Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit … · 2020. 4. 8. · Note 4: See certificate of analysis for accredited parameters. ... ASLLK12EQ532 Pump ASLLK14EQ501

Document No.: BACHTL7050919 EPA Licence No.: P0522-01 Visit No: 4 Licence Holder: Barclay Chemicals Manufacturing Limited Year: 2019 Facility Location: Damastown, Mulhuddart, County Dublin Office: Limerick Version No: 1

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Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Environmental Efficiency

Facility Name Barclay Chemicals Manufacturing Limited

Contact Person Tiernan Keane

EPA Licence Number P0522-01

Licence Holder Barclay Chemicals Manufacturing Limited

Stack Reference Number A3-6

Dates of the Monitoring Campaign 05-09-2019

Job Reference Number BACHTL7050919

Report Written By Mr. Gregory Dempsey

Report Approved by Mark McGarry

Stack Testing Team Mr. Gregory Dempsey

Report Date 18-10-2019

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver Operations Manager


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Contents

1.0 Executive Summary ................................................................................................................................................................................ 3 1.1 Overall aim of the monitoring campaign ................................................................................................................................................ 3 1.2 Summary of substances to be monitored at each emission point .......................................................................................................... 3 1.3 Special Requirements ............................................................................................................................................................................. 3 1.4 Summary of Results ................................................................................................................................................................................ 4 Emission Point Number: A3-6 ...................................................................................................................................................................... 4 1.5 Operating Information ........................................................................................................................................................................... 5 1.6 Monitoring Deviations ............................................................................................................................................................................ 5 1.7 Reference Documents ............................................................................................................................................................................ 5 1.8 Revision History ...................................................................................................................................................................................... 5 Part 2: Supporting Information ........................................................................................................................................................................ 6 Appendix I ......................................................................................................................................................................................................... 7 1.1 Monitoring Personnel ............................................................................................................................................................................. 7 1.2 Equipment Inventory .............................................................................................................................................................................. 8 Appendix II ........................................................................................................................................................................................................ 9 2.1 Stack Emission Point Reference: A3-6 .................................................................................................................................................... 9 2.1.1 Suitability of Sample Location: .......................................................................................................................................................... 9 2.1.2 Stack Diagram ................................................................................................................................................................................. 10 2.1.3 Stack Raw Data ............................................................................................................................................................................... 11 Appendix III: Certificates and Process Detail Form ........................................................................................................................................ 20

Opinions and interpretations expressed herein will be outside the scope of Air Scientific Limited INAB accreditation. This test report shall not be reproduced, without the written approval of Air Scientific Limited.

All sampling and reporting is completed in accordance with Environmental Protection Agency Air Guidance Note 2 requirements.


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1.0 Executive Summary

1.1 Overall aim of the monitoring campaign

The aim of the monitoring campaign was to demonstrate compliance with a set of emission limit values as specified

in the site licence.

1.2 Summary of substances to be monitored at each emission point

Stack Name: A3-6

Individual Gaseous Organic Compounds

Volumetric Flow Rate (Ref)

1.3 Special Requirements

There were no special requirements


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1.4 Summary of Results

Emission Point Number: A3-6

Parameter Method Units Result MU +/- Limit O2 Ref.

(%)

Moisture

Ref. (%) Compliant Blanks Date Time on Time off

Accreditation

Sampling Analysis

Speciated Organics Class I EN 13649 mg.m-3 >2.0 - <2.6 0.08 – 0.1 20 Note 3 N/a N/a N/a 0.44 05/09/2019 11:10 11:40 Yes Yes Note 4

Speciated Organics Class I EN 13649 kg.hr-1 >0.00028 - <

0.00037 0.00011 – 0.00014

0.1 N/a N/a Yes 0.0003 05/09/2019 11:10 11:40 Yes Yes Note 4

Volumetric Flow Rate (Ref) EN 16911 m3.h-1 140 53 N/a N/a N/a Yes N/a 05/09/2019 11:20 11:30 Yes N/a

Note 1: All results are normalised to standard temperature and pressure (0OC and 101.3kPa)

Note 2: All results are reported in the format as defined by the EPA in guidance note AG2:2018.

Note 3: Limit applied if mass threshold exceeded;

Note 4: See certificate of analysis for accredited parameters.


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1.5 Operating Information

Please reference Process Details as per Appendix III attached.

1.6 Monitoring Deviations

Stack Name: A3-6

Parameter Deviation

Individual Gaseous Organic Compounds None

Volumetric Flow Rate (Ref) EN 16911 - in accordance with MID 16911-1

1.7 Reference Documents

Risk Assessment (RA) SOP 1011

Site Review (SR) SOP 1015

Site Specific Protocol (SSP) SOP 1015

1.8 Revision History

Revision Number Changes to the report

1 Original version of the report


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Part 2: Supporting Information

Report Title Air Emissions Compliance Monitoring Emissions Report

Company address Air Scientific Ltd., Unit 5, Caherdavin Business Centre, Caherdavin,

Park, Ennis Road, Limerick V94 NT63.

Stack Emissions Testing Report Commissioned by Environmental Efficiency

Facility Name Barclay Chemicals Manufacturing Limited

Contact Person Tiernan Keane

EPA Licence Number P0522-01

Licence Holder Barclay Chemicals Manufacturing Limited

Stack Reference Number A3-6

Dates of the Monitoring Campaign 05-09-2019

Job Reference Number BACHTL7050919

Report Written By Mr. Gregory Dempsey

Report Approved by Mark McGarry

Stack Testing Team Mr. Gregory Dempsey

Report Date 18-10-2019

Report Type Test Report Compliance Monitoring

Version 1

Signature of Approver Operations Manager


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Appendix I

1.1 Monitoring Personnel

Team Leader Name Gregory Dempsey

System approval ASL Team Leader Approved


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1.2 Equipment Inventory

ID Item of Equipment Used ID Item of Equipment Used ID Item of Equipment Used

ASLLK12EQ500 Pump ASLLK12EQ525 Horiba (PG-250) X ASLLK13EQ501 Vernier Calipers

ASLLK12EQ532 Pump ASLLK14EQ501 Horiba-PG 350 ASLLK14EQ503 Vernier Calipers

ASLLK12EQ533 Pump ASLLK14EQ512 Horiba PG250Y ASLLK14EQ507 Vernier Calipers

ASLLK12EQ534 Pump ASLLK16EQ508 Horiba- PG250z ASLLK17EQ533 Vernier Calipers

ASLLK12EQ535 Pump ASLLK17EQ515 Horiba 350 ASLLK18EQ506 Vernier Calipers

ASLLK12EQ536 Pump

ASLLK12EQ537 Pump

ASLLK12EQ538 Pump ASLLK12EQ526 Chiller ASLLK13EQ503 1kg weight

ASLLK12EQ540 Pump ASLLK14EQ513 Chiller ASLLK13EQ508 500g Hafner weight

ASLLK12EQ541 Pump ASLLK16EQ509 Chiller ASLLK13EQ509 500g Hafner weight

ASLLK12EQ542 Pump ASLLK18EQ505 Chiller ASLLK14EQ515 500g Weight

ASLLK12EQ543 Pump ASLLK15EQ511 1kg Weight

ASLLK13EQ513 Pump ASLLK15EQ512 1kg weight

ASLLK13EQ514 Pump ASLLK16EQ501 Velocity Meter ASLLK16EQ511 1kg weight

ASLLK16EQ518 Pump ASLLK17EQ508 Velocity Meter ASLLK16EQ512 500g weight

ASLLK16EQ519 Pump ASLLK17EQ514 Velocity Meter ASLLK17EQ529 500g weight

ASLLK17EQ509 Pump ASLLK18EQ504 Velocity Meter ASLLK17EQ530 1kg weight

ASLLK17EQ510 Pump ASLLK19EQ502 Velocity Meter

ASLLK17EQ522 Pump ASLLK13EQ504 G4

ASLLK17EQ523 Pump ASLLK13EQ515 G4

ASLLK17EQ524 Pump ASLLK14EQ500 FID ASLLK15EQ501 G4

ASLLK17EQ525 Pump ASLLK16EQ502 FID ASLLK17EQ534 ST5



ASLLK18EQ518 Pump ASLLK17EQ535 Signal Cutter ASLLK19EQ509 ST5

ASLLK13EQ512 PCDD thermometer ASLLK14EQ510 Digital Protractor

ASLLK15EQ506 MF Meter ASLLK14EQ511 Digital Protractor

ASLLK17EQ501 MF Meter ASLLK16EQ510 Measuring Tape ASLLK15EQ505 Digital Protractor




