Eco Friendly Textile

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    TECHNOLOGY OF ECO-FRIENDLY TEXTILE

    PROCESSING- A ROUTE TO SUSTAINABILTY

    KEYNOTE PRESENTED BY

    Asif Muhammad Sami

    BSc . Textil e Engg, MBA , CText (ATI), Fellow - IEB, Textile Consult antCEO- EuroAsiatic Resources, Chairman - S S Vision Ltd &

    Textile Consultant - Perseus Ltd.

    Cell: 01819213971, email: [email protected]

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    ABSTRACTS:

    Textile Project like eco-friendly or green project must bedesigned for sustainable green factory building conceptalso textile raw materials , dyes & chemicals, textileprocesses all should be based on 3R (reduce-recycle-reuse) concept.

    The processing of textiles should be cost effective andenvironment-friendly. Innovative and efficient strategiesto achieve these goals are needed. This paper reportsvarious problems in different stages of processingtextile materials and theirgreen solutionsthealternatives by which the problems can be avoided

    through innovative techniques and various measures oftextile cleaner production(CP)which ensures textileprocessing eco-friendly, cost effective andsustainable business.

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    ECO FRIENDLY / GREEN TEXTILES CONCEPT

    The project factory building should be designed on go greenconcept.

    Textile raw materials are processed in eco-friendly manner

    and certified by GOTS etc.

    Dyes and chemicals should be OKEOTEX certified standard.

    Textile processing right from Raw fiber, Yarn manufacturing,Weaving/knitting, wet processing, finishing processes allshould be maintained using eco- friendly technology.

    Textile waste water should be treated considering basis of 3R(reduce- recycled & re-use ) concept.

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    ECO- FRIENDLY TEXTILES PROCESSING CONCEPT

    Textile Cleaner Production (CP) like Water saving, energy

    savings using all possible methods.

    Re-use of textile waste, recycled & re-use of waste water,

    recovering and re-using salt, re-use of waste heat energy.

    Carbon emission control

    Environmental sustainability care for the environment- Influence the supply chain to use sustainable

    processes/method.

    Operate business in environmental friendly way.

    Work to conserve water, energy and reduce / recycle waste.

    Sustainable design approachexplore the use sustainable

    materials and products.

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    NEED FOR ECO- FRIENDLY & RECYCLABLE +

    RE-USABLE TEXTILES:

    Concerns related to textile industries are-

    Textiles production and processing- chemical intensive

    applications

    Associated social and environmental concerns

    GROWING CONCERNS- Increasing industrial pollution

    Industrial waste disposal problems

    Economic and social health of the farmers and industrial

    workers.

    Unawareness about socially responsible business structures

    are required.

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    ENERGY SAVING GREEN FACTORY BUILDING SHED:

    Using insulation of building walls, floor & ceiling.

    Replace old windows which are bad thermal insulators.

    Make the building shell as air tight as possible.

    Install heat exchange for proper ventilation.

    Roof of sunny side should use collects solar energy. Heavily frequented door should have automatically closing

    system.

    Light from shaded side yields natural light but not heat.

    New building using geothermal energy exchange.

    Use of insulation of all steam pipe and wire duct.

    Using rain water for garden irrigation, technical use or as

    toilet flash water.

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    WHY WE ALL NEED TO BE CONCERN ABOUT ECO-

    FRIENDLY (GREEN) PROCESSING IN TEXTILES:

    Textiles /Garment industry is contributing to the global warming& pollution from the stages like -

    Cultivation of the fibres

    Yarn manufacture

    Fabric manufacture wet processing

    Manufacturing of the garment

    Transportation to customers

    Usage and disposal

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    ECO-FRIENDLY OR GREEN SOLUTIONS

    Substitute cotton for other natural eco- friendly materials like

    hemp, wool, organic cotton, soy silk, bamboo fabrics ,jute,

    corn fibre etc having without any harmful effects of chemicals

    or toxics.

    Synthetic fabrics such as polyesters are

    - Easy care and more durable alternative to natural fabrics.

    - These are more energy intensive in production, but these

    fibers need to be washed at lower temperatures thus saving

    a lot of energy throughout their life cycle.

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    ECO-FRIENDLY OR GREEN SOLUTIONS

    Cellulose based fibres like viscose can be used.

    There are now developments of new fibres of natural origin likeTencel (Lyocell) made from wood.

