Chemical Analysis of Floors in La Casa de las Aguilas, Templo Mayor, Using NITON pXRF and Spot Tests Claudia Brackett, Richard Lundin, Luis Barba, Agustin

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Chemical Analysis of Floors in La Casa de las Aguilas, Templo Mayor, Using NITON pXRF and Spot Tests Claudia Brackett, Richard Lundin, Luis Barba, Agustin Ortiz, and Martin Terreros Slide 2 This PowerPoint has been modified from its original presentation format to make easier to understand by a single viewer without narration by an oral presenter Slide 3 The study site is located in the Aztec City of Tenochtitlan and is presently in downtown Mexico City Slide 4 The study site, The House of the Eagles, is located to the north of Templo Mayor Slide 5 Samples were collected with a masonry drill. Samples were bagged and taken to the laboratory for analysis. Slide 6 The samples were treated to chemical spot tests for protein, carbohydrates, fatty acids, pH, and phosphorous The samples were treated to chemical spot tests for protein, carbohydrates, fatty acids, pH, and phosphorous. Slide 7 Then the samples were analyzed for up to 22 elements by portable X-ray fluorescence Slide 8 Do not try to read all this data. Just understand the wealth of information that we had to choose from. 22 elements times all of the sample sites gave us a lot to work with. Slide 9 We decided to focus attention on elements that complemented the results of the chemical spot tests Slide 10 First, the raw numbers were graphed so that trends could be determined. Relevant elements were selected for further analysis and mapping. Slide 11 This is the floor plan for the House of the Eagles. Numbers indicate sample locations. The chemical spot tests were done for all of these samples. Slide 12 pXRF analysis of the elements was done only for samples taken from the inner room. Slide 13 The pXRF data will be displayed on this schematic of the inner room. Slide 14 Statuary was found at the site. Their locations are indicated here. Slide 15 The results of the chemical tests suggested use areas Slide 16 High pH (dark red) is associated with ash. Slide 17 Here ashes are associated with the braziers. High values are in portico area, while the lower values are in the central room. Higher pH values occur in areas surrounding the main altar. The highest values are around the braziers in the north doorway and the corners of the pillars. X X X X Slide 18 Potassium, (K), is also associated with wood fires. The pXRF distribution in the inner room indicated a fairly even distribution of K Slide 19 Potassium distribution is reasonably consistent with pH thus supporting the assignment of ash. Slide 20 Phosphorous can be an indication of organic tissue deposition. Phosphorous enrichment has been associated with food preparation and burials. Possible sources of phosphorous are nucleic acid and the phospho-lipid cell membrane. Phosphorous could also be expected from blood deposition. Slide 21 High levels of phosphorous were in the portico while low values were in the open patio. Important concentrations can be observed close to the altars and braziers. Phosphorous values increase in the doorways between the sculptures. Slide 22 Protein, specifically albumin was assayed. Protein suggests the presence of blood. Slide 23 The highest values of protein were in the portico while the inner rooms were clean. Slide 24 Protein was present where Mictlantecuhtli with flesh statues were placed on both sides of the north doorway Slide 25 This can be explained by the reported practice of pouring blood on the sculptures head Slide 26 Protein was also present in the middle of the doorway where eagle-dressed men figures were placed. Also, high concentrations of protein were found in front of the skeletal Mictlantecuhtli suggesting a self sacrifice Slide 27 Iron from hemoglobin would be associated with blood. It could also be a pigment used in wall decorations Slide 28 The pXRF analyzed distribution of iron showed definite activity areas Slide 29 To further confirm the presence of blood deposition, we would like all of the chemical evidence to be consistent. Blood contains albumin protein, iron from hemoglobin, and phosphorous from cell membranes. If the concentration patterns coincide it further corroborates the presence of blood. Slide 30 It was found that the concentration patterns of protein, iron, and phosphorus did correspond in two areas of the room. This is shown on the next slide. Slide 31 Phosphorous IronProtein Slide 32 The results of phosphorous, iron and protein chemistry all indicate the deposition of blood. Slide 33 Iron could also be explained as coming from paint or decorative pigments. In this case we wanted to establish a negative coorelation between iron and copper. Slide 34 Copper is an important ingredient for certain blue and green pigments. Its distribution could indicate decorative features. Copper was plotted to contrast with iron distribution. Slide 35 Copper distribution is concentrated near walls Slide 36 Copper distribution patterns are dissimilar to iron except along one wall. Slide 37 Fatty acids are associated with animal fats and tissue. Such fatty acids could be deposited around braziers where offerings were burnt. Fatty acids can also be found in the tree resins used to make copal. Copal was most frequently burnt as an incense, but could also be used as a paint binder. Fatty acids can also be found in the tree resins used to make copal. Copal was most frequently burnt as an incense, but could also be used as a paint binder. Slide 38 Fatty acid depositions were found near braziers and in front of altars. Slide 39 Gas Chromatography has identified high molecular weight fatty acids that suggests copal resins in front of the main altar. Slide 40 Conclusions Chemical analysis was useful in determining different activity areas of the House of the Eagles. Examples are as follows. Slide 41 Conclusions The location of braziers and ritual fires.The location of braziers and ritual fires. The use of copal at the main altar.The use of copal at the main altar. The pouring of blood on the Mictlantecuhtli with flesh sculpture, but not the other sculptures.The pouring of blood on the Mictlantecuhtli with flesh sculpture, but not the other sculptures. The practice of self sacrifice near the inner door sculptures.The practice of self sacrifice near the inner door sculptures. Slide 42 Thanks To Thermo Fisher Scientific NITON Analyzers.Thermo Fisher Scientific NITON Analyzers. Universidad Nacional Autnoma de Mxico (UNAM)Universidad Nacional Autnoma de Mxico (UNAM) California State University StanislausCalifornia State University Stanislaus