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1996 oxidation, dehydrogenation, ozonolysis oxidation, dehydrogenation, ozonolysis O 0210 18 - 054 Selective Oxidation of O-Isopropylidene Derivatives of Diols to 2- Hydroxy Ketones Employing Dioxiranes. — The title oxidation is performed in a very eﬃcient way without loss of optical quality in the cases where chiral acetonides are used. The reaction leads to interesting hydroxy ketones, which are diﬃcultly accessible using common oxidation reagents. — (CURCI, R.; D’ACCOLTI, L.; DINOI, A.; FUSCO, C.; ROSA, A.; Tetrahedron Lett. 37 (1996) 1, 115-118; Dip. Chim., Univ. Bari, I-70126 Bari, Italy; EN) 1

ChemInform Abstract: Selective Oxidation of O-Isopropylidene Derivatives of Diols to 2- Hydroxy Ketones Employing Dioxiranes

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Page 1: ChemInform Abstract: Selective Oxidation of O-Isopropylidene Derivatives of Diols to 2- Hydroxy Ketones Employing Dioxiranes

1996 oxidation, dehydrogenation, ozonolysis

oxidation, dehydrogenation, ozonolysisO 0210

18 - 054Selective Oxidation of O-Isopropylidene Derivatives of Diols to 2-Hydroxy Ketones Employing Dioxiranes. — The title oxidation isperformed in a very efficient way without loss of optical quality in the caseswhere chiral acetonides are used. The reaction leads to interesting hydroxyketones, which are difficultly accessible using common oxidation reagents. —(CURCI, R.; D’ACCOLTI, L.; DINOI, A.; FUSCO, C.; ROSA, A.; TetrahedronLett. 37 (1996) 1, 115-118; Dip. Chim., Univ. Bari, I-70126 Bari, Italy; EN)

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