8
Effect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakurai a,b , Bo Zhao a , Zhuomin M. Zhang a,n a George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA b Department of Mechanical and Production Engineering, Niigata University, 8050, Ikarashi 2-no-cho, Niigata 950-2181, Japan article info Article history: Received 17 September 2014 Received in revised form 26 November 2014 Accepted 28 November 2014 Keywords: Absorptance Emittance Metamaterials Nanostructures Polarization effect abstract This work deals with the spectral radiative properties of metamaterials made of a 2D metallic pattern on a dielectric thin film that separates the top periodic structure from a metal ground plane. Two distinct patterns are considered: one consists of disconnected double-rectangle gold pattern and the other is made of L-shape pattern. Both structures exhibit dual-band emission or absorption peaks in the infrared region. Unlike the disconnected rectangular pattern for which the normal emittance is independent of the polarization angle, the L-shape structure shows strong polarization dependent due to near-field coupling. The electromagnetic fields at the resonant frequencies are analyzed using the finite-difference time-domain technique to elucidate the physical mechanisms accounting for the different behaviors. For both structures, the resonance mechanisms can be explained by magnetic polaritons. Inductorcapacitor circuit models are developed to quantitatively predict the resonance frequencies. This work helps the understanding of polarization dependence in metamaterials and may facilitate their applications in biosensing and infrared spectroscopic system. & 2014 Elsevier Ltd. All rights reserved. 1. Introduction Electromagnetic metamaterials refer to a class of engi- neered artificial structures containing periodic patterns of (usually) metallic elements with geometric features smal- ler than the wavelength. Exotic and superior optical, thermal radiative, or microwave characteristics, which are absent or rarely exit in natural materials, have been demonstrated using metamaterials [13]. Recently, meta- material emitters or absorbers with a metalinsulatormetal structure have attracted much attention [48]. Specifically, wavelength-selective infrared absorption or emission shows promising biosensing applications due to the infrared vibrational fingerprints of biomolecules that can be applied for their identification [9]. To meet the requirement for various applications, single-band, dual- band, and multi-band emitters and absorbers have been demonstrated. For example, polarization and angular insensitive near-perfect absorbers have been developed in the near infrared for plasmonic sensing with a single- band response [10]. Liu et al. [4] demonstrated dual-band and multi-band mid-infrared emitters using cross-shape patterns with different sizes. Zhang et al. [11] fabricated elliptical nanodisks, with a 901 rotation between two adjacent disks, to realize dual-band near-perfect absorp- tion. Tao et al. [12] observed two absorption peaks in the far-infrared region based on the electric-field-coupled resonators. These metamaterial absorbers or emitters are designed for polarization-independent response. However, some metamaterial absorbers or emitters exhibiting polar- ization control ability are also attractive for practical applications where polarization selectivity is desired [1317]. Contents lists available at ScienceDirect journal homepage: www.elsevier.com/locate/jqsrt Journal of Quantitative Spectroscopy & Radiative Transfer http://dx.doi.org/10.1016/j.jqsrt.2014.11.018 0022-4073/& 2014 Elsevier Ltd. All rights reserved. n Corresponding author. E-mail address: [email protected] (Z.M. Zhang). Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]]]] Please cite this article as: Sakurai A, et al. Effect of polarization on dual-band infrared metamaterial emitters or absorbers. J Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1016/j.jqsrt.2014.11.018i

Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

  • Upload
    others

  • View
    4

  • Download
    0

Embed Size (px)

Citation preview

Page 1: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

Contents lists available at ScienceDirect

Journal of Quantitative Spectroscopy &Radiative Transfer

Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]]

http://d0022-40

n CorrE-m

PleasJ Qua

journal homepage: www.elsevier.com/locate/jqsrt

Effect of polarization on dual-band infrared metamaterialemitters or absorbers

Atsushi Sakurai a,b, Bo Zhao a, Zhuomin M. Zhang a,n

a George W. Woodruff School of Mechanical Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USAb Department of Mechanical and Production Engineering, Niigata University, 8050, Ikarashi 2-no-cho, Niigata 950-2181, Japan

a r t i c l e i n f o

Article history:Received 17 September 2014Received in revised form26 November 2014Accepted 28 November 2014

Keywords:AbsorptanceEmittanceMetamaterialsNanostructuresPolarization effect

x.doi.org/10.1016/j.jqsrt.2014.11.01873/& 2014 Elsevier Ltd. All rights reserved.

