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International Conference on the 20 th Anniversary of Bhopal Gas Tragedy “Bhopal and its Effects on Process Safety” The Indian Institute of Technology, Kanpur, India, December 1 to 3, 2004 Hazardous Material Storage Installations Steps to address concerns on Safety and build Public Confidence D.C Sorte, Director (Technical) Dr M.P Sukumaran Nair*, Dy Chief Engineer (Corp Planning) Fertilizers And Chemicals Travancore (FACT) Ltd Cochin, India Abstract. Much public concern is raised on hazardous material bulk storages at vulnerable locations that cater the requirements of basic industries. This concern has grown into alarming proportions after the ‘Bhopal’. Over these years considerable improvements have taken place in almost all aspects relating to the design, construction, operation, maintenance and troubleshooting, assessment and mitigation of risk from such installations. Relying on concepts of inherent safety and with the help of modern 1

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Page 1: DC Sorte Storage of Hazardous Chemicals s-62.doc

International Conference on the 20th Anniversary of Bhopal Gas Tragedy“Bhopal and its Effects on Process Safety”The Indian Institute of Technology, Kanpur, India, December 1 to 3, 2004

Hazardous Material Storage InstallationsSteps to address concerns on Safety and build Public Confidence

D.C Sorte, Director (Technical)Dr M.P Sukumaran Nair*, Dy Chief Engineer (Corp Planning)

Fertilizers And Chemicals Travancore (FACT) LtdCochin, India

Abstract.

Much public concern is raised on hazardous material bulk storages at vulnerable locations

that cater the requirements of basic industries. This concern has grown into alarming

proportions after the ‘Bhopal’. Over these years considerable improvements have taken place

in almost all aspects relating to the design, construction, operation, maintenance and

troubleshooting, assessment and mitigation of risk from such installations. Relying on

concepts of inherent safety and with the help of modern instrumentation and renewed

operating philosophy such units are operated today with a high degree of safety and

reliability. Competent Emergency Management and Response Plans are also in place to

tackle emergency situations that are likely to crop up even with the remotest probability. This

paper attempt to trace the course of developments in increasing process safety to reasonably

address public concerns on the risk to the neighboring community emanating from units with

a particular review in the case of port based refrigerated atmospheric pressure ammonia

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storage tank which store and handle large quantities of ammonia imported for fertilizer

manufacturing.

Industrial accidents remain a major concern before the Governments consequent to the loss

of lives, damage to property and environment that is inflicted on the society besides upsets in

tranquil and a heavy economic strain. Along with the growth of the processing industry, the

problem of accidents caused in the industry poses a big question with its regional and global

implications and efforts are also underway to minimize the damages and ensure all safer

working environments around industrial installations. Known experiences of accidents

caused in the industry over and again caution us that the price of process safety is

increasingly becoming a concern on the profitability of the unit, morale of its employees and

the public image of the institution. Still, the growth and development of the processing

industry is not deterred by occasional mishaps. At the same time these lessons from past

industrial accidents urge industry operators to continue efforts to better their safety

standards and enhance pubic perception of the industry. Incidents like Flixborough, Sevaso,

Bhopal, Chernobyl, North Sea and recently Toulouse etc have taught us where do we stand

with regard to achieving an accident free operating environment in the chemical processing

industry, which direction we are to go, and what commitment is needed for future.

Everywhere and especially in the matter of process safety, Murphy’s Law holds good and it

also provide the impetus for continuous research and improvement to unearth , identify and

overcome the hidden and the unknown through a process of elimination.

Key Words: hazard, risk, ammonia

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The safety and environmental concerns are often shared by public interest groups, which lead

to outcries, litigations and in certain cases even closure of units. The loss to the society on

account of such closures is enormous and thus it is in the interest of the industry and the

community that dialogues to address the conflict between them are always maintained. This

prescription, though looks simple, is difficult to practice in the real operating environment of

the industry. More often, a cultural change is needed to understand and effectively address

the community’s rights to know and Government’s concern on public health and safety.