    EXAMPLES OF SOME ECO-FRIENDLY FIBERS :

    Organic Cotton, Organic wool, Organic Silk, Organic Jute etc

    Manmade fibers like corn/Soya bean, Pineapple, Banana leaf, Lyocell

    Recycled fibers like Recycled Cotton, Recycled Polyester

    Natural fiber like colored Raw Cotton

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    ORGANIC COTTONA SUSTAINABLE ALTERNATIVES

    SOCIAL AND ENVIRONMENTAL BENEFITS

    Organic Cotton helps in pollution control, improving soil

    fertility.

    Organic cotton farming helps in preventing contamination of

    water, soil & air.

    Apart from using in all diversified products, organic cotton

    also suitable for baby products, apparels, hygiene and careproducts like cotton balls, ear buds, sanitary pads, medical

    textiles, cosmetics bags etc.

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    RECYCLED COTTON;

    RECYCLED COTTON is nothing but made from recovered

    cotton that would otherwise be cast off during either spinning,weaving, knitting or garment cutting process.

    THE DISCARDED COTTON WASTE from above mentioned

    process are collected , shredded into small fibers and

    processed once again into yarns and fabrics in cost effectivemethod.

    RECYCLED COTTON is also known as eco friendly choice in

    clothing fashion industry.

    COTTON WASTE RE-CYCLING PROCESS involves no

    chemical addition rather it helps in generating employment

    and better positive impact in the environment (clean

    production).

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    RECYCLED POLYESTER (PET):

    Polyester is one the most non-biodegradable polymer which

    creates environmental problems.

    Wellman inc. Introduced in 1993 as the first polyester textile

    fiber made from post consumer pet packaging.

    Recycled pet is used in diversified products like backpacks and

    blankets, t-shirts, sportswear, soft luggage and socks etc.

    Eco friendly recycled pet is certified by OEKOTEX and SGS

    etc.

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    STAGE 2: YARN FABRICATION AND FABRIC

    MANUFACTURE

    Contributors to carbon footprint

    There are many stages required to process cotton from fibre

    to fabrics the fibre are cleaned, carded (combed) spun into

    yarn, coated with starches or chemicals, woven or knitted

    into fabrics,

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    CONTRIBUTORS TO CARBON FOOTPRINT & GREEN

    SOLUTION

    In sizing process ,starch is used in sticky paste form toyarn to enhance its strength and its abrasion resistance. The

    starch paste consists of preservative in order to protect it from

    the stains get formed on the fabrics surface.

    Some preservatives like penta-chloro phenol that are toxic

    effect on human skin, should be avoided by utilizing a

    synthetic starchdecreasing the health hazards.

    Use oil stain removerduring the weaving operations before

    textile wet process so that oil stains do not get formed.

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    PROCESS INVOLVEDCONTRIBUTION TOPOLLUTIONS

    FIBRE PREPARATION

    YARN SPINNING

    Fiber waste,

    Packaging waste,packaging waste, sized

    yarn, fiber waste,

    cleaning and processing

    waste

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    PROCESS INVOLVEDCONTRIBUTION TO POLLUTIONS

    SLASHING/SIZING

    WEAVING

    KNITTING

    Fiber lint, yarn waste, unused

    starch based sizes, water with

    high level of BOD, COD

    Packaging waste, yarn waste

    and fabric scraps, used oil.

    Waste yarn and fabric scraps

    packaging

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    WASTE YARN AND FABRIC SCRAPS PACKAGING

    Textile processing industry requires huge volume of water ,

    energy & various chemicals for Desizing, Scouring,

    Mercerization, dyeing, printing and finishing stage.

    Textile industry, backbone of fashion garments, is large

    variation in demand of type, pattern & color of fabric resulting

    into significant fluctuation in waste generation.

    Textile processing generates much waste steam, including

    liquid gaseous and solid wastes, some of which may be

    hazardous.

    Wet processing creates the highest volume of waste water.

    Textile finishing represents the most variable area in the

    production process. A wide and ever-growing range of finishes

    are now available that either improves the properties, handle or

    texture of the fabric.

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    TEXTILE WET PROCESSING- VITAL ENVIRONMENTAL

    ISSUE

    Some important environmental concerns related to textilewet processing;

    Intensive chemical based wet processing like scouring,bleaching, mercerizing, dyeing, printing etc

    Heavy metalslike iron, lead, copper etc consist indyestuffs auxiliaries, binders etc.

