FOR USE AS AN AGRICULTURAL HERBICIDE. FOR PROFESSIONAL USE ONLY

A contact herbicide for selective use in cabbages, Brussels sprout and bulb onions.

Wettable powder (WP) formulationcontaining 45 % w/w pyridate.

Contents : 1 kg

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6010

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Production date / Batch number: see packaging

Lentagran® WP - wettable powder (WP) containing 45% w/w pyridate.

DO NOT OPEN WATER SOLUBLE BAG

DO NOT TOUCH WITH WET HANDS OR GLOVES

DO NOT STORE HALF BAGS OR DAMAGED BAGS USE IMMEDIATELY

PROTECT FROM FROST

Approval Holder :Belchim Crop Protection NV/SATechnologielaan 7, 1840 LonderzeelBelgiumTel.: 0032 52 300906Fax: 0032 52 301135info@belchim.com

® Registered trademark of Belchim Crop Protection NV/SA

PCS No 03082

Important InformationFOR USE AS AN AGRICULTURAL HERBICIDE.

Crops Maximumindividualdose(kg productper hectare)

Maximum number of applications at maximum single dose

Maximumtotal dose(kg product/ha/crop)

Latesttime ofapplication

CABBAGE 2 1 2 Before 6leaf stage

BRUSSELSSPROUT

2 1 2 Before 6leaf stage

BULBONION

2 1 2 Before 7leaf stage

READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THE LABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT

PROTECTION PRODUCTS.

RISK AND SAFETY INFORMATION

Distributed by:Whelehan Crop Protection Suite 12, Bunkilla PlazaBracetown Business ParkClonee, Co. MeathTechnical enquiries: 00 353 1 4688900

Warning

May cause an allergic skin reaction.Very toxic to the aquatic life with long lasting effects.

Contaminated work clothing should not be allowed out of the workplace.Avoid release to the environment.Wear protective gloves/protective clothing.IF ON SKIN: Wash with soap and water.If skin irritation or a rash occurs: Get medical advice/attention.Collect spillage.Dispose of contents/container to a licensed waste disposal contractor or collection site except for triple rinsed empty containers which can be disposed of as non-hazardous waste.

Do not contaminate water with the product or its container; Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.

To avoid risks to human health and the environment, comply with the instructions for use.

UN 3077

24-hour emergency number: 0032 14 58 45 45

SPECIMEN -

2014

TO DATE

SAFETY PRECAUTIONSOperator protection- ENGINEERING CONTROL OF OPERATOR EXPOSURE

must be used where reasonably practicable in addition to the following personal protective equipment:

- WEAR SUITABLE PROTECTIVE GLOVES when handling contaminated surfaces.

- WASH CONCENTRATE from skin or eyes immediately. - WASH HANDS AND EXPOSED SKIN before meals and

after work. - WHEN USING DO NOT EAT, DRINK OR SMOKE.

Environmental protection- Do not contaminate water with the product or its container. Do not clean application equipment near surface water and avoid contamination via drains

from farmyards and roads.- Extreme care must be taken to avoid spray drift onto

non-crop plants outside the target area.

Storage and disposal- KEEP OUT OF REACH OF CHILDREN.- KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDINGSTUFFS.- KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.

Water-soluble bag precautions and labelling- DO NOT TOUCH WATER SOLUBLE BAG WITH WET

HANDS OR GLOVES. - PLACE WHOLE BAG DIRECTLY INTO SPRAY TANK.- DO NOT STORE HALF BAGS OR DAMAGED BAGS.- USE IMMEDIATELY.- ENSURE ALL OTHER LABEL INSTRUCTIONS ARE FOLLOWED.

StorageLENTAGRAN WP should be stored for at least 24 hours at room temperature (18-20oC) before use.

Restrictions:- Apply only on dry crops- The temperature of the diluted spray solution and air

should be above 10°C at spraying- Overdosing (spray boom overlap) and spray drift

should be avoided

Anti-resistance strategyWeed control may be reduced if resistant strains develop to pyridate. To prevent the development of resistance, Lentagran WP should not be used continuously or as the sole method of control. Consideration should be given to alternation of products having a different mode of action (from a different chemical HRAC group) with satisfactory effi cacy against the targeted pest. Pyridate is classifi ed as belonging to HRAC Group C3.

FOLLOWING CROPSThere is no restriction on following crops after application of LENTAGRAN WP, even in crop failure situations. Soil cultivation is not necessary.

DIRECTIONS FOR USELENTAGRAN WP is a contact herbicide with no residual activity. Application should be made when all weeds have emerged, provided that the crop is within the correct stage of growth and not under stress. Best results are obtained from a fi ne spray applied whilst the weeds are small and actively growing and before the crop forms a canopy of foliage over the weeds. When the crop canopy is protecting the weeds, spray volume should be increased.

Weeds Controlled LENTAGRAN WP can be used to control the following weeds: black nightshade, cleavers and fat hen. For optimum control the weeds should be treated at the cotyledon to 4 leaf stage and when the ambient daytime temperature is above 10ºC. Do not apply during periods when night temperatures are consistently below 2°C or when day temperatures exceed 18°C.

Application

Cabbage and Brussels Sprouts Timing: Apply LENTAGRAN WP once the crop has 4 fully expanded leaves. If the crop is transplanted allow 2 weeks after planting for plants to establish. Applications should be made before the 6 leaf stage (GS 16 BBCH).A crystal violet test should be carried out to ensure the leaves have a good wax layer before applying LENTAGRAN WP. There may be some yellowing of the older leaves but this effect is no longer visible after 8 weeks and has no infl uence on yield or time of harvest. Do not apply LENTAGRAN WP in mixture with any product that can cause de-waxing of the crop leaves. Do not apply LENTAGRAN WP within 14 days of any product that causes de-waxing of the crop leaves. Optimum weed control will result if LENTAGRAN WP is applied when all the weeds have emerged. In view of the wide range of cabbage cultivars available, it is recommended that selectivity trials are conducted locally before applying LENTAGRAN WP, especially on varieties that are newly introduced. Under unfavourable conditions LENTAGRAN WP may lead to crop damage when applied at 2-4 leaf stage (cabbage) especially when the crop is not suffi ciently rooted after transplantation. The latest application timing is before the 6 leaf stage.Dose: Apply LENTAGRAN WP at 2 kg/ha.

Bulb onion Timing: A single application of LENTAGRAN WP should be applied from when the crop has 4 leaves. If the crop is transplanted allow 2 weeks after planting for plants to establish. Do not apply LENTAGRAN WP in mixture with any product that can cause de-waxing of the crop leaves. Do not apply LENTAGRAN WP within 14 days of any product that causes de-waxing of the crop leaves. Optimum weed control will result if LENTAGRAN WP is applied when all the weeds have emerged. A crystal violet test should be carried out to ensure the leaves have a good wax layer before applying LENTAGRAN WP.There may be some yellowing of the older leaves, but this effect is no longer visible after 8 weeks and has no infl uence on yield or time of harvest.

Dose: Apply LENTAGRAN WP at 2 kg/ha.

PREPARATION OF THE SPRAY SOLUTIONLENTAGRAN WP should not be creamed in a bucket but added directly to the spray tank. Half fi ll the spray tank with clean water and begin agitation. Add the required number of water soluble bags to the tank and complete fi lling. Continue agitation until spraying is completed. Thoroughly wash all spray equipment with water and a wetting agent immediately after use.

Water volume Apply in no less than 325 litres water per hectare up to 400 litres of water per hectare at a minimum pressure of 2 bar as good spray coverage is essential for effective weed control.

Spray Nozzles A FINE quality spray (as defi ned by BCPC) is preferred for application of LENTAGRAN WP. Choice of nozzle is determined by consulting manufacturer’s literature and selecting a nozzle that produces a fi ne quality spray at an output consistent with the nozzle spacing on the boom, chosen forward speed, required spray volume and operating in the range 2-3 bar.

WARRANTY: The seller makes no warranty, expressed or implied, concerning the use of the product other than indicated on the label. The purchaser and user shall assume all risk associated with the use and/or handling and/or storage of the product if this use and/or handling and/or storage are carried out contrary to label instructions.

DAMAGES: Buyer’s or user’s exclusive remedy for damages for breach of warranty or negligence shall be limited to direct damage not exceeding the purchase price of the product, and shall not include incidental or consequential damages.

MATERIAL SAFETY DATA SHEET Version 9 UK+IR

Date: 28/01/2014 Replaces: 03/10/2012LENTAGRAN® WP Date of printing: 07/02/2014

SECTION 1: Identifi cation of the substance/preparation and of the company/undertaking: 1.1 Identifi cation of the substance/mixtureProduct name: Lentagran® WP Active ingredient: Pyridate Formulation type: WP (Wettable powder) 1.2 Recommended uses: Herbicide 1.3 Company identifi cation: Belchim Crop Protection NV/SA Technologielaan 7, 1840 Londerzeel - Belgium Tel. +32 (0)52 30 09 06 - Fax +32 (0)52 30 11 35 e-mail: info@belchim.com1.4 24 h emergency number: +32 (0)14 58 45 45

