (residential plants and plants in agriculture, forestry and aquaculture). Large part of HCB emission (82%) comes from sinter and pelletizing plants. Above 72% of PCBs emission results from leakage in capacitors, mainly because of using a high emission factor in this category. Data about pesticides were obtained from Wood Technology Institute and from the Office for Plant Protection and Product Registration at the Institute for Cultivated Plant Protection. As there are no current data on some solvents use in wood conservation processes, the old value was applied. Pesticides listed by EMEP have not been in use in Poland since early eighties and DDT since 1972, so no emission for all the listed pesticides was given.

Table 5a. Currently and previously used emission factors for PCDD/F in Poland in 2001.

PCDD/F Emission source Emission factor currently used [µg TEQ / Mg]

Emission factor previously used [µg

TEQ / Mg]

02. Non-industrial combustion plants

0203 Plants in agriculture, forestry and aquaculture

Hard coal 0,06 18

Brown coal 0,06 10Fuel oil 1 1Fuel wood 1 503. Combustion in manufacturing industry

030301 Sinter and pelletizing plants 1,45 5030307 Secondary lead production 8 none030308 Secondary zinc production (basic APCs) 100 none

030309 Secondary copper production in BOF 0,01

noneEF of 50 was used

for all secondary copper production

030310 Secondary aluminium production (including scrap processing) 150 none

030311 Cement* 0,07 0,15030312 Lime (no or minimal APCs) 10 none030312 Lime (good APCs) 0,07 none030313 Asphalt mixing (no APCs) 0,07 none030313 Asphalt mixing (scrubbers, fabric filters) 0,007 none030314 Flat glass (no or minimal APCs) 0,2 none030315 Container glass (no or minimal APCs) 0,2 none030319 Bricks and tiles (no or minimal APCs) 0,2 none030319 Bricks and tiles (good APCs) 0,02 none030320 Ceramics (no or minimal APCs) 0,2 none030320 Ceramics (good APCs) 0,02 none

04. Production processes

040201 Coke production (APCs/flue gas burn out) 0,3 none040617 Other (smoke houses - clean fuel, no flue gas burn out) 6 none040617 Other (smoke houses - clean fuel, with flue gas burn out) 0,6 none

09. Waste treatment and disposal

090201 Municipal waste incineration (modern APCs) 0,5 none090202 Industrial waste incineration (no APCs) 3500 none

36

090202 Industrial waste incineration (minimal APCs) 350 none090202 Industrial waste incineration (good APCs) 30 none090202 Industrial waste incineration (very good APCs) 0,5 none090205 Sewage sludge incineration (with APCs) 4 none

090207 Hospital waste incineration (minimal APCs) 68 830907 Open burning of agricultural wastes (excluding code 1003) 30 none090901 Cremation of corpses** 10 µg TEQ / body none

10. Agriculture

1003 On-field burning of stubble and straw 5 none1003 On-field burning of stubble and straw (waste land fires) 5 none

11. Other sources and sinks

1103 Forest and other vegetation fires 5 none1125 Other (landfill fires) 1000 none1125 Other (automobile fires) 94 µg TEQ / fire none1125 Other (household and plant fires) 400 none

1125 Other (cigarette smoking) 1,00E-7 µg TEQ/

cigarette none* activity figure is production of clinker in Gg, EF is in g/Gg clinker** activity figure is the number of bodies cremated, emission factor is expressed in mg TEQ/body *** activity figure is the number of cigarettes burned, emission factor is expressed in mg TEQ/cigarette numbers in bold and italic have been calculated on the basis of most recent domestic measurements

Table 5b. Currently and previously used emission factors for HCB in Poland in 2001.

HCB Emission source Emission factor currently used

[mg/Mg]

Emission factor previously used

[mg/Mg]

02. Non-industrial combustion plants 0202 Residential plants Hard coal 0,125 0,013 03. Combustion in manufacturing industry 030301 Sinter and pelletizing plants 0,14 4,7 030309 Secondary copper production 39 39

030311 Cement* 0,021 0,17 07. Road transport Leaded gasoline** 0,355 none Unleaded gasoline** 0,000368 none Diesel oil*** 6,00E-03 none 09. Waste treatment and disposal

090201 Municipal waste incineration 0,15 none 090202 Industrial waste incineration (no or minimal APCs) 19 none 090202 Industrial waste incineration (good and v. good APCs) 0,139 none

090207 Hospital waste incineration (installations that comply with EU Directive)

0,295 none EF of 29 was used

for all hospital waste incineration

* activity figure is production of clinker in Gg, EF is in g/Gg clinker** EF has been computed based upon literature EF for leaded gasoline: 21 ng/km, for unleaded gasoline 0,024 ng/km assuming

average fuel consumption 8 and 8,8 litres respectively per 100 km and gasoline density 0,74 kg/l *** EF has been computed based upon literature EF: 0.87 ng/km, assuming average fuel consumption 16.5 litres/100km and diesel

oil density 0,84 kg/l (including buses and tractors) numbers in bold and italic have been calculated on the basis of most recent domestic measurements

Table 5c. Currently and previously used emission factors for PCB in Poland in 2001.

PCB Emission source Emission factor currently used

[mg/Mg]

Emission factor used previously

[mg/Mg]

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01. Combustion in energy and transformation industries 0101 Public power Hard coal 0,31 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 0102 District heating plants Hard coal 0,31 3,6 Fuel oil 0,6 3,6 0103 Petroleum refining plants Hard coal 0,31 3,6 Fuel oil 0,6 3,6 0104 Solid fuel transformation plants Hard coal 0,31 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 0105 Coal mining, oil/gas extraction Hard coal 0,31 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 02. Non-industrial combustion plants 0201 Commercial and institutional plants Hard coal 0,413 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 Coke 3,6 none 0202 Residential plants Hard coal 31,6 3,6 Brown coal 183,2 3,6 Fuel oil 3,6 3,6 Fuel wood 9 3,5 Coke 9,7 none 0203 Plants in agriculture, forestry and aquaculture Hard coal 0,413 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 Coke 3,6 none 03. Combustion in manufacturing industry 0301 Combustion in boilers, gas turbines and stationary engines Hard coal 0,31 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 Coke 3,6 none 0302 Process furnaces without contact Hard coal 0,31 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 Coke 3,6 none 0303 Processes with contact Hard coal 0,31 3,6 Brown coal 1,8 3,6 Fuel oil 0,6 3,6 Fuel wood 0,9 3,5 Coke 3,6 none

38

030301 Sinter and pelletizing plants 0,065 2,4 030311 Cement* 0,007 none

07. Road transport Leaded gasoline** 106 none Unleaded gasoline 0,02 none Diesel oil (passenger cars and light duty vehicles)*** 0,67 none Diesel oil (heavy duty vehicles)**** 24,5 none 09. Waste treatment and disposal

090201 Municipal waste incineration (modern APCs) 0,2 none 090202 Industrial waste incineration (no APCs) 30,4 none 090202 Industrial waste incineration (minimal APCs) 19,3 none 090202 Industrial waste incineration (good and v. good APCs) 0,38 none 090207 Hospital waste incineration (no or minimal APCs) 20 none

090207 Hospital waste incineration (installations that comply with EU Directive) 0,39 none

* activity figure is production of clinker in Gg, EF is in g/Gg clinker** EF has been computed based upon literature EF: 6.32 µ/km assuming average fuel consumption 8 l/100 km and gasoline density

0,74 kg/l *** EF has been computed based upon literature EF: 0.05 µ/km, assuming average fuel consumption 9 l/100 km and diesel oil

density 0,84 kg/l **** EF has been computed based upon literature EF: 5.53 µ/km, assuming average fuel consumption 26 l/100 km and diesel oil

density 0,84 kg/l numbers in bold and italic have been calculated on the basis of most recent domestic measurements Estimation of emissions of dioxins/furans – PCDD/F (Tables: 6a and 6b), hexachlorobenzene - HCB (Tables: 7a and 7b), polychlorinated biphenyls - PCBs (Tables: 8a and 8b), and four polyaromatic hydrocarbons PAHs indicators (Tables 9a and 9b) in the year 2001 was based on national activity data including fuel statistics as well as on emission factors taken from literature and recent domestic measurements described in detail in the following. Changes in the inventories of POPs compared to the year 2000. PCDD/F Emissions of PCDD/F in 2001 increased by 34% compared to 2000. This increase is caused mainly by taking into account new EFS and new emission sources: industrial waste incineration, fires of: landfills, households, vehicles and forest (all fires accounted for app. 25% of the national total). Among other new sources were:

• municipal waste incineration, sewage sludge incineration, secondary non-ferrous metal production: lead, zinc, aluminium; lime production, production of glass, asphalt mixing, production of bricks, ceramics and coke; open burning of agricultural wastes, on-field burning of stubble and straw, smokehouses and cremation of corpses and cigarette smoking

With respect to methodology the following modifications were made: • based on Polish measurements and literature (UNEP Chemicals Toolkit) verification of

EFs was made in the following categories: SNAP 0202 - new EF for coke production, SNAP 0203 - lower EFs for several fuels were taken based on literature, EF for sinter plants was lowered based on domestic measurements, cement production - lower EF was taken based on domestic measurements, secondary copper production was divided into BOFs (lower EF due to specific combustion conditions) and other furnaces, EFs for hospital waste incineration were corrected for installations with APCs of low effectiveness - based on domestic research.

PCB PCB emissions in 2001 grew by 2.8% compared to 2000. There were significant changes in several source categories namely in fuel combustion in various sectors due to introduction of varying EFs for different fuels in different sub-categories what is justified by different

39

combustion conditions and hence emissions. Emissions from transport were added (with a share of 3.8% of the total) which were not taken into account in previous inventories. All these modifications did not change the national total which is dominated by estimation of emission from leaking capacitors and other electric equipment. This estimate - although highly uncertain has not been changed and still accounts for about 70% of the national total.

• new sources: municipal, industrial and hospital waste incineration and cement production • correction of EFs in SNAP 0101, 0202 and 0203, lower EF for sinter plants based on

domestic measurements. HCB Estimated HCB emissions in 2001 are lower by 80% compared to 2000. The reason for this dramatic change is assuming much lower EF for sinter plants. This category was the dominating emission source in previous inventories of HCB. The EF was lowered from 4.7 mg/Mg (literature value) to 0.14 mg/Mg. The basis for this change were dedicated measurements carried out in the only two existing plants in Poland. Other changes included:

• new sources: municipal and industrial waste incineration and road transport • verification of EFs based on domestic research in: cement production, hospital waste

incineration at installations that comply with strict regulations of the respective EU Directive; combustion of coal in residential and commerce sector.

PAHs Emissions of PAHs decreased slightly (2.2%) compared to 2000 (BaP – 3.2% decrease, BbF - 4.2% decrease, BkF - 7.3% decrease, I_P – 2.5% increase). There were no changes of emission factors or emission sources in 2001. All the changes in emissions result from changes in activity data. Table 6a. Dioxins and furans emissions in Poland in 2001.