Efforts are to be organized from the side of the industries to empower the public understand

what is happening with in the processing facilities and effectively communicate the risk from

such operations. Major industries have a specific role in this regard in building public

understanding as a first step to enhancing public confidence and build a better community

perception on the industry. At the State level, there shall be efforts to organize effective

mechanisms to ensure public safety through well-defined policy prescription and legislation.

In the past 20 years since Bhopal, there is an increasing concern and resurgence of public

interest in the matter and so also the efforts to address them have increased considerably.

Major contributory factors to accidental releases in the hydrocarbon –chemical industries are

mechanical failures and operator error. Today, industries use a predictive maintenance

strategy based on condition monitoring of equipment to overcome the shortcomings of

preventive maintenance. It is also possible to most satisfactorily assess the integrity of

equipment and structures with the help of modern inspection tools and methods and predict

likely failure situations well in advance to enable them to take effective remedial action. A

recent development in ultrasonic technology with its patented equipment and technology

eliminates the use of hazardous chemicals associated with radiographic examination

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commonly used for flaw detection. Better training, simplified procedures and work practices

and a ready access to vital information help to reduce human error and enable the operator to

spot exact locations in the plant where problems are likely to crop up and take corrective

actions before the situation go out of control. Thus with the currently available technology

and skill it is possible to operate and maintain hazardous installations with a very high degree

of safety and environmental protection standards.

The following case study illustrates the success of the above approach.

The Willington Island Ammonia Import Terminal belonging to the major fertilizer producer

and Govt Company, Fertilizers And Chemicals Travancore (FACT) Ltd came under suspicion

that it posed a serious threat to safety the local community of Cochin. A Public Interest

Litigation (PIL) initiated by a local NGO before the High Court.

The facts came under judicial scrutiny are

In the case of a catastrophic accident to the storage tank resulting in a major crack or

rupture it would lead to disastrous and devastating consequences of annihilating all

living beings inverting the city of Cochin a city of dead and nearby places a morbid

graveyard.

The catastrophic failure of the tank is not an unreal or remote possibility but a credible

and contingent possibility to be reasonably anticipated on the facts unfolded in the

case.

Though the catastrophic event is only a possibility and when it would happen is

unpredictable it is unwise to forget or slur it. Once it happens it is irreversible so

prudence dictates not complaisance, but positive action.

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The Ammonia tank

The 10000 MT double wall double integrity refrigerated atmospheric ammonia tank was built

as per API Code 620 including Appendix R in the year 1976 by UHDE GmbH , Germany to

receive imported ammonia consignments for the phosphatic fertilizer plants of FACT located

at Ambalamedu 30 kilometers from the Cochin Port. The tank has 41.6 metre in diameter and

is 17.4 metre tall. Thickness of the bottom plate 5 millimeters and that of the annular plate is

8mm. The inner cup shell consists of six courses , design thickness varying from 8 mm to

11.2 mm .Outer shell consists of 14 courses and the design thickness varying from 5 mm to 22

mm. Roof is constructed with built up support beams in the spherical segments and with

connection between the roof plates and the beams. The thickness of the roof plate is 5 mm.

The outer tank is anchored to the reinforced concrete foundation with tie rods.

During the construction phase while the tank was tested hydraulically, at a water load of 8000

MT 6 piles (among 217 ) in the outer row was found cracked. A detailed investigation was

done by Central Building Research Institute (CBRI), Roorkee and a thorough rectification

was done. Subsequently water load test was conducted at a maximum of 10000 MT plus 1600

MT of over pressure load. Thus the tank was tested at a water load of 11600 MT after the

repairs and the differential settlement was found to be with in acceptable limits. Clearance for

loading ammonia was also given. Since then the tank continued to be in operation till

1985.The tank was decommissioned and inspected thoroughly in 1985 . During this time

FACT engaged Indian Institute of Technology (IIT) Chennai to ascetain the soundness of the

foundation and integrity of the tank. After exhaustive studies IIT , Chennai concluded that the

foundation was in sound condition after operation of 10 years. The tank and associated

facilities were got inspected by the world-renowned inspection agency M/s TUV,

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Netherlands. They suggested certain measures to avoid normal deterioration of the tank while

in service FACT implemented their recommendations and the tank was serviced back to

operation.