    Residual dyestuffs, chemicals in water:due to poordye fixation with fiber.

    PVC and Phathalets:used in Plastisol printing pasteand colorant fixatives.

    Formaldehyde: found in dispersing agents, printingpaste and colorant fixatives.

    Dye effluent-wastewater issue.

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    CONTRIBUTORS TO CARBON FOOTPRINT

    The conventional preparation process of Desizing, Scouring

    and Bleaching with their related wash-off stages, producesheavy BODin effluents.

    Chlorine used in bleaching creates halogenated organic

    substances, of which some are suspected to be carcinogenic

    e.G.., Chloroform thus is not preferred.

    Use of banned amines and toxic dyes,banned amines are

    the chemicals which are released from some of the azo dyes

    on reductive cleavage. These are suspected to be

    carcinogenic and being banned.

    Carriers ( disperse dyes) and solventsmay be emitted

    during dyeing operations may lead to volatilization of aqueous

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    CONTRIBUTORS TO CARBON FOOTPRINT

    hemical emulsions during heat setting, drying or curing process, thus

    creating harmful volatile organic compounds.

    Acetic acid and Formaldehyde are two major emissions of concern in

    textiles.

    Textile mills usually generate Nitrogen and Sulphur oxides from boilers.

    Significant sources of air emissions in textile operations -Resin finishing

    and dyeing operations, printing, fabric preparation and waste water

    treatment plants hydrocarbons are emitted .These processes can emit

    formaldehyde, acids, softeners and other volatile compounds.

    Wool industry used chlorine based compounds for anti-shrinking

    dealing and such practice also generates toxic effluents.

    Oxalic Acid is used for removing rust stains before bleaching. The

    oxalic acid is lethal aquatic organisms and increase COD & BOD to a

    significant level.

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    TEXTILE PROCESSES CONTRIBUTION TO POLLUTION

    SIZING

    DESIZING

    SCOURING

    BLEACHING

    Penta-chloro phenol as anti

    mildew agent

    Vocsfrom glycol esters

    Emulsifying agents like nonyl

    phenyl ethyloxylates, chloroformas scoring assistance.

    Hypochlorite (chlorine bleaching)

    products like chlorine dioxide

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    TEXTILE PROCESSES CONTRIBUTION TO POLLUTIONS

    DYEING & PRINTING

    FINISHING

    Azo dyes containing

    carcinogenic amines

    CDFA based on formaldehydes

    dyes containing heavy metals

    such as Iron, Zinc etc

    Formaldehyde as mordant

    Formaldehyde fixer/binder inpigment printing

    Formaldehyde as cross linker

    Reactive softener

    metal fluorides, DDT, and other

    anti bacterial materialscontaining metals in rot proofing.

    Amides like melamine amides in

    water repellent

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    ECO-FRIENDLY OR GREEN SOLUTIONS:

    Dyes made from natural pigments and soymilkused as

    binding agent and sizing agent makes the whole dyeing gentler

    on the environment.

    Dyes that forms carcinogenic amines on reduction and thus

    increase bod/cod need to be avoided.

    Where possible, use high fastness direct dyes having 90%upto 99% exhaustion rate should be chosen instead of using

    reactive dyes which having low exhaustion rate 65%-75% to

    reduce dyeing cost as well as etp running cost.

    Usage of Hydrolas a substitute of sodium sulphide isrecommended for sulphur dyeing.

    low salt

    Dyeing process requires more salt for exhaustion. So usage

    dyes may be used.

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    ECO-FRIENDLY OR GREEN SOLUTIONS:

    An integrated chemical pre-treatment (single bath

    process)

    i.e. Combined Desizing, Scouring, Bleaching is

    recommended to reduce the water, chemical consumption

    and also energy.

    Fabrics to be dyed with deeper shades may not be bleached.

    In case of dyeing and printing toxic chemicals may be

    avoided.

    Formaldehyde free resins and finishing chemicals may be

    used for finishing.

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    SUSTAINABLE PROCESSING OF TEXTILES:

    EXPLORE INTO BIO PROCESSING OF TEXTILES -

    Bio-processing can simply be defined as the applicant of livingorganisms and their components to industrial products and

    processes, which are mainly based on enzymes. Like-

    Enzymatic Desizing- by using Amylase bacteria.