ASLLK19EQ500 MF Meter ASLLK18EQ508 Measuring Tape

ASLLK19EQ501 MF Meter

ASLLK12EQ522 Balance

ASLLK12EQ527 Heated Line ASLLK16EQ515 Thermocouple K type ASLLK12EQ544 Balance

ASLLK14EQ509 Heated Line ASLLK16EQ516 Thermocouple K type ASLLK15EQ509 Balance

ASLLK14EQ514 Heated Line ASLLK18EQ510 K type Thermocouple ASLLK15EQ510 Balance



ASLLK17EQ539 Heated Line ASLLK19EQ505 K type Thermocouple

ASLLK18EQ516 Heated Line

ASLLK17EQ519 Stopwatch

ASLLK12EQ518 S type Pitot Tube ASLLK17EQ520 Stopwatch

ASLLK12EQ520 L Type Pitot tube ASLLK17EQ521 Stopwatch

ASLLK13EQ506 S type Pitot Tube ASLLK18EQ509 Stopwatch

ASLLK14EQ506 Pitot + thermocouple

ASLLK16EQ506 S type Pitot Tube

ASLLK16EQ517 S type Pitot Tube Long

ASLLK17EQ507 1 m S type & K type





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Appendix II

2.1 Stack Emission Point Reference: A3-6

2.1.1 Suitability of Sample Location:

General Information

Permanent/Temporary Permanent

Inside/ Outside Outside

Platform Details

Irish EPA Technical Guidance Note AG1 / BS EN 15259 Platform Requirements

Value Comment

Sufficient Working area to manipulate probe and measuring instruments

Yes -

Platform has 2 handrails (approx. 0.5m & 1.0 m high) Yes -

Platform has vertical base boards (approx. 0.25 m high) No -

Platform has chains / self-closing gates at top of ladders No -

There are no obstructions present which hamper insertion of sampling equipment

Yes -

Safe Access Available Yes -

Easy Access Available Yes -

Sampling Location / Platform Improvement Recommendations

None

EN 15259 Homogeneity Test Requirements

1.

Select Option: 1: There is no requirement to perform a BSEN15259 Homogeneity Test on this stack 2: Test results were obtained from previous Homogeneity test carried out by ASL 3: Test results were obtained from previous Homogeneity test carried out by Alternative contractor 4: Homogeneity Test is required on this stack and the client has been informed of this requirement


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2.1.2 Stack Diagram

c.10m

Ports 1

c.2metres

Ground Level


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2.1.3 Stack Raw Data


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Title: Determination of Speciated Organic Compounds

