1
Also, there has been strong growth in the high density polyethylene (HDPE) and polyethylene terephthalate (PET) sectors, with growth rates since 2001 ranging between 3.4% and 4.4% per annum. HDPE and PET are widely used in plastic bottles and other containers. European suppliers of plastic colorants, especially organic colorants, are finding it increasingly difficult to compete on price against suppliers from India and China, with lower costs of plant construction, employee wages and pollution control. So, European colorant producers have tended to shift production to East Asia – by acquisitions or alliances – in order to curb costs and remain competitive. Press Release from: Frost & Sullivan, 1040 East Brokaw Road, San Jose, CA 95131-2309, USA. Website: http://www.frost.com (18 Oct 2006) & ICIS Chemical Business, 23 Oct 2006 (Website: http://icischemicalbusiness.com) PLANTS China: Changzhou Yabang – organic pigments Changzhou Yabang Chemical Co Ltd, a pigment manufacturer, suffered a fire on 23 August 2006 in the anthraquinone section of its Second Branch Factory at Changzhou-Wujin (Jiangsu province). The fire affected about 40 tonnes of benzene waste, contained in five storage tanks. Apparently, there were no personal injuries and no significant water pollution resulting from this incident. China Chemical Reporter, 6 Sep 2006, 17 (25), 12 China: China Nanotech – nanoPCC China Nanotech Inc (formerly known as Zeolite Exploration Co) has opened a 60,000 tonnes/y nanoparticulate precipitated calcium carbonate (NPCC) plant at the Shengda Industrial Park in Xianyang City (Shaanxi province). The plant employs the proprietary “membrane diffusion” technology developed by China Nanotech and Shandong Shengdatech in collaboration with Tsinghua University (See also ‘Focus on Pigments’, Jul 2006, 7). Compared against “ultra gravity” technology for making NPCC, the Tsinghua process offers significantly lower production costs, as well as improved quality control and product consistency. Carbon dioxide requirements are lower and the product generated has a narrow particle size range, 30-60 nanometres. Mr Xiangzhi Chen (President and CEO of China Nanotech) commented: “As the first commercial-scale producer employing this technology, we expect to realise a significant competitive advantage in the burgeoning global market for NPCC. We have already successfully tested the product in applications including tyres, rubber, plastic and paints. We believe this will give us a platform to develop exciting new applications for this versatile nano-scale material.” Press Release from: China Nanotech Inc. Tel: +1 (716) 621 3535. E-mail: [email protected] (14 Sep 2006) China: Doublestar, Henan Dongxin Tyre & local government – carbon black A 100,000 tonnes/y carbon black plant is to be built at the Hongzhou Industry Park in Hui county, Henan province. The project will cost Yuan 450-500 M ($57-63 M) and this will be financed jointly by the Qingdao Doublestar group, Henan Dongxin Tyre Co Ltd and the Henan Hui County Municipal Government. As part of the project, a large power plant will be installed, which will utilise waste gas streams from the carbon black plant. The entire project should take five years to complete. China Chemical Reporter, 16 Sep 2006, 17 (26), 7 China: Guangxi Dahua – TiO 2 Guangxi Dahua Chemical Works will spend just under $19 M to raise its TiO 2 pigment capacity in the Huahong district of Baise city from 12,000 tonnes/y to 25,000 tonnes/y by the end of 2008. TiO 2 Worldwide Update, May/Aug 2006, 14 (3/4), 19 China: Guangzhou Chemical – TiO 2 Further details have come to light regarding the reported titanium tetrachloride leak in the Tianhe district of Guangzhou city on 18 August 2006 (See ‘Focus on Pigments’, Oct 2006, 4). The emission was described as a “white acrid mist” and the source was named as the TiO 2 pigment plant owned by Guangzhou Chemical Industrial Group. As a precautionary measure, 200 residents in the Tianhe district were temporarily evacuated from their homes. In fact, the TiO 2 pigment plant under scrutiny was a 12,000 tonnes/y sulfate-route plant which had been closed by Guangzhou Chemical last year. Most of the plant and equipment at this site had been sold to a scrap metal and hardware enterprise, based at Jianmen. The white acrid mist was emitted when workers from the Jianmen enterprise were trying to clean and remove various pieces of equipment. Presumably chlorine or some chlorinated cleaning chemical reacted with titanium-containing residues, giving rise to the mist, which may have contained some titanium tetrachloride. In any event, it is now clear that the pigment plant was not operating at the time of the mishap and it had only ever employed conventional sulfate- route technology and not chloride- route technology. China Daily, 19 Aug 2006, 5 China: Nanjing – TiO 2 The 25,000 tonnes/y TiO 2 pigment plant in the Yuahuatai district of Nanjing was temporarily closed on 30 August 2006 on the orders of the Nanjing Environmental Protection Administration. The plant was said to be causing excessive pollution of the Qinghuai River and the operating company – Nanjing Titanium White Works – will have to improve its effluent control facilities before the pigment plant can be reopened. TiO 2 Worldwide Update, May/Aug 2006, 14 (3/4), 19 India: TTP – TiO 2 Government environmental approval has been granted to Travancore Titanium Products (TTP) in respect of its proposal to raise its TiO 2 pigment capacity from the current 15,000 tonnes/y to 33,000 tonnes/y. TTP has budgeted $55 M for this project. Apparently, no firm indication has been given for the target completion date. ICIS Chemical Business, 18 Sep 2006 (Website: http://icischemicalbusiness.com) NOVEMBER 2006 5 FOCUS ON PIGMENTS

China: Changzhou Yabang – organic pigments

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Page 1: China: Changzhou Yabang – organic pigments

Also, there has been strong growth inthe high density polyethylene (HDPE)and polyethylene terephthalate (PET)sectors, with growth rates since 2001ranging between 3.4% and 4.4% perannum. HDPE and PET are widelyused in plastic bottles and othercontainers.