    Enzymatic bio scouring ( by using lipase/cellulase enzyme)-saves water by 30% and energy upto 60%, less fabric weight loss &

    strength loss, better fabric quality and enhanced color brightness

    after dyeing & low TDS in discharge.

    Enzymatic bleaching(Catalases/laccases for removal of H2O2)

    saves water, energy, shorten bleaching process cycle, eco friendly

    process and consistent bleaching result, saves chemicals.

    * Bio polishing and Eznymatic based softeners (Cellulase) etc-

    enzymatic bio-finishing yields a cleaner surface, softer hand-feel,

    reduces pilling and increases luster.

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    EXPLORE INTO BIO PROCESSING OF TEXTILES -

    BIO-STONE WASHING (DENIM FINISHING)Using a special

    cellulase enzymeinstead of pumic stones. Cellulase works

    by loosening the indigo dye on the denim in a process known

    as bio-stonewashing. A small dose of enzyme can replace

    several kilograms of pumice stones. The use of less pumice

    stones results in less damage to garment, machine and less

    pumice dust in the laundry environment; in addition, itspossible to fade denim without risk of damaging the garment.

    DECOLORIZATION OF DYE HOUSE EFFLUENT BY ENZYME:

    Laccase enzymse produced from fungi like Trametes Modestaor Trametes Versicolo etc as Fungi are used for dye

    decolourization in effluent treatment which is major factor for

    environmental issue.

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    ECO-FRIENDLY OR GREEN SOLUTIONS:

    ECO-FRIENDLY SUPLHUR DYEING METHOD:Since sulphur dyesas single dyes alone consumption 20%-25% for cotton dyeingin the world. Using eco-friendly thioria di-oxide or indirectcathodic reduction/electrolysis method ( although relativeexpensive than traditional method) avoiding traditional sodiumsulphide can save dyes consumption.

    ECOFRIENDLY REACTIVE DYEING:Various environmentalproblems encountered in reacting such as high levels salt &high color concentration ( unfixed dyes) in effluent with hugevolume of water consumed.Reactive dyes poor fixation ofranging 10%-40% dyestuff hydrolysed goes down drain whichis aesthetically unpleasant, blocks sunlight, algae

    overpopulate, reduction in o2levels in water, suffocation offlora and fauna in water courses. Therefore, water effluenttreatment plant is now becoming prime consideration by theindustry and equally important as the production of textileproduct itself.

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    ECO-FRIENDLY OR GREEN SOLUTIONS:

    Significant amount of water consumption, energy

    consumption, dyeing cost and effluent load can minimized

    by using either cationic surfactants (instead of salts) Ordyes with high exhaustion rate 90%-99% ( preferably direct

    dyes) instead of reactive dyes with low exhaustion rate 60%-

    80%)

    As a result of being cationic (instead of anionic) pretreated

    cotton, the number advantages recorded such as:

    No requirement for salt

    Nucleophiles in polymer more reactive than hydroxyl roups in

    fibre.

    Neutral ph of application Hydrolysis minimised

    Colour fixation yield maximised

    Colour fixation yield maximised

    Less colour in effluent

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    ECO-FRIENDLY OR GREEN SOLUTIONS:

    Less wash-off requirement

    Significant reduction in operation time

    Significant reduction in water consumption

    DEGREE OF FIXATION OF DIFFERENT DYES ON FIBER

    ARE FOLLOWS:

    DYES----------- FIBER----------%FIXATION ----%LOSS IN ETP

    ACID DYES----POLYAMIDE--- 80-90--------------5.0-- 20.0

    BASIC DYES---- ACRYLIC--------- 95-100-------0.05.0

    DIRECT DYES --- CELLULOSE---85 - 99-------1.015.0 REACTIVE DYES -CELLULOSE-50.0- 85.0----15.050.0

    SULPHUR DYES-- CELLULOSE--60.0- 90.0---10.0-- 40.0

    DISPERSE DYES --- PES----------90.0100.0----0.010.0

    METAL COMPLEX --- WOOL-------9098 -------2.0

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    WATER FREE DYEING(SUPERCRITICAL FLUID DYEING):

    Uses carbon dioxide as the fluid medium on disperse-dyedsynthetics, eliminating aqueous effluent.

