Embed Size (px)
Citation preview
Sample ID :
Lab ID :
Date :
Client :
Sample Number :
Sample Date :
Sample Time :
Location :
Reported by : Tung Xiao Dan
Assistant Chemist
Approved by : Mark Tan
Section Head
Feedstock Evaluation Department
4/4
SAC Singlas: Environmental Testing (Cert No: LA-2000-0176-F)
2014-FED-051699
Run Down
01 October 2014
Chim Sao Crude
Premier Oil
10/9/2014
1500hrs
LRQA ISO 9001:2000 Certification (Cert No: SNG 0945092)
Our Accreditation are as follows:
SAC Singlas ISO 17025:2005 : Chemical and Biological Testing (Cert No: LA-1997-0115-A)
Disclaimer :
This report (including any enclosures and attachments) has been prepared for the exclusive use and benefit
of the addressee(s) and solely for the purpose for which it is provided. Unless we provide express prior
written consent, no part of this report should be reproduced, distributed or communicated to any third party.
We do not accept any liability if this report is used for an alternative purpose from which it is intended, nor
do we owe any duty of care to any third party in respect of this report. The interpretations or opinions
expressed represent the best judgement of Intertek Singapore. Intertek holds no responsibility nor makes
any warranty, either expressed or implied, regarding the productivity, proper operation, or profitability of any
oil, in connection with which this report is used or relied upon for any reason whatsoever.
4.5 VGO …………………………………………………..……….……….……….
16
17
4.7 Atmospheric Distillation (D86) Report …..……………..…………………….
14
3. Assay Summary ……………………………………………………………………..
4.8 Detailed Hydrocarbon Analysis ………….. …..………………………………………
7
82.5 Graph of True Boiling Point against Graph of HTSD …………………..…….
11
4. Properties of Cuts
9
15
Table of Content
Section
31. Properties of Whole Crude …………………………………………………………
Page
2. Distillation Yield Data and Curves
2.1 Distillation %mass Yield and %volume Yield Data ……….……….…………
2.4 Simulated Distillation Data ……………………………………………………………….
62.3 Graph of Cumulative Middle %volume against API Gravity, °API ………….
4
2.2 Graph of Cumulative % yield against Temperature, °C AET ……….………. 5
12
13
4.1 LPG …………………………………………………..……….……….………..
4.2 Naphtha …………………………………………………..……….……….……….
10
4.3 Kerosene …………………………………………………..……….……….……….
4.4 Gas Oil …………………………………………………..……….……….……….
4.6 Residue …………………………………………………..……….……….……….
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 2
NA1 - Unable to perform due to sample nature. Test was done at alternative temperature.
11 Ib/1000bbl
D4294 0.0280 %mass
°C
D323A (mod) 5.20
Properties of Crude
<1
ICPES wt.ppm
wt.ppmICPES
1
psi
<1
ICPMS
IP143
UOP375
Asphaltenes
Carbon Residue - Micro D4530
Arsenic
Characterisation Factor
cSt
MJ/kg
<3 wt.ppm
4.526
cSt
wt.ppb
wt.ppm
cSt
ICPES
<2
Metal - Nickel
Metal - Sodium
Metal - Lead
Sulphur - Total
Metal - Vanadium
Nitrogen - Total
Pour Point - Upper
Reid Vapour Pressure
Date
Metal - Calcium
Mercury Content
Salt Content
D56
Result
D5002
Density @15°C
Specific Gravity @60/60°F
API Gravity
01 October 2014
Sample ID Chim Sao Crude
UOP779
42.1
D240
NA1
Lab ID 2014-FED-051699
Premier OilClient ID
Unit
<0Flash Point
Chloride - Organic
Gross Calorific Value
Metal - Iron
Kinematic Vis @80°C
Kinematic Vis @50°C
Kinematic Vis @100°C
Hydrogen Sulphide
D445
Method
0.8145
0.8149
Test
12.6
°C
-
<10
<0.50
<2.0
1.18 %m/m
kg/L
°API
%m/m
wt.ppm
-
wt.ppb
<1UOP163
D445
320
+33
UOP938
wt.ppmICPES
ICPES
D5853
wt.ppm
wt.ppmD5762
42.0
ICPES
2.263
D445
D3230
46.095
wt.ppm
11
Total Acid Number D664A <0.05 mg KOH/g
Water and Sediment D4007 0 %volume
Wax Content UOP46 22.4 %mass
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 3
0.7745
17.3
11.9
2.2
100.0
23.7
2.2
8.0
