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1999 structure
structure (solids and liquids)D 2000
12 - 011(NH4)4Na2 [Mo2V2
IV V6V O28]·10H2O. — Single crystals of the title
compound are grown hydrothermally from mixtures of NH4VO3, Na2MoO4,H2C2O4, and H2O (pH 6; autoclave, 433 K, 4 d). The compound, whichcrystallizes in the triclinic space group P1 (Z = 1), has a well known de-cavanadate structure. The centrosymmetric polyanion is built up by eight(V/Mo)O6 and two VO6 edge-sharing distorted octahedra. — (XU, YAN;XU, JI-QING; YANG, GUO-YU; XING, YAN; LIN, YONG-HUA; JIA, HENG-QING; Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 54 (1998) 12,1733-1735; Dep. Chem., Jilin Univ., Changchun 130023, Peop. Rep. China; EN)
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