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    ECO- FRIENDLY EFFLUENT TREATMENT METHOD (BIO

    TECHNOLGY):

    Combined biological system with electron- beam or advancedoxidation process (AOP) method or Reverse Osmosis (RO).

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    SCHEMATIC PROCESS FLOW DIAGRAM OF ELOECTRON

    BEAM METHOD COMBINATION WITH BIOLOGICAL SYSTEM

    ETP

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    CLEANER PRODUCTION (CP) IN THE TEXTILE WET

    PROCESSING

    For sustainable eco-friendly textile processing ,cleanerproduction in each stage of specially textile wet processing is

    must. Cleaner production includes:

    Steam trap maintenance

    Insulation of un insulated steam and condensate return

    pipelines

    Insulation of steam valves, tanks, pumps etc.

    Re-use flash steam

    Using boiler economizer

    Insulated hot water tank with dyeing machine.

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    CLEANER PRODUCTION (CP) IN THE TEXTILE WET

    PROCESSING

    Condensate recovery Following right first time (RFT) dyeing method concept.

    Use multi functional concentrated chemicals and high

    exhaustion rate dyes reduces effluent problems.

    Huge water savingsby adopting eliminate water leaks in

    taps and pipes, use rain water, closed cooling system,

    continuous dyeing, digital printing, co2 dyeing, reduce

    washing and rinsing process cycles,

    Reuse water drained out of steam condensates

    Minimize washing and rinsing (overflow) operations

    CLEANER PRODUCTION IN THE TEXTILE WET

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    PROCESSING

    Reuse of the first wash water from solution preparation tanks

    Restrain hose pipe use and create a central cut sample washing place.

    Insulate steam pipes Optimize operation of air compressors and chilling plants

    Use transparent roofs

    Reduce spillage of chemicals

    Use of magnetic device for soft water in boiler.

    Recover and re- use of waste heat ( using heat exchanger)

    Co-generation/ tri generation system where ever feasible.

    Using frequency inverter, peak load management, servo motor where

    ever applicable, electronic ballast, energy saving lights,

    Increase fabric to water ratio to 1:6 or even less.

    Automatic boiler blow down mechanism

    Recovery & re-use of sodium sulfate using zero discharge etp

    Improve process control stages to avoid reprocessing

    Improve trial recipe in laboratory

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    CLEANER PRODUCTION IN THE TEXTILE WET

    PROCESSING

    Improve process control stages to avoid reprocessing

    Improve trial recipe in laboratory

    Use of magnetic device for soft water in boiler.

    Recover and re- use of waste heat ( using heat exchanger)

    Co-generation/ tri generation system where ever feasible.

    Using frequency inverter, peak load management, servomotor where ever applicable, electronic ballast, energysaving lights,

    Increase fabric to water ratio to 1:6 or even less.

    Automatic boiler blow down mechanism

    Recovery & re-use of sodium sulfate using zero discharge etp

    Improve process control stages to avoid reprocessing

    Improve trial recipe in laboratory

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    STAGE 4: GARMENT MANUFACTURING

    CONTRIBUTORS TO CARBON FOOTPRINT Many processes are involved in garment manufacturing and

    pollution occurs in each and every stage.

    1. In designing department making of prototypes produces

    garbages like fabric scraps, pattern papers stationary items,

    etc.

    2. Production department undertakes spreading, cutting and

    sewing responsibility. This department generates largeamount of waste in form of cardboard boxes, labels, tapes,

    thread cones, stickers and fabric scraps

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    CONTRIBUTORS TO CARBON FOOTPRINT

    3.Finishing department contributes to pollution while the fabric

    goes various processes like washing, pressing, stain removal,

    inspection, folding and packing. This consumes water and

    also some chemicals such as detergents, liquid soap,acetone, amyl, etc. Which are used in washing and stain

    removal and garbages also produced in packing of materials.

    4. Miscellaneous sections include computerised embroidery

    section, effluent treatment plant, kitchen, canteen, mess and

    general maintenance which also contribute in pollution.

