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1.0 Introduction Carbon-based fuel is the energy sources that widely used in industrial and transportation. Petroleum is one of the examples of carbon based fuel use in car, but it is non-renewable source and its supply is become scarce (Chungtai, O & Shannon, D n.d.). As to resolve this problem, scientist had found a new practical alternative to replace the using of carbon-based fuel in car which is hydrogen-oxygen fuel cell. This fuel cell is an electrochemical system with the combination of hydrogen and oxygen to produce a water and electricity (Kruger, P 2006). Therefore, the aim of my research is to determine whether hydrogen-oxygen fuel cell technology is practical alternative to carbon-based fuel cell. 2.0 Chemical concept In fuel cell vehicle, it functions by replacing the electric battery in electrical vehicle by supplying a current for the electric motor to turn the wheel. There are two types of electrodes in fuel cells which are porous anode and porous cathode. From the figure 9-1, these two electrodes sandwiched

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1.0 Introduction

Carbon-based fuel is the energy sources that widely used in industrial and transportation.

Petroleum is one of the examples of carbon based fuel use in car, but it is non-renewable source

and its supply is become scarce (Chungtai, O & Shannon, D n.d.). As to resolve this problem,

scientist had found a new practical alternative to replace the using of carbon-based fuel in car

which is hydrogen-oxygen fuel cell. This fuel cell is an electrochemical system with the

combination of hydrogen and oxygen to produce a water and electricity (Kruger, P 2006).

Therefore, the aim of my research is to determine whether hydrogen-oxygen fuel cell technology

is practical alternative to carbon-based fuel cell.

2.0 Chemical concept

In fuel cell vehicle, it functions by replacing the electric battery in electrical vehicle by

supplying a current for the electric motor to turn the wheel. There are two types of electrodes in

fuel cells which are porous anode and porous cathode. From the figure 9-1, these two electrodes

sandwiched onto a proton exchange membrane (PEM) which permits the transfer of proton at

porous anode by ionizing of hydrogen to the porous cathode and combine with the oxygen at

porous cathode to form water. Below is the equation of reaction occurring in porous anode and

cathode.

Anode : H₂ → 2H⁺ + 2e⁻

Cathode : 2H⁺ + ₂⅟ O₂ + 2e → 2H₂O

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In order to increase the reaction of fuel cell, platinum catalyst is needed for proton

exchange membrane (PEM) in both anode and cathode to speed up the ionization reaction in

both electrode (Kruger, P 2006).

3.0 Advantage and disadvantage of carbon based fuel

Petroleum, a carbon-based fuel is made of hydrocarbon that contain to elements which

are hydrogen and carbon. This hydrocarbon becomes valuable and highest quality in

transportation nowadays because it contains a lot of energy within them. The source of this

energy can be found in the atomic bond of compound which originally a solar energy that

trapped in the prehistoric organism in last million years ago. In order to obtain the energy,

combustion process is used by breaking down an atomic bond to produce the energy in the form

of light and heat (Chungtai, O & Shannon, D n.d.). 2,2,4-Trimethylpentane is one of the

examples of hydrocarbon that found in petroleum and widely use in gasoline. It has a chemical

formula which is C₈H₁₈, and then reacts with oxygen exothermically (Math and Science Activity

Centre 1999).

C₈H₁₈ (aq) + 12.50O₂ (g) → 8CO₂ (g) + 9H₂ (g) + heat

However, combustion of carbon based fuel is dangerous especially harmful to health. The

byproduct of burning this fossil fuel can enter deeply into the lung because of its smaller particle

which is 10 microns in diameter. Thus, the particles that carry harmful substances like heavy

metal and pollutants will enter to the blood stream and effects to the lung. People who are longer

expose to this environment will slow down the transportation of oxygen in lung. So, they might

be affected with a fatal asthma attack and other serious lung problems (Chungtai, O & Shannon,

D n.d.). A part from that, incomplete combustion of carbon based fuel also will lead to the

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emission of harmful gas like carbon monoxide and nitric oxide (Math and Science Activity

Centre 1999). Carbon monoxide also can contribute and enhanced to greenhouse effects.

C₈H₁₈ (aq) + 12.50O₂ (g) + N₂ (g) → 6CO₂ (g) + 2CO (g) +2NO (g) + 9H₂O (g) +heat

4.0 Advantage and disadvantage of hydrogen oxygen fuel cell

Hydrogen fuel cell is a clean burning process of hydrogen fuel. Compare to carbon based

fuel, byproduct of burning hydrogen fuel cell only release water and hydrogen gas. So, it will not

contribute to the environmental problem. In fuel cell, the temperature used for a electrochemical

combination of hydrogen and oxygen occur is low which about 80 ̊C rather than combustion of

gasoline in internal-combustion engine which is around 2400 ̊C. The lower in temperature will

reduce the production of nitrous oxide ( Kruger, P 2006).

N₂ + O₂ → 2NO

A part from that, in vehicle especially a car, using of hydrogen fuel cell is more efficient

compare to internal combustion engine. This because, 60 to 70 percent of the energy in the

hydrogen fuel would be converts into motion but only 20 to 25 percent of energy converted for

internal combustion engine (New Scientist 2003)

There is still having problem in development of hydrogen fuel cell technology such as

hydrogen storage and delivery. Scientist have been tried to find a best way to store hydrogen and

carry this fuel in vehicles. It seems like having a difficulty to fit the fuel tank into a small size

with a higher pressure during running the car. Besides, conflict between a companies and

customers also contribute to problems of fuel cell technology. People do not want to buy a

hydrogen fuel cell car if there is no companies provide a place for them to refill the fuel. This

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also happen to the companies where they do not want to build an infrastructure to deliver a

hydrogen fuel as there is no hydrogen car on the road (New scientist 2003). Other than that,

different kind of vehicle production had been released nowadays. Therefore, scientists have to

provide a specific designed to each types of vehicle to run it. The markets also have a problem to

provide the different types of refueling (Kruger, P 2006).

5.0 Conclusion

In conclusion, each technology development has its own advantages and disadvantages.

However, using of carbon fuel cell has given biggest negative impact compare to hydrogen fuel

cell because it will lead to the environmental and health problems. Besides, its also non

renewable energy source which might reduce for another several years. Therefore, hydrogen

oxygen fuel cell technology is practical alternative to replace the use of carbon based fuel in

vehicle.