SECTION 2: Hazard identifi cation (*)2.1 Classifi cation of the substance or mixture2.1.1 DSD/DPDIndication of danger: Xi, Irritant N, Dangerous for the environment Adverse human health effects: R43: May cause sensitisation by skin contact.Environmental effects: R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.2.1.2 CLPSymbol: GHS 07, GHS 09Indication of Danger: WarningAdverse human health effects:Skin Sens. 1 : May cause allergic skin reactionEnvironmental effects:Aquatic Chronic 1: Very toxic to aquatic life with long lasting effects2.2 Label elementsCLPSymbol:

Indication of Danger: WarningH-statements:H317: May cause an allergic skin reaction.H410: Very toxic to the aquatic life with long lasting effects.P-statements:P272: Contaminated work clothing should not be allowed out of the workplace.P273: Avoid release to the environment.P280: Wear protective gloves/protective clothing.P302+352: IF ON SKIN: Wash with soap and water.P333+313: If skin irritation or a rash occurs: Get medical advice/attention.P391: Collect spillage.P501: Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste.Sp-phrases:SP1: Do not contaminate water with the product or its container; Do not clean application equipment near surface water. Avoid contamination via drains from farmyards and roads.EUH-phrases:EUH401: To avoid risks to human health and the environment, comply with the instructions for use.2.3 Other hazards: Combustible

SECTION 3: Composition/information on ingredients3.2. Mixtures

Hazardous ingredi-ents

Con-centra-tion (w/w)

n° CAS / n° EINECS / Index EC

Classifi cation according to DSD/DPD(symbols / R-phrases)(1)

Classifi cation ac-cording to CLP(2)

Pyridate 45% 55512-33-9/ 259-686-7/ -

Xi, NR38-43-50/53

Skin Irrit 2: H315Skin Sens 1: H317Aquatic Acute 1: H400Aquatic Chronic 1: H410

Sodium Methyl- Oleoyl-Taurate

< 3% 137-20-2/ 205-285-7/ -

XiR41

Eye Irrit 2: H319

Sodium Diisobu-tyl- Naphtale-nesul-phonate

< 3% 27213-90-7/ 248-326-4/-

XnR20/22,R36/38,R52/53

Acute Tox 4: H302Acute Tox 4: H332Skin Irrit 2: H315Eye Irrit 2: H319Aquatic Chronic 3: H412

(+)-Bor-nan-2-on

≤ 2% 464-49-3/207-355-2

F, XiR11, R36/37/38

Flam Sol 2: H228Skin Irrit 2: H315Eye Irrit 2: H319STOT Single 3: H335

(1) For R-phrases in full: see heading 2 and 16(2) For H-phrases in full: see heading 2 and 16

SECTION 4: First aid measures4.1 First-aid measuresInhalation: Move the affected person to the fresh air, protect him from hypothermia and let him rest. If breathing problems develop, seek medical advice immediately (show the label where possible).Ingestion: Repeatedly administer medical charcoal in a large quantity of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. if you feel unwell, seek medical advice immediately (show the label where possible).Skin contact: Remove contaminated clothing and thoroughly wash the affected part of the body with soap and water, rinse afterwards with warm water. If irritation persists, seek medical advice immediately (show the label where possible).Eye contact: Rinse immediate with plenty of water during at least 15 minutes. If irritation persists, seek medical advice immediately (show the label where possible).Protection of fi rst aiders4.2 Description of effects and symptomsOn the substance pyridate: There are no specifi c symptomatology expected for Pyridate poisoning.4.3 Indication of any immediate medical treatment or otherNo specifi c antidote is known. Apply symptomatic therapy.For additional information, please consult the 24 - hour emergency number: 0032 (0)14 58 45 45

SECTION 5: Firefi ghting measures5.1 Extinguishing mediaSuitable: Carbon dioxide (CO2) Foam Dry chemical extinguisher Water sprayUnsuitable: Do not use direct jet of water.5.2 Special hazardsThis product is combustible at elevated temperatures.Combustion products are toxic and/or irritantHazardous combustion products: carbon dioxide, carbon monoxide, nitrogen oxides, sulfur dioxide, hydrogen chloride.5.3. Advice for fi re-fi ghtersSpecifi c fi re-fi ghting methods:Isolate fi re area. Evacuate downwind.Contain the extinguishing fl uids by bunding (the product is hazardous for the environment). Measures have to be taken to prevent the contaminated extinguishing agent from seeping into the ground or from spreading uncontrollably.Do not attempt to fi ght the fi re without suitable protective equipment. Do not breathe fumes.Protection of fi re-fi ghters:Use self-contained breathing apparatus.Wear complete protective clothing.

SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency proceduresWear appropriate personal protective equipment (P.P.E.). For further information, refer to point 8 “Exposure control/individual protection”. 6.2 Environmental precautionsDo not allow product to spread into the environment.6.3 Methods for cleaning upContain the spilled material by bunding (product is hazardous for the environment).Collect product and dispose of in an incinerator approved for chemicals. Dampen solid material carefully to prevent it being blown away. Collect material in specially marked, tightly closed containers. Spilled product cannot be used further and must be disposed of. If safe disposal is not possible, contact the manufacturer, the dealer or the local representative; Do not contaminate waters and sewers.6.4 Reference to other sections: See section 8 and 13

SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions: Read the label before use. Use only in presence of adequate ventilation. Ensure that there are effi cient emergency eyewash facilities and showers in proximity. In addition to the measures usually taken when working with chemicals, such as dustproof fi lling and measuring equipment (including dust extraction), further personal protection measures may have to be implemented to avoid possible contact with the product.

Hygiene measures: Adopt standard personal hygiene measures. Do not drink, eat or smoke while working. Do not keep food in working area. Wash hands and exposed parts before eating, drinking or smoking and after work. Avoid all contact with the product to skin, eyes and clothing. Avoid inhaling of dusts.7.2 Storage and packaging conditionsStorage conditions: Store out of reach of children. Store separately from food, drinks, animal foodstuffs and stimulants. Do not store near pharmaceuticals or cosmetics. Store the product in a tightly closed and dry container. Store in a cool, well-ventilated area, in the original containers. Protect from excessive heat and cold, away from direct sunlight. Store in accordance with national or local regulations.Packaging materials: Original packaging.7.3 Specifi c end uses: Herbicide

SECTION 8: Exposure controls/ Personal protection8.1 Control parameters:8.2. Exposure controlsAppropriate engineering controls: Ensure good ventilation of the work station.Individual protection measures: - Hygiene: When using do not eat, drink or smoke. Wash hands and face with water and soap before taking a break and after work. Change working cloths each day. Observe normal industrial hygiene standards. Thoroughly clean protective gear. Thoroughly clean contaminated equipment with soap or soda solution.- Eye/Face protection: Ensure that there are effi cient emergency eyewash facilities and showers in proximity.- Skin/Hand protection: Wear long-sleeved protective work clothing. Heavy duty cotton or synthetic fabric working clothes (e.g. overalls). Rubber apron. Heavy duty shoes or boots.Chemical resistant gloves [EN 374 “Protective gloves against chemicals and micro-organisms“].- Respiratory protection: In case of presence of dusts or insuffi cient ventilation, use dust masks to avoid dust inhalation [EN 149 “Respiratory protective devices. Filtering half masks to protect against particles. Requirements, testing, marking” - Protection Class: FFP2(S)].Environmental exposure controls

SECTION 9: Physical and chemical properties9.1 Basic physical and chemical informationAppearance: Solid, PowderColour: White to off whiteOdour: Characteristic odourpH value: 4.67 (1%; in water) [CIPAC MT 75.3]Auto-fl ammability: Does not represent a self-ignition up to 220°CTap density: 0,36 g/cm³ [CIPAC MT 169, MT 186]Explosive properties: No explosive propertiesOxidising properties: No oxidising properties9.2 Other Information: No data available

SECTION 10: Stability and reactivity10.1 Reactivity: Not known10.2 Chemical stability: Yes10.3 Possibility of hazardous reactions: Not known10.4 Conditions to avoid: Not known10.5 Incompatible materials: Not known10.6. Hazardous decomposition products:Carbon dioxide, carbon monoxide, nitrogen oxides, sulphur dioxide, hydrogen chloride.

SECTION 11: Toxicological information11.1 Information on toxicological effectsGeneral: May cause sensitisation by skin contact.Acute Oral Toxicity LD50: LD50 (rat): 2330 mg/kg [OECD 401]Acute Dermal Toxicity LD50: LD50 (rat): > 4000 mg/kg [OECD 402]Acute Inhalation Toxicity LC50: LC50 (rat): > 2.14 mg/l [OECD 403]Skin Irritation: Not irritant (rabbit)Eye Irritation: Not irritant (rabbit)Skin sensitization: Sensitizing (Guinea pig maximization test)

