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viii
International Conference on
Emerging Trends in Chemical Sciences
Thursday-Friday, 14-15th March, 2013
School of Chemical Sciences, Central University of Gujarat, Gandhinagar
Program Schedule
Screen-I (Chancellor Hall)
___________________________________________________________________________________________ March 14th, 2013, Thursday
08:30 am Arrival at the Conference Venue: Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25, Gandhinagar–382044, Gujarat, India
08.30 am onwards Help Desk
Inaugural Session Venue: Chancellor Hall, Cambay Spa & Golf Resort 09:00 am - 09:10 am Organizing Secretary’s Introductory Speech
Man Singh, Dean, School of Chemical Sciences, Central University of Gujarat, Gandhinagar, Gujarat, India
09:10 am - 09:30 am Welcome Address
R. K. Kale, Vice-Chancellor, Central University of Gujarat, Gandhinagar, Gujarat, India
09:30 am - 09:40 am Academic Cognizance 09:40 am - 10:00 am Chief Guest’s Address
Y. K. Alagh, Chancellor, Central University of Gujarat, Gandhinagar, Gujarat, India
10:00 am - 10:05 am Vote of Thanks
Man Singh, Dean, School of Chemical Sciences, Central University of Gujarat, Gandhinagar, India
10:05 am - 10:20 am Chemistry as central science
Janusz Lipkowski, Department of Supramolecular Complexes, Institute of Physical Chemistry, Poland
10:20 am - 10:50 am Tea/Coffee Break
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Session 1 at Chancellor Hall Chair: Prof. Ajai Kumar Singh, Department of Chemistry, Indian Institute of Technology, New Delhi, India
10:50 am - 11:10 am Green chemistry and nanotechnology: Enhanced selectivity of
formation of 2,6-bis (benzylidene) cyclohexanone (ABA product) vs. 2-(benzylidene) cyclohexanone (AB product) by micellar catalysis in aqueous solutions Dinesh O. Shah, Department of Chemical Engineering and Department of Anesthesiology, University of Florida, USA
11:10 am - 11:30 am Computational chemistry: an emerging field for chemical education
and research Ponnadurai Ramasami, Department of Chemistry, University of Mauritius, Mauritius
11:30 am - 11:50 am Green chemistry in education and research
R. K. Sharma, Department of Chemistry, University of Delhi, India 11:50 am - 12:10 pm Effect of high intensity focused ultrasound (HIFU) on the occurrence
of induction period in crystallization of sucrose: industrial application Kaman Singh, Advance Center of Surface Science and Nanotechnology, Department of Applied Chemistry, School for Physical Sciences, BBAU, Lucknow, India
12:10 pm – 12:30 pm Porous molecules and crystals Janusz Lipkowski, Department of Supramolecular Complexes, Institute of Physical Chemistry, Poland
12:30 pm - 02:00 pm Lunch/Poster Session Session 2 at Chancellor Hall Chair: Prof. Kaman Singh, Department of Applied Chemistry, School for Physical Sciences, Babasaheb Bhimrao Ambedkar Universitry, Lucknow, India 02:00 pm - 02:15 pm Synthesis and characterization of sodium salt of partially
carboxymethylated guar gum Jay Kumar J. Patel, Department of Chemical Sciences, Natubhai V. Patel College of Pure and Applied Sciences, V. V. Nagar, Gujarat, India
02:15 pm - 02:30 pm n-Alkanes as greener solvents for selective heterogeneous organic
transformation
Kamlesh N. Tayade, Chemical Engg. Department, DDU, Nadiad, India 02:30 pm - 02:45 pm Bioconversion of glycerol to 1,3-propanediol and its application
Mandar K. Karve, Department of Chemical Sciences, Natubhai V. Patel College of Pure and Applied Sciences, V. V. Nagar, Gujarat, India
02:45 pm - 03:00 pm Heterogeneous catalysis and green chemistry Manish Dixit, Department of Chemical Engineering and Shah-Schulman Center for Surface Science and Nanotechnology, Dharmsinh Desai University, Nadiad, Gujarat, India
x
03:00 pm - 03:15 pm Selective determination of Nd3+ using polymeric membrane electrode
and coated graphite electrode Koteswara Rao Bandi, Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee, India
03:15 pm - 03:30 pm ESIPT-Inspired benzothiazole fluorescein: synthesis, photophysics of microenvironment pH, viscosity and DFT approach towards its photophysical properties Abhinav B. Tathe, Institute of Chemical Technology, Mumbai, MH, India