Activity Emission factor Emission NFR Emission source [Gg] [mg TEQ/Gg] [mg TEQ] code

TOTAL 447 490 01. Combustion in energy and transformation industries 7 374,9 0101 Public power plants Hard coal 41742,7 0,06 2 504,6 1 A 1 a Brown coal 59127,2 0,06 3 547,6 1 A 1 a Fuel oil 178,5 1 178,5 1 A 1 a 0102 District heating plants Hard coal 1041,2 0,06 62,5 1 A 1 a Brown coal 0,0 0,06 0,0 1 A 1 a Fuel oil 128,8 1 128,8 1 A 1 a Coke 2,6 0,0 1 A 1 a 0103 Petroleum refining plants Hard coal 3 0,06 0,2 1 A 1 b Brown coal 0,0 0,06 0,0 1 A 1 b Fuel oil 850 1 850,0 1 A 1 b Fuel wood 0,0 1 0,0 1 A 1 b 0104 Solid fuel transformation plants Hard coal 102 0,06 6,1 1 A 1 c Brown coal 0,0 0,06 0,0 1 A 1 c Fuel oil 0,0 1 0,0 1 A 1 c Fuel wood 0,0 1 0,0 1 A 1 c 0105 Coal mining, oil/ gas extraction, pipeline compressors

40

Hard coal 1476 0,06 88,6 1 A 1 c Brown coal 33 0,06 2,0 1 A 1 c Fuel oil 5 1 5,0 1 A 1 c Fuel wood 1,0 1 1,0 1 A 1 c 02. Non-industrial combustion plants 207 169,3 0201 Commercial and institutional plants Hard coal 6371,1 0,06 382,3 1 A 4 a Brown coal 38,2 0,06 2,3 1 A 4 a Fuel oil 36,2 1 36,2 1 A 4 a Fuel wood 8,4 1 8,4 1 A 4 a Coke 51,9 0,0 1 A 4 a 0202 Residential plants Hard coal 9112 18 164 016,0 1 A 4 b i Brown coal 159 10 1 590,0 1 A 4 b i Fuel oil 1540 1 1 540,0 1 A 4 b i Fuel wood 7 349 5 36 745,0 1 A 4 b i Coke 558 0,61 340,4 0203 Plants in agriculture, forestry and aquaculture Hard coal 1701 0,06 102,1 1 A 4 c i Brown coal 144 0,06 8,6 1 A 4 c i

Fuel oil 1131 1 1 131,0 1 A 4 c i Fuel wood 1 267 1 1 267,0 1 A 4 c i Coke 130 1 130,0 1 A 4 c i 03. Combustion in manufacturing industry 44 987,0 0301 Combustion in boilers, gas turbines and stationery engines Hard coal 2991,8 0,06 179,5 1 A 2 f Brown coal 2,6 0,06 0,2 1 A 2 f Fuel oil 382,8 1 382,8 1 A 2 f Fuel wood 2,0 1 2,0 1 A 2 f Coke 5,6 0,0 1 A 2 f 0302 Process furnaces without contact Hard coal 5 836,0 0,06 350,2 1 A 2 f Brown coal 34,0 0,06 2,0 1 A 2 f Fuel oil 681,0 1 681,0 1 A 2 f Fuel wood 143,6 1 143,6 1 A 2 f Coke 190,0 0,0 1 A 2 f 0303 Processes with contact Hard coal 2 463,0 0,06 147,8 1 A 2 f Brown coal 2,0 0,06 0,1 1 A 2 f Fuel oil 173,0 1 173,0 1 A 2 f Fuel wood 1,3 1 1,3 1 A 2 f Coke 2 644,0 0,0 1 A 2 f

030301 Sinter and pelletizing plants 6770 1,45 9 816,5 1 A 2 a 030307 Secondary lead production 32,2 8 257,6 1 A 2 b 030309 Secondary zinc production (basic APCs) 8,1 100 810,0 1 A 2 b 030309 Secondary copper production (BOF copper) 27,9 0,01 0,3 1 A 2 b 030309 Secondary copper production (other furnaces) 58,7 50 2 935,0 1 A 2 b 030310 Secondary aluminium production (including scrap processing) 116,9 150 17 535,0 1 A 2 b 030311 Cement* 9335,1 0,07 653,5 1 A 2 f 030312 Lime (no or minimal APCs) 1024,7 10 10 247,0 1 A 2 f 030312 Lime (good APCs) 1024,7 0,07 71,7 1 A 2 f

41

030313 Asphalt mixing (no APCs) 391 0,07 27,4 1 A 2 f 030313 Asphalt mixing (scrubbers, fabric filters) 391 0,007 2,7 1 A 2 f 030314 Flat glass (no or minimal APCs) 480,5 0,2 96,1 1 A 2 f 030315 Container glass (no or minimal APCs) 993,4 0,2 198,7 1 A 2 f 030319 Bricks and tiles (no or minimal APCs) 853,4 0,2 170,7 1 A 2 f 030319 Bricks and tiles (good APCs) 1280,1 0,02 25,6 1 A 2 f 030320 Ceramics (no or minimal APCs) 343,9 0,2 68,8 1 A 2 f 030320 Ceramics (good APCs) 343,9 0,02 6,9 1 A 2 f

04. Production processes 33 077,8 040201 Coke production (APCs/flue gas burn out) 8954,3 0,3 2 686,3 1 B 1 b

040203 Pig iron tapping 5 440 2 10 880,0 2 C 1 040205 Open heart furnace steel plants 177,6 2 355,2 2 C 2 040206 Basic oxygen furnace steel plants 5822,5 2 11 645,0 2 C 2 040207 Electric furnace steel plants 2809 2 5 618,0 2 C 2 040301 Aluminium production (electrolysis) 54,6 2 109,2 2 C 3

040617 Other (smoke houses - clean fuel, no flue gas burn out) 247,8 6 1 486,8 2 A 7 040617 Other (smoke houses - clean fuel, with flue gas burn out) 495,5 0,6 297,3 2 A 7

07. Road transport 882,1 0701 Passenger cars

Leaded gasoline** 84,3 2,2 185,5 1 A 3 b i

Unleaded gasoline** 3751,1 0,104 390,1 1 A 3 b i Diesel oil*** 551,6 0,043 23,7 1 A 3 b i

0702 Light duty vehicles < 3.5 t Leaded gasoline** 16,1 2,2 35,4 1 A 3 b ii Unleaded gasoline** 703 0,104 73,1 1 A 3 b ii Diesel oil*** 700,9 0,043 30,1 1 A 3 b ii

0703 Heavy duty vehicles > 3.5 t an buses Leaded gasoline** 0,2 2,2 0,4 1 A 3 b iii Unleaded gasoline** 7 0,104 0,7 1 A 3 b iii Diesel oil*** 3127,7 0,043 134,5 1 A 3 b iii

0704 Mopeds and motorcycles < 50cm3 Leaded gasoline** 0,5 2,2 1,1 1 A 3 b ivUnleaded gasoline** 20,9 0,104 2,2 1 A 3 b iv

0705 Motorcycles > 50cm3 Leaded gasoline** 0,8 2,2 1,8 1 A 3 b ivUnleaded gasoline** 33,9 0,104 3,5 1 A 3 b iv08. Other mobile sources and machinery 58,1

0802 Railways 080201 Shunting locs

Diesel oil 76,2 0,043 3,3 1 A 3 c 0803 Inland waterways

Diesel oil 10,9 0,043 0,5 1 A 3 d ii 080402 National sea traffic

Diesel oil 14,0 0,043 0,6 1 A 3 d ii 080403 National fishing

Diesel oil 21,8 0,043 0,9 1 A 4 c iii 0806 Agriculture

Diesel oil 600,2 0,043 25,8 1 A 4 c ii 0808 Industry

Diesel oil 31,9 0,043 1,4 1 A 2 f 0810 Other off-road

42

Leaded gasoline 11,2 2,2 24,6 1 A 3 e ii Diesel oil 23,1 0,043 1,0 1 A 3 e ii 09. Waste treatment and disposal 41 094,8

090201 Municipal waste incineration (modern APCs) 14,2 0,5 7,1 6 C 090202 Industrial waste incineration (no APCs) 3,0 3500 10 500,0 6 C 090202 Industrial waste incineration (minimal APCs) 30,3 350 10 605,0 6 C 090202 Industrial waste incineration (good APCs) 133,1 30 3 993,0 6 C 090202 Industrial waste incineration (very good APCs) 136,1 0,5 68,1 6 C 090205 Sewage sludge incineration (with APCs) 32,5 4 130,0 6 C 090207 Hospital waste incineration (no APCs) 9,7 453,3 4 397,0 6 C 090207 Hospital waste incineration (minimal APCs) 11,0 68 748,0 6 C 090207 Hospital waste incineration (installations that comply with EU

Directive) 3,3 1,4 4,6 6 C 0907 Open burning of agricultural wastes (excluding code 1003) 352,4 30 10 572,0 6 C 090901 Cremation of corpses** 7000 0,01 70,0 6 C

10. Agriculture 611,0 1003 On-field burning of stubble and straw 19,6 5 98,0 4 F 1003 On-field burning of stubble and straw (waste land fires) 102,6 5 513,0 4 F

11. Other sources and sinks 112 235,2 1103 Forest and other vegetation fires 125 5 625,0 6 D 1125 Other (landfill fires) 95,4 1000 95 400,0 6 D

1125 Other (automobile fires) 43,0 94 4 042,0 6 D 1125 Other (household and plant fires) 30,4 400 12 160,0 6 D 1125 Other (cigarette smoking) 8,17E+10 1,00E-10 8,2 6 D

* activity figure is production of clinker in Gg, EF is in g/Gg clinker** activity figure is the number of bodies cremated, emission factor is expressed in mg TEQ/body *** activity figure is the number of cigarettes burned, emission factor is expressed in mg TEQ/cigarette

Table 6b. Dioxins and furans emissions in Poland in 2001.

NFR code Emission in mg TEQ

TOTAL 447 4901 A 1 a 6 422,01 A 1 b 850,21 A 1 c 102,71 A 2 a 9 816,51 A 2 b 21 537,91 A 2 f 13 634,01 A 3 b i 599,31 A 3 b ii 138,61 A 3 b iii 135,61 A 3 b iv 8,61 A 3 c 3,31 A 3 d ii 1,11 A 3 e ii 25,61 A 4 a 429,21 A 4 b i 204 321,41 A 4 c i 2 508,71 A 4 c ii 25,81 A 4 c iii 0,91 B 1 b 2 686,32 A 7 1 784,12 C 28607,4

43

4 F 611,06 C 41 094,86 D 112 235,2

Table 7a. HCB emission in Poland in 2001.

Activity Emission factors Emission NFR Emission source [Gg] [g/Gg] [kg] code

TOTAL 8,35 01. Combustion in energy and transformation industries 0,57 0101 Public power plants Hard coal 41 742,7 0,013 0,54 1 A 1 a 0102 District heating plants Hard coal 1 041,2 0,013 0,01 1 A 1 a 0103 Petroleum refining plants Hard coal 3,0 0,013 0,00 1 A 1 b 0104 Solid fuel transformation plants Hard coal 102,0 0,013 0,00 1 A 1 c

0105 Coal mining, oil/ gas extraction, pipeline compressors Hard coal 1 476,0 0,013 0,02 1 A 1 c Fuel wood 1,0 0,06 0,00 1 A 1 c 02. Non-industrial combustion plants 1,76 0201 Commercial and institutional plants Hard coal 6 371,1 0,013 0,08 1 A 4 a Fuel wood 8,4 0,06 0,00 1 A 4 a 0202 Residential plants Hard coal 9 112,0 0,125 1,14 1 A 4 b i Fuel wood 7 349,0 0,06 0,44 1 A 4 b i 0203 Plants in agriculture, forestry and aquaculture Hard coal 1 701,0 0,013 0,02 1 A 4 c i Fuel wood 1 267,0 0,06 0,08 1 A 4 c i 03.Combustion in manufacturing industry 4,69 0301 Combustion in boilers, gas turbines and stationery engines Hard coal 2 991,8 0,013 0,04 1 A 2 f Fuel wood 2,0 0,06 0,00 1 A 2 f 0302 Process furnaces without contact Hard coal 5 836,0 0,013 0,08 1 A 2 f Fuel wood 143,6 0,06 0,01 1 A 2 f 0303 Processes with contact Hard coal 2 463,0 0,013 0,03 1 A 2 f Fuel wood 1,3 0,06 0,00 1 A 2 f 030301 Sinter and pelletizing plants 6 770,0 0,14 0,95 1 A 2 a 030309 Secondary copper production 86,6 39 3,38 1 A 2 b 030311 Cement 9 335,1 0,021 0,20 1 A 2 f 07. Road transport 0,06

0701 Passenger cars Leaded gasoline** 84,3 0,355 0,03 1 A 3 b i Unleaded gasoline** 3751,1 0,000368 0,00 1 A 3 b i Diesel oil*** 551,6 6,00E-03 0,00 1 A 3 b i

0702 Light duty vehicles < 3.5 t

44

Leaded gasoline** 16,1 0,355 0,01 1 A 3 b ii Unleaded gasoline** 703 0,000368 0,00 1 A 3 b ii Diesel oil*** 700,9 6,00E-03 0,00 1 A 3 b ii

0703 Heavy duty vehicles > 3.5 t an buses Leaded gasoline** 0,2 0,355 0,00 1 A 3 b iii Unleaded gasoline** 7 0,000368 0,00 1 A 3 b iii Diesel oil*** 3127,7 6,00E-03 0,02 1 A 3 b iii

0704 Mopeds and motorcycles < 50cm3 Leaded gasoline** 0,5 0,355 0,00 1 A 3 b ivUnleaded gasoline** 20,9 0,000368 0,00 1 A 3 b iv

0705 Motorcycles > 50cm3 Leaded gasoline** 0,8 0,355 0,00 1 A 3 b ivUnleaded gasoline** 33,9 0,000368 0,00 1 A 3 b iv09. Waste treatment and disposal 1,27

090201 Municipal waste incineration 14,2 0,15 0,00 6 C 090202 Industrial waste incineration (APCs of low effectiveness) 33,3 19 0,63 6 C 090202 Industrial waste incineration (APCs of high effectiveness) 269,2 0,139 0,04 6 C 090207 Hospital waste incineration (installations that comply with EU

Directive) 3,3 0,295 0,00 6 C 090207 Hospital waste incineration (installations with no or poor APCs) 20,7 29 0,60 6 C

* activity figure is production of clinker in Gg, EF is in g/Gg clinker** EF has been computed based upon literature EF for leaded gasoline: 21 ng/km, for unleaded gasoline 0,024 ng/km assuming

average fuel consumption 8 and 8,8 litres respectively per 100 km and gasoline density 0,74 kg/l *** EF has been computed based upon literature EF: 0.87 ng/km, assuming average fuel consumption 16.5 litres/100km and diesel

oil density 0,84 kg/l (including buses and tractors)

Table 7b. HCB emission in Poland in 2001 according to NFR codes. NFR code Emission in kg

TOTAL 8,351 A 1 a 0,551 A 1 b 0,001 A 1 c 0,021 A 2 a 0,951 A 2 b 3,381 A 2 f 0,361 A 3 b i 0,031 A 3 b ii 0,011 A 3 b iii 0,021 A 3 b iv 0,001 A 4 a 0,081 A 4 b i 1,581 A 4 c i 0,106 C 1,27

Table 8a. PCB emission in Poland in 2001.