esponding author.ail address: [email protected]

e cite this article as: Sakurai A, et al.nt Spectrosc Radiat Transfer (2015

a b s t r a c t

This work deals with the spectral radiative properties of metamaterials made of a 2Dmetallic pattern on a dielectric thin film that separates the top periodic structure from ametal ground plane. Two distinct patterns are considered: one consists of disconnecteddouble-rectangle gold pattern and the other is made of L-shape pattern. Both structuresexhibit dual-band emission or absorption peaks in the infrared region. Unlike thedisconnected rectangular pattern for which the normal emittance is independent of thepolarization angle, the L-shape structure shows strong polarization dependent due tonear-field coupling. The electromagnetic fields at the resonant frequencies are analyzedusing the finite-difference time-domain technique to elucidate the physical mechanismsaccounting for the different behaviors. For both structures, the resonance mechanisms canbe explained by magnetic polaritons. Inductor–capacitor circuit models are developedto quantitatively predict the resonance frequencies. This work helps the understandingof polarization dependence in metamaterials and may facilitate their applications inbiosensing and infrared spectroscopic system.

& 2014 Elsevier Ltd. All rights reserved.

1. Introduction

Electromagnetic metamaterials refer to a class of engi-neered artificial structures containing periodic patterns of(usually) metallic elements with geometric features smal-ler than the wavelength. Exotic and superior optical,thermal radiative, or microwave characteristics, whichare absent or rarely exit in natural materials, have beendemonstrated using metamaterials [1–3]. Recently, meta-material emitters or absorbers with a metal–insulator–metal structure have attracted much attention [4–8].Specifically, wavelength-selective infrared absorption oremission shows promising biosensing applications due tothe infrared vibrational fingerprints of biomolecules that

(Z.M. Zhang).

Effect of polarization o), http://dx.doi.org/10.1

can be applied for their identification [9]. To meet therequirement for various applications, single-band, dual-band, and multi-band emitters and absorbers have beendemonstrated. For example, polarization and angularinsensitive near-perfect absorbers have been developedin the near infrared for plasmonic sensing with a single-band response [10]. Liu et al. [4] demonstrated dual-bandand multi-band mid-infrared emitters using cross-shapepatterns with different sizes. Zhang et al. [11] fabricatedelliptical nanodisks, with a 901 rotation between twoadjacent disks, to realize dual-band near-perfect absorp-tion. Tao et al. [12] observed two absorption peaks in thefar-infrared region based on the electric-field-coupledresonators. These metamaterial absorbers or emitters aredesigned for polarization-independent response. However,some metamaterial absorbers or emitters exhibiting polar-ization control ability are also attractive for practicalapplications where polarization selectivity is desired [13–17].

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 2: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

xz

kEH

y hdw

w

y

xz

w s

s

w

w

s

s E

w

y

xz

ww

w E

Fig. 1. Schematic of the metamaterial emitter and absorber. (a) Side viewof the three-layer structure, also showing the incident wavevector kinc

and polarization angle; (b) top view of the double-rectangle pattern;(c) top view of the L-shape pattern. Note that gold (Au) is used forthe metallic patterns and the ground plane, and Al2O3 is used for thedielectric film or spacer.

Table 1Geometric parameters for the metamaterial structure used in thepresent study.

Period Λ [μm] 3.2

Thickness of top metallic pattern h [nm] 100Thickness of dielectric spacer d [nm] 140Length of long side w1 [μm] 1.7

Length of short side of rectangle w2 [μm] 1.1

Length of short side of L-shape w2 [μm] 0.85

Length of margin s1 [μm] 0.15

Length of margin s2 [μm] 0.10

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]]2

Although polarization-dependent radiative properties ofasymmetric metamaterials have been observed [18–20],the near-field coupling in these structures has not beenfully investigated. Further studies on the resonant mecha-nisms and coupling effects in metamaterial absorbers oremitters are necessary in order to better understand theirpolarization sensitivity to assist future design tailoredtoward specific applications.

