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Edit here in Slide Maste “Quantum Mechanics in Our Lab.” Optoelectronics and Semiconductors Laboratory 김김김 , 김김김 , 김김김

Edit here in Slide Master. Table of contents 1.Introduction to Laboratory 2.Raman spectroscopy 3. Photoluminescence

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Edit here in Slide Master Slide 2 Table of contents 1.Introduction to Laboratory 2.Raman spectroscopy 3. Photoluminescence Slide 3 Edit here in Slide Master 1. Introduction to Laboratory Slide 4 Edit here in Slide Master Slide 5 Introduction to Laboratory Graphene 2-dimensional (2D) honeycomb lattice consisting of carbon atoms Solar Cell Semiconductors which convert Sun light into electricity Raman spectroscopy, Photoluminescence Slide 6 Edit here in Slide Master 2. Raman spectroscopy Slide 7 Edit here in Slide Master Raman spectroscopy In the Raman effect a photon is scattered inelastically by a crystal, with creation or annihilation of a phonon. RayleighAnti-Stokes Stokes Virtual state =0 1 2 Slide 8 Edit here in Slide Master Phonon quantized elastic wave simple model of phonon linear lattice of particles connected by springs. Phonon Slide 9 Edit here in Slide Master Phonon Slide 10 Edit here in Slide Master Phonon Optical The atoms vibrate against each other, but their center of mass is fixed. Acoustic The atoms move together. Raman probes k=0 because of the very small momentum of photon Slide 11 Edit here in Slide Master Example of Raman spectrum -Raman spectrum of single crystal CZTSe Slide 12 Edit here in Slide Master 3. Photoluminescence Slide 13 Edit here in Slide Master Photoluminescence (PL) Slide 14 Edit here in Slide Master Photoluminescence (PL) DFT(Density Functional Theory) Tight binding First principle kp perturbation theory Solution of Hamiltonian Slide 15 Edit here in Slide Master Tight binding model in 1D Slide 16 Edit here in Slide Master Application of PL GaAs band structure Diatomic crystal (2 atoms per unit cell) Slide 17 Edit here in Slide Master Thanks for your attention! Q&A