17.06.8
10.2
Cumulative
88.2
88.9
24.3
11.1
74.9
86.7
340 - 450
6.8
6.0
27.3
33.3
50.6
230 - 260
260 - 340
6.1
17.3
20.6
0.6842
2.2
Specific Gravity
%volume
23.14.1
0.7560
0.7679
1.7 0.5712
Cut Range%volume
Distillation %mass Yield and %volume Yield
155 - 185
6.6
95 - 140
140 - 155
3.9
6.3
1.9
1.7
C5 - 95
185 - 230
565+
450 - 540
540 - 565
8.6
2.0
11.2
19.0
100.0
77.0
90.2
29.9
9.8
14.9
16.8
0.7883
°C
6.8
Water removed during distillation - 48ml (0.32vol%)
Data is based on dewatered sample (Dry Crude)
%mass%mass
Cumulative
LPG
2.0
53.3
@60/60°F
0.9245
0.8168
0.8824
0.8353
36.0
0.8599
0.8079
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 4
%mass
53.32
76.99
15
20.65
16.76
260
565
140
Temperature
17.0014.86
19.02
23.10
36.02
27.26
90.25
90.25
565 90.25
88.94
90.25
90.25
90.25
90.25
95
88.94
88.22
90.25
90.2588.94
88.94
90.25
90.25
88.94
86.74
74.89
565
565
0
90.25
Cumulative
33.28
0.00
2.21
10.22
%volume
88.94
88.94
565
565
565
88.94
88.94565
88.94
88.94
88.94
88.94
88.94
565
88.94
88.94
88.94
88.94
565
565
565
88.94
155
0.00
88.94
88.94
88.94
90.25
90.25
565
565
29.94
90.25
90.25
565
565
565
565
185
°C AET
90.25
90.25
90.25
565
90.25
90.25
88.94
88.94565
88.94
565
450
90.25
230
88.94
Cumulative
Graph of Cumulative % yield against Temperature, °C AET
90.25
90.25
565
565
565 90.25
88.94
1.75
8.57
50.63
565
340
540
565
565
90.25
90.25
90.25
90.25
88.94
565
88.94565
0
50
100
150
200
250
300
350
400
450
500
550
600
0 10 20 30 40 50 60 70 80 90 100
Cumulative % yield
Te
mp
era
ture
, °C
AE
T
Graph of Cumulative %mass against AET, °C Graph of Cumulative %volume against AET, °C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 5
21.6
28.9
21.6
565
565 21.6
185
565
565
565
565
565
565
565
41.7
95
230 43.6
155
13.61
0
15
48.0
95.12
6.21
21.6
565
95.12
95.12
95.12
95.12
21.6
21.6 95.12
565
565
21.6
95.12
37.9
21.6
95.12
21.6
95.12
95.12
21.6
21.6
21.6
18.01
26.52
44.67
95.12
95.12
21.06
565
Temperature
89.23
95.12
21.6
95.12
21.6
21.6
95.12
95.12
95.12
21.6
21.6
21.6
21.6
21.6
65.15
95.12
95.12
95.12
95.12
95.12
95.12
95.12
Middle %volume
55.7
95.12
95.12
565
565
565
565
565
565
565
95.12
565
140
340
260
565
33.1450
540
21.6
°C AET
52.8
565
21.6
565
21.6
21.6
565
Graph of Cumulative Middle %volume against API Gravity, °API
565
21.6
21.6
21.6
565
565
565
51.2
21.6
21.6
95.12
82.60
1.10
95.12
°API
API Gravity Cumulative
116.2
32.98
75.3
0.0
10.0
20.0
30.0
40.0
50.0
60.0
70.0
80.0
90.0
100.0
110.0
120.0
130.0
0 10 20 30 40 50 60 70 80 90 100
Cumulative Middle %volume
AP
I G
rav
ity
, °A
PI
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 6
°C
<36
421
39
276
<36
<36 36
37
270
11
19
12
13
14
2
10
7
3
6
8
9
5
4
29
24
15
18
17
16
22
25
21
20
107
95
42
113
43
85
99
46
45
44
85
83
84
81
40
41
47
316
257
287
38
303
302
Temperature%mass
70
271
415
Temperature
°C °C
422
427
Simulated Distillation Data
%mass
<36
%mass
IBP
1
34
35
520
492
440
86
470
76
73
68
75
310
69
71
72
74
286
292
300
142
137
332
431
54
70
77
39
483
317
443
476
80
79
78
77
465
458
449
330
264
151
55
190
166
235
49
50
58
179
401
391
64
63
214
230
223
379
395
381
388
366
357
369
56
57
216 60
62
61
59
26
30
28
27
23
251
246
238
65
196
202
123
33 254 67
402
40932
31 750
66
412
593
724
93
639
97
98
621
95
690
96 661
607
94
92
99
373
88
510
90
91
543
82
581
531
434
453
501
555
568
89
174
129
356
325
53
54
34251
159 344
Temperature
349 87
48
52
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 7
#REF!
0
0
30
#REF!20
15
#REF!
0
#REF!5
#REF!
#REF!
#REF!
#REF!
25
#REF!
10
#REF!
#REF!
°C%mass%mass
0
#REF!
0
#REF!
#REF!
#REF!
#REF!
#REF!
#REF!
#REF!
#REF!
#REF!
%mass
#REF!1 0
Temperature Temperature
0
°C
0
0
Graph of True Boiling Point against Graph of HTSD
°C
Temperature
#REF!#REF!
