Date: PO No.: WO No.: Project Ref: Sample ID: GB #1 ... · 0.099 14.8 192 Sample ID: GB #2 L2304543 Date: PO No.: WO No.: 17-JUL-19 * * * 12-JUL-19 14-JUL-19 12-JUL-19 14-JUL-19 13-JUL-19

ResultCDWQG

MACUnits of MeasureTest Description Aesthetic

ObjectiveDate

AnalyzedQualifier

ALS CANADA LTD Part of the ALS Group A Campbell Brothers Limited CompanyADDRESS: 8081 Lougheed Hwy, Suite 100, Burnaby, BC V5A 1W9 Canada | Phone: +1 604 253 4188 | Fax: +1 604 253 6700

L2304543-103-JUL-19 Date Collected:

General

Drinking Water Full Package

Colour, True

Conductivity

Turbidity

pH

Total Dissolved Solids

Sulfate (SO4)

Nitrite (as N)

Nitrate (as N)

Fluoride (F)

Chloride (Cl)

Alkalinity, Total (as CaCO3)

Total Dissolved Solids by Gravimetric

Sulfate in Water by IC

Nitrite in Water by IC (Low Level)

Nitrate in Water by IC (Low Level)

Fluoride in Water by IC

Chloride in Water by IC

Alkalinity Species by Titration

Matrix:Lab Sample ID:

Sampled By:

Box 219 - 1350 Aster StreetPemberton BC V0N 2L0

Edward WitwickiATTN:

SQUAMISH-LILLOOET REG. DISTRICT

CU

uS/cm

NTU

pH

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

1

10

1.5

15

7-10.5

500

500

250

<5.0

493

1.23

8.46

345

56.9

<0.0010

0.147

0.098

15.0

193

GB #1Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

*

*

*

06-JUL-19

08-JUL-19

05-JUL-19

08-JUL-19

09-JUL-19

16-JUL-19

16-JUL-19

16-JUL-19

16-JUL-19

16-JUL-19

08-JUL-19

1PAGE of

HTD

HTD

ADDITIONAL 12-JUL-19 12:28

* CDWQG for Nitrate+Nitrite-N is the limit for nitrate only. If present as Nitrate then the limit is 10mg/L < or N.D. = less than detection limit.* Turbidity guideline based on membrane filtration. For guidelines on conventional treatment and slow sand or diatomaceous earth filtration please see Summary Table of Guidelines for Canadian Drinking Water Quality- A blank entry designates no known limit.- A shaded value in the Results column exceeds CDWQG MAC and/ or Aesthetic Objective.

CDWQG = Health Canada Guideline Limits updated JUNE 2019

Approved byCarla FuginskiAccount Manager

Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



General

Drinking Water Full Package

Colour, True

Conductivity

Turbidity

pH


Sulfate (SO4)

Nitrite (as N)

Nitrate (as N)

Fluoride (F)

Chloride (Cl)



Sulfate in Water by IC



Fluoride in Water by IC

Chloride in Water by IC

Alkalinity Species by Titration


Sampled By:




CU

uS/cm

NTU

pH

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

1

10

1.5

15

7-10.5

500

500

250

<5.0

468

0.70

8.18

309

56.2

<0.0010

0.146

0.099

14.8

192

GB #2Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

*

*

*

12-JUL-19

14-JUL-19

12-JUL-19

14-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

14-JUL-19

2PAGE of





Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



Metals

Hardness (as CaCO3)

Aluminum (Al)-TotalAntimony (Sb)-TotalArsenic (As)-TotalBarium (Ba)-TotalBeryllium (Be)-TotalBismuth (Bi)-TotalBoron (B)-TotalCadmium (Cd)-TotalCalcium (Ca)-TotalCesium (Cs)-TotalChromium (Cr)-TotalCobalt (Co)-TotalCopper (Cu)-TotalIron (Fe)-TotalLead (Pb)-TotalLithium (Li)-TotalMagnesium (Mg)-TotalManganese (Mn)-TotalMolybdenum (Mo)-TotalNickel (Ni)-TotalPhosphorus (P)-TotalPotassium (K)-TotalRubidium (Rb)-TotalSelenium (Se)-TotalSilicon (Si)-TotalSilver (Ag)-TotalSodium (Na)-TotalStrontium (Sr)-TotalSulfur (S)-TotalTellurium (Te)-TotalThallium (Tl)-TotalThorium (Th)-TotalTin (Sn)-TotalTitanium (Ti)-TotalTungsten (W)-TotalUranium (U)-TotalVanadium (V)-TotalZinc (Zn)-TotalZirconium (Zr)-Total

