DRIFT-MINE RECLAMATION IN BIG FOUR HOLLOW NEAR …Four Hollow Creek near Lake Hope, water years 1979-80 12 5. Station 03201630 East Fork Big Four Hollow Creek near Lake Hope, water

DRIFT-MINE RECLAMATION IN BIG FOUR HOLLOW NEAR LAKE HOPE, OHIO

A PRELIMINARY DATA REPORT

By Vance E. Nichols

U.S. GEOLOGICAL SURVEY

Open-File Report 83-217

Prepared in cooperation with

OHIO DEPARTMENT OF NATURAL RESOURCES, DIVISION OF RECLAMATION

Columbus, Oh io

1983

UNITED STATES DEPARTMENT OF THE INTERIOR

JAMES G. WATT, Secretary

GEOLOGICAL SURVEY

Dallas L. Peck, Director

For additional information write to:

District Chief Water Resources Division U.S. Geological Survey 975 West Third Avenue Columbus, Ohio 43212

Copies of this report can be purchased from:

Open-File Services Section Western Distribution Branch U.S. Geological Survey Box 25425, Federal Center Denver, Colorado 80225 (Telephone: (303) 234-5888)

CONTENTS

Page

Abstract 1Introduction 2Purpose and scope 5Methods and approach 5

Surface water- 5Ground water- 7Mine entrances, seeps, and drains 9Precipitation- 9

Results - 10References cited- 11

ILLUSTRATIONS

Figure 1. Map showing location and major hydrologic features of Big Four Hollow Creek and Mine 88 complex area- 3

2. Map showing Big Four Hollow waterquality sampling sites- 4

3. Map showing Big Four Hollow waterquality sampling sites 8

4-8. Discharge hydrographs:

4. Station 03201600 Sandy Run above Big Four Hollow Creek near Lake Hope, water years 1979-80 12

5. Station 03201630 East Fork Big Four Hollow Creek near Lake Hope, water year 1979 14

6. Station 03201660 Big Four Hollow below East Fork Big Four Hollow Creek near Lake Hope, water years 1979-80 15

7. Station 03201700 Big Four Hollow Creek Creek near Lake Hope, water years 1979-80 17

8. Station 03201720 Hull Hollow CreekLake Hope, water years 1979-80 19

9. Water-level hydrograph: well RM-1near Lake Hope, water years 1979-80 21

III

TABLE

Page

Table 1. Station names, numbers, and types of data collected in Sandy Run drainage basin, 1Q "7 Q RO 6

APPENDIXES

1. Water-quality monitor data, station03201700, Big Four Hollow Creek near Lake Hope, water years 1979-80

a. Water temperature 22 b. Specific conductance 26

d. Air temperature 34

2. Daily sediment discharge, station03201700, Big Four Hollow Creek nearLake Hope, water years 1979-80 38

3-15. Water-quality data:

3. Station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, water years 1979-80 40

4. Station 03201615, Big Four Hollow Creek above East Fork Big Four Hollow Creek near Lake Hope, water year 1979 50

5. Station 03201630, East Fork Big Four Hollow Creek near Lake Hope, water

1 Q"7Q_ ___ ._ __ __ _ _____ ___ __ . __ __ _ f^f^^.y i y jj

6. Station 03201660, Big Four Hollow Creek below East Fork Big Four Hollow Creek near Lake Hope, water years 1979-80 60

7. Station 03201700, Big Four HollowCreek near Lake Hope, water years

8. Station 03201720, Hull Hollow Creeknear Lake Hope, water yearsi Q"?Q_Qn _ __ _ _ _ _ _ _ _ _ _ __ __ _ oni. y i y ov ov/

IV

APPENDIXES ContinuedPage

9. Station 03201722, Sandy Run below Hull Hollow Creek near Lake Hope, water years 1979-80 90

10. Well RM-1 in Big Four Hollow nearLake Hope, June 26, 1980 100

11. Surface mine seep 15 (392218082191500) in Big Four Hollow near Lake Hope, April 8 and 15, 1980 101

12. Surface mine seep 16 (392218082191600) near Lake Hope, March 17, April 8 and 25, 1980 103

13. Mine Entrance 88 above Four Hollow Creek near Lake Hope, water years 1979-80 105

14. Mine Entrance 89A above Big Four Hollow Creek near Lake Hope, water years 1979-80 110

15. Mine Entrance 90B near Lake Hope,May 2 and 22, 1980 113

16. Daily rainfall, in inches, at Sandy Run near Lake Hope, 82184701, water years 1979-80 114

CONVERSION FACTORS

For the benefit of readers who prefer to use metric units, conversion factors for terms used in this report are listed below:

Multiply

inch (in)foot (ft)mile (mi)square mile (mi2)square mile (mi2)pounds (Ib)cubic foot per second

(ft3/s ) ton ton per acre foot

(ton/acre-ft) degree Fahrenheit (°F)

By_

25.400.30481.6092.590

2590.45360.02832

0.90727.35

(°F-32)/1.8

To obtain

millimeter (mm)meter (m)kilometer (km)square kilometer (km2)hectares (ha)kilogram (kg)cubic meter per second

(m3/s )metric tonmetric ton per hectare-

meterdegree Celsius (°C)

V

DRIFT-MINE RECLAMATION IN BIG FOUR HOLLOW NEAR LAKE HOPE, OHIO A PRELIMINARY DATA REPORT

By Vance E. Nichols

ABSTRACT

A subsurface clay dike and hydraulic seals were constructed in 197<J by the Ohio Department of Natural Resources, Division of Reclamation, to reduce acid mine drainage from an abandoned drift mine into Big Four Hollow Creek; Big Four Hollow Creek flows into Sandy Run, the major tributary to Lake Hope. A monitoring pro gram was established in 1979 by the U.S. Geological Survey, Water Resources Division, to evaluate sealing effects on surface-water and ground-water systems of the Big Four Hollow Creek and Sandy Run area just below the mine.

Data were collected by private consultants in 1970-71 near the mouth of Big Four Hollow Creek (U.S. Geological Survey station 03201700). Results showed an average pH of 3.1 (calcu lated from mean hydrogen-ion concentration in moles per liter) and a pH range of 2.7 to 4.8. The estimated sulfate load was 1,000 pounds per day, and the estimated iron load was 100 pounds per day.

Data collected in 1979, before dike construction at this site, showed a daily mean pH range of 3.4 to 5.4, with an average of 3.7, and a daily mean specific-conductance range of 160 to 600 microrrihos per centimeter at 25 degrees Celsius (.umho/cm), averag ing 400. Again, the estimated sulfate load was 1,000 pounds per day, but the estimated iron load had decreased to 50 pounds per day.

The first 6 months of postconstruction data from the site in 1980 showed a daily mean pH range of 4.5 to 6.8, with an average of 4.9, and a daily mean conductance range of 175 to 405 pmho/cm with average of 300. The estimated sulfate load had decreased to 570 pounds per day and the iron load to 8.5 pounds per day.

Data collected during the first 6 months after construction indicate moderate improvement in water quality. However, acidic water is still being impounded behind the dike and seals and has not yet been flushed out by infiltrating rain and ground water. Because the system has not yet stabilized, no interpretation or conclusive statement can be made at this time.

INTRODUCTION

Lake Hope, in Vinton County, Ohio, 55 miles southeast of Columbus, was formed in 1939 when Sandy Run was dammed 0.25 mile upstream from its mouth (Tobin and Youger, 1975). The lake is in Zaleski State Forest and is used for recreation. Acid drainage from abandoned drift (underground) mines and unreclaimed surface mines has affected the lake's water quality.

Sandy Run has its headwaters in the northeast corner of Vinton County, Brown Township, sections 11 and 12, and repre sents 53 percent of the drainage area contributing to Lake Hope (fig. 1). Both Sandy Run and Big Four Hollow Creek, a tributary of Sandy Run, carry mine drainage. Sandy Run above Big Four Hollow Creek (U.S. Geological Survey (USGS) station 03201600) has a drainage area of 1.01 square miles; Big Four Hollow Creek (03201700) has a drainage area of 0.98 square mile. Station locations and principal features of the mine area are shown in figure 1.

On June 20, 1979, the Ohio Department of Natural Resources, in cooperation with U.S. Environmental Protection Agency, began construction on a demonstration project designed to reduce acid mine discharge to Sandy Run, the principal tributary of Lake Hope. A large underground clay dike and 35 mine seals were placed in the down-dip side of the outcrop of the Middle Kittanning No. 6 coal at mine complex 88 (fig. 1). Toe drains were installed to remove water from the outside undisturbed trench wall before the clay dike was placed in the trench. The dike and seals will impound water in mine complex 88 and other smaller mines to the north (fig. 1). When the mines fill with water, free oxygen will be removed from the processes producing the acid and iron complexes, thus reducing acid mine discharge.

Acid mine drainage develops when the minerals pyrite and marcasite (iron sulfides), which are found in coal-bearing rocks in Ohio, react with free oxygen and water in partly filled under ground mines. This highly acidic, highly mineralized water can flow from mine openings or can emerge from springs and seeps, eventually flowing into local streams. If the abandoned under ground mines are completely flooded, however, free oxygen is removed from the chemical processes producing the acids.

A small surface mine (fig. 2, springs 15 and 16) north of the construction area was reclaimed at the same time as con struction of the dike to reduce another source of acidic surface water.

82°19'

39°22'15"

Drift mine

Direction of flow

Base from U.S. Geological Survey Mineral 1:24.OOO.1961

Figure 1.--Big Four Hollow Creek and Mine 88 complex.

82C19

39*22'15" 03201630

0320166<m

EXPLANATION03201600

Direction of flow

9 Spring

Surface mine

Drift mine

Mine entrance :

A Stage-discharge

V Water quality sampling site '.

V Monitor station

Weather station (ahr temperature record)

Weather station (precipitation recorded)

Base from U.S. Geological Survey Mineral 1:24.OOO,1961

Figure 2. Big Four Hollow water quality sampling sites.

PURPOSE AND SCOPE

This report documents the changes that occurred in the sur face water and ground water as a result of the demonstration project to abate mine drainage into Big Four Hollow Creek. Hydrologic data were collected before, during, and after the 1979 dike and seal construction to evaluate the effect of mine sealing on the hydrologic system and the usefulness of mine sealing in reducing acid mine drainage from drift mines.

This report is not intended to be conclusive or final be cause only 1 year of postconstruction data were available as of this writing. Several years may pass before the drift-mine complex fills completely and the formation of acid decreases.

METHODS AND APPROACH

Surface Water

Six surface-water sampling stations (03201600, 03201615, 03201630, 03201700, 03201720, and 03201722) were established October 1, 1978, near Lake Hope, Ohio. (Locations are shown in fig. 1.) Sampling sites 03201615 and 03201630 were discontinued July 10, 1979, and combined at a downstream sampling station 03201660. Table 1 lists the stations in downstream order. The types of data collected at each site are shown in figure 2.

Sandy Run above Big Four Hollow Creek (03201600) and Hull Hollow Creek (03201720) were selected as control sites. They are near, but not affected by, the construction area in Big Four Hollow. Sandy Run above Big Four Hollow Creek was selected as a control stream representing acid mine drainage from the middle Kittanning No. 6 coal. Hull Hollow Creek was considered a non- acidic control stream. These sites served as water-quality- sampling and discharge-measuring sites for comparison with sites 03201660 and 03201700. The Hull Hollow Creek site was also selected to record any stream-quality or discharge change due to leakage through the west side of Mine 88 (fig. 2).

Two-surface-water sites 03201660 and 03201700 were selected on Big Four Hollow Creek (fig. 2). These sites, one upstream and one downstream from the construction site, were used to collect water-quality samples and discharge measurements. The downstream site (03201700) was the most critical to the project because it would probably be the first to show any change in water quality or discharge resulting from mine seepage or ground-water leakage from the construction area. This station

Table 1. Sandy Run basin gaging station names, numbers,and type of data collected*

Downstream order number Station name Activity

03201615

03201630

03201660

03201700

03201600

03201720

03201722

Left Fork Big Four Hollow Creek near Lake Hope

Right Fork Big Four Hollow Creek near Lake Hope

Big Four Hollow Creek below confluence of left and right forks

Big Four Hollow Creek near Lake Hope

Sandy Run above Big Four Hollow Creek

Hull Hollow Creek near Lake Hope

Sandy Run below Hull Hollow

Q,C

Q

Q,C,M,S

Q,C

Q,C

C

C Biweekly sampling for water qualityQ Daily dischargeM Four-parameter water-quality monitorS Daily sediment station

was upgraded October 1, 1978, with a water-stage manometer and a water-quality monitor that measures water temperature, outside air temperature, specific conductance, and pH. Water-quality data are summarized in appendix 1. Daily sediment samples were also collected at this station; data are summarized in appendix 2.

Sandy Run below Hull Hollow (station 03201722) was selected for water-quality sampling. This site is far enough downstream from Hull Hollow Creek (200 ft) to allow mixing of all inflow before discharging into Lake Hope.

A chemical schedule was followed once every 2 weeks at stations 03201600, 03201630, 03201700, and 03201722 (fig. 2). In addition, monthly and quarterly chemical schedules were followed at the above stations, and at station 03201720 on Hull Hollow Creek. Specific conductance, pH, dissolved oxygen, alka linity, acidity, temperature, and flow (all field-measured char acteristics) were measured at the stations when water samples were collected.

Certain chemical constituents were dropped from the sampling schedule after May 9, 1980, because they were not found at sig nificant levels. Water samples collected biweekly were analyzed for dissolved nutrients, iron (dissolved, suspended, and total), manganese, lead (total), and zinc (dissolved, suspended, and total). Samples collected monthly were analyzed for the same constituents, plus aluminum (total), nitrogen (as N), phosphorus (as P), carbon (total, dissolved, and suspended), and chemical oxygen demand. Samples collected quarterly were analyzed for the same constituents as the monthly samples plus nickel and mercury (both total). All samples in accordance with field techniques described by Rainwater and Thatcher (1960), and by Brown and others (1970; updated by Skougstad and others, 1979). All chem ical constituents listed in appendixes 3-15 were analyzed in the U.S. Geological Survey Central Laboratory in Atlanta, Ga.

Discharge hydrographs for the five stage-discharge sites are shown in figures 4 through 8 at the back of this report.

Ground Water

Six wells were drilled to monitor ground-water impoundment behind the clay dike. Holes were drilled, and 4-inch PVC plastic pipe was installed as casing. Three of the wells (designated RM- wells) were drilled into mine rooms (fig. 3). Automatic data recorders were installed at each well to record changes in the mine-pool level. Water levels at well RM-1 are plotted in fig. 9 (at the back of this report). No water entered wells RM-2 and RM-3 during the data-collection period (Oct. 1978 - Sept. 1980). Well RM-3 was destroyed during construction of the dike.

82°19' 82°18'30"

39°22'15"

906 Remote hydraulic seal

A

50 METERS

EXPLANATION

Dike

Drain

Drift mine

Surface mine

Direction of flow

Observation well

Observation well with recorder

Base from U.S. Geological Survey Mineral 1:24.OOO,1961

Figure 3. Big Four Hollow water quality sampling sites.

Well RM-1 was sampled quarterly as soon as it contained enough water. The same chemical constituents were sampled as in the monthly surface-water samples (appendix 10). A PVC plastic point sampler was used to bail and sample the water. Well RM-2 is to be sampled when the water level rises sufficiently.

Three other wells (designated SS-wells) were drilled, one next to each RM-well, into the sandstone ceiling above the coal (fig. 3). The SS-wells were periodically measured to detect ground water in the sandstone unit above the top of the coal. No water above the top of the coal was detected.

The "Old House Well", a domestic well about 200 feet east of mine entrance 90B (fig. 3), taps the sandstone below the coal. This well was sampled to determine the ground-water quality below the coal and underclay; it is to be sampled in the future to detect any leakage from the mine pool into the lower sandstone unit.

Mine Entrances, Seeps, and Drains

Before construction of the clay dike, the area between mine entrances 7 and 84 contained many springs and seeps and about 30 mine entrances (fig. 2). Nearly all acid drainage into Big Four Hollow Creek came from those mine entrances. They were inspected at least quarterly. Water seeping from mine entrances 88 and 89A was sampled before the clay dike was placed and the mine complex closed in November 1979. Water-quality data from three sites are tabulated in appendixes 13 and 14.

During dike construction, toe drains were installed on the outside edge of the clay dike to drain seepage. Outflows near selected mine entrances 5 and 89A were sampled after October 1979; data are included in appendixes 13 and 14. Mine entrance 90B was sampled after April 1980, when built-in weep holes began flowing. (See appendix 15.)

Seeps 15 and 16 (fig. 2) were sampled to obtain antecedent data. Results are given in appendixes 11 and 12, respectively. These seeps will be observed and sampled again yearly for compar ison if the project continues.

Precipitation

A recording rain gage was installed at Sandy Run near Lake Hope (station 03201600), on May 17, 1979. Appendix 16 lists the amounts of rain collected, in inches per day, from May 17, 1979 to Sept. 30, 1980.

RESULTS

Data collected by private consultants in 1970 and 1971 near the mouth of Big Four Hollow Creek (station 03201700) showed an average pH of 3.1 (calculated from mean hydrogen-ion concentra tion, in moles per liter) and a pH range of 2.7 to 4.8. The estimated sulfate load was 1,000 Ib/d (pounds per day), and the estimated iron load was 100 Ib/d (Stanley Consultants, 1971).

Data collected at the same site before construction of the dike in 1979 showed a daily mean pH range of 3.4 to 5.4, averag ing 3.7, and a daily mean specific-conductance range of 160 to 600 >imho/cm (micromhos per centimeter at 25 degrees Celsius), averaging 400 jamho/cm. The data also indicated a sulfate load of 1,000 Ib/d as before, but a decreased iron load of 50 Ib/d.

All mine entrances and nearly all seeps stopped flowing after construction of the clay dike, except around mine entrance 84 (fig. 2) and upstream from Big Four Hollow Road along Mine 88 Hollow tributary (fig. 3).

Data from November 2, 1979 to May 1, 1980, indicate an improvement of water quality in Big Four Hollow Creek. The average pH (calculated from mean hydrogen-ion concentrations, in moles per liter) increased from 3.7 to 4.9. Specific-conductance averaged 400 >imho/cm before construction and 300 jimho/cm after construction. Average sulfate loads had decreased from 1,000 Ib/d before and to 570 Ib/d after, and average iron loads decreased from 50 Ib/d before and to 8.5 Ib/d after.

Sediment loads before dike construction were smaller than during construction and after construction. The slopes in the basin were initially covered with established vegetation, but during and after construction (before new growth from reseeding), the disturbed areas were susceptible to erosion, which increased the sediment load in the stream.

Although the data indicate an improvement for the most part in the water quality of Big Four Hollow Creek since completion of the reclamation work in 1979, this does not imply that the im pounded mine water has improved. Water in the flooded mines is still acidic and high in iron and sulfate.

Once the mines are flooded, less oxidation of the sulfate minerals and less mineralization of the mine water can be ex pected. Precipitation and percolating ground water will slowly dilute and flush the impounded water. Only after a complete replacement of water in the mines, with a constantly-flooded condition, will reduction of acid mine drainage into Big Four Hollow Creek be possible.

10

REFERENCES CITED

Brown, Eugene; Skougstad, M. W.; and Fisher, M. J.; 1970, Methods for collection and analysis of water samples for dissolved minerals and gases: U.S. Geological Survey Techniques of Water-Resources Investigations, Book 5, chap. Al, 160 p.

Rainwater, F. H., and Thatcher, L. L., 1960, Methods of collec tion and analysis of water samples: U.S. Geological Survey Water-Supply Paper 1454, 301 p.

Skougstad, M. W., Fishman, M. J., Friedman, L. C., Erdmann, D. E., and Duncan, S. S., 1979, Methods for determination of inor ganic substances in water and fluvial sediments: U.S. Geological Survey Techniques of Water-Resources Investiga tions, Book 5, chap. Al, 626 p.

Stanley Consultants, 1971, Baseline water quality, Lake Hope: Ohio Department of Natural Resources, 97 p.

Tobin, R. L., and Youger, J. D., 1977, Limnology of selected lakes in Ohio - 1975: U.S. Geological Survey Water- Resources Investigation 77-105, p. 124-132.

11

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WATER LEVEL, IN FEET BELOW LAND SURFACE DATUM

55 50 45 403530

-Opened ^!ine 88 complex opening, September 27, 1979

Closed various mine opening!?, November, December, and January

Appendix 1. Water-quality monitor data, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio,

water years 1979 and 1980

TEMPERATURE* WATER (DEG. C)

» WATER YEAR OC

TOrt

ER 1978 10

SEPTEMBER 1979

DAY

MONTH

MAX

MIN

OCTOBER

MAX

MIN

MAX

MIN

MAX

MIN

NOVEMBER

OECEM3EP

JANUARY

MAX

MIN

FEBRUARY

18.5

5.5

13.0

2.5

9.0

.37.5

.55.5

.0

MAX

MIN

MARCH

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23

24 25

26 27 28

29 30 31

18.5

17.0

16.5

15.5

15.0

12.5

12.5

11.0

13.5

14.0

13.0

16.5

13.5

12. U

11.5

12.0

12.0

1J.5

13.5

14.0

14.0

14.5

12.0

12.5

11.5

12.5

11.5

12.0

12.0

13.0

13.5

14.0

11.5

10.5

12.5

10.5

11.0

10.0

8.0

6.5

7.0

8.0

11.0

11.5

10.5

9.5

9.0

8.0

6.5

9.5

7.5

7.0

7.5

9.0

7.0

5.5

10.5

7.5

6.0

6.5

5.5

5.5

13.0

12.5

13.0

13.0

13.0

12.0

8.5

10.5

7.0

10.0

11.5

9.0

12.0

10.5

9.5

8.5

11.5

10.0

9.5

8.0

8.0

9.0

9.0

8.0

6.5

5.5

8.0

7.5

5.0

6.5

6.5

5.0

5.5

6.0

6.0

6.5

7.t>

5.0

4.0

4.5

4.5

7.5

9.0

8.0

7.5

7.5

8.5

8.0

5.5

4.5

5.5

6.0

7.0

5.0

4.0

4.0

4.5

4.0

3.0

2.5

5.3

6.0

8.5

9.0

6.0

6.0

6.5

-__

6.0

4.0

3.5

5.0

5.0

3.5

4.5

5.0

5.0

3.5

3.0

8.0

7.0

4.5

3.5

3.5

3.5

3.0

2.5

1.0

1.5

2.0

6.3

1.0

2.0

4.5

5.5

4.0

3.0

3.5

__-

4.0

1.0 .5

2.0

2.0

1.0

1.0

1.5

1.5

1.0

2.5

3.0

3.0

1.5 .5

1.0

1.3

1.0 .5 .5 .5

1.0

2.0

7.5

5.0

1.0

1.0

1.0

1.5

1.5

1.0

1.0

1.0

1.0

1.0

1.0

2.0

1.0

1.0

1.5

2.0

1.0

2.0

3.5

3.5

4.0

3.5

2.0

2.0

3.5

2.5

2.0

1.5

1.5

5.0 .5 .5 .5 .5

1.0 .5 .5 .5 .5 .5 .5 .5 .5 .5 .5

1.0 .5 .5

1.0

2.0

1.5

1.0

1.0

1.0

1.0

1.0

1.5

1.0 .5 .5

1.0

1.0

1.0

2.5

1.0

1.0 .0 .5 .5 .5 .5 .5 .3 .5 .5 .5 .5 .5 .3 .5 .0 .5

___

___

___

5.5

5.5

-__

-__

.5 .0 .0 .0 .5 .0 .0 .0 .0 .0 .0 .0 .0 .0 . o .0 .0 .0 .0 .0 .0 .0

___

-

-

___

2.5

1.0

___

...

5.5

7.0

9.5

10.5

-

--_

8.5

8.0

6.5

8.0

5.0

9.5

8.0

6.5

5.5

7.0

9.5

12.0

11.5

12.5

15.5

14.5

11.5

9.0

7.5

3.5

8.5

12.0

12.5

15.0

11.5

2.5

3.5

3.0

6.5

-

-__

2.0

3.5

2.5

4.0

1.5

2.0

1.0

4.b

1.0

1.0 .5

3.3

4.0

7.0

6.0

5.0

8.0

6.0

4.0

3.5

3.0

1.5

7.5

8.5

9.0

15.5

.5

DAY

MONTH

YEAR

Appendix 1.--Water-quality monitor data, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio

water years 1979 and 1980 Continued

TEMPERATUREt WATER

(fiEo. C)» WATER YEAR OCTOBER 1978 TO SEPTEMBER 1979

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

APRIL

MAY

JUNE

JULY

20.0

28.5

2.0

.0

23.5

6.b

26.0

11.5

28.5

11.5

20.0

12.0

MAX SEPTEMBER

1 2 3 4 5 6 7 8 9 10 11 12 13 1^ 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31

9.0

11. 5

11.5

8.5

10.5

11.5

9.0

12.0

8.5

12.5

10.5

14.0

13.0

15.0

9.b

9.0

14.5

16.5

17.5

19.0

17.5

16.5

15.0

19.5

20.0

15.0

16.5

14.5

14.0

18.5

8.0

8.5

7.0

6.5

7.0

3.5

2.0

4.5

5.0

3.5

4.5

8.0

9.0

7.0

7.0

b.5

5.0

5.0

4.5

6.0

7.0

10.5

11.0

11.0

12.5

13.0

10.5

9.0

7.5

7.0

19.5

21.5

14.5

12.0

16.0

IB. 5

21.0

21.5

23.5

22.0

23.5

23.5

16.0

21.5

20.0

21.5

21.5

23.0

23.5

22.0

23.5

22.5

16.5

15.5

13.5

15.5

12.5

16.0

19.0

21.0

16.5

6.5

7.0

12.0

9.0

7.5

7.5

9.5

11.0

12.5

15.0

14.0

15.0

12.5

10.5

12.5

9.5

9.0

9.5

10.5

14.0

15.5

12.5

15.0

13.5

10.5

10.0

11.0

11.0

9.5

10.5

14. U

19.5

20.0

18.0

22.5

23.5

22.5

22.0

17.5

19.0

23.0

20.0

21.5

18. b

23.0

24.5

22. b

23.5

24.0

25.5

26.0

19.0

23.5

21.5

19.5

£?3.0

24.0

23.0

20.5

18.5

17. b

14.0

14.0

14.5

12.0

13.5

15.0

15.5

16.0

15.5

16.0

14.5

12.5

13.0

12. b

14.0

15.0

16.0

16.5

15.5

15.0

17.0

16.0

16.5

14.5

11.5

12.0

13.0

14.5

14. b

15.5

18.0

22.5

25.5

18. b

20.0

23.0

23.0

25.0

17.5

20.0

22.5

21.5

19.5

25.0

25.0

28.5

27.0

27.0

25.0

23.5

25.0

27.0

21.5

16.0

ia.o

19.5

20.5

19.0

22.5

23.5

24.5

14.0

15.0

14. U

15.5

12.5

11. D

12.0

13.5

17.0

16.0

15.0

17.5

15.0

15.0

18.5

15.0

18.0

17. U

15.0

15.0

18.0

16.5

11.5

12.0

14.0

16.0

16.0

17.0

18.0

17.0

18.0

24. b

20.5

23.0

22.5

24.0

22.5

24.5

24.5

26.0

26.0

20. U

19.5

20.0

19.5

19.5

20.5

21.0

19.5

21.0

20.0

19.5

20.5

20.0

20.5

19.5

18. b

19.0

20. b

20.5

20.5

22.0

19.0

12.5

16.5

16.5

17.5

18.5

18.5

19.5

18.5

19.5

17. b

16. b

14.0

15.0

14.0

12.0

12.. 0

15.5

17.0

14.5

17.5

17. b

lb.0

18.0

17. b

17.0

17.5

17.0

18.5

15.5

16.5

22.0

21.0

23.0

23.5

21.5

22.5

22.0

15.5

18.0

18.5

18.5

22.0

18.5

18.5

16.5

17.0

18. b

19.0

18.0

18.0

15. b

15. 0

15.5

16.5

16.5

17.5

15.5

15.5

17.5

17.5

17. U

18.0

18.5

18.0

18. u

18. b

14.0

13. U

H. b

11.5

U.O

14.0

15. b

15.0

13.0

11.5

10.0

10.0

13.0

11.0

15.0

13.5

12. U

11.0

12.0

12.0

12.5

15.0

15.0

14.0

---

23.5

10.0

DAY

MONTH



TEMPERATURE. WATER (DEG. C)

» HATER YEAR OCTOBER 1979 TO SEPTEMrfER 1980

MAX

MIN

OCTOBER

MAX

MIN

MAX

MIN

MAX

MIN

NOVEMBER

DECEMBER

JANUARY

MAX

MIN

FEBRUARY

17.b

b.b

13.5

3.0

b.b

.b7.5

.b6.5

.5

MAX

MIN

MARCH

1 2 3 4 5 6 7 8 9 10 11 12 13 1* lb 16 17 Itt

19 20 21 22 23 24 2b 26 27 28 29

30 31

17.5

16.0

lb.0

14.0

13.0

12.5

11.5

11.5

12.0

11.0

10.0

11.5

1U.5

10.0

9.0

12.0

13.5

14.0

14.5

16.0

16.5

17.0

14.5

10.5

9.5

11.0

10.0

11.5

12.5

13.0

14.0

14.0

14.5

13.5

13.0

11.0

1U.O

9.5

b.5

10.5

9.0

B.5

9.5

b.o

7.0

b.5

9.0

10.5

10.0

10.5

11.5

12.0

12.5

10.5

9.0

7.5

6.0

5.5

8.5

7.0

7.0

8.5

13.5

11.5

10.0

9.0

9.0

8.5

9.5

- .

9.5

9.5

8.0

7.0

7.5

6.5

6.0

7.5

7.5

8.0

8.0

9.5

10.0

10.0

11.0

10.5

12.0

11.0

9.0

8.0

5.0

4.0

...

10.5

9.0

7.0

5.b

5.0

6.0

8.5

...

7.0

8.0

6.0

b.O

6.0

5.0

4.5

5.0

3.b

4.5

4.b

6.0

6.5

9.0

9.0

9.0

9.0

8.b

6.5

5.b

3.5

3.0

...

4.0

3.5

3.0

4.0

4.5

4.5

b.O

4.5

4.0

3.5

5.5

7.0

6.5

b.O

3.5

4.b

J.O

2.0

3.0

3.0

J.O

4.0

5.5

8.5

7.5

b.5

4.b

3.0

3.b

3.0

2.5

2.5

2.0

1.0

1.5

2.0

3.b

3.0

2.5

2.0

1.5

2.0

5.0

5.0

3.0

l.b

2.0 .5 .b

1.0

1.0

1.0

2.5

4.0

5.5

5.0

4.5

3.0

2.0

2.5

2.0

2.0

2.5

2.0

3.0

2.5

1.5

2.0

3.0

2.b

2.5

1.5

4.5

2.5

3.0

4.6

4.5

5.5

7.5

5.5

5.0

5.5

4.0

3.5

2.b .b

2.0

2.5

2.5

l.b

2.0

1.0

1.0

2.0

2.0

2.0

1.0

1.0

1.0

1.0 .5 .b .5

1.0

1.0

1.0

3.0

4.0

3.0

5.0

3.5

2.5

2.5 .5

2.5 .5 .5 .5 .5

1.0

1.0 .5 .5 .b

1.0 .b

1.0

1.0

1.0 .5 .5

1.0

1.0

1.0

1.0

1.0

1.0

1.0

l.o

1.0

1.0

l.o

l.s

1.0

l.b

6.5

5.0

b.O

b.O

3.0

l.b

1.5

l.b

- _

.5 .5 .b .5 .5 .5 .5 .5 .5 .5 .5 .b .5 .5 .5 .b

.b .5 .5 .5 .51.5

2.5

2.5 .5 .5 .5 .5 .5

-

- .

.51.

01.0

1.0

3.0

6.0

b.O

9.5

8.5

8.0

6.5

4.5

3.5

4.0

9.0

9.5

7.5

9.5

8.0

8.0

8.0

9.5

9.5

8.0

7.0

9.5

12.5

7.5

8.0

9.5

9.5

.b .5 .5 .5 .b

2.5

2.b

4.0

3.0

2.b

1.0

1.0

l.b

l.b

1.0

2.0

4.b

2.b

l.b

4.5

4.b

3.5

3.0

6.0

b.O

3.b

2.0

5.0

6.b

6.0

6.5

12.b

.b

Appendix 1. Water-quality monitor data, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio


TEMPERATUREf WATER

(Ofc

G. C)» WATER YEAR OC

TOtt

ER 1979 TO SEPTEMBER 1980

DAY

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

WAY

JUNE

JULY

AUGUST

1 2 3 4 b 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 2223

2425 26 27 28 30 31

MONTH

YEAR

9.0

14.5

13.0

9.5

...

