2001 C-C bond formation

C-C bond formationO 0282

37 - 073Atom-Efficient Metal-Catalyzed Cross-Coupling Reaction of In-dium Organometallics with Organic Electrophiles. — A new andgenerally high-yielding metal-catalyzed cross-coupling reaction is developedinvolving triorganoindium compounds. The reaction proceeds with differentorganoindium compounds and a range of electrophiles. It shows high regio- andchemoselectivity and high atom efficiency. All three organic groups attached toindium can be transferred. — (PEREZ, IGNACIO; SESTELO, JOSE PEREZ;SARANDESES, LUIS A.; J. Am. Chem. Soc. 123 (2001) 18, 4155-4160; Dep.Quim. Fundam. Ind., Fac. Cienc., Univ. La Coruna, E-15071 La Coruna,Spain; EN)

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