Method: EN 13649

Client: Barclay

Test Date: 05/09/2019

Test Time: 11:10

Laboratory Used: CLS

Stack Reference: A3-6

Leak Check Results VOCs

Prior to test: 0 l/min

Post Test: 0 l/min

Sample Volume Flow Rate: 0.35 l/min

Standard Requirement: <5 %

Test Result: 0 %

Test Status Pass

Calibration Details VOCs

Pump Number: ASLLK12EQ536

Calibration Unit: ASLLK17EQ501

Calibration Unit Uncertainty: <2 %

Calibration Rate Before Test: 0.35 Nl/min

Calibration Rate After Test: 0.35 Nl/min

Maximum allowed flow 0.5 Nl/min

Average sample Volume: 0.35 Nl/min

Sample Test Time: 30 minutes

Pump Gas Temperature: 12 OC

Pump Sample Pressure: 101.2 kPa

Normalised Gas Volume: 0.01050 Nm3

Tube Details VOCs

Tube Type: 226-09

Tube Identification Number: 7899201682

Blank Identification Number: 7899201673

Main Adsorbent Layer 400 mg

Backup Adsorbent Layer 200 mg

Containment Material Glass

Breakthrough Occurred No

Tubes in Lab in <7 days Yes

Tubes >7 days were stored <4 Deg C

Tubes >7 days were stored Dark -

Transport Container Airtight Yes

Exposed to Sunlight No

Transport Temp <20 Deg C Yes

Field Blank <10% Analyte Value Yes

Field Blank <10% ELV Yes

Test Details

Adsorption Tube Temperature: 12 OC

Stack Flow Rates Uncertainty

Normalised Flow Rate: 140 m3.hr-1 38 %


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Speciated Organic Results

Class I ug/tube mg.Nm-3 kg.hr-1

Benzene 1 0.10 0.0000

Carbon Tetrachloride 14 1.33 0.0002

Chloroform 3 0.29 0.0000

Dichloromethane 4 0.38 0.0001

Tetrachloroethylene 3 0.29 0.0000

Trichloroethylene 3 0.29 0.0000

Concentration Uncertainty ELV

mg.Nm-3 mg.Nm-3 mg.Nm-3

Total Class I 2.67 0.10 20

Mass Emission Uncertainty Threshold

kg.Hr-1 kg.Hr-1 kg.Hr-1

Total Class I 0.0004 0.00014 0.1

Speciated Organic Results - Detected


Benzene - - -


Chloroform - - -



Trichloroethylene - - -






Total Class I 0.0003 0.00011 0.1


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Speciated Organic Results - Blanks


Benzene 1 0.10 0.0000


Chloroform 3 0.29 0.0000



Trichloroethylene 3 0.29 0.0000






Total Class I 0.0004 0.00014 -


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Uncertainty calculation A3-6 TA Luft Class 1

Measurement Equation

Limit value (ELV) 20 mg.m-3

Reference oxygen % by volume

Measured concentration 2.67 mg.m-3

(at reference conditions)

Measured Quantities Symbol Value Standard uncertainty Units Uncertainty as percentage Uncertainty at lv Requirement of std

Sampled Volume Gas Vm 0.0105 uVm 0.0001 m3

0.95 <=2%

Sampled gas Temperature Tm 285 uTm 2 k 2.00 <2.5 k

Sampled gas Pressure ρm 101.2 uρm 1 kPa 0.99 <=1%

Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%

Oxygen content O2,m uO2,m 0.1 % by volume #DIV/0! <=5%

Note - Sampled gas humidity, temperature and pressure are values at the gas meter

Leak L 0.5 % 0.50 <=2%

Intermediate calculations

Factor for std conds fs 0.96

uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009

Hm 0.010 0.010

Tm 0.003 0.007

ufs 0.015 1.57

Corrected volume V 0.01 uV 0.000 m3

1.86

Factor for O2 correction fc 1.00

uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005

Factor for O2 Correction ufc 1.00 0.005 0.48

Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %

Corrected Volume (standard conditions) V 0.01 m3

265.39 0.05 mg.m-3

1.86 %

Factor for O2 Correction fc 1.00 2.67 0.01 mg.m-3

0.48 %

Leak L 0.01 mg.m-3

1.00 0.01 mg.m-3

0.29 %

Combined uncertainty 0.05 mg.m-3

Expanded uncertainty as percentage of measured value 3.88 % measured of value expressed with a level of confidence of 95%

(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.1035 mg.m-3

Expanded uncertainty as percentqge of limit value 0.52 % ELV

sm fVV

m

ref

cO

Of

,2

,2

21

21

cfV

mc

3.101

273

100

)100( m

m

m

sT

Hf


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Title: Determination of Stack Flow Rate