__

15.0

13.0

13.5

tt.O

15.0

10.5

8.0

10.0

8.0

13.0

14.0

16.5

15.5

19.0

20.5

18.5

20.0

19.0

13.5

11.5

11.0

11.0

13.0

13.5

20.5

34.0

6.0

5.0

6.0

6.5

__

7.5

7.5

8.0

6.0

4.0

7.5

6.0

6.5

6.0

5.0

4.5

5.0

6.0

6.0

8.0

7.0

9.5

7.5

7.0

7.0

7.0

6.0

7.5

8.0

4.0 .5

18.0

18.0

20.5

23.0

22.5

20.0

17.0

14.5

18.0

20.5

24.5

19.0

23.0

15.5

20.5

21.5

16.0

18.5

16.5

14.5

20.5

22.5

19.0

23.5

24.0

23.0

22.5

23.5

24.5

22.5

25.0

25.0

9.0

8.0

8.5

9.0

9.5

10,5

9.b

6.0

5.0

6.0

11.5

14.0

13.0

11.5

8.b

9.0

12.0

12.0

12.5

12.5

12.5

12.0

14.5

14.5

14.0

11. b

10.0

11.0

12.5

15.5

15.5

5.0

19.5

19.0

21.0

21.5

24,0

22.0

23.0

22.5

23.5

23.0

20.0

22.0

23.5

25.5

22.5

20.0

23.0

24.0

24.5

23.5

23.0

25.0

26.0

21.5

23.5

27.5

26.5

29.0

22.5

22.5

29.0

15.5

15.0

15.0

14.0

12.0

14.5

15.5

18.0

19.0

20.5

15.0

10.0

10.5

12. b

15.5

13.5

10. b

12.0

12.0

13.0

11.5

11. b

13.5

17.0

15.0

15.0

17.5

17.0

18.5

15.0

-

10.0

25.0

28.0

22.5

25.5

27, b

27.5

24.5

31.5

22.0

20.5

27.0

21.0

21.5

24.5

33.0

34.0

30.5

28.5

30.0

31.0

30.5

20.5

21.5

24.5

25.0

25.5

25.0

22.5

25.5

25.0

27.0

34.0

14.0

16.5

18.5

16.5

18.0

17.5

14.0

17.5

17.5

17. b

17.0

18.0

17.0

15.0

16.0

25.0

21.0

18.0

16.5

19.5

21.0

18.0

18. 0

16.5

16.0

17.0

18.5

19.0

17.5

17.5

16.0

14.0

26.0

27.5

23.5

26.0

27.5

2U.5

2b.5

28.5

20.0

26.5

26.0

24.0

25.5

26. b

21. b

23.5

20.0

22.5

24. b

20.5

22.5

21.0

21.0

23. S

24.0

24.5

25.5

26.0

25.5

24.0

24. b

28.5

20.0

19.0

20.0

19.0

19.0

19.5

21.0

20.0

21.0

20.5

20.5

19.5

17. b

19.0

20.0

17.5

17.5

16.0

19.0

18.5

18.5

18.5

16.5

16. b

16.5

17.0

17.0

18.0

18.5

18.5

17.5

16.5

26.0

26.0

25.0

15. 5

25.5

25.5

24.5

24.0

23.5

22.5

21.5

22.5

24.0

24.0

20.0

21.5

20.0

20.0

22.0

^3.5

24.0

22.0

20.0

19.5

20.0

18.0

17.5

18.5

19.0

16.5

___

26.0

18.5

19.0

17.0

17.0

18. b

18.5

17.5

16.5

17.0

16.0

13.0

13.0

16.0

18.0

17.5

15.0

17.0

15.

;>13

. b

14. b

17.0

ltt.

017

. 0

14.5

14.5

U.5

10.0

11.5

11.6

11.5

*~"*

10.0

DAY

MONTH



SPECIFIC CONDUCTANCE (MICROMHOS/CM AT 25 DEG. C)» WATER YEAR OCTOBER 1978 TO SEPTEMBER 1979

MAX

MIN

NOVEMBER

MAX

MIN

DECEMBER

MAX

MIN

MAX

MIN

MAX

MIN

JANUARY

FEBRUARY

MARCH

1 2 3 4 b & 7 6 9 10 11 1*?

13 1* 15 16 17 18 19 20 21 22 23

2*

25

26 27

2829 30 31

1570

1350

1370

...

1190

1190

1220

1280

1280

1340

1220

549

...

651

747

765

858

b55

822

891

918

915

879

981

972

951

528

1140

699

669

984

1220

1230

...

1150

1110

1120

1160

1160

1130

1060

255

...

630

633

738

753

777

789

798

870

828

792

888

267

297

513

525

576

654

699

702

849

894

1090

876

771

1440

1180

1650

1700

lloO

1060

903

864

564

798

906

987

699

840

534

534

666

1040

1150

540

315

351

387

663

669

687

693

741

735

741

738

795

903

804

810

855

798

567

498

204

279

423

423

489

438

492

489

591

549

189

225

315

339

411

438

483

243

384

501

5b8

201

288

507

720

396

651

471

489

567

801

525

5b8

564

342

519

432

804

549

4*7

534

534

534

558

396

375

393

153

135

228

363

240

120

144

246

294

372

381

450

435

459

462

507

504

255

240

339

426

411

411

435

465

468

495

372

150

225

642

318

459

432

393

393

...

...

468

483

483

477

294

327

354

354

390

393

360

249

288

309

306

276

318

339

366

393

399

459

111

180

267

324

354

351

258

...

...

438

441

429

255

186

276

315

267

27b

321

174

162

249

291

183

213

279

315

327

360

351

363

465

459

444

558

522

606

489

486

498

522

522

b22

519

b28

546

46b

495

507

b04

519

519

264

213

225

207

240

273

273

...

...

393

417

429

438

471

474

468

468

483

483

507

498

498

516

459

432

4b9

474

468

495

267

144

153

147

120

147

237

240

...

...

264

279

309

318

-

...

351

342

348

366

369

399

411

408

396

414

444

432

438

447

462

486

483

318

297

339

375

387

411

426

420

234

24v

279

234

...

...

276

309

288

264

23i

315

375

360

348

381

40^

411

420

435

444

450

297

216

243

303

342

363

387

405

189

1570

255

1700

189

804

120

642

111

606

120

486

189

to vj

DAY 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

21 22

2324

25

26

2728

29

30 31

MONTH

YEAH



SPECIFIC CONDUCTANCE (MlCROMHQS/CM AT 25 OEG. C). WATEK YEAR OCTOBER 1978 TO SEPTEMBER 1979

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

APRIL

MAY

JUNE

JULY

MAX

MIN

SEPTEMBER

252

243

285

294

327

330

321

336

324

303

318

360

360

*79

303

321

339

3b4

366

378

387

390

396

411

420

423

387

396

411

426

162

174

243

282

303

3UO

297

309

243

270

291

321

246

243

279

303

318

327

339

351

363

381

387

396

405

405

348

372

396

405

438

462

456

276

273

330

366

390

414

420

411

432

414

438

456

477

489

501

525

537

549

567

567

480

486

426

435

387

516

552

546

414

432

270

156

192

273

330

360

381

375

384

384

40^

411

435

450

468

483

498

519

531

549

450

429

387

336

186

243

387

495

255

405

450

465

504

537

597

558

450

462

543

474

540

5tf2

606

600

585

6U6

621

612

624

399

4dO

558

606

639

744

558

759

627

543

-._

285

405

444

465

498

339

516

171

312

225

273

471

534

558

516

555

564

585

531

345

258

396

483

558

597

564

531

543

576

336

459

492

525

522

789

645

582

600

597

780

6bO

606

600

618

630

660

690

717

762

732

732

753

1540

1600

1590

1210

1240

1240

720

882

9^2

387

<*44

492

237

372

558

558

573

360

420

300

600

300

300

600

600

630

690

720

720

714

720

750

1490

694

1140

1140

522

420

732

870

972

2900

1350

1350

1320

1090

1010

1060

1200

1530

1390

b79

747

837

1100

U10

1410

1400

1230

2650

291

387

411

420

342

354

dbl

330

309

1860

414

903

4b3

1250

1290

1070

519

846

9dl

1060

1130

213

279

588

750

840

1130

1270

1140

192

171

132

294

321

243

264

150

183

ttu

267

312

375

453

471

507

552

570

606

1760

1670

1370

1970

1950

1730

1320

594

591

687

732

846

870

864

903

264

354

429

570

531

2750

651

294

339

417

453

471

501

531

558

564

1370

1220

1130

1640

717

396

156

441

597

600

600

807

828

129

147

234

357

372

351

387

159

234

288

426

2900

162

111

567

156

759

171

1600

2900

132

2750

129

DAY



SPECIFIC CONDUCTANCE (MICROMHOS/CM AT 25 DEG. C)» WATER YEAR OCTOBER 1979 TO SEPTEMBER 1980

MAX

MIN

OCTOBER

MAX

MIN

MAX

MIN

MAX

MIN

NOVEMBER

DECEMBER

JANUARY

MAX

MIN

FEBRUARY

MAX

MIN

MARCH

1 2 3 4 5 b 7 a 9 10 11 12 13 14 15 16 17 lb 19 20 21 22 23 24 25 26

27 2fa

29

30 31

468

1370

774

1230

504

1190

498

621

258

303

327

339

558

375

1580

357

516

624

477

477

498

717

438

918

420

411

432

417

2200

1250

801

333

318

306

312

438

3t>9

429

156

162

258

297

258

270

327

303

297

303

330

426

438

465

369

387

387

381

390

402

396

378

408

423

1510

582

612

651

657

516

474

327

231

246

258

267

276

285

297

330

303

306

312

318

318

336

336

294

228

237

252

267

273

609

429

525

543

357

342

384

219

192

225

246

256

267

273

276

285

288

294

300

306

309

31b

285

25d

147

219

237

252

267

285

288

300

297

303

300

318

318

324

327

330

3<»8

360

237

249

264

282

297

288

306

309

306

J33

348

297

264

270

279

288

291

300

273

279

288

291

294

297

303

312

315

318

324

318

16b

204

237

252

267

282

279

288

303

303

303

300

264

258

264

270

279

285

291

306

315

333

327

321

333

336

351

348

366

345

225

249

28b

297

315

333

327

312

312

324

318

342

357

324

297

300

306

336

348

330

300

306

315

315

312

321

327

327

330

345

141

171

225

249

258

279

288

300

306

309

312

312

318

324

267

273

294

297

303

321

321

351

372

381

381

384

363

36J

372

369

381

390

399

411

408

399

363

369

399

369

342

330

273

276

279

288

324

321

339

360

---

333

351

357

360

363

354

354

363

366

369

3dl

384

399

399

363

324

348

348

327

288

2b4

252

258

273

273

279

291

285

306

---

354

336

J54

339

276

234

231

225

237

258

270

294

294

225

246

258

315

243

258

276

282

216

240

270

252

267

279

316

219

264

213

324

321

327

288

135

171

201

189

219

240

252

264

180

177

225

246

189

219

243

258

114

177

219

240

240

237

249

153

171

156

159

MONTH

2200

156

1510

147

360

165

366

141

411

252

354

114

DAY

MONTH

YEAR



SPECIFIC CONDUCTANCE (MICROMHOS/CM AT 25 DEG. C>» WATER YEAR OCTOBER 1979 TO SEPTEMBER 1960

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MAX

MIN

MAX

MIN

APRIL

MAY

JUNE

JULY

AUGUST

SEPTEMBER

237

252

264

270

279

286

300

318

234

246

258

303

27b

252

213

234

645

258

264

276

282

288

297

306

315

321

324

333

339

366

216

216

252

258

270

279

288

159

169

234

249

234

234

120

177

213

234

252

258

264

276

282

268

297

306

315

318

324

327

339

375

381

381

390

429

447

432

510

429

438

438

591

327

339

366

381

573

318

480

312

324

501

435

369

375

411

444

462

483

513

558

346

363

369

375

384

390

399

405

411

420

426

312

276

318

339

360

270

282

300

300

309

327

33U

336

342

375

411

438

462

411

429

393

531

285

330

366

57J

423

336

___

_._

684

513

5b2

744

588

546

597

643

675

723

777

604

756

816

819

664

615

741

513

228

183

210

288

333

339

339

327

---

___

444

477

516

402

417

486

549

576

532

669

702

711

681

756

771

354

480

345

303

582

624

831

513

621

603

642

666

492

330

3B7

501

291

3^7

372

37o

552

594

636

684

774

276

330

364

429

468

621

387

399

444

483

513

582

333

435

469

537

603

348

159

273

330

135

165

294

354

369

378

552

591

630

279

147

216

330

384

429

300

297

342

402

447

496

576

657

534

591

b79

588

672

699

714

714

357

420

<*35

438

501

322

534

56*

465

336

258

309

348

396

438

483

525

711

468

423

450

496

381

4b9

537

b43

513

562

648

609

270

243

360

321

411

438

483

486

339

132

126

150

264

312

33 1

399

4J8

474

4J2

d<*Q

330

480

459

b!9

564

612

657

708

750

825

579

666

726

780

942

660

711

729

613

637

873

912

912

900

939

960

990

1010

1U50

1080

1090

330

402

462

522

567

612

645

705

276

309

591

669

723

40^

495

660

681

732

774

813

864

858

831

826

936

936

978

1010

1020

1040

---

645

2200

120

114

591

270

664

183

831

13b

714

1090

276

Appendix 1.--Water-quality monitor da

ta,

station 03201700, Big Four Hollow Creek near Lake Hope,

Ohio

,


PH (STANDARD UNITS)» WATER YEAR OCTOBER 19

78 TO

SEPTEMBER 19

79

DAY

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

OCTOBER

NOVEMBER

DECEMBER

JANUARY

FEBRUARY

MARCH

1 2 3 4 5 6 7 6 9 10 11 12 13 14 15 16 17 lb 19 20 21 22 23 24 25 26 27 28 29 30 31

3.8

3.7

3.6

3.8

3.8

3.8

3.8

3.8

3.8

3.8

3.7

3.8

6.3

4.5

3.«

J.6

3.5

3.5

3.4

3.4

3.4

3.3

3.3

3.4

3.4

5.6

5.0

4.0

3.9

3.8

3.7

3.4

3.2

3.5

3.6

3.6

3.6

3.7

3.7

3.6

3.6

2.9

3.5

3.8

3.8

3.6

3.4

3.3

3.2

3.3

3.2

3.2

3.1

3.2

3.2

3.2

3.2

4.0

3.7

3.6

3.5

3.4

3.6

3.6

3.6

3.5

3.5

3.5

3.4

3.5

3.6

3.5

3.5

3.4

3.3

3.4

3.8

3.9

6.0

5.2

H.3

4.2

4.1

4.6

*.o

3.9

3.9

3.9

6.4

5.9

5.1

4.6

3.4

3.4

3.3

3.3

3.3

3.3

3.4

3.3

3.4

3.3

3.3

3.3

3.2

3.3

3.4

3.8

3.7

4.3

4.1

4.1

3.4

3.9

3.9

3.9

3.tt

3.tt

3.tt

5.1

4.6

4.2

4.5

4.3

4.1 -

.-

_

-

5.5

4.2

H.O

___

4.1

4.0

t.O

4.0

3.6

4.9

5.2

*.l

4.0

3.9

3.9

3.9

3.9

3.8

3.8

3.7

5.1

3.9

3.8

3.9

...

..

...

.-

4.3

3.9

3.9

...

4.0

3.8

3.9

3.7

...

3.6

3.2

4.0

3.6

3.3

3.6

3.6

3.5

3.7

3.5

3.1

3.5

3.6

5.0

6.0

4.2

4.1

3.9

3.9

4.4

4.1

3.9

3.9

3.9

3.7

5.3

5.7

4.4

4.1

4.9

4.5

4.1

5.7

5.7

4.3

4.1

5.9

4.6

4.1

3.9

3.6

3.9

4.0

4.0

4.4

3.9

4.1

3.9

3.8

3.7

3.8

3.8

3.6

3.4

3.4

3.4

3.6

4.3

4.1

3.8

3.6

4.0

3.6

3.7

4.3

3.9

3.5

3.9

4.1

3.9

3.7

3.6

3.7

3.8

3.6

4.0

3.9

3.8

3.7

3.ti

3.8

3.7

3.8

3.8

3.8

3.7

3.7

3. a

3.7

3.9

4.0

4.0

3.9

3.9

3.9

t>.4

5.H

b.8

5.4

5.5

4.b

4.3

4.3

_

...

3.8

3.6

3.4

3.5

3.7

3.3

3.0

3.5

3.4

3.4

3.4

3.D

3.<f

3.3

3.5

3.7

3.6

3.7

3.6

3.2

3.6

4.8

f .2

4.1

4.5

4.1

3.9

4.0

...

4.3

4.2

4.1

4.9

...

...

4.0

4.0

4.0

3.9

3.9

4.0

4.1

*.2

<f.l

3.9

4.0

4.0

4.0

3.9

3.9

3.9

4.9

6.0

5.2

4.2

4.0

4.0

3.6

3.8

5.9

4.1

3.7

3.8

3.7

...

...

3.8

3.8

3.8

3.7

3.8

3.0

3.ti

3.9

3.0

3.6

3.7

3.9

3.7

3.7

3.7

3.5

3.6

4.5

4.2

4.0

3.0

3.8

3.7

3.7

3.6

MONTH

6.3

2.9

6.4

3.2

5.b

3.1

6.0

3.4

b.6

3.2

6.0

3.5

OAY



PH (STANDARD UNITS)* WATER YEAR OCTOBER 1978 TO StPTEMdEH 1979

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

APRIL

MAY

JUNE

JULY

MAX

MIN

SEPTEMBER

1 2

3 4 5 6 7 8 9 10 11

Id

13

14

15 16

17

18

19

20

21

22

23

2*

25

26

21

28

29

30

31

MONTH

YEAR

5.9

5.6

4.4

4.1

4.1

4.1

4.2

4.1

5.8

5.0

4.5

4.2

5.8

6.0

4.7

4.3

4.1

4.1

4.1

4.1

4.0

3.9

3.9

3.9

3.8

3.8

4.1

4.0

3.9

3.9

6.0

6.4

4.7

4.4

4.0

4.1

4.0

4.0

4.0

4.0

4.1

4.3

4.2

4.0

3.9

4.6

4.3

4.1

4.1

4.0

3.9

3.9

3.8

3.8

3.8

3.8

3.7

3.8

3.9

3.9

3.8

3.8

3.7

2.8

3.9

3.8

6.1

6.3

5.9

4.7

4.2

4.0

3.9

3.8

3.8

3.7

3.8

3.8

3.8

3.8

3.7

3.7

3.7

3.6

3.6

3.6

3.7

3.8

4.0

4.6

6.0

5.6

3.9

3.7

5.8

6.3

3.8

3.7

3.7

5.7

4.7

4.0

3.8

3.7

3.6

3.6

3.6

3.6

3.7

3.6

3.6

3.6

3.6

3.b

3.5

3.b

3.5

3.4

3.5

3.6

3.7

3.8

3.8

3.9

3.5

3.6

3.5

3.4

b.6

3.8

3.6

3.7

3.6

4.1

3.b

6.0

4.4

b.6

5.1

3.7

3.6

3.6

J.5

3.5

3.5

3.4

3.5

4.1

b.9

4.1

3.8

3.6

3.6

3.6

3.7

3.7

3.7

4.3

6.0

3.7

3.6

3.b

3.4

3.4

3.4

3.4

3.b

3.5

3.3

3.6

3.b

3.4

3.3

3.3

3.3

3.3

3.3

3.3

3.3

4.0

3.7

3.6

3.5

3.3

3.3

3.6

3.3

3.6

3.7

3.3

4.1

3.9

3.8

6.0

4.3

3.8

3.7

3.7

4.1

3.8

3.6

3.6

3.6

3.6

3.5

3.b

3.5

3.b

3.4

3.4

3.4

3.4

3.4

3.4

3.6

3.2

3.2

3.6

4.4

3.4

3.2

6.0

3.8

3.7

3.6

3.6

3.3

3.6

3.6

3.5

3.6

3.3

3.3

3.J

3.0

3.0

3.3

3.3

3.3

3.3

3.0

3.3

3.3

3.3

3.2

3.2

3.0

3.0

3.0

3.0

3.3

3.0

3.0

3.0

3.2

3.8

3.2

3.2

3.2

3.7

3.2

3.1

3.1

3.0

6.0

6.1

3.6

J.4

3.3

3.2

3.1

3.1

6.0

6.0

6.1

5.5

5.0

6.3

6.3

6.4

6.2

5.8

5.7

b.O

4.5

6.4

3.0

2.8

3.0

3.0

3.0

3.2

3.0

3.0

2.9

2.9

3.0

3.6

3.3

3.2

3.2

3.0

2.9

. 2.9

3.0

2.8

5.6

4.2

4.2

4.5

5.0

4.9

5.8

4.7

5.0

3.0

4.1

2.8

4.2

3.9

3.8

3.7

3.6

3.6

3.6

3.5

3.4

3.4

3.4

3.6

4.3

5.9

4.6

4.1

3.9

3.6

3.6

3.6

6.3

6.4

6.1

5.0

4.5

4.3

4.1

6.1

5.9

b.b

6.4

3.9

3.7

3.6

3.5

3.5

3.3

3.3

3.3

3.3

3.2

3.1

3.^

3.4

4.0

4.1

3.8

3.0

3.0

3.4

3.4

3.4

6.0

5.0

4.4

3.8

3.4

2.9

3.6

5.5

4.y

2.9

DAY



PH (STANDARD UNITS). WATER YEAR OCTOBER 1979 TO SEPTEMBER 1980

MAX

MIN

OCTOBER

MAX

MIN

NOVEMBER

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22

23

24 25

26

272829 30 31

5.1

5.0

6.1

5.1

5.5

6.3

5.3

6.5

6.5

6.3

6.1

6.5

6.3

5.9

6.0

6.0

5.9

5.3

4.6

4.4

4.3

4.5

4.4

4.4

4.4

4.4

5.1

4.4

4.4

4.4

4.4

4.2

3.7

4.2

3.7

4.6

4.9

4.5

4.2

6.3

6.1

5.8

5.8

5.9

5.5

4.7

5.7

5.4

4.2

4.3

4.2

4.0

3.8

4.2

4.1

4.3

4.3

4.2

4.3

3.2

3.6

3.7

4.1

5.7

5.2

...

...

...

-

...

...

...

...

-

...

...

...

...

...

...

...

...

...

...

...

...

...

3.6

4.5

4.6

...

...

...

.

...

...

.

...

...

...

...

...

»-

...

...

...

...

...

...

...

MAX

MIN

DECEMBER

MAX

MIN

JANUARY

MAX

MIN

FEBRUARY

5.6

5.9

5.6

5.6

5.5

5.4

5.1

6.3

6.3

6.4

6.2

6.2

6.0

5.7

5.8

5.6

5.3

b.l

6.1

6.2

6.2

6.0

6.0

5.8

5.8

5.7

5.4

5.6

5.4

5.2

5.0

4.6

4.7

5.0

6.2

5.9

5.9

5.9

5.5

5.4

5.3

4.9

4.8

4.7

4.6

6.1

6.1

5.9

5.8

5.7

5.6

5.5

5.5

5.3

5.1

5.1

5.2

5.1

5.2

3.3

5.1

5.0

6.1

6.2

6.1

6.2

6.1

6.4

6.3

5.8

5.5

5.4

5.4

5.4

5.4

5.2

6.3

6.2

5.9

5.9

5.7

5.5

5.5

5.3

5.1

5.0

5.0

5.1

4.8

5.0

4.8

4.8

4.5

4.7

6.0

5.d

5.7

5.6

5.7

5.6

5.t>

5.3

5.3

5.2

5.2

4.8

5.1

5.1

5.8

5.7

5.7

5.0

4.6

b.O

0.4

t>

.3

5.2

5.2

5.2

5.0

5.1

5.1

4.8

5.0

4.9

4.9

4.9

4.8

4.8

6.1

5.7

5.4

5.6

6.1

6.1

5.9

5.9

6.0

6.0

6.0

5.9

5.9

5.7

...

4.9

4.7

4.8

4

.84.8

4.9

5.0

4.7

4.7

4.7

4.7

4.5

4.3

4.3

4.3

4.9

'

5.4

4.8

4.9

5.3

5.4

5.7

5.7

5.8

5.7

5.6

5.5

5.4

5.2

...

5.3

5.3

5.5

5.4

6.1

6.1

6.1

5.9

5.9

5.8

5.9

5.6

6.0

6.2

6.0

6.0

6.0

5.8

5.8

5.8

5.8

5.9

5.8

5.9

5.7

5.7

5.7

5.6

5.9

5.7

6.4

4.8

4.9

4.8

4.8

i>.4

5.9

5.8

5.5

5.5

5.4

5.6

4.6

5.4

5.4

5.0

5.0

4.9

4.9

4.6

4.7

5.1

5.1

5.1

5.0

5.2

4.8

4.7

4.6

5.4

5.0

5.3

MONTH

6.5

3.2

5.7

3.6

6.4

4.6

6.4

4.5

6.1

4.3

6.4

4.6

CO

CO

DAY

Appendix 1.--Water-quality monitor data, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio,


PH (STANDARD UNITS) »

WATER YEAR OCTOBER 1979 TO SLPTE-tBfcR

I9d0

MAX

MIN

APRIL

MAX

MIN

MAY

1 2 3 4 5 6 7 b 9 10 11 12 13 14 15 16 17 18 19

20

21 22

23

24

25

26

27 28

29

30 31

MONTH

YEAR

NOTE:

6.2

6.2

6.2

6.2

6.0

5.9

5.6

6.4

6.5

6.4

6.3

6.6

6.5

6.6

6.5

6.4

6.2

6.2

6.2

5.9

5.9

5.7

5.7

5.4

5.3

5.1

5.2

5.1

5.1

4.9

...

6.6

6.6

NUMBtR OF

6.1

5.9

5.9

6.0

5.8

b.5

4.7

4.7

6.4

6.3

6.1

5.b

5.9

5.8

6.2

6.0

3.0

5.3

5.5

5.6

5.4

5.3

5.2

5.0

5.0

5.0

5.0

4.9

4.9

4.7

...

3.0

3.0

MISSING D

4.8

4.8

4.7

4.7

4.6

4.5

4.5

4.6

4.8

4.5

4.3

6.2

6.5

6.2

5.9

4.9

6.3

6.1

6.2

6.1

6.0

5.9

5.9

5.7

5.4

4.8

4.4

4.3

4.1

4.1

5.2

6.5

AYS OF Rf

4.6

4.4

4.4

4.4

4.3

4.3

4.3

4.3

4.1

4.1

4.1

4.2

6.0

5.6

4.6

4.2

3.9

5.b

4.9

5.9

5.9

3.4

4.2

4.7

4.7

4.3

4.2

4.0

3.6

3.7

3.7

3.4

ECORO E

MAX

MIN

MAX

JUNE

JULY

6.2

5.4

6.3

4.4

6.3

4.4

MAX

...

...

3.9

3.U

3.b

3.8

6.2

6.4

5.8

6.1

4.5

4.5

4.2

4.6

6.1

6.3

6.3

6.2

6.2

5.9

5.2

4.5

4.4

4.2

4.3

6.0

S.9

MIN

AUGUST

...

.-.

.__

-

...

...

3.b

3.6

3.7

3.5

3.6

5.4

4.7

4.5

4.4

4.2-

4.1

3.9

3,d

4.2

4.6

6.1

5.9

5.2

4.S

4.3

4.0

3.9

3.7

4.1

4.5

MAX

MIN

SEPTEMBER

5.7

4.7

4.3

4.1

3.9

3.b

3.7

3.6

5.7

5.7

3.9

3.8

3.6

4.2

4.1

3.7

3.6

J.6

3.6

3.6

3.5

3.4

3.5

3.6

3.5

3.5

3.6

3.5

3.5

3.5

...

4.2

4.3

4.1

3.8

3.7

3.6

3.S

3.S

3.4

3.9

3.7

3.5

3.4

3.4

3.7

3.6

3.5

3.4

3.4

3.3

3.3

3.3

3.4

3.4

3.3

3.4

3.4

3.3

3.3

3.3

6.4

3.5

5.7

3.3

DAY

MONTH



TEMPERATURE* AIR (DEG. C>» WATER YEAR OCTOBER 1978 TO SEPTEMBER 1979

MAX

MIN

OCTOBER

MAX DECEMBER

MAX

HIM

FEBRUARY

-3.0

25.0

-6.5

17.5

-13.0

15.5

-21.5

13.5

-23.5

MAX

MIN

i-iAPCH

1 2 3 4 5 b 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22

23

2425 26

27 28 29

30 31

20.5

24.0

24.0

17.0

21.5

13.0

12.5

11.5

18.0

22.5

21.0

26.5

16.0

11.0

11.0

12.5

12.5

20.5

17.5

20.5

24.0

27.0

20.0

16.0

20.5

17.5

17.0

21.0

16.0

23.0

23.0

8.5

5.0

4.0

10.5

4.0

5.0

4.5 .5

-1.5 .5

4.0

11.5

9.5

6.5

4.0

5.0 .0

-1.5

4.5 .0 .5

2.0

5.5

-1.0

-3.0

8.0

-0.5

-2.0 .0

-2.5

-0.5

18.5

21.5

22.5

23.5

25.0

24.0

9.0

13.0

7.0

17.0

21.5

12.0

20.5

17.5

7.0

10.0

18.5

10.5

12.0

9.0

8.5

14.0

12.5

9.5

5.0

4.0

12.0

7.5

4.0

7.5

-0.5

-3.0

-O.b .5

1.0

l.b

5.5

-3.0

-4.0

-1.5

-0.5

6.5

7.0

5.0

5.0

5.0

9.5

6.0

-2.U

-3.5

2.0

1.0

6.0

1.0

-2.5 .0

2.0

-5.0

-6.5

-b.O

11.5

13.0

14.5

15.0

10.5

13.5

12.0

17.0

1.5

-3.0

4.0

7.5

8.5

2.5

10.0

1 1.

03.5

b.O

1.5

17.5

6.5

7.5

8.0

8.5

2.5

2.5

-1.0

1.0

9.0

7.5

15.5

-8.5

-4.0

2.5

1.5

-2.0

-3.5

-0.5

2.0

-7.5

-12.5

-12.5

-4.0

-5.0

-8.0

-3.0

-4.0

-5.0

-b.b

-0.5

1.0

-2.0

-5.5

-8.0

-5.5

-4.0

-4.5

-10.0

-13.0

-8.5

-0.5

5.5

15.5

-1.5

-7.5

-2.0

-2.5

1.5

-l.b

-5.5

-5.0

-2.0

-5.0

1.5

o.b

5.5

-6.b

*.o

7.0

-1.5

-0.5

4.0

2.b

3.5

9.5

3.5

-4.5

-2.5

3.5 .0

-3.0

-1.0

-2.5

-0.5

-16.5

-17.5

-10.0

-10.0

-8.5

-7.0

-20.5

-21.5

-12.0

-13.5

-9.5

-5,s

-14.5

-20. b

-8.0

-6.5

-11.5

-12.0 .5

-0.5

-5.5

-7.0

-9.0

-9.0

-b.5

-3.0

-3.0

-5.5

-b.5

-8.5

-6.0

2.0

4.5 .5

-4.0

1.0

1.0

-1.5

-7.0

-5.5

-<*.b

-2.0

-4.0 .0

3.0 .0

-8.0

-4.0

1.5

13. b

8.t>

10.0

10. D

5.0

3.5

1.5

7.0

12.0

---

---

-14.0

-U. 0

-7.0

-14.5

-21.5

-22.0

-7.0

-18.5

-23.0

-23.5

-19.0

-16.0

-23.0

-17.0

-2.0

-16.5

-21.0

-13. i

-18.0

-20.0

-6.5

-3.0

2.0

1.0

1.0

-4.0

-3.b

-6.5

._

---

11.0

12.5

21.0

19.0

12.0

10.5

14.0

13.5

9.0

b.O

-2.5

8.5

18.5

13.0

-2.0

9.0

18.5

20.5

20.5

21.0

23.0

26.0

19.0

9.5

4.0 .0

5.0

19.5

24.5

2b.b

18.5

-2.0

-0.5

-1.5

9.0

-l.b

-3,b

-6.b

-2.0

-b.5

-5.0

-9.5

-b.b

-8.0 .0

-11. b

-13.5

-8.b

2.0 .0

5.0 .5

-l.o 6.0

1.0

-3.5

-3.5

-7.0

-8.5

9.t>

8.5

10.0

2b.O

-13.5

DAY



TEMPERATURE* AIR <D£G. C)» WATER YEAR OCTOBER 1978 TO

SEPTEMbER 1979

MAX

MIN

MAX

MIN

MAX

MIN

MAX

MIN

APRIL

MAY

JUNE

JULY

MONTH

30.0

-9.0

YEAR

32.0

-23.5

32.0

-3.0

32.0

32.0

b.o

32.0

t>.0

MAX SEPTEMBER

1 2 3 4 5 6 7 8 910 11 12 13 14 16 16 17 IB 19 20

21 22

23

24

25

26

27 28 2930

31

10.5

20.0

11.5

10.5

12.0

11.0

7.5

21.0

11.5

14.0

19.0

24.5

23.0

20.0

8.5

10.0

13.5

16.5

19.5

2b.5

29.0

23.0

21.5

30.0

30.0

20.0

15. b

12.5

16.0

19.0

6.0

7.0 .5

1.0

3.5

-b.5

-9.0

-1.5

-0.5

-4.5

-3.0

9.0

B.5

1.0 .0

-2.0

-2.0

-4.0

-4.5

-2.0 .5

10.5

11.0

10.5

13.0

11.0

2.5

1.5

-1.0

-1.0

19.0

28.0

21.5

12.0

18.5

26.0

32.0

32.0 ___

16.5

25.0

23.5

20.5

26.0

29.5

31.5

27.0

27.5

21.0

19.0

10.0

18.0

18.5

25.0

23.5

30.5

24.5

-3.0

-1.0

12.5

4.0

-1.0

-0.5

4.5

8.5

11. b

16.5

13. b

14.5

7.0

3.5

6.5

1.0

-0.5

1.5

3.5

13.0

12.0

5.5

14.0

10.0

5.0

5.0

8.0

7.5

3.0

5.5

15.5

29.0

£7.5

^4.b

30.5

31.0

31. b

31.5

31.5

31.5

24.5

tb.Q

tb.O

--_

__

31.5

<;8.o

2B.5

---

28.5

31.0

28.0

21 .0

23.5

2*. 5

30.5

32.0

25.0

20.5

ltt.