03:30 pm - 04:00 pm Tea/Coffee Break Session 3 at Chancellor Hall Chair: Prof. M. H. Fulekar, Dean, School of Environment and Sustainable Development Central University of Gujarat, Gandhinagar, India 04:00 pm - 04:15 pm Preparation and characterization of SiO2 thin films by Sol-Gel using
TEOS, cationic, anionic and nonionic surfactants Sanjan Choudhary, School of Chemical Sciences, Central University of Gujarat, Gandhinagar, Gujarat, India
04:15 pm - 04:30 pm Suzuki-Miyaura cross-coupling reaction in aqueous media catalyzed
by keggin type mono Pd(II)- substituted phosphomolybdate Soyeb Pathan, Department of Chemistry, The M. S. University of Baroda, Gujarat, India
04:30 pm - 04:45 pm Spectral, electrochemical and molecular modeling studies of (N4E,
N4'E)- 3,3'-dimethyl-N4,N4'-bis (pyridin-2-ylmethylene) biphenyl-4,4'-diamine Gudipati S. Rao, Department of Chemistry, National Institute of Technology, Andhra Pradesh, India
04:45 pm – 05:00 pm Bioactive flavonoids of therapeutic importance Rajpratap B. Kshatriyaa, Poona College, University of Pune, Pune, India
05:00 pm – 05:15 pm Indirect chiral separation of pregabalin enantiomers by O-phthalaldehyde-N-acetyl-L-cysteine as chiral derivatizing agent followed by fluorescence detection Nagesh K. Kandukuri, IICT, Hyderabad, India
05:30 pm – 08:00 pm Interaction Followed by Cultural Program 08:00 pm - 09:00 pm Dinner at Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25,
Gandhinagar–382044, Gujarat, India
xi
Screen-I (Chancellor Hall) ____________________________________________________________________________________________________________________ March 15th, 2013, Friday 08:30 am Arrival at the Conference Venue: Chancellor Hall, Cambay Spa & Golf
Resort, GIDC, Sector-25, Gandhinagar–382044, Gujarat, India 08.30 am onwards Help Desk
Session 4 at Chancellor Hall Chair: Prof. R. K. Sharma, Department of Chemistry, University of Delhi, Delhi, India 09:00 am - 09:20 am Determining antioxidant distributions between oil, water, and
interfacial regions of emulsions: generalization of pseudophase kinetic models Laurence S. Romsted, and Carlos Bravo-Díaz, Department of Chemistry and Chemical Biology, The State University of New Jersey, New Jersey, USA
09:20 am - 09:40 am Computational Chemistry: a reliable tool to interpret the
structure-dependent photophysical properties of transition metal complexes Zainul A. Siddique, Department of Chemistry, Chittagong University,
Chittagong, Bangladesh
. 09:40 am - 10:00 am Organochalcogen ligands: Story of catalyst designing and metal
chalcogenide nanoparticle generation Ajai Kumar Singh, Department of Chemistry, Indian Institute of Technology, New Delhi, India
10:00 am - 10:20 am Chitosan: A versatile material for a controlled delivery of the drugs
K. C. Gupta, Polymer Research Laboratory, Department of Chemistry I.I.T. Roorkee, India
10:20 am - 10:40 am Green chemistry in chemical sciences Kishor Bhai R. Desai, Veer Narmad South Gujarat University, Gujarat, India
10:40 am - 11:00 am Bioremediation of petrochemical hydrocarbon compound in a designed and developed partitioning bioreactor M. H. Fulekar, Dean, School of Environment and Sustainable Development, Central University of Gujarat, Gandhinagar, India
11:00 am - 11:15 am Tea/Coffee Break Session 5 at Chancellor Hall Chair: Prof. D. D. Pathak, Department of Applied Chemistry, Indian School of Mines, Dhanbad, India
11:15 am - 11:30 am Corrosion behaviour of mild steel exposed to D. desulfuricans in marine environment R. S. Dubey, Department of Chemistry, R. J. College, University of Mumbai, Mumbai, India
xii
11:30 am - 11:45 am Modification in dielectric and piezoelectric properties of the of PZT-CHR doped PVA 0-3 nano-composites by CNT inclusion 1Manmeeta and 2Dhiraj Saxena, 1Faculty of Science, National law University, Rajasthan, India; 2Lachoo Memorial College of Science & Technology, Jodhpur
11:45 am - 12:00 pm A combined experimental and dft-tddft study of the excited-state
intramolecular proton transfer (ESIPT) of 2-(2'-hydroxyphenyl) imidazole derivatives Vikas S. Padalkar, Institute of Chemical Technology, MH, India
