190
Example 15
OPh
O
O
1. hQ, cyclohexane, 83%
2. H2 (3 atm), Pd/C (10%) HOAc, rt, 18 h, 83% O
O
Example 29O
OH
hQ, MeOH
> 90%
O
HO
O
O
H
H
H
H
References
1. de Mayo, P.; Takeshita, H.; Sattar, A. B. M. A. Proc. Chem.
Soc., London 1962, 119. Paul de Mayo received his doctorate from
Sir Derek Barton at Birkbeck College, Uni-versity of London. He
later became a professor at the University of Western Ontario in
London, Ontario, Canada, where he discovered the de Mayo
reaction.
2. Corey, E. J.; Bass, J. D.; LeMahieu, R.; Mitra, R. B. J. Am.
Chem. Soc. 1964, 86,5570.
3. Challand, B. D.; Hikino, H.; Kornis, G.; Lange, G.; de Mayo,
P. J. Org. Chem. 1969,34, 794.
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Oppolzer, W.; Godel, T. J. Am. Chem. Soc. 1978, 100, 2583. 6.
Oppolzer, W. Pure Appl. Chem. 1981, 53, 1181. (Review). 7.
Pearlman, B. A. J. Am. Chem. Soc. 1979, 101, 6398. 8. Kaczmarek,
R.; Blechert, S. Tetrahedron Lett. 1986, 27, 2845. 9. Disanayaka,
B. W.; Weedon, A. C. J. Org. Chem. 1987, 52, 2905. 10. Crimmins, M.
T.; Reinhold, T. L. Org. React. 1993, 44, 297588. (Review). 11.
Quevillon, T. M.; Weedon, A. C. Tetrahedron Lett. 1996, 37, 3939.
12. Blaauw, R. H.; Brire, J.-F.; de Jong, R.; Benningshof, J. C.
J.; van Ginkel, A. E.;
Fraanje, J.; Goubitz, K.; Schenk, H.; Rutjes, F. P. J. T.;
Hiemstra, H. J. Org. Chem.2001, 66, 233.
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