514.0

11. b

7.0

11.0

15.0

15.0

19.5

18.5

16.0

11.5

6.5

8.5

8.b

12.0

12.5

15.0

16.0

12.5

12.0

18.0

15.5

16.0

8.5

4.0

5.5

8.0

12.0

15.5

13.5

23.5

26.5

30.0

23.5

23.5

2t>.5

29.5

22.0

30.0

___

32.0

26.0

---

-_-

31.0

28.0

31.5

32.0

___

31.5

27.5

31.0

31.0

27.5

31.5

-__

12.0

14.5

9.b

11. 0

7.0

b.O

7.0

10.5

19.0

19.0

16.0

15.5

21.0

21.0

20.0

19.0

Ib.u

12.5

9.0

10.0

18.0

17.5

20.0

21.0

21.5

22.0

21.5

22. b

21.0

17.0

21.0

2tf .5

_-

22.5

24.5

27.0

26. b

21. b

24.0

27. b

29.0

30.5

29.0

31.0

32.0

29.0

28.0

27.5

29.0

30.0

30.0

31.0

2^.5

19.0

16.5

16.5

1«. 5

19.5

19. b

20.5

19.0

22.0

17.0

12.5

9.b

13.0

8.5

6.0

7.0

17.0

20.5

21.0

20.5

19.0

21.0

20. b

18.0

18. b

21.0

19.0

20.0

19.5

16.0

£9.5

29.5

30.0

27.5

19.0

23.0

28.0

30.5

32.0

28.0

d\ .5

20.5

23.5

2b.5

^7.5

£2.0

2b.5

18.5

lb.0

22.0

26.0

26.0

28.0

26.5

21.5

2b.O

26.5

18. U

19.5

21.0

18. D

19.0

19.5

14. U

9.D

6.5

8.0

12.0

It. 5

16.5

14.5

8.5

5.5

7.5

10.0

8.5

6.U

16.0

10.5

7.0

6.5

9.0

9.0

10. b

17.0

14.5

13. b

32.0

5.5

DAY



TEMPERATURE* AIR (DEG. C)» WATER YEAR OCTOBER 1979 TO SEPTEMBER 1980

MAX

MIN

MAX

MIN

MAX

MAX

NOVEMBER

DECEMBER

FEBRUARY

MARCH

1 2 3 4 5 6 7 fa 91U 11 12 13

1^ 15 16 17 IB 19 20

21 22

23

2425

26

27

28

29

30 31

27.0

20.5

21.0

15.0

14.5

Id. 5

14.0

18.5

13.5

11.0

12.5

15.5

10.0

13.0

14.5

19.5

25.0

26.0

27.5

30.5

31.0

31.0

15.5

7.5

9.0

9.0

19.0

17.0

21.5

24.5

26.5

13.5

13.5

11.5

10.5

b.5

3.0

3.0

1.5

7.0

2.5

3.0

8.0 .0

-0.5

-2.0

10.0

10.0

8.0

7.5

10.0

10.5

11.0

4.5

4.5

-0.5

-3.5

-3.5

2.0

-0.5

1.5

5.5

25.5

14.0

13.0

12.5

18.0

11.5

6.5

14.0

11.0

5.0

8.5

8.5

7.0

7.5

9.5

18.0

20.5

20.0

22.5

23.5

18.0

22.5

10.5

22.0

16.0

17.0

16.0

-0.5

-0.5

9.5

3.0

-2.U

-4.0

-3.0

-1.0

4.0

7.5

3.5

-1.5

-3.0

-1.5

-2.0

-2.0

-3.0

-5.0

-1.&

-2.0

3.0

3.0

10.5

9.5

7.0

7.5

5.0 .0

-2.0

-4.0

-6.5

4.0

-1.5

4.5

9.5

lt>.5

14.0

12.0

5.5

7.5

12.0

21 .0

17.5

4.5

4.0

9.0

8.5

-4.5

2.5

7.5

9.5

12.5

11.0

13.5

15.5

7.0

3.5

3.0 .0

2.0

-0.5

-1.5

-6.0

-9.0

-11.5

-2.5

-3.5

3.0

-3.0

-6.5

-6.0

-5.0

-2.U

5.0

-1.0

-5.5

-8.0

-5.5

-11.3

-12.5

-5.0

-7.0

-b.O

1.5

5.0

8.0

1.5

1.0

-4.5

-7.0

-3.3

-5.0

-5.0

-1.0

1.0

3.5

-1.0

-2.0

2.0

4.5

1.0

1.5

8.5

12.0

-1.0

8.0

7.0

5.5

12.5

15.0

4.5

5.3

5.0

4.5

4.0 .5

2.0

8.5

1.5

2.5

-3.0

4-.5

-4.0

-3.5

-3.5

-2.0

-1.0

-4.0

-4.5

-3.5

-9.0

-9.5

-12.0

-12.5

-1.5

-9.0

-7.5

2.0 .0

-O.b

3.0

-2.5

-3.5

-4.0

-9.5 .0

-10.0

-11.5

-1.5

-8.0

-4.0

-5.0

-12.5

-11.5

-13.5

-3.0

-3.5

-4.U

-2.5

l.U

3.0

-2.0

3.0 .0 .0

l.U

2.5

4.5

6.5

b.5

2.5

-3.0

4.0

13.0

5.0

9.5

18. b

8.0

4.5

6.0

-2.5

1.0 .0

-5.5

-16.0

-18.0

-17.3

-17.0

-15.0

-4.0

-7.0

-10.5

-4.0

-13.0

-12. b

-18.3

-17.3

-9.5 .5

-13.0

-16.0

-18.5

-8.5

-0.5

2.5 .5

1.0

-1.0

-7.0

-11.5

-6.0

-16.0

-16.5

-10.5

-6.0

2.5

9.0

8.0

7.U

8.0

22.5

10.5

15.5

2.0

2.5

b.5

1.5

Ib.b

22.0

14.5

7.5

15.5

14.5

12.5

8.0

15.0

13.5

6.0

6.5

17.5

12.0

13.0

13.0

11.0

-14.3

---

-12.0

-1.5

-3.0

-2.5

1.0

-3.0

-*.o

-6.5

-9.5

-1.5

-4.5

-7.b

-3.0 .0

-5.5

-6.5

3,b .0

-3.b

-b.5

b.O

1.5

-3.0

-5.5

3.0

5.0

4.b

2.5

MONTH

31.0

-3.5

25.5

-6.b

21.0

15.0

-13.5

18.5

-18.5

22.5

-14.5

DAY

MONTH

YEAR



TEMPERATURE* AIR (DEG. C)» WATER YEAR OCTOBER 1979 TO SEPTEMBER

MAX

MIN

MAX

MIN

MAX

MIN

MAX

APRIL

MAY

JUNE

JULY

29.5

34.5

-5.5

-18.5

34.5

-3.5

32.0

2.b

32.0

10.0

32.0

15.5

MAX

MIN

SEPTEMBER

1 2 3 4 5 6 7 8 910 11 12 13 14 15 16 17 18 19 20 21 22

23 2425 26

27 2829

30 31

11.5

21.5

22.5

12.5

14.0

21.5

22.5

20.5

17.5

9.0

20.5

13.5

7.0

16.5

b.b

8.5

17.5

21.0

25.0

25.5

23.5

29.5

23.0

22.5

12.0

12.0

11. b

13.0

16.0

17.5

.0-1.0 .5

2.5

-1.0

-2.5 .0

5.0

5.0 .0

-2.5

2.0 .0

3.5

1.5

-1.5

-b.b

-1.0

1.0

1.5

1.5

-0.5

3.5

1.0 .0

1.0

1.5

-1.0

4.0

4.0

22.5

22.0

25.5

30.0

32.0

25.0

19.0

13.5

18.0

26.5

30.5

28.0

31.5

21.5

22.0

27.5

22.0

27.5

24.5

20.5

27.5

30.0

27.0

30.0

29.5

24.5

25.5

31.0

34.5

32.0

31.0

5.5

2.0

3.5

3.5

4.0

5.0

1.0

-3.0

-3.5

-0.5

12.5

14.5

16.0

8.0

2.5

4.0

14.0

15.0

13.5

14.0

11. b

10.5

16.0

16.0

10.0

5.0

3.0

5.5

8.3

16.0

16.0

27.5

28.5

30.0

24.0

c!8.0

32.0

._

d^.O

23.5

20.0

20.0

25.5

30. b _

31. b

21.0

2b.O

27.0

29.5

24.0

28.0

31. b

._

30.0

30.5

_ _

- .

.-

28.5

25.0

16.0

18.5

16.5

11. b

6.0

13.0

18.0

7.5

8.0

7.0

2.5

2.5

5.5

8.5

16.5

9.b

3.b

7.0

7.0

8.0

b.b

6.b

10. b

16. b

13.5

13.0

17.5

17.0

18.5

11.5

29.5

---

29.3

.-

32.0

^b.5

30.5

-

31.0

-

29. b

30.3

---

.-

_ -

-

...

-

_

24.5

28.5

29.5

32.0

__

-

29.5

30.5

31.5

10.0

17.0

22.0

22.5

19.5

14.5

10.0

18.3

21.0

21.5

19.0

20.0

1 7.0

12.5

16.5

23.0

19.5

16.0

17.5

19.5

22.0

20.5

18.3

14.5

13.0

16.5

20.0

20.0

17.0

17.5

17.5

3^.0

...

30.0

...

26.0

3*.0

.._

...

...

29.0

32.0

._

27.0

25.5

24. b

31.5

31.5

dti.

O

...

29. b

29. b

31.5

...

---

...

.

31. b

22.0

19.5

21.0

20.0

20.5

dl.O

23.5

21.5

22.5

22.0

22. b

21.0

16.5

20.0

Id. 5

16.5

17.5

19.5

22.3

21.0

22. b

21.0

16.0

lt>.

515

. b

16.0

16.5

18.0

18.5

19.3

18.0

...

30.5

.

32.0

29.0

32.0

J2.0

23.0

27.0

30.0

31.5

«?4.0

28.0

dtt.

Q23.5

28.5

-

-_-

31.0

23.5

24.0

27.0

18.5

21.5

25.0

df.\

)24.5

20.0

20.5

16.0

16.5

19.0

19.0

16.0

14.0

16.0

12.0

7.5

8.0

16.0

20.5

18.0

12.0

17.0

12.3

9.b

13. b

17.5

19.5

13. b

11.0

13.0

6.5

2.b

6.b

7.0

8.0

32.0

2.5

DAY

Appendix 2.--Daily sediment discharge, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio,


SEDIMENT DISCHARGE* SUSPENDED (TONS/DAY)» WATER YEAR OCTOBER 1978 TO SEPT£Md£R 1979

MEAN VALUES

OCT

NOV

DEC

JAN

FE8

MAR

APR

MAY

JUN

JUL

AUG

SEP

1 2 3 4 5 6 7 8 910 11 12 13 1415 16

17 16 19 20

21 22

232425

26

272829

30

31 IEAN

!TR

YR

.01

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.80

.27

.01

.01

.01

.00

.00

.00

.01

.00

.01

.01

.01

2.0 .29

.02

.01

.01

.03

.11

1979

.02

.01

.01

.00

.00

.00

.00

,00

.00

.00

.00

.00

.00

.00

.01

.02

2.6 .26

.00

.00

.00

.00

.00

.01

.00

.00

.74

.07

.04

.04

.13

MEAN

.01

.01

6.6

4.5 .15

.07

.15

27 16.29

.17

.12

.10

.05

.03

.04

.03

.02

.03

.22

.84

.06

.04

.08

.04

.01

.02

.02

.02

.12

3.0

1.9

.76

6.4 .24

.06

.04

.03

.02

.16

.03

.03

.02

.02

.01

.19

2.3 .17

.04

.10

.13

.05

.85

1.5 .10

.06

.29

.11

.06

.03

.02

.01

.00

.01

.42

MAX

.01

.01

.01

.01

.01

.01

.00

.00

.00

.00

.00

.00

.00

.00

.00

.03

.00

.00

.00

.01

.04

.54

2.2

2.1

4b 4.4 .17

.15

...

2.0

45

.14

.12

.09

.36

.15

.07

.10

.18

.08

.03

.03

.02

.01

.02

.01

.01

.01

.01

.01

.01

.01

.01

.12

1.1 .07

.03

.03

.02

.02

.01

3.6 .21

1.6 .91

.20

.10

.04

.04

.02

.03

.43

.03

.02

.02

.26

.08

.03

.02

.02

.02

.02

.01

.01

.01

.01

.00

.00

.01

.01

.00

.00

.00

.14

MIN

.00

.00

.15

5.6 .19

.10

.06

.03

.02

.01

.01

.01

.01

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.04

3.2 .08

.04

.02

.21

.32

.00

.06

.01

.01

.01

.00

.19

.01

3.7 .07

.44

.08

.04

.03

.02

.01

.00

.00

.00

.00

.04

.51

.01

.01

.00

.00

.00

.00

.04

.00

.03

.Id

.00

.00

.00

.21

.02

.00

.00

.00

.01

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

1.3 .J8

.34

.07

.03

.06

.11

.02

.01

.08

.01

.88

.00

.00

.00

.16

.01

.00

.00

.00

1.9 .14

.05

.02

.01

.01

.00

.01

2.0

2.5

41.20

.13

.45

.06

20.28

2.1

1.1 .50

.16

2.4

.08

.03

.01

.02

.01

.00

.06

.01

.00

.01

.01

.13

.20

7.7 .09

.Of

.02

.01

.00

.00

20 3.8 .24

.10

.09

.10

1.1

7.6 .19

.07

-

1.4

DAY

Appendix 2.--Daily sediment discharge, station 03201700, Big Four Hollow Creek near Lake Hope, Ohio,


SEDIMENT DISCHARGE* SUSPENDED (TONS/DAY)* WATER YEAR OCTOBER 1979 TO SEPTEMBER 1980

MEAN VALUES

OCT

NOV

DEC

JAN

FEB

MAR

APR

MAY

JUN

JUL

MEAN

.39

.71

.27

1.3

.21

WTR YR I960

MEAN

.99

MAX

77

4.6

.66

.71

.71

1.0

MIN

,00

AUG

1.1

SEP

1 2 3 4 5 6 7 tt 9 10 11 12 13 14 15 16 17 18 19 20 21 2223

2425

2b

2728

29

30 31

.09

.08

.05

.08

.06

.11

.05

5.8

3.8 .25

.13

.46

.17

.08

.11

.04

.06

.06

.05

.07

.03

.06

.04

.03

.00

.00

.00

.00

.20

.03

.04

.33

1.8 .13

.11

.05

.03

.01

.01

3.9

4.6 .25

.12

.03

.03

.02

.02

.04

.04

.03

.02

.01

.00

.00

.16

.23

8.7 .24

.12

.14

.04

.03

.02

.02

.02

.01

.02

.01

.01

.00

.00

.00

.02

7.4 .18

.03

.05

.03

.03

.02

.02

.01

.01

.02

.14

.21

.05

.03

.03

.03

.03

.02

.01

.01

.00

.01

.01

.00

.01

.01

.00

.00

36.73

.16

.24

.36

.27

.17

.12

.07

.06

.07

.04

.03

.04

1.7 .48

.04

.04

.02

.03

.02

.01

.02

.01

.01

.01

.01

.01

.00

.00

.00

.00

.00

.00

.00

.00

.04

.02

.00

.03

.bo

1.3

2.7 .46

.15

.31

.21

.10

.03

.02

. _

.02

.02

.07

.03

77 t>

.31.1

2.2 .22

.09

.06

.08

1.5

1.1 .12

.Of

2.6 .28

.10

.09

311.6 .38

.17

.09

.07

.08

121.6

1.9

2.4

.23

.14

.11

.09

.15

.04

.03

6.0 .66

.11

.06

.36

.17

9.9 .55

.23

.48

.09

.06

.04

.04

.02

.02

.02

.01

.00

.02

.02

.02

.01

.00

.02

.03

.00

.02

.12

.09

.01

.00

.00

.00

5.6

4.4

4.4 .05

.03

5.7 .55

.36

.08

.06

.05

.09

.04

.03

.01

.01

.00

.00

.00

.15

5.4

12.70

.18

.10

1.7 .06

.14

.03

.22

.05

.04

.03

.01

.04

.05

.00

.01

.OU

.00

.00

.00

.03

.01

.00

.00

.17

.01

.16

.22

-

.00

.00

.26

.00

.00

.1)0

.00

.oa

t>.s .41

.04

10 5.J .33

.Ib

.09

.01

.00

.00

.00

1.8

7.3 .21

.03

.01

.00

.08

.11

.01

.00

.00

.00

.00

.33

.01

.01

.00

.00

.00

.00

.00

2.3 .23

.01

.04

.00

.00

.00

.00

.43

15 121.8 .08

.03

.02

.01

.00

.00

.12

1.2 .02

.Ob

.02

.00

.00

.00

.00

.00

.00

.69

.21

.00

.00

. OU

.29

.01

.00

. Ou

.00

.00

.00

.00

.OU

.00

.00

.00

.OU

.00

.00

.00

.00

---

.04

Appendix 3. Water-quality data,

station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope,

Ohio,


DATE

WATER

YEAR

OCT 12..

.12

...

24..

.NOV 06...

22..

.30...

DEC 08...

09...

21..

.21...

JAN 04...

16..

.FEB 01...

14...

27...

MAR 13..

.26

...

APR 09..

.11

...

30...

MAY 15..

.30

...

JUN 11..

.28...

JUL 10..

.26...

AUG 08...

23...

SEP 05..

.17...

TIME

1979

1030

1615

1530

1000

1000

0930

1400

1145

1330

1620

1500

1500

1400

0900

1500

1100

1430

1130

1100

1200

1300

1100

1430

1100

1130

1300

0845

1200

1400

1230

STREAM-

FLOW,

INSTAN

TANEOUS

(CFS

) .90

.Ob

.70

.80

.20

.46

34 101.6

1.5

1.4

1.3 .59

.26

3.0 .76

1.0

2.9

1.3 .61

.40

.61

.59

.14

.25

.20

.13

1.0 .24

.19

SPE

CIFIC

CON-

DUCT-

ANCF

(MICRO-

MHOS)

1800 --

1500

1400

1000

550

?70

410

375

450

640

330

675

355

350

750

730

695

500

1300

900

1000

1100

314

950

790

PHFIELD

(UNITS)

2.7 --

2.8

2.7

2.9

3.3 -- --

4.4--

3.7

3.7

3.5

3.2

3.9

3.3

4.0

4.0

3.4

3.4

3.5

4.0

3.0

3.4

3.4

2.9

5.0

3.1

3.5

TEMPER

ATURE,

WATER

(DEG

C)

13.0 --

11.5

10.0

7.0

4.5 -- --

4.5 -- 1.0

2.0 .5 .0

6.5

6.0

5.0

7.0

12.5

17.0

12.0

18.0

17.5

16.5

20.5

18.5

18.0

19.0

14.0

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LEVEL)

(MG/L)

32 17 13 6 13 -- -- 27

171 8 7

11 12 8

13 10 240 3 12 4 2

50 39 127

HArt

D-

NESS

(MG/L

ASCAC03)

600 -

450

480

300

210 94 -- 120

110

140

210 n

190

110 110

210

190

190

150

360

270

270

320

120

300

220

NtSS,

NONCAR-

BONATE

(MG/

LCA

C03) 600 --

450

480

300

210 -- -- 94 -- 120

110

140

210 77 190

110 110

210

190

190

150

360

270

270

320

110

300

220

ACIDITY

TOTAL

HEATED

(Mb/

LAS H) 7.

5--

5.3

5.5

3.3

1.5 -- _-.

.5 1.0

1.0

1.0

2.0 .6

2.5 .4

.6

2.2

1.6

1.6 .8

4.0

2.5

2.2

3.3

3.3

2.0

ACIDITY

(MG/

LAS

CAC0

3)

372

288

273

164 74

2b

--

50 50 50 99 30 124 20

30 109 79 79 40 199

124

109

164

164 99

CALCIUM

DIS

SOLVED

(MG/

LAS CA)

130--

100

110

69 4d

----

'id

--

2626

314618

42 2b

--2b 46 43 42

37 77 60 60 73

- 2d 67 51

MAGNF-

UIS-

SOLVEO

(MG/

LAS Mfi)

bf--

49 50 32 21

V.4

13 12 l<f

227.

8

20 11

11 23 21 21 15 41 3u 29 J4 11 $<L

22

Appendix 3.--Water-quality da

ta,

station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Ohio,


SODI

UM*

SODI

UM

POTAS-

SODIUM,

AD-

SIUM

DI

S-

SORP-

DIS

SOLVED

TION

SO

LVED

(MG/L

SODI

UM

RATIO

(MG/L

DATE

AS NA)

PERC

ENT

AS NA>

WATER YEAR 1979

OCT 12...

12...

24...

NOV 06...

22...

30...

DEC 08...

09...

21...

21...

JAN 04...

16..

.FEB 01...

14..

.27...

MAR 13...

26...

APR 09...

11...

30. . .

MAY 15...

30...

JUN 1 1...

28...

JUL 10...

26...

AUG08...

23...

SEP05...

17...

32--

29

26

20 14

----

6.8

6.1

6.8

11 15 13 139.6 ..

8.6

15 15 13 11 26

2425

26 8.8

20 11

10 12 10 12 13 -- 13 -- 10 11 15 14 26 13 16 -- 15 13 14 13 13 13 16 17 15 14 13 10

.6 _- .6 .5 .5 .4

_- .3 _- .2 .3 .4 .5 .6 .4 .4 __

_.

.4 .5 .5 .4

15

.4 .6

29

.6 .7

28

.6

29

.4

11

.5

23

.3

13

POTAS-

CARBON

SIUM,

BICAR-

ALKA-

DIOXIDE

SULFATE

DIS-

BONATE

CAR-

LINITY

OIS-

DIS

SOLVED

(MG/L

BONAU

(MQ/L

SOLVED

SOLVED

(MG/L

AS

(MG/L

AS

(MG/L

(MG/L

AS K)

HC03)

AS C03)

CAC03)

AS C02)

AS 504)

J.O

3.0

3.0

2.6

2.3 --

1.7--

1.4

1.3

1.6

2.0

1.4

2.0

1.5

-

1.6

2.J

2.2

2.0

1.9

2.7

2.9

2.7

2.7

2.0

2.6

2.4

0 0 0 0 0

0

--

0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 3 0 0

0 0 0 0 0

-- 0

0 0 0 0 0 0 0

--u 0 0 0 0 0 0 0 0 0 0 0

0-_0 0 0 0

0

0 0 0 0. 0 0 0

-- 0 0 0 0 0 0 0 0 0 2 0 0

.0 .0 .0 .0 .0 -- -- .0 -- .0 .0 .0 .0 .0 .0 .0 -- .0 .0 .0 .0 .0 .0 .0 .0 .0

48

.0 .0

910--

660

640

470

2dO

--

110

170

IbO

180

280 96

280

130

--

130

300

270

260

200

560

390

400

480

120

430

320

CHLO-

RlDt,

DIS

SOLVED

(MG/L

AS CD

24-

24

23 17 14

- -b. -

b. 7.

12 14 23 11 11

-10 11 13 U 14 21 21 23 247. Ib 13

- - - 3 - 4 4 - 2

Appendix 3. Water-quality data, station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Ohio,


SOLIOSt

RESIDUE

SOLIDS*

AT 180

DIS-

DATE

WATER

OCT 12...

12...

24...

NOV 06...

22...

30...

DEC 06...

09...

21...

21...

JAN 04...

16...

FE8 01...

14...

27...

MAR 13...

26...

APR 09...

11...

30...

MAY 15...

30...

JUN 11...

26...

JUL 10...

26...

AUG08...

23...

SEP 05...

17...

DEG. C

DIS

SOLVED

(MG/L)

YEAR 1979

1320

992

981

671

374

174

251

233

275

445

185

424

219

--

213

453

470

416

341

905

648

620

802

217

702

490

SOLVED

(TONS

PER

AC-FT)

1.80

1.35

1.33

.91

.51 --

--

.24 .34

.32

.37

.61

.25

.58

.30

--

.29

.62

.64

.57

.46

1.23

.88

.84

1.09

.30

.95

.67

NITRO

GEN*

N02*N03

TOTAL

(MG/L

AS N) .08 .13

.12

.09

.12

-- .11

.16

.11

.09

.13

.18

.08

.09

.04

.03

.06

.05

.06

.11

.09

.12

.11

.07

.02

.11

NITRO-

GENtAM-

MONIA *

ORGANIC

TOTAL

(MG/L

AS N)

39

--

.50

--

.32

.24

.09

.07

,4t>

.18

.49

.22

.33

.35

.15

.28

.31

.00

.30

.44

.37

.23

.34

.23

.34

.81

NI IRO-

GEN,

TOTAL

(MG/L

AS N)

39

.63

.41

.36

.20

.23

.t>7

.27

.62

.40

.41

.44

.19

.31

.37

.05

.36

.55

.46

.35

.45

.30

.36

.92

NITRO

GEN.

TOTAL

(MG/L

AS N03)

170 2.8 --

l.fl

1.6 --

.89

1.0

2.5

1.2

2.7

1.3

1.8

1.9 --

.84

1.4

1.6 .22

1.6

2.4

2.0

1.6

2.0

1.3

1.6

4.1

PHOS

PHORUS*

TOTAL

(MG/L

AS P) .000

.050

.000

.000

.000

.000

.000

.000

.000

.000

.010

.000

.040 --

.000

.000

.000

.000

.010

.000

.000

.030

.010

.010

.000

.000

PHOS

PHORUS,

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P04) --

-- -- --

--

--

.00

.00

.00

.03

.00

--

__

PHOS

PHORUS,

TOTAL

(M(i/L

AS P04) -- -- --

'

-- -- --

_-

.00

.00

.00

.03

.00

.00

.09

.03

.03

.00

.00

ALUM

INUM,

TOTAL

KECOV-

tRABLE

(UG/I.

AS AL

>

110

UOOO

15000

«200

1000

IbOO

4700

2000

4000

5400

310

6600

3500 --

4100

7200

6200

7600

5000

13000

8300

9000

9300

2000

12000

890

ANTI

MONY,

TOTAL

(UG/L

AS SB) 3 1 0 0 0

0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0

Appendix 3.--Water-quality data, station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Ohio,


DATE

WATER

OCT 12...

12...

24...

NOV 06...

22...

30...

DEC 08...

09...

21...

21...

JAN 04...

16...

FE8 01...

14...

27...

MAR 13...

26...

APR 09...

11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17.. .

ARSENIC

TOTAL

(UG/L

AS AS

)YEAR 1979

0 0 0 0 0

-- 1

0 1 1 0 0 1 1--0 0 0 0 1 1 1 1 2 2 0 0

BERYL

LIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS BE

)

100 .

10 10 10 5

0

0 0 010 0 10 0

0 10 10 0 0

20 10 10 10 0 0 10

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD

) 5 2 1 5

77 -- . 3

0 1 7 1 0 1 0

1 5 2 4 7 0 1 0 3 1 0 0

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR

) 4-- b 3 4 4

---- d

3 6 0 4 1 0 0

6 9 5 12 a 9 17 19 20 13 6 19

COPPER,

TOTAL

RECOV

ERABLE

(UG/L

AS CU

) 12 -- 16 106 3

4

6 4 5 6 5 6 4

4 7 6 6 6 10 9 1 9 4 9 8

IRON,

TOTAL

RECOV

ERABLE

(UG/L

AS FE

)

90000

24000

30000

28000

14000

bdOOO

9300

7400

d300

12000

1400

19000

5900

5700

17000

11000

12000

7400

22000

15000

12000

26000

5800

18000

10000

IRON,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE) _. -- . .

--

--

4000

4800

4700

6100 0

3000

6200

10000

4600 -- ._

IRON,

DIS

SOLVED

(UG/L

AS FE

)

44000

24000

30000

26000

8200 -- --

1900

6600

6100

4900

11000

1400

17000

960

830

13000

6200

7300

1300

22000

12000

5600

16000

1200

16000

7400

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB

) 39 84 46 15 41 -- 39

729

140 11 0 12 7

34

32 25

92 213 4 4 5 5 0 3

MANGA

NESE,

TOTAL

RECOV

ERAB

LE(UG/L

AS MN

)

4900

4200

J900

2600

1400

--

bÔ

850

800

990

1800

450

1400

670 --

630

1500

1500

1400

1100

3400

2100

2200

3000

660

2800

3800

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/L

AS MN) -- -- -- . --

--

0

100 0 0

300 0

100

100 20

500

400

Appendix 3. Water-quality da

ta,


Ohio,


DATE

oWER

12...

12...

24...

NOV 06...

22...

30...

DEC 08...

09...

21...

21...

JAN04...

16...

FEB 01...

14...

27...

MAR 13..

.26...

APR 09...

11..

.30...

MAY 15..

.30

...

JUN 11..

.28...

JUL 10...

26...

AUG 08..

.23...

SEP 05..

.17...

MANGA-

MERCURY

NESE.

TOTAL

DIS-

RECOV-

SOLVED

ERABLE

(UG/L

(UG/

LAS

MN

) AS

HG)

YEAR 19

79

4900

<.5

..4200

<.5

3600

<.5

2300

<.5

1400

<.5

-_

.._.

..

520

<.5

100

<.5

800

<.5

990

<,5

1800

<.

5450

<,5

1400

<.5

670

<.5

..

-_63

0 <.

515

00

<.5

1400

<.5

1400

<.5

1100

<.

53100

<.5

2100

<.5

2100

<.5

2900

<.5

640

<.5

2300

<.5

3400

<.5

NICKEL*

TOTAL

RECOV

ERABLE

(UG/L

AS NI)

180 -- 160

150

100 61 -- -- 35 48 26 56 794

69 41 -. 57 98 84 60 66

130

110 0

110 22 110 75

SELE

NIUM*

TOTAL

(UG/

LAS

SE) 0--0 0 0 0

--0

0 0 0 0 0 0 0

--0 0 0 0 0 0 0 0 0 0 0 0

SILVER*

TOTAL

RECOV

ERABLE

(UG/

LAS

AG) 0..0 0 0 0

-- --0

0 0 0 0 0 0 0

__0 0 0 0 0 0 0 0 0 1 0 0

ZINC.

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN) _- -- -- -- -- -- 20

0 0

30 10 60 70

0 0

60 20

ZINC.

DIS

SOLVED

(UG/L

AS ZN)

520 ..

350

470

220

120 .. 60

1000 110 80 170 50 130 80 .. 80 170

160

220 90

330

210

200

250 60

260

150

ZINC.

TOTAL

RECOV

ERABLE

(UO/

LAS

ZN)

520 -_

360

470

2200

120 -_ 80

1000 110 90 170 50 160 80 -_ 90 190

160

220

120

340

270

270

250 60

320

170

CARBON.

ORGANIC

DIS

SOLVED

(MG/

LAS C) J.

O __ 1.9

l.d

2.8

8.3

--_-

d» I

l.ti

1.7

1.5

1.6

4.4

4.7

4.6 __ 1.1

2.9

3.7

2.0

2.0

2.7

1.1

3.1

1.9

4.1

2.0

5.2

CARBON.

ORGANIC

SUS

PENDED

(MG/

LAS C)

.3 .. .1 .3 .6 .3 -- __ 1.0 .2 .2 .1 .2 .2 .2 __ .2 .1 .2 .2 .2 .1 .2 .0 .1 .b .1 .1

PHENOLS

(UG/L)

1__0 1 0 0

-- __2

0 0 0 0 2 0 0

-_0 0 1 0 0 2 0 0 0 0 2 2

Appendix 3. Water-quality data, station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Ohio,


DATE

WATER

YEAR

OCT 02..

.23...

NOV 09.. .

20...

DEC 06...

20...

JAN 10...

24...

FE8 12...

26.. .

MAR 12...

25...

APR 08...

24...

MAY 09.. .

23...

JUN 12...

24...

JUL 10...

21...

AUG

06. .

.19...

SEP 08...

22...

TIME

1980

1230

1600

IbOO

1000

0930

IbOO

IbOO

1400

1100

1400

1100

IbOO

110U

0900

0930

1130

0930

1030

0845

0915

1620

1000

1300

1045

STREAM-

FLOW*

INSTAN

TANEOUS

(CFS

)

1.0 .31

7.6 .40

.68

.65

Ob

.50

.29

1.0 .95

1.1

l.b .81

.28

1.2 .26

.15

1.8 .20

.15

,b6

.11

.13

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) 525

870

220

625

560

408

710

510

710

520

290

330

520

400

660

485

650

1200

300

1100

1000

450

1050

1100

PH

(UNITS)

3.6

3.2

6.5

3.6

3.7

4.2

3.5

3.9

3.6

3.0

5.U

5.1

3.7

4.4

3.6

3.9

3.7

3.2

6.7

3.2

3.1

b.9

3.4

3.3

TEMPER

ATURE*

WATER

(DEG C)

15.0

11.0

8.3

6.5

b.5

3.0

1.5 .5 .5

2.5

l.b

6.5

11.0

9.0

6.5

14.

-a

11.0

15.0

17.5

19.0

23.0

19.0

18.0

17. U

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LEVEL)

MG/L)

423

2229 015

6 19 22 10 83 10 26 5

14 12 14 16 33

HARD

NESS

(MG/L

AS

CAC03)

160

250 82

170

180

140

2^0

160

230

160

120

no

IbO

140

200

160

190

330

110

300 loO

3oO

29U

HARU-

NESS»

NONCAR-

BONATE

(MG/L

CAC03)

160

2bO 03

170

180

140

220

160

230

160

120

110

IbO

140

lOO

160

190

330 9b

300

160

350

290

rtCIOITY

TOTA

LHEATtU

HG/L

AS H) 1.4

<i.t

>

l.b

l.b

1.0

2.6

2.0

2.7

1.9

'

1.4 .9

2.5

1.4

2.0

5.7 .6

3.8

3.0 b

3.0

4.0

ACIDITY

(MG/L

AS

CAC03)

70

129

H9 79 bO

129

99

134

94

--

70 4b

124 70

129

283 30

189

149

2b

179

199

CALCIUM

Ulb-

bOLVEO

(MG/L

AS CA)

36

b6

dQ

40

40 32

48 38

b2

37 27 26 J3

J2

43

34

43 73

29bb

40

76

62

Appendix 3.--Water-quality data, station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Ohio,


DATE

SODIUM*

MAGNE-

SODIUM

POTAS-

POTAS-

CAKbON

SIUM,

SODIUM,

AD-

SIUM

SIUM,

BICAR-

ALKA-

DiOXIDt

bULMTE

Q!S-

DIS-

SORP-

DIS-

DIS-

BONATE

CAR-

LiNlTY

Olb-

DIS

SOLVED

SOLVED

TION

SOLVED

SOLVED

<*b/L

bONATE

(MG/

L SOLVtO

SOLVED

H H

, sss

sT HATI

° sis

, is-

s *&

.rss,

c£»,

.rsa,

.ras,

WATER YEAR 1980

OCT 02...

23...

NOV

09...

20...

DEC

06.. .

20...

JAN

10..

. 24...

FEB

12...

28...

MAR 12...

25...

APR 08..

.

24...

MAY 09...

23...

JUN

12..

. 24...

JUL 10...

21...

AUG 06...

19...

SEP

08...

22...

17

27

7.B

18 20

14 24

16 24

17 12

12 16

14 23

17 21

37 10

34 IS

4033

11

17

7.6

10 13 8.7

13

10 14

13 7.2

6.7

11 8.8

14

12 15

21 V

7.

(

22 13 18 21

13

21 24

18 22

19 19

18 12

15 12

11 14

12 13

14 14

12 15 14 15 10 13

.*

13

2.3

.b

20

2.9

.4

iO

eL.I

.3

12

1.8

.<*

lb

1.9

.J

lu

1.4

.<*

lb

2.2

.3

12

2.2

,<t

l.b

.t

lb

1.6

.3

o.2

1.0

.3

8.2

l.b

.4

1.7

.3

2.0

.4

1.9

.4

l.b

.S

1.9

.b

2.6

it.

2.0

e *T

*-

w

.6

2.9

.*

2.2

.4

2.9

.b

3.2

0 0

230 0 0 U 0 0 0 2 3 0 0 0 0 0 0

210 0 6 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 u 0 0 0 0 0 0

0 0 19 u 0 0 0 0 0 0 t. 4 0 0 0 0 0 0 170 u b 0 0

.0

.0

12 .0 .0

.0 .0

.0 .0 .0

3264

.0

.0 .0 .0 .0

.0

6.7 .0 .a

12

.0 .0

2UO

330 yi

2bO

230

170

310

210

320

220

UO

110

210

100

300

200

260

490

110

500

-.

170

460

b«iO


station 03201600, Sandy Run above Big Four Hollow Creek near Lake Hope, Oh

io,


SOLIDS*

CHLO-

RESIDUE

RIDE*

AT 18

0 OIS-

DEG. C

DATE

WATER

02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12..

.28...

MAR 12..

.25...

APR 08...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10..

.21...

AUG 06. ..

19...

SEP 08...

22...

SOLVED

(MG/L

AS CD

YEAR 1980

8.1

10 4.4

9.6

7.8

7.0

9.1

6.5

10 11

8.0

6.6

6.8

7.0

9.3

7.3

12

12 6.8

14

10 11 12

DIS

SOLVED

(MG/

L) 327

513

171

399

3e»8

262

465

349

502

365

208

203

325

289

470

317

417

844

220

803

312

744

792

SOLIDS*

DIS

SOLVED

(TON

SPER

AC-FT) .44

.70

.23

.54

.50

.36

.63

.47

.68

.50

.28

.28

.44

.39

.64

.43

.57

1.15 .30

1.09 .42

1.01

1.08

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .0

6.O

b

.23

,0s

.12

.07

.07

.Oa

.oa

. 14

.13

.13

.07

.00

-- .06 .10

.1* .22

.08

.09

NITRO

GEN* AM

MONIA

+ ORGANIC

TOTAL

(MG/L

AS N) .2

4.2

1

.70

.21

.13

.04

.45

.£l

.67

.11

.17

,J*

dQ

.d*

_- .31 .43

.18 .20 .13

NITRO

GEN*

TOTAL

(MG/

LAS

N) .3

0.26

.93

.26

.25

.11

.5^:

.29

.75

.85

.30

.47

.27

.35

.37 .53

.32

.48

.27

NITRO

GEN*

TOTAL

(MG/

LAS NOJ)

1.3

1 .d

.

4.1

1.2

1.1 .4*

2.3

1.3

3.J

3. a

1.3

2.i

1.2

1.0

1.0

2.3

1.4 -- --

2.1

1.2

PHOS

PHORUS*

TOTAL

(MG/L

AS P) .010

.000

.000

.000

.000

.000

.000

.000

.000

.010

.010

.010

.000

.010

.020

.010

.010

.010

.000

.010

PHOS

PHORUS*

TOTAL

(MG/

LAS

P04) .OJ

.00

.la

.00

.00

.Ou

.00

.uO

.00

.03

.03

,0-J

.00

.03

.00 .Oj

.03 -- .03

.00

.03

ALUM

IN

UM*

TOTAL

RECOV

ERABLE

(UG/L

AS AD

4900

6000

2000

5200

4900

4400

O800

4bOO

7700

5300

bOO

1300

3700

3500

4300

1500

0

1900 --

1000

02300 --

ANTI

MONY*

TOTA

L(UO/L

AS Sb

) 0 0 0 u 0 0 0 0 0 0 0 0 0 0

-- -- -

-- --

Appendix 3. Water-quality data, station 03201600, Sandy Run above Big Four Hollow Creek near Lake Ho

pe,

Ohio,


DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10..

.24...

FEti 12..

.28...

MAR 12..

.25...

APR OB..

.24...

MAY 09...

23...

JUN 12..

.24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

ARSENIC

TOTAL

(UG/L

AS AS

)YEAR 1980

2 1 1 1 0 0 1 2 1 1 1 0 1 0

0

BERYL-

LI UM»

TOTAL

RECOV

ERABLE

(UG/L

AS BE) 10 10

0 0

20 20 20 10 10 0 0 0 10 10 --

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CO) 0 0 0 0 0 0 0 0 0 1 0 0 0 0

1

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/

LAS CR) 10 16 10 20 302 10 30 39 13 13 b c 6

20

COPPER*

TOTAL

RECOV

ERABLE

(UG/L

AS CU) 4 7 J b 4 b 6 3 6 4 3 2 4 4

8

IRON

* TOTAL

RECOV

ERABLE

(UG/

LAS FE)

13000

IbOOO

13000

12000

12000

6400

1800

022000

1400

011000

5000

4400

1200

06600

11000

14000

8600

19000

10000

16000

11000

bOOO

1600

0

IRON*

SUS

PENDED

RECOV

ERABLE

(UG/

LAS FE)

bOOO 0

bOOU 0

4bOO

4500

3900

4700

b200

3400

12000

4800

17000

9100

3000

4300

2000

IRON

* DIS

SOLVED

(UG/L

AS FE)

2700

13000

bbO

6200

7100

1400

18000

17000

1400

06bOO

blO

b40

7300

1400

7600

1800

3800

1800

880

13000

670

14000

12000

LEAD*

TOTAL

RECOV

ERABLE

(JG/L

AS

Pfa) 1 0 2 t 0 1 1 0 0 12

1'

1 0 3 0 0 1 4 <L 9 91*

9

MANGA

NESE*

TOTAL

RECOV-

ERABuE

(UG/L

AS Mi

N)

1100

1900

480

1400

1200

890

1600

1200

1900

990

600

b30

960

880

IbOO

9bO

1600

2800

5t>0

2700

2300

930

2900

MANGA

NESE*

SUS

PENDED

HECOV.

(UG/L

AS MN)

100 0

100

100 0 0 0 0 0

20 100

20 0

100

90

100 0 0 0

bO

2000


ta,


Ohio

,


DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FE6 12...

28...

MAR 12...

25...

APR 08...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

MANGA-

MERCURY

NESE*

TOTAL

DIS-

RECOV-

SOLVED

ERABLE

(UG/L

(UG/L

AS MN

) AS HG)

YEAR 1979

1000

<.b

1900

<.l

380

<.l

1300

.1

1200

1.4

890

<.l

1600

.21200

<.l

1900

<.l

970

.6

590

.1b30

.1

940

.1880

<.l

1400

860

1500

2800

bbO

.12700 --

880

330

<.l

3000

NICKEL*

TOTAL

RECOV

ERABLE

(UG/

LAS NI) 48 75 17 b5 58 34 65 47 71 42

280

40 31 ....

....

21 ....

....

SELE

NIUM*

TOTAL

(UG/L

AS SE) 0 U U u 0 0 U 0 0 0 0 0 u 0

-- -- _. -- ....

--

0

SILVER*

TOTAL

RECOV

ERABLE

(UG/

LAS AG) 0 0 0 0 0 0 0 0 0 U 0 U 0 0

-- -- -- -- -_ -_

0

ZINC*

SUS

PENDED

RECOV

ERABLE

(UG/

LAS ZN

) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

-- 10 0 0 0

ZINC

*DIS

SOLVED

(UG/L

AS ZN

)

130

190

40

IbO

170

120

190

IbO

210

UO 60

130

no 100

IbO 90

150

290 70

330 --

BO

260

320

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZlM*

130

190

40

IbO

17U

120

190

IbO

c\0

120

60 130

110

100 -- 100 --

290 70 .

bo

2bO

CARBON*

ORGANIC

DIS

SOLVED

(MG/

LMS

O a.

t6.2

4.4

0.1

2.1

<d.2

2.3

i./

3.3

2.U

e>.3

1.6

/.2

1.6

--

2.3 --

4.3

1.4 --

2.3 --

<i.4

CARBON*

ORGANIC

SUS-

PENDtD

(MG/L

AS C)

.a .0 .1 .3 .2 .1 .2 .1 .2 .2 .t>

.1 .1 -- .t>

.0

1.0 -- .0

PHENOLS

(UG/L) 1 0 0 0 0 0 £ 0 0 0 6 3 0 0

-- --

-- -_

--

--


station 03201615, Big

Four Hollow Creek above East Fork Big Four Hollow

Creek near Lake Ho

pe,

Ohio,

water year 1979.

L»ATt

OCT 12...

25. ..

NUV Ob. .

.20...

30...

OtC

tn

22 *

0

JAM0*...

17...

FtB u 1

. .

.16. .

.27. ..

MArt

12. ..

2b. .

.Ai->*

10.. .

27.. .

MAY lb...

Jl .

..

|i j

l\J

u u * 1 1

...

2o .

. .

TIMt

13*3

1 1 30

1 10U

IdOO

1*30

1 1 0 u

1030

iboo

1 b U U

1 1 JO

1 10

0

1200

0*30

1200

UÔu

1 u U U

0^30

1130

iDOO

^-T:.-

JAYoL -

JfJihlC

<J!i<<iA\J»

HA^J-

CJ./

- CHc.""-

HAHII-

"JES

S*

ACii

)lTY

CALCIUM

DJCF-

1CAL

M-SS

\F)MCA-<-

TOTAL

ACUITY

DIS-

4\iC

tL

PM

Tt^D^^-

(hib^

Mb/L

ÔNAfi

HEATtD

(M6/L

SOLV

Et)

( 11L-VO-

AT.J

-^F

L^VcL)

AS

(^b/_

(MG/L

AS

(Mb/L

4HOs)

(JMlTs)

(utO C)

('Vi(iXL)

CACOJ)

C^Ca3)

AS H)

CACJ3)

AS CA

)

JbO

3.0

ID.O

110

110

.7

3D

23

joO

D.H

7.D

J2

120

120

26

JbO

b.l

?.b

15

1^0

120

--

--

27dbU

t>.9

b.O

^ 110

-rfW

2b

S.3U

b.H

b.O

ib

111)

HO

2b

220

-J.n

d.v

K

* *

7*

--

20

i^b

b.7

,D

^rl

7o

b7

--

17c:UJ

b.U

,D

* *b

77

--

20

190

-a.-y

.^

S> H^

7<+

192bO

b.9

,D

5 MO

idO

31Ib

i)

5.^

3.0

H 51

*7

12

^00

5.9

D.D

12

-55

^*

201VO

b.l

'-f.O

12

-itt

»0

21

210

b.l

11.

u U

7b

bl

1«250

b.*

11.

0 10

-T7

32

23

£JU

b.b

17.0

d7

>0

7D

21dbn

o.d

ID.U

3 *J

bJ

22

232

b.ci

l^.U

13

-JH

bo

--

22

c75

o.2

17.0

21

^1

43

20

MAbNE-

SIUM,

ÎS-

bDLVEO

(M3/L

A5 MG

)

13 1* 13 12 12 ti.3

8.7

8. 6

H.b

135.0

b.4

b.7

7.5

9.b

9.1

9.3

B.l

9.9

Appendix 4. Water-quality data, station 03201615, Big Four Hollow Creek above East Fork Big Four Hollow

Creek near Lake Hope, Ohio, water year 1979 Continued

SODIJM+

SODIUM

POTAS-

POTAS-

CARBON

SODIUM,

AO-

SUM

SiUM,

rtlC

AR-

ALKA-

DIOXIDE

1->I

S-

SORP-

DI5-

Ois-

BONATE

CAR-

LINITY

OIS-

SOLVEU

TION

SOLVED

SOLVED

( 1G

/L

DONATE

(MG/L

SOLVED

(MG/L

SODIUM

RATIO

(MG/L

(MG/

L AS

(MG/

L AS

(M

G/L

DATE

AS iMA)

PERCENT

AS

\IA>

AS

N>

HC03)

AS C0

3)

CAC03)

AS CO

*)

OCT \d...

25...

MOV 06...

20...

30...

OtC ^2...

JAN04...

11...

FE6 ul..

.Ib...

dl...

MAR 12...

26...

APR 10...

27...

MAY 15...

31...

JUN 11...

dti...

5.2

5.1

5.5

6.<»

5.7

4.5

3.4

4.3

4.5

b.2

2.b

4.2

5.1

4.b

4.7

4.5

4.5

4. 3

4.6

9 8 911 10 10 «10 108

10 10 11 11 9

10 9 910

.2 .2 .2 .3 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2

2. 2. 2. d. 2. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1. 1.6.1

1. 1.5.4

1.

5 5 0 d 0 1 <+ 3 6 7 3 5 4 6 8 7 *> b b

U 0 420 2 Id 14 10 10 14 4 1

10 lb 18 18 1* 28 10

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 3162

10 118 8

113 1 8

15 15 15 10 238

.0 .0

51 40b.l

30 4b 16 20 28

20 2.0

13 23 11

9.1

12

7.1

10

SULFATE

DIS

SOLVED

(MG/L

AS 504)

140

150

148

110

100 84 75 73 86

17653 90

84 73

97 92

95 78

100

CHLO

RIDE,

OIS-

S1LVED

MG/L

AS CD

3.0

3.7

4.3

6.6

6.3

4.7

3.3

5.0

4.8

4.9

2.7

4.2

4.9

4.3

3.7

2.5

3.1

3.5

2.4

Appendix 4. Water-quality data, station 03201615, Big Four Hollow Creek above East Fork Big Four Hollow


en

to

DATE

OCT 12...

25...

NOV 06. ..

20...

30...

DEC 22...

JAM 04...

17...

FEd 01...

16..

.27...

MAR 12...

26...

APR 10...

27...

MAY 15...

31...

JUN 11...

28...

SOLIDS,

RESIDUE'

AT IbO

OEG. C

DIS

SOLVED

(MG/

L) 2d5

246

2*1m 192

147

135

134

144

275

96

Ib4

151

Ib2

lt>3

179

166

160

199

.

SOLIDS,

JIS-

SDLVED

(TONS

PER

AC-FT)

.31

.33

.33

.26

.26

.20

.18

.IB

.20

.37

.13

.21

.21

.21

.22

.24

.23

.22

.27

NITRO

GEN,

M02+N03

TOTAL

(MG/L

AS N) .06

.05

.05

.08

.05

.06

.07

.11

.U6

.35

.25

.07

.06

.04

.04

.03

.05

.02

.05

NITRO

GEN),

TOTAL

(MG/L

AS NO

31.4

3

.41

.26

.11

.11

.14

.11

.2U

.64

.47

.13

.35

.33

.37

.31

.16

.15

.32

NITRO

GEN,

TOTAL

(MG/L

AS N03)

140 1.9

l.d

1.2 .75

.49

.62

.49

.89

2.8

2.1 .58

1 .6

1.3

1.6

1.4 .71

.66

1.4

PHOS

PHORUS,

TOTAL

(MG/L

AS P) .0

1.00

.00

.00

.00

.00

.00

.00

.00

.00

.02

.00

.00

.00

.00

.00

.01

.01

.00

PHOS

PHATE,

TOTAL

(MG/L

AS P04) .00

.00

.03

.03

.00

PHOS

PHORUS

TOTAL

(MG/L

AS P04) --

..

--

-- ..

-_ .00

.00

.03

.03

.00

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS AL)

210

100000

410

350

320

310

520

350

340

400

350

680

500

700

220

300

400

600

400

ANTI

MONY,

TOTAL

(UG/L

AS SB

) 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

ARSENIC

TOTAL

( JG/L

A5 AS

) 1 0 0 1 0 1 0 1 1 0 0 1 1 0 0 0 0 1 1


station 03

2016

15,

Big Four Hollow Creek above Ea

st Fork Big

Four Hollow

Creek near Lake Ho

pe,

Ohio,

water year 1979 Continued

un

to

DATE

OCT I'd,.

.25...

NOV 06.. .

20...

30...

DEC 22...

JAN 04...

17...

FEB01. ..

16.. .

27...

MAM 12...

26...

APR 10. ..

27...

MAY 15...

31 ...

JUN 11 ...

28...

HERYL

LIUM,

TOTAL

-

K6COV-

tRAt

fL(UG/L

L-

AS 8t

) 0 0 0 0 0 0 u u u 0 0 0 0 u 0 0 0 0 0

CA3M1UM

TOTAL

RiCOV-

ERArfLE

( J6/L

AS CD) d 2 0 8 2 4 2 1 6 818 1 2

19 12 5 3 1 0

CHRO-.

M 1 U?

4 «

TOTAL

RECOV

ERABLE

(JG/L

AS CR

) U 1 1 0 1 1 0 5 0 1 0 0 0 5 b 2 6 5 7

COPPER,

TOTAL

REC3V-

ERASLt

(UG/L

AS CU

) ^ * 3 d d d d 1 1 1 a 2 * 0 * 1 1 1 3

IRON,

TOTAL

RELOV-

ERAriLE

(UG/L

AS FE

)

^300

14000

11000

69UO

30UO

3000

3100

dlOU

3400

6100

1500

3400

2700

1900

3000

2?00

4000

d300

3300

IRON,

SUS

PENDED

RtCOV-

FRAB

Lt.

(UG/L

Ab FE

) ..

--

__ -- __ -- _

-- __

600

400

700

800 0

IRON,

DIS

SOLVED

(UG/L

AS FE

) DO

14000

1100

t>000

4000

2600

2900

1500

3100

61UO

1200

3000

2200

1400

2400

2300

3300

IbOO

5300

LEAD,

TOTAL

RtCOV-

ERAdLE

(UG/L

AS P3) 76 45

150 58 17 40 29

20

150

100

180 834

150

140 20 30

3 0

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

6800

7500

6600

3400

2500

1500

1400

96U

1800

3600

BOO

1900

1500

1100

2000

2300

2600

14UO

4200

MANIGA-

MESE,

SUS

PENDED

RECOV.

(UG/L

AS MN

) ^

__ __

__ -

__

_-

100 0

100 0 0

MANGA-

NiSE»

DIS-

SDLVED

(JG/L

A5 MN)

6800

7500

6100

310

2300

1500

1400

960

1700

3200

800

1900

1400

1100

1900

2300

2500

1400

4200

Appendix 4. Water-quality data

, station 03201615, Big Four Hollow Creek above East Fork Big Four Hollow


DATE

OCT 12...

25. ..

NOV 05.

. .

20...

30...

OFC 22...

JAN04. ..

17...

FE6 01 ...

16...

27...

MAR 12...

26...

APR 10...

27...

ÂY 15...

31 ...

JUN 11...

28...

v»E-

<C<J

RY

NlCKhL,

TOTA

L TO

TAL

RECOV-

RECcv-

£RAH

I_-

EWAH

LE(Uo/L

(UG/L

Ab HG)

AS Ml)

<.D

2V

<.D

19

<.D

34

<.D

0

<.D

t\

<.D

18

<.D

19

<.3

7

<.D

16

<.D

15

<.D

15

< . D

19

<.D

ID

<.D

40

< .3

25

<.D

20<.D

15

<.D

22

<.D

27

SELE

NIUM,

TOTAL

(UG/L

Ab SE) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o" 0

SILVER,

TOTAL

KtCOV-

ERAbLE

(UG/L

AS AG) U 0 0 0 U 0 0 0 0 0 0 0 0 0 0 0 0 0 0

ZINC,

sus-

RENDEO

ZINC,

RECOV-

DIS-

ERAtlLE

SOLVED

(UG/L

(UG/L

AS ZN)

AS ZN

) 10 20

2030

20

20 30 40

20

90 0 0

20

40

30

10

0 30

0 30

b 2

3U

20

ZINC,

TOTAL

RECOV

ERABLE

(JG/L

AS ZN

) 40 30 20 30 20 30 40

40

20 90 40 30 20 40

40 30 30 10 50

CAR30N*

ORGANIC

DIS

SOLVED

(MG/L

AS C) 4.6

3.0

1.2

.2.0

1.0

3.7

1.3

2.0

4.0

1.6

4.3

4.5

3.9

1.1

3.7

3.6

2.9

8.9

3.9

CARBON,

ORGANIC

SUS

PENDED

TOTAL

(MG/L

AS C)

.4 .7 .3 .b .2 .4 .3 .2 .2 .2 .2 .0 __ .1 .1 .6 .3 .3

PHENOLS

(UG/L) 1 4 0 2 0 2 4 1 0 0 3 0 2 0 0 0 0 0 0

Appendix 5. Water-quality data, Station 03201630, East Fork Big Four Hollow Creek near Lake Hope, Ohio,

water year 1979

DATE

OCT 13..

.25...

NOV 06...

20...

30...

OEC 08...

en

09...

(Jl

->y

C.C.

...

JAN04...

17...

FEB 01...

16...

25...

27...

MAR 12..

.26...

APR 02...

10...

27...

MAY 15...

31...

JUN 11...

29...

TIME

1445

1000

1200

1030

1330

1600

1000

1000

0930

1400

1500

1000

2030

1000

1300

1030

1300

1500

1000

0900

0900

1030

1200

STREAM-

FLOW,

INSTAN

TANEOUS

(CFS

)

1.4 .12

.10

.25

.51

19 6.2

1.9

1.3

1.7 .25

.25

9.8

1.6 .20

.60

3.0

1.2 .22

.10

.10

.31

.01

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) 220

350

350

230

220 __

165

UO

170

190

210 __

110

190

180

220

225

130

235

190

315

PH

FIELD

(UNI

TS)

6.5

5.3

5.6

6.3

6.0

6.2

6.5

6.7

6.3

6.6

6.2

6.7

6.7

6.2

6.8

7.1

7.2

7.1

6.1

TEMPER

ATURE,

WATER

(DEG

C)

13.0

6.5

12.0

7.5

6.5

2.0 .5

1.5 .5 .0

1.5

5.0

4.0 --

11.0

11.0

16.5

13.0

14.5

16.0

OXYGEN

DEMAND,

CHEM

ICAL

(HIG

HLEVEL)

(MG/

L)

239 9 9 11 43 260 10 9 8 11 8

10 4

24 4

229

HARD

NESS

(MG/

LAS

CAC03) 86

150

140

100 97 . 72 63

78 76 92 47 75 75 71 91 92 91 80 120

HARD

NESS,

NONCAR-

BONATE

(MG/L

CAC03) 59

150

140 77 77 54 47 61 61 74 39 74 57 55 68 71 68 53 110

CALCIUM

DIS

SOLVED

(MG/L

AS CA)

22 33 33 24 24

17 15 18 18 22

11 18 18

17 22 22 22 20 29

MAGNE

SIUM,

DIS

SOLVED

(MG/L

AS MG)

7.6

17 14 10 9.0

7.2

6.3

8.0

7.5

9.0

4.7

7.4

7.4

7.0

8.8

9.0

8.8

7.4

12

SODIUM,

DIS

SOLVED

(MG/L

AS NA)

4.4

5.3

5.4

5.5

5.0 __ __

4.2

3.2

4.0

4.0

4.8

2.5

3.8

4.1 .

4.1

4.6

5.0

4.6

4.1

5.1


ta.

Station 03201630,

East Fork Big

Four Hollow Creek near Lake Hope,

Ohio

,


SODIUM*

SODIUM

POTAS-

AO-

SIUM

SORP-

DIS-

TION

SOLVED

SODIUM

RATIO

(MG/L

DATE

PERCENT

AS NA

)

OCT 13..

.25...

NOV 06...

20...

30..

.DE

C 08..

.09...

22...

JAN04...

17...

FE8 01...

16...

25..

.27

...

MAR 12...

26...

APR 02...

10...

27...

MAY 15...

31...

JUN 11...

29...

107 8

10 10 -- 11 10 10 10 10 -- 10 10 10

-- 11 10 10

10 10 8

.2 .2 .2 .2 .2 __

--.2 .2 .2 .2 .2 __

--.2 .2 .2 __

--.2 .2 .2 .2

6.5

.2 .2

POTAS-

CARBON

SIUM»

BICArt-

ALKA-

DIOXIDE

DIS-

BONATE

CAR-

UNITY

DIS

SOLVED

(MG/L

80NATE

(MG/L

SOLVED

(MG/L

AS

(MG/L

AS

(MG/L

AS K)

HC03)

AS C0

3)

CAC0

3)

AS C02)

2.4

2.6

2.0

2.0

1.9 -- 1.7

1.4

1.3

1.5

1.5

--

1.3

1.5

1.3 -- 1.7

1.9

1.9

1.9

1.7

2.0

33 0 6

30

24

--

-- 2? 20 20 18 22 10 222 20 28 26 28 349

0 0 0 0 0

0 0 0 0 0

--0 0 0

0 0 0 0 0 0

270 5

2b 20 -- -- 18 16 16 15 18 8 2 18 <--

16 23 21 23 2ti 7

17.0

24 24 38

-- --22 10 6.

4

14 8.8

10

.67.

0 207.

1

3.3

2.8

4.3

11

SULFATE

DIS

SOLVED

(MG/

L AS

S0

4)

62 150

140 8b 71

--57 b8 56 64 83

--40

08

61

--

59 75 79 77 54 120

SOLIDS*

CHLO-

RESIDUE

RIDE

» AT 180

DIS-

DEG. C

SOLVED

DIS-

(M

G/L

SOLVED

AS CD

(MG/

L)

2.7

2.8

4.4

5.9

5.2

--3.8

3.0

3.7

4.0

4.2 --

2.6

3.7

3.6 --

3.6

3.6

3.5

3.3

4.3

3.0

130

233

227

158

134 -- -- 111

106

109

118

145 -<-

81 120

123 -- 119

138

164

149

143

216


Station 03

2016

30,

East

Fork Big

Four Hollow Creek near Lake Hope,

Ohio,


DATE

OCT 13...

25...

NOV 06...

20...

30...

DEC 08...

09...

22...

JAN04...

17...

FEB 01...

16...

25...

27...

MAR 12..

.26

...

APR 02...

10...

27...

MAY 15...

31...

JUN 11...

29...

SOLIDS.

DIS

SOLVED

(TONS

PER

AC-FT)

.18

.32

.31

.21

.18 --

.15

.14

.15

.16

.20 _-

.11

.16

.17

--

.16

.19

.22

.20

.19

.29

NITRO

GEN,

N02+N03

TOTAL

(MG/L

AS N) .72

.04

.06

.15

.15

.13

.15

.17

.11

.42 -- .24

.13

.12

-- .07

.04

.63

.12

.11

.08

NITRO-

GEN.AM-

MONIA

*ORGANIC

TOTAL

(MG/L

AS N) .45

.22

1.5 .07

.05

.00

.02

.07

.49

.22

_-

.11

.07

.16

--

.13

.14

.27

.00

.06

.03

NITRO

GEN*

TOTAL

(MG/L

AS N) 1.2 .26

1.6 .22

.20 -

.13

.17

.24

.60

.64

--

.35

.20

.28

_-

.20

.18

.90

.12

.17

.11

NITRO

GEN*

TOTAL

(MG/L

AS N03)

5.2

1.2

6.9 .97

.89

--

.58

.75

1.1

2.7

2.8 --

1.6 .89

1.2 .89

.80

4.0 .53

.7b

.49

PHOS

PHORUS.

TOTAL

(MG/L

AS P)

.020

.050

.050

.000

.000 .-

.000

.000

.000

.000

.000 --

.000

.000

.010 --

.000

.000

.020

.010

.020

.010

PHOS

PHORUS.

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P04) .. -- -- _- _- ..

--

--

.00

.Ob

.03

.06

.03

PHOS

PHORUS.

TOTAL

(MG/L

AS P04) -- .. -

-- -- --

--

.00

.06

.03

.06

.03

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS A

L> 100

330

970

3bO

290

-

190

dSQ

150

270 0-- 10

260

320 --

22U

230

J30

J70

180

2300

ANTI

MONY,

TOTAL

(UG/L

AS Srf) 3 1 0 0 0

0 0 0 0 0

-- 0 0 0

0 0 0 0 0 0

AKSENIC

TOTAL

(UG/L

AS AS

) 0 0 0 0 0

-

1 0 1 1 0

-- 0 1 1

0 0 0 0 0 1

Appendix 5. Water-quality data. Station 03201630, East Pork Big Four Hollow Creek near Lake Hope, Ohio,


DATE

OCT 13..

.25...

NOV 06...

20...

30...

DEC 08...

09...

22...

JAN 04...

17...

FEB 01...

16...

25...

27...

MAR 12...

26...

APR 02...

10...

27...

MAY 15..

.31...

JUN 11..

.29...

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS 8E) 0 0 0 0 0

0 0 0 0 0 0 0 0

0 0 0 0 0 0

CADMIUM

TOTAL

RECOV

ERABLE

(UG/

LAS

CD) 3 1 0 2 3

« 14 3 1

10 3 7 1 0

1

20

1 9 5 0

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR

) 0 0 4 1 1

-- 1 1 5 0 0

1 0 0

6 5 4 4 8 7

COPPER*

TOTAL

RECOV

ERABLE

(UG/

LAS CU

) 4 7 3 2 1

-- 3 1 1 1 0

to 2 2

1 3 3 0 1 5

IRON*

TOTAL

RECOV

ERABLE

(UG/

LAS FE

)

1300

7500

6300

1100

770 --

510

800

180

560

670

330

670

770

550

400

850

1200

410

5700

IRON

*SUS

PENDED

RECOV

ERABLE

(UG/

LAS FE

) 320

650

840

380

5100

IRON

*DIS

SOLVED

(UG/L

AS FE

)

300

1600

1400

390

180 --

260

170

ItiO

140

220 70

190

190

50 80

200

360 30

630

LEAD*

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 30 25 21 16 10 --

140 26 15

17023 63

6 3

9

180 23 36 Id 2

MANGA

NESE*

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

130

900

650

160

110

70 80 70 100

90 --

110

130

90 -- 70 100

190

180

60550

MANGA

NESE*

SUS

PENDED

RECOV.

(UG/L

AS MN) -- __ 0 10 10 0 0

MANGA

NESE*

DIS

SOLVED

(UG/L

AS MN)

120

810

600

140

110

-- 70 bO 70 100

80 70 UO 90 -- 70 100

180

170

60550

Appendix 5. Water-quality data, Station 03201630, East Fork Big Four Hollow Creek near Lake Hope, Ohio,

water year 197-9 Continued

DATE

OCT 13...

25...

NOV 06...

20...

30...

DEC 06...

09...

22...

JAN 04...

17...

FEB 01...

16...

25...

27...

MAR 12...

26...

APR 02...

10...

27...

MAY 15...

31...

JUN 11...

29...

MERCURY

NICKEL,

TOTAL

TOTAL

RECOV-

RECOV

ERABLE

ERARLE

(UG/L

(UG/L

AS HG)

AS NI

)

<.5

21<.5

41

<.5

48

<.b

21<.5

13

~ --

--

<.5

18

<.5

15<.b

5

<.5

9<.5

15--

--

<.b

7

<.5

17<.5

11

--

<.5

23

<.5

21

<.5

27

<.5

16

<.5

17<.5

28

SELE

NIUM,

TOTAL

(UG/L

AS SE) 0 0 0 0 0

--

--0 0 0 0 0 0 0 0

0 0 0 0 0 0

SILVER,

TOTAL

RECOV

ERABLE

(UG/L

AS AG) 0 0 0 0 0

-- 0 0 0 0 0

.. 0 0 0

--0 0 0 0 0 0

ZINC,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN) -- --~ --

-- --

-- 30

0 0

20 10

ZINC,

DIS

SOLVED

(UG/L

AS ZN) 10 50 40 10 10 .

_-

20 20 20 10 10 --0

20 10 20 10 50 90

030

ZINC,

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 10 60 90 20 20 -- -- 50 20 20

20 30 JO 20 10 -- 40

40 50 90 20 40

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C) 4.8

3.2

2.9

4.2

1.2

-- __

3.8

d.7

5.9

1.3

2.9--

4.6

4.1

1.9

..4.8

3.1

14 6.8

2.6

5.7

CARBON,

ORGANIC

SUS

PENDED

(MG/L

AS C)

.7 .5 .5 .5 .5 -- -- .4

.1 .1 .1 .1 --

.1 .0 .1 .2 .4 .2 .5

PHENOLS

(UG/

L)

1 3 0 1 0

-- ._ 1 0 3 0 0

1 0 1-- 0 0 0 0 0 2


Station 03201660,

Big Four Hollow Creek below East Fork Big

Four Hollow

Creek

ne«r Lake tiope, on

ic*

water y

ears

1979 an

d 19

80

ea

STREAM-

FLOWt

INSTAN-

TIME

TANEOUS

DATE

WATER

NOV 06...

20...

30...

DEC 08...

08...

09...

18...

22...

FEB 25...

MAR 12...

APR 02...

MAY 31...

JUN 08...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17..

.

YEAR 1979

1230

1230

1500

1315

1316

1030

1615

1100

2100

1530

1400

1130

1200

0900

1515

1200

1400

1500

1300

<CFS) .96

1.6

2.0

21 21 11 262.7

16

.42

6.2 .19

4.5 .37

.29

.25

.62

.17

.81

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) -- -- ~ --

265

300

300

245

258

280

PHFIELD

(UNITS)

6.9

6.5

6.5

6.8

6.6

6.5

TEMPER

ATURE.

