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CMA on-site 2 17./18.9.08 Budapest, Hungary. - PowerPoint PPT Presentation
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October 2008
CMA on-site 217./18.9.08
Budapest, Hungary
October 2008
Field trial in support to CMA (Activity 1)
organised by JRC IES RWERwith support by the Hungarian Ministry for
Environment and Water, the Serbian Ministry for Environment and Spatial Planning, the Slovak Environment Institute, the Italian Institute for Water Research and ICPDR
October 2008
Target compounds:
• Polycyclic Aromatic Hydrocarbons
• Polybrominated Diphenylethers
• Alkylphenols
Sampling and analysis according to current WFD chemical guidance draft document and WFD EQS proposal
Comparison of monitoring methods on-site among Member State laboratories
October 2008
18 participants from 12 countries
(2 non-EU)
+ 4 laboratories without sampling, only PAH
October 2008
Technical workshop:
1st day preparation and briefing
2nd day sampling
October 2008
Argus and Leanyfalu
October 2008
Sampling location
October 2008
Measurements on board
• Continuous logging of turbidity + temperature
• SPM concentration (gravimetric)
• DOC/POC
• Homogeneity measurements for PAH/PBDE/Alkylphenols
• Large volume sampling Filtration/Adsorption
• Large volume water centrifugation
October 2008
Sampling plan scheme for the CMA on-site 2 exercise
9:00 9:30 10:00 10:30 11:00 11:30 12:00 12:30 13:00
Time
In-situ Probe, temperature, turbidity
SPM gravimetric
DOC/POC
PAH/PBDE homogeneity sampling
Alkylphenol homogeneity sampling
PAH/PBDE sampling (filtration/adsorption)
Large volume sampling (centrifuge)
Grab Sampling by participants
October 2008
Laboratory of Argus
October 2008
Sampling on Leanyfalu
October 2008
Logistics.....
October 2008
The CMA on-site 2 team !
October 2008
• River water samples (whole procedure including sampling)
• River water extract (measurement with real sample matrix)
• Standard solutions (instrumental measurement only)
3 levels of comparison:
October 2008
Provided standard solutions and homogenised extracts (5 ampoules):
S1 PBDE Standard in Toluene (screw cap ampoule)A solution of WFD relevant PBDE (PBDE-28, PBDE-47, PBDE-99. PBDE-100, PBDE-153, PBDE-154) and (Decabromodiphenylether PBDE-209).Concentration of single compounds is < 1 µg/mlPlease note: While DecaBDE is not on the Priority Substance list, it appears to be of interest to collect further data on the analytical performance for this compound. Why encourage you therefore to report also this result. S2 PAH Standard solution in n-NonaneA solution of WFD relevant PAH*: Anthracene, Fluoranthene, Benzo[a]pyrene, Benzo[b]fluoranthene, Benzo[k]fluoranthene, Benzo[ghi]perylene and Indeno[1,2,3-cd]pyrene.Concentration of single compounds is < 1 µg/ml*except Naphthalene, as this is typically analysed by different analytical lines
October 2008
S3 Alkylphenol Standard solution in AcetoneA solution of WFD relevant Alkylphenols: 4-tert-octylphenol (OP) [CAS no. 140-66-9] and 4-nonylphenols (NP) –mixture of isomers [CAS no. 84852-15-3].Concentration of single compounds is < 1 µg/mlPlease note: The solution contains also 4-nonylphenol monoethoxylates (NP1EO) –mixture of isomers [CAS no. 26027-38-3] and4-nonylphenol diethoxylates (NP2EO) –mixture of isomers [CAS no. 26027-38-2]. While not being on the WFD Priority Substance list, we encourage you to report also data for these compounds in case they are included in your target list. E1 River spm extract for PAH and PBDE in HexaneThis is an extract of suspended particulate matter from a total of 300 L of water from the Danube River. The particulate matter has been extracted and the extract been apportioned into ca. 40 portions of ca. 0.6 ml each.E2 River water extract for Alkylphenol in Acetone*This is an elute from solid phase extraction of river water.*The solution could contain traces of methanol used during cartridge conditioning.
October 2008
Current state:
• Data reporting sheets have been send to participants
• Participants are asked to provide results until 30.11.08
• Presentations and info will be put on Circa
• Report to next CMA plenary