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Early Models of the Atom
History of the AtomStandard Atomic
Notation
Some Intro Songs for your entertainment:
The Atom Song: http://www.youtube.com/watch?v=vUzTQWn-wfE&NR=1 (3 min)
HISTORY OF THE ATOMHISTORY OF THE ATOM
460 BC Democritus develops the idea of atoms
- ancient Greek philosopher
-suggested that matter was made up of
tiny particles called:
- his theory was not accepted for 2000
years
ATOMOSATOMOS
(greek for indivisible)
HISTORY OF THE ATOMHISTORY OF THE ATOM
1808 John Dalton
- working with gases, reconsidered
Democritus’ theory that particles are
indivisible
- Described matter as tiny spheres that were
able to bounce around with perfect elasticity
and called them:ATOMSATOMS
History of the Atom
Dalton’s Atomic Model:1) All matter is made up of atoms, which are
particles too small to see2) Each element has its own kind of atom, with its
own particular mass3) Compounds are created when atoms of different
elements link to form molecules4) Atoms cannot be created, destroyed, or
subdivided in chemical changes
Problem with Dalton’s Theory:
– unable to explain the Electrical nature of matter:
Like charges repelUnlike charges attract
History of the Atom
1879 William Crookes- worked with cathode ray tubes- beam of particles was attracted to a
positive plate- these particles were called:
ELECTRONS
- have a negative charge
History of the Atom
1886 Eugen Goldstein
-most samples of matter are NOT charged
-the atom must contain positively charged particles
-used cathode ray tubes to prove this and they were called:
PROTONS
HISTORY OF THE ATOMHISTORY OF THE ATOM
1898 Joseph John Thompson
- atom had a positive core and electrons
were embedded in this
HISTORY OF THE ATOMHISTORY OF THE ATOM
Thompson develops the idea that an atom was made up of
electrons scattered unevenly within an elastic sphere
surrounded by a soup of positive charge to balance the
electron's charge
1904
like plums surrounded by pudding.
PLUM PUDDING
MODEL
Or
RAISIN BUN MODEL
HISTORY OF THE ATOMHISTORY OF THE ATOM
1910 Ernest Rutherford
- designed an experiment using RADIUM (this element spits out positive ALPHA particles)
- he placed a piece of gold foil in front of
the beam, surrounded by a screen to
detect the path of the particles
- they found that although most of them
passed through, about 1 in 10,000 hit
HISTORY OF THE ATOMHISTORY OF THE ATOM
gold foil
helium nuclei
They found that while most of the particles passed
through the foil, a small number were deflected and, to
their surprise, some particles bounced straight back.
helium nuclei
Rutherford’s Gold Foil ExperimentRutherford & Bohr (4 min)
http://videos.howstuffworks.com/hsw/25133-icons-of-science-bohr-and-the-structure-of-the-atom-video.htm
HISTORY OF THE ATOMHISTORY OF THE ATOM
Rutherford’s new evidence allowed him to propose a
more detailed model with a central nucleus.
He suggested that the positive charge was all in the
central nucleus. This held the electrons in place by
electrical attraction, so the electrons swarm around the
nucleus.
However, this was not the end of the story.
History of the Atom
1932 Chadwick- Nucleus contains another particle which
has NO charge (neutral) called a:NEUTRON
- This particle and the proton have approximately the same mass, but the electron is very small. It takes 1837 electrons to have the same mass as ONE proton or neutron.
HISTORY OF THE ATOMHISTORY OF THE ATOM
1913 Niels Bohr
studied under Rutherford at the Victoria
University in Manchester.
Bohr refined Rutherford's idea by
adding that the electrons were in
orbits. Rather like planets orbiting the
sun. With each orbit only able to
contain a set number of electrons.
ATOMIC STRUCTUREATOMIC STRUCTURE
SubatomicParticle
Location Charge Mass
Protons In nucleus Positive 1
Neutrons In nucleus Neutral 1
Electrons Orbit around nucleus
negative None (1/1837)
STANDARD ATOMIC NOTATIONSTANDARD ATOMIC NOTATION
the number of protons in an atom
the number of protons and neutrons in an atomHeHe
22
44 Mass number
Atomic number
Atomic number = number of electrons = number of protons
mass number – atomic number = number of neutrons
ATOMIC STRUCTUREATOMIC STRUCTURE
Electrons are arranged in Energy Levels
or Shells around the nucleus of an atom.
• first shell a maximum of 2 electrons
• second shell a maximum of 8
electrons
• third shell a maximum of 8
electrons
• fourth shell assume up to 8
electrons
ATOMIC STRUCTUREATOMIC STRUCTURE
There are two ways to represent the atomic
structure of an element or compound;
1. Electronic Configuration
2. Bohr-Rutherford Diagrams
ELECTRONIC CONFIGURATIONELECTRONIC CONFIGURATION
With electronic configuration, elements are
represented numerically by the number of
electrons in their shells and number of shells. For
example;
N
Nitrogen
7
142 in 1st shell
5 in 2nd shell
configuration = 2 , 5
2 + 5 = 7
ELECTRONIC CONFIGURATIONELECTRONIC CONFIGURATION
Write the electronic configuration for the following elements;
Ca O
Cl Si
Na20
40
11
23
8
17
16
35
14
28
B11
5
a) b) c)
d) e) f)
2,8,8,2 2,8,1
2,8,7 2,8,4 2,3
2,6
SUMMARYSUMMARY
1. The Atomic Number of an atom = number of
protons in the nucleus.
2. The Atomic Mass of an atom = number of
Protons + Neutrons in the nucleus.
3. The number of Protons = Number of Electrons.
4. Electrons orbit the nucleus in shells.
5. Each shell can only carry a set number of electrons.
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S.Morris 2006 – outline of this powerpoint