Method: EN 16911

Client: Barclay Chemicals

Stack Reference: A3-6

Stack details Value Units

Date of survey 05/09/2019

Time of survey 11:20

Type (Circular or Rectangular) Circular

Stack Diameter / Depth, D 0.15 Length (m) m

Stack Width, W m

Average Stack Gas Temp., Ta 15.8 288.95 C

Average Static Pressure, P static 0.02 kPa

Average Barometric Pressure, Pb 101.2 kPa

Type of Pitot (S or L) S

Are Water Droplets Present ? No

Average Pitot Tube Calibration Coeff, Cp 0.81

No local negative flow Yes

Highly homogeneous flow stream/gas velocity Yes

Sample Port Size 25.4 mm

Initial Pitot Leak Check Pass Pa

Final Pitot Leak Check Pass Pa

Stagnation Check Pass Pa

Orientation of Duct

Pitot Tube Cp 0.998

Number of Lines Available 1

Number of Lines Used 1

Sampling Line A

Point Distance Pa Temp C Velocity Oxygen Swirl

1 0.05 5.1 15.8 2.3 20.9 2

2 0.1 5 15.8 2.3 29,9 1

3 - - - - - -

4 - - - - - -

5 - - - - - -

6 - - - - - -

7 - - - - - -

8 - - - - - -

9 - - - - - -

10 - - - - - -

Average 5.05 15.8 2.3 20.9 2

Min 5 15.8 2.3

Max 5.1 15.8 2.3

Sampling Line B

Point Distance Pa Temp C Velocity Oxygen Swirl

1 - - - - - -

2 - - - - - -

3 - - - - - -

4 - - - - - -

5 - - - - - -

6 - - - - - -

7 - - - - - -

8 - - - - - -

9 - - - - - -

10 - - - - - -

Average 0 0.0 0.0 0 0

Min 0 0 0.0

Max 0 0 0.0


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Average stack Gas Velocity 2.33 m/s

Lowest Differential Pressure 5.00 Pa

Lowest Gas Velocity 2.32 m/s

Highest Gas Velocity 2.34 m/s

Average Differential Pressure 5.05 Pa

Velocity Ratio of High to Low (3:1) 1.01

Average Angle of flow 1

Component Conc ppm

Conc Dry % v/v

Conc Wet % v/v

Molar Mass

Carbon Dioxide CO2 - 0.1 44.01

Oxygen O2 - 20.9 32

Nitrogen N2 - 79 28.1

Moisture (H2O) - - 0 18.02

Reference Conditions Units Numbers

Temperature K 273.13

Total Pressure kPa 101.3

Moisture % -

Oxygen (Dry) % -

General Stack Details

Stack details Units Value

Stack Diameter / Depth, D m 0.15

Stack Width, W m 0

Stack Area, A m2 0.02

Average Stack Gas Temp., Ta C 15.8 288.95 K

Average Static Pressure, P static kPa 0.02

Average Barometric Pressure, Pb kPa 101.2

Average Pitot Tube Calibration Coeff, Kpt 0.81

Calc box Area

Circular Duct Rectangular Duct

R = 0.075 Length (m) 0

R2 = 0.005625 Width (m) 0

Area = Pie*R2 0.02 Area 0

Stack Gas Composition & Molecular Weights

Component Molar Mass

M Density Kg/m3 p

Conc Dry % v/v

Dry Volume Fraction r

Carbon Dioxide CO2 44.01 1.96 0.1 0.001

Oxygen O2 32 1.43 20.9 0.209

Nitrogen N2 28.1 1.25 79 0.79

Moisture (H2O) 18.02 0.80

where p=M/22.41

pi = r x p

Dry Conc kg/m3 pi

Conc wet % v/v

Wet Volume Fraction r

Wet Conc kg/m3 pi

Carbon Dioxide CO2 0.00 0.10 0.00 0.00

Oxygen O2 0.30 20.90 0.21 0.30

Nitrogen N2 0.99 79.00 0.79 0.99

Moisture (H2O) - 0 0.00 0.00


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Calculation of Stack Gas Densities

Determinant Units Result

Dry Density (STP), P STD kg/m3 1.291

Wet Density (STP), P STW kg/m3 1.291

Dry Density (Actual), P Actual kg/m3 1.219

Average wet Density (Actual), P Actual kg/m3 1.219

Where

P STD = sum of component concentrations, kg/m3 (excluding water vapour)

P STW = (P STD + pi of H2O) / ( 1 + (pi of H2O / 0.8036))

P actual = P STD x (T STP / (P STP)) x (Pa / Ta)

P actual W (at each sampling point) = P STW x (Ts / Ps) x (Pa / Ta)