The present study deals with two patterns that supportmagnetic resonances for dual-band emission or absorptionpeaks. A comparative study of the two metamaterialdesigns with different polarization dependences is per-formed. Both designs consist of a three-layer metamaterialstructure with a metal (gold) pattern, a dielectric (Al2O3)film, and a gold ground plane. The difference lies in thatunit cell of the top layer has different gold patterns. One ofthe structures is made of two separate gold rectangles andthe other is constructed by connecting the two rectanglesto form an L-shape pattern. The former structure showspolarization-independent radiative properties, while thelatter exhibits strong polarization dependence. The objec-tive of this study is to explore the underlying mechanismsthat result in either polarization-dependent or polarization-independent radiative properties near the magnetic reso-nance or magnetic polariton (MP) wavelengths. The finite-difference time-domain (FDTD) technique is employed tocalculate the radiative properties and the electromagneticfield distributions, which are then used to elucidate theresonance mechanism and to scrutinize the near-fieldcoupling effect. Furthermore, the inductor–capacitor (LC)circuit model is developed for each structure consideringthe different geometries following the field distributions toquantitatively predict the MP frequencies.

2. Metamaterial structures and numerical method

Fig. 1 shows a unit cell of the double-rectangle andL-shape metamaterial emitters or absorbers. Gold patternsare placed over a dielectric film or spacer (Al2O3) on aground plane made of a gold film that is thick enough tobe treated as opaque. In the following, the rectangularpattern whose long side is along the y-direction is calledthe vertical rectangle, and the one along the x-direction iscalled the horizontal rectangle. The geometric parametersinclude period Λ, thickness of gold patterned layer h,thickness of dielectric layer d, long-side length w1, short-side length w2, and distances between the edge of the goldpattern and cell boundary s1 and s2. The parameters usedfor both metamaterial structures are listed in Table 1.

The FDTD method (Lumerical Solutions, Inc.) is used forcalculating the infrared reflectance of the two metamater-ial emitters and absorbers by solving the Maxwell equa-tions. The optical constants of gold and Al2O3 are obtainedfrom Palik [21]. For simplicity and ease of revealing theunderlying mechanisms, the refractive index of Al2O3 isassumed to be constant according to n¼1.57 at thewavelength λ¼6.25 μm. In practice, Al2O3 becomes dis-persive at wavelengths beyond 8 μm, resulting in a drop ofthe refractive index along with an increased absorption.Although the effect of the dispersive behavior should betaken into account for more realistic simulation, the focus

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

of the present study is on elucidating the underlyingmechanisms and therefore Al2O3 is treated as a losslessnondispersive dielectric. A unit cell of the consideredstructure is calculated using periodic boundary conditions

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 3: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

Fig. 2. Normal spectral emittance for (a) the structure with double-rectangle gold pattern, which is independent of the polarization angle ψ,and (b) the structure with L-shape pattern for different ψ. Note thatcurves for ψ¼01 and 901 overlap with each other.

H H

Fig. 3. Electromagnetic field profile at the resonant wavelength at ψ¼01:(a) λ¼4.72 μm where the resonance is under the horizontal rectangle;(b) λ¼6.67 μm where the resonance is under the vertical rectangle.The contour shows the relative magnitude of the y-component ofthe magnetic field. The arrows show the direction and magnitude ofthe electric field.

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]] 3

along both x and y directions. A perfectly matched layer isassumed along the propagation direction (z-direction sinceonly normal incidence is considered). The plane of inci-dence is parallel to the x–z plane, and the polarizationangle ψ is defined, as shown in Fig. 1, such that thetransverse magnetic (TM) wave and the transverse electric(TE) wave are at ψ¼01 and 901, respectively. A frequencydomain power monitor is placed above the plane wavesource to detect the reflected waves. According to Kirchh-off's law [22], spectral-directional emittance ελ is equal tospectral-directional absorptance αλ, which is equal to1�Rλ since the metamaterial structure is opaque. Normalspecular reflectance Rλ is simulated from the FDTD. All ofthe FDTD simulations in this study are performed in 3Dcomputational domain. It takes approximately 1 h to run afull spectral calculation for a certain polarization on a dualeight core XEON E5-2687W workstation with all theprocessors running in parallel.

3. Results and discussion

3.1. Polarization independence of metamaterial

The normal spectral emittance for both structures isshown in Fig. 2. It can be seen that emittance for thedouble-rectangle patterned metamaterial is enhanced sig-nificantly around λ¼4.72 μm and 6.67 μm and the emit-tance is independent of the polarization angle. On theother hand, the polarization effects can be observed inFig. 2b for the L-shape patterned metamaterial. Note thatthe curves for the cases ψ¼01 and 901 overlap but theother curves show distinct differences, even for 451 and1351 polarization angles. The emittance peak for theresonance at the longer wavelength shows up for ψ¼451but disappears when ψ¼1351. The reverse is true for theresonance at the shorter wavelength where the emittancepeak occurs for ψ¼1351 but disappears when ψ¼451. Thefollowing focuses on the case of the double-rectanglepatterned metamaterial. The L-shape patterned metama-terial will be discussed in Section 3.2.

