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Chapter 13 Transfer of Heat Three mechanisms for transfer heat from hotter object to cooler object: Convection Conduction Radiation

Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

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Page 4: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

surrounding cooler and denser air pushes heated and less

dense air upwards; resulting updraft called a “thermal”

Page 6: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Example of forced convection

cool air duct

warm air duct

Page 10: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

CONDUCTION OF HEAT THROUGH A MATERIAL

heat Q conducted during a time t through a bar of length

L and cross-sectional area A is

L

tTkAQ

Δ

SI Units of thermal conductivity: J/(s·m·oC)

thermal

conductivity

Page 11: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

excellent thermal

insulator

excellent thermal

conductors

Page 12: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Materials such as styrofoam,

goose, and wool contain small,

dead-air spaces.

Net effect is very poor thermal

conductor (excellent thermal

insulator).

Dead-air spaces inhibit heat

transfer by convection currents,

and air itself has very low

thermal conductivity.

Page 13: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

QUESTION: Find the amount of heat per second

conducted through a glass picture window (1.5 m x 2.0 m)

that is 4.0-mm thick when the outside temperature is 5oC

(41 F) and the room is at 22.2oC (72 F)?

SOLUTION:

2.0 m

1.5 m

4.0 mm

Page 17: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

QUESTION: One wall of a house consists of plywood

backed by insulation. The thermal conductivities of the

insulation and plywood are, respectively, 0.030 and 0.080

J/(s·m·oC), and the area of the wall is 35 m2.

Find the amount of heat

conducted through the wall

in one hour.

Page 18: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

SOLUTION

Page 19: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection
Page 20: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

radiation = process in which

energy is transferred by means of

electromagnetic waves

A material that is a good absorber

is also a good emitter.

A material that absorbs

100% of the received

radiation is called a

perfect blackbody.

Page 21: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

THE STEFAN-BOLTZMANN LAW OF RADIATION

radiant energy Q, emitted in a time t by an object that has a

Kelvin temperature T, a surface area A, and an emissivity e, is

given byAtTeQ 4

emissivity e = dimensionless number between zero and one

= ratio of what an object radiates to what the

object would radiate if it were a perfect emitter

Stefan-Boltzmann constant

481067.5 K

2msJ

e = 1.0 for blackbody radiator

Page 22: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

QUESTION:

The supergiant star Betelgeuse has a surface

temperature of about 2900 K and emits a power of

approximately 4x1030 W (1 W = 1 J/s).

Assuming that Betelgeuse is a perfect emitter and

spherical, find its radius.

SOLUTION:

Page 25: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

ratings of thermal insulation = R-values

R

TA

kL

TA

L

TkAtQ

D

D

D

//

R value = L/k

ADDITIONAL APPLICATIONS OF HEAT TRANSFER

larger R values reduce heat per unit time Q/t flowing

through material and, therefore, mean better insulation

increase R by increase thickness (length) of insulation or

using a material (combination of materials in series) with

smaller thermal conductivities k

Page 26: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Thermos bottle minimizes heat transfer

via conduction, convection, and radiation.

Vacuum space

reflects radiation

no air convection

poor conductor

Page 28: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Chapter 14.4 Diffusion

diffusion = process in which molecules move from a region

of higher concentration to one of lower concentration

Page 29: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Why Diffusion is Relatively Slow

A gas molecule has a translational rms speed of hundreds of

meters per second at room temperature. At such speed, a

molecule could travel across an ordinary room in just a fraction

of a second. Yet, it often takes several seconds, and sometimes

minutes, for the fragrance of a perfume to reach the other side

of the room. Why does it take so long?

zigzag path result of

millions of collisions =

Brownian motion

Page 30: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

A Transdermal Patch

Page 31: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Diffusion

Conduction

Similarity between Diffusion and Conduction

Page 32: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

L

tCDAm

D

FICK’S LAW OF DIFFUSION

mass m of solute that diffuses in a time t through a solvent

contained in a channel of length L and cross sectional area A

concentration gradient

between ends, DCdiffusion

constant, D

SI Units for the Diffusion Constant: m2/s

Page 33: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

Water Given Off by Plant Leaves

Large amounts of water can be given

off by plants. Inside the leaf, water

passes from the liquid phase to the

vapor phase at the walls of the

mesophyll cells.

The diffusion constant for water is

2.4x10-5m2/s. A stomatal pore has a

cross sectional area of about

8.0x10-11m2 and a length of about

2.5x10-5m. The concentration on the

interior side of the pore is roughly

0.022 kg/m3, while that on the outside

is approximately 0.011 kg/m3.

Determine the mass of water that

passes through the stomatal pore in

one hour.

Page 34: Convection Conduction Radiationnordlund/Courses/PH201/Links/...Convection = process by which heat is carried from place to place by the movement of a fluid (liquid or gas) Convection

SOLUTION: