CONFIDENTIAL CHEMICALANALYSIS(%) · ISO 11126-5 :1993 (E) *THE SAMPLE OF GRIT WHICH WAS ANALYZED, IS HARMLESS FOR HUMAN HEALTH AND ENVIRONMENT Conductivity 137 Μs/cm (at 25 oC) Hardness

E

Constituent

Percent by Weight

Methodology Constituent Percent by Weight

Methodology

Na2O 0.09 ΕΝ 955-4 / AAS CI 0.014 EN 196-21 SiO2 37.90 ΕΝ 955-4 / AAS MgO 7.48 ΕΝ 955-4 / AAS NiO Traces ΕΝ 955-4 / AAS K2O 0.42 ΕΝ 955-4 / AAS

AI2O3 7.61 ΕΝ 955-4 / AAS TiO2 Traces ΕΝ 955-4 / AAS CaO 5.59 ΕΝ 955-4 / AAS Cr2O3 0.58 mg/kg ΕΝ 955-4 / AAS SO4 <0.10 EN 196-2 Fe2O3 39.54 ΕΝ 955-4 / AAS CuO Traces ΕΝ 955-4 / AAS ZnO Traces ΕΝ 955-4 / AAS

REMARKS THE SAMPLE TESTED AS PER ISO – 11126-5 STANDARDS OF NICKEL SLAG COMMENTS *THE ABOVE RESULTS ARE WITHIN THE RANGE OF VALUES SPECIFIED FOR METALLURGICAL SLUGS IN SPECIFICATION

ISO 11126-5 :1993 (E) *THE SAMPLE OF GRIT WHICH WAS ANALYZED, IS HARMLESS FOR HUMAN HEALTH AND ENVIRONMENT

Conductivity

137 Μs/cm (at 25 oC)

Hardness 6.5 ISO 11127-4- 93

Moisture 0.05% ISO 11127-5-93 Apparent ( kgr/m3) ISO 11127-4- Density 3500 93

Water soluble chlorides EN 196-2

0.01

Particle Size Distribution 0,2-2,8mm

REMARKS

Code Nr.: 785

Date of issue: 04.03.2015

TEST REPORT [ISO/IEC GUIDE 45-1985(E)]

CONFIDENTIALTEST DESCRIPTION

CHEMICAL ANALYSIS (%)METHOD SPEC: ELOT EN 955-4 PROCEDURE: 501 PERFORMANCE DATE: 04.03.2015 PREMISES: GRITSABLARE.RO

SPECIMENS DESCRIPTION. GRIT MATERIAL Sample of grit material

SPECIMENS NR 2-3

SPECIMENS IDENTIFICATION

Sample of grit material

MEASURMENT / TEST EQUIPMENT DESCRIPTION / IDENTIFICATION ATOMIC ABSORPTION SPECTROPHOTOMETER

REFERENCE AND CONSUMABLE MATERIALS

CALCULATED OR ESTIMATED CERTAINTY OF MEASUREMENTS INVOLVED

ATTACHMENTS CONCERNING THIS TEST

RESULTS

GritSablare Tel.: (+4) 0722.279.481 Fax: (+4) 0372.870.589Email: [email protected] Web: www.gritsablare.ro

D a t a R e v i z u i r i i : S e p t . 2 0 1 4 1 | P a g

Material: BLASTING GRIT MATERIAL (ISO 11126-5) MATERIA L SAFETY DATA SHEET (MSDS)

Section I. Product Identification

Material chemical name: FeNi-ERF slag (FeNi production)

Commercial names or synonyms: Blasting Grit Material

Chemical Family: Complex silica salts

Formula: None

Main uses: Sandblasting, ceramic industry, non-reinforced concrete, anti-slippery road paving, innovative construction material

Distributor: GritSablare Headquarter: 10 Eliza Zamfirescu Leonida Street, Bucharest

Storage & Logistic:

Termele Romane Street (between Gate 1 / Gate 2), Constanţa Seaport, Romania

Phone: (+4) 0722.279.481

Fax: (+4) 0372.870.589

Email: [email protected]

Website: www.gritsablare.ro

Section II. Composition and information on ingredients

Composition (typical analysis in weight %):

SiO2: 37.90

FeO: 23.69 Al2O3: 7.61

MgO: 7.48 CaO: 5.59 Fe2O3: 39.54

Cr2O3: 0.58 mg/kg

S: <0.10 Nichel: 40 mg / kg Fe (total): 39.54


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Nr CAS: 69012-29-9

Nr. EINECS: 273-729-7

Section III. Hazards identification

General: The exposure to FeNi-ERF slag does not cause any known health or environmental hazards, under normal handing and use. The properties of FeNi-ERF slags are usually very different from those of its constituent elements and thus the hazard of a slag cannot be simply related to the concentration of a hazardous element in it. Both animal and epidemiological studies indicate that FeNi-ERF slag does not present a possible cancer hazard.

Acute effects:

Inhalation: None

Ingestion: Not a normal route of entry

Skin: May cause either contact dermatitis or skin irritation in sensitive individuals after prolonged exposure.

Eye: May cause slight irritation from mechanical abrasion and existence of Cl ions on the surface.

Section IV. First-aid measures

Inhalation: Not anticipated

Ingestion: An unlikely route of entry due to pro duct form

Skin: Flush water, wash with mild soap

Eye: Flush water, remove contacts if worn

Section V. Fire-fighting measures

FeNi-ERF slag does not present fire or explosion hazards. Fires involving FeNi-ERF slag may be extinguished by any means consistent with other substances involved.

Section VI. Accidental release measures

Appropriate measures should be taken in order to avoid spillage.

Personal protection: Wear recommended personal protective equipment.

Procedure for cleaning: Sweep up with a minimum of dusting and recollection. Collection in a container e.g. mini bulk bag.


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Section VII. Handling and storage

Use gloves to avoid prolonged skin contact if handling contents directly.

Section VIII. Exposure controls / Personal protection

General Precautions: Good industrial hygiene should be followed. Avoid eye and skin contact.

Exposure Limit Values: Not established.

Personal Protection: Wear protective gloves, safety glasses and if dust is generated such that exposure is not maintained below recommended exposure limits, respiratory protection should be used.

Health Hazard Data: Medical Conditions Generally Aggravated by Exposure: Chronic lung conditions may be aggravated by exposure to high

concentrations of dust; Long-term dust inhalation may decrease the ability of the lungs to

clear particulate matter which may cause shortness of breath and increased susceptibility to respiratory disease.

Section IX. Physical and chemical properties

Appearance: Dark gray

Odour: None

Physical state: Solid particles

Liquidus temperature: (approx.) 1,350°C

Boiling point: (approx.) 2,875°C

Molecular weight: 1.7

Density: (approx.) 1.7g/cm3

Vapour pressure: N/A

Vapour density: N/A

Solubility: Not soluble in water

Section X. Stability and reactivity

Chemical stability: Stable

Incompatibility: None

Hazardous decomposition products: Cl-ions from the surface

Conditions to avoid: None

Reactivity: When FeNi-ERF slags dissolve in water Cl-ions are released


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Section XI. Toxicological information

General: Under normal handling and use of FeNi-ERF slags, no hazards are anticipated.

Acute effects:

Eye: May cause irritation due to mechanical effects and Cl-ions release.

Skin: Prolonged exposure may cause contact dermatitis or other allergic reactions especially in sensitive individuals because of Cl-ions release

Ingestion:: Not a normal route of entry.

Inhalation: No hazards are anticipated.

Chronic effects: FeNi-ERF slag does not present a possible cancer hazard.

Section XII. Ecological information

The concentration of all the metals analyzed in the TCLP test of the FeNi-ERF slag is one to four orders of magnitude lower than the US EPA toxicity limits and thus it is characterized as non toxic. The customer is responsible for the proper handling of the material after use, according to the specific regulations of the country it is imported in.

Take special precaution to note the potential hazards of the substrate, coatings or contamination that are removed by the use of our product. All Material Certifications and chemical analyses should be obtained before commencement of work.

Section XIII. Disposal consideration

Disposal is to be performed in compliance with all State Regulations.

Section XIV. Transport information

FeNi-ERF slag is regulated as inert, non-hazardous.

Section XV. Regulatory information

This product is classified as non-hazardous.

Section XVI. Other information

References: United States Environmental Protection Agency: "Test methods for evaluating solid waste, Voluce IC: Laboratory manual physical / chemical methods” (Washington, SW 846, 1986), 1311-1-1311-35.

Glossary: CAS No.: Chemical Abstracts Service Number EINECS No.: European Inventory of Existing Commercial Substances


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Notice to reader

GRITSABLARE has exercised reasonable care in the preparation of this information; however, the company assumes no responsibility as to the accuracy or suitability of such information for application to the intended purposes or for the consequence of its use. Moreover, since regulatory standards and guideline recommendations change from time to time, there is no assurance that hazard classifications, exposure limits and other regulatory requirements reflected in this MSDS will be current at the time the MSDS is used.

Documents

CONFIDENTIAL CHEMICALANALYSIS(%) · ISO 11126-5 :1993 (E) *THE SAMPLE OF GRIT WHICH WAS ANALYZED, IS HARMLESS FOR HUMAN HEALTH AND ENVIRONMENT Conductivity 137 Μs/cm (at 25 oC) Hardness