Total Metals in Water by CRC ICPMS


Sampled By:




mg/L

mg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L

0.0060.01

1

50.005

0.05

2.0

0.005

0.12

0.05

0.02

500

0.1

1.00.3

0.02

200

5.0

246

<0.00300.000110.003250.0188

<0.00010<0.000050

0.259<0.0000050

47.9<0.0000100.00495

<0.000100.001130.161

0.0001330.007330.7

0.001180.004440.00216<0.0504.20

0.000510.00185

9.90<0.000010

6.450.20020.5

<0.00020<0.000010<0.00010<0.00010<0.000300.000110.0000920.000570.0070

<0.00020

GB #3Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

15-JUL-19

13-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-19

3PAGE of

HTC

Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



MetalsMatrix:Lab Sample ID:

Sampled By:




GB #3Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

4PAGE of





Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



Metals

Hardness (as CaCO3)

Aluminum (Al)-TotalAntimony (Sb)-TotalArsenic (As)-TotalBarium (Ba)-TotalBeryllium (Be)-TotalBismuth (Bi)-TotalBoron (B)-TotalCadmium (Cd)-TotalCalcium (Ca)-TotalCesium (Cs)-TotalChromium (Cr)-TotalCobalt (Co)-TotalCopper (Cu)-TotalIron (Fe)-TotalLead (Pb)-TotalLithium (Li)-TotalMagnesium (Mg)-TotalManganese (Mn)-TotalMolybdenum (Mo)-TotalNickel (Ni)-TotalPhosphorus (P)-TotalPotassium (K)-TotalRubidium (Rb)-TotalSelenium (Se)-TotalSilicon (Si)-TotalSilver (Ag)-TotalSodium (Na)-TotalStrontium (Sr)-TotalSulfur (S)-TotalTellurium (Te)-TotalThallium (Tl)-TotalThorium (Th)-TotalTin (Sn)-TotalTitanium (Ti)-TotalTungsten (W)-TotalUranium (U)-TotalVanadium (V)-TotalZinc (Zn)-TotalZirconium (Zr)-Total

Total Metals in Water by CRC ICPMS


Sampled By:




mg/L

mg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/Lmg/L

0.0060.01

1

50.005

0.05

2.0

0.005

0.12

0.05

0.02

500

0.1

1.00.3

0.02

200

5.0

251

<0.00300.000110.003340.0192

<0.00010<0.000050

0.259<0.0000050

47.5<0.0000100.00481

<0.000100.001150.167

0.0001390.007032.1

0.001330.004640.00214<0.0504.39

0.000570.00184

9.43<0.000010

7.010.20520.3

<0.00020<0.000010<0.00010<0.00010<0.000300.000100.0001040.000650.0064

<0.00020

GB #4Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

15-JUL-19

13-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-1913-JUL-19

5PAGE of

HTC

Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



MetalsMatrix:Lab Sample ID:

Sampled By:




GB #4Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

6PAGE of





Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



Merc

Mercury (Hg)-Total


Sampled By:




mg/L 0.001<0.000050

GB #5Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

16-JUL-19

7PAGE of





Project Ref:

9

ResultCDWQG


ObjectiveDate

AnalyzedQualifier



Merc

Mercury (Hg)-Total


Sampled By:




mg/L 0.001<0.000050

GB #6Sample ID:

L2304543

Date:PO No.:

WO No.:

17-JUL-19

16-JUL-19

8PAGE of





Project Ref:

9

Guidelines & Objectives

L2304543 CONTD....

Health Canada MAC Health Related Criteria LimitsNitrate/Nitrite-N* Criteria limit is 10 mg/L (1.0 mg/L if present as all Nitrite-N). High concentrations may contribute to blue baby syndrome in infants.Lead* A cumulative body poison, uncommon in naturally occurring hard waters.Fluoride* Present in fluoridated water supplies at 0.8 mg/L to reduce dental caries. Elevated levels causes fluorosis (mottling of teeth).Total Coliforms* Criteria is 0 CFU/100mL. Adverse health effects.E. Coli* Criteria is 0 CFU/100 mL. Certain E. Coli bacteria can be life threatening.

*Health Canada Canadian Drinking Water Quality Guidelines (MAC limit)

Aesthetic Objective Concentration LevelsAlkalinity Acid neutralizing capacity. Usually a measure of carbonate and bicarbonates and calculated and reported as calcium carbonate.Balance Quality control parameter ratioing cations to anionsBicarbonate See Alkalinity. Report as the anion HCO3-1Carbonate See Alkalinity. Reported at the anion CO3-2Calcium See Hardness. Common major cation of water chemistry.Chloride Common major anion of water chemistry.Conductance Physical test measuring water salinity (dissolved ions or solids)Hardness Classical measure or capacity of water to precipitate soap (chiefly calcium and magnesium ions). Causes scaling tendency in water if carbonates/bicarbonates are present (if >200 mg/L). For drinking water purposes waters with results <200 mg/L are considered acceptable, results >200 mg/L are considered poor but can be tolerated. Results >500 mg/L are unacceptable.Hydroxide See alkalinityMagnesium See hardness. Common major cation of water chemistry. Elevated levels (>125 mg/L) may exert a cathartic or diuretic action.pH Measure of water acidity/alkalinity. Normal range is 7.0-8.5.Potassium Common major cation of water chemistry.Sodium Common major cation of water chemistry. Measure of salinity (saltiness).The aesthetic objective (not related to health) for sodium in drinking water is 200 mg/L. However, where sodium concentration of the drinking water exceeds 20 mg/L, it is recommended that any person on a sodium restricted diet consult with his/her physician or Medical Officer of Health concerning the use of that water.Sulphate Common major anion of water chemistry. Elevated levels may exert a cathartic or diuretic action.Total Dissolved Solids A measure of water salinity.Iron Causes staining to laundry and porcelain and astringent taste. Oxidizes to red-brown precipitate on exposure to air.Manganese Elevated levels may cause staining of laundry and porcelain.HeterotrophicPlate Count Criteria is 500 cfu/mL Measure of heterotrophic bacteria present.

9PAGE of

HTD

HTC

Hold time exceeded for re-analysis or dilution, but initial testing was conducted within hold time.

Hardness was calculated from Total Ca and/or Mg concentrations and may be biased high (dissolved Ca/Mg results unavailable).

Sample Parameter Qualifier key listed:

Description Qualifier

GLOSSARY OF REPORT TERMSSurrogates are compounds that are similar in behaviour to target analyte(s), but that do not normally occur in environmental samples. For applicable tests, surrogates are added to samples prior to analysis as a check on recovery. In reports that display the D.L. column, laboratory objectives for surrogates are listed there.mg/kg - milligrams per kilogram based on dry weight of samplemg/kg wwt - milligrams per kilogram based on wet weight of samplemg/kg lwt - milligrams per kilogram based on lipid-adjusted weight mg/L - unit of concentration based on volume, parts per million.< - Less than.D.L. - The reporting limit.N/A - Result not available. Refer to qualifier code and definition for explanation.

Test results reported relate only to the samples as received by the laboratory.UNLESS OTHERWISE STATED, ALL SAMPLES WERE RECEIVED IN ACCEPTABLE CONDITION.Analytical results in unsigned test reports with the DRAFT watermark are subject to change, pending final QC review.

9

Quality Control ReportPage 1 of

Client:

Contact:

SQUAMISH-LILLOOET REG. DISTRICTBox 219 - 1350 Aster Street Pemberton BC V0N 2L0Edward Witwicki