Activity Emission factor Emission NFR Emission source [Gg] [g/Gg] [kg] code

TOTAL 2 327 01. Combustion in energy and transformation industries 120,9 0101 Public power plants Hard coal 41742,7 0,31 12,94 1 A 1 a Brown coal 59127,2 1,8 106,43 1 A 1 a Fuel oil 178,5 0,6 0,11 1 A 1 a

45

0102 District heating plants Hard coal 1041,2 0,31 0,32 1 A 1 a Fuel oil 128,8 0,6 0,08 1 A 1 a Coke 2,6 0,00 1 A 1 a 0103 Petroleum refining plants Hard coal 3 0,31 0,00 1 A 1 b Fuel oil 850 0,6 0,51 1 A 1 b Fuel wood 0,0 0,9 0,00 1 A 1 b 0104 Solid fuel transformation plants Hard coal 102 0,31 0,03 1 A 1 c Fuel oil 0,0 0,6 0,00 1 A 1 c Fuel wood 0,0 0,9 0,00 1 A 1 c 0105 Coal mining, oil/ gas extraction, pipeline compressors Hard coal 1476 0,31 0,46 1 A 1 c Brown coal 33 1,8 0,06 1 A 1 c Fuel oil 5 0,6 0,00 1 A 1 c Fuel wood 1,0 0,9 0,00 1 A 1 c 02. Non-industrial combustion plants 400,3 0201 Commercial and institutional plants Hard coal 6371,1 0,413 2,63 1 A 4 a Brown coal 38,2 1,8 0,07 1 A 4 a Fuel oil 36,2 0,6 0,02 1 A 4 a Fuel wood 8,4 0,9 0,01 1 A 4 a Coke 51,9 3,6 0,19 1 A 4 a 0202 Residential plants Hard coal 9112 31,6 287,94 1 A 4 b i Brown coal 159 183,2 29,13 1 A 4 b i Fuel oil 1540 3,6 5,54 1 A 4 b i Fuel wood 7 349 9 66,14 1 A 4 b i Coke 558 9,7 5,41 1 A 4 b i 0203 Plants in agriculture, forestry and aquaculture Hard coal 1701 0,413 0,70 1 A 4 c i Brown coal 144 1,8 0,26 1 A 4 c i Fuel oil 1131 0,6 0,68 1 A 4 c i Fuel wood 1 267 0,9 1,14 1 A 4 c i Coke 130 3,6 0,47 1 A 4 c i 03. Combustion in manufacturing industry 15,7 0301 Combustion in boilers, gas turbines and stationery engines Hard coal 2991,8 0,31 0,93 1 A 2 f Brown coal 2,6 1,8 0,00 1 A 2 f Fuel oil 382,8 0,6 0,23 1 A 2 f Fuel wood 2,0 0,9 0,00 1 A 2 f Coke 5,6 3,6 0,02 1 A 2 f 0302 Process furnaces without contact Hard coal 5 836,0 0,31 1,81 1 A 2 f Brown coal 34,0 1,8 0,06 1 A 2 f Fuel oil 681,0 0,6 0,41 1 A 2 f Fuel wood 143,6 0,9 0,13 1 A 2 f Coke 190,0 3,6 0,68 1 A 2 f 0303 Processes with contact Hard coal 2 463,0 0,31 0,76 1 A 2 f

46

Brown coal 2,0 1,8 0,00 1 A 2 f Fuel oil 173,0 0,6 0,10 1 A 2 f Fuel wood 1,3 0,9 0,00 1 A 2 f Coke 2 644,0 3,6 9,52 1 A 2 f 030301 Sinter and pelletizing plants 6770 0,065 0,44 1 A 2 a 030309 Secondary copper production 86,6 2,6 0,23 1 A 2 b 030310 Secondary aluminium production 116,9 2,6 0,30 1 A 2 b

030311 Cement* 9335,1 0,007 0,07 1 A 2 f 04. Production processes 68,9 040203 Pig iron tapping 5 440 3,6 19,58 2 C 1 040205 Open heart furnace steel plants 177,6 2,6 0,46 2 C 2 040206 Basic oxygen furnace steel plants 5822,5 2,6 15,14 2 C 2 040207 Electric furnace steel plants 2809 2,6 7,30 2 C 2 040208 Rolling mills 10161,2 2,6 26,42 2 C 2 06. Solvent and other product use 1632 060507 Electrical equipment 1,02 1600000 1632 2 G 07. Road transport 88,4

0701 Passenger cars Leaded gasoline** 84,3 106 8,94 1 A 3 b i

Unleaded gasoline** 3751,1 0,02 0,08 1 A 3 b i Diesel oil*** 551,6 0,67 0,37 1 A 3 b i

0702 Light duty vehicles < 3.5 t Leaded gasoline** 16,1 106 1,71 1 A 3 b ii Unleaded gasoline** 703 0,02 0,01 1 A 3 b ii Diesel oil*** 700,9 0,67 0,47 1 A 3 b ii

0703 Heavy duty vehicles > 3.5 t an buses Leaded gasoline** 0,2 106 0,02 1 A 3 b iii Unleaded gasoline** 7 0,02 0,00 1 A 3 b iii Diesel oil**** 3127,7 24,5 76,63 1 A 3 b iii

0704 Mopeds and motorcycles < 50cm3 Leaded gasoline** 0,5 106 0,05 1 A 3 b iv Unleaded gasoline** 20,9 0,02 0,00 1 A 3 b iv

0705 Motorcycles > 50cm3 Leaded gasoline** 0,8 106 0,08 1 A 3 b iv Unleaded gasoline** 33,9 0,02 0,00 1 A 3 b iv 09. Waste treatment and disposal 1,2

090201 Municipal waste incineration 14,2 0,2 0,00 6 C 090202 Industrial waste incineration (no APCs) 3,0 30,4 0,09 6 C 090202 Industrial waste incineration (APCs of low effectiveness) 30,3 19,3 0,58 6 C 090202 Industrial waste incineration (APCs of high effectiveness) 269,2 0,38 0,10 6 C 090207 Hospital waste incineration (installations that comply with

EU Directive) 3,3 0,39 0,00 6 C 090207 Hospital waste incineration (installations with no or poor

APCs) 20,7 20 0,41 6 C * activity figure is production of clinker in Gg, EF is in g/Gg clinker** EF has been computed based upon literature EF: 6.32 µ/km assuming average fuel consumption 8 l/100 km and gasoline density

0,74 kg/l *** EF has been computed based upon literature EF: 0.05 µ/km, assuming average fuel consumption 9 l/100 km and diesel oil

density 0,84 kg/l **** EF has been computed based upon literature EF: 5.53 µ/km, assuming average fuel consumption 26 l/100 km and diesel oil

density 0,84 kg/l

Table 8b. PCB emission in Poland in 2001 according to NFR. NFR code Emission in kg

TOTAL 2 327

47

1 A 1 a 119,881 A 1 b 0,511 A 1 c 0,551 A 2 a 0,441 A 2 b 0,531 A 2 f 14,721 A 3 b i 9,391 A 3 b ii 2,191 A 3 b iii 76,651 A 3 b iv 0,131 A 4 a 2,921 A 4 b i 394,161 A 4 c i 3,252 C 68,902 G 1 632,006 C 1,18

Table 9a. Emission factors of PAH indicators in Poland in 2001.

Emission source

BaP* [kg/Gg]

BbF* [kg/Gg]

BkF* [kg/Gg]

I_P* [kg/Gg]

01. Combustion in energy and transformation industries 0101 Public power plants Hard coal 0,00000352 0,00000732 0,00000732 0,00000703Brown coal 0,00000352 0,00000732 0,00000732 0,00000703Fuel oil 0,00468 0,00398 0,00398 0,00757 0102 District heating plants Hard coal 0,00000352 0,00000732 0,00000732 0,00000703Brown coal 0,00000352 0,00000732 0,00000732 0,00000703Fuel oil 0,00468 0,00398 0,00398 0,00757

0103 Petroleum refining plants Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,00017 0104 Solid fuel transformation plants Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,00017 0105 Coal mining, oil/ gas extraction, pipeline compressors Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,0001702. Non-industrial combustion plants 0201 Commercial and institutional plants Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,00017 0202 Residential plants

48

Hard coal 1,5 1,6 0,05 3,0Brown coal 0,845 1,15 0,525 1,11Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 2,48 3,26 1,08 1,76 0203 Plants in agriculture, forestry and aquaculture Hard coal 1,5 1,6 0,05 3,0Brown coal 0,845 1,15 0,525 1,11Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 2,48 3,26 1,08 1,7603. Combustion in manufacturing industry 0301 Combustion in boilers, gas turbines and stationery engines Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,00017 0302 Process furnaces without contact

Hard coal 0,000586 0,0234 0,0234 0,0176

Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,00017 0303 Processes with contact Hard coal 0,000586 0,0234 0,0234 0,0176Brown coal 0,000586 0,0234 0,0234 0,0176Fuel oil 0,00343 0,00181 0,00283 0,00684Fuel wood 0,000095 0,019 0,019 0,0001704. Production processes

040201 Coke oven (door leakage and extinction) 0,75 0,25 0,25 0,30040301 Aluminium production (electrolysis) 11 40,18 40,18 5,0

06. Solvent and other product use 060107 Wood preservation 0,5 0,25 0,25 0,2507. Road transport Motor gasoline 0,0107 0,00001498 0,00000642 0,0000107Diesel oil 0,297 0,0004158 0,0001782 0,00029708. Other mobile sources and machinery Motor gasoline 0,0107 0,00001498 0,00000642 0,0000107Diesel oil 0,297 0,0004158 0,0001782 0,000297* BaP -benzo(a)pyrene, BbF - benzo(b)fluoranthene, BbF - benzo(b)fluoranthene, I_P - indeno(1,2,3-cd)pyrene Table 9b. Emission of PAH indicators in Poland in 2001.