SECTION 12. Ecological information12.1 Toxicity: Product is dangerous for the environment. Toxic to aquatic organisms, may cause long-term adverse effects.LC50 (Salmo gairdneri /96h): 118 mg/lLC50 (Cyprinus carpio/96h): 187.1 mg/l [OECD 203]EC50 (Daphnia magna/48h) 2.13 mg/l [OECD test medium]EC50 (Scenedesmus subspicatus/72h): 4.59 mg/l [OECD 201]12.2. Persistence and degradability: Not known12.3. Bioaccumulative potential: No (active substance pyridate BCF=116,3 for whole fi sh edible tissues)12.4. Mobility in soil: Not known12.5. Results of PBT and vPvB assessment: Not known12.6. Other adverse effects: Not known

SECTION 13: Disposal considerations13.1 Waste treatment methodsWaste-disposal procedures: Surplus and wastes must be disposed of in compliance with the country specifi c regulations, in a site authorised for collection and disposal of waste. Pay attention to protective clothing and measures. Cover up product with absorptive material such as sand, soil, diatomaceous earth, etc. Collect material in specially marked, tightly closed containers. Treat contaminated surfaces with water. Collect washings in containers to avoid any contamination of surface and ground water, water supplies and drains. Hose down the area for a prolonged period. Heavily contaminated soil layers have to be dug out down to clean soil. Spilled product cannot be used further and must be disposed of. If safe disposal is not possible, contact the manufacturer, the dealer or the representative and dispose of in an incinerator approved for chemicals.Waste of residues: Carry out the separation of waste. Evacuate as dangerous chemical waste, in accordance with the national or local regulation.Contaminated packaging: Do not reuse empty containers. Used containers must be disposed of in compliance with the current local/national regulations Dispose of empty containers in an incinerator approved for chemicals. Damaged containers: place original containers in specially marked larger ones. Check possibilities of recycling large empty containers, drums and barrels.

SECTION 14: Transport informationInternational regulationsLand transportation (RID/ADR)Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (pyridate)UN number: 3077Hazard identifi cation number: 90Labelling: 9Class: 9Classifi cation code: M7Packaging group: IIIMarine transport (IMO/IMDG)Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (pyridate)UN number: 3077Hazard identifi cation number: 9Packaging group: IIIMarine pollutant: YesAir transport (ICAO/IATA)Proper shipping name: Environmentally hazardous substance, solid, n.o.s. (pyridate)UN number: 3077Class: 9Packaging group: III

SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specifi c for the substance or mixture: No data available15.2. Chemical safety assessment: No data available

SECTION 16: Other informationR-phrases:R11: Highly fl ammableR20/22: Harmful by inhalation and if swallowedR36/38: Irritating to eyes and skinR36/37/38: Irritating to eyes, respiratory system and skinR38: Irritating to skinR52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environmentH-phrases:H228: Flammable solidH302: Harmful if swallowedH315: Causes skin irritationH319 :Causes serious eye irritationH332 Harmful if inhaledH335 :May cause respiratory irritationH400 :Very toxic to aquatic lifeH412: Harmful to aquatic life with long lasting effectsClasses:Acute Tox 4: Acute toxicity category 4Aquatic Acute 1: Acute toxicity category 1Aquatic Chronic 1: Chronic toxicity category 1Aquatic Chronic 3: Chronic toxicity category 3Eye Irrit 2: Eye irritation category 2Flam Sol 2: Flammable Solid category 2Skin Irrit. 2: Skin irritation category 2Skin Sens.1: Skin sensitisation category 1STOT Single 3: STOT single exposure category 3

Sources of key data used: Dossier Belchim Crop Protection NV SDS-sheets of ingredients Database ESIS

Trade name: Lentagran ® WP is a registered trade name of Belchim Crop Protection NV/SA

Further information: This SDS was updated (see date given at the top of the page) Subheadings and text which have been modifi ed since the previous version are indicated with an asterisk *.

This sheet completes the technical sheets but it does not replace them. The information given is based on our knowledge of this product, at the time of publication. It is given in good faith. The attention of the user is drawn to the risks possibly incurred by using the product for any other purpose than that for which it was intended. This does not in any way excuse the user from knowing and applying all the regulations governing his activity. It is the sole responsibility of the user to take all precautions required in handling the product. The mandatory regulations mentioned are only intended to help the user to fulfi l his obligations regarding the use of hazardous products. This listing must not be considered exhaustive. It does not exonerate the user from ensuring that other legal obligations than those mentioned do not exist, relating to the use and storage of the product for which he solely is responsible.

This safety data sheet is compliant with EC Regulation 1907/2006 (REACH) as adapted by 453/2010, Directive 67/548/EEC, 1999/45/EC (DSD/DPD) and EC Regulation 1272/2008 (CLP) and EC Regulation 1107/2009 (PPP).

14_0

6010

101_

XY

SPECIMEN -

2014

TO DATE