Similar to the structure for which the unit cell has justone single rectangular pattern, the physical mechanismresponsible for the wavelength-selective emission andabsorption in the double-rectangle pattern can beexplained as due to the excitation of MPs [7,8,23–25].As shown in Fig. 3, the electric and magnetic fields ofthe double-rectangle patterned structure are visualizedwith ψ¼01 at the cross-section along the x–z plane in themiddle of the vertical and horizontal rectangles, respec-tively, at the corresponding resonance wavelength. Thecontour indicates the strength of the resulting magneticfield normalized to the incident, and the vectors representthe direction and magnitude of electric field. The magneticfield inside the dielectric spacer is greatly enhanced,indicating the diamagnetism response. The oscillatingantiparallel currents can be induced by the time-varyingmagnetic field and a closed current loop can be formed [8]around the enhanced magnetic field at the resonancewavelengths. This characteristic of electromagnetic fielddistribution shows excitation of magnetic resonanceor MPs.

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

Fig. 4 shows the magnetic field profile in the x–y planeat the middle of the dielectric spacer. As shown in Figs. 4aand 4b, when MPs are excited under TM-wave incidence

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 4: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

x

y

z

x

y

z

x

y

z

H H H H

Fig. 4. Magnetic field profile in the middle plane of the dielectric spacer.(a,b) The y-component for ψ¼01 at λ¼4.72 μm and λ¼6.67 μm, respec-tively; (c–f) ψ¼451 with λ¼4.72 μm in (c and d) and λ¼6.67 μm in (eand f). Note that (c and e) are for the x-component, while (d and f) are forthe y-component of the magnetic field. The contour shows the squaremagnitude of the magnetic field relative to the incidence and all figuresused the same scale bar at the bottom.

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]]4

(ψ¼01), the field enhancement only occurs under thevertical and horizontal rectangles at the resonant wave-length λ¼4.72 μm and 6.67 μm, respectively. For TE-waveincidence (ψ¼901), since it can be viewed as TM-waveincidence with a 901 rotation of the x–y plane along the z-axis, the result is simply the interchange of the fieldenhancement between the two rectangles and the mag-netic field is changed from the y direction to the xdirection. However, for other polarization angles, the fieldenhancement locations will not be the same, though theabsorptance is polarization-independent. Fig. 4b–f showsthe x- and y-components of the magnetic field for thepolarization angle ψ¼451. For the MP resonance atλ¼4.72 μm, the x-component of magnetic field excitesthe MP under the horizontal rectangle (Fig. 4c), and

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

the y-component of magnetic field excites the MP underthe vertical rectangle (Fig. 4d) simultaneously. Because theincoming magnetic field is split into two directions, thefield strength is not as strong as in Fig. 4a and b. Sincethe enhancement of the magnetic field in both directionscontributes to the absorption, the overall absorptance isthe same as for ψ¼01. Similarly, for resonance atλ¼6.67 μm, the x-component of magnetic field excitesthe MP under the vertical rectangle (Fig. 4e), and the y-component of magnetic field excites the MP under thehorizontal rectangle (Fig. 4f) simultaneously, and theycontribute equally to the absorption enhancement. Forother polarization angles, the field enhancement isunevenly distributed to these two patterns at the MPresonance wavelength, although not shown. It is interest-ing to note that while the macroscopic far-field radiativeproperties are independent of the polarization angle. Thenear-field power dissipation or absorption distribution isvery different. The difference may be employed for localselective heating with a spatial resolution on the order of1 μm. These two rectangular patterns are separated and,therefore, there is no field coupling between each other,resulting in the dual peaks that are independent of thepolarization angle. Note that the MP resonance atλ¼4.72 μm is associated with the length of the short sidew2 of the rectangular pattern and the MP resonance atλ¼6.67 μm depends on the length of the long side w1,which can be explained with an LC model as discussed next.