12:00 pm - 12:15 pm Factors that influence the nuclearity/aggregation and carboxylate
coordination modes in Lewis base coordinated zinc (II) carboxylate complexes Umesh Kumar, Department of Chemistry, University of Delhi, Delhi, India
12:15 pm – 12:30 pm Effect of acid hydrolysis on bioconversion of lignocellulose to biogas
Rajan Sharma, University of Petroleum & Energy Studies, Dehradun, India
12:30 pm – 12:45 pm Potential sources of error in the determination of arsenic in environmental water samples by hydride generation atomic absorption spectrometry A. Ramesh Kumar, National Institute of Occupational Health, Indian Council of Medical Research, Ahmedabad, Gujarat, India
12:45 pm - 02:00 pm Lunch/Poster Session Session 6 at Chancellor Hall: Chair: Dr. M. Kamil, Department of Petroleum Studies, AMU, Aligarh, UP, India 02:00 pm - 02:15 pm Poly-N-vinylpyrrolidone oximo-l-isoleucyl-siliconate, preparation,
molecular and microstructures study with IR, 1H-NMR and SEM
G. Vani Padmaja, Chemistry Research Lab, Deshbandhu College,
University of Delhi, New Delhi, India
02:15 pm - 02:30 pm Fabrication of iron selective PVC membrane electrode based on newly
synthesized Schiff bases as carrier Anjali Upadhyay, Department of Chemistry, Indian Institute of Technology-Roorkee, India
02:30 pm - 02:45 pm Modified dextrin based semi-IPN hydrogel: A novel matrix for colon
targeted drug delivery Dipankar Das, Department of Applied Chemistry, Indian School of Mines, Dhanbad, India
02:45 pm – 03:00 pm (Diacetoxyiodo)benzene mediated facile oxidation of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ols): Synthesis of spiro compounds Girdharilal B. Tiwari, School of Chemical Science SRTM University of
xiii
Nanded, India 03:00 pm - 03:15 pm Development and validation of a stability indicating assay of
Paliperidone by RP-HPLC: ESI-MS/MS, 1H and 13C NMR spectroscopic characterization of degradation products and process related impurities Ch. Gangu Naidu, Indian Institute of Chemical Technology, Hyderabad, India
03:15 pm – 03:30 pm Quality analysis of Centella asiatica (Mandukparni)-A memory
improving herbal drug by LCMS/MS-multiple reactions monitoring (mrm) method Jayanti Makasana, Directorate of Medicinal and Aromatic Plant Research, Gujarat, India
03:30 pm - 03:45 pm A Novel thermotropic liquid crystal based on azomaterial linked with zinc oxide nanoparticles and its dielectric property Alok Pandya, Department of Chemistry, Gujarat University, India
03:45 pm - 04:00 pm Tea/Coffee Break Session 7 at Chancellor Hall: Concluding Session /Award presentations Chair: Prof. Kaman Singh, Department of Applied Chemistry, School for Physical Sciences, Babasaheb Bhimrao Ambedkar University, Lucknow, India 04:00 pm - 05:30 pm Valedictory Address/Award Distribution 05:30 pm - 06:30 pm Departure to Central University of Gujarat (CUG) and High Tea at
MPH, CUG 06:30 pm - 08:30 pm Local Visit 08:30 pm - 09:30 pm Dinner at Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25,
Gandhinagar–382044, Gujarat, India
xiv
Screen-II (Viceroy Hall) ___________________________________________________________________________________________ March 14th, 2013, Thursday
08:30 am Arrival at the Conference Venue: Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25, Gandhinagar–382044, Gujarat, India
08.30 am onwards Help Desk
Session 1 at Viceroy Hall Chair: Prof. P. Nageswara Rao, Chemistry Department, National Institute of Technology, Warangal, AP, India 10:50 am - 11:10 am Nanoadsorbents for the removal of metallic species from water and
wastewaters Yogesh C. Sharma, Department of Applied Chemistry, Indian Institute of Technology, BHU, India
11:10 am - 11:30 am Cloud point method of extraction of heavy metal ions
N. V. Sastry, Department of Chemistry, Vallabh Vidyanagar, Gujarat
11:30 am - 11:50 am Interactions between gemini/conventional surfactants with polymers M. Kamil, Department of Petroleum Studies, AMU, UP, India
11:50 am – 12:10 pm Importance of small molecule computational chemistry related to macromolecular computations S. Aravamudhan, Department of Chemistry, North Eastern Hill University, Meghalaya, India
12:10 pm – 12:30 pm Forensic science and criminal investigation