0
50
100
150
200
250
300
350
400
450
500
550
600
650
700
750
800
0 10 20 30 40 50 60 70 80 90 100
Cumulative %mass
Te
mp
era
ture
, °C
AE
T
TBP HTSD
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 8
Sample ID
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 1.7 6.8 6.3 1.9 3.9 6.6 6.0 17.3 24.3 11.9 2.2 11.1
Volume Yield %volume 2.2 8.0 6.8 2.0 4.1 6.8 6.1 17.3 23.7 11.2 2.0 9.8
Density @15°C kg/L 0.8145 0.5712 0.6840 0.7558 0.7676 0.7742 0.7879 0.8075 0.8164 0.8349 0.8594 0.8819 0.9240
Specific Gravity @60/60°F - 0.8149 0.5712 0.6842 0.7560 0.7679 0.7745 0.7883 0.8079 0.8168 0.8353 0.8599 0.8824 0.9245
API Gravity °API 42.1 116.2 75.3 55.7 52.8 51.2 48.0 43.6 41.7 37.9 33.1 28.9 21.6
Aniline Point D611 °C 57.10 68.75 74.55 87.00 107.50 117.30 123.30
Arsenic ICPMS wt.ppb <10
Ash D482 %mass <0.001 <0.001 <0.001 0.012
Asphaltenes IP143 %m/m <0.50 <0.50 <0.50 <0.50 <0.50
Carbon Residue - Micro D4530 %m/m 1.18 <0.01 0.10 0.94 10.9
Cetane Index D4737 (Proc.A) - 43.7 54.6 59.6 74.8
Characterisation Factor UOP375 - 12.6
Chloride - Organic UOP779 wt.ppm <2.0
Cloud Point D2500 °C -19 +8
Cold Filter Plugging Point IP309 °C -20 +7
Colour - ASTM D1500 - L0.5 1.5 4.0 D8.0
Colour - Saybolt D156 - +30 +30 +30 +30
Copper Corrosion D130 - 1a 1a 1a 1a
DHA - Paraffins D6730 %mass 74.4 47.6 60.1
DHA - Olefins D6730 %mass <0.1 <0.1 <0.1
DHA - Naphthenes D6730 %mass 20.3 31.6 14.9
DHA - Aromatics D6730 %mass 5.4 20.7 24.0
DHA - Unknowns D6730 %mass <0.1 0.1 1.0
FIA - Aromatics D1319 %volume 9.2 10.0
Flash Point D56/ IP170/ D93A °C <0 26.5 41.5 67.5 100.0 134.0 198.0 230.0 262.0
Freeze Point D5972 °C <-60 -53.8 -36.6 -13.8
Gross Calorific Value D240 MJ/kg 46.095
Hydrogen Sulphide UOP163 wt.ppm <1
Kinematic Vis @40°C D445 cSt 0.7325 0.8965 1.350
Kinematic Vis @50°C D445 cSt 4.526 1.694 2.963 8.950
Kinematic Vis @80°C D445 cSt 2.263
Kinematic Vis @100°C D445 cSt NA1 3.245 6.593 13.01 78.91
Kinematic Vis @135°C D445 cSt 3.683 6.526 29.73
Mercury Content UOP938 wt.ppb 42.0
Metal - Calcium ICPES wt.ppm <3 <3 <3 <3 4
Metal - Iron ICPES wt.ppm <2 <2 <2 <2 8
Metal - Lead ICPES wt.ppm <1 <1 <1 <1 <1
Metal - Nickel ICPES wt.ppm 1 <1 <1 <1 8
Metal - Sodium ICPES wt.ppm 11 <1 <1 <1 85
Metal - Vanadium ICPES wt.ppm <1 <1 <1 <1 <1
Naphthalenes D1840 %volume 0.07 2.44 5.52
Nitrogen - Total D4629/ D5762 wt.ppm 320 <1 <1 <1 <1 <1 2.4 24 130 350 730 2100
Octane Number - Research Calculation - 67.3 68.3 77.3
Octane Number - Motor D2700 - 66 53 NA2
Octane Number - Research D2699 - 69 56 NA2
PNA - Paraffins D5443 Ext %mass 60.94
PNA - Naphthenes D5443 Ext %mass 19.19
PNA - Aromatics D5443 Ext %mass 19.38
PNA - High Boiling D5443 Ext %mass 0.49
Pour Point - Upper D5853 °C +33
Pour Point D97 °C -18 +6 +42 +57 +72
Reid Vapour Pressure D323A (mod) psi 5.20
Reid Vapour Pressure D323A psi 8.75 1.05
Refractive Index @70°C D1747 - 1.4299 1.4350 1.4444 1.4570 NA3
Salt Content D3230 Ib/1000bbl 11
Smoke Point D1322 mm 25.5 27.0 28.5 24.5
Softening Point D36 °C NA4 70.6
Sulphur - Mercaptan D3227 wt.ppm <3 <3 <3 <3 <3 <3
Sulphur - Total D4294 %mass 0.0280 <0.0016<0.0016<0.0016<0.0016<0.0016 0.0065 0.0234 0.0260 0.0399 0.0612 0.0968
Total Acid Number D3242/ D974/ D664A mg KOH/g <0.05 0.003 0.005 0.009 0.047 0.034 0.04 <0.05 <0.05 <0.05 <0.05
Water and Sediment D4007 %volume 0
Wax Content UOP46 %mass 22.4
Note :
NA1 - Unable to perform due to sample nature. Test was done at alternative temperature.
NA2 - Insufficient cut yield to perform test.
NA3 - Colour ASTM >4.0, not applicable for D1747.
NA4 - Unable to perform, out of method scope.
D5002/ D4052/
D2598
D2892 / D5236
LP
G
Cut Range
Wh
ole
Chim Sao Crude
2014-FED-051699
Premier Oil
01 October 2014
C5
- 9
5°C
95
- 1
40
°C
14
0 -
15
5°C
15
5 -
18
5°C
45
0 -
54
0°C
54
0 -
56
5°C
56
5+
°C
18
5 -
23
0°C
23
0 -
26
0°C
26
0 -
34
0°C
34
0 -
45
0°C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 9
Sample ID
Lab ID
Cut Range
Date
Test Method Result Unit
Mass Yield 1.7 %mass
Volume Yield 2.2 %volume
Density @15°C 0.5712 kg/L
Specific Gravity @60/60°F 0.5712 -
API Gravity 116.2 °API
Ethane 0.061
Propane 9.755
n-Butane 55.175
Isobutane 29.067
n-Pentane 0.426
Isopentane 5.042
2,2-dimethylpropane 0.426
C6+ 0.049
D2892
D2598
D2421 / D2598 /
D2163%mass
Chim Sao Crude
2014-FED-051699
LPG
01 October 2014
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 10
Sample ID
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 6.8 6.3 1.9
Volume Yield %volume 8.0 6.8 2.0
Density @15°C kg/L 0.6840 0.7558 0.7676
Specific Gravity @60/60°F - 0.6842 0.7560 0.7679
API Gravity °API 75.3 55.7 52.8
Colour - Saybolt D156 - +30
DHA - Paraffins D6730 %mass 74.4 47.6 60.1
DHA - Olefins D6730 %mass <0.1 <0.1 <0.1
DHA - Naphthenes D6730 %mass 20.3 31.6 14.9
DHA - Aromatics D6730 %mass 5.4 20.7 24.0
DHA - Unknowns D6730 %mass <0.1 0.1 1.0
Flash Point IP170 °C 26.5
Freeze Point D5972 °C <-60
Kinematic Vis @40°C D445 cSt 0.7325
Nitrogen - Total D4629 wt.ppm <1 <1 <1
Octane Number - Research Calculation - 67.3 68.3 77.3
Octane Number - Motor D2700 - 66 53 NA2
Octane Number - Research D2699 - 69 56 NA2
Reid Vapour Pressure D323A psi 8.75 1.05
Smoke Point D1322 mm 25.5
Sulphur - Mercaptan D3227 wt.ppm <3 <3 <3
Sulphur - Total D4294 %mass <0.0016 <0.0016 <0.0016
Total Acid Number D3242 mg KOH/g 0.003 0.005
Note :
NA2 - Insufficient cut yield to perform test.
D4052
D2892
01 October 2014
NaphthaChim Sao Crude
2014-FED-051699
Premier Oil
C5 -
95°C
95 -
140°C
140 -
155°C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 11
Sample ID
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 3.9 6.6
Volume Yield %volume 4.1 6.8
Density @15°C kg/L 0.7742 0.7879
Specific Gravity @60/60°F - 0.7745 0.7883
API Gravity °API 51.2 48.0
Aniline Point D611 °C 57.10 68.75
Cetane Index D4737 (Proc.A) - 43.7 54.6
Colour - Saybolt D156 - +30 +30
Copper Corrosion D130 - 1a 1a
FIA - Aromatics D1319 %volume 9.2
Flash Point IP170 °C 41.5 67.5
Freeze Point D5972 °C -53.8 -36.6
Kinematic Vis @40°C D445 cSt 0.8965 1.350
Naphthalenes D1840 %volume 0.07 2.44
Nitrogen - Total D4629 wt.ppm <1 <1
PNA - Paraffins D5443 Ext %mass 60.94
PNA - Naphthenes D5443 Ext %mass 19.19
PNA - Aromatics D5443 Ext %mass 19.38
PNA - High Boiling D5443 Ext %mass 0.49
Smoke Point D1322 mm 27.0 28.5
Sulphur - Mercaptan D3227 wt.ppm <3 <3
Sulphur - Total D4294 %mass <0.0016 <0.0016
Total Acid Number D3242 mg KOH/g 0.009 0.047
D4052
D2892
185 -
230°C
01 October 2014
KeroseneChim Sao Crude
2014-FED-051699
Premier Oil
155 -
185°C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 12
Sample ID
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 6.0 17.3
Volume Yield %volume 6.1 17.3
Density @15°C kg/L 0.8075 0.8164
Specific Gravity @60/60°F - 0.8079 0.8168
API Gravity °API 43.6 41.7
Aniline Point D611 °C 74.55 87.00
Cetane Index D4737 (Proc.A) - 59.6 74.8
Cloud Point D2500 °C -19 +8
Cold Filter Plugging Point IP309 °C -20 +7
Colour - ASTM D1500 - L0.5
Colour - Saybolt D156 - +30
Copper Corrosion D130 - 1a 1a
FIA - Aromatics D1319 %volume 10.0
Flash Point D93A °C 100.0 134.0
Freeze Point D5972 °C -13.8
Kinematic Vis @50°C D445 cSt 1.694 2.963
Naphthalenes D1840 %volume 5.52
Nitrogen - Total D4629 wt.ppm 2.4 24
Pour Point D97 °C -18 +6
Refractive Index @70°C D1747 - 1.4299 1.4350
Smoke Point D1322 mm 24.5
Sulphur - Mercaptan D3227 wt.ppm <3
Sulphur - Total D4294 %mass 0.0065 0.0234
Total Acid Number D3242/ D974 mg KOH/g 0.034 0.04
D4052
D2892
Gas OilChim Sao Crude
2014-FED-051699
Premier Oil
01 October 2014
230 -
260°C
260 -
340°C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 13
Sample ID
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 24.3 11.9 2.2
Volume Yield %volume 23.7 11.2 2.0
Density @15°C kg/L 0.8349 0.8594 0.8819
Specific Gravity @60/60°F - 0.8353 0.8599 0.8824
API Gravity °API 37.9 33.1 28.9
Aniline Point D611 °C 107.50 117.30 123.30
Ash D482 %mass <0.001 <0.001 <0.001
Asphaltenes IP143 %m/m <0.50 <0.50 <0.50
Carbon Residue - Micro D4530 %m/m <0.01 0.10 0.94
Colour - ASTM D1500 - 1.5 4.0 D8.0
Flash Point D93A °C 198.0 230.0 262.0
Kinematic Vis @50°C D445 cSt 8.950
Kinematic Vis @100°C D445 cSt 3.245 6.593 13.01
Kinematic Vis @135°C D445 cSt 3.683 6.526
Metal - Calcium ICPES wt.ppm <3 <3 <3
Metal - Iron ICPES wt.ppm <2 <2 <2
Metal - Lead ICPES wt.ppm <1 <1 <1
Metal - Nickel ICPES wt.ppm <1 <1 <1
Metal - Sodium ICPES wt.ppm <1 <1 <1
Metal - Vanadium ICPES wt.ppm <1 <1 <1
Nitrogen - Total D5762 wt.ppm 130 350 730
Pour Point D97 °C +42 +57 +72
Refractive Index @70°C D1747 - 1.4444 1.4570 NA3
Softening Point D36 °C NA4
Sulphur - Total D4294 %mass 0.0260 0.0399 0.0612
Total Acid Number D664A mg KOH/g <0.05 <0.05 <0.05
Note :
NA3 - Colour ASTM >4.0, not applicable for D1747.