BaP* BbF* BkF* I_P* PAH NFR Emission source [kg] [kg] [kg] [kg] [kg] code

Total 46 775 50 641 14 912 51 279 163 606

01. Combustion in energy and transformation industries 5,7 41,3 42,2 37,3 126,5

0101 Public power plants Hard coal 0,147 0,306 0,306 0,293 1,05 1 A 1 a

Brown coal 0,208 0,433 0,433 0,416 1,49 1 A 1 a

Fuel oil 0,835 0,710 0,710 1,351 3,61 1 A 1 a

0102 District heating plants

Hard coal 0,004 0,008 0,008 0,007 0,03 1 A 1 a

Brown coal 0,000 0,000 0,000 0,000 0,00 1 A 1 a

Fuel oil 0,603 0,513 0,513 0,975 2,60 1 A 1 a

0103 Petroleum refining plants

49

Hard coal 0,002 0,070 0,070 0,053 0,19 1 A 1 b

Brown coal 0,000 0,000 0,000 0,000 0,00 1 A 1 b

Fuel oil 2,916 1,539 2,406 5,814 12,67 1 A 1 b

Fuel wood 0,000 0,000 0,000 0,000 0,00 1 A 1 b

0104 Solid fuel transformation plants Hard coal 0,060 2,387 2,387 1,795 6,63 1 A 1 c

Brown coal 0,000 0,000 0,000 0,000 0,00 1 A 1 c

Fuel oil 0,000 0,000 0,000 0,000 0,00 1 A 1 c

Fuel wood 0,000 0,000 0,000 0,000 0,00 1 A 1 c

0105 Coal mining, oil/ gas extraction, pipeline compressors

Hard coal 0,865 34,538 34,538 25,978 95,92 1 A 1 c

Brown coal 0,019 0,772 0,772 0,581 2,14 1 A 1 c

Fuel oil 0,017 0,009 0,014 0,034 0,07 1 A 1 c

Fuel wood 0,000 0,019 0,019 0,000 0,04 1 A 1 c

02. Non-industrial combustion plants 37856,3 45892,4 10162,8 48070,8 141982,3

0201 Commercial and institutional plants

Hard coal 3,733 149,084 149,084 112,131 414,03 1 A 4 a

Brown coal 0,022 0,894 0,894 0,672 2,48 1 A 4 a

Fuel oil 0,124 0,066 0,102 0,248 0,54 1 A 4 a

Fuel wood 0,001 0,160 0,160 0,001 0,32 1 A 4 a

0202 Residential plants Hard coal 13668,000 14579,200 455,600 27336,000 56038,80 1 A 4 b i

Brown coal 134,355 182,850 83,475 176,490 577,17 1 A 4 b i

Fuel oil 5,282 2,787 4,358 10,534 22,96 1 A 4 b i

Fuel wood 18225,520 23957,740 7936,920 12934,240 63054,42 1 A 4 b i

0203 Plants in agriculture, forestry and aquaculture

Hard coal 2551,500 2721,600 85,050 5103,000 10461,15 1 A 4 c i

Brown coal 121,680 165,600 75,600 159,840 522,72 1 A 4 c i

Fuel oil 3,879 2,047 3,201 7,736 16,86 1 A 4 c i

Fuel wood 3142,160 4130,420 1368,360 2229,920 10870,86 1 A 4 c i

03.Combustion in manufacturing industry 10,9 270,1 271,4 207,9 760,3

0301 Combustion in boilers, gas turbines and stationery engines

Hard coal 1,753 70,008 70,008 52,656 194,43 1 A 2

Brown coal 0,002 0,061 0,061 0,046 0,17 1 A 2

Fuel oil 1,313 0,693 1,083 2,618 5,71 1 A 2

Fuel wood 0,000 0,038 0,038 0,000 0,08 1 A 2

0302 Process furnaces without contact

Hard coal 3,420 136,562 136,562 102,714 379,26 1 A 2

Brown coal 0,020 0,796 0,796 0,598 2,21 1 A 2

Fuel oil 2,336 1,233 1,927 4,658 10,15 1 A 2

Fuel wood 0,014 2,728 2,728 0,024 5,49 1 A 2

0303 Processes with contact

Hard coal 1,443 57,634 57,634 43,349 160,06 1 A 2

Brown coal 0,001 0,047 0,047 0,035 0,13 1 A 2

Fuel oil 0,593 0,313 0,490 1,183 2,58 1 A 2

Fuel wood 0,000 0,025 0,025 0,000 0,05 1 A 2

04. Production processes 7316,3 4432,4 4432,4 2959,3 19140,4

040201 Coke oven (door leakage and extinction) 6715,725 2238,575 2238,575 2686,290 13879,17 1 B 1 b

040301 Aluminium production (electrolysis) 600,600 2193,828 2193,828 273,000 5261,26 2 C 3

06. Solvent and other product use 4,2 2,1 2,1 2,1 10,6

060107 Wood preservation 4,227 2,114 2,114 2,114 10,57 3 A

50

07. Road transport 1350,3 1,9 0,8 1,4 1354,4 0701 Passenger cars

Motor gasoline 41,039 0,057 0,025 0,041 41,16 1 A 3 b i

Diesel oil 163,825 0,229 0,098 0,164 164,32 1 A 3 b i 0702 Light duty vehicles < 3.5 t

Motor gasoline 7,694 0,011 0,005 0,008 7,72 1 A 3 b ii

Diesel oil 208,167 0,291 0,125 0,208 208,79 1 A 3 b ii0703 Heavy duty vehicles > 3.5 t and buses

Motor gasoline 0,077 0,000 0,000 0,000 0,08 1 A 3 b iii

Diesel oil 928,927 1,300 0,557 0,929 931,71 1 A 3 b iii0704 Mopeds and motorcycles < 50cm3

Motor gasoline 0,229 0,000 0,000 0,000 0,23 1 A 3 b iv0705 Motorcycles > 50cm3

Motor gasoline 0,371 0,001 0,000 0,000 0,37 1 A 3 b iv08. Other mobile sources and machinery 231,2 0,3 0,1 0,2 231,9

0802 Railways 080201 Shunting locs

Diesel oil 22,631 0,032 0,014 0,023 22,70 1 A 3 c 0803 Inland waterways

Diesel oil 3,237 0,005 0,002 0,003 3,25 1 A 3 d ii080402 National sea traffic

Diesel oil 4,158 0,006 0,002 0,004 4,17 1 A 3 d ii080403 National fishing

Diesel oil 6,475 0,009 0,004 0,006 6,49 1 A 4 c iii0806 Agriculture

Diesel oil 178,259 0,250 0,107 0,178 178,79 1 A 4 c ii 0808 Industry

Diesel oil 9,474 0,013 0,006 0,009 9,50 1 A 2 0810 Other off-road

Leaded gasoline 0,120 0,000 0,000 0,000 0,12 1 A 3 e iiDiesel oil 6,861 0,010 0,004 0,007 6,88 1 A 3 e ii* BaP -benzo(a)pyrene, BbF - benzo(b)fluoranthene, BbF - benzo(b)fluoranthene, I_P - indeno(1,2,3-cd)pyrene Table 9c. Emission of PAH indicators in Poland in 2001 according to NFR.

Emission NFR BaP* BbF* BkF* I_P* PAH code [kg] [kg] [kg] [kg] [kg]

TOTAL 46 775 50 641 14 912 51 279 163 606 1 A 1 a 1,80 1,97 1,97 3,04 8,78 1 A 1 b 2,92 1,61 2,48 5,87 12,87 1 A 1 c 0,96 37,73 37,73 28,39 104,81 1 A 2 20,37 270,15 271,40 207,89 769,82 1 A 3 b i 204,86 0,29 0,12 0,20 205,48 1 A 3 b ii 215,86 0,30 0,13 0,22 216,51 1 A 3 b iii 929,00 1,30 0,56 0,93 931,79 1 A 3 b iv 0,60 0,00 0,00 0,00 0,60 1 A 3 c 22,63 0,03 0,01 0,02 22,70 1 A 3 d ii 7,40 0,01 0,00 0,01 7,42 1 A 3 e ii 6,98 0,01 0,00 0,01 7,00 1 A 4 a 3,88 150,20 150,24 113,05 417,38 1 A 4 b i 32033,16 38722,58 8480,35 40457,26 119693,35

51

1 A 4 c i 5819,22 7019,67 1532,21 7500,50 21871,59 1 A 4 c ii 178,26 0,25 0,11 0,18 178,79 1 A 4 c iii 6,47 0,01 0,00 0,01 6,49 1 B 1 b 6715,73 2238,58 2238,58 2686,29 13879,17 2 C 600,60 2193,83 2193,83 273,00 5261,26 3 A 4,23 2,11 2,11 2,11 10,57

52

APPENDIX

53

Tab

le 1

-(T

). N

atio

nal a

nnua

l em

issi

ons 1

980-

2001

Pa

rty:

Pol

and

S

ecto

r: A

ll se

ctor

s

19

80

1981

19

82

1983

19

84

1985

19

86

1987

19

88

1989

19

90

1991

19

92

1993

19

94

1995

19

96

1997

19

98

1999

20

00

2001

SOx(

as S

O2)

41

00

4300

42

00

4200

41

80

3910

32

10

2995

28

20

2725

26

05

2376

23

68

2181

18

97

1719

15

11

1564

NO

x(as

NO

2) 12

29

1500

15

10

1530

15

50

1480

12

80

1205

11

30

1120

11

05

1120

11

54

1114

99

1 95

1 83

8 80

5

NH

3 55

0

55

0 55

0 55

0 55

0 55

0 50

8 45

0 44

7 38

2 38

4 38

0 36

4 35

0 37

1 34

1 32

2 32

8

NM

VO

C

1036

91

2 88

9 95

4 98

5 10

11

1029

10

14

1026

10

16

831

833

805

756

819

769

766

774

730

731

599

873*

CO

74

06

70

83

8655

51

15

4547

48

37

4700

43

01

4363

34

63

3528

TSP

4639

23

4913

61

PM10

28

1885

30

3150

PM2.

5

13

5317

14

2071

SO2,

NO

2, N

MV

OC

s, N

H3 an

d C

O in

Gig

a gr

ams p

er y

ear;

PMs i

n M

ega

gram

s per

yea

r.

*inc

lude

s 297

Gg

from

cat

egor

y SN

AP

11

54

Tab

le 2

-(T

). N

atio

nal

annu

al e

mis

sion

s of h

eavy

met

als 1

990-

2001

Pa

rty:

Pol

and

S

ecto

r: A

ll se

ctor

s

19

90

1991

19

92

1993

19

94

1995

19

96

1997

19

98

1999

20

00

2001

Lead

(Pb)

13

71.7

13

35.6

98

6.0

996.

9 96

6.1

936.

6 95

9.7

895.

8 73

6 74

5 64

7.5

609,

8

Cad

miu

m (C

d)

91

.6

85.0

84

.1

91.9

85

.8

82.6

91

.2

85.8

55

.4

61.7

50

.4

52,5

Mer

cury

(Hg)

33.3

32

.7

31.9

32

.5

32.4

32

.3

33.6

33

.0

29.5

27

.1

25.6

23

,2

Ars

enic

(As)

82.1

79

.8

78.9

82

.4

76.2

73

.4

75.6

71

.0

54.3

58.8

50

.4

52,6

Chr

omiu

m (C

r)

154.

6 13

3.5

121.

6 12

7.8

120.

0 11

8.3

117.

0 11

6.0

89.8

89.8

84

.3

64,1

Cop

per (

Cu)

599.

4 53

0.4

497.

3 51

1.0

478.

3 46

4.9

494.

8 47

5.1

388.

7

420.

9 37

4.5

394,

3

Nic

kel (

Ni)

370.

0 35

4.8

349.

8 35

2.9

322.

5 31

2.3

328.

3 36

4.9

251.

3 25

9.8

251.

4 28

7,3

Sele

nium

(Se)

Zinc

(Zn)

30

91.5

27

80.9

26

77.5

28

29.9

26

23.7

25

80.2

27

49.0

25

79.6

21

91.4

23

77.1

21

73

1709

U

nits

: Meg

a gr

ams p

er y

ear.

55

Tab

le 3

-(T

). N

atio

nal a

nnua

l em

issi

ons o

f per

sist

ent o

rgan

ic p

ollu

tant

s 199

0-20

01

Part

y: P

olan

d

Sect

or: A

ll se

ctor

s A

NN

EX I1/

19

90

1991

19

92

1993

19

94

1995

19

96

1997

19

98

1999

20

00

2001

Ald

rin (C

AS:

309

-00-

2)

Chl

orda

ne (C

AS:

57-

74-9

)

Chl

orde

cone

(CA

S: 1

43-5

0-0)

D

ield

rin (C

AS:

60-

57-1

)

En

drin

(CA

S: 7

2-20

-8)

Hep

tach

lor (

CA

S: 7

6-44

-8)

H

exab

rom

obip

heny

l (C

AS:

363

55-0

1-8)

Mire

x (C

AS:

238

5-85

-5)

Toxa

phen

e (C

AS:

800

1-35

-2)

AN

NEX

II2/

H

exac

hlor

ocyc

lohe

xane

(HC

H) (

CA

S: 6

08-7

3-1)

D

DT

(CA

S:50

-29-

3)**

*

Poly

chlo

rinat

ed b

iphe

nyls

(PC

Bs)

****

2425

23

67

2322

23

48

2330

23

23

2348

23

42

2353

23

31

2265

23

27

AN

NEX

III3/

D

ioxi

ns &

Fur

ans

529,

1 53

5,4

517,

1 59

1,8

519,

5 51

4,5

484,

2 43

9,5

381,

3 38

1,1

333,

4 44

7,5

Poly

arom

atic

hyd

roca

rbon

s (PA

Hs)

*

159,

2 17

4,3

171,

7 25

3,2

231,

4 23

7,3

224,

9 19

5,2

176,

2 17

5,9

167,

3 16

3,6

Hex

achl

orob

enze

ne (H

CB

)**

(CA

S: 1

18-7

4-1)

62,1

38

,6

39,1

42

,5

38,1

50

,7

48,0

51

,1

43,2

39

,5

46,3

8,

4

OTH

ER4/

Pe

ntac

hlor

ophe

nol (

PCP)

(CA

S: 8

7-86

-5)

Sh

ort c

hain

ed c

hlor

inat

ed p

araf

fins (

CA

S: 8

5535

-84-

8)

U

nits

in k

g pe

r yea

r exc

ept f

or d

ioxi

ns a

nd fu

rans

, whi

ch a

re re

porte

d in

gra

ms t

oxic

equ

ival

ents

(g I-

Teq)

per

yea

r (as

def

ined

by

NA

TO C

CM

S in

tern

atio

nal t

oxic

equ

ival

ent s

chem

e). F

or P

AH

s, un

its M

ega

gram

s per

yea

r. Pl

ease

lis

t PA

Hs a

nd so

urce

s inc

lude

d in

this

inve

ntor

y. A

ll ai

r em

issi

ons s

houl

d be

repo

rted

in th

is ta

ble

(e.g

. HC

B c

an b

e us

ed a

s pes

ticid

e bu

t can

als

o be

em

itted

as a

byp

rodu

ct o

f com

bust

ion

and

as a

con

tam

inan

t in

othe

r pes

ticid

es).