Dr. G. Rajesh Babu, Department of Chemistry, Institute of Forensic Science, Gujarat Forensic Sciences University, Gandhinagar, Gujarat, India
12:30 pm - 02:00 pm Lunch/Poster Session Session 2 at Viceroy Hall Chair: Prof. K. C. Gupta, Polymer Research Laboratory, Department of Chemistry, I.I.T. Roorkee, India 02:00 pm - 02:15 pm Ionic liquid supported metal complexes–an environmentally benign
catalytic approach Bharti Khungar, Department of Chemistry, Birla Institute of Technology and Science, Pilani, Rajasthan, India
02:15 pm - 02:30 pm Synthesis, characterization and antitubercular activity of
N-substituted phenothiazine 1-carboxylic acid derivatives Manish J. Solanki, Nirma University, Gujarat, India
xv
02:30 pm - 02:45 pm Development of antidotes against organophosphorus poisoning Hitendra N. Karade, Process Technology Development Division, Defence Research & Development Establishment, Jhansi Road, Gwalior, India
02:45 pm – 03:00 pm Colorimetric receptors for naked eye detection of inorganic fluoride ion in aqueous media Darshak R. Trivedi, Department of Chemistry, National Institute of Technology, Manglore, Karnataka
03:00 pm – 03:15 pm Thermodynamic and viscometric investigation of multicompoenent liquid mixtures Ranjan Dey, Department of Chemistry, BITS Pilani, Goa, India
03:15 pm - 03:30 pm A new method for the determination of pesticide residues in fruits using ultra pressure liquid chromatography/time-of-flight mass spectrometry (UPLC/TOF-MS) P. Sivaperumal, Pesticide Toxicology Division, NIOH, Ahmedabad, India
03:30 pm - 04:00 pm Tea/Coffee Break Session 3 at Viceroy Hall Chair: Prof. Ponnadurai Ramasami, Computational Chemistry Group, Department of Chemistry, Faculty of Science, University of Mauritius, Mauritius 04:00 pm - 04:15 pm Dissociation of multiply charged molecular ions formed in keV
electron-molecule collisions: kinetic energy release distributions Pragya Bhatt, Atomic Physics Laboratory, Department of Physics, BHU, UP, India
04:15 pm - 04:30 pm Development of an ion selective electrode for amitriptyline
hydrochloride based on calixarene – carbon nanotube composite Reena R. Gaichore, Department of Chemistry, University of Mumbai, Mumbai, India
04:30 pm - 04:45 pm Synthesis of amide and ester derivatives of naphthopyrone
2-carboxylic acid Soni J. Nareshkumar, M. S. University of Baroda, Varodara, Gujarat, India
04:45 pm - 05:00 pm A study of why we need environmental chemistry? Tushar K. Gandhi, Sabar Kantaa, Gujarat, India
05:00 pm – 08:00 pm Interaction followed by Cultural Program 08:00 pm - 09:00 pm Dinner at Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25,
Gandhinagar–382044, Gujarat, India
xvi
Screen-II (Viceroy Hall) ____________________________________________________________________________________________________________________ March 15th, 2013, Friday 08:30 am Arrival at the Conference Venue: Chancellor Hall, Cambay Spa & Golf
Resort, GIDC, Sector-25, Gandhinagar–382044, Gujarat, India 08.30 am onwards Help Desk
Session 4 at Viceroy Hall Chair: Prof. S. Aravamudhan, Department of Chemistry, North Eastern Hill University, Meghalaya, India 09:00 am - 09:20 am Kinematics and fragmentation dynamics of multiply charged
molecules of atmospheric interest under impact of keV electrons R. Shanker, Department of Physics, Banaras Hindu University, UP, India
09:20 am - 09:40 am Multifunctional nanoparticles derived from calix-system
V. K. Jain, Chemistry Department, School of Sciences, Gujarat University, Ahmedabad, Gujarat, India
09:40 am - 10:00 am Single and mixed micelles of pluronic® polymers for a nano-sized drug delivery system Rakesh K. Sharma, Applied Chemistry Department, The Maharaja Sayajirao University of Baroda, Vadodara, Gujarat, India
10:00 am - 10:20 am NISCAIR, CSIR activities and about Journal of Scientific & Industrial (JSIR) S. Sengupta, Scientist, CSIR, Ministry of Science & Technology, New Delhi, India
10:20 am - 10:40 am Template synthesis of cyclic phosphines and phosphorus macrocycles
D. D. Pathak, Department of Applied Chemistry, Indian School of Mines, Dhanbad, India
10:40 am - 11:00 am Oxidative functionalization of alkenes by an intramolecular sulfinyl
