5/21/2018 dise o de diagrama BAUR GLASSNER.xlsx

1/6

REACCION DE EQUIL IBRIO 1:

T C G Kcal K Xco Xco2

0 1.751 0.040 0.962 0.038100 1.171 0.206 0.829 0.171

200 0.605 0.525 0.656 0.344

300 0.065 0.944 0.514 0.486

400 -0.452 1.402 0.416 0.584

500 -0.950 1.855 0.350 0.650

600 -1.434 2.285 0.304 0.696

700 -1.907 2.681 0.272 0.728

800 -2.374 3.044 0.247 0.753

900 -2.835 3.375 0.229 0.771

1000 -3.417 3.860 0.206 0.794

1100 -4.407 5.029 0.166 0.834

1200 -5.398 6.323 0.137 0.863

1300 -6.390 7.724 0.115 0.885

1400 -7.381 9.210 0.098 0.9021500 -8.371 10.760 0.085 0.915

REACCION DE EQUIL IBRIO 2:

T C G Kcal K Xco Xco2

0 -1.196 9.060 0.099 0.901

100 -1.417 6.763 0.129 0.871

200 -1.576 5.347 0.158 0.842

300 -1.934 5.464 0.155 0.845

400 -2.374 5.900 0.145 0.855500 -2.791 6.152 0.140 0.860

600 -3.187 6.276 0.137 0.863

700 -3.562 6.310 0.137 0.863

800 -3.918 6.279 0.137 0.863

900 -4.254 6.202 0.139 0.861

1000 -4.448 5.802 0.147 0.853

1100 -4.213 4.684 0.176 0.824

1200 -3.958 3.865 0.206 0.794

1300 -3.683 3.249 0.235 0.765

1400 -3.392 2.774 0.265 0.735

1500 -3.085 2.400 0.294 0.706

REACCION DE EQUIL IBRIO 3:

T C G Kcal K Xco Xco2(i) Xco2(i i)

0 0.555 0.360 2.500 -1.500 0.375

100 -0.246 1.394 -5.535 6.535 0.541

200 -0.971 2.809 -1.479 2.479 0.626

0

100

200300

400

500

600

700

800

900

1000

1100

1200

13001400

1500

1600

0.0 0.1 0.2 0.3 0.

TEMPERATURA

C

DIAGRAMA BAOU

Sn

2

2 :

CO

CO

xSnO CO Sn CO si k

x

2

2

2 2 22 2 :

CO

CO

xSnO CO Sn CO si k

x

5/21/2018 dise o de diagrama BAUR GLASSNER.xlsx

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300 -1.869 5.160 -0.786 1.786 0.694

400 -2.826 8.269 -0.533 1.533 0.742

500 -3.741 11.410 -0.421 1.421 0.772

600 -4.620 14.340 -0.359 1.359 0.791

700 -5.469 16.920 -0.321 1.321 0.804

800 -6.291 19.110 -0.297 1.297 0.814

900 -7.089 20.930 -0.280 1.280 0.821

1000 -7.865 22.400 -0.268 1.268 0.826

1100 -8.620 23.550 -0.260 1.260 0.829

1200 -9.356 24.440 -0.254 1.254 0.832

1300 -10.073 25.090 -0.249 1.249 0.834

1400 -10.773 25.540 -0.247 1.247 0.835

1500 -11.456 25.830 -0.245 1.245 0.836

nota: la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.

REACCION DE EQUIL IBRIO 4:

T C G Kcal K Xco2 Xco(i) Xco(ii )

0 -29.729 6.14E+23 1.000 0.000 0.000

100 -25.508 8.73E+14 1.000 0.000 0.000

200 -21.238 6.47E+09 1.000 0.000 0.000

300 -16.958 2.93E+06 0.999 0.001 -0.001

400 -12.688 1.32E+04 0.991 0.009 -0.009

500 -8.435 2.42E+02 0.938 0.062 -0.066

600 -4.204 1.13E+01 0.743 0.257 -0.345

700 -0.004 9.98E-01 0.382 0.618 -1.620

800 4.189 1.40E-01 0.111 0.889 -8.032

900 8.352 2.78E-02 0.026 0.974 -36.945

1000 12.492 7 .17E-03 0.007 0.993 -140.463

1100 16.612 2 .27E-03 0.002 0.998 -441.526 1200 20.712 8.45E-04 0.001 0.999 -1184.431

1300 24.794 3.59E-04 0.000 1.000 -2786.515

1400 28.856 1.70E-04 0.000 1.000 -5883.353

1500 32.901 8.80E-05 0.000 1.000 ########

nota: la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.