NA4 - Unable to perform, out of method scope.
D4052
D5236
Chim Sao Crude
2014-FED-051699
Premier Oil
01 October 2014
450 -
540°C
540 -
565°C
340 -
450°C
Vacuum Gas Oil
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 14
Sample ID Residue
Lab ID
Client ID
Date
Test Method Unit
Mass Yield %mass 11.1
Volume Yield %volume 9.8
Density @15°C kg/L 0.9240
Specific Gravity @60/60°F - 0.9245
API Gravity °API 21.6
Ash D482 %mass 0.012
Asphaltenes IP143 %m/m <0.50
Carbon Residue - Micro D4530 %m/m 10.9
Kinematic Vis @100°C D445 cSt 78.91
Kinematic Vis @135°C D445 cSt 29.74
Metal - Calcium ICPES wt.ppm 4
Metal - Iron ICPES wt.ppm 8
Metal - Lead ICPES wt.ppm <1
Metal - Nickel ICPES wt.ppm 8
Metal - Sodium ICPES wt.ppm 85
Metal - Vanadium ICPES wt.ppm <1
Nitrogen - Total D5762 wt.ppm 2100
Softening Point D36 °C 70.6
Sulphur - Total D4294 %mass 0.0968
Total Acid Number D664A mg KOH/g <0.05
565+
°C
D4052
D5236
Chim Sao Crude
2014-FED-051699
Premier Oil
01 October 2014
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 15
Sample ID
Lab ID
Client ID
Date
Description °C °C °C °C
IBP 155.2 188.6 225.5 265.2
Recovery @ 5% 159.4 194.1 232.6 275.8
Recovery @ 10% 161.8 197.3 236.1 280.3
Recovery @ 15% 163.0 199.1 237.3 281.7
Recovery @ 20% 163.6 199.9 237.7 282.7
Recovery @ 30% 164.9 201.7 238.7 284.8
Recovery @ 40% 166.1 203.6 239.5 287.4
Recovery @ 50% 167.4 205.6 240.4 290.2
Recovery @ 60% 168.9 207.4 241.5 293.3
Recovery @ 70% 170.8 209.9 242.7 297.4
Recovery @ 80% 173.0 212.8 244.3 302.4
Recovery @ 85% 174.5 214.7 245.4 305.6
Recovery @ 90% 176.7 217.1 246.8 309.5
Recovery @ 95% 180.8 220.9 248.9 314.3
FBP 186.2 224.1 252.3 318.6
% vol % vol % vol % vol
Total Recovered 97.6 97.4 98.2 98.4
Residue 1.3 1.4 1.4 1.0
Loss 1.1 1.2 0.4 0.6
Cut Range 155 - 185°C 185 - 230°C 230 - 260°C
Distillation Report (ASTM D86)
Chim Sao Crude
2014-FED-051699
Premier Oil
01 October 2014
260 - 340°C
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 16
Detailed Hydrocarbon Analysis
Boiling Range °C
mass %
vol %
Component mass % vol %
n-butane 0.266 0.312
2,2-dimethylpropane 0.014 0.016
i-pentane 13.375 14.660
n-pentane 13.614 14.765
2,2-dimethylbutane 1.052 1.101
cyclopentane 1.202 1.095
2,3-dimethylbutane 2.211 2.269
2-methylpentane 9.639 10.023
3-methylpentane 5.407 5.528
n-hexane 12.716 13.096
2,2-dimethylpentane 0.488 0.492
methylcyclopentane 5.907 5.359
2,4-dimethylpentane 0.802 0.810
2,2,3-trimethylbutane 0.172 0.169
benzene 3.952 3.054
3,3-dimethylpentane 0.266 0.261
cyclohexane 4.883 4.260
2-methylhexane 3.625 3.627
2,3-dimethylpentane 1.091 1.066
1,1-dimethylcyclopentane 0.595 0.536
3-methylhexane 3.258 3.220
1c,3-dimethylcyclopentane 0.975 0.889
1t,3-dimethylcyclopentane 0.875 0.794
3-ethylpentane 0.191 0.185
1t,2-dimethylcyclopentane 1.344 1.215
n-heptane 5.969 5.928
methylcyclohexane 4.294 3.790
2,2-dimethylhexane 0.118 0.116
ethylcyclopentane 0.135 0.120
2,5-dimethylhexane 0.043 0.042
2,4-dimethylhexane 0.040 0.038
1c,2t,4-trimethylcyclopentane 0.029 0.026
1t,2c,3-trimethylcyclopentane 0.017 0.015
1.434 1.123
C5 - 95
6.8
8.0
Yield
toluene
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 17
Boiling Range °C
mass %
vol %
Component mass % vol %
Class Summary
n-Paraffins 32.565 34.101
Iso-Paraffins 41.791 43.623
Naphthenes 20.258 18.099
Aromatics 5.386 4.177
Olefins 0.000 0.000
Unidentified 0.000 0.000
Average Molecular Weight : 83.716
Relative Density : 0.679
Vapor Pressure, 8.41
calc. RVP (EPA method) : @ 100F
Octane Number (calculated) : 67.26
Percent Carbon : 84.620
Percent Hydrogen : 15.380
C5 - 65
Yield 6.8
8.0
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 18
Totals by Group Type & Carbon Number (in Mass Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.266 0.000 0.000 0.000 0.000 0.266
C5: 13.614 13.389 0.000 1.202 0.000 28.205
C6: 12.716 18.309 0.000 10.791 3.952 45.768
C7: 5.968 9.892 0.000 8.219 1.434 25.514
C8: 0.000 0.201 0.000 0.046 0.000 0.247
C9: 0.000 0.000 0.000 0.000 0.000 0.000
C10: 0.000 0.000 0.000 0.000 0.000 0.000