The circuit model has been successfully applied topredict magnetic resonance conditions for nanostructures[26–30]. Especially, our previous work [29] focuses on thedevelopment of a RLC circuit model and the structureconsidered has only one emission peak. The RLC circuitmodel includes the effect of resistance so that it canpredict both the resonance wavelength and the shape ofemission spectra. The present study aims at investigatingthe different polarization mechanisms of the differentpatterns. For simplicity, the LC circuit model shown inFig. 5 is used to explain the MP resonances for eachstructure considering the different geometries. WhenMPs are excited, electromagnetic field is strongly confinedbetween the top metallic structure and the bottom metal-lic film. Therefore, the considered structure can beassumed to be metal strip pairs although a thick bottommetallic film is used. For the double-rectangle patternedmetamaterial, the MPs can be excited independently foreach rectangle. The total impedance for the LC circuit asshown in Fig. 5 can be expressed as

ZtotðωÞ ¼ 21

ω2CmþLkþLm

� �ð1Þ

where Lm is the magnetic inductance or mutual induc-tance, which is originated from the magnetic energystored in the dielectric spacer of distance d between thetwo parallel plates. Lk is the kinetic inductance, which isoriginated from the kinetic energy of the electrons insidethe metal. The dielectric that separates top metal structureand the ground plate serves as a capacitor and a capaci-tance Cm is considered. Gap capacitance which describesthe capacitance of the air gap between the neighboringpatterns is negligibly small compared to Cm and thus is not

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 5: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

Fig. 5. Schematic of the equivalent LC circuit for both structures. Notethat the parameter modeling is different for the two structures asdiscussed in the text.

Fig. 6. Normal emittance contour for the L-shape patterned metamaterial.

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]] 5

included in the model. These four parameters are definedas [30]

Lm ¼ 12μ0

wdl; Lk ¼ � w

ε0ω2lδε0

ðε02þε002Þ; and

Cm ¼ c0εdε0wld

ð2Þ

where w and l are the characteristic lengths perpendicularand parallel to the main stream of magnetic field, respec-tively. Penetration depth of the electric field δ¼λ/2πκ,where κ is the extinction coefficient, is introduced. Also, anoptimized parameter c0 represents the fringe effect or non-uniform charge distribution along the surface of capacitorand can be varied between 0.2 and 0.3 [27]. The resonancewavelength can be obtained by zeroing the total impe-dance in Eq. (1). For the resonant wavelength λ¼4.72 μm,the MP is mainly excited by the short side, therefore,the optimized parameters c0 can be obtained as 0.279 withw¼w2 and l¼w1. For the resonant wavelength λ¼6.67 μm, the MP is mainly excited by the long side, there-fore, the optimized parameters c0 can be obtained as 0.234with w¼w1 and l¼w2. Note that the predicted resonancewavelengths are independent of length l since it is can-celed out in the LC model. Consequently, the predicted MPresonance wavelengths agree well with the FDTDsimulation.

3.2. Polarization-dependent metamaterial

The strong polarization effects shown in Fig. 2 can beclearly seen in Fig. 6 for the L-shape patterned metamaterial,especially at the wavelength when either of the resonances isexcited. The first and second resonances are at λ¼5.70 μmand 8.13 μm, respectively. The emittance of TE and TMwavesare identical for normal incidence for any wavelength due tothe symmetry of the structure, which can be also observed inFig. 6 at ψ¼01, 901, and 1801. Both of the emittance peaksshow up in the spectrum at these polarization angles.However, at ψ¼451, only the peak at λ¼5.70 μm occurs,while at ψ¼1351, only the peak at λ¼8.13 μm, which showsstrong polarization dependence.

The instantaneous electromagnetic field distributionsare shown in Fig. 7 in order to explain the effect ofpolarization for the L-shape pattern metamaterial. Theseelectromagnetic field profiles are for the plane in themiddle of dielectric spacer at the resonant wavelengthunder illuminations of different incidence with varyingpolarization angles. The magnitudes of incident electricwave are all unit. The contour shows the z component ofthe electric field normalized by the magnitude of the

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

incident electric field and the vectors show the directionand magnitude of the magnetic field. Also, the length ofthe arrows indicates the magnitude of the instantaneousmagnetic field and the scale bar for the magnetic fields isthe same for all plots. The wavelengths of incidence areλ¼5.70 μm and 8.13 μm in Fig. 7a–d and Fig. 7e–h,respectively. Also, the polarization angles are 01, 451, 901,and 1351. Although it does not show here, the case forpolarization angle ψ¼1801 was calculated, and the fieldsare pointing to the opposite direction at each space pointfor both the electric and magnetic field as compared withthe case for ψ¼01, since ψ¼1801 can be treated as ψ¼01with an additional π phase delay. It clearly shows that themagnetic fields in Figs. 7a and 7c are generally pointing tothe same direction. Since the electromagnetic field atψ¼451 can be obtained by linearly adding the field shownin Figs. 7a and c with an amplitude modulation of