The tank is insulated by poly urethane foam and bottom of the tank by poly styrene foam

board. The tank is protected against over pressure and vacuum by two relief/vacuum valves.

Other associated facilities included two large capacity refrigeration compressors (for use

during tank loading), two pressure holding compressors (one driven by motor and the other

diesel engine), a diesel generation set to take care of power failure situations, three pumps for

loading rail wagons and barges, three sets of wagon loading and one set og barge loading

arms, connected piping, cooling tower, instruments and a flare system.

Liquid ammonia at -33 deg C is moved in rail wagons to the plant. The tank terminal is a self

contained facility with provisions for emergency supplies and is guarded round the clock by

security personnel. It was operated and maintained by competent personnel with all

mandatory inspections, tests and certifications.

Based on its finding that ‘the catastrophic failure of the tank is not a remote possibility, but a

credible and contingent possibility to be reasonably anticipated on the facts unfolded in the

case’, the High Court

ordered to decommission, empty and close down operations of the installation.

Against the verdict FACT appealed to the Supreme Court of India for reconsidering the case.

The Supreme Court appointed Engineers India Limited (EIL), a consulting group of

international repute to re-examine the issues and submit a report.

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Following the Supreme Court directive, EIL conducted extensive inspection and tests to

ascertain the present condition of the tank. It included

1). Visual examination

2). Non-Destructive Test (NDT) methods such as Schmidt Hammer test (as per IS

13311 Part II) on piles, beams and slabs to assess strength of concrete

3). Ultrasonic Pulse Velocity Test to assess condition of structures as cracks, voids etc.

4). Carbonation Test for assessing alkaline protection of reinforcement steel

5). Test of Compressive strength for concrete (IS 456:2000)

6). Half-Cell Potentiometer Test to assess corrosion of steel reinforcements and

7). Chemical analysis of soil samples.

From the above analysis EIL inferred that the foundation of the tank is in a sound condition.

EIL also evaluated the heath and integrity of the tank through visual inspection and with the

help of a series on NDT methods.

These methods involved use of

1). Wet Fluorescent Magnetic Particle Testing (WFMPT) to ensure that weld joints are

free from cracks and discontinuities,

2). Liquid Penetrant Testing (LPT) for weld joints in the annular area not accessible

to WFMPT 3). Ultrasonic thickness measurement (UTT) of shell, plates, piping,

nozzles,

4). Ultrasonic flaw detection (UFD) to detect sub surface defects in T joints of shell

plates of inner cup,

5). Hardness testing of weld heat affected zones to know degradation of parent

material,

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6). In-situ metallographical examination by advanced replication technique,

7). Vacuum box leak test to ensure that there is no leak through bottom plates of inner

cup and annular plates of inner and outer tanks,

8). Water load test at 10000 MT ,

9). Hydro pneumatic test by pressurizing to 1000 mm WG for one hour to see any

settlement and then maintaining a vacuum of 50 mm WG for 30 minutes .

All these tests were satisfactory and it was considered that the tank is in sound condition.

EIL further evaluated the probabilities of leaks and other failures from accessories and

connected systems. Reviewing the chronology of the history of leaks occurred in the

installation EIL opined that the leaks had developed outside the storage tank and can be

handled effectively by proper monitoring and maintenance.

Safety audit

FACT conducted a full fledged safety audit and Hazard and Operability (HAZOP) study in

1988 engaging M/s Cremer & Warner Ltd (CWL) , London, UK who are specialists in the

field. The idea was to identify the potential hazards involved in the plant and their likelihood

of occurring and its effect on the local population. They reviewed site safety policies, safety

responsibilities, design standards and guidelines, operating procedures, safety checks,

inspection and maintenance, modifications, detection systems, disaster management plans,

training facilities, fire fighting, emergency shut down systems etc and identified areas of

concern

Results of the above study showed that generally the leaks from the plant would not appear to

affect the surrounding population to a significant extent. However, reduction of the potential

effects of some of the release cases can be achieved by the use of automatic shut off facilities.