Report Date: 17-JUL-19Workorder: L2304543

Test Matrix Reference Result Qualifier Units RPD Limit Analyzed

ALK-TITR-VA

CL-IC-N-VA

COLOUR-TRUE-VA

EC-PCT-VA

Water

Water

Water

Water

R4696300

R4710468

R4707905

R4712725

R4712860

R4695596

R4709367

Batch

Batch

Batch

Batch

Batch

Batch

Batch

CRM

MB

CRM

MB

LCS

MB

LCS

MB

LCS

MB

CRM

MB

CRM

MB

WG3097567-3

WG3097567-1

WG3103651-3

WG3103651-1

WG3096945-2

WG3096945-1

WG3103657-2

WG3103657-1

WG3106300-2

WG3106300-1

WG3096692-2

WG3096692-1

WG3103587-2

WG3103587-1

VA-ALK-TITR-CONTROL

VA-ALK-TITR-CONTROL

VA-COLOUR-T

VA-COLOUR-T





Chloride (Cl)

Chloride (Cl)

Chloride (Cl)

Chloride (Cl)

Chloride (Cl)

Chloride (Cl)

Colour, True

Colour, True

Colour, True

Colour, True

101.3

<1.0

102.1

<1.0

100.8

<0.50

101.5

<0.50

103.4

<0.50

96.1

<5.0

97.6

<5.0

08-JUL-19

08-JUL-19

14-JUL-19

14-JUL-19

06-JUL-19

06-JUL-19

13-JUL-19

13-JUL-19

16-JUL-19

16-JUL-19

06-JUL-19

06-JUL-19

12-JUL-19

12-JUL-19

85-115

85-115

90-110

90-110

90-110

85-115

85-115

%

mg/L

%

mg/L

%

mg/L

%

mg/L

%

mg/L

%

CU

%

CU

1

1

0.5

0.5

0.5

5

5

11

Quality Control ReportPage 2 ofReport Date: 17-JUL-19Workorder: L2304543


EC-PCT-VA

F-IC-N-VA

HG-TOT-CVAFS-VA

MET-T-CCMS-VA

Water

Water

Water

Water

R4696300

R4710468

R4707905

R4712725

R4712860

R4712364

R4709654

Batch

Batch

Batch

Batch

Batch

Batch

Batch

CRM

MB

CRM

MB

LCS

MB

LCS

MB

LCS

MB

LCS

MB

LCS

WG3097567-4

WG3097567-1

WG3103651-4

WG3103651-1

WG3096945-2

WG3096945-1

WG3103657-2

WG3103657-1

WG3106300-2

WG3106300-1

WG3106081-2

WG3106081-1

WG3104190-2

VA-EC-PCT-CONTROL

VA-EC-PCT-CONTROL

Conductivity

Conductivity

Conductivity

Conductivity

Fluoride (F)

Fluoride (F)

Fluoride (F)

Fluoride (F)

Fluoride (F)

Fluoride (F)

Mercury (Hg)-Total

Mercury (Hg)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

100.1

<2.0

96.7

<2.0

100.7

<0.020

104.0

<0.020

104.5

<0.020

99.0

<0.000050

110.3

106.0

103.8

08-JUL-19

08-JUL-19

14-JUL-19

14-JUL-19

06-JUL-19

06-JUL-19

13-JUL-19

13-JUL-19

16-JUL-19

16-JUL-19

16-JUL-19

16-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

90-110

90-110

90-110

90-110

90-110

80-120

80-120

80-120

80-120

%

uS/cm

%

uS/cm

%

mg/L

%

mg/L

%

mg/L

%

mg/L

%

%

%

2

2

0.02

0.02

0.02

0.00005

11



MET-T-CCMS-VA Water

R4709654BatchLCSWG3104190-2

Barium (Ba)-Total

Beryllium (Be)-Total

Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Calcium (Ca)-Total

Cesium (Cs)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total

Magnesium (Mg)-Total

Manganese (Mn)-Total

Molybdenum (Mo)-Total

Nickel (Ni)-Total

Phosphorus (P)-Total

Potassium (K)-Total

Rubidium (Rb)-Total

Selenium (Se)-Total

Silicon (Si)-Total

Silver (Ag)-Total

Sodium (Na)-Total

Strontium (Sr)-Total

Sulfur (S)-Total

Tellurium (Te)-Total

Thallium (Tl)-Total

Thorium (Th)-Total

Tin (Sn)-Total

Titanium (Ti)-Total

Tungsten (W)-Total

Uranium (U)-Total

Vanadium (V)-Total

103.0

98.5

103.0

91.0

99.96

99.2

104.5

101.6

102.3

100.0

101.5

103.4

96.0

104.5

105.3

100.2

100.4

113.1

110.9

107.0

100.9

100.9

101.1

110.1

105.5

103.6

101.3

102.6

105.5

102.3

103.6

105.9

105.0

105.1

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

11



MET-T-CCMS-VA Water

R4709654BatchLCS

MB

WG3104190-2

WG3104190-1

Zinc (Zn)-Total

Zirconium (Zr)-Total

Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Calcium (Ca)-Total

Cesium (Cs)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total




Nickel (Ni)-Total


Potassium (K)-Total

Rubidium (Rb)-Total

Selenium (Se)-Total

Silicon (Si)-Total

Silver (Ag)-Total

Sodium (Na)-Total


Sulfur (S)-Total


Thallium (Tl)-Total

103.6

100.1

<0.0030

<0.00010

<0.00010

<0.00010

<0.00010

<0.000050

<0.010

<0.0000050

<0.050

<0.000010

0.00013

<0.00010

<0.00050

<0.010

<0.000050

<0.0010

<0.0050

<0.00010

<0.000050

<0.00050

<0.050

<0.050

<0.00020

<0.000050

<0.10

<0.000010

<0.050

<0.00020

<0.50

<0.00020

<0.000010

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

80-120

80-120

%

%

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

MB-LOR

0.003

0.0001

0.0001

0.0001

0.0001

0.00005

0.01

0.000005

0.05

0.00001

0.0001

0.0001

0.0005

0.01

0.00005

0.001

0.005

0.0001

0.00005

0.0005

0.05

0.05

0.0002

0.00005

0.1

0.00001

0.05

0.0002

0.5

0.0002

0.00001

11



MET-T-CCMS-VA Water

R4709654

R4712092

Batch

Batch

MB

LCS

WG3104190-1

WG3104133-2

Thorium (Th)-Total

Tin (Sn)-Total

Titanium (Ti)-Total

Tungsten (W)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total


Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Calcium (Ca)-Total

Cesium (Cs)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total




Nickel (Ni)-Total


Potassium (K)-Total

Rubidium (Rb)-Total

Selenium (Se)-Total

<0.00010

<0.00010

<0.00030

<0.00010

<0.000010

<0.00050

<0.0030

<0.00020

106.1

106.1

103.0

112.1

105.1

105.3

104.4

108.2

105.4

100.6

110.1

104.3

104.1

104.3

107.3

104.2

103.1

106.8

107.6

106.1

102.2

110.8

109.8

110.7

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

0.0001

0.0001

0.0003

0.0001

0.00001

0.0005

0.003

0.0002

11



MET-T-CCMS-VA Water

R4712092BatchLCS

MB

WG3104133-2

WG3104133-1 NP

Silicon (Si)-Total

Silver (Ag)-Total

Sodium (Na)-Total


Sulfur (S)-Total


Thallium (Tl)-Total

Thorium (Th)-Total

Tin (Sn)-Total