Not

es:

1 / T

he P

OPs

list

ed in

ann

ex I

to th

e Pr

otoc

ol o

n PO

Ps a

re su

bsta

nces

sche

dule

d fo

r elim

inat

ion.

2/

The

PO

Ps li

sted

in a

nnex

II to

the

Prot

ocol

on

POPs

are

subs

tanc

es sc

hedu

led

for r

estri

ctio

n us

e.

**

* D

DT

is a

lso

liste

d in

ann

ex I.

****

PC

Bs a

re a

lso

liste

d in

ann

ex I.

3/

The

PO

Ps li

sted

in a

nnex

III t

o th

e Pr

otoc

ol o

n PO

Ps a

re su

bsta

nces

refe

rred

to in

arti

cle

3, p

ara.

5 (a

), of

the

Prot

ocol

.

* Po

lycy

clic

aro

mat

ic h

ydro

carb

ons (

PAH

s): F

or th

e pu

rpos

es o

f the

em

issi

on in

vent

orie

s, th

e fo

llow

ing

four

indi

cato

r com

poun

ds sh

all b

e us

ed: b

enzo

(a)p

yren

e, b

enzo

(b)f

luor

anth

ene,

ben

zo(k

)flu

oran

then

e an

d

inde

no(1

,2,3

-cd)

pyre

ne

**

H

CB

is a

lso

incl

uded

in a

nnex

I to

the

Prot

ocol

as a

subs

tanc

e sc

hedu

led

for e

limin

atio

n.

4/ S

ee a

rticl

e 8

of th

e Pr

otoc

ol (R

esea

rch,

dev

elop

men

t and

mon

itorin

g; re

porti

ng v

olun

tary

).

56

TA

BL

E IV

1A

: N

atio

nal s

ecto

r em

issi

ons:

Mai

n po

lluta

nts,

part

icul

ate

mat

ter

and

heav

y m

etal

s

Ver

sion

200

2-1

CO

UN

TR

Y:

PL(a

s IS

O2

code

)

DA

TE:

31.0

3.2

003

(as

DD

.MM

.YYY

Y)

YEA

R:

2001

(as

YYYY

, yea

r of

Emm

issi

ons)

Th

ese

five

yello

w li

nes w

ill n

ot b

e re

ad b

y U

NEC

E! T

hese

line

s can

be

mod

ified

free

ly fo

r you

r ow

n re

fere

nce

purp

oses

. Fo

otno

tes t

o th

e em

issi

on fi

gure

s rep

orte

d sh

ould

be

subm

itted

toge

ther

with

the

emis

sion

dat

a, b

ut in

a se

para

te d

ocum

ent.

Plea

se fi

ll ou

t the

blu

e m

arke

d fie

lds.

You

may

use

the

aggr

egat

ion

leve

ls in

stea

d of

the

gray

mar

ked

field

s in

aggr

egat

ion.

Y

ou m

ust u

se fo

r eac

h fie

ld e

ither

a n

umbe

r or o

ne o

f the

follo

win

g co

des (

capi

tals

, no

dots

in b

etw

een,

see

EB.A

IR/G

E.1/

2002

/2):

NO

, N

A ,

NE

, IE

, C

Foot

note

s or a

ny o

ther

info

rmat

ion

ente

red

into

this

tabl

e w

ill n

ot b

e ta

ken

into

acc

ount

.

N

FR

sect

ors t

o be

repo

rted

to

CLR

TAP

Ye

arly

min

imum

repo

rtin

g

Add

ition

al re

port

ing

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

NO

x C

O

NM

VO

CSO

x N

H3

TSP

PM10

PM

2.5

Pb

Cd

Hg

A

s C

r C

u N

i Se

Zn

A = Allowable Aggregation

Gg

NO

2 G

g G

g G

g SO

2G

g M

g M

g M

g M

g M

g M

g

Mg

Mg

Mg

Mg

Mg

Mg

1 A

1 a

(a

) 1

A 1

a P

ublic

El

ectri

city

and

Hea

t Pr

oduc

tion

24

9,80

6637

,985

511

,421

785,

7NA

58

879,

729

7706

8104

,419

,416

1,00

89,

855

4,

635

5,68

915

,352

14,5

37N

E 53

,454

1

A 1

b

(a)

1 A

1 b

Pet

role

um

refin

ing

9,

234

1,5

0,20

727

,2N

A

1612

,590

5,4

550,

51,

066

0,84

40,

001

0,

843

1,01

92,

393

22,9

46N

E 0,

896

1 A

1 c

(a

) 1

A 1

c

Man

ufac

ture

of

Solid

Fue

ls a

nd

Oth

er E

nerg

y In

dust

ries

5,

488

10,5

0,92

710

,6N

A

6008

,530

82,3

868

7,04

91,

123

0,33

2

0,71

40,

923,

954

3,66

3NE

28,5

95

1 A

2

(a

) 1

A 2

M

anuf

actu

ring

In

dust

ries

and

C

onst

ruct

ion

A

11

8,02

7817

,971

7,09

832

7,6N

A

5622

5,7

3422

3,7

1796

7,8

285,

698

12,5

728,

2657

23

,235

13,5

224

1,16

266

,254

NE

738,

111

57

1 A

2 a

(a

) 1

A 2

a Ir

on a

nd

Stee

l

0,

203

0,86

17N

A

NA

N

A

6602

,529

62,4

2069

,2N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

1 A

2 b

(a

) 1

A 2

b N

on-f

erro

us

Met

als

0,

3056

0,09

37N

A

NA

N

A

946,

271

6,2

513,

521

2,33

32,

181

0,13

576

17

,094

020

6,38

10N

E 49

7,34

6 1

A 2

c

(a)

1 A

2 c

Che

mic

als

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 2

d

(a)

1 A

2 d

Pul

p, P

aper

an

d Pr

int

0,

0176

0,00

72N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

1 A

2 e

(a

) 1

A 2

e F

ood

Proc

essi

ng,

Bev

erag

es a

nd

Toba

cco

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 2

f

(a)

1 A

2 f

Oth

er

(Ple

ase

spec

ify in

a

cove

ring

note

)

11

7,50

1617

,007

NA

N

A

NA

48

677

3054

5,1

1538

5,1

73,3

6510

,391

8,13

6,

141

13,5

234

,781

66,2

54N

E 24

0,76

5 1

A 3

a ii

(i)

1 A

3 a

ii C

ivil

Avi

atio

n (D

omes

tic,

LTO

)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 3

a ii

(ii

)

1 A

3 a

ii C

ivil

Avi

atio

n (D

omes

tic,

Cru

ise)

4,

2606

4,87

0,33

7NA

N

A

0,1

0,1

0,1N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

1 A

3 b

(a

) 1

A 3

b R

oad

Tra

nspo

rtat

ion

A

24

4,57

7165

9,88

6513

5,56

835

,5N

A

5546

7,1

2043

0,4

1872

4,4

19,8

570,

219

0

02,

309

2,69

94,

499N

E 0

Not

e 1:

Mai

n Po

lluta

nts s

houl

d co

ver t

he ti

mes

pan

from

19

80 to

late

st y

ear.

H

M sh

ould

cov

er th

e tim

espa

n fr

om 1

990

to la

test

yea

r.

PM sh

ould

cov

er th

e tim

espa

n fr

om 2

000

to la

test

yea

r.

Not

e 2:

The

A=A

llow

able

Agg

rega

tion

illus

trate

s the

leve

l of a

ggre

gatio

n th

at c

an b

e us

ed if

mor

e de

taile

d in

form

atio

n is

not

ava

ilabl

e. G

rey

cells

show

whi

ch se

ctor

s can

be

aggr

egat

ed in

to th

e se

ctor

m

arke

d A

. Bla

ck c

ells

occ

ur w

hen

two

poss

ible

leve

ls o

f agg

rega

tion

are

poss

ible

.

N

FR

sect

ors t

o be

repo

rted

to

CLR

TAP

Ye

arly

min

imum

repo

rtin

g

Add

ition

al re

port

ing

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

NO

x C

O

NM

VO

CSO

x N

H3

TSP

PM10

PM

2.5

Pb

Cd

Hg

A

s C

r C

u N

i Se

Zn

A = Allowable Aggregation

Gg

NO

2 G

g G

g G

g SO

2G

g M

g M

g M

g M

g M

g M

g

Mg

Mg

Mg

Mg

Mg

Mg

1 A

3 b

i

1

A 3

b i

R

.T.,

Pass

enge

r car

s

76

,187

544

5,68

3272

,484

11N

A

1984

,419

84,4

1984

,4IE

IE

N

A

IE

IE

IE

IE

N

E IE

58

1 A

3 b

ii

1 A

3 b

ii

R.T

., Li

ght d

uty

vehi

cles

24

,979

396

,702

118

,121

5,6N

A

1959

,619

59,6

1959

,6IE

IE

N

A

IE

IE

IE

IE

N

E IE

1

A 3

b

iii

1

A 3

b ii

i R

.T.,

Hea

vy d

uty

vehi

cles

14

3,10

7789

,289

229

,145

18,8

NA

13

740,

813

740,

813

740,

8IE

IE

NA

IE

IE

IE

IE

NE

IE

1 A

3 b

iv

1 A

3 b

iv

R.T

., M

oped

s &

Mot

orcy

cles

0,

3026

28,2

1215

,818

0,1N

A

0,6

0,6

0,6I

E IE

N

A

IE

IE

IE

IE

N

E IE

1

A 3

b

v

1

A 3

b v

R

.T.,

Gas

olin

e ev

apor

atio

n

NA

N

A

NA

N

A

NA

N

A

NA

N

A

IE

IE

NA

IE

IE

IE

IE

NE

IE

1 A

3 b

vi

1 A

3 b

vi

R.T

., A

utom

obile

tyre

an

d br

ake

wea

r

NA

N

A

NA

N

A

NA

37

781,

727

4510

39IE

IE

N

A

IE

IE

IE

IE

N

E IE

1

A 3

b

vii

1

A 3

b v

ii R

.T.,

Aut

omob

ile ro

ad

abra

sion

NA

N

A

NA

N

A

NA

N

A

NA

N

A

IE

IE

NA

IE

IE

IE

IE

NE

IE

1 A

3 c

(a)

1

A 3

c R

ailw

ays

4,

1148

2,24

790,

968

0,5N

A

358,

135

8,1

358,

1NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 3

d

ii

1 A

3 d

ii N

atio

nal

Nav

igat

ion

1,

4062

0,43

360,

138

0,2N

A

107,

210

7,2

107,

2NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 3

e (

a)

1 A

3 e

Oth

er

(Ple

ase

spec

ify in

a

cove

ring

not

e)

A

1,

914

1,27

6NA

0,

4NA

28

3,5

283,

528

3,5

1,52

20,

037

0

00,

177

0,32

90,

548N

E 0

1 A

3 e

i

1

A 3

e i

Pip

elin

e co

mpr

esso

rs

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 3

e

ii

1 A

3 e

ii O

ther

m

obile

sour

ces a

nd

mac

hine

ry

1,

914

1,27

6NA

0,

4NA

28

3,5

283,

528

3,5

1,52

20,

037

0

00,

177

0,32

90,

548N

E 0

1 A

4 a

(a)

1

A 4

a C

omm

erci

al

/ Ins

titut

iona

l

22

,851

717

,704

42,

898

95,8

NA

20

293,

710

148,

824

76,1

47,1

947,

439

1,14

3

4,85

36,

153

27,1

9324

,322

NE

188,

798

1 A

4 b

(a)

1

A 4

b R

esid

entia

lA

79

,927

615

84,0

25 599

,361

203,

6NA

14

9916

,411

6647

,853

424,

911

9,70

821

,388

0,98

9

14,0

7217

,371

74,1

5310

2,69

4NE

475,

39

1 A

4 b

i

1 A

4 b

i

Res

iden

tial p

lant

s

78

,558

115

77,7

46 994

,527

203,

6NA

14

9916

,411

6647

,853

424,

911

9,70

821

,388

0,98

9

14,0

7217

,371

74,1

5310

2,69

4NE

475,

39

1 A

4 b

ii

1 A

4 b

ii

Hou

seho

ld a

nd

gard

enin

g (m

obile

)

1,

3695

6,27

864,

834N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

N

ote

1: M

ain

Pollu

tant

s sho

uld

cove

r the

tim

espa

n fr

om

1980

to la

test

yea

r.

