Electrical Properties of Semiconductors.pdf

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  • Electrical Properties of Semiconductors

    It goes without saying that electrons rotate round the nucleus in specific circular orbits under theinfluence of nuclear forces which are the short range attractive forces. If the influence of electronis strong enough to conquer this force of attraction, it can be designated as conductors. If theenergy of electrons, on the other hand, is least to overcome the nuclear short range forces, it iscalled as insulators. In simple words, the materials which reveal intermediate behavior inbetween insulators and conductors, and both are termed as semiconductors. Depending on theirconducting properties, semiconductors can be classified into 2 types: Intrinsic semiconductorsand Extrinsic semiconductors.

    Intrinsic Semiconductors:

    Basically electrons and holes are charge carriers present in semiconductors, holes as +velycharged and electrons being -vely charged. The unique characteristic property of intrinsicsemiconductors is the possession neutralisation current. As a consequence of this currentintrinsic semiconductor, they only have carrying capability of little current. This is to enhance itsconducting properties that need to be modified in the case of intrinsic semiconductors. Doping isthe property that enhances the conductivity of semiconductors. The amount of doping should bemoderate. Extrinsic semiconductors are formed by intiating doping process.

    Extrinsic Semiconductors:

    Extrinsic semiconductors present in an impure form. The impurities added belongs to 3rd and 5thgroup in the periodic table, the trivalent impurities are 3rd group elements such as aluminium,boron, gallium, indium and pentavalent impurities. For the 5th group elements are arsenic,phosphorous, antimony, bismuth. Germanium and Silicon semiconductors are tetravalent innature. When phosphorous, the pentavelent impurity, is added to silicon, take note that 4 valenceelectrons of silicon form a covalent bond with 4 valence electrons of silicon, but one electronwill lie free without any participation.

    Therefore, adding a small amount of impurity, electrons are generated, thus thesesemiconductors are n-type extrinsic semiconductors. By adding trivalent impurities, such asboron to a semiconductor 3 valence electrons of silicon form covalent bond with 3 valenceelectrons of impure atom. While one electron is electron deficient, the semiconductor completesits bonding process by stealing an electron from its neighboring atom. By adding trivalentimpurity, there is a vacancy created. Thus, these impurities are known as acceptor impurities,while the semiconductors are called as p-type semiconductors.

    Currents In Semiconductors

    The current in semiconductors is usually carried by holes and electrons. The currents insemiconductors are of two types depending on the application of the external field. The first oneis the drift current, and the second one is the diffusion current.

    Applications

  • The first application is the crucial role of semiconducting materials to play a pivotal role inelectronic field due to its peculiar property of temperature coefficient of resistivity. The secondone is the semiconducting principle that can be utilised in the form of voltage regulator in zenerdiode where forward bias and reverse biasing action takes place. The third application is the factthat the semiconductors play a key role as an electronic device in the industry. Last but not theleast, the semiconducting materials are used by Photodiodes and LED's as display devices.