70
Drill: Draw & Name Reactants & Products of: •Two oxidations of 1-butanol:

Drill: Draw & Name Reactants & Products of:

Embed Size (px)

DESCRIPTION

Drill: Draw & Name Reactants & Products of:. Two oxidations of 1-butanol:. Drill: Draw & Name Reactants & Products of:. Oxidation of 2-butanol:. Drill: Draw & Name 3 isomers containing carboxyl groups of:. C 5 H 10 O 2. Drill: Draw & Name 4 isomers containing carboxyl groups of:. - PowerPoint PPT Presentation

Citation preview

Page 1: Drill: Draw & Name Reactants & Products of:

Drill: Draw & Name Reactants & Products of:

•Two oxidations of 1-butanol:

Page 2: Drill: Draw & Name Reactants & Products of:

Drill: Draw & Name Reactants & Products of:

Oxidation of

2-butanol:

Page 3: Drill: Draw & Name Reactants & Products of:

Drill: Draw & Name 3 isomers containing carboxyl groups of:

C5H10O2

Page 4: Drill: Draw & Name Reactants & Products of:

Drill: Draw & Name 4 isomers containing carboxyl groups of:

C6H12O2

Page 5: Drill: Draw & Name Reactants & Products of:

Acid Derivatives

Page 6: Drill: Draw & Name Reactants & Products of:

Acid Anhydrides

Page 7: Drill: Draw & Name Reactants & Products of:

Acid Anhydrides O O

R1-C-O-C-R2

Page 8: Drill: Draw & Name Reactants & Products of:

Acid Anhydrides•Formed through the dehydration of two carboxylic acids

Page 9: Drill: Draw & Name Reactants & Products of:

Making Anhydrides O O

R1-C-OH + HO-C-R2

Page 10: Drill: Draw & Name Reactants & Products of:

General Anhydride O O

R1-C-O-C-R2

+ H2O

Page 11: Drill: Draw & Name Reactants & Products of:

Making Anhydrides O

CH3-C-OH +

O

HO-C-CH3

Page 12: Drill: Draw & Name Reactants & Products of:

Diacetic Anhydride O O

CH3-C-O-C-CH3

+ H2O

Page 13: Drill: Draw & Name Reactants & Products of:

H2C OH

H2C OH

OC

CO

SuccinicAcid

Heat

Page 14: Drill: Draw & Name Reactants & Products of:

H2C O + H2OH2C

OC

CO

SuccinicAnhydride

Page 15: Drill: Draw & Name Reactants & Products of:

OH

OH

OC

CO

PhthalicAcid

Heat

Page 16: Drill: Draw & Name Reactants & Products of:

O

OC

C + H2OO

PhthalicAnhydride

Page 17: Drill: Draw & Name Reactants & Products of:

Anhydride Hydrolysis

•The reverse of the anhydride

formation reaction

Page 18: Drill: Draw & Name Reactants & Products of:

Acyl Group

O

R-C-

Page 19: Drill: Draw & Name Reactants & Products of:

Acyl Group

O

CH3-C-

Acetyl Group

Page 20: Drill: Draw & Name Reactants & Products of:

Drill:• Draw the reactants, then

predict, draw, & name the product of the dehydration of the combination butanoic acid & propanoic acid.

Page 21: Drill: Draw & Name Reactants & Products of:

Esters

Page 22: Drill: Draw & Name Reactants & Products of:

Esters O

R1-C-O-R2

Page 23: Drill: Draw & Name Reactants & Products of:

Esterification•The formation of

esters

Page 24: Drill: Draw & Name Reactants & Products of:

Esterification O

R1-C-OH + HO-R2Acid

Page 25: Drill: Draw & Name Reactants & Products of:

Ester O

R1-C-O-R2

+ H2O

Page 26: Drill: Draw & Name Reactants & Products of:

O

OH + HO-CH3

OH HCl

Methanol

Salicylic Acid

Page 27: Drill: Draw & Name Reactants & Products of:

O

O-CH3

OH + H2O

Methyl Salicate

Oil of Wintergreen

Page 28: Drill: Draw & Name Reactants & Products of:

EsterificationO

OH O

OH + O

AceticAnhydride

Salicylic Acid

C-CH3

C-CH3 O

Page 29: Drill: Draw & Name Reactants & Products of:

Acetyl salicylic AO

OH O

O

Acetic acid

Aspirin

C-CH3

OC-CH3

HO+

Page 30: Drill: Draw & Name Reactants & Products of:

Common Esters

Page 31: Drill: Draw & Name Reactants & Products of:

Ethyl Formate O

H-C-O-CH2-CH3

Rum

Page 32: Drill: Draw & Name Reactants & Products of:

Octyl acetate O

H3C-C-O-(CH2)7-CH3

Oranges

Page 33: Drill: Draw & Name Reactants & Products of:

Pentyl acetate O

H3C-C-O-(CH2)4-CH3

Bananas

Page 34: Drill: Draw & Name Reactants & Products of:

Ethyl butyrate O

H2C-C-O-CH2-CH3

CH2-CH3

Pineapples

Page 35: Drill: Draw & Name Reactants & Products of:

Pentyl butyrate O

H2C-C-O-(CH2)4-CH3

CH2-CH3

Apricots

Page 36: Drill: Draw & Name Reactants & Products of:

Methyl butyrate O

H2C-C-O-CH3

CH2-CH3

Apples

Page 37: Drill: Draw & Name Reactants & Products of:

Predict Product O

CH3-CH2-CH2-C-OH

O

+ HO-C-CH3 + Heat

Page 38: Drill: Draw & Name Reactants & Products of:

Common Biological Ester O

H2C-OH + HO-C-R1

O

HC-OH + HO-C-R2

O

H2C-OH + HO-C-R3

Page 39: Drill: Draw & Name Reactants & Products of:

Triglyceride O

H2C-O-C-R1

O

HC-O-C-R2

O + 3 H2O

H2C-O-C-R3

Page 40: Drill: Draw & Name Reactants & Products of:

Common Biological Ester

H2C-OH + HO-PO3-2

O

HC-OH + HO-C-R2

O

H2C-OH + HO-C-R3

Page 41: Drill: Draw & Name Reactants & Products of:

Phosphoglyceride

H2C-O-PO3-2

O

HC-O-C-R2

O + 3 H2O

H2C-O-C-R3

Page 42: Drill: Draw & Name Reactants & Products of:

Drill:•Draw the reactants, then predict & draw the products of dehydration synthesis when phenol is added to formic acid.

Page 43: Drill: Draw & Name Reactants & Products of:

Ester Hydrolysis•Adding water to an ester in acid or base to break it down into an acid & an alcohol

Page 44: Drill: Draw & Name Reactants & Products of:

Ester Hydrolysis O

R1-C-O-R2base + H2O

Page 45: Drill: Draw & Name Reactants & Products of:

Acid & Alcohol O

R1-C-OH + HO-R2

Page 46: Drill: Draw & Name Reactants & Products of:

Polyester•A polymer made up

of monomers connected by ester

bonds

Page 47: Drill: Draw & Name Reactants & Products of:

Making Polyesters O O

HO-C-R-C-OH

+

HO-R2-OH

Page 48: Drill: Draw & Name Reactants & Products of:

Thioesters O

R1-C- S-R2

Page 49: Drill: Draw & Name Reactants & Products of:

Thioesters In thioesters, the single bonded oxygen is replaced with sulfur

Page 50: Drill: Draw & Name Reactants & Products of:

Making Thioesters Addition of a thiol to an acid or an anhydride

Page 51: Drill: Draw & Name Reactants & Products of:

Acid & Thiol O

R1-C-OH + HS-R2

Page 52: Drill: Draw & Name Reactants & Products of:

Thioesters O

R1-C- S-R2 + H2O

Page 53: Drill: Draw & Name Reactants & Products of:

Making a Common Thioester

O

CH3-C-OH + HS-CoA

Page 54: Drill: Draw & Name Reactants & Products of:

Making a Common Thioester

O

CH3-C-OH + HS-CoA

Page 55: Drill: Draw & Name Reactants & Products of:

Acyl Group

O

CH3-C-S-CoA

Acetyl CoA

Page 56: Drill: Draw & Name Reactants & Products of:

Phosphoric Acid O

HO-P-OH

OH

Page 57: Drill: Draw & Name Reactants & Products of:

At pH 7 ish O O

-O-P-OH & -O-P-O-

OH OH

Page 58: Drill: Draw & Name Reactants & Products of:

P A Anhydrides O + O

HO-P-OH HO-P-OH

OH OHHeat

Page 59: Drill: Draw & Name Reactants & Products of:

P A Anhydrides O O + H2O

HO-P-O-P-OH

OH OH

Page 60: Drill: Draw & Name Reactants & Products of:

Phospho Esters O

HO-P-OH + HO-R

OH Heat

Page 61: Drill: Draw & Name Reactants & Products of:

Phosphoesters O

HO-P-O-R

OH + H2O

Page 62: Drill: Draw & Name Reactants & Products of:

Phosphodiesters O

HO-P-OH + HO-R

OH + H-O-R

Page 63: Drill: Draw & Name Reactants & Products of:

Phosphodiesters O

HO-P-O-R

O-R + 2 H2O

Page 64: Drill: Draw & Name Reactants & Products of:

Phosphorylation•Transfer of this phosphoryl group

through phosphoester bonds

Page 65: Drill: Draw & Name Reactants & Products of:

Inorganic Ester H2C-OH HO-NO2

HC-OH + HO-NO2

H2C-OH HO-NO2

Page 66: Drill: Draw & Name Reactants & Products of:

Nitroglycerin H2C-O-NO2

HC-O-NO2 + 3 H2O

H2C-O-NO2

Page 67: Drill: Draw & Name Reactants & Products of:

Draw & Name 10 Isomers of:

C3H6O2

Page 68: Drill: Draw & Name Reactants & Products of:

Drill:•Draw the reactant, then

predict, draw, & name the products for the

hydrolysis of Propylthioacetate.

Page 69: Drill: Draw & Name Reactants & Products of:

Name

OH

Page 70: Drill: Draw & Name Reactants & Products of:

Name

OH

OH