HM

shou

ld c

over

the

times

pan

from

199

0 to

late

st y

ear.

59

PM sh

ould

cov

er th

e tim

espa

n fr

om 2

000

to la

test

yea

r.

Not

e 2:

The

A=A

llow

able

Agg

rega

tion

illus

trate

s the

leve

l of a

ggre

gatio

n th

at c

an b

e us

ed if

mor

e de

taile

d in

form

atio

n is

not

ava

ilabl

e. G

rey

cells

show

whi

ch se

ctor

s can

be

aggr

egat

ed in

to th

e se

ctor

m

arke

d A

. Bla

ck c

ells

occ

ur w

hen

two

poss

ible

leve

ls o

f agg

rega

tion

are

poss

ible

.

N

FR

sect

ors t

o be

repo

rted

to

CLR

TAP

Ye

arly

min

imum

repo

rtin

g

Add

ition

al re

port

ing

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

NO

x C

O

NM

VO

CSO

x N

H3

TSP

PM10

PM

2.5

Pb

Cd

Hg

A

s C

r C

u N

i Se

Zn

A = Allowable

Aggregation G

g N

O2

Gg

Gg

Gg

SO2

Gg

Mg

Mg

Mg

Mg

Mg

Mg

M

g M

g M

g M

g M

g M

g 1

A 4

c

(a)

1 A

4 c

Agr

icul

ture

/ F

ores

try

/ Fis

hing

A

48

,938

529

5,75

3621

,498

47,4

NA

29

505,

623

809,

613

462,

520

,116

5,04

70,

157

3,

269

3,95

514

,498

41,4

65N

E 76

,433

1

A 4

c i

1

A 4

c i

Stat

iona

ry

15

,812

626

7,73

6416

,416

43,4

NA

26

297,

420

601,

410

254,

320

,116

5,04

70,

157

3,

269

3,95

514

,498

41,4

65N

E 76

,433

1

A 4

c

ii

1

A 4

c ii

Off

-roa

d V

ehic

les a

nd O

ther

M

achi

nery

31

,852

827

,842

85,

082

3,6N

A

3121

3121

3121

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1A

4 c

iii

1A 4

c ii

i Nat

iona

l Fi

shin

g

1,

2731

0,17

44N

A

0,4N

A

87,2

87,2

87,2

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 5

a

(a)

1 A

5 a

Oth

er,

Stat

iona

ry (i

nclu

ding

M

ilita

ry)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

A 5

b

(a)

1 A

5 b

Oth

er,

Mob

ile (I

nclu

ding

m

ilita

ry)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1B

1 (a

) 1B

1 Fu

gitiv

e E

mis

sion

s fro

m

Solid

Fue

ls

A

NA

N

A

14,8

76N

A

NA

39

144,

318

555,

125

75,5

1,97

0,44

80,

269

0,

179

1,52

20,

806

0,58

2NE

1,97

1

B 1

a

(a)

1 B

1 a

Coa

l Min

ing

and

Han

dlin

g

NA

N

A

10,3

99N

A

NA

37

353,

416

764,

216

80,1

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 1

b

(a)

1 B

1 b

Sol

id fu

el

trans

form

atio

n

NA

N

A

4,47

7NA

N

A

1790

,917

90,9

895,

41,

970,

448

0,26

9

0,17

91,

522

0,80

60,

582N

E 1,

97

1 B

1 c

(a

) 1

B 1

c O

ther

(Ple

ase

spec

ify in

a c

over

ing

note

)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 2

(a

) 1

B 2

Oil

and

natu

ral g

as

A

NA

N

A

43,4

07N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

60

1 B

2 a

(a

) 1

B 2

a O

il A

NA

N

A

36,5

19N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 2

a i

(a)

1 B

2 a

i E

xplo

ratio

n Pr

oduc

tion,

Tr

ansp

ort

NA

N

A

2,59

2NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

1 B

2 a

iv

(a

) 1

B 2

a iv

Ref

inin

g /

Stor

age

NA

N

A

16,3

02N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 2

a v

(a)

1 B

2 a

v

Dis

tribu

tion

of o

il pr

oduc

ts

NA

N

A

17,6

25N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 2

a

vi

(a)

1 B

2 a

vi O

ther

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

1

B 2

b

(a)

1 B

2 b

Nat

ural

gas

NA

N

A

6,88

8NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

1 B

2 c

(a

) 1

B 2

c V

entin

g an

d fla

ring

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

N

ote

1: M

ain

Pollu

tant

s sho

uld

cove

r the

tim

espa

n fr

om 1

980

to la

test

yea

r.

H

M sh

ould

cov

er th

e tim

espa

n fr

om 1

990

to

late

st y

ear.

PM

shou

ld c

over

the

times

pan

from

200

0 to

la

test

yea

r.

Not

e 2:

The

A=A

llow

able

Agg

rega

tion

illus

trate

s the

leve

l of a

ggre

gatio

n th

at c

an b

e us

ed if

mor

e de

taile

d in

form

atio

n is

not

ava

ilabl

e. G

rey

cells

show

whi

ch se

ctor

s can

be

aggr

egat

ed

into

the

sect

or m

arke

d A

. Bla

ck c

ells

occ

ur w

hen

two

poss

ible

leve

ls o

f agg

rega

tion

are

poss

ible

.

N

FR

sect

ors t

o be

repo

rted

to

CLR

TAP

Ye

arly

min

imum

repo

rtin

g

Add

ition

al re

port

ing

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

N

Ox

C

O

NM

VO

CSO

x

NH

3 TS

P PM

10

PM2.

5 Pb

C

d H

g

As

Cr

Cu

Ni

Se

Zn

A = Allowable Aggregation G

g N

O2

Gg

Gg

Gg

SO2

Gg

Mg

Mg

Mg

Mg

Mg

Mg

M

g M

g M

g M

g M

g M

g 2

A

(a)

2 A

MIN

ER

AL

PR

OD

UC

TS

(b)

A

0,

7589

16,5

997

3,69

2NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 A

1

(a)

2 A

1 C

emen

t Pr

oduc

tion

0,

0191

0,00

67N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 A

2

(a)

2 A

2 L

ime

Prod

uctio

n

0,

7398

16,5

93N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 A

3

(a)

2 A

3 L

imes

tone

an

d D

olom

ite U

se

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

61

2 A

4

(a)

2 A

4 S

oda

Ash

Pr

oduc

tion

and

use

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

A 5

(a

) 2

A 5

Asp

halt

Roo

fing

NA

N

A

3,69

2NA

N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 A

6

(a)

2 A

6 R

oad

Pavi

ng

with

Asp

halt

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

A 7

(a

) 2

A 7

Oth

er

incl

udin

g N

on F

uel

Min

ing

&

Con

stru

ctio

n (P

leas

e sp

ecify

in a

co

verin

g no

te)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

B

(a)

2 B

CH

EM

ICA

L

IND

UST

RY

A

11

,240

50,

935

17,8

9615

,23,

244

13,9

3522

,426

38,5

00,

209

0,98

0

00

0NE

0 2

B 1

(a

) 2

B 1

Am

mon

ia

Prod

uctio

n

NA

N

A

5,72

9NA

3,

2NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 B

2

(a)

2 B

2 N

itric

Aci

d Pr

oduc

tion

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

B 3

(a

) 2

B 3

Adi

pic

Aci

d Pr

oduc

tion

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

B 4

(a

) 2

B 4

Car

bide

Pr

oduc

tion

0,

480,

0081

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

B 5

(a

) 2

B 5

Oth

er (P

leas

e sp

ecify

in a

co

verin

g no

te)

10

,760

50,

9269

12,1

6715

,2N

A

4413

,935

22,4

2638

,50

0,20

90,

98

00

00N

E 0

2 C

(a

) 2

C M

ETA

L PR

OD

UC

TIO

N

2,

7796

3,37

243,

984

14,5

NA

96

63,0

7762

,850

88,8

79,1

451,

566

0,57

4

0,77

211

,408

13,1

715,

738N

E 14

1,29

2 2

D

(a)

2 D

OTH

ER

PRO

DU

CTI

ON

(b)

A

0,

0569

0,23

811

,026

0,1N

A

NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

2 D

1

(a)

2 D

1 P

ulp

and

Pape

r

0,

0569

0,23

81,

34N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

D 2

(a

) 2

D 2

Foo

d an

d D

rink

NA

N

A

9,68

60,

1NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

2

G

(a)

2 G

OTH

ER (P

leas

e sp

ecify

in a

co

verin

g no

te)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

62

Not

e 1:

Mai

n Po

lluta

nts s

houl

d co

ver t

he ti

mes

pan

from

19

80 to

late

st y

ear.

H

M sh

ould

cov

er th

e tim

espa

n fr

om 1

990

to la

test

yea

r.

PM sh

ould

cov

er th

e tim

espa

n fr

om 2

000

to la

test

yea

r.

Not

e 2:

The

A=A

llow

able

Agg

rega

tion

illus

trate

s the

leve

l of a

ggre

gatio

n th

at c

an b

e us

ed if

mor

e de

taile

d in

form

atio

n is

not

ava

ilabl

e. G

rey

cells

show

whi

ch se

ctor

s can

be

aggr

egat

ed in

to th

e se

ctor

m

arke

d A

. Bla

ck c

ells

occ

ur w

hen

two

poss

ible

leve

ls o

f agg

rega

tion

are

poss

ible

.

N

FR

sect

ors t

o be

repo

rted

to

CLR

TAP

Ye

arly

min

imum

repo

rtin

g

Add

ition

al re

port

ing

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

N

Ox

C

O

NM

VO

CSO

x

NH

3 TS

P PM

10

PM2.

5 Pb

C

d H

g

As

Cr

Cu

Ni

Se

Zn

A = Allowable Aggregation G

g N

O2

Gg

Gg

Gg

SO2

Gg

Mg

Mg

Mg

Mg

Mg

Mg

M

g M

g M

g M

g M

g M

g 3

A

(a)

3 A

PA

INT

APP

LIC

ATI

ON

NA

N

A

79,5

81N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

3

B

(a)

3 B

DEG

REA

SIN

G

AN

D D

RY

C

LEA

NIN

G

NA

N

A

17,5

05N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

3

C

(a)

3 C

CH

EMIC

AL

PRO

DU

CTS

, M

AN

UFA

CTU

RE

AN

D

PRO

CES

SIN

G

NA

N

A

14,7

59N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

3

D

(a)

3 D

OTH

ER

incl

udin

g pr

oduc

ts

cont

aini

ng H

Ms a

nd

POPs

(Ple

ase

spec

ify in

a

cove

ring

note

)

NA

N

A

52,8

22N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B

(a)

4 B

MA

NU

RE

M

AN

AG

EM

EN

T

(c)

A

NA

N

A

NA

N

A

229,

5323

524,

410

589,

127

3,1N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

4 B

1

(a)

4 B

1 C

attle

NA

N

A

NA

N

A

IE

IE

IE

IE

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 1

a

(a)

4 B

1 a

Dai

ry

NA

N

A

NA

N

A

83,5

426

68,4

1202

26,7

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 1

b (

a)

4 B

1 b

Non

-Dai

ry

NA

N

A

NA

N

A

34,1

124

23,4

1091

,624

,2N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

4 B

2

(a)

4 B

2 B

uffa

lo

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

63

4 B

3

(a)

4 B

3 S

heep

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 4

(a

) 4

B 4

Goa

ts

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 5

(a

) 4

B 5

Cam

els a

nd

Llam

as

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 6

(a

) 4

B 6

Hor

ses

NA

N

A

NA

N

A

6,83

473,

421

2,9

4,7N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

4 B

7

(a)

4 B

7 M

ules

and

A

sses

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 8

(a

) 4

B 8

Sw

ine

NA

N

A

NA

N

A

87,8

914

830

6671

148,

3NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

B 9

(a

) 4

B 9

Pou

ltry

NA

N

A

NA

N

A

17,1

631

29,2

1411

,669

,2N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

4 B

13

(a)

4 B

13

Oth

er

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

C

(a)

4 C

RIC

E C

ULT

IVA

TIO

N

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NO

NO

N

O

NO

N

O

NO

N

O

Not

e 1:

Mai

n Po

lluta

nts s

houl

d co

ver t

he ti

mes

pan

from

19

80 to

late

st y

ear.