C11: 0.000 0.000 0.000 0.000 0.000 0.000
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 32.565 41.791 0.000 20.258 5.386 100.000
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 0.000 100.000
Totals by Group Type & Carbon Number (in Volume Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.312 0.000 0.000 0.000 0.000 0.312
C5: 14.765 14.676 0.000 1.095 0.000 30.535
C6: 13.096 18.921 0.000 9.619 3.054 44.690
C7: 5.928 9.830 0.000 7.344 1.123 24.226
C8: 0.000 0.196 0.000 0.041 0.000 0.237
C9: 0.000 0.000 0.000 0.000 0.000 0.000
C10: 0.000 0.000 0.000 0.000 0.000 0.000
C11: 0.000 0.000 0.000 0.000 0.000 0.000
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 34.101 43.623 0.000 18.099 4.177 100.000
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 0.000 100.000
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 19
Detailed Hydrocarbon Analysis
Boiling Range °C
mass %
vol %
Component mass % vol %
i-pentane 0.047 0.057
n-pentane 0.020 0.024
2,3-dimethylbutane 0.015 0.017
2-methylpentane 0.070 0.081
3-methylpentane 0.068 0.077
n-hexane 0.294 0.335
2,2-dimethylpentane 0.043 0.047
methylcyclopentane 0.365 0.367
2,4-dimethylpentane 0.076 0.085
2,2,3-trimethylbutane 0.023 0.025
benzene 0.325 0.278
3,3-dimethylpentane 0.063 0.068
cyclohexane 0.898 0.867
2-methylhexane 1.147 1.270
2,3-dimethylpentane 0.380 0.411
1,1-dimethylcyclopentane 0.205 0.204
3-methylhexane 1.391 1.521
1c,3-dimethylcyclopentane 0.468 0.472
1t,3-dimethylcyclopentane 0.478 0.479
3-ethylpentane 0.109 0.117
1t,2-dimethylcyclopentane 0.769 0.769
n-heptane 7.557 8.307
methylcyclohexane 12.063 11.784
2,2-dimethylhexane 0.822 0.888
ethylcyclopentane 0.619 0.607
2,5-dimethylhexane 0.736 0.798
2,4-dimethylhexane 0.757 0.813
1c,2t,4-trimethylcyclopentane 0.605 0.595
3,3-dimethylhexane 0.255 0.270
1t,2c,3-trimethylcyclopentane 0.517 0.504
2,3,4-trimethylpentane 0.046 0.048
toluene 9.564 8.291
2,3-dimethylhexane 0.760 0.802
2-methyl-3-ethylpentane 0.107 0.113
2-methylheptane 4.762 5.128
4-methylheptane 1.353 1.443
3-methyl-3-ethylpentane 0.082 0.087
3,4-dimethylhexane 0.153 0.159
95 - 140
6.3
6.8
Yield
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 20
Boiling Range °C
mass %
vol %
Component mass % vol %
1c,2c,4-trimethylcyclopentane 0.093 0.092
3-methylheptane 3.261 3.472
1c,2t,3-trimethylcyclopentane 4.430 4.322
1t,4-dimethylcyclohexane 1.799 1.773
1,1-dimethylcyclohexane 0.595 0.573
2,2,5-trimethylhexane 0.101 0.108
3c-ethylmethylcyclopentane 0.219 0.214
3t-ethylmethylcyclopentane 0.197 0.193
2t-ethylmethylcyclopentane 0.292 0.285
1,1-methylethylcyclopentane 0.073 0.071
1t,2-dimethylcyclohexane 1.448 1.402
n-octane 14.069 15.052
i-propylcyclopentane 0.100 0.097
N1 0.055 0.053
2,3,4-trimethylhexane 0.069 0.070
N2 0.035 0.034
N3 0.260 0.251
1c,2-dimethylcyclohexane 0.687 0.648
2,3,5-trimethylhexane 0.013 0.013
1,1,4-trimethylcyclohexane 1.927 1.876
2,2,3-trimethylhexane 1.297 1.363
2,4-dimethylheptane 0.026 0.027
4,4-dimethylheptane 0.723 0.759
n-propylcyclopentane 0.177 0.171
*1c,3c,5-trimethylcyclohexane 1.018 0.994
2,5-dimethylheptane 0.250 0.262
2,6-dimethylheptane 0.079 0.084
1,1,3-trimethylcyclohexane 0.045 0.043
N8 0.016 0.016
ethylbenzene 1.236 1.072
1c,2t,4t-trimethylcyclohexane 0.500 0.482
I4 0.030 0.031
1,3-dimethylbenzene 5.919 5.148
1,4-dimethylbenzene 1.952 1.704
2,3-dimethylheptane 0.364 0.377
3,4-dimethylheptane 0.285 0.293
N14 0.121 0.117
4-methyloctane 0.762 0.795
1.100 1.159
95 - 140
Yield 6.3
6.8
2-methyloctane
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 21
Boiling Range °C
mass %
vol %
Component mass % vol %
1c,2t,3-trimethylcyclohexane 0.066 0.065
3-ethylheptane 0.156 0.161
3-methyloctane 0.985 1.028
1c,2t,4c-trimethylcyclohexane 0.035 0.034
1,2-dimethylbenzene 1.495 1.276
N19 0.019 0.018
N20 0.327 0.315
I9 0.151 0.156
i-butylcyclopentane 0.013 0.013
N23/t-nonene-2 0.029 0.028
I10 0.016 0.016
n-nonane 2.540 2.660
N24 0.014 0.013
i-propylbenzene 0.055 0.048
N27 0.049 0.046
i-propylcyclohexane 0.026 0.024