WATER

(DEG C) -- --

19.0

^1.0

22.5

19.0

20.5

15.5

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LFVE

L)(M

G/L)

-- -_ -- --

3 2

41 37

2 6

HARD

NESS

(MG/L

ASCAC03) -- -- -- -- -- -- 110

110

no 91 100 99

HARD

NESS

* CALCIUM

NONCAR-

DIS-

BONATE

SOLVED

(MG/L

(MG/L

CAC0

3)

AS CA)

-_ --

--

--

-- --

98

2690

26

100

2665

22

83

24

tJi

24

MAGNE-

SIUM

t SODIUM,

DIS-

UIS-

SOLVEO

SOLVED

(MG/

L (MG/L

AS MG)

AS NA)

-_ --

-- ---- --

--

--

-_

--

--

--

--

11

6.0

10

5.4

11

6.0

a. 7

5.6

9.7

b.6

9.6

S.I


Station 03201660,

Big Four Hollow Creek below East Fork Big Four Hollow

Creek near Lake Ho

pe,

Ohio,

water years 19

79 and

1980-Continued

o\

SODIUM*

SODIUM

POTAS-

AD-

SIUM

SORP-

DIS-

TION

SOLVED

SODIUM

RATIO

(MG/

L DATE

PERCENT

AS NA)

WATER YEAR 19

79

NOV 06.,.

20..

. 30

...

DEC 08...

08..

. 09...

18...

22..

. FEB

25...

MAR

12...

APR 02...

MAY 31..

. JUN

08...

JUL 10...

26..

.AU

G 08...

23..

.SEP 05...

17...

10 10 10 12 11 10

.2 .2 .2 .3 .2 .2

--7.

5

8.1

7.6

7.5

7.0

POTAS-

CARBON

SIUM

» BICAK-

ALKA-

DIOXIDE

DIb-

BONATE

CAW-

LINITY

DIS

SOLVED

(MG/

L BONATE

(MG/

L SOLVED

(MG/L

AS

(MG/L

AS

(MG/

L AS K)

HC

03)

AS C0

3)

CAC0

3)

AS C0

2)

2.1

2.1

2.1

2.0

1.9

i.y

15 20 12 32 20 22

0 0 0 0 0 0

12 16 10 26 16 18

3.0

10 6.1

tt.l

8.0

11

SULFATE

DIS

SOLVED

(MG/L

AS 50

4)

110

110

110 75 97 96

SOLIDS*

CHLO-

RESIDUE

RIDE*

AT 180

DIS-

UEG. C

SOLVED

DIS-

(MG/L

SOLVED

AS CD

(MG/

L)

4.3

3.9

4.0

4.7

3.5

4.2

213

205

233

148

203

183


Station 03

2016

60,


Cree

k near Lake Hope,

Ohio,

water

year

s 19

79 an

d 1980 Continued

to

DATE

NJj

JATER

06..

.20

...

30...

DEC 08...

08..

.09

...*

18...

22..

.FEB 25..

.MAR 12...

APR 02..

.MA

Y 31..

.JUN 08...

JUL 10...

26..

.AU

G 08..

.23

...

SEP 05...

17..

.

SOLIDS*

DIS

SOLVED

(TON

SPER

AC-FT)

YEAR 1979

-- -- --

--

--

--

--

.29

.28

.32

.20

.28

.25

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N)

--

--

~ -- --

--

.09

.12

.08

.09

.06

.08

NITRO-

GEN*AM-

MONIA '*

ORGANIC

TOTAL

(MG/L -

AS N)

-- --

--

--

.13

.18

.11

.14

.00

.57

NITRO

GEN*

TOTAL

(MG/L

AS N)

-- -- -- -- -- -- -- -- -- .22

.30

.19

.23

.06

.65

NITRO

GEN*

TOTAL

(MG/L

AS N03) -- -- -- .97

1.3 .84

1.0 .27

2.9

PHOS

PHORUS*

TOTAL

(MG/L

AS P)

~ -- -- --

.000

.030

.000

.010

.000

.010

PHOS

PHORUS*

TOTA

L(MG/U

AS P04) -- -»

-

-- -- -- .00

.09

.00

.03

.00

OJ

ALUM

INUM*

TOTAL

RECOV

ERABLE

(UG/L

AS AL) -- --

300

700

220

260

310

800

ANTI

MONY

* ARSENIC

TOTA

L TOTAL

(UG/L

(UG/

LAS

SB)

AS AS)

.. .. -- -- -

----

-- -«.

..

..

..

.- -- -- --

--

0 1

u 1

0 2

0 2

0 0

0 1

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS BE) -- -- -- ~ ~

'

.. -- ..

0 0 0 0 0 0


Station 03201660,


Cree

k ne

ar Lake Hope,

Ohio,

wate

r ye

ars

1979 and

1980 Continued

o\

u>

DATE

WATER

NOV 06...

20...

30...

DEC 08...

08...

09...

FEB 25...

MAR 12..

.APR 02...

MAY 31...

JUN 08...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17..

.

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD)

YEAR 1979

--

_- 0 0 1 1 0 u

CHRO

MIUM,

TOTAL

RECOV

ERABLE

(UG/

LAS

CR) -. -- :; 16 14 16 19 2 3

COPPER,

TOTAL

RECOV

ERABLE

(UG/L

AS CU) ^^

2 0 4 3 2 3

IRON,

TOTAL

RECOV

ERABLE

(UG/L

AS FE) :: -- ..

1600

1300

1500

1200

2200

3000

IRON,

SUS

PENDED

RECOV

ERABLE

(UG/

LAS

FE) _- _- « «

400

350

400

720 --

IRON

,DIS

SOLVED

(UG/L

AS FE) :: - ..

1200

950

1100

480

950

1300

LEAD,

TOTAL

RECOV

ERABLE

(UG/

LAS

PB) -- wii-

-. --

3 3 5 s 5 2

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN

) .. -.

-- :; -. -- .

1600

1600

2000 850

1800

1800

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/

LAS MN) .- :: .. -- .. 0

100

200 50 100

100

MANGA

NESE

*DIS

SOLVED

(UG/L

AS MN) -- ^^^

-- --

1600

1500

1800

800

1700

1700


ta,

Station 03

2016

60,

Big

Four Hollow Creek below East Fork Big Four Hollow

Creek ne

ar Lake Ho

pe,

Ohio

, water years 1^

79 an

d 1980 Continued

DATE

N$$TER

06...

20...

30...

DEC 08...

08...

09...

18...

22...

FEB 25...

MAR 12...

APR 02...

MAY 31...

JUN 08...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17...

MERCURY

TOTAL

RECOV

ERABLE

(UG/L

AS HG

)

YEAR 1979

--

« --

< &

<.5

<.b

<.5

<.5

<.b

NICKEL.

TOTAL

RECOV

ERABLE

(UG/L

AS NI) --

--

--

--

--

372 107

10 10

SILVER.

SELE-

TOTAL

NIUM.

RECOV-

TOTAL

ERA8LE

(UG/L

(UG/L

AS SE

) AS AG

) --.,

.. --

-- ,

..-_

.. .

--

..

.. ..

0 0

0 0

0 0

0 1

0 0

0 0

ZINC.

SUS

PENDED

RECOV

ERABLE

(UG/

LAS

ZN) -- -- --

t -- -- 10 30 10 0 0

30

ZINC.

DIS

SOLVED

(UG/L

AS ZN

) -- -- --

--

--

--

20 30 30 20 300

ZINC.

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) -- -- -- 30 60 40 20 30 30

CARBON.

ORGANIC

DIS

SOLVED

(MG/L

AS C)

-_--..

-- --

--

--

3.9

2.6

3.1

6.4

2.9

7.0

CARBON.

ORGANIC

SUS

PENDED

(MG/L

AS C)

-- -- -

-- .1 .0 .3 .4 .2 .6

PHENOLS

(UG/

L) .. -- -- -- --

--

--

0 0 0 0 1 0

Appendix 6. Water-quality data. Station 03201660, Big Four Hollow Creek below East Fork Big Four Hollow

Cree

k near LaKe hope,

Ohio,

water

year

s 19

79 and

1980 Continued

TIME

DATE

WATER YEAR 1980

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

28...

MAR 12...

25...

APR 03...

25...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 03...

22...

1130

1400

1200

1200

1300

1200

1000

1200

1430

1130

1000

1500

1300

1000

1300

1430

1530

1430

1230

1130

1450

1400

1430

1300

SPE-

OXYGEN

CIFIC

DEMAND*

STREAM-

CON-

CHEM-

FLOW»

DUCT-

TEMPER-

ICAL

INSTAN-

ANCE

PH

ATU«E»

(HIGH

TANEOUS

(MICRO-

WATER

LEVEL)

(CFS)

MHOS)

(UNITS)

(OEo

C)

(MG/

L)

1.1

1.1

3.0 .50

.50

.50

.40

.40

.40

.80

1.5

1.3

1.3 . t»0

.30

.70

.30

.10

.80

.70

.60

.70

.50

.50

220

260

260

250

250

200

240

240

270

230

190

220

220

215

275

275

280

315

225

310

290

290

280

310

7.1

6.2

6.2

6.7

b.f

6.9

7.6

7.0

7.1

7.0

6.6

7.5

7.4

6.8

6.4

6.2

7.4

5.9

7.0

7.2

6.7

6.7

6.4

7.4

15.0

11.5

8.0

8.0

6.0

1.5 .5 .5 .5 .5 .5

6.3

11.0

9.0

13.5

16.0

18.5

21.0

18. b

25.0

24.0

21.5

21.0

18.0

320 33 8 15 7 6

63 15 8

87 2 12 8

15 40 3 19 20

HARD-

HARD-

NESS*

ACIDITY

CALCIUM

NESS

NONCAR-

TOTAL

ACIDITY

DIS-

(MG/

L BONATE

HEATED

(MG/L

SOLVED

AS

(MG/L

(MG/L

AS

(MG/L

CAC03)

CAC03)

AS H)

LAC03)

AS CA)

82

100

110 99 98

96 110

100

12099

110 85 84

94 110

110

110

120

92 120 --

120

120

120

55

84 95 79 74 74 90 11

98 69

8962

64 73 96 78 83

100

58

100 80 110

100

20 25

2924 23 23 2725

27 24 21 2U 20 23 26

.2

10

25

25

30

2328

.2

10.3

15

29

.2

10

30 28


ta,

Station 03201660,

Creek near Lake Hope, Ohio,

bODIUM*


water years 19

79 and 1980 Continued

DATE

MAbiMt-

SODIUM

POlAb-

KUIJ»:J-

SIUM,

SODIUM,

AD-

SIUM

SIUM,

tilCAk-

ALKA-

D ji

s.

DIS.

SO^-

DIS-

DIS-

dONATt

CA9-

LINITY

SOLVED

SOLVED

TIOI

M SOLVED

SOLV

ED

(MG/L

BONA

TE

(MG/L

(MG/L

(MG/L

SODIUM

RATIO

(MG/L

(MG/L

AS

<M^

L ** >

. AS MG)

AS NA)

PERCENT

AS NA)

AS K)

HC03)

AS C03)

CAC03)

A

IOAIDE

SULFATE

DIS-

DIS-

bOLVtD

SOLVED

(MG/L

(MG/L

,b 00

2)

AS SO<O

WATER YEAR 1980

OCT

02...

23...

NOV

09...

20...

DEC

06.. .

20...

JAN

10..

.24

. . .

FE8

12...

23...

MAP

12..

. 25...

APR

03...

25...

MAY

09...

23...

JUN

12...

24...

JUL

10...

21...

AUG 06.

. .

19..

.SEP

08.

. .

22...

7.9

9.9

9.b

9.6

9.9

9.3

11 10 129.6

138.4

8.3

8.9

11

11 11

12

b.4

12 11 12

12

4.9

5.2

4.3

4.b

b.7

4.7

4.9

b.O

b.7

5.0

4.1

3.7

4.3

4.3

5.7

5.5

b.7

5.5

4.0

5.7

6.4

b.4

5.7

11

15 11

14 17 10 139 9 10

6 9 10 9

10 10 109

109 10

8 9

.2

.2 .2 .2 .3

.2 .2

.2 .d

.2 .2

.2 .2

.2 .2 .2 .2

.£ .2

.2 .3 d

.2

7.2

8.1

8.*

O.<*

7.3

0.1

o.b

0.0

7.1

0.3

b.2

5.3 _.

2.3

2.9

4.1

1.6

1.0

1.4

1.6

1.6

1.4

1.3

1.1

1.6

1.6

1.9

1.8

2.2

2.2

2.3

2.0

2.b

_

2.6

2.3

2.7

33

23

22

db 30

27 do

33

23

37

2b

26 2b

2o 17

30 30

2«+

42

16 18

46

22

18

0 0 0 0 0 0 0 0 0 0 u 0 0 0 0 0 0 0 0 0 0 0 0 0

27 19 18

21 db dd 2J

27 19 30 21

23 21

21 14

3u 25

20 34

13 13 36 18

13

4.2

23 22 b.O

v.o

5.4

1.1

5.3

2.9

5.9

101.4

1.6 .3

11

30

1.9 .b

6.7

1.8

5.7

lb 14 1.1

65 93 97

96 69

83 110 9b 110 8b J* 6<*

76 84 110 92

100

130 t>0

120

69

130

140


Station 03201660,

Creek near ii

aKe

Hope

, un

io,

water

Big

Four Hollow Creek below East Fork Big Four Hollow

years 19

7y and

1980 Continued

SOLIDSf

CHLO-

REblDUE

RIDE,

AT 18

d

DATE

WATER

OCT U2...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

26...

MAR 12...

25...

APR 08...

2b...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG Ob...

19...

SEP 08...

22...

DIS

SOLVED

(MG/L

AS CD

YEAR 1980

3.2

3.0

3.6

3.0

3.3

3.0

3.t

3.0

3.3

3.5

3.0

2.5

2.6

2.4

2.7

4.2

4.0

3.d

3.2

3.4 --

4.7

3.5

3.4

DtG. C

DIS

SOLVED

(MG/L)

139

168

177

166

163

110

Ifa2

177

2UO

163

146

Ib2

131

170

196

167

192

230

15b

235 --

197

214

2bl

50LIDS,

DIS

SOLVED

(TONS

PER

AC-FT)

.19

.23

.24

.23

.22

.15

.25

.24

.27

.22

.20

.21

.18

.23

.27

.23

.26

.31

.21

.32

--

.27

.29

.34

NITRO

GEN,

N02+NOJ

TOTAL

(MG/L

AS N) .10

.02

.15 .u .11

.13

.10

.08

.22

.16

.20

.13

.08

--

.13

~.IV

.20 .02

.19

NlTRO-

GEHt AM

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) .Ob

.11

1.0 --

.17

.13

.50

.25

.07

.23

.09

.09

.49

.31

--

.35

--

.16

.07 --

.12

--

.31

NITRO

GEN,

TOTAL

(MG/L

AS N) .lb

.13

1.2 --

.29

.24

.63

.35

.15

.45

.25

.29

.62

.39

.48

--

.35

.27 ~ --

.14

.50

NITRO

GEN*

TOTAL

(MG/L

AS NO

-i)

.71

.38

5.1 --

1.3

1.1

2.6

1.6 .66

2.0

1.1

1.3

2.7

1.7

2.1

1.6

1.2 .62

2.2

PHOS

-PHORUS»

TOTAL

(MG/L

AS P)

.010

.010

.130

.000

.000

.000

.000

.000

.010

.010

.000

.040

.000

.010 -

.010

.000 --

.010

.010

PHOS

PHORUS*

TOTAL

(MG/L

AS P04)

.03

.03

.40 OJ

.00

.00

.00

.00

.03

.03

.00

.12

.00

--

.03

--

.03

.00 --

.03

.03

ALUM

INUM t

TOTAL

RECOV

ERABLE

(U6/L

AS AD

300

300

3200

220

200

250

500

800

4000

500

150

240

1100

6JO

40

--

150 <i\)

-- --400

--

ANTI

MONY*

TOTAL

(UG/L

AS SB) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

'

--

--

Appendix 6. Water-quality data

. Station 03201660, Big Four Hollow Creek below East Fork Big Four Hollow

Creek near La

ke Ho

pe,

Ohio

, water years 1979 and

1980 Continued

DATE

WATER

OCT 02...

23...

NOV 09...

20...

oec 06...

20...

JAN 10...

24...

FEB 12...

28...

MAR 12...

25...

APR 08...

25...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

ARStNlC

TOTAL

(UG/

LAS AS

)

YEAR 1980

2 i 1 0 0 0 1 2 1 1 1 0 2 0

BERYL

LIUM,

TOTAL

RECOV-

EKABLE

(UG/L

Ab BE) 10 0 0 0

20 10 20 10 0 0 0 0 010 --

CADMIUM

TOTAL

HECOV-

ERAriL

E(U

G/L

AS CD) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

_- -- .

--

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR) *11 1U 20

b 3 b 7

2b 23 b b 4 b

-- --

COPPtR*

TOTAL

RECO

VERABLE

(UG/

LAS CU

) 0 2 8 1 1 2 1 1 1 1 1 1 4 2

IRON*

TOTAL

RECOV

ERABLE

(UG/

LAb

FE

)

2000

1500

12000

2000

2000

1900

3600

4500

3900

1900

1800

1300

5100

2500

IbOO

1400

1100

2100

1000

IbOO

1200

1700

1400

IRON*

SUS

PENDED

RECO

VER

ABLE

(UG/L

AS Ft)

200

bOO

l<fO

O

700

600

600

4bO

4400

1400

400

1000

640

1200

b70

500

1400

200

IRON*

DIS

SOLVED

(UG/L

AS FE)

400

750

2000

1500

ItoO

j1700

3000

3100

3^00

1100

1200

850

630

1100

1100

370

460

fa9o

430

1000 -_

330

1200

1200

LEAD*

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 1 0 3 0 0 0 1 0 0 7 0 0 3 0 0 0 2 2 3 0 012 0

MANGA

NESE*

IOTAL

RECOV

ERABLE

(UG/L

AS Mb)

750

1600

1600

1200

1100

940

1600

1400

1700

640

630

570

900

1100

1400

850

1200

1900

650

17JO

1600

1000

1600

MANGA

NESE,

SUS

PENDED

KECOV.

(UG/L

AS MN) 400 0 0 0 0 0 0 0 0

10 0 0 0 040

0 0 0100 to 100

Appendix 6. Water-quality data, Station 03201660, Big Four Hollow Creek below East Fork Big Four Hollow

Creek near Lake Ho

pe,

Ohio

, water years 19

79 an

d 1980 Continued

-» T

l. If* -

DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10..

.24...

FEfl 12..

.28...

MAR 12...

25...

APR 08. ..

25...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19..

.SEP 08...

22...

MANGA-

MERCURY

NESE,

TOTAL

DIS-

RECOV-

SOLVED

ERA8LE

(UG/L

(UG/

LAS MN)

AS HG)

YEAR 1980

710

<.b

looo

<.i

1600

<.l

1200

.1

1100

.4940

.1

1600

<.l

1400

<.l

1700

.1040

.2

620

<.l

570

.1

900

.111

00

<.l

1400

810

1200

1900

obO

<.l

IbOO

9bO

iDOO

2000

NICKEL,

TOTAL

RECOV

ERABLE

(UG/

LAS NI

) 4 8

348 7 6 7 7

12 2 5 2 113

-- -- --

3--

-- --

SELE

NIUM,

TOTAL

(UG/

LAS SE) 0 0 0 0 0 0 0 0 0 U 0 u 0 0

-- -- -- -- -- --

SILVER,

TOlAL

RECOV

ERABLE

(Ub/

LAS

AG

) 0 1 0 0 0 0 0 0 0 0 c 0 0 0 ._ -- --

ZINC,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN

) 0 10 20 10

0 0 0 0 0 0

200 0

20 d

10 0 10

ZINC,

DIS

SOLVED

(UG/

LAS ZN) 20 20 700

20 d\)

20 20 dO 30 30 20 30b

202

do 20 30 30 -- 10 30 50

ZINC,

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 20 30 90 10 20 20 20 20 20 30 50 20 30 20 10 -- 30 30 -- -- 20 --

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C) 2.J

6.9

b.9

2.8

2.3

1.9

1.3

3.7

3.9

1.0

1.3

4.0

3.4

9.0 --

4.b -- f.l

l.ti -- --

2.2 1.9

CARBON,

ORGANIC

SUS

PENDED

(MG/L

AS C)

.b .2

1.7 .1 .b .2 .1 .3 .3 -- .2 .4 .b .4 -- .3 --.4

.4 -- .3 -- --

PHENOLS

(UG/

L)

0 0 0 1 0 0 0 0 0 0 4 2 1 0

-- -- -- -- -- --

Appendix

7. Water-quality data, Station 03201700, Big four Hollow Creek near Lake Hope, Ohio,


GJ

DATE

WATER

OCT 13...

24...

NOV 06...

22...

30...

DEC 21...

JAN 04...

16...

FEB 01...

14...

26...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17...

TIME

YEAR 1979

1000

1400

1600

0900

1530

1030

IbOO

1130

1430

1030

1130

1230

1530

1200

1000

1400

1330

1530

1000

1030

1400

1300

1300

1600

1400

STRE

AM-

FLOW

,INSTAN

TANEOUS

(CFS)

4.3 .11

.08

.2b

,6b

3.2

1.6

1.7 .66

.33

11

.66

1.2

1.4 .52

.39

.64

1.2 .11

.20

.43

.lb

.88

.18

.30

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) 280

850

830

490

390

270

330

285

395

520

160

390

345

100

400

425

520

420

565

500

1200

1050 370

535

755

PH

FIELD

(UNITS)

4.8

3.3

3.2

3.5

3.9

4.0

3.9

4.0

3.6

3.5

4.1

3.7

3.9

4.5

3.6

3.8

3.7

3.9

3.9

3.8

3.5

3.0

4.5

3.6

3.7

TEMPER

ATURE,

WATER

(DEG

C)

12.5

13.0

13.0

7.0

6.5

4.0 .5

1.0 .5 .5

2.0

7.0

5.0

7.5

7.5

20.5

18.0

19.5

15.5

17.0

19.0

21.5

19.0

21.0

17.0

OXYGEN

DEMAND,

CHEM

ICAL

(HIGH

LEVEL)

(MG/

L)

41 10 15 fa 13 42 171

10 8 12 9 10 13 7

254 b 9 10 16 32 35

2 12

HARD

NESS

(MG/

LAS

CAC03) 97

310

280

180

140 99 110

130

130

160 60 130

110

110

130

140

150

130

190

180

380

310

130

180

230

HARU-

NtSS,

NOfMCAR-

bONATE

(MG/L

CAC03) 97

310

280

180

140 99

110*

130

130

160 60 130

110

110

130

140

150

130

190

180

380

310

130

180

230

ACIDITY

TOTAL

HEATED

(MG/

LAS H)

.02.6

2.3

1.0 .6 .5 .8 .6 .8

1.3.4 .8 .5 .3 .5 .6

1.1 .8

1.0 .8

4.6

3.2 .6

1.4

2.5

ACIDITY

(MG/L

ASCAC03) .0

129

114

50 30 25 40 30 40 b5 20 40 25 15 2b 30 55 40 50 40

228

159

30 70124

CALCIUM

DIS

SOLVED

(MG/L

AS CA)

23

68

63

43 31 2J 25

29 30 38 14 31 26

2532

32 3b 30 43

43 86

73 32

44 54

MAGNE

SIUM,

DIS

SOLVED

(MG/

LAS r*G)

9.5

33 29 18 14 10 12 13 14 17 6.1

13 12 11 13 14 16 13 19 18 39 30 13 18 23

Appendix

7. Water-quality da

ta.

Station 03201700, Big four Hollow Creek near Lake Hope, Ohio,


SODIUM*

SOUIUM

POTAS-

SOOIUM»

AD-

SIUM

DIS-

SORP-

DIS

SOLVED

TION

SOLVED

(MG/L

SODIUM

PATIO

(MG/L

DATE

AS NA

) PERCENT

AS NA

)

WATER YEAR

1979

OCT 1 3 ..

.24...

NOV 06...

22...

30...

DEC 21...

JAN 04...

16...

FE8 01...

14...

26...

MAR 13...

26...

APR 11...

30.

. .

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17...

b.4

6.8

7.0

6.2

5.5

4.2

3.8

4.5

b.O

5.8

2.3

4.8

4.9

4.9

5.5

5.8

5.4

4.6

6.5

to. 2

9.7

7.8

5.8

6.2

6.7

11 5 <3 7 8 8 7 7 7 7 7 7 8 9 8 8 7 7 7 7 5 5 8 7 6

.2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .1 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2 .2

-- -- .

7.2

--

8.5

13 11 7.9

b.6

9.3

POTAS-

CASdON

SIUM»

rtlCAP-

ALKA-

DIOXIDE

OIS-

60NATE

CAR-

LINITY

DIS

SOLVED

(MG/

L 80NATE

(MG/L

SOLVED

(Mb/L

AS

(MG/

L AS

(MG/L

AS K)

HC03)

AS CO

J)

CAC03)

AS C02)

2.7

2.7

2.4

2.3

2.0

1.7

1.5

1.4

1.6

1.7

1.4

1.6

1.7

1.7

1.9

1.9

1.8

1.8

2.0

2.2

3.6

2.9

2.1

2.4

2.6

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 u 0 0 0 0 0 0 0 0 0 0

.0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0

SULFATE

DIS

SOLVED

(MG/L

AS S0

4)

100

410

380

220

150

110

140

130

170

220 71 160

130

120

170

180

200

150

220

220

550

430

150

210

330

CHLO

RIDE*

DIS

SOLVED

(MG/L

AS CD

4.6

2.5

3.1

4.5

4.4

3.1

2.6

3.3

4.3

3.5

2.9

3.2

3.6

2.7

2.9

2.4

2.4

3.1

2.4

3.1

2.0

2.9

3.8

2.6

3.0

Appendix



DATE

WATER

OCT 13..

.24...

NOV 06...

22...

30...

DEC 21...

JAN 04...

16..

.FEB 01...

14...

26...

MAR 13..

.26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17...

SOLIDS.

RESIDUE

AT

ItfO

DEG. C

DIS

SOLVED

(MG/

L)YEAR 1979

172

585

521

340

252

175

216

198

246

330

117

231

211

188

252

289

321

271

402

361

1000

835

2b3

385

544

SOLIDS*

DIS

SOLVED

(TONS

PER

AC-FT)

.23

.80

.71

.46

.34

.24

.29

.27

.33

.45

.16

.31

.29

.26

.34

.39

.44

.37

.55

.49

1.36

1.14

.34

.52

.74

NITRO

GEN.

N02+N03

TOTAL

(MG/

LAS N) .5

5.1

2

.13

.16

.15

.13

.12

.13

.11

.13

.13

.13

.11

.07

.06

.07

.10

.07

.07

.07

.05

.04

.10

.06

.U9

NITRO-

GEN«AM-

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) .7

8.1

3

.03

.00

.00

.08

.00

.22

.16

.25

.18

.07

.17

.14

.17

.11

.04

.10

.10

.01

.27

.3b

.34

.06

.17

NITRO-

GtN*

TOTAL

(MG/

LAS

N) 1.3 .25

.16

.16

.lb

.21

.12

.35

.27

.38

.31

.20

.28

.21

.23

.18

.14

.17

.17

.03

.32

.40

.44

.12

.26

NITRO

GEN*

TOTAL

(MG/L

AS NO 3)

5.9

1.1 .71

.71

.66

.93

.53

1.6

1.2

1.7

1.4 .89

I.?. .93

1.0 .30

.62

.75

.75

.36

1.4

1.3

1.9 .53

1.2

PHOS

PHORUS*

TOTAL

(MG/

LAS

P) .070

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.000

.010

.010

.000

.000

.0^0

.000

.030

.010

.000

PHOS

PHORUS*

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P0

4) --

--

--

-- --

.00

.00

.03

.03

.00 -- --

-- --

PHOS

PHORUS*

TOTAL

(MG/L

AS P0

4) -- -- -- -- -- -- -- -- .00

.00

.03

.03

.00

.00

.06

.00

.09

.03

.00

ALUM

INUM

*TOTAL

RECOV

ERABLE

(UG/L

AS AL>

540

10000 --

4400

3000

1400

880

860

3100

3900

1400

3100

1900

1900

2000

24UO

3600

2800

4100

3200

13000

11000

2400

4000

5900

ANTI

MONY*

TOTAL

(UG/L

AS SB) 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

Appendix



DATE

WATER

OCT 13...

24...

MOV 06. .

.22...

30.. .

OEC 21 ...

JAN 04...

16...

FEB 01...

14...

26...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG oa...

23...

SEP 05...

17...

ARSENIC

TOTAL

(UG/L

AS AS)

YEAR 1979 1 0 0 0 u 1 0 1 1 0 0 1 0 0 0 0 0 0 1 1 2 2 2 0 1

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS BE) 010 0 0 0 0 0

10 100 0 0 0 0

10 10

010

010 100 0

10

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD) 311 3 4 6 2 7

101 8 3 0 2 15 4 4 10 0 0 0 1 1 1 0

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR) 3 1

2 1 4 2 b

30 2 0 0 0 7 b 3 8 910 15 9 19

1 d 4

COPPER*

TOTAL

RECOV

ERABLE

(UG/L

AS CU

) 318 -- 6 4 5 5 3 5 5 4 b 4 3 6 b 6 5 8 8 0

19 11 6 9

IRON*

TOTAL

RECOV

ERABLE

(Ub/L

AS FE

)

dlOO

2700

1800

1300

2000

4300

7000

b600

7200

7800

4400

6400

5000

2700

2500

2300

9100

10000

2000

570

66000

29000

5400

6800

28000

IRON*

SUS

PENDED

RECOV-

ERAHLE

(UG/L

AS FE

) 500

200

800

3700

1100 0 0

10000 0

IRON*

DIS

SOLVED

(UG/L

AS FE

)

730

2700

1800

1300

1500

2300

6000

4000

6600

7000

3000

4600

3600

1300

200U

2100

8300

6300

9^0

570

66000

19000

5400

5900

23000

LEAD.

TOTAL

RECOV

ERABLE

(UG/L

AS P3

) 26

100

270 16 35

87

3095

200 d68

43 7

1715

0

54 60 42 1 5 0 8 8 8 4

MANGA

NESE*

TOTAL

RECOV

ERABLE

(UG/L

AS MN

)

1300

6400

5bOO

3300

2400

860

1200

1000

1500

2200

460

1500

1000

840

13UO

1400

1600

11 00

2000

2100

5700

6400

2000

3600

4700

MANGA

NESE

,SUS

PENDED

RECOV.

(UG/L

AS MN

) --

..

--

0

100 0 0 0 0 0

100

200

300

400

Appendix

7. Water-quality data. Station 03201700, Big four Hollow Creek near Lake Hope, Ohio,


DATE

WATER YEAR

OCT 13...

24...

NOV 06.. .

22...

30...

DEC 21...

JAN 04...

16...

FEQ01...

14.

26...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 10...

26...

AUG 08...

23...

SEP 05...

17...

MANGA-

MERCURY

NESE*

TOTAL

DIS-

RtCOV-

SOLVED

ERABLE

(UG/L

(UG/L

AS MN)

Ab HG

)

1979 1200

<.5

6400

<.5

5500

<.5

2800

<.5

2200

<.5

860

<.5

1200

<.5

1000

<.5

1500

<.5

2200

<.5

460

<.5

1400

<.5

1000

<.5

840

<.5

1300

<.5

1300

<.5

1600

<.5

1100

<.5

2000

<.5

2100

<.5

5700

<.5

6300

<.5

1800

<.5

3300

<.5

4300

<.5

NICKEL*

TOTAL

RECOV

ERABLE

(UG/L

AS NI

) 35

120

63

46 30 39 13 44 77 19 38

35

39

47

6537

4455

82 1

11044

47 78

SELE

NIUM,

TOTAL

(UG/L

AS SE

) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 u 0 0

SILVER,

TOTAL

RECO

V

ERABLE

(UG/L

AS AG

) 0 0

--0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0

ZINC*

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN) -.

10

0 0

40 0

50 40

0 0

10 (SO

ZINC*

DIS

SOLVED

(UG/L

AS ZN) 40

220 30

100 70 50 70 90

70

120 20

50 50

5080

80

90

40

170

220

360

320 80

130

140

ZINC,

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 60

230

260

120

90 70

80

90

100

310 50

80 50

6090

8U

90

80

170

270

420

320 80

140

200

CARBON*

ORGANIC

DIS

SOLVED

(MG/L

AS C) 6.9

2.5

1.1

2.1

1.2

2.8

1.1

4.3

1.3

1.6

4.4

3.2

1.7

2.0

<*.2

1.8

7.5

5.0

7.6

2.0

3.0

2.9

3.3

5.2

4.4

CARBON*

ORGANIC

SUS

PENDED

(MG/L

AS C) 2.5 .2 .2 .4 .4 .7 .2 .2 .1 .5 - .1 .1 .1 .1 .1 .2 .2 .1 .1 .0 .1 .5 .2 .1

PHENOLS

(UG/L) 1 2 0 0 0 5 0 0 0 2 1 0 0 0 0 1 0 0 2 0 0 0 0 2

170

Appendix



TIME

DATE

WATER YEAR 1980

OCT 02...

23...

NOV U9...

20...

DEC 06. ..

20...

JAN 10...

24...

FEB 12...

28...

MAR 12...

25. .

.APR07...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

1030

1100

0930

11UO

1400

10UO

1300

1300

1300

1000

1330

1130

1100

1130

1200

1330

1^30

1330

1115

1030

1000

1300

Ibl5

1230

SPt-

OXYGEN

CIFIC

DEMAND*

STKEAM-

CON-

CHEM-

FLOW.