H

M sh

ould

cov

er th

e tim

espa

n fr

om 1

990

to la

test

yea

r.

PM

shou

ld c

over

the

times

pan

from

200

0 to

late

st y

ear.

N

ote

2: T

he A

=Allo

wab

le A

ggre

gatio

n ill

ustra

tes t

he le

vel o

f agg

rega

tion

that

can

be

used

if m

ore

deta

iled

info

rmat

ion

is n

ot a

vaila

ble.

Gre

y ce

lls sh

ow w

hich

sect

ors c

an b

e ag

greg

ated

into

the

sect

or

mar

ked

A. B

lack

cel

ls o

ccur

whe

n tw

o po

ssib

le le

vels

of a

ggre

gatio

n ar

e po

ssib

le.

NF

R se

ctor

s to

be re

port

ed to

C

LRTA

P

Year

ly m

inim

um re

port

ing

A

dditi

onal

repo

rtin

g

Mai

n Po

lluta

nts

Parti

cula

te m

atte

r Pr

iorit

y m

etal

s

Oth

er m

etal

s

N

Ox

C

O

NM

VO

CSO

x

NH

3 TS

P PM

10

PM2.

5 Pb

C

d H

g

As

Cr

Cu

Ni

Se

Zn

A = Allowable Aggregation G

g N

O2

Gg

Gg

Gg

SO2

Gg

Mg

Mg

Mg

Mg

Mg

Mg

M

g M

g M

g M

g M

g M

g 4

D

(a)

4 D

A

GR

ICU

LT

UR

AL

SO

ILS

A

NA

N

A

33,6

5NA

87

,71N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

64

4 D

1

(a)

4 D

1 D

irect

Soi

l Em

issi

on

NA

N

A

33,6

5NA

87

,71N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

F

(a)

4 F

FIEL

D

BU

RN

ING

OF

AG

RIC

ULT

UR

AL

WA

STES

NA

N

A

0,33

9NA

N

A

574,

640

3,4

344,

7NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

4

G

(a)

4 G

OTH

ER (d

)

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

5

B

(a)

5 B

FO

RES

T A

ND

G

RA

SSLA

ND

C

ON

VER

SIO

N

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

6

A

(a)

6 A

SO

LID

W

AST

E D

ISPO

SAL

ON

LA

ND

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

6

B

(a)

6 B

WA

STE-

WA

TER

H

AN

DLI

NG

NA

N

A

NA

N

A

8NA

N

A

NA

N

A

NA

N

A

N

A

NA

N

A

NA

N

E N

A

6 C

(a

) 6

C W

AST

E IN

CIN

ERA

TIO

N

(e)

NA

87

2,60

052,

57N

A

NA

31

907,

619

314,

311

582,

67,

039

0,60

30,

603

0,

010,

060,

603

0,02

NE

4,22

3 6

D

(a)

6 D

OTH

ER

WA

STE

(f)

NA

N

A

NA

N

A

NA

34

75,4

3300

,532

40,5

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

7 (

a)

7 O

THER

NA

N

A

296,

857N

A

NA

N

A

NA

N

A

NA

N

A

NA

NA

N

A

NA

N

A

NE

NA

Nat

iona

l Tot

al

80

5,38

3527

,90

873,

3915

6432

8,43

4913

61,3

3031

50,5

1420

71,3

609,

852

,523

,2

52,6

64,1

394,

328

7,3N

E

1709

,2

Mem

o It

ems

1 A

3 a

i (

i)

(a)

Inte

rnat

iona

l A

viat

ion

(LTO

)

1 A

3 a

i (

ii)

(a)

Inte

rnat

iona

l A

viat

ion

(Cru

ise)

1 A

3 d

i

(a)

Inte

rnat

iona

l N

avig

atio

n

65

5 E

(a)

5 E

Oth

er

X

X

(11

08

Vol

cano

es)

(a

) Sec

tors

alre

ady

repo

rted

to U

NFC

CC

for N

Ox,

C

O, N

MV

OC

, SO

2.

(b) I

nclu

ding

Pro

duct

han

dlin

g.

(c

) Inc

ludi

ng N

H3

from

Ent

eric

Fe

rmen

tatio

n.

(d

) Inc

ludi

ng P

M so

urce

s.

(e) E

xclu

des w

aste

inci

nera

tion

for e

nerg

y (th

is is

in

clud

ed in

1 A

1).

(f

) Inc

lude

s acc

iden

tal f

ires.

N

ote

1: M

ain

Pollu

tant

s sho

uld

cove

r the

tim

espa

n fr

om 1

980

to la

test

yea

r.

HM

shou

ld c

over

the

times

pan

from

19

90 to

late

st y

ear.

PM

shou

ld c

over

the

times

pan

from

20

00 to

late

st y

ear.

N

ote

2: T

he A

=Allo

wab

le A

ggre

gatio

n ill

ustra

tes t

he le

vel o

f agg

rega

tion

that

can

be

used

if m

ore

deta

iled

info

rmat

ion

is n

ot a

vaila

ble.

Gre

y ce

lls sh

ow w

hich

sect

ors c

an b

e ag

greg

ated

into

the

sect

or m

arke

d A

. Bla

ck c

ells

occ

ur w

hen

two

poss

ible

leve

ls o

f agg

rega

tion

are

poss

ible

.

66

T

AB

LE

IV 1

B:

Nat

iona

l sec

tor

emis

sion

s:

Pers

iste

nt o

rgan

ic p

ollu

tant

s

Ver

sion

200

2-1

CO

UN

TRY

: PL

(a

s IS

O2

code

)

DA

TE:

31.0

3.20

03

(as

DD

.MM

.YYY

Y)

YEA

R:

2001

(as

YYYY

, yea

r of

Emm

issi

ons)

Th

ese

five

yello

w li

nes w

ill n

ot b

e re

ad b

y U

NEC

E! T

hese

line

s can

be

mod

ified

free

ly fo

r you

r ow

n re

fere

nce

purp

oses

.

Foot

note

s to

the

emis

sion

figu

res r

epor

ted

shou

ld b

e su

bmitt

ed to

geth

er w

ith th

e em

issi

on d

ata,

but

in a

sepa

rate

doc

umen

t.

Plea

se fi

ll ou

t the

blu

e m

arke

d fie

lds.

You

may

use

the

aggr

egat

ion

leve

ls in

stea

d of

the

gray

mar

ked

field

s in

aggr

egat

ion.

You

mus

t use

for e

ach

field

eith

er a

num

ber o

r one

of t

he fo

llow

ing

code

s (ca

pita

ls, n

o do

ts in

bet

wee

n, se

e EB

.AIR

/GE.

1/20

02/2

): N

O ,

NA

, N

E , I

E , C

Foot

note

s or a

ny o

ther

info

rmat

ion

ente

red

into

this

tabl

e w

ill n

ot b

e ta

ken

into

acc

ount

.

NF

R se

ctor

s to

be re

port

ed

to C

LRTA

P

Year

ly m

inim

um re

port

ing

Ad

ditio

nal

repo

rtin

g

A

NN

EX I

(1)

AN

NEX

II (

2)

AN

NEX

III

(3)

O

THER

(4

)

PA

H

benzo(a)

benzo(b)

benzo(k)

Indeno

PCP

SCCP

pyrene

fluoranthene

fluoranthene

(1,2,3-cd)

Aldrin

Chlordane

Chlordecone

Dieldrin

Endrin

Heptachlor

Hexabromo-biphenyl

Mirex

Toxaphene

HCH

DDT

PCB

DIOX

pyrene

Total 1-4

HCB

A = Allowable Aggregation kg

kg

kg

kg

kg

kg

kg

kg

kg

kg

kg

kg

g

I-Te

qM

g M

g M

g M

g M

g kg

kg

kg

1 A

1 a

1

A 1

a P

ublic

El

ectri

city

and

Hea

t Pr

oduc

tion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

11

9,88

6,42

20,

0018

000,

0019

700,

0019

700,

0030

400,

0087

80

0,55

NA

NO

67

1 A

1 b

1

A 1

b P

etro

leum

re

finin

g

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

510,

8502

0,00

2920

0,00

1610

0,00

2480

0,00

5870

0,01

2870

0

NA

NO

1

A 1

c

1 A

1 c

Man

ufac

ture

of

Solid

fuel

s and

Oth

er

Ener

gy In

dust

ries

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

550,

1027

0,00

0960

0,03

7730

0,03

7730

0,02

8390

0,10

4810

0,

02 N

A N

O

1 A

2

1 A

2 M

anuf

actu

ring

In

dust

ries

and

C

onst

ruct

ion

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

15

,69

44,9

884

0,02

0370

0,27

0150

0,27

1400

0,20

7890

0,76

9820

4,

33 N

A N

O

1 A

2 a

1

A 2

a Ir

on a

nd S

teel

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

449,

8165

IE

IE

IE

IE

IE

0,95

NA

NO

1

A 2

b

1 A

2 b

Non

-fer

rous

M

etal

s

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

5321

,537

9IE

IE

IE

IE

IE

3,

38 N

A N

O

1 A

2 c

1

A 2

c C

hem

ical

s

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A IE

IE

IE

IE

IE

N

E N

A N

O

1 A

2 d

1

A 2

d P

ulp,

Pap

er

and

Prin

t

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A IE

IE

IE

IE

IE

N

A N

A N

O

1 A

2 e

1

A 2

e F

ood

Proc

essi

ng, B

ever

ages

&

Tob

acco

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A IE

IE

IE

IE

IE

N

A N

A N

O

1 A

2 f

1

A 2

f O

ther

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

14

,72

13,6

34IE

IE

IE

IE

IE

0,

36 N

A N

O

1 A

3 a

ii (i

) 1

A 3

a ii

Civ

il A

viat

ion

(Dom

estic

, LT

O)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 a

ii (i

i) 1

A 3

a ii

Civ

il A

viat

ion

(Dom

estic

, C

ruis

e)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 b

1

A 3

b R

oad

Tra

nspo

rtat

ion

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 b

i

1 A

3 b

i

R.T

., Pa

ssen

ger c

ars

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

9,

390,

5993

0,20

4860

0,00

0290

0,00

0120

0,00

0200

0,20

5480

0,

03 N

A N

O

68

1 A

3 b

ii

1 A

3 b

ii

R.T

., Li

ght

duty

veh

icle

s

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

2,

190,

1386

0,21

5860

0,00

0300

0,00

0130

0,00

0220

0,21

6510

0,

01 N

A N

O

1 A

3 b

iii

1 A

3 b

iii

R.T

., H

eavy

dut

y ve

hicl

es

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

76

,65

0,13

560,

9290

000,

0013

000,

0005

600,

0009

300,

9317

90

0,02

NA

NO

1

A 3

b iv

1

A 3

b iv

R

.T.,

Mop

eds &

M

otor

cycl

es

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

130,

0086

0,00

0600

00

00,

0006

00

0 N

A N

O

1 A

3 b

v

1 A

3 b

v

R.T

., G

asol

ine

evap

orat

ion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 b

vi

1 A

3 b

vi

R.T

., A

utom

obile

tyre

and

br

ake

wea

r

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 b

vii

1 A

3 b

vii

R.T

., A

utom

obile

road

ab

rasi

on

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 c

1

A 3

c R

ailw

ays

N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NA

0,

0033

0,02

2630

0,00

0030

0,00

0010

0,00

0020

0,02

2700

NA

N

A

NO

1

A 3

d ii

1

A 3

d ii

Nat

iona

l N

avig

atio

n

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A 0,

0011

0,00

7400

0,00

0010

00,

0000

100,

0074

20 N

A N

A N

O

1 A

3 e

1

A 3

e O

ther

(Ple

ase

spec

ify in

a c

over

ing

note

)