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Additionally containment of the spill and hence boil off rate will reduce the distance of the

cloud travel and hence the risk to the local population. Comprehensive inspection , testing and

maintenance routines will also help in minimizing likelihood of any failure leading to the

release of ammonia and therefore these procedures should continue to be carried out on a

regular schedule with periodic review of maintenance frequencies. Following the report the

recommendations were implemented by FACT.

CWL concluded that ‘the management and organization structure appears to be well balanced

and efficient with good back up from the technical services, maintenance and inspection

groups. Due to the sensitive siting of the tank the management have taken every effort to

ensure the integrity of the facility is not undermined and that it is operated by well trained,

competent staff Everyone interviewed at ite had a good working knowledge of the plant and

how to react in an emergency situation. All senior operations staff were qualified engineers

and had long experience of the operation of a chemical plant’.

Expert opinion

During the course of the hearing, the High Court sought the opinion of Dr John M.Campbell

of CHERRYROSE Ltd, UK to go into the merits of the PIL. Dr Campbell after studying of

the documents made available to him suggested that the issue is not limited to leakages that

can be contained and which may not cause major hazards. He was of the opinion that worst

cases like tank rupture, terrorist attack , aircraft crash, extreme high speed wind or cyclone

and earthquake should have been considered. CWL has not addressed these issues, he pointed

out. Later EIL carried out a separate HAZOP study and Quantitative Risk Analysis covering

all these issues.

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Risk assessment study by EIL

M/s Engineers India Ltd (EIL) conducted another HAZOP study and quantitative risk

assessment (QRA) covering the tank, ammonia ship unloading facilities, barge and rail

loading facilities, storage tank and associated facilities and flare and other utilities. The

recommendations arisen out of the above studies intended to improve safety during operation

were listed. The QRA identified the type of hazards that could emanate from the facilities,

likely failure scenarios and evaluated the potential hazards, their damage effects and risk

posed to the surrounding population in the event of an unforeseen release of ammonia. The

likely hood of a catastrophic failure as an an air crash on to it was also evaluated. EIL

suggested certain mitigation measures also to reduce the hazard and its risk potentials.

Major observations and recommendations of the study are

Catastrophic failure of the tank can be considered as a remote possibility considering the fact

that the storage is a double containment type of construction.

The failure frequency associated with the catastrophic failure of such storage tank indicates

that this event may be classified as an unforeseeable scenario.

Possible causes that could lead to this remote scenario are earthquakes, because of terrorism

or air crash on to the tank.

Latest prevalent seismic data has been already considered during the design of the tank.

Sabotage is an issue that cannot be predicted and it can cause disaster at any time and to any

place even with the best of safety measures. A properly tight security and surveillance of the

installation is the answer in this case.

The study also assessed the air crash rates and compared the assessed crash rates with that of

the inherent failure frequencies associated with such failures. It is observed that the assessed

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crash rate on to the tank with respect to one of the runways, is 1.36 per million years which is

of the same order of magnitude as that due to inherent failures. The assessed crash rate due to

second runway is estimated about 0.67 times that due to inherent failures. Thus the possibility

of air crash on the tank can be considered as remote and pose a low level of risk.

In the case of a catastrophic failure of the tank, fatalities to one percent of the exposed

population can be expected to reach about 1.5 kilometres from the storage facilities under

stable weather conditions. It is the control room and its personnel that are most vulnerable to

the havoc. On this account, EIL recommended pressurizing of the control room to make it air

tight, provision for ammonia detectors at vulnerable points, provision for alternate breathing

air system and an effective personal evacuation system.

Rupture of the ship-unloading arm could be caused by roughness of the sea leading to undue

stresses subjected on the arm. A quick connecting and disconnecting coupling will be able to

alleviate the above situation. A provision for emergency relief system for the loading and

unloading arms, automatic shutdown facilities for loading and unloading operations and

provision of ammonia detectors at strategic locations etc. would go a long way to render the

installations safe.