DUCT-

TEMPER-

ICAL

INSTAN-

Ai^CE

PH

ATURE*

(HIG

H TANEOUS

(MICRO-

WATER

LKVtL)

(CFS

) MH

OS)

(UNI

TS)

(DEG

C)

(M

G/L)

1.4 .30

.40

.42

.70

.7u

.40

.bO

.3d

.90

1.2

l.a .90

.60

.20

.95

.20

.10

.10

.05

.20

.70

.15

.16

320

410

320

310

310

300

360

335

380

320

265

290

300

310

420

370

470

600

300

690

610

425

720

8bO

b.O

4.3

5.3

5.6

5.7

5.9

3.2

5.3

b.l

6.0

b.O

b.tt

6.U

6.1

4.b

6-3

4.6

3.9

6. a

4.0

3.b

5.0

3.4

4.0

15.0

12.5

7.0

7.0

t.5

1.0

1.0 .b .5 3

+.0

3.b

9.0

iJ.O

10.5

17.0

£2.0

Ô.D

18. b

23.0

dl.O

dd.O

2<f.b

19.5

6 17 8 0 116

b32 34 14 95 3

112

15 23 10 21

7

HARD-

HARU-

NESS»

ACIDITY

CALCIUM

NESS

NONCAR-

TOTAL

ACIDITY

DIS-

(MG/L

bONATE

HEATED

(MG/L

SOLVED

AS

(MG/L

(MG/L

AS

(MG/L

CACU3)

CAC03)

AS H)

CAC03)

AS CA

)

120

160

140

140

120

130

150

ISO

IbO

140

130

1JO

120

130

170

1*0

IttO

290

130

2bO

1 70

260

300

120

16u

130

140

120

120

15u

140

160

130

120

12u

110

120

170

130

180

290

10U

250 170

2«0

300

.6

30

b

30

.

.-

..

.

..

--

--

_

--

1.2

60

2.b

129

1.6

89

1.2

60.4

20

1.9

9<*

3.1

154

26

39

3*

34

30

31 373b

4033

3030

26

31 42

34

44 70 29

60

-.

40

6673

Appendix

7. Water-quality da

ta,

Station 03201700, Big four Hollow Creek near Lake Hope,

Ohio,


SODiUM*

3lUn»

;jvj

uiui

wi»

DIS-

DIS

SOLVED

SOLVED

(MG/L

(MG/L

SO

SORP-

DIS-

DIS-

BONAFt

CAR-

LINITY

TION

SOLVED

SOLVED

(MG/L

bONATE

(MG/L

DIUM

RATIO

(MG/L

(MG/L

AS

(MG/L

AS___

._.....

»,-.^«

i ./

-/ >

} \

kc ml\

C i\r

Ci 4\

A

DIS

SOLVED

(MG/L

t; rn/M

/DIS

SOLVE

(MG/L

is Sn

<iDATE

AS MG

) AS NA

) PERCENT

Ab NHJ

«=>

rv ;

nuu-M

«^ v-

v-/

~~ '

- --

WA01

ER YEAR

02...

23...

MOV

09...

20...

DEC

06...

20...

JAN

10...

24...

FEB

12...

28. ..

MAR

12...

25...

APR

07...

24...

MAY

09...

23...

JUN

12...

24...

JUL

10...

21...

AUG Ob.. .

19...

SEP

08...

22...

1980

12

15 13

14 12

12 15 14 ID

13 13

13 12

12 17

14 18 28 13

24 16 27 29

5.1

6.7

5.8

5.3

4.8

5.1

5.4

5.1

5.5

5.6

4.2

3.8

4.9

4.6

6.3

5.6

6.4

7.0

6.7

7.2

6.5

6.7

7.6

8 13 13

12 12

12 11

11 7 8 7 6 8 7 7 8 7 5 10 6 8 5 5

.2

.tL

.d .2 .d

.2 .2

.* .2 .2 .2

.1 .2 .2 .2

.2 .2

.2 .3

.2 .2 .£

.2

7.5

9.9

8.0

7.1

t».5

6.7

7.4

7.0

7.2

7.1

D.b

5.5 __

_-

__

-_

2.4

3.2

2.2

1.8

1.7

1.6

2.0

-

l.V

1.7

1.5

1.3

1.7

1.6

2.1

2.3

4.2

2.8

3.5

2.3

3.9

2.8

2.8

3.7

0 0

12 4 6 6 8 8 2 9 6 10 14 12

118

3 0

31 0 0 1 U 0

0 0 0 0 0 0 0 0 0 0 0 0 U 0 0 0 U 0 U 0 0 U 0 0

0 0

10 3 5 5 7 7 2 7 5 8 11

10

1 ID 2 0

25 0 0 1 0 0

.0 .0

96

16

19

id

81

64

£D

14 9.6

25 22

15 40 2.3

76 .0

3.9

.0 .02.5 .0 .0

140

180

140

140

140

130

170

160

190

IbO

140

130

130

130

200

150

210

380

110

310

170

320

390

Appendix



DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FES 12...

28...

MAR 12...

25...

APR 07...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

CHLO

RI

DE.

DIS

SOLV

ED(Mo/L

AS CD

YEAR 1980

2.4

2.6

3.0

2.8

2.9

3.0

2.6

3.3

2.8

3.6

2.8

1.9

2.5

2.2

2.8

6.7

4.0

3.5

3.2

4.1 --

4.1

3.6

3.2

SOLIDS.

RESIDUE

AT 160

DEG. C

DIS

SOLVED

(MG/L)

221

285

«;46

224

215

194

263

260

301

2<»9

196

194

216

239

352

249

336

619

220

556

--

301

5<fO

690

SOLIDS.

DIS

SOLVED

( TONS

PER

AC-FT)

.30

.39

.33

.30

.29

.26

.36

.35

.41

.34

.27

.26

.29

.33

.48

.34

.46

.64

.30

.76

--

.41

.73

.94

NITRO

GEN.

N02+N03

TOTAL

(MG/L

AS N) .U

.Ob

.09

.06

.15

.12

.10

.11

.06

.23

.16

.02

.15

.10

.lb

--

.14

.21 --

.20 .20

NITKO-

t»EN. AM

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) .24

.02

.16

.21

.08

.20

.14

.2o

.60

.dO

.16

.20

.12

.01

1.4 .16

.17

.11

.16

NITRO

GEN.

TOTAL

(MG/L

AS N) .30

.67

.2b

.29

.23

.32

,3U

.37

.68

.43

.34

.22

.27

.11

1.6 --

.32

.38 --

.31 --

.38

NITRO

GEN.

TOTAL

(MG/L

AS N03)

1.6

3.0

1.1

i.3

1.0

1.*

1.3

1.6

3.0

1.9

l.b .97

1.2 .49

6.9 --

1.4

1.7 --

--

1.4

1.7

PHOS

PHORUS.

TOTAL

(MG/L

AS P) .030

ulo

.010

.000

.000

.010

.010

.000

.010

.020

.010

.010

.010

.010

--

.020 --

.000

.010

.010

.010

PHOS

PHORUS.

TOTAL

(MG/L

AS P04)

.09

.03

.03

.00

.00

.03

.03

.00

.03

.06

.03

.03

.03

.03

--

.06

--

.00

.03 -

.03

~ .03

ALUM

INUM.

TOTAL

RECOV-

LRA8LE

(UG/L

AS AD

2000

2100

900

700

820

2200

2100

2buO

2000

2200

480

1000

1500

1500

--

1100 --

7000

900 --

1400 --

ANTI

MONY.

TOTAL

(UG/L

AS SB

) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

----

--

--

Appendix



DATE

WATER

OCT 02.. .

23...

NOV 09...

£0...

DEC 06.. .

do..

.JAN 10...

24...

FEB 12...

28...

MAR 12...

25..

.APR 07...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

AKSENIC

TOTAL

(UG/L

AS AS)

YEAR 1980

2 2 0 0 0 0 1 2 2 1 1 0 2 1

--..

>

-- _-

.

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS BE

) 100 0 0

10 10 20 10 0 0 0 0 0 10 .. ..

CADMIUM

TOTAL

RECOV

ERABLE

(UG/

lAS CD

) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

-- -- _.

-.

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR

) 10 11

7 8 12b b 8

40 13 104 b 3

--

COPPtR*

TOTAL

RECOV

ERABLE

(UG/L

AS CU

) J 7 2 2 2 4 4 4 3 3 4 2 5 3

--

..

-_

IRON*

TOTAL

RECOV

ERABLE

(UG/L

AS FE

)

8800

2900

UOO

1300

1800

1900

2200

3900

2200

3000

2200

2000

1800

1500

1100

2700

3900

12000

1800

3600

0000

3000

8100

IRON*

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

)

800

700

1900

bOO

1700

1100

1200

830

790

300

1400

2400

11000

1100 0

900 0

IRON*

OIS-

SOLV

Ei)

(UG/L

AS t-E)

t>900

1700

760

650

1400

1100

1500

2000

1700

1300

1100

830

970

710

800

1300

1500

1100

690

3600

2100

8100

3600

LEAD*

TOTAL

RECOV

ERABLE

(UG/L

AS HB

) 1 3 0 2 0 0 0 1 0 4 2 1 1 2 u 1 3 5 2 b 9 13 6

MANGA

NESE*

TOTA

LRECOV-

tRABLE

(UG/L

AS MM

)

2100

2700

1900

1700

1700

1700

2^00

2200

2700

1VOO

1500

1200

1 /OO

1900

3000

2100

3ttO

O6900

1900

7500

5500

3200

7700

MANGA

NESE*

SUS

PENDED

RECOV.

(UG/L

AS MN)

100 0 0 0 0 0

100 0 0

100

'100

0 0 0 0200 0 0

200

300

100

100

Appendix

7. Water-quality data,

Station 03

2017

00,

Big four Hollow Creek near Lake Hope,

Ohio

,

water years 19

79 and

1980 Continued

DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

28...

MAR 12...

25..

.AP

R 07...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08. ..

22...

HANGA-

MERCURY

NESE*

TOTAL

DIS-

RECOV-

SOLVED

EWAt

tLE

(UG/L

(UG/L

AS MN

) AS HG

)YEAR 1980

2000

<.5

2700

<.l

1900

.61700

.1

1700

.21700

<.l

2300

<.l

2200

<.l

2700

<.l

1800

.7

1*00

.11200

.1

1700

.11900

<.l

3000

1900

3800

6900

1700

<.l

7200

3100

7600

10000

NICKEL*

TOTAL

RECOV

ERABLE

(UG/L

AS Nl) 28

33

29

21 24 19 27

30 34 22

22 16 24 21 --

--

19 _-

SELE

NIUM*

TOTAL

(UG/L

AS SE

) 0 0 0 0 0 0 0 0 0 0 1 0 0 0

SILVER*

TOTAL

RECOV-

ERAbLE

(UG/L

AS AG

) 0 0 0 0 u 0 1 0 0 0 0 0 0 0

ZINC*

SUS

PEND

EDRECOV

ERABLE

(UG/L

AS ZN

) 0 0 020 0 0 U 0 0 0 0 0 0 0

0

0 0 -- 10

ZINC*

DIS

SOLVED

(UG/L

AS ZN) bO

110

bO

20

60 80 60 70 70 100 50 110 dO 60 100

50 90

200

40

2UO 60

200

260

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 80 110

8040

6080

8070

70

100

50

110

bO60

so 200

40 70

CARbON*

ORGANIC

DIS

SOLVED

(HG/L

AS C) 2.4

4.3

2.1

5.2

4.3

1.6

4.4

2.2

2.4

2.0

5.<:

1.2

145.0 . 7.1

6.0

1.8

--

.

2.2 --

1.6

CAHb

OiM*

ORGANIC

bUS-

PENO

ED(MG/L

AS C)

.5 .0 .1 .2 .3 .4 .4 .0 .3 .3 .5 .1 .6 .5 -- .2

1.1 --

.4 ~

PHENOLS

(UG/L) 5 0 0 0 0 0 0 0 0 0 5 0 1 3

-- -- --

Appendix 8. Water-quality data, Station 03201720, Hull Hollow Creek near Lake Hope, Ohio


DATE

W^.TER

NOV 06...

21...

30...

DEC 09...

2?...

JAN 04...

17...

FErt 01...

co

1 5 ...

ta

27

c r

. .

.

MAR 13...

26...

APR02...

10...

11...

27...

MAY 15...

31...

JUN 11...

28...

JUL 09...

26...

AUG 08...

23...

SEP 05...

17...

TIME

YEAR 1979

1400

1000

1230

1115

1200

1330

1600

1200

1630

1300

0900

1130

1430

1400

1000

1100

1100

1100

0930

1430

1230

1030

0945

0900

1300

1100

STREAM-

FLOW*

INSTAN

TANEOUS

(CFS

) .15

.23

.32

1.5 .11

.44

.44

.22

.22

2.2 .70

1.1

3.8

1.7

1.4

1.0 .58

.49

.70

.27

.44

.37

.44

.53

.30

.37

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) 190

130

150

__

130

110

130

100

120

90

95

115

--

120 150

135

140

120

IbO

185

130

150

129

160

125

PH

FIELD

(UNITS)

5.9

5.9

5.8

--

6.0

6.2

6.6

6.1

6.1

6.3

6.3

7.0

.

6.3

6.9

6.3

7.1

7.3

7.0

6.8

6.6

6.7

7.1

7.1

6.9

TEMPER

ATURE*

WATER

(DEb C)

12.5

7.5

2.5

--

5.0

2.5

1.5 .5

-1.0

b.O

2.0

5.5

11.5

13. 5

16.5

14.0

14.5

19.5

17.0

19.5

19.5

18.0

20. 0

14.5

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LEVEL)

(MG/L) 11 7 13 -- 36 134 14 3 7 7 6

-- 13 . 7

25 7

10 9 8 05

3742 3 5

HARO-

NESS

(MG/L

AS

CAC03) 6b5656

--

48

4452

«*8

50 35

<fb

49

49 57 50 52

52

50

54

53

53

52

49

48

HARD

NESS*

NONCAR-

BONATE

(MG/L

CAC03) 5045

56

37 32

41 39

40 30

4432

32

--

44

3938

34 36

39

36

4232

3232

CALCIUM

DIS

SOLVED

(MG/L

AS CA

)

16 14 14

--

12 11 13 12 12 8.7

11 12

~12

. 14 12 13 13 12 13 13 13 13 12 12

MAGNE

SIUM*

DIS

SOLVED

(MG/L

AS MG

)

6.0

5.2

5.2 --

4.4

4.0

4.8

4.3

4.8

3.3

4.3

4.6

4.5 .

5.3

4.9

4.8

4.7

4.8

5.2

5.0

5.0

4.7

4.5

4.4

SODIUM*

DIS

SOLVED

(MG/L

AS NA)

2.8

2.4

2.6

-..

1.8

1.6

2.0

1.8

2.0

1.2

1.6

2.1 .

2.0--

2.3

2.3

2.2

2.0

2.4

2.5

2.3

2.5

2.2

2.2

2.0



DATE

SjJgJEAR

06...

21...

30...

DEC 09...

22...

JAN 04...

17...

FER 01...

15...

27...

MAR 13...

26...

APR 02...

10...

11...

27...

MAY 15...

31...

JUN 11...

28...

JUL 09...

26...

AUG 08...

23...

SEP 05...

17...

SODIUM

PERCENT

1979

8 8 9

-- 7 7 8 7 8 7 7 8

8 8 9 8 7 9 9 8 9 8 9 8

SODIUM

AD

SORP

TION

RATIO .2 .1 .2 -- .1 .1 .1 .1 .1 .1 .1 .1 -- .1 .1 .1 .1 .1 .1 .1 .1 .2 .1 .1 .1

SODIUM*

POTAS

SIUM

DIS

SOLVED

(MG/L

AS NA) -- --

__ --

--

--

--

.

3.8

. --

--

4.0

4.2

4.0

3.8

3.5

POTAS

SIUM*

DIS

SOLVED

(MG/L

AS K) 2.0

l.b

1.7

--

1.5

1.3

1.2

1.4

1.4

1.3

1.3

1.3

_-

1.6 l.b

1.7

1.6

1.7

1.5

l.b

1.7

1.7

1.8

1.6

1.5

BICAR

BONATE

(MG/L

AS

HC03) 18 14

1

-- 14

1414

10 12 6 1

21 .

20-- 16 13 17 22 17 Ib 18 13 24

20

20

CAR

BONATE

(MG/L

AS C03) 0 0 0

-- 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0

ALKA

LINITY

(MG/L

AS

CAC03) 15 111

_- 11 11 11 8

10b 1

17 .

16 13 11 14 18 14 15 15 11 20 16 16

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C02)

36 28 2.5

-_

22 14 5.6

13 15 4.8 .8

3.4

--

16--

3.2

10 2.2

1.8

2.7

4.6

7.2

4.2

3.1

2.5

4.0

SULFATE

DIS

SOLVED

(MG/L

AS S04)

b745

51

__

42

3b

38

42

4432

4U

40

--

35--

50

44

45

41 51 4846

48

44

39

47

CHLO

RIDE*

DIS

SOLVED

(MG/L

AS CD

1.6

1.6

1.6

__

1.2

1.0

1.2

1.4

1.2 .9 .9 .9 -- .8 --

1.1 .7 .y .8 .9

3.1

1.0 .9 .3 .9

1.2

SOLIDS*

RESIDUE

AT 18

0 DEG. C

DIS

SOLVED

(MG/L)

102

93

90

__85 76 84

79

85

64 /b 78

_-75

__ 98

92

88

92

88

112

100

110 85

104

86



DATE

WATER

NOV 06...

21...

30...

DEC 09...

22. .

.JAN 04...

17...

FE<3 01...

15...

27...

MAR 13...

26...

APR 02...

10...

11...

27...

MAY 15...

31...

JUN 11...

28...

JUL 09...

26...

AUG08...

23...

SEP 05...

17...

SOLIDS.

DIS

SOLVED

(TONS

PER

AC-FT)

YEAR 1979

.14

.13

.12

--

.12

.10

.11

.11

.12

.09

.10

.11 .10--

.13

.13

.12

.13

.12

.15

.14

.15

.12

.14

.12

NITRO

GEN.

N02+N03

TOTAL

(MG/L

AS N) .03

.17

.17

--

.Ud

.09

.10

.09

.23

.18

.07

.09

.04

.02

.03

.06

.05

.03

.07

.06

.03

.08

.06

.21

NITKO-

GEN. AM

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) .0

1.00

.08

--

.07

.00

.05

.08

.34

.00

.02

.15

.12

--

.06

.12

.14

.30

.12

.03

.00

.26

.10

.00

.37

NITRO

GEN.

TOTAL

(MG/L

AS N) .04

.17

.25

--

.15

.09

. Ib

.17

.57

.Itt

.09

.24

--

.16

--

.08

.15

.20

.35

.15

.10

.06

.29

.18

.06

.58

NITRO

GEN.

TOTAL

(MG/L

AS N03)

.18

.75

1.1 --

.66

.40

.66

.75

«i.5 .80

*»o

1.1 .7

1 .35

.66

.89

1.6 .66

.44.

.27

1.3 .80

.27

2.6

PHOS

PHOR

US.

TOTAL

(MG/L

AS P)

.000

OOU

.000

--

.000

.000

.000

.000

.000

.000

.000

.000

.010 --

.000

.010

.000

.010

.030

.000

.040

.010

.000

.010

.010

PHOS

PHORUS.

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P0*») -- .00

.03

.00

.03

.09

PHOS

PHORUS.

TOTAL

(MG/L

AS P04) -- --

.00

.03

.00

.03

.09

.00

.12

.03

.00

.03

.03

ALUM

INUM

.TO

TAL

RECO

VER

ABLE

(UG/L

AS AL) 90 80 110

--

130

170

80 180 90

170 50

130

--

130 80 90 160

130

280

100

70 90

15U

190

140

ANTI

MONY.

TOTAL

(UG/L

AS Sd

) 0 0 0

-- 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

ARSENIC

TOTAL

(UG/L

AS AS) 0 0 0

-- 0 1 1 1 0 1 1 1 0 0 0 0 0 1 1 0 2 2 0 0



DATE

WATER

NOV 06..

21..

30..

DEC 09..

22..

JAN 04..

17..

FEB 01..

15..

27..

MAR 13..

26..

APR02..

10..

11..

27..

MAY 15..

31..

JUN 11..

28..

JUL 09..

26..

AUG 08..

d3..

SEP 05..

17..

BERYL

LIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS BE

)YEAR 1979 0 0 0

** 0 0 0 0 0 0 0 0

. 0

.0 0 0 0 0 0 0 0 0 0 0

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD

) 2 16 4

1 2

22

68 1 8 2 0

9 7 4 6

120 0 0 1 1 0 0

CHRO

MIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS CP

) 0 1 1

1 0 3 0 2 0 0 0

6 6 3 9 9 11 16 5

20 18 4 2

COPPER»

TOTAL

RECOV-

ERAt

tLE

(UG/L

AS CU

) 1 2 2

-- d I 1 1 2 2 1 1

1 d 1 1 1 6 3 0 3 3 d 3

IRON,

TOTAL

RECOV

ERABLE

(UG/L

AS FE)

130

100

210 ~

250

100

100

IbO 70

210

120

100

IbO 40

90

400

100

890

160

2bO

440

^30

b60

310

IKON

,SUS

PENDED

RECO

VERABLE

(UG/L

AS FE

) . -- -- -- 30 80

400 90

860

140

240

420

220

IRON,

DIS

SOLVED

(UG/L

AS F£)

130 10

210 80 70 90 10 10 30 20 20 10 10 100

10 30 20 10 20 10 40 0

LEAD*

TOTAL

RECOV

ERABLE

(UG/L

AS PB

) 41 76 24 -_ 10 24

190

900 13 92 19 b

110 72

40 3b 28 4 4 5 b 7 6 1

MANGA

NESE*

TOTAL

RECOV

ERABLE

(UG/L

AS MN

)

130

300 3U _.

30 30 30 30 30 30 20 20

20-- 20 60 40

20 70 30 10 bO

40

60 30

MANbA-

NESE»

SUS

PENDED

RECOV.

(UG/L

AS MN) .-

-- -- --

-- -- 10 30 10

060 0 0

30 10 300

MANGA-

NESEt

DIS

SOLVED

(UG/L

AS MN

)

no 20 30 __

30

30

30 20 30 30

20 10 -- 10 -- 10 30 30

20 10 30 10 20

30 30 30



ZINC,

MERCURY

NICKFL,

SILVER,

SUS-

ZINC,

CARdON,

CARBON,

TOTAL

TOTAL

SELL-

TOTAL

PENOEU

ZINC,

TOTAL

ORGANIC

ORGANIC

RFCOV-

RECOV-

NIUM,

RECOV-

RECOV-

DIS-

RECOV-

DIS-

SUS-

ERABLt

ERABLE

TOTAL

ERABLE

ERABLE

SOLVED

ERABLE

SOLVED

PENOEO

PHENOLS

(UG/L

(UG/L

(UG/L

(UG/L

(UG/L

(UG/L

(UG/L

(MG/L

(MG/L

DATE

AS HG

) AS

Ml

) AS SE )

AS AG

) AS ZN

) AS ZN

) AS ZN

) Ab C)

AS C)

(UG/L)

WATER YEAR

NOV

06...

21...

30...

DEC 09...

22...

J&N

04.. .

17...

FF8

01...

15...

27...

MAR

13...

26...

APR 02...

10...

11...

27...

MAY

15...

31...

JUN

11...

28...

JUL

09...

26...

AUG

08...

23...

SFP

05...

17...

1979

<.5

27

<.5

16<.5

14

<.b

14

<.5

13

<.6

4

<.5

5 <.5

18<.5

9

<.5

12<.5

7

<.5

23

<.5

20

<.5

30<.5

15

<.5

16<.5

15

<.5

24

<.5

0

<.b

3 <.b

3

<.5

3<.5

3

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 I)

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0

:: _- 40 0 10 10 40 20 2 0 0

110 ?0

300

10

0

20

10 10

100 10

10 10

0

30

10 8 5 6 tt 10

20 100

30 0 10 30

20

20 20

70

20 20

10 20

40 30

20 2040

30

10 10

20

120 20

1.7

S.4

1.6

2.9

2.4

1.0

2.7

1.3

3.1

5.0

2.0

7.7

6.4

3.8

11

2.1

3.6

3.4

3.9

2.0

8.0

6.1

2.9

1.2 .4

.3 _ .3 .2

.1 .1

1.6

*__«M

.0

.0 .1 .1 .2

.2 .1 .3 .4

.0 .2

.2 .2 .0

2 1 0

M 2 1 0 0 4 1 0 5

__ 0 0 1 0 0 2 0 0 0 0 2 1



oo

en

TIME

DATE

WATER YEAR 1980

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

28..

.MAR 12...

25...

APR 08...

24...

MAY 09...

23...

JUN 24...

JUL 10...

AUG 19...

1430

1445

1530

1400

1200

1400

1600

1000

1200

1200

1200

0930

1530

0945

1000

1200

1130

1030

1200

SPE-

OXYGEN

CIFIC

DEMAND*

HARD-

STREAM-

CON-

CHEM-

HARU-

NtSS»

ACIDITY

CALCIUM

FLOW,

DUCT-

TEMPER-

ICAL

NESS

NONCAR-

TOTAL

ACIDITY

UIS-

INSTAN-

ANCE

PH

ATUf

tt*

(rtI

GH

(MG/L

80NATE

HEATED

(MG/L

SOLVED

TANEOUS

(MICRO-

WATER

LEVEL)

AS

(MG/L

(MG/L

AS

(MG/L

(CFS

) MHOS)

(UNI

TS)

(DEG

C)

(MG/

L)

CAC03)

CAC03)

AS H)

CAC03)

AS CA)

.60

.60

4.4 .60

.50

.50

.40

.40

.15

.30

.30

.30

.20

.20

.03

.10

<.01 .80

.06

130

130

125

140

140

120

135

120

140

140

130

125

133

135

140

"16

0

150

160

170

7.1

6.4

7.0

7.0

7.9

7.0

7.5

7.5

7.6

6.7

7.3

7.b

6.6

7.4

7.J

8.0

8.0

6.3

6.9

15.5

11.5

8.5

11.5

6.5

5.0

1.5 .5 .5 .5

3.5

5.5

11.5

11.0

tt.O

15.0

17.0

17.5

20.5

421 21 29 1 4 4 U

10 75 82 5 16 0

15 b 9 13

51 53

55

53 57 56

57 56

60

60 57 56 56

50

5665

5tt

63

63

32 37 35 3b 41 Jb 43 4*

4b 43

40 27 3b 39 39 52

24 34 36

13 13 U 13 14

14

14.

14 15 15 14 14 14 14 13 16 15

.6

30

15

.2

10

ib


ta.

Station 03201720, Hull Hollow Creek near Lake Hope,

Ohio

water years -1979

and 1980 Continued

SODIUM*

MAGNE-

SODIUM

POTAS-

POTAS-

CARBON

SIUM

t SODIUMt

AD-

SIUM

SIUM

» BICAR-

ALKA-

DIOXIDE

SULFATt

OIS-

DIS-

SORP-

OIS-

DIS-

dONATt

CAR-

LINITY

OIS-

DIS

SOLVED

SOLVED

TION

SOLVED

SOLVED

(MG/L

BONATE

(Mb/L

SOLVED

SOLVED

(MG/

L (MG/L

SODIUM

RATIO

(MG/

L (M

G/L

AS

(MG/L

AS

(MG/L

(MG/

L DATE

AS MG

) AS

NA

) PERCENT

AS NA)

AS K)

HC03)

AS C03)

CAC0

3)

AS C02)

AS S0

4)

WATER YEAR 19

80OC

T 02...

23..

.NOV 09...

20..

.DE

C 06..

.20

...

JAN 10...

24...

FES 12...

28..

.MA

R 12...

25...

APR 08..

.24...

MAY 09..

.23

...

JUN 24..

.JU

L 10..

.AU

G 19...

4.6

4.9

4.8

5.0

b.4

5.1

5.4

5.2

5.5

5.5

5.3

5.2

5.1

5.0

5.6

6.2

5.0

6.2

5.7

2.0

2.2

2.3

2.3

2.7

2.3

2.2

2.3

2.4

2.5

2.1

1.9

2.4

2.3

2.6

2.9

2.5

3.6

2.9

11 12 12 13 14 8 12 8 8 8 7 7 8 8^

9 9 8 11 9

.1 .1 .1 .1 .2 .1 .1 .1 .1 .1 .1 .1 .1 .1 .2 .2 .1 .2 .2

3.8

4.1

4.7

3.7

4.1

3.6

3.6

3.7

3.6

3.7

3.1 --

'

1.8

1.9

2.4

1.4

1.4

1.3

1.4

1.4

1.2

1.2

1.0

1.4

1.4

1.9

1.5

1.6

1.6

2.0

2.1

24 19 £4 18 20 c2 17 i7 19 21 2036

22

20

20 17 42

35

34

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

20 16

20 Ib lo 18 14 14 16 17 16 3D It)

It)

16 14 34

29

28

3.1

U 3.ti

2.^ .4

3.5 .->

.9 .86.7

1.6 .9

5.6

1.3

1.6 .3 .7

28 6.8

39

46

39

4b

4b45

5245

49 51 44 42 4b 47 51 5b 50 42 4b


Station 03

2017

20,

Hull Hollow Creek near Lake Hope,

Ohio

water year 19

79 an

d 1980 Continued

SOLIDS*

CHLO-

RESIDUE

RIDE*

AT 180

DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

CD

1AM

10...

24...

FEB 12...

28...

MAR 12...

25...

APR 08...

24...

MAY 09...

23...

JUN 24...

JUL 10...

AUG 19...

DIS

SOLVED

(MG/L

AS CD

YEAR

3.99

0

.4 .7

1.3 .9

1.0

1.4 .9

1.0

1.1

1.1

1.0 .9

1.2 .8 .9

1.0 .8 .9 .9

DEG. C

DIS

SOLVED

(MG/

L) 86

90 100 93 -- 87 97 96

106

104

98

97 91 94

106

104

105

105

99

SOLIDS*

DIS

SOLVED

(TONS

PER

AC-FT)

.12

.12

.14

.13 -- .12

.13

.13

.14

.14

.13

.13

.12

.13

.14

.14

.14

.14

.13

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .0

4.0

0

.14

.06

2.5 .13

.10

.Of

.20

.13

.11

.07

.05

..

.06

.05

.20

- .20

NITRO-

GEN»AM-

MONIA +

ORGANIC

TOTAL

(MG/L

AS N) .0

6.1

4

.29 --

.12

.19

.34

.09

.00

.01

.10

<*5

.07

.07

-

.00

.01

.09

.04

NITRO

GEN*

TOTAL

(MG/L

AS N) .1

0.1

4

.43

.10

2.7 .47

.19

.07

.21

.23

.56

.14

. .1

2

.05

.06

.29

.24

NITRO

GEN*

TOTAL

(MG/L

AS N0

3) .44

.02

1.9 .80

12 2.1 .84

.Jl

.93

1.0

2.5 .62

.53

--

.22

.27

1 .-3

1.1

PHOS

PHORUS,

TOTAL

(MG/L

AS P) .000

.010

.040

UlO

.010

.000

.020

.000

.010

.010

.000

.010

.000 ..

.010

.010

.000

.010

PHOS

PHORUS*

TOTAL

(MG/L

AS P04) .00

.03

.12 --

.03

.03

.00

.00

.00

.03

.03

.00

.OJ

.00

..

.03

.03

.00

.03

ALUM

INUM*

TOTAL

RECOV

ERABLE

(UG/L

AS AD 60 100

380

270 40

110

200 oO 13000 50 130

dOO

110 50 dO 30 50

ANTI

MONY*

TOTAL

(UG/L

AS SB) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

.. --

00


Station 03201720, Hull Hollow Creek near Lake Hope,

Ohio


1o^

1.TER YEAR 1980

02...

1 1°

0 23...

1 0

°NOV 09...

0 0

0 20...

0 0

0DEC 06...

0 10

0 20...

0 10

0

JAN

oo

10...

0 20

024...

0 10

°

FEB Si:

:: !

l! «

MAR 12.

.. i

o ;

25...

0 0

0

APR 08...

1 0

°24...

0 0

0

MAY 09...

23...

JUN24...

JUL 10...

AUG 19...

IRON,

MANbA-

MANGA-

MIUM,

COPPER,

IKON,

SUS-

LE*U-

NESE,

NESb.

- B- & »

'^sl & S&-

pSEo

fc ^ ^r

fuÊ WF ^

fuSfc6

K;

AS CR

) AS CU

) AS FE

) AS Ft

) AS FE

) AS PB

) AS MM

AS MN

)

b 10

7 b 3 4 lu 2

29

11

3 b 7 3

-- _ _

1 2 1 1 0 5 2 1 1 0 3 0 3 2

--,

^ ̂

90 60 800

250 50 150

140 20 30

60 30 100

130 80 30 110 80

230

400

_ __

140

uo 10

20

60 20 90

110 bO 10

100 70

210

J60

20 10 70 10 10 10 10

10 10 0 10 10 20 20 20 10 10 20 40

0 0 0 0 0 D 1 0 0 2 1 0 1 1 0 0 b 1 3

30dO 60 30 20 30

60

30 30

20 20dO 20 20 20 30 20 30

400

0 0

30 10

0 0

30

10

0 10

0 0 0 0

10 10 10 10

380


Station 03

2017

20,

Hull Hollow Creek near Lake Hope,

Ohio

water year 19

79 and

1980 Continued

00 vo

ZINC

, MANGA-

MERCURY

NICKEL*

SILVER,

SUS-

ZI

NC,

CARBON,

CARBON,

NESE,

TOTAL

TOTAL

SELE-

TOTAL

PENDED

ZINC,

TOTAL

ORGANIC

ORGANIC

DIS-

RECOV-

RECOV-

NIUM,

RECOV-

RECOV-

DIS-

RECOV-

DIS-

SUS-

SOLVEO

ERABLE

ERABLE

TOTAL

ERABLE

ERABLE

SOLVED

ERABLE

SOLvtD

PENOED

PHENOLS

(UG/

L (U

G/L

(UG/

L (UG/L

(UG/

L (UG/L

(Ub/L

(UG/L

MG/L

(MG/L

DATE

AS MN)

AS HG)

AS NI)

AS SE)

AS AG)

AS ZN

) AS

ZN)

AS ZN)

AS C)

AS

C)

(U

G/L)

OCT 02...