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    DEPARTMENTSCONTRIBUTIONS TOPOLLUTIONS

    ADMINISTRATIVE

    DEPARTMENTS

    DESIGN & LINE DEVELOPMENT

    DEPERTMENTS

    PRODUCTION DEPARTMENT

    FINISHING DEPARTMENT

    MISCELLANEOUS DEPARTMENT

    Stationary waste, packing waste,

    etc

    Packing waste, fabric waste,

    paper pattern waste, etc

    yarn waste, packing waste,

    threads, tapes, fusing rolls, fabric

    scraps, ploy bags and stickers. Packing waste, chemicals

    contributing to high bod/cod

    levels in waste water.

    Packing waste, fabric scraps and

    fuel

    ECO FRIENDLY OR GREEN SOLUTIONS

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    ECO-FRIENDLY OR GREEN SOLUTIONS

    Various elements that are used in design i.E, colour, texture,

    fasteners, fabrics, etc, the components of these should be

    maintained as a ready data bank.

    Biodegradable trims should be preferred against synthetic trims

    e.G., Natural buttons made up of peral, wood, shell, leather,

    porcelain and bone.

    Plastic and metal buttons may be avoided.

    Avoid use of fusible interfacings, which incorporate solvent

    treated adhesives as solvents like formaldehyde have beenclassified as unsafe for the environment as per standard given

    by OEKO-TEX 100.

    * Use of materials such as heavy metals like chrome, lead, nickel

    used as fasteners like zippers and buttons are considered

    unfriendly to environment.

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    Use of large baler bags for storage or supplies especially at fabric

    store where the fabric is stored in individual poly bags.

    CAD & CAM system can be used to gain optimum fabric Utilization.

    Installation of leds (9w) at the needle points of sewing machines will

    help to reduce the overall requirements of tube lights in the stitching

    section.

    Regular maintenance, lubrication and upkeep of the machine using

    white oil Mobil oil will result in improvement in efficiency of the machine.

    Usage of eco-friendly lubricants and stain removers, which are free

    from chlorinated solvents.

    Prefer using of eco friendly hang tags that can be hung to the garment

    by thread rather than using plastic staple or string.

    * Apparel can be packaged in bio-degradable pvc-free packaging and in

    100% recycled cardboard boxes.

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    STEP 5: TRANSPORTATION AND DISTRIBUTION

    CONTRIBUTION TO POLLUTION

    Some forms of transportation have more emissionsthan the others for e.g. Transporting one tonne of goodsover a distance of 100 km emits 0.7 kg of CO2 by ship,or 158.0 kg by air.

    ECO-FRIENDLY OR GREEN SOLUTIONS

    Use the bus or train rather than car for transportinggoods and for travelling purpose.

    Consider cleaner fuels like ethanol e10 or Bio-dieselwhich reduces CO2 emission significant amount.

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    STAGE 6: USE OF TEXTILE GOODS AND DISPOSAL

    CONTRIBUTORS TO CARBON FOOTPRINT

    More than last two decades clothing has become increasingly

    affordable for everyone. Retailers and brands have

    capitalized on this affordability by moving away from summer

    and winter collection to fresh collections more than last twodecades clothing has become increasingly affordable for

    everyone.

    ECO FRIENDLY OR GREEN SOLUTIONS

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    ECO-FRIENDLY OR GREEN SOLUTIONS

    Recycle as much as possible.For example, old fabrics can

    be used to make wipes or to make quilts, appliqu work.

    Cellulosic waste fabric can be recycled for making handmade

    paper.

    ENVIRONMENTAL SUSTAINABILITY

    Need to believe in environmental sustainability

    Implementing incremental steps in supply chain process to

    accomplish.

    Need to be aware about the social, economical and ecologicalbenefits of environmentally sustainable product development

    processes.

    CONCLUSION:

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    CONCLUSION:

    The concept of eco-friendly designing products from start to

    finish has come about. It involves considering the ecological

    dimension of the entire production process, from the fibre to the

    finished product, including its manufacturing processes, butalso its packaging and labeling, right the way through to

    recycling & reuse the product at the end of its period following

    3R concept.

    So sustainable green trends in processing of textiles are:

    Maintaining of high & consistent quality product in costeffective manner.

    Improved functionality

    Lower generation of aqueous waste and off- gases

    Minimum use or reuse of water and chemicals

    Overall environment friendliness.

    Reduce water and energy consumption during preparation,

    coloration and finishing (CP).

    Improve process efficiency

    -Reduce exposure to hazardous chemicals

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    QUESTIONS AND ANSWERS ???

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