Dow VerseneTM Chelating Agents - Prochem · VERSENE™ 100 Chelating Agent DOW CONFIDENTIAL - Do not share without ... Oil Field • Us in several operations in the drilling, production,

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Dow VerseneTM Chelating Agents

May 31th, 2017

DOW CONFIDENTIAL - Do not share without permission

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Contents

2DOW CONFIDENTIAL - Do not share without permission

1. Introduction of Chelant (Purpose of use)

2. Market segment and application

3. Information of Chelant materials

4. Structure of representative Chelant agent

5. Dow Chelant Products

6. Chelant agent application in industry (Scale remover)

7. Product Selection Guide

8. Resources (Dow)

9. How to Sell VERSENE Chelants (Guidance of chelant agent)

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VERSENE™ Chelants_What do they do??

Put the

Squeeze on

harmful metal

ions

Chelant comes from the Greek word “chele” which means “crab claw”

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VERSENE™ Chelants

The most powerful, commercially available, metal ion control ingredients

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VERSENE™ EDTA

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VERSENE™ Chelants

The most “versatile” product in the market


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Why do you need VERSENE™ Chelants?

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– Dissolve precipitates, scales

• Cleaning: household, institutional, industrial, nuclear

– Prevent precipitation

• Water treatment, down hole drilling, mining, scale formation in evaporators, boilers, exchangers

– Prevent harmful reactions

• Food, pharmaceuticals, personal care, pulp bleaching, textiles, detergents

– Facilitate reactions

• Polymer catalysis, photo bleaching, gas treating, electroplating, micronutrients

– Change metal ion interactions

• Personal care, agriculture, food fortification

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Market segment


Source: SRI

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Chelant business


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Ligands, Chelants & APCAs


ChelantsAPCAsAminoPolyCarboxylic Acids

DTPA

EDTA

NTA

Ligands = Metal

Ion Complexing

Agents

HEDTA

citrates

polyphosphates

gluconates

enzymes

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VERSENETM Chelating Agents


• Interact with metal ions by sharingelectrons to form ringed structures

• Form highly stable complexes--metalfavor chelate complexes over otherligands

• Control metal ions in aqueous solution

- Block normal reactivity of the metal ion

- Keep metal ions in solution

MM

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VERSENE™ 100 Chelating Agent

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VERSENEX™ 80 Chelating Agent


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VERSENOL™ 120 Chelating Agent

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Chelation Value vs. Chelation Strength


– Capacity = Quantity (chelation value)

• How much metal can a chelant hold?

• One gram of VERSENE™ 100 controls 102 mg of calcium carbonate

• One gram of VERSENEX™ 80 control 80 mg of calcium carbonate

– Strength = Stability/Power

• The ability to form strong, stable metal complexes (more arms are stronger)

• To out-compete other metal complexing agents (the bigger the better)

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Dow Chelant Products


discontinued

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Main Applications


Pulp and paper

Cleaners

• Hard surface cleaners

• Detergents

• Clean in Place (CIP)

Food

Pharmaceutical

Personal Care

Gypsum board

Water Treatment

Ag Micronutrients

Oil Field

Electroless plating

Textiles

Photography

Polymers

Catalyst

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Cleaning Products


• Boost cleaning performance by loosening soils and dissolving scale.

• Protect the quality and prevent degradation of cleaning formulations.

• Household cleaning products– Carpet cleaners

– Hard surface cleaners

– Laundry

• Institutional cleaning products– Commercial dish washing liquids

– Car and truck washes

– Commercial laundry detergents

• Industrial cleaning products– Scale removers

– Dairy cleaners

– Industrial equipment cleaners

VERSENE™ 100

VERSENE™ Tetraammonium

VERSENOL™ 120

VERSENEX™ 80

VERSENE™ Diammonium

Better Shelf Life, Brighter Surfaces

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Typical VERSENETM Chelant Use Levels in Cleaners


0.2 - 0.5 wt%

• For general protection against metal ions’ effects

• To assure good appearance of cleaning products

0.5 - 1.0 wt%

• To enhance cleaning product performance in hard water

• For concentrated cleaning products

1.0 - 3.0 wt%

• To provide a safety margin of protection

• Where the chelant is an important active ingredient when soils or stains have metal components

3.0 - 10.0 wt%

• Where the chelant is doing some of the cleaning

• Typically, for cleaning of metal surfaces

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Agriculture

• Supply trace iron as a plant micronutrient. This helps overcome iron deficiencies caused by intensified cropping practices or the use of higher analysis or high phosphorous fertilizers.

• VERSENOL™ AG 4.5 Fe

• VERSENE™ Acid

• Stabilize water-soluble and water-miscible herbicide and pesticide formulations when they are formulated or mixed with hard water.

• VERSENE™ 100

• VERSENE™ Na2 Crystals


Promoting Growth

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Water Treatment

• Provide excellent control of scale-forming calcium and magnesium in open circulating cooling systems.

• Effective in controlling iron and other metal ions that often accompany hardness and compound scaling problems.

• Boiler treatment

• Heat exchanger treatment

• Evaporator treatment

• Filter cloth washing

• Piping

• Process Vessels


VERSENE™ 100

VERSENEX™ 80

VERSENOL™ 120

VERSENE™ Diammonium EDTA

VERSENE™ Tetraammonium EDTA

Fighting Scale the Easy Way

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Scale in Industrial Water Treating


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Personal Care

• Prevent discoloration, rancidity, and other undesirable metal-

catalyzed reactions.

• Benefit with improved detergency, foaming, rinsability, and clarity.