Calculation of Stack Gas Volumetric Flow rate, Q

Duct gas flow conditions Units Actual REF

Temperature K 288.95 273.13

Total Pressure kPa 101.2 101.3

Moisture % 0 -

Oxygen (Dry) % 20.9 -

Gas Volumetric Flow rate Units Result

Gas Volumetric Flow Rate (Actual) m3/hr 148

Gas Volumetric Flow Rate (STP, Wet) m3/hr 140 Uncertainty

Gas Volumetric Flow rate (STP, Dry) m3/hr 140 53 m3/hr

Gas Volumetric Flow rate REF to Oxygen m3/hr - 38.0 %

Where

Actual = Va * A * 3600

STP Wet =Actual x (Ts / Ta) x (Pa / Ps)

STP , Dry = STP Wet / (100 - Water Vapour % ) / (100- Water Vapour Ref))

REF = STP Wet x (100 - Water Vapour % ) / (100- Water Vapour Ref)) x (20.9 - O2m)/ (20.9 -O2 Ref)

Sampling Plane Validation Criteria Value Units Requirement Compliance Method

Lowest Differential Pressure 5.00 Pa >5 Pa Pass EN 16911

Lowest Gas Velocity 2.32 m/s - - -

Highest Gas Velocity 2.34 m/s - - -

Ratio of Above 1.01 :1 <3:1 Pass EN 16911

Mean Velocity 2.33 m/s - - -

Angle of flow 0.75 degrees < 15 Pass EN 16911

No local negative flow Yes - - - -

Homogeneous flow Yes - - - -

Calculation of stack Gas Velocity, V

Velocity at Traverse Point, V = Kcp * Sqroot ((2 * DP ) / Density) 8.284796816

Where

Kpt = Pitot tube calibration coefficient 0.81

Compressibility correction factor, assumed at a constant 0.998 0.998


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V1.4 Oct-16

Enter data in orange cells only <---- Complete (Don’t Touch)

ConstantsGas constant 8.314 J/(K.mol)

3735 Pa

1 Pa

0.03 % of value

0.1 % of range between calibrations

0.17 % of range

0.9 Pa

Water vapour measurement 2 % relative

Pitot coefficient, K 0.81 1 °C CO content measurement 2 % relativeExpanded uncertainty (95%, k=2) 0.03 100 Pa CO2 content measurement 2 % relative

1.0 % O2 content measurement 2 % relative

Duct dimensions Circular RectangularDiameter 0.15 m a 0.0 m

Area 0.0 m2 b 0.0 m

Area 0.0 m2

All Pressures should be entered in Pascals, PaMeasurement Point Atmospheric Pressure, Pa Stack Pressure, Pa Static Pressure, Pa meas1, Pa Delta P, PaStack Temperature, CWater Vapour Content, %CO, ppm CO2, % N2, % O2, %

1 101200 101220 20 5.05 5.05 15.8 0 0 0.1 79.0 20.9

Mean 101200 101220 20.0 5.1 5.1 15.8 0.0 0.0 0.1 79.0 20.9

Mean density 1.216 kg/m3

Mean velocity 2.33 m/sec

Standard uncertainty of velocity 0.44 m/sec 19.0 % of value

Expanded uncertainty in velocity 0.89 m/sec 38.0 % of value

Circular duct Rectangular duct

Flow rate 140 m3/hour 140 m3/hour

Volume flow rate expanded uncertainty 53 m3/hour #DIV/0! m3/hour

Volume flow rate expanded uncertainty 38.0 % of value #DIV/0! % of value

28.85

dry molecular wt, g/mol

28.85

28.85

stack molecular wt, g/mol

28.85

Uncertainty in duct area measurement

Dry gas basis

Uncertainty in stack gas compositionUncertainty in Delta P transducer Enter uncertainties as (95%,k=2) where relevant

Uncertainty in temperature readout system

Uncertainty in atmospheric pressure transducer

Enter uncertainties as (95%,k=2) where relevant

Repeatability of Delta P transducer

Drift of Delta P transducer

Lack of fit of measurement system

Uncertainty calculation for Velocity and Volume Flow Rate Measurement by Pitot tube EN ISO 16911-1

Characteristics of pressure sensor used for Delta PEnter uncertainties as (95%,k=2) where relevant

Range of Delta P transducer

Resolution of Delta P transducer


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Appendix III: Certificates and Process Detail Form

Test Certificate Date 20/09/2019

AIR SCIENTIFIC (LK)**NEW**

Unit 5 Caherdavin Business Centre

Caherdavin

Ennis Road

Limerick

V94 NT63

Client Order No. BACHTL7050919

WK19-7067Certificate No.

