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Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis
by Feijie Song, Teng Zhang, Cheng Wang, and Wenbin Lin
Proceedings AVolume 468(2143):2035-2052
July 8, 2012
©2012 by The Royal Society
Chemical structures of Mn-salen-derived dicarboxylic acids L1-H2 to L4-H2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
Synthesis of CMOF-1 and CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
Powder XRD pattern (a) and TGA curve (b) for CMOF-1.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
Space-filling models of CMOF-1 (a) and CMOF-6′ (b), viewing perpendicular to the (001) plane.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
Empirical linear relationship between the MOF void space% as calculated by PLATON and the solvent weight loss% determined by TGA. Each square represents a MOF structure published by
the Lin group from 2002 to 2011.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
(a) Photos of CMOF-1 (left) and CMOF-6′ (right).
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
The coordination environment of the [Zn5(μ3-OH)2(O2CR)8] node (a) and the structure of the (L3)2 dimeric motif (b) in CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
A topological scheme of the threefold interpenetrated frameworks (a) and one of the frameworks (b) in CMOF-2.
Feijie Song et al. Proc. R. Soc. A 2012;468:2035-2052
©2012 by The Royal Society