Thermal radiation effects at ground level during flaring of ammonia vapors from the flare

were studied. It was found that the maximum ground level thermal radiation intensity is 0.2

KW/M2 and can be considered safe for operating personnel and for general population. The

thermal radiation intensity at the height level of the tank is found to be 3.8 KW/ M 2 which is

also considered acceptable.

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The discharge from blow off of the safety valves should be disposed carefully by leading it to

the flare.

Pilot burners of the flare are also to be kept lit.

A well coordinated emergency management plan is to be developed to address the detailed

on-site and off-site action plans that need be initiated in the event of any release from the tank

After the above exhaustive review EIL concluded that the tank could continue in service in its

present condition subject to certain measures being taken by the company as suggested by

them to further enhance the safety in operations.

The final verdict

On the basis of the report the Supreme Court held that “ On both these issues (structural

integrity of the tank and its operations) EIL has recommended continuance of the tank in its

present condition subject to certain measures being taken by the company The company has

taken those steps. We have to strike a balance between existing utilities which exist in public

interest on the one hand and human safety conditions on the other hand. It is not in dispute

that such plants are needed for the welfare of the society. In modern times we have nuclear

plants, which generate electricity. Their structural integrity and their operations are vulnerable

to certain risk. However, generation of electricity is equally important and within the

prescribed limits society will have to tolerate existence of such plants. It is for this reason that

we called for a report from EIL so that they can examine the structural integrity of the tank ,

its operations and the measures which are required o be taken to minimize the risk factors. If

arguments of the original petitioner is accepted then no such utility can exist, no power plant

can exist, no reservoir can exist no nuclear reactor can exist. We do not discount such risks

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but we have to live with such risks which is counterbalanced by services and amenities

provided by these utilities”. The apex court set aside the order of the High Court.

Thus the tools of process hazard analysis have become successful in logically assessing risk

emanating from installations in a credible manner so that the fear in the minds of the public

are removed and pubic acceptability is increased.

Exactly on a similar line the United States Environment Protection Agency (USEPA)

commissioned a detailed study in 1995 viz, “Innovative High Risk/High Priority Anhydrous

Ammonia Study” – Tampa Bay on the various safety aspects in the storage of liquid ammonia

on the Ammonia storage installation at Tampa Bay Area of Florida, USA. The part of the

state of Florida housed three major storage facilities belonging to CF Industries, IMC-Agro

and Farmland Hydro –all major producers of fertilizers. The combined maximum storage

facility is just over 100000 MT of Ammonia and every year 2.5 to 3 million MT of material is

handled in these installations. The main thrust of the study was to examine the level of risk

posed to the local community of half a million people. The risk assessment was done by

addressing the severity of the consequences arising out of any harmful occurrence coupled

with the likelihood of such a happening. The report also considered the following location

specific problems of the Tampa Bay area

1. Presence of a small air field only 1.1 KM from one of the storage tanks

2. A scrap metal yard nearby and

3. The possibility of a terrorist attack or earthquake.

The major findings of the exhaustive study were the following

1. The risk posed to the local community by the storage tanks is relatively small in view

of the low probability of a release.

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2. The Ammonia industry in the Tampa Bay area has shown itself to be a model for other

industries in regard to safety and concern for community welfare

3. Each of the industries are to continue to improve operations with a view to provide the

highest degree of safety possible to its employees and the surrounding community

New directions in Hazard Management

Today, industries are tuned towards more and more descriptive approaches to tackle human

error, which is the prime cause for bad memoirs from the industries. At the technology level,

there are several advancements in the bygone years, which culminated into the formulation of

standard practices in addition to occasional audits, adherence to code of practices in design,

operation and maintenance, which were prevalent earlier. The Process Safety Management

(PSM) today is a fully developed engineering stream and supports the industry with a reliable

safety management programme. Its well-defined objectives and goals, clear documentation of

systems and procedures, mechanism for checking projects and designs, risk management

programme, efforts to bring cultural changes in the organization, mechanism to ensure

process equipment and integrity, procedures for instant investigation and provisions for

training people to update their knowledge and understanding.

The degree of the havoc itself has been assessed in terms of

A most likely release scenario eg. Leaks from pump seal or relief valve

A most probable worst-case scenario eg. Truck crash or movement of a ship severing a

pipeline during unloading

Absolute worst case scenario eg. Total release from a tank due to an aircraft crashing

in on the facility and

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A nightmare scenario eg. Simultaneous release of contents of all neighboring storage

tanks by earthquake or terrorist action

More and more inherent safety aspects are being integrated into the design of projects and

processes coupled with adequate risk reduction strategies and risk management plans. Inter-

disciplinary exercises implying creative thinking among a team of experts unearth hidden

situations that can crop up to culminate in a disaster. The HAZOP and HAZAN exercises are

examples to the above. Most major accident industries today have reasonable estimates of

releases, hazard distance and evacuation and environment management plans. They also

ensure neighborhood hospital preparedness to support victims, effectively co-ordinate with

the civic administrations, government departments and neighboring institutions.

Two levels of risk that are usually encountered are the individual risk and societal risk.

Maximum permissible level of individual risk that is accepted worldwide is one in one million

per year (1x10-6/man/year). Most of the studies have shown that the risk to life for members

of the public from industrial activities is less than one in ten million per person per year and

this level is considered acceptable for the community. The accuracy of quantitative risk

assessment heavily depends on the authenticity of the data, reliability of the model used and

human error. The risk, as revealed from exercises of this kind done in numerous installations,

is often estimated very high when compared with real life accident situations occurring in the

operating environment in the industry.

Process design: changing trends

There has been a sea change in the design concepts with inputs from safety and loss

prevention. Equipment reliability and efficient operations are the corner stone of safety and

long term profitability. With plant capacities getting larger the concerns of safety and

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economic loss rising out of short production outages are indeed high. Remaining life

assessment of equipments, redundancy of instruments, software support operations have all

contributed to maintain a better safety environment around installations. A recent advance in

this line is the online performance monitoring (OPM) which is based on a rigorous

engineering model which is capable of signaling the deterioration in the performance well

before a mechanical collapse. Such dynamic systems are developed to suit individual

installations incorporating thermodynamic efficiencies, process changes such as ambient

conditions, stream composition, operating parameters etc.

Safety standards and regulatory compliance

The regulatory and social requirements for safety and reliability has initiated a revolution in

the safety technologies with an increased dependence on ‘smart’ instruments, integrated

controls and a variety of system architecture. Though, any new development towards attaining

an increased safety level is welcome it is also necessary that the whole must be done with in

an overall safety framework which maintains an appropriate level of safety and which

provides confidence that this is being achieved. An example of such a framework is the

development in the UK, of a Conformity Assessment of Safety related Systems (CASS),

which certifies safety related systems. It is a conformity assessment scheme that recognizes

compliance with the requirements of the international standard IEC 61508 and IEC 61511.

These standards define the Safety Integrity Level (SIL), the level of protection needed for a

particular safety instrumented system. There are four possible discrete SILs determined by

multiplying the risk level factors based on frequency and severity. If the product is less than 6,

the risk is low and only SIL 1 protection is needed. If it is between 7 and 15, the risk is

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moderate and SIL 2 protection is needed. For a product between 16 and 25 , the risk is

considered high and indicate the need for SIL 3 protection.

Creating awareness and preparedness

A major initiative in the public interest with regard to hazardous installations called

Awareness and Preparedness for Emergencies at Local Level (APELL) was developed by the

United Nations Environment Programme, in partnership with industry associations,

communities and governments following some major industrial accidents that had serious

impacts on health and the environment. APELL is now being implemented in nearly 30

countries around the world. APELL is a tool for bringing people together to allow effective

communication about risks and emergency response by reducing risk; improving

effectiveness of response to accidents and allowing ordinary people to react appropriately

during emergencies. APELL was originally developed to cover risks arising from fixed

installations, but it has also been adapted for specific applications. The APELL launched in