I12 0.013 0.014
2,2-dimethyloctane 0.012 0.013
2,4-dimethyloctane 0.026 0.027
2,6-dimethyloctane 0.055 0.056
2,5-dimethyloctane 0.022 0.023
3,3-dimethyloctane 0.036 0.037
n-propylbenzene 0.017 0.015
1,3-methylethylbenzene 0.053 0.046
1,4-methylethylbenzene 0.017 0.015
1,3,5-trimethylbenzene 0.021 0.018
4-methylnonane 0.016 0.016
1,2,4-trimethylbenzene 0.011 0.010
95 - 140
Yield 6.3
6.8
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 22
Boiling Range °C
mass %
vol %
Component mass % vol %
Class Summary
n-Paraffins 24.479 26.379
Iso-Paraffins 23.110 24.685
Naphthenes 31.648 30.910
Aromatics 20.664 17.920
Olefins 0.000 0.000
Unidentified 0.100 0.107
Average Molecular Weight : 107.158
Relative Density : 0.752
Vapor Pressure, 0.60
calc. RVP (EPA method) : @ 100F
Octane Number (calculated) : 68.26
Percent Carbon : 86.674
Percent Hydrogen : 13.326
95 - 140
Yield 6.3
6.8
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 23
Totals by Group Type & Carbon Number (in Mass Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.000 0.000 0.000 0.000 0.000 0.000
C5: 0.020 0.047 0.000 0.000 0.000 0.066
C6: 0.294 0.154 0.000 1.263 0.325 2.037
C7: 7.557 3.231 0.000 14.600 9.564 34.952
C8: 14.069 13.093 0.000 11.597 10.601 49.359
C9: 2.540 6.405 0.000 4.188 0.174 13.306
C10: 0.000 0.180 0.000 0.000 0.000 0.180
C11: 0.000 0.000 0.000 0.000 0.000 0.000
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 24.479 23.109 0.000 31.648 20.664 99.900
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 0.100 100.000
Totals by Group Type & Carbon Number (in Volume Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.000 0.000 0.000 0.000 0.000 0.000
C5: 0.024 0.057 0.000 0.000 0.000 0.080
C6: 0.335 0.175 0.000 1.234 0.278 2.023
C7: 8.307 3.545 0.000 14.315 8.291 34.459
C8: 15.052 14.021 0.000 11.294 9.199 49.567
C9: 2.660 6.701 0.000 4.067 0.151 13.579
C10: 0.000 0.185 0.000 0.000 0.000 0.185
C11: 0.000 0.000 0.000 0.000 0.000 0.000
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 26.378 24.685 0.000 30.910 17.920 99.893
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 0.107 100.000
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 24
Detailed Hydrocarbon Analysis
Boiling Range °C
mass %
vol %
Component mass % vol %
n-heptane 0.056 0.063
methylcyclohexane 0.406 0.401
2,2-dimethylhexane 0.029 0.032
ethylcyclopentane 0.023 0.023
2,5-dimethylhexane 0.025 0.027
2,4-dimethylhexane 0.029 0.032
1c,2t,4-trimethylcyclopentane 0.037 0.037
3,3-dimethylhexane 0.016 0.017
1t,2c,3-trimethylcyclopentane 0.036 0.035
toluene 0.587 0.514
2,3-dimethylhexane 0.082 0.088
2-methylheptane 0.440 0.478
4-methylheptane 0.133 0.143
3,4-dimethylhexane 0.016 0.017
1c,3-dimethylcyclohexane 0.015 0.015
3-methylheptane 0.372 0.401
1c,2t,3-trimethylcyclopentane 0.975 0.961
1t,4-dimethylcyclohexane 0.430 0.429
1,1-dimethylcyclohexane 0.151 0.146
2,2,5-trimethylhexane 0.017 0.018
3c-ethylmethylcyclopentane 0.047 0.046
3t-ethylmethylcyclopentane 0.045 0.045
2t-ethylmethylcyclopentane 0.067 0.066
1,1-methylethylcyclopentane 0.019 0.018
1t,2-dimethylcyclohexane 0.535 0.523
n-octane 3.618 3.910
i-propylcyclopentane 0.048 0.047
N1 0.033 0.032
2,3,4-trimethylhexane 0.034 0.035
N3 0.154 0.150
1c,2-dimethylcyclohexane 0.473 0.451
2,3,5-trimethylhexane 0.026 0.027
2,2-dimethylheptane 0.012 0.013
1,1,4-trimethylcyclohexane 1.677 1.649
2,2,3-trimethylhexane 1.051 1.116
2,4-dimethylheptane 0.026 0.027
4,4-dimethylheptane 1.042 1.106
n-propylcyclopentane 0.287 0.281
*1c,3c,5-trimethylcyclohexane 0.965 0.952
2,5-dimethylheptane 0.276 0.292
140 - 155
1.9
2.0
Yield
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 25
Boiling Range °C
mass %
vol %
Component mass % vol %
2,6-dimethylheptane 0.107 0.115
1,1,3-trimethylcyclohexane 0.065 0.062
N8 0.019 0.018
ethylbenzene 1.068 0.935
1c,2t,4t-trimethylcyclohexane 1.346 1.310
I3 0.012 0.012
I4 0.088 0.091
1,3-dimethylbenzene 7.422 6.521
1,4-dimethylbenzene 2.505 2.209
2,3-dimethylheptane 0.636 0.665
3,4-dimethylheptane 0.548 0.569