European suppliers of plasticcolorants, especially organiccolorants, are finding it increasinglydifficult to compete on price againstsuppliers from India and China, withlower costs of plant construction,employee wages and pollutioncontrol. So, European colorantproducers have tended to shiftproduction to East Asia – byacquisitions or alliances – in order tocurb costs and remain competitive.

Press Release from: Frost & Sullivan, 1040 EastBrokaw Road, San Jose, CA 95131-2309, USA.Website: http://www.frost.com (18 Oct 2006) & ICISChemical Business, 23 Oct 2006 (Website:http://icischemicalbusiness.com)

PLANTSChina: Changzhou Yabang – organicpigments

Changzhou Yabang Chemical Co Ltd,a pigment manufacturer, suffered afire on 23 August 2006 in theanthraquinone section of its SecondBranch Factory at Changzhou-Wujin(Jiangsu province). The fire affectedabout 40 tonnes of benzene waste,contained in five storage tanks.Apparently, there were no personalinjuries and no significant waterpollution resulting from this incident.

China Chemical Reporter, 6 Sep 2006, 17 (25), 12

China: China Nanotech – nanoPCC

China Nanotech Inc (formerly knownas Zeolite Exploration Co) hasopened a 60,000 tonnes/ynanoparticulate precipitated calciumcarbonate (NPCC) plant at theShengda Industrial Park in XianyangCity (Shaanxi province). The plantemploys the proprietary “membranediffusion” technology developed byChina Nanotech and ShandongShengdatech in collaboration withTsinghua University (See also ‘Focuson Pigments’, Jul 2006, 7). Comparedagainst “ultra gravity” technology formaking NPCC, the Tsinghua process

offers significantly lower productioncosts, as well as improved qualitycontrol and product consistency.Carbon dioxide requirements arelower and the product generated hasa narrow particle size range, 30-60nanometres.

Mr Xiangzhi Chen (President andCEO of China Nanotech) commented:“As the first commercial-scaleproducer employing this technology,we expect to realise a significantcompetitive advantage in theburgeoning global market for NPCC.We have already successfully testedthe product in applications includingtyres, rubber, plastic and paints. Webelieve this will give us a platform todevelop exciting new applications forthis versatile nano-scale material.”

Press Release from: China Nanotech Inc. Tel: +1 (716)621 3535. E-mail: [email protected] (14 Sep2006)

China: Doublestar, Henan Dongxin Tyre& local government – carbon black

A 100,000 tonnes/y carbon blackplant is to be built at the HongzhouIndustry Park in Hui county, Henanprovince. The project will cost Yuan450-500 M ($57-63 M) and this will befinanced jointly by the QingdaoDoublestar group, Henan DongxinTyre Co Ltd and the Henan HuiCounty Municipal Government. Aspart of the project, a large power plantwill be installed, which will utilisewaste gas streams from the carbonblack plant. The entire project shouldtake five years to complete.

China Chemical Reporter, 16 Sep 2006, 17 (26), 7

China: Guangxi Dahua – TiO2

Guangxi Dahua Chemical Works willspend just under $19 M to raise itsTiO2 pigment capacity in the Huahongdistrict of Baise city from 12,000tonnes/y to 25,000 tonnes/y by theend of 2008.

TiO2 Worldwide Update, May/Aug 2006, 14 (3/4), 19

China: Guangzhou Chemical – TiO2

Further details have come to lightregarding the reported titaniumtetrachloride leak in the Tianhe districtof Guangzhou city on 18 August 2006(See ‘Focus on Pigments’, Oct 2006,4). The emission was described as a

“white acrid mist” and the source wasnamed as the TiO2 pigment plantowned by Guangzhou ChemicalIndustrial Group. As a precautionarymeasure, 200 residents in the Tianhedistrict were temporarily evacuatedfrom their homes.

In fact, the TiO2 pigment plantunder scrutiny was a 12,000 tonnes/ysulfate-route plant which had beenclosed by Guangzhou Chemical lastyear. Most of the plant and equipmentat this site had been sold to a scrapmetal and hardware enterprise, basedat Jianmen. The white acrid mist wasemitted when workers from theJianmen enterprise were trying toclean and remove various pieces ofequipment. Presumably chlorine orsome chlorinated cleaning chemicalreacted with titanium-containingresidues, giving rise to the mist, whichmay have contained some titaniumtetrachloride.

In any event, it is now clear that thepigment plant was not operating at thetime of the mishap and it had onlyever employed conventional sulfate-route technology and not chloride-route technology.

China Daily, 19 Aug 2006, 5

China: Nanjing – TiO2

The 25,000 tonnes/y TiO2 pigmentplant in the Yuahuatai district ofNanjing was temporarily closed on 30August 2006 on the orders of theNanjing Environmental ProtectionAdministration. The plant was said tobe causing excessive pollution of theQinghuai River and the operatingcompany – Nanjing Titanium WhiteWorks – will have to improve itseffluent control facilities before thepigment plant can be reopened.

TiO2 Worldwide Update, May/Aug 2006, 14 (3/4), 19

India: TTP – TiO2

Government environmental approvalhas been granted to TravancoreTitanium Products (TTP) in respect ofits proposal to raise its TiO2 pigmentcapacity from the current 15,000tonnes/y to 33,000 tonnes/y. TTP hasbudgeted $55 M for this project.Apparently, no firm indication has beengiven for the target completion date.

ICIS Chemical Business, 18 Sep 2006 (Website:http://icischemicalbusiness.com)

NOVEMBER 2006 5

F O C U S O N P I G M E N T S