23..

.NO

V 09...

20...

DEC 06...

20..

.JAN 10...

24...

FE8 12...

28...

MAR 12...

25...

APR 08...

24...

MAY 09..

.23

...

JUN 24...

JUL 10...

AUG 19...

30

<.5

20

<.l

30

.220

<.l

20

<.l

30

<.l

30

.420

.9

30

<.l

10

.3

20

<.l

20

.1

20

.120

<.

l

10 20 10 20 20

1 2 2 6 3 3 2 2 3 0

28 21

2 1""

--

0 0 0 0 0 0 0 0 0 0 0 0 0 0

.. --

0 0 0 0 0 0 0 0 0 0 0 0 0 0

-. -- -- --

010

010

0 0 0 0 0 0 0 0 7 6

.. b t> 0 0

10 10 100

20

30

20 10 10 30 10 40 3 4 6 5 4 10 10

10 20 10 10 20

30

20 10 10 30 10 40 10 10 MM 10 10 10 10

b.7

b.b

6.b

3.3

4.1

3.0

1.7

1.7

1.2

2.2

3.4

2.2

b.ti

11

MM

11 b.

9

1.9

2.b

.1 .1 .6 .2 .3 .£ .2 .1 .1 .1 .1 .2 .1 .2 __ .1 .4 .4 .2

0 2 0 0 0 0 0 0 0 0 0 2 0 0

..

Appendix 9. Water-quality data, Station 03201722, Sandy Run below Hull Hollow Creek near Lake Hope, Ohio


DATE

WAJER YEAR

13...

24...

NOV

06...

21...

30.

DEC

21...

JAN

04...

16...

FES

01...

15...

27...

MAR

13...

26...

APR

11...

30...

MAY

15...

30...

JUN

11...

28...

JUL

09...

26...

AUG

08...

23...

SEP

05...

17...

TIME

1979

1300

1300

1500

11

0011

30

1430

1430

14

00

1300

1530

14

00

1000

13

30

1000

11

00

1200

12

30

1330

1330

1300

11

00

1015

1030

1200

1130

SPE

CIFIC

CON

DUCT

ANCE

OXYGEN

DEMAND*

HARD-

CHtM-

HA*U-

NESS*

ACIDITY

TEMPER-

ICAL

NESS

NONCAR-

TOTAL

ACIDITY

PH

ATUR

tff

(HIGH

(MG/

L BONATE

HEATED

(MG/L

(MICRO-

FIELD

WATER

LEVtL)

AS

(MG/

L MHOS)

(UNI

TS)

(OEG

C)

(M

G/L)

CAC03)

CAC03)

410

1100

1100

720

470

275

350

320

430

620

270

450

350

285

480

540

570

390

780

500

1100

1000

320

710

740

4.6

3.1

3.2

3.1

3.3

4.1

3.6

3.9

3.5

3.4

3.9

3.5

4.1

4.2

3.4

3.6

3.6

4.2

3.3

4.1

3.4

3.0

4.6

3.3

3.5

13.0

9.0

12.0

7.5

5.0

4.5

l.o

1.0 ,t>

.0

5.0

2.5

6.0

6.5

10.0

15.5

14.5

17.0

18.5

17.0

19.5

20.5

18.0

20.0

13.0

27 15 14 3 13 27 25 2 10 4 13 12

17 14 9 17 4 12 10

6 11 28

<fU 9 b

130

390

340

210

170

94

110

120

140

190 76 140

110

100

150

160

160

130

250

160

340

230

120

220

220

130

390

340

210

170 94 110

120

140

190 76

140

110

100

IbO

160

160

130

250

IbO

340

260

120

220

220

(MG/L

AS H)

.43.6

3.0

1.5

1.0 .5 .8

.6 .81.8 .5

1.3 .4 .4

1.0 .9

1.0 .6

2.5 .5

3.7

2.6 .4

1.9

1.9

AS

CAC03)

20 179

149 74 50 2b 40

30 40 69

2b 6b'

20 20

bO 4b

50 30 124 25

184

129 20 94 94

CALCIUM

DIS

SOLVED

(MG/L

AS CA)

32 88 77

46 40 22

24

27 31 42

18 33

25 24

35 36

36 31 55 37

77 66

30 51 50

MAGNE

SIUM,

DIS

SOLVED

(MG/L

AS MG)

13 41 36

23 18

9.5

12

13 14 20 7.6

Ib

11 10

16 16

16 12 27 16

Jb 29

12 22 23


water

year

s 19

79 and

1980 Continued

SODIUM*

SODIUM

POTAS-

SODIUM»

AD-

SIUM

DIS-

SORP-

DIS

SOLVED

TIOM

SOLVED

(MG/L

SODIUM

RATIO

(MG/

L DATE

AS NA

) PERCENT

AS NA

)WATER YEAR 1979

OCT 13..

.24...

NOV 06...

21...

30...

DEC 21...

JAN 04...

16...

FE8 01...

15...

27...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 09...

26...

AUG08...

23...

SEP 05...

17...

9.6

20 18 12 9.5

5.1

5.1

6.0

8.2

11 5.0

8.4

7.3

6.7

9.1

11 9.1

7.0

18 15 16 16 8.2

14 16

13 10 10 11 10 10 9 10 12 11 12 11 13 12 11 13 11 11 13 17 9 11 12 12 14

.4 .4 .4 .4 .3 .2 .2 .2 .3 .4 .3 .3 .3 .3 .3 .4 .3

11

.3 .5

20

.5 .4

19

.4

19.3

10

.4

16.5

lb

POTAS-

CARBON

SIUM,

BICAP-

ALKA-

DIOXIDE

DIS-

HONATE

CAR-

LINITY

DIS

SOLVED

(Mvi

/L

BONATE

(MG/L

SOLVED

(MG/

L A5

(M

G/L

AS

(MG/L

AS K)

HC

03)

AS C0

3)

CAC03)

AS C02)

2.5

3.2

2.8

2.4

2.2

1.7

1.6

1.4

1.7

1.9

1.4

1.7

1.4

1.6

2.1

2.1

1.9

1.8

2.3

2.3

3.2

2.8

2.0

2.4

2.1

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0

.0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .0 .080

.0 .0

SULFATE

DIS

SOLVED

(MG/L

AS 50

4)

160

540

470

260

200

110

140

120

170

270 94 190

120

110

220

200

220

150

350

190

510

400

140

280

280

CHLO

RIDE*

DIS

SOLVED

(MG/L

AS CD

9.0

16 15 13 9.5

4.6

4.7

5.3

8.4

8.6

6.8

9.2

8.5

7.4

8.2

9.4

8.7

8.4

15 14 10 15 7.1

13 18


water years 19

79 and

1980 Continued

VO to

DATE

WATER

OCT 13...

24...

NOV 06...

21...

30...

DEC 21...

JAN 04...

16...

FEB 01...

15...

27...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 09...

26...

AUG 08...

23...

SEP 05...

17..

.

SOLIDS*

RESIDUE

AT 180

DEG. C

DIS

SOLVED

(MG/

L)YEAR 1979

241

794

683

404

303

173

219

193

256

395

153

292

201

193

311

325

315

266

575

341

839

647

237

49b

470

SOLIDS*

DIS

SOLVED

(TONS

PER

AC-FT)

.33

1.08

.93

.55

.41

.24

.30

.26

.35

.54

.21

.40

.27

.26

.42

.44

.43

.36

.78

.46

1.14 .88

.32

.67

.64

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .4

9.2

0

.18

.16

.15

.11

.12

.12

.10

.19

.19

.11

.12

.06

.08

.10

.08

.08

.13

.14

.12

.11

.10

.02

.12

NITRO-

GEN»AM-

MONIA

*ORGANIC

TOTAL

(MG/

LAS

N) .3

0.1

9

.09

.11

.11

.07

.01

.04

.24

.38

.07

.16

.20

.12

.20

.16

.11

.09

.08

.20

.2b

.19

.22

.10

.16

NITRO

GEN*

TOTAL

(MG/L

AS N) .7

9.3

9

.27

.27

.26

.18

.13

.16

.34

.57

.26

.27

.32

.18

.26

.26

.19

.17

.21

.34

.37

.30

.32

.12

.28

NITRO

GEN,

TOTAL

(MG/

LAS

N0

3)

3.5

1.7

1.2

1.2

1.2 .80

.58

.71

1.5

2.5

1.2

1.2

1.4 .80

1.2

1.2 .84

.75

.93

1.5

1.6

1.3

1.4 .53

1.2

PHOS

PHORUS,

TOTAL

(MG/L

AS P) .010

.120

.000

.000

.010

.000

.000

.000

.000

.000

.000

.000

.000

.010

.000

.000

.000

.010

.000

.000

.030

.000

.010

.000

.000

PHOS

PHORUS,

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P0

4) -- . -- .00

.00

.00

.03

.00

--

PHOS

PHORUS,

TOTAL

(MG/L

AS P0

4) -- --

--

--

.00

.00

.00

.03

.00

.00

.09

.00

.03

.00

.00

ALUM

INUM,

TOTAL

RECO

VER

ABLE

(UG/L

AS AL)

2900

10000

12000

5800

3900

1600

3100

1400

3300

4500

2300

4000

2400

2700

3800

3800

4700

3000

8300

2700

13000

9200

2300

6500

7200

ANTI

MONY,

TOTAL

(UG/L

AS SB) 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0


ta,

Station 03201722, Sandy Run below Hull Hollow Creek near Lake Hope, Ohio

water years 19

79 and

1980 Continued

BERYL

LIUM,

TOTAL

ARSENIC

RECOV-

TOTAL

ERABLE

(UG/L

(UG/

LDATE

water

OCT 13..

.2*». .

.NOV 06.

. .

21...

30...

DEC 21...

JAN04...

16...

FE8 01...

15...

27...

MAR 13...

26...

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 09...

26...

AUG 08. ..

23...

SEP 05...

17...

AS AS)

AS

year

1979

0 0 0 0 0 1 1 1 0 0 0 1 1 0 0 1 0 0 1 2 2 2 3 0 0

BE) 0 10 10 b 0 0 10 0 10 10 0 0 0 0 0

100 0 10 0

10 10 0 0 10

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD

) 7 12 143 3 3 1 1 6 119

1 1 7 13 4 2 10 0 0 0 1 1 0 0

CHRO

MIUM

*TOTAL

RECOV-

ERABLt

(UG/L

AS CR

) 0 1 3 4 2 1 0 b 0 2 2 0 0 6 6 4 11 b V

16

17 14 1 0 5

COPPER*

TOTAL

RECOV

ERABLE

(UG/

LAS

CU

) 620 12 7 4 7 5 4 4 8 5 6 <t 3 5 b 6 5 9 6 0 14 5 8 7

IRON

, TOTAL

RECOV

ERABLE

(UG/

LAS

FF

.)

2200

5400

3600

6000

4900

3500

5500

4700

5900

8400

3900

77JO

3800

3000

6100

3700

5700

5300

4300

1200

24000

6100

3800

*200

12000

IRON,

SUS-

PENOEU

RECOV

ERABLE

(UG/

LAS

FE

) -- -- --

1800

1400

IbOO

3000

300

870 0 0

1700 --

IRON

, DIS

SOLVED

(UG/L

AS FE)

500

5000

3500

4500

2800

1200

3700

2300

3900

7900

2000

7000

1500

680

4300

2300

4100

2300

4000

330

24UOO

6100

2100

3700

3400

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 43 71

200 22 22 10 11 16 934

220 10 16 60 170 37 16 423 4 2 6 6 10 4

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

1600

5600

4600

3000

1900

710

1000

880

1300

2000

600

1300

830

720

1300

1400

1400

1100

2700

1400

5500

4900

1400

3000

2000

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/L

AS MN) --

. --

100 0 0 0 0 0 0

300

100

300

100


ta,

Station 03201722, Sandy Run below Hull Hollow Creek near Lake Hope, Ohio

water years 19

79 and

1980 Continued

DATE

WATER

OCT 13...

24...

NOV 06.

. .

21...

30...

DEC 21...

JAN 04...

16...

FEB 01...

15...

27...

MAR 13...

26.. .

APR 11...

30...

MAY 15...

30...

JUN 11...

28...

JUL 09...

26...

AUG 08...

23...

SEP 05...

17...

MANGA-

MERCURY

NESE*

TOTAL

DIS-

RECOV-

SOLVED

ERABLE

(UG/

L (UG/L

AS MN

) AS

HG)

YEAR 1979

1600

<.5

5600

<.5

10

<.5

2400

<.5

1900

<,5

710

<.5

1000

<.b

880

<.5

1300

<.5

2000

<.5

600

<.5

1300

<.5

830

<.5

720

<.5

1200

<.5

1400

<.5

1400

<.5

1100

<.b

2700

<.5

1400

<.5

5500

<.5

4600

<.5

1300

<.5

2700

<.5

1900

<.5

NICKEL*

TOTAL

RECOV

ERABLE

(UG/

LAS

NI) 49 150

150 81 53 36 44 19 39 76 32 57 34 46 70 76 43 48 90 580

100 26 75 79

SELE

NIUM*

TOTAL

(UG/L

AS SE) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

SILVER*

TOTAL

RECOV

ERABLE

(UG/L

AS AG) 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0

ZINC*

SUS

PENDED

RECOV

ERABLE

(UG/

LAS

ZN) -- 20

0 0

100

30 30

0 0 040

ZINC*

DIS

SOLVED

(UG/

LAS

ZN) bO

3bO

310

130

100 bO 90 90 80 140 30

300 70 70 120

120

120 60 190

120

330

260 70 180

130

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 90

350

320

160

100

110

90 110

60 190 60

300 70 70 140

120

120 70 190

150

360

260 70 180

170

CARBON*

ORGANIC

DIS

SOLVED

(MG/L

AS C) 4.3

1.9

1.1

2.3 .8

3.7

1.2

2.9

2.2

1.0

8.7

2.9

1.4

3.9

1.4

4.6

1.7

1.8

6.7

2.0

3.4

1.8

4.?

2.4

3.8

CARBON*

ORGANIC

SUS

PENDED

(MG/

LAS C)

.8 .4 .1 .3 .2 .7 .0 .2 .1 -- -- .2 .2 .2 .1 .1 .2 .1 .3 .0 .1 .5 .1 .0

PHENOLS

(UG/

L)

1 0 0 0 4 3 3 0 0 0 0 4 2 0 0 1 0 0 0 0 0 0 0 2480



vo

en

SPE

CIFIC

CON

DUCT

ANCE

PH

TIME

(MICRO-

DATE

MHOS)

(UNI

TS)

WATER YEAR 1980

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

28...

MAR 12..

.25...

APR 08...

24...

MAY 09...

23...

JUN 12..

.24...

JUL 10..

.21...

AUG 06...

19..

.SEP 08...

22...

IbOO

1515

1600

1300

1100

1430

1630

1015

1130

1300

1300

1030

1545

1030

1030

1230

1130

1200

0930

1230

1530

1100

1600

1200

490

725

245

475

460

340

460

385

540

380

270

280

370

330

340

490

490

890

315

720

690

420

750

830

3.9

3.3

5.6

3.8

3.9

4.5

4.0

4.2

3.7

4.2

5.0

5.2

4.5

4.7

3.8

4.1

4.2

3.4

7.3

3.7

3.5

5.8

3.4

4.0

OXYGEN

DEMAND t

CHEM-

TEMPER-

ICAL

ATURE*

(HIGH

WATER

LEVEL)

(DEG

C)

(MG/

L)

15.5

11.5 a.o

7.5

5.5

2.5 .5 .0 .5 .5

2.0

5.5

12.0

10.0

6.0

15.0

12.5

17.5

17.5

23.0

24.0

20.0

20.0

17.0

18 6

96 48 13 14 5 13 20 81 85 to 157

-- 18 -- 16 3 12 -- lb

HARD-

HAtfD-

NESS*

ACIDITY

NESS

NONCAR-

TOTAL

(MG/L

BONATE

HEATED

AS

(MG/

L (MG/L

CACQ3)

CAC03)

AS H)

160

20U 97 150

150

130

160

150

180

140

110

110

130

120

180

160

170

280

120

230 160

270

26U

160

200 91 150

150

130

lt>0

150

180

140

110

110

130

120

180

160

170

280

110

230 --

150

270

1.6

1.7

.9

1.2 .6

1.2 d

1.4 .8 -- .8 .5

1.2

1.2

1.4

2.8 1.7

1.4 .3

2.0

2.2

CALCIUM

ACIDITY

OIS-

(MG/L

SOLVED

AS

(MG/L

CAC03)

AS CA)

79 84

45

60 30

60

<*0

70

40

--

40 25

60

60 70

139

84 70 15 99

109

34

47

24 35

3t>

31 37 36

42 34 27 26 30 29

40 36 40 63 30 52

--

39 63 58

MAGNE

SIUM,

DIS

SOLVED

(MG/L

AS MG)

17 21

*.i

16 16 13 1615

18

14

11 11 13 12 19 16 18 29 11 24

15 28 27


ta.

Station 03201722,

Sandy Run below Hull Hollow Creek near Lake Ho

pe,

Ohio

water years 1979 an

d 1980 continued

vo

SODIUM*

SODIUM

POTAS-

SOOIUMt

AD-

SIUM

OIS-

SORP-

DIS

SOLVED

TION

SOLVED

(MG/L

SODIUM

RATIO

(MG/L

DATE

AS NA)

PERCENT

AS NA)

POTAS-

CARBON

SIUMt

8ICAH-

ALKA-

DIOXIDE

DIS-

BONATE

CAR-

LINITY

DIS

SOLVED

(MG/L

BONATE

(MG/L

SOLVED

(MG/L

AS

(MG/L

AS

(MG/L

AS K)

HC03)

AS C03)

CAC03)

AS C02)

SULFATE

DIS

SOLVED

(MG/L

AS S04)

CHLO-

RIDtt

DIS

SOLVED

(MG/L

AS CD

WATER YEAR

1980

02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10...

24...

FEB 12...

28...

MAR 12...

25...

APR 08...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG06...

19...

SEP 08.. .

22...

7.9

12 5.8

9.5

10 7.4

8.7

7.9

9.9

8.7

5.8

5.4

7.6

7.0

11 9.4

11 15

7.3

16

10 13 15

10 18 16 19 20 17 17 16 11 12 10 9

12 11 12 11 12 10 11 13 12 911

.3 .4 .3 .3 .4 .3 .3 .3 .3 .3 .2 .2 .3 .3 .4 .3 .4 .4 .3 .5 .3 .3 .4

10 15

9.2

11 12 8.9

11 9.7

12 10 6.9

7.0 -- --

-- -- --

2.4

3.2

3.4

1.8

1.8

1.5

1.8

1.8

1.7

1.5

1.1

1.6

1.6

2.0

2.0

2.9

2.3

2.9

2.2

3.3

2.5

2.9

3.5

0 0 8 0 0 0 0 0 0 0 2 6 0 0 0 0 0 0

160 0 7 0

0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0

0 0 7 0 0 0 0 0 0 0 2 5 0 0 0 0 0 0

150 0 6 0

.0 .0

32.0 .0 .0 .0 .0 .0 .0

32

61

.0 .0 .0 .0 .0 .0

1.4 .0 .0

18

.0 --

200

260 94

190

160

150

210

180

230

180

120

100

160

150

220

190

220

360

120

290

--

170

310

370

o.l

7.7

3.9

6.5

t>. 2

5.6

7.5

6.5

7.2

7.4

5.8

4.9

5.1

5.5

7.2

7.1

9.1

10 5.2

5.1 --

7.0

9.3

10


water years 19

79 and

1980 Continued

DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10..

.24...

FEB 12..

.28...

MAR 12..

.25...

APR 08...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06..

.19

...

SEP 08...

22...

SOLIDS*

RESIDUE

AT

ItiO

DEG.

CDIS

SOLVED

(MG/

L)YEAR 1980

325

410

170

292

281

236

310

284

J72

283

189

196

253

236

392

320

363

614

230

508

303

545

625

SOLIDS*

DIS

SOLVED

(TONS

PER

AC-FT)

.44

.56

.23

.40

.38

.32

.42

.39

.51

.38

.26

.27

.34

.32

.53

.44

.49

.84

.31

.69

.41

.74

.85

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .0

9,0

2

.20 .15

,14

,11

,11

.08

,19

.16

.16

.11

.10 .13

.19

.20 ,14 .18

NITRO-

GEN»AM-

MONIA

*ORGANIC

TOTAL

(MG/

LAS

N) .2

2.3

5

1.4 .17

.20

. 13

.36

.39

.21

.06

.11

.14

.19

.84

.13

.16

.11

.09

NITRO

GEN*

TOTAL

(MG/L

AS N) .3

1.3

7

1.6

.32

.34

.24

.49

.47

.40

.22

.27

.25

.29 .97

.32

.36 .25

.27

NITRO

GEN*

TOTAL

(MG/

LAS

N0

3)

1.4

1.6

f . 1

1.4

1.5

1.1

2.2

2.1

1.8 .97

1.2

1.1

1.3

4.3

1.4

1.6

1.1

1.2

PHOS

PHORUS*

TOTAL

(MG/

LAS

P) .030

.000

.220

OU

O.0

10

.000

.010

.010

.010

.010

.010

.020

.010

.030

.010

.010

.010

.010

PHOS

PHORUS*

TOTAL

(MG/L

AS P0

4) .09

.00

.67 .00

.03

.00

.03

.03

.03

.03

.03

.06

.03 .09 .03

.03

.03 .03

ALUM

INUM*

TOTAL

RECOV

ERABLE

(UG/L

AS AL)

4UOO

4200

1UOOO

2900

3300

3200

390U

3f 00

4JOO

3400

290

1000

^900

2100

340U

9000

IbOO

610

ANTI

MONY *

TOTAL

(UG/L

AS SB) 0 0 0 0 6 0 0 0 0 0 0 0 0 0

. ~

.

ARSENIC

TOTAL

(UG/L

AS AS) 2 1 2 1 0 0 0 0 2

. 1 1 0 1 0

, . .

. -- .

-- -_


Station 03201722,

Sandy Ru

n below Hull Hollow Creek ne

ar Lake Hope,

Ohio

water

year

s 1979 and

1980 Continued

vo 00

BERY

L-LI

UM*

CADMIUM

DATE

WATER

OCT 02..

.23

...

NOV 09...

20...

DEC 06...

20...

JAN 10..

.24

...

FEB 12..

.28

...

MAR

-12

...

25..

.AP

R 08...

24...

MAY 09...

23..

.JU

N 12...

24...

JUL 10...

21...

AUG 06...

19..

.SE

P 08...

22...

TOTA

LRE

COV

ERABLE

(UG/L

AS BE)

YEAR 19

80

10 10 0 0 10 10 20 10 100 0 0 10 0

-- -- -- -- -- --

TOTAL

RECOV

ERABLE

(UG/

LAS CD

) 0 1 0 0 0 0 0 0 0 2 0 0 0 0

-- -- -- --

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/

LAS

CR) 12 15 203 6 4 7 1

53 12 2 4 4 3

-- -- -- -- -- --

COPPER*

TOTAL

RECOV

ERABLE

(UG/

LAS CU) 7 7 15 4 3 4 5 4 4 3 4 2 7 to

*"

--

-- --

IRON*

TOTAL

RECOV

ERABLE

(UG/L

AS Ft)

21000

5900

25000

4200

5700

3300

6000

5*00

4600

6500

3000

2/00

9100

2700

2200

t>500

1900

3500

2600

10000

1300

1500

2300

IRON*

SUS

PENDED

RECOV

ERABLE

(UG/L

AS F£) -- --

--

2400

3400

4000

1200

<f300

2400

2000

7000

2200

600

4600

900 0

2000

9000 --

840 0

IRON*

DIS

SOLVED

(UG/L

AS F£)

15000

5400

460

IdOO

2800

U90

2600

1400

3400

2200

640

670

2100

550

1600

1900

1000

3500

630

1000

--

660

2300

1600

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 2 0

100 0 1 2 0 0

14 4 0 0 1 0 1 2 6 2 0 9 6 3--

MANGA

NESE.

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

2000

2300

990

1600

1500

1300

1700

1/00

2100

1400

980

b20

1200

1300

2000

1900

2400

4100

1500

3900

3600

2100

4<»00

MANGA

NESE*

SUS

PENDED

RECOV.

(UG/L

AS Mi

M)

200 0

220 0 J 0 0 0 0 0 0 0 0

100 0

100 0 0 0 0

-- 100

100

MANGA

NESE*

DIS

SOLVED

(UG/L

AS MN

)

1600

<f300

770

1600

1500

1300

1700

1700

2100

1400

980

820

1200

1200

2000

1800

2400

4100

1500

3900 --

2000

4300

5300

Appendix 9.--Water-quality data, Station 03201722, Sandy Run below Hull Hollow Creek near Lake Hope, Ohio

water years 1979 an

d 1980 Continued

MERCURY

NICKEL,

TOTAL

TOTAL

NECOV-

RECOV

ERABLE

ERABLE

DATE

WATER

OCT 02...

23...

NOV 09...

20...

DEC 06...

20...

JAN 10..

.24...

FEB 12...

28...

MAR 12..

.25...

APR 08...

24...

MAY 09...

23...

JUN 12...

24...

JUL 10...

21...

AUG 06...

19...

SEP 08...

22...

(UG/L

AS HG

)YEAR 1980

<.b

<.l .1

<.l

1.0 .1

<.l .4

<.l .3 .1 .1 .1

<.l .3

(UG/L

AS NI) 49

60

35

39

45

26 39 36 48 29 25

23 31 25 -- 22 - --

SELE

NIUM*

TOTAL

(UG/L

AS SE) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

-- -- --

SILVER*

TOTAL

RECOV

ERABLE

(UG/L

AS AG) 0 0 0 0 0 0 0 0 0 0 0 0 0 0

--

ZINC,

SUS

PENDED

RECO

V

ERAB

LE(UG/L

AS ZN) 100

6020 0 0 0 0 0 0 0 0 010 0

0 0 -- lu

ZINC*

DIS

SOLVED

(UG/

LAS

ZN)

110

lt>0 40 70 130

100

110

120

130 90 SO 120 70 50 120

160 yo

210 50

280 --

60 20

230

ZlNCf

TOTAL

RECOV

ERABLE

(UG/L

Ab ZN)

120

160

100 90 130

100

110

120

130 90 50 120 70 60

160

--

210 50 -- 70 --

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS O 3.5

1.5

6.2

4.6

4.3

2.9

4.3

4.2

1.4

1.9

1.2

3.5

2.1

4.0 ~

3.5 --

9.2

1.2

2.9 -- 1.7

CARBON*

ORGANIC

SUS

PENDED

(MG/L

AS C) 1.

0 .1

100.2 .4 .2 .1 .5 -- .2 .4 .8 .3 .2 -- 1.0 .2 .r -- .5 --

PHENOLS

(UG/

L)

0 0 0 4 0 0 0 0 0 0 0 7 0 0

-- -- --

Appendix

10. Water-quality data, well RM-1 in Big Four

June 26

, 1980

Hollow near Lake Hope, Ohio,

DATE

JUN

26...

SPE-

OXYbEN

CIFIC

DEMAND,

HARD-

MAGNE-

CON-

CHEM-

HARD-

NESS,

ACIDITY

CALCIUM

SIUM,

DUCT-

TEMPER-

ICAL

NESS

NONCArt-

TOTAL

ACIDITY

DIS-

DIS-

ANCE

PH

ATURE,

(HIGH

(MG/L

BONATE

HEATED

(MG/L

SOLVED

SOLVED

TIME

(MICRO-

WATER

LEVEL)

AS

(MG/L

(MG/L

AS

(MG/L

(MG/L

MHOS)

(UNITS)

(DEG C)

(MG/L)

CAC03)

CAC03)

AS H)

CAC03)

AS CA

) AS MG

)

1200

6700

2.4

18.0

190

720

720

94

46fO

39

150

DATE

JUN

26...

SODIUM,

DIS

SOLVED

(MG/L

AS NA

)SODIUM

PERCENT

DATE

JUN

26...

DATE

23.7

SODIUM

AD

SORP

TION

RATIO .3

POTAS

SIUM,

BICAR-

DIS-

BONATE

SOLVED

(MG/L

AS K) 2.2

(MG/L

AS

HC03)

CAR

BONATE

(MG/L

AS C03)

ALKA

LINITY

(MG/L

AS

CAC03)

CARBON

DIOXIDE

Dlb-

SOLVED

(MG/L

AS C02)

SULFATE

DIS

SOLVED

(MG/L

AS S04)

CHLO

RIDE,

DIS-

bOLVEO

(MG/L

AS CL)

SOLIDS,

RESIDUE

AT IbO

DEG. C

DIS

SOLVED

(MG/L)

.15300

.02

1.9

1.9

b.5

.290

.89

180000

520000

.217400

SOLIDS,

DIS

SOLVED

(TONS

PER

AC-FT)

NITRO

GEN,

N02+N03

TOTAL

(Mb/L

AS N)

NITRO

GEN, AM

MONIA

+ORGANIC

TOTAL

(MG/L

AS N)

NITRO

GEN,

TOTAL

(MG/L

AS N)

NITRO

GEN,

TOTAL

(MG/L

AS N03)

PHOS

PHORUS,

TOTAL

(MG/L

AS P)

PHOS

PHORUS,

TOTAL

(MG/L

Ab P04)

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS AL

)

IRON,

TOTAL

MECOV-

tRABLE

(UG/L

AS FE

)

IRON,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

)

IRON,

DIS

SOLVED

(UG/L

AS FE)

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS Pb

)

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/L

AS MN

)

MANGA

NESE,

DIS

SOLVED

(UG/L

AS MN

)

ZINC,

SUS-

PENUEJ

RECOV

ERABLE

(UG/L

AS ZN)

ZINC,

DIS-

bOLVED

(UG/L

AS ZN

)

ZINC,

TOTAL

RECOV-

ERAbLE

(UG/L

AS ZN

)

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C)

CARBON,

ORGANIC

SUS

PENDED

(Mb/L

AS C)

JUN

26...

520000

90

13000

12000

1400

4100

4100

4.b

.8


ta,

surface mine seep 15

(392218082191500) in

Big Four Hollow

near Lake Hope,

Ohio,

April 8

and 25

, 1980

DATE

APR

08...

25...

TIME

1345

1100

STRE

AM-

FLO*

*INSTAN

TANE

OUS

(CFS)

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS)

TEMPER-

PH

ATURE,

WATER

(UNITS)

(DEG C)

OXYGEN

DEMAND,

CHEM

ICAL

(HIGH

LEVEL)

(MG/L)

HARD

NESS

(MG/L

AS

CAC03)

HARD

NESS,

NONCAR-

BONATE

(MG/L

CAC03)

CALCIUM

DIS

SOLVED

(MG/L

AS CA

)

MAGNE

SIUM,

DIS

SOLVED

(MG/L

AS MG

)

SODIUM*

DIS

SOLVED

(MG/L

AS NA

)

.01

DATE

APR

08...

25...

DATE

APR

08...

25...

SODIUM

PERCENT

.26

.24

360

310

6.0

b.9

8.b

9.t>

43

23

89

13 820

2U

11

.a4.6

4.4

100 93

82

ttO

160

197

11U

65

1.6

1.3

4.0

3.7

SODIUM

AD

SORP

TION

RATIO

POTAS

SIUM*

DIS

SOLVED

(MG/L

AS K)

BICAR

BONATE

(MG/L

AS

HC03)

CAR

BONATE

(MG/L

AS C03)

ALKA

LINI

TY(MG/L

AS

CAC03)

CARBON

DIOXIDE

DIS

SOLVED

(M6/L

AS C02)

SULFATE

DIS

SOLVED

(MG/L

AS S04)

CHLO

RIDE*

DIS

SOLVED

(MG/L

AS CD

SOLIDS,

RESIDUE

AT IdO

DEG. C

Dlb-

SOLVED

(MG/L)

194

178

SOLIDS,

DIS

SOLVED

(TONS

PER

AC-F

T)

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N)

NITRO

GEN, AM

MONIA

*ORGANIC

TOTAL

(MG/L

AS N)

NITRO

GEN,

TOTAL

(.MG/L

AS N)

NITRO

GEN,

TOTA

L(MG/L

AS N03)

PHOS

PHORUS,

TOTAL

(MG/L

AS P)

PHOS

PHORUS,

TOTAL

(MG/L

AS P04)

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS AL)

ANTI

MONY,

TOTAL

(UG/L

AS SB)

ARSENIC

TOTAL

(UG/L

AS AS

)

.00

.00

.40

.49

.40

a.a

.910

.160

2.8

.49

900

300

Appendix 11. Water-quality data, surface mine seep 15

(392218082191500) in Big Four Hollow

near Lake Hope, Ohio, April 8

and 25,

1980 Continued

ta (O

DATE

APR

08...

25...

DATE

APR

08...

25...

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS BE) 0 0

MANGA

NESE,

DIS

SOLVED

(UG/L

AS MN)

7600

6700

CADMIUM

TOTAL

RECOV

ERABLE

(UG/

LAS

CD) 0 0

MERCURY

TOTAL

RECOV

ERABLE ̂

(UG/L

AS HG

) .2 .1

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR

) 7 4

NICKEL*

TOTAL

RECOV

ERABLE

(UG/L

AS NI

) 10 5

COPPER,

TOTAL

RECOV

ERABLE

(UG/L

AS CU

) 5 0

SELE

NIUM,

TOTAL

(UG/L

AS SE) 0 0

IRON*

TOTAL

RECOV

ERABLE

(UG/

LAS

FE

)

33000

26000

SILVER*

TOTAL

RECOV

ERABLE

(UG/

LAS

AG) 0 0

IRON*

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

) 0 0

ZINC*

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN) 309

IRON,

DIS

SOLVED

(UG/L

AS KE)

33000

26000

ZINC,

DIS

SOLVED

(UG/L

AS ZN) 0 1

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS P3) 2 2

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 30 10

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

7oOO

6700

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C) 8. 6

3.1

MANGA

NESE*

SUS

PENDED

RECOV.