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 e

i

1 A

3 e

i

Pip

elin

e co

mpr

esso

rs

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

1 A

3 e

ii

1 A

3 e

ii

Oth

er

mob

ile so

urce

s and

m

achi

nery

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A 0,

0256

0,00

6980

0,00

0010

00,

0000

100,

0070

00 N

A N

A N

O

1 A

4 a

1

A 4

a C

omm

erci

al /

Inst

itutio

nal

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

2,

920,

4292

0,00

3880

0,15

0200

0,15

0240

0,11

3050

0,41

7380

0,

08 N

A N

O

1 A

4 b

1

A 4

b R

esid

entia

l A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

A N

A N

A N

A N

A N

A N

A N

A N

O

69

1 A

4 b

i

1 A

4 b

i

Res

iden

tial

plan

ts

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

39

4,16

204,

231 4

32,0

3316 0

38,7

2258

08,

4803

5040

,457

26 011

9,69

335 0

1,58

NA

NO

1

A 4

b ii

1

A 4

b ii

H

ouse

hold

an

d ga

rden

ing

(mob

ile)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 A

4 c

1

A 4

c A

gric

ultu

re /

Fore

stry

/ Fi

shin

g A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 A

4 c

i

1 A

4 c

i St

atio

nary

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

3,

252,

5087

5,81

9220

7,01

9670

1,53

2210

7,50

0500

21,8

7159

0 0,

1 N

A N

O

1 A

4 c

ii

1 A

4 c

ii O

ff-r

oad

Veh

icle

s and

Oth

er

Mac

hine

ry

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,02

580,

1782

600,

0002

500,

0001

100,

0001

800,

1787

90

NA

NO

1A

4 c

iii

1A 4

c ii

i Nat

iona

l Fi

shin

g

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,00

090,

0064

700,

0000

100,

0000

000,

0000

100,

0064

90

NA

NO

1

A 5

a

1 A

5 a

Oth

er,

Stat

iona

ry (i

nclu

ding

M

ilita

ry)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 A

5 b

1

A 5

b O

ther

, Mob

ile

(Inc

ludi

ng m

ilita

ry)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1B1

1B1

Fugi

tive

Em

issi

ons f

rom

Sol

id

Fuel

s

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

1 a

1

B 1

a C

oal M

inin

g an

d H

andl

ing

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

1 b

1

B 1

b S

olid

fuel

tra

nsfo

rmat

ion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

2,68

636,

7157

302,

2385

802,

2385

802,

6862

9013

,879

170

N

A N

O

1 B

1 c

1

B 1

c O

ther

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2

1 B

2 O

il an

d na

tura

l ga

s A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

70

1 B

2 a

1

B 2

a O

il A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2 a

i

1 B

2 a

i E

xplo

ratio

n Pr

oduc

tion,

Tra

nspo

rt

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2 a

iv

1 B

2 a

iv R

efin

ing

/ St

orag

e

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2 a

v

1 B

2 a

v D

istri

butio

n of

oil

prod

ucts

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2 a

vi

1 B

2 a

vi O

ther

N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

O

NA

N

O

1 B

2 b

1

B 2

b N

atur

al g

as

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

1 B

2 c

1

B 2

c V

entin

g an

d fla

ring

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

2

A M

INE

RA

L

PRO

DU

CT

S ( a

) A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

1

2 A

1 C

emen

t Pr

oduc

tion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

2

2 A

2 L

ime

Prod

uctio

n

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

3

2 A

3 L

imes

tone

and

D

olom

ite U

se

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

4

2 A

4 S

oda

Ash

Pr

oduc

tion

and

use

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 A

5

2 A

5 A

spha

lt R

oofin

g

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

71

2 A

6

2 A

6 R

oad

Pavi

ng

with

Asp

halt

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

1,78

41

N

A N

O

2 A

7

2 A

7 O

ther

incl

udin

g N

on F

uel M

inin

g &

C

onst

ruct

ion

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

2

B C

HE

MIC

AL

IN

DU

STR

Y

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

1

2 B

1 A

mm

onia

Pr

oduc

tion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

2

2 B

2 N

itric

Aci

d Pr

oduc

tion

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

3

2 B

3 A

dipi

c A

cid

Prod

uctio

n

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

4

2 B

4 C

arbi

de

Prod

uctio

n

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 B

5

2 B

5 O

ther

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 C

2

C M

ETA

L PR

OD

UC

TIO

N

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

68

,928

,607

40,

6006

002,

1938

302,

1938

300,

2730

005,

2612

60

NA

NO

2

D

2 D

OTH

ER

PRO

DU

CTI

ON

(a)

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 D

1

2 D

1 P

ulp

and

Pape

r

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 D

2

2 D

2 F

ood

and

Drin

k

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

2 G

2

G O

THER

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

16

32

NA

NO

72

3 A

3

A P

AIN

T A

PPLI

CA

TIO

N

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,

0042

300,

0021

100,

0021

100,

0021

100,

0105

70

NA

NO

3

B

3 B

DEG

REA

SIN

G

AN

D D

RY

C

LEA

NIN

G

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

3 C

3

C C

HEM

ICA

L PR

OD

UC

TS,

MA

NU

FAC

TUR

E A

ND

PR

OC

ESSI

NG

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

3 D

3

D O

THER

incl

udin

g pr

oduc

ts c

onta

inin

g H

Ms a

nd P

OPs

(Ple

ase

spec

ify in

a c

over

ing

note

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

4

B M

AN

UR

E

MA

NA

GE

ME

NT

(b)

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

1

4 B

1 C

attle

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

1 a

4

B 1

a D

airy

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

1 b

4

B 1

b N

on-D

airy

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

2

4 B

2 B

uffa

lo

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

3

4 B

3 S

heep

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

4

4 B

4 G

oats

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

5

4 B

5 C

amel

s and

Ll

amas

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

6

4 B

6 H

orse

s

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

73

4 B

7

4 B

7 M

ules

and

Ass

es

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

8

4 B

8 S

win

e

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

9

4 B

9 P

oultr

y

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 B

13

4 B

13

Oth

er

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 C

4

C R

ICE

CU

LTIV

ATI

ON

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 D

4

D

AG

RIC

UL

TU

RA

L

SOIL

S

A

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 D

1

4 D

1 D

irect

Soi

l Em

issi

on

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

4 F

4

F FI

ELD

BU

RN

ING

O

F A

GR

ICU

LTU

RA

L W

AST

ES

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

0,61

1

N

A N

O

4 G

4

G O

THER

(c)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

5 B

5

B F

OR

EST

AN

D

GR

ASS

LAN

D

CO

NV

ERSI

ON

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

6 A

6

A S

OLI

D W

AST

E D

ISPO

SAL

ON

LA

ND

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

6 B

6

B W

AST

EWA

TER

H

AN

DLI

NG

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

6 C

6

C W

AST

E IN

CIN

ERA

TIO

N (d

)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

1,

1841

,094

8

1,27

NA

NO

74

6 D

6

D O

THER

WA

STE

(e)

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

112,

235 2

NA

NO

7

7 O

THER

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

N

A N

O

N

atio

nal T

otal

N

O

NO

N

O N

O

NO

N

O

NO

N

O

NO

N

O

NO

23

2744

7,49

46,7

7550

,641

14,9

1251

,279

163,

606

8,35

NA

NO

Mem

o It

ems

1 a

3 a

i (i)

Inte

rnat

iona

l Avi

atio

n (L

TO)

1 a

3 a

i (ii)

In

tern

atio

nal A

viat

ion

(Cru

ise)

1 a

3 d

i In

tern

atio

nal M

arin

e (b

)

5 E

5 E

Oth

er

X

X (

11 0

8 V

olca

noes

)

(a) I

nclu

ding

Han

dlin

g;

(b) I

nclu

ding

NH

3 fr

om E

nter

ic

Ferm

enta

tion;

(c

) Inc

ludi

ng P

M so

urce

s;

(d) E

xclu

des w

aste

inci

nera

tion

for e

nerg

y (th

is is

incl

uded

in 1

A 1

);

(e) I

nclu

des a

ccid

enta

l fire

s.

N

otes

1:

POPs

shou

ld c

over

the

times

pan

from

199

0 to

the

late

st y

ear.

(1

): T

he P

OPs

list

ed in

ann

ex I

to th

e Pr

otoc

ol o

n PO

Ps a

re su

bsta

nces

75

sche

dule

d fo

r elim

inat

ion;

DD

T an

d PC

Bs a

re a

lso

liste

d in

ann

ex I;

(2

): T

he P

OPs

list

ed in

ann

ex II

to th

e Pr

otoc

ol o

n PO

Ps

are

subs

tanc

es sc

hedu

led

for r

estri

ctio

ns o

n us

e;

(3):

The

PO

Ps li

sted

in a

nnex

III t

o th

e Pr

otoc

ol o

n PO

Ps a

re su

bsta

nces

refe

rred

to in

arti

cle

3, p

ara.

5 (a

), of

the

Prot

ocol

. P

olyc

yclic

aro

mat

ic h

ydro

carb

ons (

PAH

s): F

or th

e pu

rpos

e of

the

emis

sion

inve

ntor

ies,

the

follo

win

g fo

ur in

dica

tor c

ompo

unds

shou

ld b

e us

ed: b

enzo

(b)p

yren

e, b

enzo

(b)f

luor

anth

ene,

ben

zo(k

)flu

oran

then

e an

d in

deno

(1,2

,3-c

d)py

rene

. HC

B is

als

o in

clud

ed in

ann

ex I

to th

e Pr

otoc

ol a

s a su

bsta

nce

for

elim

inat

ion.

(4

): S

ee a

rticl

e 8

of th

e Pr

otoc

ol (R

esea

rch,

dev

elop

men

t an

d m

onito

ring;

repo

rting

vol

unta

ry).

N

ote

2: T

he A

=Allo

wab

le A

ggre

gatio

n ill

ustra

tes t

he le

vel o

f agg

rega

tion

that

can

be

used

if m

ore

deta

iled

info

rmat

ion

is n

ot a

vaila

ble.

Gre

y ce

lls sh

ow

whi

ch se

ctor

s can

be

aggr

egat

ed in

to th

e se

ctor

mar

ked

A. B

lack

cel

ls o

ccur

whe

n tw

o po

ssib

le le

vels

of a

ggre

gatio

n ar

e po

ssib

le.

76

TA

BL

E IV

2A

: Fiv

e-ye

arly

, Min

imum

rep

ortin

g of

pro

ject

ed n

atio

nal t

otal

em

issi

ons o

f mai

n po

lluta

nts

Ver

sion

200

2-1

C

OU

NTR

Y:

(a

s IS

O2

code

)

D

ATE

:

(as

DD

.MM

.YYY

Y)

YEA

R:

(a

s YY

YY, y

ear o

f Em

mis

sion

s)

Th

ese

five

yello

w li

nes w

ill n

ot b

e re

ad b

y U

NEC

E! T

hese

line

s can

be

mod

ified

free

ly fo

r you

r ow

n re

fere

nce

purp

oses

. Fo

otno

tes t

o th

e em

issi

on fi

gure

s rep

orte

d sh

ould

be

subm

itted

toge

ther

with

the

emis

sion

dat

a, b

ut in

a se

para

te d

ocum

ent.

Plea

se fi

ll ou

t the

blu

e m

arke

d fie

lds.

You

mus

t use

for e

ach

field

eith

er a

num

ber o

r one

of t

he fo

llow

ing

code

s (ca

pita

ls, n

o do

ts in

bet

wee

n, se

e EB

.AIR

/GE.

1/20

02/2

): N

O ,

NA

, N

E , I

E , C

Fo

otno

tes o

r any

oth

er in

form

atio

n en

tere

d in

to th

is ta

ble

will

not

be

take

n in

to a

ccou

nt.

U

NIT

C

urre

nt le

gisl

atio

n pr

ojec

tions

a)

Cur

rent

redu

ctio

n pl

ans

Pollu

tant

:

2010

20

15

2020

20

10

2015

20

20

Sul

phur

oxi

des (

SOx a

s SO

2) G

g N

E N

E N

E N

E N

E N

E

Nitr

ogen

oxi

des (

NO

x as N

O2)

G

g N

E N

E N

E N

E N

E N

E

Non

-met

hane

vol

atile

org

anic

co

mpo

unds

(NM

VO

C)

Gg

804

NE

NE

NE

NE

NE

Am

mon

ia (N

H3)

G

g N

E N

E N

E N

E N

E N

E

a) C

urre

nt le

gisl

atio

n pr

ojec

tions

shou

ld b

e ba

sed

on th

e ac

tivity

pro

ject

ions

as r

epor

ted

in ta

bles

IV 2

B, I

V 2

C, I

V 2

D, a

nd IV

2E

in a

nnex

IV.

Not

e:

Fo

r the

def

initi

on o

f ‘cu

rren

t leg

isla

tion

proj

ectio

ns’ a

nd ‘c

urre

nt re

duct

ion

plan

s’ p

leas

e re

fer t

o pa

ragr

aph

24 o

f the

gui

delin

es (c

hap.

V).