I5 0.278 0.289
4-ethylheptane 1.967 2.073
2-methyloctane 3.335 3.550
1c,2t,3-trimethylcyclohexane 0.362 0.363
3-ethylheptane 0.573 0.599
3-methyloctane 3.383 3.566
1c,2t,4c-trimethylcyclohexane 0.210 0.206
1,2-dimethylbenzene 3.764 3.247
I6 0.017 0.017
N18 0.131 0.128
N19 0.253 0.247
N20 2.323 2.261
I8 0.184 0.191
I9 1.095 1.139
i-butylcyclopentane 0.137 0.133
N21 0.048 0.047
N22 0.271 0.264
I10 0.113 0.118
n-nonane 28.590 30.252
N24 0.209 0.201
i-propylbenzene 0.525 0.462
N27 0.717 0.690
i-propylcyclohexane 0.577 0.546
I12 0.365 0.380
2,2-dimethyloctane 0.249 0.261
2,4-dimethyloctane 0.834 0.871
N28 0.132 0.127
N29 0.151 0.145
2,6-dimethyloctane 1.785 1.863
2,5-dimethyloctane 0.866 0.901
140 - 155
Yield 1.9
2.0
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 26
Boiling Range °C
mass %
vol %
Component mass % vol %
n-butylcyclopentane 0.224 0.217
N30 0.756 0.717
I14 0.127 0.132
3,3-dimethyloctane 2.260 2.322
N31 0.206 0.196
n-propylbenzene 0.622 0.548
3,6-dimethyloctane 0.209 0.216
3-methyl-5-ethylheptane 0.546 0.571
N32 0.147 0.139
1,3-methylethylbenzene 2.419 2.124
1,4-methylethylbenzene 0.845 0.745
N33 0.098 0.093
1,3,5-trimethylbenzene 1.938 1.701
I15 0.251 0.258
I16 0.087 0.090
5-methylnonane 0.324 0.335
4-methylnonane 0.789 0.809
1,2-methylethylbenzene 0.352 0.303
2-methylnonane 0.810 0.847
3-ethyloctane 0.178 0.183
3-methylnonane 0.583 0.604
I18 0.012 0.012
1,2,4-trimethylbenzene 1.592 1.380
I20 0.067 0.069
i-butylcyclohexane 0.090 0.086
I21 0.027 0.028
I22 & I23 0.016 0.016
N37 0.012 0.011
1t-methyl-2-n-propylcyclohexane 0.014 0.013
I24 0.019 0.020
i-butylbenzene 0.030 0.027
sec-butylbenzene 0.040 0.035
n-decane 1.458 1.516
1,2,3-trimethylbenzene 0.124 0.105
1,3-methyl-i-propylbenzene 0.047 0.041
1,4-methyl-i-propylbenzene 0.016 0.014
2-3-dihydroindene 0.015 0.012
sec-butylcyclohexane 0.012 0.011
1,2-methyl-i-propylbenzene 0.038 0.033
3-ethylnonane 0.014 0.014
0.042 0.043
140 - 155
Yield 1.9
2.0
I31
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 27
Boiling Range °C
mass %
vol %
Component mass % vol %
1,3-methyl-n-propylbenzene 0.012 0.010
1,2-methyl-n-propylbenzene 0.014 0.012
Class Summary
n-Paraffins 33.722 35.741
Iso-Paraffins 26.418 27.704
Naphthenes 14.931 14.537
Aromatics 23.971 20.979
Olefins 0.000 0.000
Unidentified 0.958 1.039
Average Molecular Weight : 120.970
Relative Density : 0.759
Vapor Pressure, 0.01
calc. RVP (EPA method) : @ 100F
Octane Number (calculated) : 77.30
Percent Carbon : 86.672
Percent Hydrogen : 13.328
140 - 155
Yield 1.9
2.0
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 28
Totals by Group Type & Carbon Number (in Mass Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.000 0.000 0.000 0.000 0.000 0.000
C5: 0.000 0.000 0.000 0.000 0.000 0.000
C6: 0.000 0.000 0.000 0.000 0.000 0.000
C7: 0.056 0.000 0.000 0.429 0.587 1.072
C8: 3.618 1.141 0.000 3.370 14.758 22.887
C9: 28.590 14.819 0.000 9.798 8.415 61.621
C10: 1.458 10.403 0.000 1.334 0.211 13.406
C11: 0.000 0.055 0.000 0.000 0.000 0.055
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 33.722 26.418 0.000 14.931 23.971 99.042
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 0.958 100.000
Totals by Group Type & Carbon Number (in Volume Percent)
Paraffins: I-paraffins: Olefins: Naphthenes: Aromatics: Total:
C1: 0.000 0.000 0.000 0.000 0.000 0.000
C2: 0.000 0.000 0.000 0.000 0.000 0.000
C3: 0.000 0.000 0.000 0.000 0.000 0.000
C4: 0.000 0.000 0.000 0.000 0.000 0.000
C5: 0.000 0.000 0.000 0.000 0.000 0.000
C6: 0.000 0.000 0.000 0.000 0.000 0.000
C7: 0.062 0.000 0.000 0.424 0.514 1.000
C8: 3.910 1.233 0.000 3.300 12.912 21.356
C9: 30.252 15.629 0.000 9.547 7.368 62.795
C10: 1.516 10.785 0.000 1.267 0.184 13.753
C11: 0.000 0.057 0.000 0.000 0.000 0.057
C12: 0.000 0.000 0.000 0.000 0.000 0.000
C13: 0.000 0.000 0.000 0.000 0.000 0.000
Total : 35.741 27.704 0.000 14.537 20.978 98.961
Oxygenates : Total C14+ : Unknowns : Grand Total :
0.000 0.000 1.039 100.000
2014-FED-051699 Chim Sao Crude Assay Report.xls Page 29
