Embed Size (px)
Citation preview
Dr. Kjell Ankner
Physical-Organic Chemist
Pharma chemist Astra-Zeneca
Petrochemical development Neste-Oxo
Biobased Feedstock
• Chemical price/Energy price =2-3 ?
• Cost of black liqueur 0,2 Eu ?
Hydroxisyror
HYDROXY ACIDS
Functional
Fluids
Coatings
MaterialsChemicals
ka20101210
Lubricants
• Automotive• Compressor• Hydralic Turbine• Gear• Process oils• Heat Transfer• Metal working• Textile• Chain
Esters Use Areas
• Heat transfer• Hydralic fluids• Lubricants• Fuel additives• Lube additives• Insulators• Transformers
Monomers
Solvents
Surface active products
Plasticizers
Inks
Coalescers
Cosmetics
Flavour Fragrance
Herbicides Pesticides
ka20101210
Coating Types
• Industrial Systems
• Automtive• Marine• Aircraft• Appliances• Coil coating• Can• Machinery Appliances• Wood, Flat board• Plastic Coating
• Decorative
• Housing• Interior• Wood furniture
• Solvent-based• Water-based
Raw Materials
• Alkyd Resins• Polyesters• Amino Resins• Polyurethanes• Epoxy Resins• Acrylics• Vinyl Acetate Copolym.• PVC PVDC• Polyimides• Silicones Silanes
• Functional Groups
• Caboxylic acids• Alcohols• Amines
• Esters• Amides• Ethers
coatings
Acrylic acid
waterbased
paint
polylactic acid
if optical pure
metacrylic acid MMA
MeOH
Plexi
O
OH
O
HO
O
O
OH
O
H HO
HO
O
O
O
O
C
NH3
nitrile
acrylnitrils
R
Quats
Hydroxy acids and amines ammonia
Heterocycles Aromatic heterocycles
amines
O
O
OO
N
O
OO
N
OO
N
O
C
N
lINEAR HY DROXY ACIDS
ε-Caprolactone
Short straight chain (C6-C10) not available from natural sources
and expansive from oilbased feeds
OO
O
O
HH
H
HO
O
O
Typical complexity of a chemical industrial unit
Several unit operations is normal
H2/CO
Separation
Hydrogenation
n-ButanolisobutanolAldolisation
Hydrogenation
Octanol
Hydrogenation
Selective
H2CO DiolBEPD
Oxidation
Octanoic acid
NPGTMP
Orthoxylene
Acids
OxidationEsterification
Phathalic acidPlasicizers
O
H
O
H
O
H
+ +
propene aldehyde C4 alcohole
NPG 1700TMP 1800
900-1000 1200
Octanol Octanoic acid BEPD
13-1400 19003000
PHTHALICDEHP
70011001600
Eu/t
Value of different processing steps in oxo industry as an example
The choice of product is depending of market size not profitabillty
orthoxylene
• Vanillinsyra (VA)
– Metyl vanillat (MVA)
– Metyl vanillin octanoat (MVO)
O
O
O
OH
O
OH
O
OH
O
O
O
O
O
• Eugenyl acetat (EA)
– Epoxiderad eugenyl acetat (EEA)
– Acetyl och syramodifierad EEA (AMEEA)
– Eugenyl oktanoat (EO)
O
O
O
O
O
O
O
O
O
O
O
R O
O
O
O
O
O
• Vanillinsyra (VA)
– Metyl vanillat (MVA)
– Metyl vanillin octanoat (MVO)
O
O
O
OH
O
OH
O
OH
O
O
O
O
O
