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SulfoxidesQ 0600 DOI: 10.1002/chin.201142073
First Enantioselective Iron—Porphyrin-Catalyzed Sulfide Oxidation with Aque-ous Hydrogen Peroxide. — The asymmetric oxidation of sulfides (I) by hydrogen per-oxide to give optically active sulfoxides (II) is carried out in aqueous MeOH using a chiral water-soluble iron-porphyrin complex. — (LE MAUX, P.; SIMONNEAUX*, G.; Chem. Commun. (Cambridge) 47 (2011) 24, 6957-6959, http://dx.doi.org/10.1039/c1cc11675d ; Lab. Sci. Chim., Ing. Chim. Mol. Vivant, Univ. Rennes, F-35042 Rennes, Fr.; Eng.) — M. Paetzel
42- 073
ChemInform 2011, 42, issue 42 © 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim