2000 copper, Cu

copper, CuI 7400

34 - 017A Novel Microporous Cluster Polymer {[Et4N]2 [WS4Cu4(CN)4]}n

with Cyanide-Bridged Three-Dimensional Open-Framework. —The title compound (III) crystallizes in the orthorhombic space group Fdddwith Z = 8 (single crystal XRD). The structure contains one crystallographicallyindependent [(CuCN)4WS4]2− anion which is bridged by cyanide groups toproduce a three-dimensional intersecting channel system. The Et4N+ cationsare located within the channels. — (ZHANG, CHI; JIN, GUOCHENG; XU,YAN; FUN, HOONG-KUN; XIN, XINQUAN; Chem. Lett. (2000) 5, 502-503;State Key Lab. Coord. Chem., Nanjing Univ., Nanjing 210093, Peop. Rep.China; EN)

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