1988, sets out a ten-step process for the development of an integrated and functional

emergency response plan involving local communities, governments, emergency responders

and others. This process creates awareness of hazards in communities close to industrial

facilities, encourages risk reduction and mitigation, and develops preparedness for emergency

response. Communication is often between the three main groups of stakeholders - company,

community, and local authorities. Discussion on hazards usually leads to the identification of

risk reduction measures, thus making the area safer than before. Structured communication

between emergency response bodies (public and company) results in a better-organized

overall emergency response effort. APELL can apply to any risk situation, whether industrial

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or natural. Any party can initiate it, although companies can be expected to take the lead. It

can be facilitated by governments, or by industry associations.

Though things are fine and well coordinated, in most countries the public is little aware of

such strengths associated with the industry. Even in countries where the ‘community right to

know’ legislation has come to effect, most people do not believe what the industry

communicate to them. Thus, there is need to regularly explain in clear-cut terms what risk

they are posed from an industry and how safe are the neighboring industrial environments.

They have to be told that there is an acceptable level of risk that were subjected in our pursuit

for development and industries are committed to maintain their operations within the levels of

the acceptable limits. The preparedness of the industry for management of the abnormal

situations, real time monitoring of systems and equipment and guard against human error

should be well publicized. The social cause for the industries justify such a risk level and the

efforts to further sharpen the tools for process safety shall also continue.

Even in the best-designed and operated plants accidents take place. The question that is often

asked is, how safe is ‘safe enough’ when it comes to potentially risky processes in chemical

plants? Here comes the relevance of a workable environment management plans. Industries

are capable of developing such plans. But the most important point is that such plans are to

be updated very frequently, tested and kept ready so that it can be pressed to operation as and

when such situations arise.

In other words, Bhopal reminds us that process safety needs continuous improvement,

training, group exercises, building more and more security incorporating an effective social

repatriation of victims of industrial disasters also.

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References 

1. A New World of Safety, Emerson Process Management, Austin, Texas, USA, 2003, www.PlantWeb.com

2. Andrews J.D and Moss T.R. Reliability and Risk Assessment, Professional Engineering Publishing Ltd., London, UK, 2002.

3. Awareness and Preparedness for Emergencies at Local Level (APELL) Handbook, A Process for Responding to Technological Accidents, Industry And Environment office, United Nations Environment Programme (UNEP), 1988

4. Barry Lytollis, MTL Ltd, Safety Instrumentation Systems : How Much is Enough?, Chemical Engineering, McGraw Hill Publications,USA, Dec 2002

5. Bwonder B. Industrial Hazard Management, Administrative Staff College of India, Hyderabad, India, 1986.

6. Code of Practice for Liquid Ammonia Storage Vessels, Projects and Developments India Ltd (PDIL), Sindri, India, 1988 

7.  Kolluru R.V. Understand the Basics of Risk Assessment, Chemical Engineering Progress, American Institute of Chemical Engineers (AIChE), New York, March 1991.

8.  Lemkowitz. SM, Korevaar. G, Marmsen.GJ and Pasman.HJ. Sustainability as the Ultimate Form of Loss Prevention: Implications for Process Design and Education, Proceedings of the 10th International Symposium on Loss Prevention and Safety Promotion in the Process Industries, European Federation of Chemical Engineering, Stockholm, Sweden, 2001.

9. Major Hazard Control - A Practical Manual, International Labour Organisation, Geneva 1988.

10. Nair, MP Sukumaran, Hazard Identification and Management –an Overview Hydrocarbon Processing, Gulf Publishing Co, Huston, USA, July 2002

11. Ozog Henry and Bendixen M. Hazard Identification and Quantification, Chemical Engineering Progress, American Institute of Chemical engineers (AIChE), New York, 1987.