ffiffiffi2

p=2,

the resonance in Fig. 7b is enhanced. Similarly, the field atψ¼1351 can be obtained by linearly adding the fieldshown in Fig. 7c with an amplitude modulation of

ffiffiffi2

p=2

and the field for ψ¼1801 with the same amplitudemodulation. Since the field for ψ¼1801 is pointing to theopposite direction compared with Fig. 7a, the magneticfields cancel out with each other and resonance effect issuppressed at ψ¼1351 as shown in Fig. 7d. This is thereason why at λ¼5.70 μm the emittance peak is max-imized at ψ¼451. Similar explanation can be applied tounderstand the polarization dependence at λ¼8.13 μm.However, at this wavelength, the magnetic fields in Figs. 7eand 7g, which correspond to ψ ¼ 01 and 901, respectively,are generally pointing to opposite directions. Also, themagnetic field which correspond to ψ ¼ 901 (Fig. 7g) andthe case for ψ ¼ 1801, respectively, are pointing to thesame direction, resulting in that the resonance is enhancedat the polarization angle of 1351 (Fig. 7h) but annihilatedwhen the polarization angle is 451 (Fig. 7f). Therefore, theemittance peak is maximized at ψ ¼ 1351 for λ¼8.13 μm.Another explanation for the polarization dependence isthe in-phase and anti-phase electromagnetic resonancesas shown in Fig. 8, which depicts the time-dependentnormalized amplitude of the magnetic field in the middleof dielectric spacer. Since a pulse source in the timedomain is used in the simulation, the resonances are builtafter 200 fs. After 200 fs, the resonance for different

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 6: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

zE E

Fig. 7. Electric field contour at each resonant wavelength in the middleplane of the dielectric spacer with varying polarization angles. Thecontour shows the relative magnitude of the z component of the electricfield. The arrows show the direction and magnitude of the magneticfield: (a) ψ¼01, (b) ψ¼451, (c) ψ¼901, and (d) ψ¼1351 at λ¼5.70 μm;(e) ψ¼01, (f) ψ¼451, (g) ψ¼901, and (h) ψ¼1351 at λ¼8.13 μm.

Fig. 8. Time-dependent normalized amplitude of magnetic field at thecenter of the dielectric spacer: (a) the in-phase response and (b) the anti-phase response.

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]]6

polarization shows the in-phase and anti-phase feature.For λ¼8.13 μm, it is clearly observed that the magnetic

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

field for the cases ψ ¼ 901 and 1801 are in-phase response(Fig. 8a), on the other hand, the magnetic field for thecases ψ ¼ 01 and 901 are anti-phase response (Fig. 8b).Therefore, the resonances are enhanced by the in-phaseresponse and annihilated by the anti-phase response.These interference effects and the existence of the eigen-polarization states for each wavelength have been alsodiscussed in detail by Zhao et al. [31]. The polarizationangles ψ ¼ 451 and 1351 are the eigenpolarization in theconsidered L-shape pattern metamaterial. For other polar-ization angles, the resonance magnitude falls in betweenthe maximum and minimum cases.

For the L-shape pattern metamaterial, the two reso-nances at λ¼5.70 μm and 8.13 μm can be attributed to theMPs. However, the electromagnetic fields are differentfrom MPs in the metamaterial with double-rectanglepatterns as shown in Fig. 7. For wavelength λ¼5.70 μmand ψ ¼ 451 (Fig. 7b), the magnetic field is curved alongthe diagonal. For wavelength λ¼8.13 μm and ψ ¼ 1351(Fig. 7h), the magnetic field along the diagonal can also beobserved. Therefore, all the parameters used in Eq. (1)have to be reevaluated for the L-shape metamaterial basedon the field distribution at resonances. For the resonant

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 7: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]] 7

wavelength λ¼5.70 μm, the modified mutual and kineticinductance and capacitance can be evaluated as

Lm ¼ 12μ0

ðffiffiffi2

p=2Þw1d

ðπ=4Þw1¼

ffiffiffi2

p

πμ0d ð3Þ

Lk ¼ � ðffiffiffi2

p=2Þw1

ε0ω2ðπ=4Þw1δε0

ðε02þε002Þ ¼ � 2ffiffiffi2

p

πε0ω2δε0

ðε02þε002Þ ð4Þ

Cm ¼ c0εdε03w2

14d

ð5Þ

For the inductance calculation, the length l is assumed tobe curved along the diagonal, and also the characteristiclength w is defined along the diagonal. For the capacitance,the area of L-shape pattern is simply calculated 3/4 of w2