2

( ) 2( ) 2 2

12 :

CO COg g

CO CO

x xCO C CO si k

x x

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4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

Xco2

R-GLASSNER+BOUDUARD

- CO - CO2

reaccin de equilibrio 1reaccin de equilibrio 2reaccin de equilibrio 3reaccin de equilibrio 4

5/21/2018 dise o de diagrama BAUR GLASSNER.xlsx

4/6

REACCION DE EQUIL IBRIO 1:

T C G Kcal K Xco Xco2

0 1.751 0.040 0.962 0.038

100 1.171 0.206 0.829 0.171

200 0.605 0.525 0.656 0.344

300 0.065 0.944 0.514 0.486

400 -0.452 1.402 0.416 0.584

500 -0.950 1.855 0.350 0.650

600 -1.434 2.285 0.304 0.696

700 -1.907 2.681 0.272 0.728

800 -2.374 3.044 0.247 0.753

900 -2.835 3.375 0.229 0.771

1000 -3.417 3.860 0.206 0.794

1100 -4.407 5.029 0.166 0.834

1200 -5.398 6.323 0.137 0.8631300 -6.390 7.724 0.115 0.885

1400 -7.381 9.210 0.098 0.902

1500 -8.371 10.760 0.085 0.915

REACCION DE EQUIL IBRIO 2:

T C G Kcal K Xco Xco2

0 -1.196 9.060 0.099 0.901

100 -1.417 6.763 0.129 0.871200 -1.576 5.347 0.158 0.842

300 -1.934 5.464 0.155 0.845

400 -2.374 5.900 0.145 0.855

500 -2.791 6.152 0.140 0.860

600 -3.187 6.276 0.137 0.863

700 -3.562 6.310 0.137 0.863

800 -3.918 6.279 0.137 0.863

900 -4.254 6.202 0.139 0.861

1000 -4.448 5.802 0.147 0.853

1100 -4.213 4.684 0.176 0.824

1200 -3.958 3.865 0.206 0.794

1300 -3.683 3.249 0.235 0.7651400 -3.392 2.774 0.265 0.735

1500 -3.085 2.400 0.294 0.706

REACCION DE EQUIL IBRIO 3:

0

100

200

300

400

500

600

700

800

900

1000

1100

1200

1300

1400

1500

1600

0.0 0.1 0.2 0.3

TEMPERATURA

C

DIAGRAMA B AOU

Sn

2

2 :

CO

CO

xSnO CO Sn CO si k

x

2

2

2 2 22 2 :

CO

CO

xSnO CO Sn CO si k

x

5/21/2018 dise o de diagrama BAUR GLASSNER.xlsx

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T C G Kcal K Xco Xco2(i) Xco2(i i)

0 0.555 0.360 2.500 -1.500 0.375

100 -0.246 1.394 -5.535 6.535 0.541

200 -0.971 2.809 -1.479 2.479 0.626

300 -1.869 5.160 -0.786 1.786 0.694

400 -2.826 8.269 -0.533 1.533 0.742

500 -3.741 11.410 -0.421 1.421 0.772

600 -4.620 14.340 -0.359 1.359 0.791

700 -5.469 16.920 -0.321 1.321 0.804

800 -6.291 19.110 -0.297 1.297 0.814

900 -7.089 20.930 -0.280 1.280 0.821

1000 -7.865 22.400 -0.268 1.268 0.826

1100 -8.620 23.550 -0.260 1.260 0.829

1200 -9.356 24.440 -0.254 1.254 0.832

1300 -10.073 25.090 -0.249 1.249 0.834

1400 -10.773 25.540 -0.247 1.247 0.835

1500 -11.456 25.830 -0.245 1.245 0.836

nota: la fraccion de CO2 tiene dos raices i,ii y se toma para el grafico ii.

REACCION DE EQUIL IBRIO 4:

T C G Kcal K Xco2 Xco(i) Xco(i i)

0 -29.729 6.14E+23 1.000 0.000 0.000

100 -25.508 8.73E+14 1.000 0.000 0.000

200 -21.238 6.47E+09 1.000 0.000 0.000

300 -16.958 2.93E+06 0.999 0.001 -0.001

400 -12.688 1.32E+04 0.991 0.009 -0.009500 -8.435 2.42E+02 0.938 0.062 -0.066

600 -4.204 1.13E+01 0.743 0.257 -0.345

700 -0.004 9.98E-01 0.382 0.618 -1.620

800 4.189 1.40E-01 0.111 0.889 -8.032

900 8.352 2.78E-02 0.026 0.974 -36.945

1000 12.492 7.17E-03 0.007 0.993 -140.463

1100 16.612 2.27E-03 0.002 0.998 -441.526

1200 20.712 8.45E-04 0.001 0.999 -1184.431

1300 24.794 3.59E-04 0.000 1.000 -2786.515

1400 28.856 1.70E-04 0.000 1.000 -5883.353

1500 32.901 8.80E-05 0.000 1.000 ########

nota: la fraccion de CO tiene dos raices i,ii y se toma para el grafico i.

2

( ) 2( ) 2 2

12 :

CO COg g

CO CO

x xCO C CO si k

x x

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0.4 0.5 0.6 0.7 0.8 0.9 1.0 1.1

Xco2

R-GLASSNER+BOUDUARD

- CO - CO2

reaccin de equilibrio 1

reaccin de equilibrio 2reaccin de equilibrio 3reaccin de equilibrio 4