12. Premises for Risk Management, Dutch National Environment Policy Plan, Publication of the Directorate General for Environmental Protection at the Ministry of Housing, Physical Planning and Environment, The Hague, 1988-89

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13. Prevention of Major Industrial Accidents, International Labour Organization (ILO) Office, Geneva, 1991

14. R. Mallett, Total Prevention Systems, Inc, Rate your risk management plans, Hydrocarbon Processing, Gulf Publishing Co, Huston, USA, Aug 1992

15. Recommendations for the Safe and Reliable Inspection of Atmospheric Refrigerated Ammonia Storage Tanks, European Fertilizer Manufacturing Association (EFMA) , Brussels, Belgium, 2002

16. Reducing costs with PlantWeb® digital plant architecture: Safety, Health, & Environment, Emerson Process Management, Austin, Texas , USA, 2003

17. Smith. Kevin E. and Whittle David K. Six steps to effectively update and revalidate PHAs, Chemical Engineering Progress, American Institute of Chemical engineers (AIChE), New York, Jan 2001.

18. Stanley M.Englund, Design and operate plants for inherent safety, Chemical Engineering Progress, American Institute of Chemical Engineers (AIChE), New York, March 1991

19. Steve Kemp, Jan Seiving, Occidental petroleum Corp, The Road to Zero Accidents, Chemical Engineering, McGraw Hill Publications,USA, June 2003

20. Steve Wilson, Wilson Group Communications Inc., Develop an Effective Crisis Management Strategy, Chemical Engineering, McGraw Hill Publications,USA, Sept 2003

21.  Technical Guidance for Hazard Analysis - Emergency Planning for Extremely Hazardous substances, US Environment Protection Agency (EPA), Washington, USA, 1987.

22.  Techniques for Assessing industrial Hazards-A Manual, World Bank Technical Paper No 55, The World bank, Washington, USA, 1988 .

23. The CASS Scheme, Accredited Certification to IEC 61508,The CASS Secretariat, Kent, UK, 2004

24. US Environmental Protection Agency, Innovative High Risk/ High Priority Anhydrous Ammonia Study: Tampa Bay, USA, June 1995.

25. Withers, John. Major Industrial Hazards- their Appraisal and Control, Gower Technical Press, Hunts, England, 1998.

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Authors

DC Sorte is currently the Director (Technical) of the Fertilizers and Chemicals (FACT) Ltd, a major Central Public Sector Undertaking in India involved in Fertilizer and Caprolactum manufacturing, Engineering Consultancy and Marketing. He is a Mechanical Engineer from Nagpur University and has held several senior positions including General Manager (Human Resources) at Rashtriya Chemicals and Fertilizers Ltd, Mumbai.He has extensive experience in fertilizer plant operation, maintenance, commissioning, troubleshooting and management. His specializations also include project management, water treatment, boiler and energy management and corporate personnel and industrial relations. He was the leader of the commissioning team for Jamuna Fertilizer plant in Bangladesh and has visited UK and Sweden in connection with Energy Management Programmes.

Dr MP Sukumaran Nair is currently with the Corporate Planning Dept of The Fertilizers and Chemicals Travancore (FACT) Ltd, India's pioneer Fertilizer and Chemicals manufacturing, Engineering design and Consultancy Organization. Formerly he was the Managing Director of the state-owned Travancore- Cochin Chemicals Ltd., Cochin. He is well experienced in process plant design, operation, troubleshooting and management in the Chemical Processing Industry. Mr. Nair is a Fellow of the Institution of Engineers (India) and a member of the AIChE and the National Safety Council.  He serves on several Expert Advisory Committees to the Central and State Governments in India and has published over 40 papers on management ad technology in different national as well as international journals.   He is listed in the Marquis' Who's Who in the World and by the International Biographical Centre , Cambridge, England.

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Fig 1. Contributory factors to accidental releases in the hydrocarbon –chemical industries

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Risk Level Frequency

Descriptor Occurrence  

5 Frequent 1/year  

4 Probable 1/10 years  

3 Occasional 1/100 years  

2 Remote 1/1000 years  

1 Improbable 1/10000 years

Risk Level Severity

Descriptor Consequences

5 Catastrophic Multiple deaths

4 Severe Death

3 Serious Lost time accident

2 Minor Medical treatment

1 Negligible No injury

Source: Emerson Process Management

Table 1. Risk Levels- Frequency and Severity

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