1.Note that the relationship w1 ¼ 2w2 has been used to obtainEqs. (3)–(5). For the resonant wavelength λ¼8.13 μm, themodified parameters can be expressed as

Lm ¼ 12μ0

ffiffiffi2

pw1d

ðffiffiffi2

p=2Þw1

¼ μ0d ð6Þ

Lk ¼ �ffiffiffi2

pw1

ε0ω2ðffiffiffi2

p=2Þw1δ

ε0

ðε02þε002Þ ¼ � 2ε0ω2δ

ε0

ðε02þε002Þ ð7Þ

Cm ¼ c0εdε03w2

14d

ð8Þ

Since the mainstream of magnetic field is not curved, thecharacteristic lengths can be defined along the diagonals. Theoptimized parameters c0 for the L-shape pattern metamater-ial can be obtained as 0.253 and 0.231 for fitting the resonantwavelengths λ¼5.70 μm and 8.13 μm, respectively. Conse-quently, this explanationwith the LC circuit model is valid forthe L-shape metamaterial. Thus, the two emittance peaks aredue to two different modes of MPs.

4. Conclusions

The spectral radiative properties of metamaterialsmade of either double-rectangle or L-shape gold patternare investigated based on FDTD simulations. Dual-bandemission or absorption peaks can be achieved in theinfrared region from both structures and can be explainedby magnetic resonances quantitatively using the LC circuitmodel considering the particular geometry and field dis-tributions in each structure. For the two disconnectedrectangular patterns, polarization insensitivity can beobtained at normal emittance. However, strong near-fieldcoupling or interference can occur in the L-shape pat-terned metamaterial, resulting in polarization selectivity ofthe individual emission peaks. The underlying mechan-isms are illustrated with the field distributions. The knowl-edge gained from this work may benefit the design ofwavelength-selective multi-band emitters or absorbersthat are either polarization independent or polarizationselective.

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

Acknowledgments

This work was supported by the National ScienceFoundation (CBET-1235975).

References

[1] Fu CJ, Zhang ZM. Thermal radiative properties of metamaterials andother nanostructured materials: a review. Front Energy Power EngChina 2009;3:11–26.

[2] Watts CM, Liu XL, Padilla WJ. Metamaterial electromagnetic waveabsorbers. Adv Mater 2012;24:OP98–120.

[3] Pendry JB, Holden AJ, Robbins DJ, Stewart WJ. Magnetism fromconductors and enhanced nonlinear phenomena. IEEE Trans MicrowTheory Tech 1999;47:2075–84.

[4] Liu XL, Tyler T, Starr T, Starr AF, Jokerst NM, Padilla WJ. Taming theblackbody with infrared metamaterials as selective thermal emitters.Phys Rev Lett 2011;107:045901.

[5] Landy NI, Sajuyigbe S, Mock JJ, Smith DR, Padilla WJ. Perfectmetamaterial absorber. Phys Rev Lett 2008;100:207402.

[6] Aydin K, Ferry VE, Briggs RM, Atwater HA. Broadband polarization-independent resonant light absorption using ultrathin plasmonicsuper absorbers. Nat Commun 2011;2:517.

[7] Wang LP, Zhang ZM. Wavelength-selective and diffuse emitterenhanced by magnetic polaritons for thermophotovoltaics. ApplPhys Lett 2012;100:063902.

[8] Zhao B, Wang LP, Shuai Y, Zhang ZM. Thermophotovoltaic emittersbased on a two-dimensional grating/thin-film nanostructure. Int JHeat Mass Transf 2013;67:637–45.

[9] Wu CH, Khanikaev AB, Adato R, Arju N, Yanik AA, Altug H, et al. Fano-resonant asymmetric metamaterials for ultrasensitive spectroscopyand identification of molecular monolayers. Nat Mater 2012;11:69–75.

[10] Liu N, Mesch M, Weiss T, Hentschel M, Giessen H. Infrared perfectabsorber and its application as plasmonic sensor. Nano Lett 2010;10:2342–8.

[11] Zhang BX, Zhao YH, Hao QZ, Kiraly B, Khoo IC, Chen SF, et al.Polarization-independent dual-band infrared perfect absorber basedon a metal–dielectric–metal elliptical nanodisk array. Opt Express2011;19:15221–8.