(UG/L

AS MN) 0 0

PHENOLS

(UG/L)

7 2

Appendix 12. Water-quality data, surface mine seep 16 (392218082191600) near Lake Hope, Ohio,

March 17

and 25,

1980

ts>

LJ

DATE

MAR 17...

APR 08...

25...

DATE

MAR 17...

APR 08...

25...

DATE

MAR 17...

APR 08...

25...

TIME

1100

1330

1200

SODIUM

PERCENT 5 5 4

SOLIDS.

DIS

SOLVED

(TONS

PER

AC-FT)

.31

.36

<.38

STREAM-

FLOW*

INSTAN

TANE

OUS

(CFS

) .01

<.01

SODIUM

AD-

SORP-

TION

RATIO .1 .1 .1

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .0

3

.00

.00

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS) 400

450

335

SODIUM*

POTAS

SIUM

DIS

SOLVED

(MG/

LAS

NA

)

8.6 ----

NITRO-

GEN»AM-

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) .6

7

.77

.56

PH

(UNITS)

6.2

6.1

6.1

POTAS

SIUM*

DIS

SOLVED

(MG/L

AS K) 4.7

6.3

6.3

NITRO

GEN*

TOTAL

(MG/L

AS N) .7

0

.77

.56

TEMPER

ATURE*

WATER

(DEG

C)

9.b

9.5

10.0

BICAR

BONATE

(MG/

LAb

HC03

) 177

150

170

NITRO

GEN*

TOTAL

(MG/

LAS

N0

3)

3.1

3.4

2.5

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LEVEL)

(MG/

L)

36 48 40

CAR-

bONATE

(MG/

LAS

C0

3)

0 0 0

PHOS

PHORUS*

TOTAL

(MG/

LAS

P) .060

.030

.050

HARD

NESS

(MG/L

ASCAC03)

140

160

160

ALKA

LINITY

(MG/L

ASCAC03)

150

120

140

PHOS

PHORUS*

TOTAL

(MG/L

AS P0

«*>

.18

.09

.16

HARD

NESS*

NONCAR-

BONATE

(MG/L

CAC03) 0

40 4b

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C0

2)

179

191

170

ALUM

INUM*

TOTAL

RECOV

ERABLE

(UG/L

AS AL)

1500

600

200

CALCIUM

DIS

SOLVED

( rtG

/LAS CA)

3b 39 39

SULFATE

DIS

SOLVED

(MG/L

AS S04)

85 110 89

ANTI

MONY*

TOTAL

(UG/L

AS SB) 0 0 0

MAGN

E

SIUM*

DIS-

bOLVED

(MG/L

AS MG)

U 16 14

CHLO

RIDE*

DIS

SOLVED

(MG/L

AS CL)

1.5

2.0

1.7

ARSENIC

TOTAL

(UG/L

AS AS) 2 2 1

SODIUM*

DIS

SOLVED

(MG/L

AS NA)

3.9

3.7

3.3

SOLIDS*

RtSlUUE

AT 160

DEG. C

DIS

SOLVED

(MG/

L) 226

265

279

BERYL

LIUM*

TOTA

LRECOV

ERABLE

(UG/L

AS BE) 0 0 0

Appendix 12. Water-quality data, surface mine seep 16

(392218082191600) near Lake Hope, Ohio,

March 17

and 25,

1980 Continued

DATE

MAR 17...

APR 08...

25...

DATE

MAR 17...

APR 06...

26...

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD) 0 0 0

MERCURY

TOTAL

RECOV

ERABLE

(UG/L

AS HG) .2 .1 .2

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR) 10 3 4

NICKEL*

TOTAL

RECOV

ERABLE

(UG/

LAS

NI) 9 3 1

COPPERt

TOTAL

RECOV

ERABLE

(UG/

LAS

CU

) 1 5 1

SELE-

NlUMt

^TOTAL

(UG/

LAS

SE

) 0 0 0

IRON*

TOTAL

KECOV-

tRABLE

(UG/L

AS FE

)

32000

29000

23000

SILVER*

TOTAL

RECOV

ERABLE

(UG/L

AS AG

> 0 0 0

IRON

*SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

) 0 0 0

ZINC,

SUS

PENDED

RECOV

ERABLE

(UG/

LAS

ZN) 0 10 7

IRON*

DIS

SOLVED

(UG/

LAS

FE

)

32000

29000

23000

ZINC,

DIS

SOLVED

(UG/L

AS ZN

) 30

0 3

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 3 1 0

ZINC,

TOTAL

RECOV

ERABLE

(UG/L

AS ZN) 30 10 10

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

4900

6600

6BOO

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C) d.O

b.3

6.1

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/

LAS

MN) 0 0 0

CARBON,

ORGANIC

SUS

PENDED

(MG/L

AS C) 2.2 .5 .t>

MANGA

NESE,

DIS

SOLVED

(UG/L

AS MN)

4900

6600

6800

PHENOLS

(UG/L)

0 0 0

Appendix 13. Water-quality, mine entrance 88

, above Big Four Hollow Creek near Lake Hope, Ohio


DATE

WATER

OCT 13..

OCT 25..

JAN 04..

MAR 13..

MAY 30..

DATE

OCT 12..

OCT 25..

JAN 04..

MAR 13..

MAY 30..

TIME

YEAR 19

79

1500

1300

1700

1500

1430

SOOIUMt

DIS

SOLVED

(MG/

LAS

NA)

21 21 15 16 21

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS)

4000

2500

2300

5400

SODIUM

PERCENT 3 3 4 3 4

PH

FIELD

(UNI

TS)

2.5

2.2

2.9

2.8

2.8

SODIUM

AD

SORP

TION

RATIO .2 .2 .2 .2 .3

TEMPER

ATURE.

WATER

(DEC

C)

15.0

11.0

10.5

11.0

11.0

POTAS

SIUM*

DIS

SOLVED

(MG/L

AS K)

-

2.2

2.6

3.2

2.6

1.5

OXYGEN

DEMAND.

CHEM

ICAL

(HIGH

LEVEL)

(MG/

L)

_ _

130 36 53 85

BICAR

BONATE

(MG/

LAS

HC03)

0 0 0 0 0

HARD

NESS

(MG/L

AS

CAC03)

1500

1700

800

1000

1100

CAR

BONATE

(MG/L

AS C0

3)

0 0 0 0 0

HARD

NESS,

NONCAR-

BONATE

(MG/

LCAC03)

1500

1700

800

1000

1100

ALKA

LINITY

(MG/

LAS

CAC03) 0 0 0 0 0

ACIDITY

TOTAL

HEATED

(MG/L

AS H)

56 39 16 21 36

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C02) .0 .0 .0 .0 .0

ACIDITY

(MG/L

AS

CAC03)

2780

1940

794

1040

1790

SULFATE

DIS

SOLVED

(MG/L

AS S04)

3200

3400

1500

1800

3700

CALCIUM

DIS

SOLVED

(*G/L

AS CA)

290

320

160

200 58

CHLO

RIDE,

DIS

SOLVED

(MG/L

AS CD

1.3

1.5

1.4

1.1

1.5

MAGNE

SIUM,

DIS

SOLVED

(MG/L

AS MG)

190

230 86 130

230

SOLIDS,

RESIDUE

AT 180

DEG. C

DIS

SOLVED

(MG/

L)

4990

5760

2240

3080

6050

Appendix 13. Water-quality, mine entrance 88,

above Big Four Hollow Creek near Lake Hope,

Ohio

water years 19

79 and 1980 Continued

DATE

WATER

OCT 12...

OCT 25..

.JAN 04...

MAR 13...

MAY 30...

DATt

OCT

12.

OCT 25..

.JAN 04..

.MAR 13...

MAY 30..

.

SOLIDS.

DIS

SOLVED

(TONS

PER

AC-FT)

YEAR 1979

6.79

7.83

3.05

4.19

8.23

BERYL

LIUM.

TOTAL

RECOV

ERABLE

(UG/

LAS BE

)

600

70 30 40 80

NITRO

GEN.

N02+N03

TOTAL

(MG/L

AS N) .0

1

.00

.00

.00

.00

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD) 2 1 0 0 1

NITRO

GEN.

AM

MONIA +

ORGANIC

TOTAL

(MG/

LAS N) 1.4

1.5 .74

.84

1.3

CHRO

MIUM

.TOTAL

RECOV

ERABLE

(UG/

LAS

CR) 3 2 0 2 18

NITRO

GEN.

TOTAL

(MG/L

AS N) 1.4

1.5 .74

.84

1.3

COPPER.

TOTAL

RECOV

ERABLE

(UG/

LAS

CU) 61 95 32 44

210

NITRO-

GtN,

TOTAL

(MG/

LAS

N0

3)

6.2

6.6

3.3

3.7

5.8

IRON.

TOTAL

RECOV

ERABLE

(UG/L

AS FE)

460000

730000

230000

310000

630000

PHOS

PHORUS.

TOTAL

(MG/

LAS

P) .020

.090

.020

.010

.030

IRON.

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

) _ _

0

PHOS

PHORUS.

ORTHOPH

OSPHATE

TOTAL

(MG/L

AS P0

4) -- -- .09

IRON,

DIS

SOLVED

(UG/L

AS FE)

440000

720000

230000

310000

630000

PHOS

PHORUS,

TOTAL

(MG/

LAS

P0

4) _ _

-- .09

LEAD

,TO

TAL

RECOV

ERABLE

(UG/

LAS PB) 9

23

0

22

0

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS AL) 0

1400

0

32000

53000

110000

MANGA

NESE

,TOTAL

RECOV

ERABLE

(UG/

LAS MN)

19000

1600

6600

8800

17000

ANTI

MONY

,TO

TAL

(UG/

LAS

SB) 1 1 0 0 0

MANGA

NESE.

SUS

PENDED

RECOV.

(UG/L

AS MN

) _. --

--

0

ARSENIC

TOTAL

(UG/

LAS AS) 1 1 1 2 2

MANGA

NESE

.DIS

SOLVED

(UG/

LAS MN)

19000

1600

6600

8800

.

17000


above Big Four Hollow Creek near Lake Ho

pe,

Ohio

,


DATE

WATER

OCT 12...

OCT 25..

JAN 04..

MAR 13..

MAY 30..

DATE

WATER

NOV 20..

MAR 14..

25..

APR 07..

24..

MAY 02..

22..

MERCURY

TOTAL

RECOV

ERABLE

(UG/L

AS HG)

YEAR 1979

> *

. <.

5 .6

. ^ . 3

. ^ . 3

TIME

YEAR 1980

1500

1330

1300

1300

1300

1430

1430

NICKEL,

TOTA

LRECOV

ERABLE

(UG/L

AS NI)

100 61 110 66 39

SPE

CIFIC

CON

DUCT

ANCE

(MIC

RO-

MHOS)

4500

5200

5600

5400

5500

5600

5500

SELE

NIUM,

TOTAL

(UG/L

AS SE

) 0 2 0 0 2

PH

(UNITS)

2.9

4.5

3.6

3.5

3.6

3.6

3.5

SILVER,

TOTAL

RECOV

ERABLE

(UG/L

AS AG) 0 0 0 0 0

TEMPER

ATURE*

WATtR

(DEG C)

12.0

7.0

a.o

9.0

tt.5

9.0

11.0

ZINC

, SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN)

« _ --

0

OXYGEN

DEMAND,

CHtM-

ICAL

(HIGH

LEVEL)

(MG/

L) 160

300

240

230

230 --

ZINC,

DIS

SOLVED

(UG/

LAS ZN)

2000

300

760

1100

2500

HARD

NESS

(MG/L

ASCAC03)

1100

1200

170U

1600

2500 --

ZINC

, TOTAL

RECOV

ERABLE

(UG/L

AS ZN)

2000 300

760

1100

2500

HARD

NESS

,NONCAR-

BONATE

(MG/

LCA

C03)

1100

1200

170U

1600

2500 --

CARBON,

ORGANIC

DIS

SOLVED

(MG/L

AS C)

.2

3.5

1.4

2.1

9.4

ACIDITY

TOTAL

HEATED

(MG/L

AS H)

64 <*3

46 49

50

6256

CARBON,

ORGANIC

SUS

PENDED

(MG/L

AS C)

.8 .3 .3 .2 .2

ACIDITY

(MG/L

AS

CAC03)

31«0

2140

2280

2430

2460

3oao

2860

PHENOLS

(UG/L) 1 0 2 0 0

CALCIUM

DIS

SOLVED

(MG/L

AS CA)

140

72 170

150

190

MAGNE

SIUM

,DIS

SOLVED

(MG/L

AS MG

)

190

250

310

290

490

--


above Big Four Hollow Creek near Lake Hope,

Ohio


IS)

00

DATE

WATER

NOV 20...

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

DATE

NOV 20...

MAR 14..

.25

...

APR 07...

24...

MAY 02...

22..

.

SODIUM*

DIS

SOLVED

(MG/

LAS

NA

)YE

AR 1980

25 242*

24

23

--

SOLIDS*

RESIDUE

AT 180

OEG. C

DIS

SOLVED

(MG/L)

5110

7960

7900

8020

8330 --

SODIUM

PERCENT 13 4 3 3 2

--

SOLIDS*

DIS

SOLVED

(TONS

PER

AC-FT)

6.95

10.8

10.7

10.9

<11.3 --

SODIUM

AD

SORP

TION

RATIO .3 .3 .3 .3 .2

NITRO

GEN*

N02+N03

TOTAL

(MG/L

AS N) .04

.0*

.18

.09

.15

SODIUM*

POTAS

SIUM

DIS

SOLVED

(MG/L

AS NA)

27

32 --

NITRO-

GEN»AM-

MONIA

+ORGANIC

TOTAL

(MG/L

AS N) 1.4

2.4

1.9

1.8

2.2 --

POTAS

SIUM,

DIS

SOLVED

(MG/L

AS K) 2.2

8.2

8.6

8.7

8.1

NITRO

GEN,

TOTAL

(MG/L

AS N) 1.4

2.4

2.1

1.9

2.4

BICAR

BONATE

(MG/L

AS

HC03)

0 0 0 0 0 0 0

NITRO

GEN*

TOTAL

(MG/L

AS N03)

6.4

11 9.2

8.4

10

--

CAR

BONATE

(MG/L

AS C03) 0 0 0 0 0 0 0

PHOS

PHORUS*

TOTAL

(MG/L

AS P) .730

.050

.120

.060

.060

ALKA

LINITY

(MG/L

AS

CACU3) 0 0 0 0 U 0 0

\

PHOS

PHORUS,

TOTAL

(MG/L

AS P04)

2.2 .15

.37

.18

.Id --

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C02) .0 .0 .0 .0 .0 .0 .u

ALUM

INUM*

TOTAL

RECOV

ERABLE

(UG/L

AS AL

)

73000

110000

120000

100000

120000 ----

SULFATE

DIS

SOLVED

(MG/L

AS S04)

3300

4700

4600

4800

b500

b300

b200

ANTI

MONY ,

TOTAL

(UG/L

AS SB

) 0 0 0 0 0

--

CHLO

RIDE,

DIS

SOLVED

(MG/L

AS CD .1 .6 .6 .8 .3

ARSENIC

TOTAL

(UG/L

AS AS) 16 2 2 163

Appendix 13. Water-quality, mine entrance 88

, above Big Four Hollow Creek near Lake Hope, Ohio


DATE

WATER

NOV 20...

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

DATE

NOV 20...

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

BERYL

LIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS BE

)YEAR 19

80 90 120 80 80 90 __ --

MERCURY

TOTA

LRE

COV

ERABLE

(UG/L

AS HG

)

2.0 .1 .1 .2

<.l

CADMIUM

TOTAL

RECOV

ERABLE

(UG/

LAS

CD

) 0 0 0 0 0

__ --

NICKEL*

TOTAL

RECOV

ERABLE

(UG/

LAS NI

)

520 97

2400

120

110 --

CHRO

MIUM*

TOTAL

RECOV

ERABLE

(UG/L

AS CR

) 90 703 2 2

--

SELE

NIUM*

TOTAL

(UG/L

AS SE

) 1 0 3 <* 9

--

COPPER*

TOTAL

RECOV

ERABLE

(UG/

LAS CU) 5

250

370

310

2?0

SILVER*

TOTAL

RECOV

ERABLE

(UG/

LAS AG) 0 0 0 0 0

--

IRON*

TOTAL

RECOV

ERABLE

(UG/

LAS FE

)

50000

1100000

9SOOOO

1200000

1 100000

1300000

1100000

ZINC,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS ZN) 0 0 0 0 0

IRON

*DIS

SOLVED

(UG/

LAS

FE

)

30000

320000

950000

93000

1100000

1300000

1100000

ZINC

*DIS

SOLVED

(UG/L

AS ZN)

3700

4900

6700

blOU

5500

LEAD*

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 7 1 0 0 0

--

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZN)

3700

4900

5700

blOO

5500

MANGA

NESE

*TOTAL

RECOV

ERABLE

(UG/

LAS MN)

IbOOO

4SOOO

73UOO

530JO

6oOOO

55000

42000

CARBON*

ORGA

.vil

CDIS

SOLVED

(MG/

LAS

C) 5.2

5.8

1.9

6.4

7.6 --

MANGA

NESE*

SUS

PENDED

RECOV.

(UG/L

AS MN) 0

4000 0 0

6000 0 0

CARBON*

ORGANIC

SUS

PENDED

(MG/L

AS C)

.2 .1 .3 .1 .3 --

MANGA

NESE*

DIS

SOLVED

(UG/

LAS

MN)

IbOOO

4100U

73000

53000

58000

55000

42000

PHENOLS

(UG/L)

0 0 0 i 0

-- --

Appendix 14. Water-quality data, mine entrance 89A above Big Four Hollow Creek near Lake Hope, Ohio,


DATE

WATER

MAR 13..

.

DATE

MAR 13...

DATE

MAR 13..

DATE

MAR 13..

.

TIME

YEAR

1979

1600

MAGNE

SIUM*

DIS

SOLVED

(MG/L

AS MG)

35

CHLO

RIDE

.DIS

SOLVED

(MG/L

AS CD

1.1

ARSENIC

TOTAL

(UG/L

AS AS

) 1

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS)

1300

SODIUM*

DIS

SOLVED

(MG/L

AS NA

)

10

SOLIDS,

RESIDUE

AT 18

0DEG. C

DIS

SOLVED

(MG/

L) 897

BERYL

LIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS BE) 10

PH

FIELD

(UNITS)

3.0

SODIUM

PERCENT 6

SOLIDS,

DIS

SOLVED

(TONS

PER

AC-FT)

- 1.22

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD

) 0

TEMPER

ATURE,

WATER

(OEG

C)

9.5

SODIUM

AD

SORP

TION

RATIO .2

NITRO

GEN,

N02+N03

TOTAL

(MG/

LAS

N) .0

3

CHRO

MIUM,

TOTAL

RECOV

ERABLE

(UG/

LAS

CR) 0

OXYGEN

DEMAND,

CHEM

ICAL

(HIGH

LEVEL)

(MG/

L)

15

POTAS

SIUM,

DIS

SOLVED

(MG/L

AS K) 2.8

NITRO

GEN, AM

MONIA *

ORGANIC

TOTAL

(MG/L

AS N) .3

5

COPPER,

TOTAL

RECOV

ERABLE

(UG/L

AS CU

) 10

HARD

NESS

(MG/

LAS

CAC03)

370

BICAR

BONATE

(MG/

LAS

HC03

)

0

NITRO

GEN,

TOTAL

(MG/

LAS N) .3

8

IRON

,TOTAL

RECOV

ERABLE

(UG/L

AS FE)

41000

HARD

NESS,

NONCAR-

BONATE

(MG/L

CAC03)

370

CAR

BONATE

(MG/L

AS C03)

0

NITRO

GEN,

TOTAL

(MG/L

AS N03)

1.7

IRON,

DIS

SOLVED

(UG/L

AS FE)

41000

ACIDITY

TOTAL

HEATED

(MG/L

AS H) b.6

ALKA

LINITY

(MG/L

ASCAC03) 0

PHOS

PH

ORUS

,TOTAL

(MG/L

AS P) .000

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB) 91

ACIDITY

(MG/L

ASCAC03)

278

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C0

2) .0

ALUM

INUM,

TOTAL

RECOV

ERABLE

(UG/L

AS AL)

9600

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

2200

CALCIUM

DIS

SOLVED

(MG/L

AS CA)

89

SULFATE

DIS

SOLVED

(MG/L

AS S0

4)

560

ANTI

MONY,

TOTAL

(UG/L

AS Sd) 0

MANGA

NESE'

DIS

SOLVED

(UG/L

AS MN)

2100

-App

endi

x 14. Water-quality data,

mine entrance 89A above Big Four Hollow Creek near Lake Ho

pe,

Ohio,


DATE

MERCURY

TOTAL

RECOV

ERABLE

(UG/L

AS HG)

NICKEL*

TOTAL

RECOV

ERABLE

(UG/L

AS NI)

SELE

NIUM*

TOTAL

(UG/L

AS SE

)

SILVER*

TOTAL

RECOV

ERABLE

(UG/L

AS AG

)

ZINC*

DIS

SOLVED

(UG/L

AS ZN

)

ZINC*

TOTAL

RECOV

ERABLE

(UG/L

AS ZN)

CARBON*

ORGANIC

DIS

SOLVED

(MG/L

AS C)

CARBON*

ORGANIC

SUS

PENDED

(MG/L

AS C)

PHENOLS

(UG/L)

WATER YEAR 1979

DATE

WATER

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

DATE

MAR 14.. .

25...

APR 07...

24...

MAY 02...

22...

MAR 13...

TIME

YEAR 19

80

14JO

1400

UOO

1330

1400

IbOO

MAGNE

SIUM*

DIS

SOLVED

(Mb/L

AS MG)

130

150

190

180

<.5

STREAM-

FLOW*

INSTAN

TANEOUS

(CFS) .01

<.01

<.01

SODIUM*

DIS

SOLVED

(MG/L

AS NA

)

11 13 17 17

83

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS)

3410

3100

3300

3200

3050

2400

SODIUM

PERCENT 2 2 2 3

0

PH

(UNITS)

3.3

3.4

3.4

H.7

5.6

4. fa

SODIUM

.AD

SORP

TION

RATIO .2 .1 .2 .2

0

TEMPER

ATURE*

WATER

(DEb C)

6.5

7.5

ti.O

9.U

9.5

9.0

SODIUM*

POTAS

SIUM

DIS

SOLVED

(MG/L

AS NA)

16 --

240

OXYGEN

DEMAND*

CHEM

ICAL

(HIGH

LEVEL)

(MG/L) 97

110

130

120

POTAS

SIUM*

DIS

SOLVED

(MG/L

AS K) 5.2

6.3

8.4

8.5

240

HARD

NE

SS(MG/L

AS

CAC03)

1000

1500

1600

1200

BICAR

BONATE

(MG/L

AS

HC03)

0 0 0 0

3326

1.1

HARD

NESS*

NONCAR-

BONATE

(MG/L

CAC03)

1000

1500

1600

1200

CAR

BONATE

(Mb/L

AS C03) 0 0 0 0 0 0

.1

ACIDITY

TOTAL

HEATED

(MG/L

AS H)

22 16 IV 12

10

ALKA

LINITY

(MG/L

AS

CAC03) 0 0 0 0

27

21

0

ACIDITY

(MG/L

AS

CAC03)

1090

794

943

5*6

497

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C02) .0 .0 .0 .0

133

6b9

CALCIUM

DIS

SOLVED

(Mb/L

AS CA

)

190

340

330

200

--

SULI-ATE

DIS

SOLVED

(MG/L

AS S0

4)

2200

18uo

26UU

2300

2600

1700

Appendix 14. Water-quality data, mine entrance 89A above Big Four Hollow Creek near Lake Hope, Ohio,


DATE

WATER

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

DATE

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

DATE

MAR 14...

25...

APR 07...

24...

MAY 02...

22...

CHLO

RIDE,

DIS

SOLVED

(MG/L

AS CD

YEAR 1980

2.5

2.0

2.9

2.7

ARSENIC

TOTAL

(UG/L

AS AS) 19 17 16 4

MANG

ANE

SE*

DIS

SOLV

ED(UG/L

AS MN)

61000

71000

88000

74000

80000

42000

SOLIDS.

RESIDUE

AT IbO

DEG. C

DIS

SOLVED

(MG/

L)

3490

30bO

4160

3870 --

BERYL

LIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS BE) 50 30 30 20

MERCURY

TOTAL

RECOV

ERABLE

(UG/

LAS

HG

) .1 .1 .2 .1

SOLIDS,

DIS

SOLVED

(TONS

PER

AC-FT)

4.75

4.15

5.66

<5.26 --

CADMIUM

TOTAL

RECOV

ERABLE

(UG/L

AS CD) 0 0 0 b

NICKEL*

TOTAL

RECO

VER

ABLE

(UG/L

AS NI)

230

1600

460

6vO --

NITRO

GEN,

N02+N03

TOTAL

(MG/L

AS N) .3

3.l

b

.27

.33

--

CHRO

MIUM,

TOTAL

RECOV

ERABLE

(UG/L

AS CR) 303 6 2

--

SELE

NIUM,

TOTAL

(UG/

LAS

SE

) 0 0 2 1

NITRO

GEN, AM

MONIA

*ORGANIC

TOTAL

(MG/L

AS N) .9

b.«2

.93

i.2 --

~

COPPER,

TOTAL

RECOV

ERABLE

(UG/L

AS CU)

200 10

IbO66

SILVER,

TOTAL

RECOV

ERABLE

(UG/L

AS AG

) 0 0 0 0

NITRO

GEN,

TOTAL

(MG/L

AS N) 1.3 .9f

1.2

1.5 --

IRON,

TOTAL

RtCOV-

ERABLE

(UG/L

AS FE)

390000

160000

1*0000

170000

180000

900000

ZINC,

SUS

PENDED

RECOV

ERABLE

(UG/

LAS

ZN

) 0 0 0 0

--

NITRO

GEN,

TOTAL

(MG/L

AS N03)

b.f

4.3

5.3

6.tt

IRON,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE

)

1300UU 0

40000

30000

10000 0

ZINC*

DIS

SOLVED

(UG/L

AS ZN

)

4700

<»bO

O

4900

<tOO

O

--

PHOS

PHORUS,

TOTAL

(MG/L

AS P) .030

.100

.110

.010

IRON,

DIS

SOLVED

(UG/L

AS f-E)

260000

160000

150000

140000

17UOOO

900000

ZINC,

TOTAL

RECOV

ERABLE

(UG/L

AS ZN)

4700

4500

4900

4000 -_

PHOS

PHORUS,

TOTAL

(MG/L

AS P0

4) .09

.31

.34

.03

LEAD,

TOTAL

RECOV

ERABLE

(UG/L

AS PB) J 0 0 0

--

CARBON,

ORGA

-NIC

DIS

SOLVED

(MG/L

AS C) 2.9

b.9

3.7

2.0

ALUM

INUM,

TOTAL

nECOV-

ERABLE

(UG/L

AS AD

5*000

3700

37000

19000

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

63000

71000

88000

86000

82000

42000

CARBON,

ORGANIC

SUS-

PtNDEU

(MG/L

AS C)

.1 .2

.1 .7

--

ANTI

MONY,

TOTAL

(UG/L

AS SB

) 0 0 0 0

--

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/

LAS MN)

2000 0 0

12000

2000 0

PHENOLS

(UG/

L)

3 0 0 0

_-

Appendix 15. Water-quality data, mine entrance 90B near Lake Hope, Ohio,

May 2 and 22

, 1980

DATE

MAY

02..

22..

DATE

MAY

02...

22...

TIME

1330

1530

ALKA

LINITY

(MG/L

AS

CACOJ) 0 0

STREAM-

FLOW,

INSTAN

TANEOUS

(CFS

)

»

.05

CARBON

DIOXIDE

DIS

SOLVED

(MG/L

AS C02) .0 .0

SPE

CIFIC

CON

DUCT

ANCE

(MICRO-

MHOS)

1200

1750

SULFATE

DIS

SOLVED

(MG/L

AS S04)

810

1200

HH

(UNITS)

3.4

3.2

IRON,

TOTAL

RECOV

ERABLE

(UG/L

AS FE

)

74000

110000

TEMPER

ATURE,

WATER

(DEG C)

12.0

10.5

IRON,

SUS

PENDED

RECOV

ERABLE

(UG/L

AS FE)

6000

10000

ACIDITY

TOTAL

HEATED

(MG/L

AS H) 6.0

10

IRON,

DIS

SOLVED

(UG/L

AS FE

)

68000

100000

ACIDITY

(MG/L

ASCAC03)

29b

497

MANGA

NESE,

TOTAL

RECOV

ERABLE

(UG/L

AS MN)

3500

3700

6ICAR-

dONATE

(MG/L

AS

HC031

0 0

MANGA

NESE,

SUS

PENDED

RECOV.

(UG/L

AS MN)

x 500 0

CAR

BONATE

(MG/L

AS C03) 0 0

MANGA

NESE,

DIS

SOLVED

(UG/L

AS MN)

3000

3700

WATER YEAR 1979

M

OCT

Appendix 16

. Daily rainfall, in inches, at Sandy Run

near Lake Hope, Ohio, 82184701


SUMMATION VALUES

KtH

MAR

DEC

JAN

MAY

JUN

JUL

AUG

SEP

--_

---

---

---

--..

- .

---

-

_-_

--._

---

--_

.00

.00

.00

.00

.02

.00

,bb

.19

.35

.14

.82

.00

.01

.00

.bb

.01

.00

.05

.01

.00

.62

.24

.82

.00

.It

.00

.00

.00

.00

.00

.00

.01

.10

.02

.80

.b9

.03

.00

.01

.01

.00

.00

.00

.12

.40

.16

.00

.00

.46

.00

.00

.00

.00

,6b

.03

.00

.04

.06

.00

.00

.01

.00

.00

.00

.00

.00

.00

.Ob

.2e.

.63

.07

.03

.58

.18

.00

.00

.03

.b8

.00

.00

.00

.00

.00

.12

.00

.34

1.3

6.0

0.0

1.0

2.0

0

.00

.02

.18

.91

1.1

1

.11

.31

.14

.30

.01

.73

.01

.02

.01

.00

.01

.00

.00

> -

".0

,,0

0

.00

.00

.00

.00

.00

.00

.00

.*y

l.lo .0

1

.00

.00

.01

.00

.00

1.6

tt.5

1.0

1.0

0.0

1

.00

.23

.90

.00

.00

TOTAL

2.74

3.2b

6.33

Appendix 16.--Daily rainfall, in inches, at Sandy Run

near Lake Hope, Ohio, 82184701


water year 1980

DAY

OCT

T')TAI_

rf.4

1

L)tC

JAN

SUMMATION VALUES

FErt

MAP

APR

MAY

JUN

JUL

3.03

2.52

2.13

1.36

5.14

2.37

3.26

4.11

6.6H

AU&

b.71

SEP

] s 3 4 5 6 7 J }10 1

I12 13 14 15 16 1 7

1« IV ?o ?l 22 ?3 24 22 ?627?o?? <o 31

.00

.21

.01

.13

.00

.3?

. 0 0

.67

.0*

.00

.1 1

.20

.00

.00

.01

.11

.01

.00

.00

.01

.00

.Ou

.12

.01

.00

.on

.06

.13

.01

.01

.00

.57

.01

.00

.01

.00

.02

.02

.00

.67

.It.

.00

.00

.00

.00

.Ob

.00

.00

.01

.03

.01

. 0 0

.03

.01

.45

.31

.3*

.00

.11

.02

.01

.10

.04

.11

.01

.00

.16

.00

.00

.00

.00

.00

.40

.62

.00

.01

.01

.08

.14

.02

.05

.02

.no

.12

.29

.23

.00

.00

.01

.01

.04

.05

.04

.03

.01

.02

.06

.0*

.45

.02

.03

.00

.73

.04

,0o

.04

.01

.00

.03

.00

.00

.00

.01

.00

.02

.03

.43

.00

.00

.00

.00

.03

.00

.00

.00

.00

.00

.00

.13

.01

.01

.00

.00

.00

.00

.00

.05

.11

.37

.11

.01

.00

.17

.10

.01

.OH

.00

.00

.01

.11

.07

.01

.00

.00

.00

.00

1.10

.00

.00

.30

.00

.00

.00

.05

.95

.00

.10

.00

.03

.00

.00

.05

.83

.00

.Id

.19

.00

.00

.00

.78

.01

.51

.06

.00

.ul

.06

.OS

.00

.00

.00

.67

.07

.01

.03

.32

.32

.55

.04

.00

.00

.01

.00

.00

.00

.00

.00

.00

.00

.02

.13

.07

.01

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.00

.04

1.08

.11

.00

.00

.01

.72

.06

.22

.03

.01

.00

.21

.07

.07

.00

.00

.00

.00

.25

.36

.17

.5*

.00

.00

.00

.74

.13

.00

.17

.13

.00

.00

.00

.01

.2*

.29

.00

.00

.08

.00

.00

.00

.06

.01

.00

.00

.59

.15

.70

.00

---

.00

.00

.50

.00

.19

.00

.00

.53

1.26

.07

.00

1.U3

.02

.00

.01

.00

.00

.00

.00

.00

1.47

1.60

.00

.00

.00

---

.00

.00

.00

.00

.09

.00

.57

.00

.02

.01

.17

.00

.03

.02

1.19

.02

.00

.14

.13

.00

.09

.06

.45

1.02

.70

.00

.00

.00

.00

.00

.00

.00

.47

.53

.00

.IV

.01

.00

.00

.00

.00

.00

.00

.53

.00

.00

.01

.00

.66

.00

.00

.01

.00

.00

.00

.00

.09

.11

.00

.00

.00

.00

.00

.00

.00

---

1.61

Documents

DRIFT-MINE RECLAMATION IN BIG FOUR HOLLOW NEAR …Four Hollow Creek near Lake Hope, water years 1979-80 12 5. Station 03201630 East Fork Big Four Hollow Creek near Lake Hope, water