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Deep-Sea Biogenic Sediments
Calcareous Ooze
Biogenic calcareous ooze composed of precipitated CaCO3 (usually calcite, but occasionally aragonite) shells of microscopic plankton
Planktonic foraminifera
Coccolithophore
Dominant calcifying plankton evolved in Mesozoic (coccolithophores in Triassic,
forams in Jurassic) so deep-sea carbonate likely rare prior to that time
Chalk – carbonate rock made nearly entirely from coccolithophores (calcareous nannofossils)
What controls accumulation of calcareous ooze in the ocean?
What factors promote accumulation of carbonate sediment?
Ca+2 + CO3-2 ↔ CaCO3
1. Concentration of Ca and CO3
Ω=[Ca+2 ] [CO3−2 ]
K sp
W is the saturation state of calcite (or aragonite)
When W < 1, carbonate is undersaturated and will dissolve
When W > 1, carbonate is supersaturated and will precipitate2. Temperature
W higher in warm water (shallow, tropical water)W higher at low pressure (shallow water)
3. Pressure
[Ca] is relatively constant because of calcium’s long residence time
Carbonate concentration [CO3] is most variable and is the main control on WCarbonate speciation is pH-sensitive
CO2 + H2O ↔ H2CO3
H2CO3 ↔ H+ + HCO3-
HCO3- ↔ H+ + CO3
-2
Adding CO2 reduces pH and [CO3]
W decreases with depth because of decreasing pH, decreasing T, increasing P
Lysocline: depth at which calcite becomes undersaturated (W<1)
W<1
W>1Calcite lysocline
W<1
W>1
But carbonate sediments can still accumulate below lysocline as long as sediment supply exceeds the rate of dissolution
Calcite compensation depth (CCD)
Depth where dissolution rate exceeds sedimentation rate and no calcite is preserved in sediment (like a snow line)
There is also an “aragonite compensation depth” which is slightly shallower (because aragonite is more soluble than calcite)
Typically 3-5 km depth today
Diatoms
Radiolarians
Skeletons constructed from opal-A, amorphous hydrous silica: SiO2 · nH2O
Siliceous Ooze
Siliceous ooze – radiolarian chert
A biogenic sedimentary rock formed from silica (SiO2) skeletons of microscopic radiolarians (marine protists; Cambrian-Recent)
Radiolarians
Diatoms
Miocene, Gulf of California
Siliceous ooze – diatomite
A biogenic sedimentary rock formed from silica (SiO2) skeletons of microscopic diatoms (marine/freshwater; Cretaceous-Recent)
Highly undersaturated in surface ocean (concentration <10 mM)
Still undersaturated in deep ocean but with substantial inter-ocean variation
SiO2(OH)2-2, SiO(OH)3
-, Si(OH)4
1. Preserved where silica flux (sedimentation rate) is high so that silica supply exceeds silica dissolution
2. Siliceous microfossils covered by organic coating, protecting their frustules from dissolution even after death
Biogenic silica production (g/m2/yr)
Abyssal Red Clay
Primary source: windblown dust
Deep-sea clay deposited everywhere but dominates wherever carbonate or siliceous sedimentation rates are low (below CCD, mid-latitudes)