Titanium (Ti)-Total

Tungsten (W)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total


Aluminum (Al)-Total

Antimony (Sb)-Total

Arsenic (As)-Total

Barium (Ba)-Total


Bismuth (Bi)-Total

Boron (B)-Total

Cadmium (Cd)-Total

Calcium (Ca)-Total

Cesium (Cs)-Total

Chromium (Cr)-Total

Cobalt (Co)-Total

Copper (Cu)-Total

Iron (Fe)-Total

Lead (Pb)-Total

Lithium (Li)-Total



102.4

106.1

101.8

106.6

101.6

103.7

109.0

107.9

105.4

105.5

111.2

105.8

107.8

110.5

110.4

<0.0030

<0.00010

<0.00010

<0.00010

<0.00010

<0.000050

<0.010

<0.0000050

<0.050

<0.000010

<0.00010

<0.00010

<0.00050

<0.010

<0.000050

<0.0010

<0.0050

<0.00010

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

80-120

%

%

%

%

%

%

%

%

%

%

%

%

%

%

%

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

0.003

0.0001

0.0001

0.0001

0.0001

0.00005

0.01

0.000005

0.05

0.00001

0.0001

0.0001

0.0005

0.01

0.00005

0.001

0.005

0.0001

11



MET-T-CCMS-VA

NO2-L-IC-N-VA

Water

Water

R4712092

R4707905

R4712725

Batch

Batch

Batch

MB

LCS

MB

LCS

MB

WG3104133-1

WG3096945-2

WG3096945-1

WG3103657-2

WG3103657-1

NPMolybdenum (Mo)-Total

Nickel (Ni)-Total


Potassium (K)-Total

Rubidium (Rb)-Total

Selenium (Se)-Total

Silicon (Si)-Total

Silver (Ag)-Total

Sodium (Na)-Total


Sulfur (S)-Total


Thallium (Tl)-Total

Thorium (Th)-Total

Tin (Sn)-Total

Titanium (Ti)-Total

Tungsten (W)-Total

Uranium (U)-Total

Vanadium (V)-Total

Zinc (Zn)-Total


Nitrite (as N)

Nitrite (as N)

Nitrite (as N)

Nitrite (as N)

<0.000050

<0.00050

<0.050

<0.050

<0.00020

<0.000050

<0.10

<0.000010

<0.050

<0.00020

<0.50

<0.00020

<0.000010

<0.00010

<0.00010

<0.00030

<0.00010

<0.000010

<0.00050

<0.0030

<0.00020

98.4

<0.0010

102.5

<0.0010

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

06-JUL-19

06-JUL-19

13-JUL-19

13-JUL-19

90-110

90-110

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

%

mg/L

%

mg/L

0.00005

0.0005

0.05

0.05

0.0002

0.00005

0.1

0.00001

0.05

0.0002

0.5

0.0002

0.00001

0.0001

0.0001

0.0003

0.0001

0.00001

0.0005

0.003

0.0002

0.001

0.001

11



NO2-L-IC-N-VA

NO3-L-IC-N-VA

PH-PCT-VA

SO4-IC-N-VA

Water

Water

Water

Water

R4712860

R4707905

R4712725

R4712860

R4696300

R4710468

R4707905

Batch

Batch

Batch

Batch

Batch

Batch

Batch

LCS

MB

LCS

MB

LCS

MB

LCS

MB

CRM

CRM

LCS

MB

WG3106300-2

WG3106300-1

WG3096945-2

WG3096945-1

WG3103657-2

WG3103657-1

WG3106300-2

WG3106300-1

WG3097567-2

WG3103651-2

WG3096945-2

WG3096945-1

VA-PH7-BUF

VA-PH7-BUF

Nitrite (as N)

Nitrite (as N)

Nitrate (as N)

Nitrate (as N)

Nitrate (as N)

Nitrate (as N)

Nitrate (as N)

Nitrate (as N)

pH

pH

Sulfate (SO4)

Sulfate (SO4)

102.8

<0.0010

101.2

<0.0050

102.2

<0.0050

103.9

<0.0050

7.01

7.00

102.7

<0.30

16-JUL-19

16-JUL-19

06-JUL-19

06-JUL-19

13-JUL-19

13-JUL-19

16-JUL-19

16-JUL-19

08-JUL-19

14-JUL-19

06-JUL-19

06-JUL-19

90-110

90-110

90-110

90-110

6.9-7.1

6.9-7.1

90-110

%

mg/L

%

mg/L

%

mg/L

%

mg/L

pH

pH

%

mg/L

0.001

0.005

0.005

0.005

0.3

11



SO4-IC-N-VA

TDS-VA

TURBIDITY-VA

Water

Water

Water

R4712725

R4712860

R4704050

R4709650

R4694924

R4709191

Batch

Batch

Batch

Batch

Batch

Batch

LCS

MB

LCS

MB

LCS

MB

DUP

LCS

MB

CRM

DUP

MB

CRM

MB

WG3103657-2

WG3103657-1

WG3106300-2

WG3106300-1

WG3099519-2

WG3099519-1

WG3104183-3

WG3104183-2

WG3104183-1

WG3097106-2

WG3097106-3

WG3097106-1

WG3103695-2

WG3103695-1

L2304543-2

VA-FORM-40

L2304543-1

VA-FORM-40

Sulfate (SO4)

Sulfate (SO4)

Sulfate (SO4)

Sulfate (SO4)