nucleophile as the key step in the synthesis of (-)-tetrahydrolipstatin
(THL), analogues of mannostatin A and toward a synthesis of
tetrahydroxy long chain base (LCB)
K. Rathore, Natural Product Chemistry Division, Indian Institute of
Chemical Technology, Hyderabad, India
11:00 am - 11:15 am Tea/Coffee Break Session 5 at Viceroy Hall Chair: Prof. Kishor Bhai R. Desai, Head of the Chemistry Department, Veer Narmad South Gujarat University, Gujarat, India
11:15 am - 11:30 am The structural properties of BaCo2Fe16O27 hexaferrite materials prepared by a simple heat treatment method
xvii
Chetna Chauhan, Institute of Technology, Nirma University, Ahmedabad, Gujarat, India
11:30 am - 11:45 am Synthesis and characterization of core-shell structured fluorescent star polymers Harjinder Kaur, Department of Chemistry, Gujarat University, Ahmedabad, Gujarat, India
11:45 am - 12:00 pm Antifouling, permeation and desalination performance of TiO2
nanotube incorporated PSf/CS blend membranes Arun Isloor, Chemistry Department, National Institute of Technology, Karnataka, India
12:00 pm – 12:15 pm The role of medicinal chemist in drug discovery: Then and Now Dhurke Kashinath, Department of Chemistry, National Institute of Technology, Warangal, AP, India
12:15 pm – 12:30 pm Elemental composition a possible indicator of the tree survival on the rehabilitated lignite mine spoil Kapil Gehlot, Department of Chemistry, Lachoo Memorial College of Science and Technology, Jodhpur
12:30 pm – 12:45 pm Band gap bowing at nanoscale: investigation of CdSxSe1-x alloy quantum dots through cyclic voltammetry and density functional theory Pravin P. Ingole, Department of Chemistry, Central University of Rajasthan, Rajasthan, India
12:45 pm – 02:00 pm Lunch/Poster Session Session 6 at Viceroy Hall Chair: Prof. Yogesh Chandra Sharma, Department of Applied Chemistry, Indian Institute of Technology, BHU, India 02:00 pm - 02:15 pm Xanthan gum-g-poly (acrylamide)/silica hybrid nanocomposite:
application as efficient adsorbent for removal of Congo red dye Soumitra Ghorai, ISM, Dhanbad, India
02:15 pm - 02:30 pm An efficient RP – HPL method for the quantitative determination of
dobutamine in rat plasma, suitable for bioequivalence and pharmacokinetics studies in healthy rat subjects T. Ramesh, Department of Chemistry, National Institute of Technology, AP, India
02:30 pm - 02:45 pm In-silico designing of dipeptidyl peptidase (DPP)-IV inhibitors as
novel anti-diabetic molecules Bhumika D. Patel, Department of Pharmaceutical Chemistry, Institute of Pharmacy, Nirma University, Ahmedabad, Gujarat, India
02:45 pm - 03:00 pm Controlled drug delivery of antileishmanial chalcones from Layer-by-Layer (LbL) self-assembled PSS/PDDAC thin films Uma M. Bhalerao, Process Technology Development Division, Defence R & D Establishment, Madhya Pradesh, India
xviii
03:00 pm - 03:15 pm Investigation of ex vivo stability of fesoterodine in human plasma and
its simultaneous determination together with its active metabolite 5-HMT by LC-ESI-MS/MS: Application to a bioequivalence study Jignesh M. Parekh, Chemistry Department, Kadi Sarva Vishwavidyalaya, Gandhinagar, Gujarat, India
03:15 pm - 03:30 pm Application of nanotechnology for detoxification of toxic effluent generated from pesticide industries Richa Sharma, Institute of Pesticide Formulation Technology Gurgaon, Haryana, India
03:30 pm - 03:45 pm Validated spectrophotometric methods for the estimation of paracetamol, domperidone and flunarizine in the combined tablet dosage form Sandip K. Sharma, Saraswati Institute of Pharmaceutical Sciences, Ahmedabad, Gujarat, India
03:45 pm - 04:00 pm Tea/Coffee Break Session 7 at Chancellor Hall: Concluding Session /Award presentations Chair: Prof. Kaman Singh, Department of Applied Chemistry, School for Physical Sciences, Babasaheb Bhimrao Ambedkar University, Lucknow, India 04:00 pm - 05:30 pm Valedictory Address/Award Distribution 05:30 pm - 06:30 pm Departure to Central University of Gujarat (CUG) and High Tea at
MPH, CUG 06:30 pm - 08:30 pm Local Visit 08:30 pm - 09:30 pm Dinner at Chancellor Hall, Cambay Spa & Golf Resort, GIDC, Sector-25,
Gandhinagar–382044, Gujarat, India