• Water hardness protection

• Creams and lotions

• Shower gels

• Hair care products

• Hand cleaners

• Facial cleanser

• Baby wipes

• Conditioners


VERSENE™ 220 Crystals

VERSENE™ 100XL

VERSENE™ Na2

VERSENE™ Odor Control Crystals

VERSENE™ Acid

Preserving Brand Loyalty

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Pulp and Paper

• Improve product quality and reducing costs in pulp and paper operations.

» Control metal-catalyzed bleach degradation in peroxide bleaching.

» Increase brightness gains in hydrosulfite bleaching of thermomechanical or refiner pulps.

» limit reactions that cause brightness reversion or produce colored complexes in pulp or sheet.

• Peroxide bleaching

• Hydrosulfite bleaching

• Kraft peroxide bleaching


VERSENE™ 100

VERSENEX™ 80

The Right, Bright Idea for Sheet Appearance

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Hydrogen Peroxide


• Elemental Chlorine Free (ECF) and Totally Chlorine Free (TCF) bleaching processes

• are the trend for pulp bleaching with reduced footprint to environment.

• Hydrogen peroxide H2O2 is the key bleach in ECF and TCF processes.– Increase bleaching capability

– Lower cost than chlorine dioxide

– Process flexibility

– Stable brightness with little yellowing

– No chloride in waste water and little pollution

– Lower corrosion

– Chemistry and heat recyclability

• Bleaching Mechanism

H2O2 + OH- OOH- + H2O

• Metal ions like Mn, Fe and Cu, catalyze the decomposition of hydrogen peroxide, so

some improvement in the efficiency of peroxide bleaching can be achieved if the metal

levels are controlled.

2H2O2 2H2O + O2

Mn, Fe and Cu

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Food Products

• Help prevent the degradation of colors and flavors in food products by controlling trace amounts of pro-oxidant metal ions such as copper and iron.

• High purity, special process for direct food use– USP/FCC quality

– Kosher/Parve certified

– GB2760

• Allowed in specific applications only– Beverages

– Dressing, sauces, and mayonnaise

– Canned vegetables

– Canned seafood

– Pickled products


Preserving Color, Flavor and Clarity

VERSENE™ CA

VERSENE™ NA

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Direct Food Use According to FDA


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Metalworking

• Use from the preparation and cleaning of metal surfaces to the final finishing and plating operations.

• Surface preparation

• Dip-rinsing

• Oxide prevention

» Metal cleaning

• Oxide removal

• Iron rust cleaning

• Electrolytic cleaning

» Metal Finishing and plating

• Metal ion control in plating baths

• Primary electrolytes

• Immersion plating

• Electroless plating

• Metalworking fluids


Preparation, Prevention, Preservation

VERSENE™ 100


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Oil Field

• Us in several operations in the drilling, production, and recovery of oil.

• Enhanced oil recovery (boiler water treatment)

• Scale control in casings and formations

• Stimulation/Fracturing

• Acidizing systems

• Fracturing fluids


Less Downtime Downhole

VERSENE™ 100

VERSENE™ Na2 Crystals

VERSENOL™ 120

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Polymerization

• Use in the polymerization of suspension, emulsion, and solution polymers.

• Act as metal ion reservoirs in metal-catalyzed polymerization reactions

• Stabilize finished polymers by controlling metal ions


Stabilize Processes and Polymers

VERSENE™ 100

VERSENE™ Diammonium EDTA


VERSENEX™ 80

VERSENE™ NA

VERSENE™ CA

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Pharmaceuticals


• VERSENE™ NA Pharm Grade Disodium ethylenediaminetetraacetate dihydrate• CAS：6381-92-6 • Antioxidant, Antimicrobial booster and Vitamin stabilizer• Regulation Compliance

• Compliance with cGMP, Kosher, FCC(Food Chemicals Codex) and US Pharmacopeia XXII

Applications Issue VERSENE™ NA Benefit Dosage(wt%)

Ocular care decomposition Perseverative booster 0.05% - 0.1%

Syrups and elixirs Color or flavor change Protect color, flavor and ingredients 0.1%

Medicated creams

and ointmentsOxidative rancidity Prevent or control oxidative rancidity 0.1% - 0.3%

Vitamin and liquid

nutritional drinks

Decomposition and color

change

improves the stability of beverages

and acts as preservative0.1%

Syrups and elixirs Decomposition Stabilize color, flavor and ingredients 0.1%

Tablet coatings Decompositionpreservative and stabilizer to extend

the in-process life0.1%

API Preservative oxidation or chemical attack Improve the stability of API 0.1%

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Product Selection Guide


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How to Sell VERSENE Chelants, Technical questions:

• What is the application?

• Describe the metal ion control need or problem.

• Which metals are believed to be causing the problem?

• How is metal ion control being accomplished now?

• Competitive product or technology

• Describe the customer’s process

• Water-based system?• pH• Temperature• Metals and their concentrations• Does customer need liquid or solid product


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Resources


• CIG (Customer Information Group) [email protected], [email protected]

• Contact for most basic customer technical inquiries• MSDS, Customer surveys/forms, samples, etc.

• Website http://www.dow.com/versene/

• downloadable literature and letters via• tech data sheet available for each product

• Answer Center http://dow-answer.custhelp.com

• an online, self-service database of technical information

• frequently asked questions (FAQs)

• 24 hours, 7 days per week

• TS&D

mailto:[email protected]

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VERSENETM Product Recommendations


Documents

Dow VerseneTM Chelating Agents - Prochem · VERSENE™ 100 Chelating Agent DOW CONFIDENTIAL - Do not share without ... Oil Field • Us in several operations in the drilling, production,