Turbidity

Turbidity

Turbidity

Turbidity

Turbidity

103.6

<0.30

105.4

<0.30

102.2

<10

312

99.3

<10

108.1

1.20

<0.10

103.8

<0.10

13-JUL-19

13-JUL-19

16-JUL-19

16-JUL-19

09-JUL-19

09-JUL-19

13-JUL-19

13-JUL-19

13-JUL-19

05-JUL-19

05-JUL-19

05-JUL-19

12-JUL-19

12-JUL-19

1.0

2.5

20

15

90-110

90-110

85-115

85-115

85-115

85-115

%

mg/L

%

mg/L

%

mg/L

mg/L

%

mg/L

%

NTU

NTU

%

NTU

0.3

0.3

10

10

0.1

0.1

309

1.23

11


Sample Parameter Qualifier Definitions:

Description Qualifier

MB-LOR Method Blank exceeds ALS DQO. Limits of Reporting have been adjusted for samples with positive hits below 5x blank level.

Limit ALS Control Limit (Data Quality Objectives)DUP DuplicateRPD Relative Percent DifferenceN/A Not AvailableLCS Laboratory Control SampleSRM Standard Reference MaterialMS Matrix SpikeMSD Matrix Spike DuplicateADE Average Desorption EfficiencyMB Method BlankIRM Internal Reference MaterialCRM Certified Reference MaterialCCV Continuing Calibration VerificationCVS Calibration Verification StandardLCSD Laboratory Control Sample Duplicate

Legend:

11


ALS Product Description Sample

ID Sampling Date Date Processed Rec. HT Actual HT

Physical Tests

Anions and Nutrients

2

2

2

12

12

12

03-JUL-19 15:40

03-JUL-19 15:40

03-JUL-19 15:40

03-JUL-19 15:4003-JUL-19 15:40

03-JUL-19 15:4003-JUL-19 15:40

03-JUL-19 15:4003-JUL-19 15:40

12-JUL-19 23:19

13-JUL-19 01:20

12-JUL-19 12:29

08-JUL-19 09:1414-JUL-19 08:09

16-JUL-19 07:4213-JUL-19 08:28

16-JUL-19 07:4213-JUL-19 08:28

3

7

3

0.250.25

33

33

9

9

9

114257

1310

1310

Colour (True) by Spectrometer


Turbidity by Meter

pH by Meter (Automated)



EHT

EHT

EHT

EHTR-FMEHTR-FM

EHTEHT

EHTEHT

Qualifier

Legend & Qualifier Definitions:

The ALS Quality Control Report is provided to ALS clients upon request. ALS includes comprehensive QC checks with every analysis to ensure our high standards of quality are met. Each QC result has a known or expected target value, which is compared against pre-determined data quality objectives to provide confidence in the accuracy of associated test results.

Please note that this report may contain QC results from anonymous Sample Duplicates and Matrix Spikes that do not originate from this Work Order.

Hold Time Exceedances:

Notes*:Where actual sampling date is not provided to ALS, the date (& time) of receipt is used for calculation purposes.Where actual sampling time is not provided to ALS, the earlier of 12 noon on the sampling date or the time (& date) of receipt isused for calculation purposes. Samples for L2304543 were received on 05-JUL-19 08:40.

ALS recommended hold times may vary by province. They are assigned to meet known provincial and/or federal governmentrequirements. In the absence of regulatory hold times, ALS establishes recommendations based on guidelines published by theUS EPA, APHA Standard Methods, or Environment Canada (where available). For more information, please contact ALS.

Units

days

days

days

hourshours

daysdays

daysdays

EHTR-FM: EHTR: EHTL: EHT: Rec. HT:

Exceeded ALS recommended hold time prior to sample receipt. Field Measurement recommended.Exceeded ALS recommended hold time prior to sample receipt.Exceeded ALS recommended hold time prior to analysis. Sample was received less than 24 hours prior to expiry.Exceeded ALS recommended hold time prior to analysis.ALS recommended hold time (see units).

11

Documents

Date: PO No.: WO No.: Project Ref: Sample ID: GB #1 ... · 0.099 14.8 192 Sample ID: GB #2 L2304543 Date: PO No.: WO No.: 17-JUL-19 * * * 12-JUL-19 14-JUL-19 12-JUL-19 14-JUL-19 13-JUL-19