1
1999 structure structure (solids and liquids) D 2000 27 - 001 Synthesis and Crystal Structure of [Re 2 Br 4 (Te 2 )(TeBr) 2 (TeBr 2 ) 2 ], a Dinuclear Complex with Te 2 2- , TeBr - , and TeBr 2 Ligands. Single crystal XRD shows that the title compound (V) crystallizes in the monoclinic space group P2 1 with Z = 4. The structure contains discrete dinuclear molecular units consisting of Re–Re dumbbells each coordinated by a μ-Te 2 group and two μ-TeBr groups. Additionally each Re atom is coordinated by two terminal Br and a TeBr 2 ligand. — (BECK, JOHANNES; MUELLER-BUSCHBAUM, KLAUS; Eur. J. Inorg. Chem. (1999) 5, 839-842; Inst. Anorg. Anal. Chem., Justus-Liebig-Univ., D-35392 Giessen, Germany; EN) 1

ChemInform Abstract: Synthesis and Crystal Structure of [Re2Br4(Te2)(TeBr)2 (TeBr2)2], a Dinuclear Complex with Te22-, TeBr-, and TeBr2 Ligands

Embed Size (px)

Citation preview

Page 1: ChemInform Abstract: Synthesis and Crystal Structure of [Re2Br4(Te2)(TeBr)2 (TeBr2)2], a Dinuclear Complex with Te22-, TeBr-, and TeBr2 Ligands

1999 structure

structure (solids and liquids)D 2000

27 - 001Synthesis and Crystal Structure of [Re2Br4(Te2)(TeBr)2 (TeBr2)2],a Dinuclear Complex with Te2

2−, TeBr−, and TeBr2 Ligands. —Single crystal XRD shows that the title compound (V) crystallizes in themonoclinic space group P21 with Z = 4. The structure contains discretedinuclear molecular units consisting of Re–Re dumbbells each coordinatedby a µ-Te2 group and two µ-TeBr groups. Additionally each Re atom iscoordinated by two terminal Br and a TeBr2 ligand. — (BECK, JOHANNES;MUELLER-BUSCHBAUM, KLAUS; Eur. J. Inorg. Chem. (1999) 5, 839-842;Inst. Anorg. Anal. Chem., Justus-Liebig-Univ., D-35392 Giessen, Germany;EN)

1