Chemistry Test for Ions 1

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    Test for IonsTest for the positive ions Na+K+Ca+

    Sr+Ba+Cu2+

    ApparatusTake nichrome wire and and dip it with

    concentrated HCl acid and bring it to the roaring

    fame. Keep doing it until no colour is produced.

    This is done to clean the nichrome wire and to

    make sure that no other chemical Is present. Next

    we will do ame test take the acid with nichrome

    wire arain and dip with the unknown solid. Place the

    nichrome wire in the roaring fame. !emember to

    clean nichrome wire beore beore each experimentb" concentrated HCl acid#.

    The resulting fame will produce di$erent colour

    Na% K% Ca% &r% 'a% Cu(%

    Nichrome

    !oari

    'unse)nknown

    Flame

    test is

    applicable

    for

    Group

    1 an

    !roup

    2

    metal

    s

    inclu

    in!

    coppe

    r

    ions"

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    *ellow+

    orange

    ,ilac fame 'rick red

    fame

    !ed fame ,ight green

    fame

    'lue

    fame

    ,ithum ions - red

    &ulphur ions - blue Carbon ions - orange

    Test for Transaction metal ionor transaction metal ion we can add &odium h"droxide to a unknown

    transaction ion.

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    Cu2+ Fe2+ Fe#+ $n2+

    'lue prcipitate /reen precipitate

    but become red+

    brown upon

    standing because

    Iron II# h"droxide

    gets oxidi0ed.

    !ed+brown

    precipitate

    1hite precipitate

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    N2T3+ Copper ions can be tested in either fame test wa" or precipitation

    test.

    Test for Ammonium ions4mmonium ions is dipped in sodium h"droxide.

    It reacts with h"droxide to orm ammonia and water

    4mmonia can be tested b" putting holding damp red litmus paper which

    turns blue.

    2rdip a glass rod into the concentratedHCi 5essel and dip it into the solution

    and this will produce 4mmonium

    chloride with white smoke that

    con6rms 4mmonia is present.

    Test for ne!ative ions

    Carbonate ions C%#2&

    Test- To either the solid7 or an a8ueous solution o the solid7 under test add

    dilute h"drochloric acid.

    It is best to use dilute nitric acid. &ome acid+carbonate combinations can

    produce an insoluble salt that coats the solid carbonate and stops the

    reaction7 but this doesn9t happen i "ou use nitric acid because all nitrates

    are soluble.

    !esult- This will or bubbles o gas carbon dioxide#. This gas will turn

    limewater milk". Carbonate % acid salt % water % carbon dioxide

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    Sulphate ions S%'2&

    Test- To an a8ueous solution o the solid under test7 add dilute h"drochloric

    acid ollowed b" a ew drops o barium chloride solution.

    !esult- This will orm a white precipitate o barium sulphate#.

    Test for (alie Ions4pparatus

    )nknown &olid is taken )nknown &olid is

    :isssol5ed in 1ater

    :ilute Nitric acid is

    added to to remo5e

    an" Impurities in orderto gi5e a clear result.

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    Then 4dd ew drops o 48ueous &il5er

    Nitrate and &il5er halides precipitate will

    orm which gi5es di$erent colours or

    di$erent Halide ions.

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    Chlorine Cl&

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    Bromine Br&

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    Ioine I&

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    )roblems

    4::

    :ilute 48ueous 4mmonia dissol5e &il5er chloride but not sil5er bromide

    'ut concentrated 48ueous 4mmonia will dissol5e both &il5er chloride and

    &il5er bromide

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    'ut