Issue No. 1

Contact 12/09/2019Date ReceivedGregory Dempsey

Description 2 Tubes for VOCs Technique GC-FID

Sample No. 1068078 A3-6 VOC Method

O8(U)<1 µgBenzene

G8(N)14 ugCarbon tetrachloride

G8(N)<3 µgChloroform

O8(U)4 µgDichloromethane

O8(U)3 µgTetrachloroethylene

O8(U)<3 µgTrichloroethylene

Sample No. 1068079 Blank VOC Method

O8(U)<1 µgBenzene

G8(N)<3 ugCarbon tetrachloride

G8(N)<3 µgChloroform

O8(U)<3 µgDichloromethane

O8(U)<2 µgTetrachloroethylene

O8(U)<3 µgTrichloroethylene

RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen

Road. Salford. M5 3EZ

Page 1 of 2

Date 20/09/2019Test Certificate

WK19-7067Certificate No.

1Issue No.

Client AIR SCIENTIFIC (LK)**NEW**

Approved By Date

Jun Huan ZhaoTested By 13/09/2019Date

Joanne Dewhurst

Operational

For and on authority of RPS Laboratories Ltd.

Method Symbols (U) Analysis is UKAS Accredited

(N) Analysis is not UKAS Accredited

Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.

Results stated as ml are refering to the sample volume.

Analysis carried out on samples 'as received'

This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.

RPS Laboratories terms and conditions apply - a copy is available on request.

Tammy Illingworth 19/09/2019

20/09/2019

RPS Environmental Management Ltd trading as RPS laboratories. Unit 12. Waters Edge Business Park. Modwen

Road. Salford. M5 3EZ

Page 2 of 2

Process Details Form


Licensee Barclay Chemicals Contractor Air Scientific

Reg. Number P0522-01

Site Contact Elizabeth Monaghan Contractor’s Contact Mark McGarry

Role EHS Team Lead Role Operation manager

Signature Signature

Emission Point as per License

N/A N/A A3-6

Type of process

O Rotogravure printing O Rotogravure printing O Rotogravure printing

O Cement plant O Cement plant O Cement plant

O Electrical generation O Electrical generation O Electrical generation

O Steam boiler O Steam boiler O Steam boiler

O Other: O Other: x Other: process scrubber

Load of Process (Rotogravure printing: the solvent type and content of the ink, the ink delivery rate, the press temperature, the status of abatement plant, printing rate (m/s), etc.; Cement plant: Clinker source and loading rate, fuel source and load rate; Power plant: Electrical generation (MW) and fuel; Cement, chemical or pharmaceutical plants: Rate of material processed (tons/ hour); General manufacturing processes: Rate of items processed per hour; Steam boilers: Percentage with regards maximum capacity where appropriate )

N/A N/A 2,500 kg of MIPA per hour based on 8.5 hour day approx. 5 batches per day

Abatement system

O Bag filter O Bag filter O Bag filter O Electrostatic precipitator O Electrostatic precipitator O Electrostatic precipitator

O Cyclone O Cyclone O Cyclone

O Thermal oxidiser O Thermal oxidiser O Thermal oxidiser

O Active carbon bed O Active carbon bed O Active carbon bed

O NSCR O NSCR O NSCR

O SCR O SCR O SCR

O Dry scrubber O Dry scrubber O Dry scrubber

O Wet scrubber O Wet scrubber X Wet scrubber

O Lime injection O Lime injection O Lime injection

O Biofilter O Biofilter O Biofilter

O None O None O None

O Other:

O Other:

O Other:


List of solvents used per process (to be added to the solvent suite)

Emission point as per Licence

A1-1 A1-2 A3-6

N/A N/A Client to inform Environmental Efficiency once monitoring complete