[12] Tao H, Bingham CM, Pilon D, Fan KB, Strikwerda AC, ShrekenhamerD, et al. A dual band terahertz metamaterial absorber. J Phys D –

Appl Phys 2010;43:225102.[13] Chen K, Adato R, Altug H. Dual-band perfect absorber for multi-

spectral plasmon-enhanced infrared spectroscopy. ACS Nano2012;6:7998–8006.

[14] Montelongo Y, Tenorio-Pearl JO, Milne WI, Wilkinson TD. Polariza-tion switchable diffraction based on subwavelength plasmonicnanoantennas. Nano Lett 2013;14:294–8.

[15] Syrenova S, Wadell C, Langhammer C. Shrinking-hole colloidallithography: self-aligned nanofabrication of complex plasmonicnanoantennas. Nano Lett 2014;14:2655–63.

[16] Grady NK, Heyes JE, Chowdhury DR, Zeng Y, Reiten MT, Azad AK,et al. THz metamaterials for linear polarization conversion andanomalous refraction. Science 2013;340:1304–7.

[17] Black L-J, Wang YD, de Groot CH, Arbouet A, Muskens OL. Optimalpolarization conversion in coupled dimer plasmonic nanoantennasfor metasurfaces. ACS Nano 2014;8:6390–9.

[18] Canfield BK, Kujalal S, Jefimovs K, Vallius T, Turunen J, Kauranen M.Polarization effects in the linear and nonlinear optical responses ofgold nanoparticle arrays. J Opt A – Pure Appl Opt 2005;7:S110–7.

[19] Yang J, Zhang J-S, Wu X-F, Gong Q-H. Resonant modes of L-shapedgold nanoparticles. Chin Phys Lett 2009;26:067802.

[20] Husu H, Mäkitalo J, Laukkanen J, Kuittinen M, Kauranen M. Particleplasmon resonances in L-shaped gold nanoparticles. Opt Express2010;18:16601–6.

[21] Palik ED. Handbook of optical constants of solids, vol. I and vol. II.San Diego, CA: Academic Press; 1997.

[22] Zhang ZM. Nano/microscale heat transfer. New York: McGraw-Hill;2007.

[23] Lee BJ, Wang LP, Zhang ZM. Coherent thermal emission by excitationof magnetic polaritons between periodic strips and a metallic film.Opt Express 2008;16:11328–36.

[24] Wang LP, Zhang ZM. Phonon-mediated magnetic polaritons in theinfrared region. Opt Express 2011;19:A126–35.

[25] Wang LP, Haider A, Zhang ZM. Effect of magnetic polaritons on theradiative properties of inclined plate arrays. J Quant Spectrosc RadiatTransf 2014;132:52–60.

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i

Page 8: Effect of polarization on dual-band infrared metamaterial ... et al. 2014 JQSRT.pdfEffect of polarization on dual-band infrared metamaterial emitters or absorbers Atsushi Sakuraia,b,

A. Sakurai et al. / Journal of Quantitative Spectroscopy & Radiative Transfer ] (]]]]) ]]]–]]]8

[26] Engheta N. Circuits with light at nanoscales: optical nanocircuitsinspired by metamaterials. Science 2007;317:1698–702.

[27] Zhou J, Economon EN, Koschny T, Soukoulis CM. Unifyingapproach to left-handed material design. Opt Lett 2006;31:3620–3622.

[28] Sakurai A, Zhao B, Zhang ZM. Prediction of the resonance conditionof metamaterial emitters and absorbers using LC circuit model.In: Proceedings of the 15th international heat transfer conference,IHTC15-9012; 2014. p. 1–10.

Please cite this article as: Sakurai A, et al. Effect of polarization oJ Quant Spectrosc Radiat Transfer (2015), http://dx.doi.org/10.1

[29] Sakurai A, Zhao B, Zhang ZM. Resonant frequency and bandwidth ofmetamaterial emitters and absorbers predicted by an RLC circuitmodel. J Quant Spectrosc Radiat Transf 2014;149:33–40.

[30] Zhao B, Zhang ZM. Study of magnetic polaritons in deep gratings forthermal emission control. J Quant Spectrosc Radiat Transf 2014;135:81–9.

[31] Zhao B, Sakurai A, Zhang ZM. Polarization dependence of thereflectance and transmittance of anisotropic metamaterials. AIAA JThermophys Heat Transf (Forthcoming).

n dual-band infrared metamaterial emitters or absorbers.016/j.jqsrt.2014.11.018i