Chapter 7 Application of Thermodyanamics to Flow Processes

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Chemical Engineering Chemical Engineering Thermodynamics I Thermodynamics IApplication of Thermodynamics to Flow process Application of Thermodynamics to Flow process2105370 2105370 2105370 2105370Apinan Soottitantawat Apinan [email protected] 7 Chapter 72Energy Balance: Differentiate forms Energy Balance: Differentiate formsS.ApinanEnergy Balance Energy Balance = + + + + + +insys sysSout dtU m dW Q gzuH m gzuH m ) ()2( )2( 2 2 0 ) ( = + + SW d Q d gdz udu dH m Systemmsysu1m1P1A1u2m2P2A2H1H2UsysQWS3Objectives Objectives Use the mass, energy and entropy balance with common Unit Operation as throttling process, compressors, turbine, pump, nozzle, pipe and duct Develop the general relations for compressible flows encountered when gases flow at high speeds. Derive the effects of area changes for one-dimensional isentropic subsonic and supersonic flows. Solve problems of isentropic flow through converging and convergingdiverging nozzles. Solve the problems for compressible fluid flow in adiabatic and isothermal pipeS.Apinan4SOME STEADY SOME STEADY- -FLOW ENGINEERING DEVICES FLOW ENGINEERING DEVICESA modern land-based gas turbine used for electric power production. This is a General Electric LM5000 turbine. It has a length of 6.2 m, it weighs 12.5 tons, and produces 55.2 MW at 3600 rpm with steam injection.Many engineering devices operate essentially under the same conditionsfor long periods of time. The components of a steam power plant (turbines,compressors, heat exchangers, and pumps), for example, operate nonstop formonths before the system is shut down for maintenance. Therefore, these devices can be conveniently analyzed as steady-flow devices.At very high velocities, even small changes in velocities can cause significant changes in the kinetic energy of the fluid.S.Apinan5S.ApinanMass Balance Mass BalanceSystemmsysu1V1P1A1u2V2P2A2dtdmm m sysout in = dtdmA u A u sys= 2 2 2 1 1 1 Continuity equation Continuity equation6S.ApinanEnergy Balance Energy BalanceSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWS = + + + + + +insys sysSout dtU m dW Q gzuH m gzuH m ) ()2( )2( 2 2 11st stlaw Thermodynamics law Thermodynamics 7S.ApinanEntropy Balance Entropy BalanceSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWSdtS m dSTQS m S m sys systotal Gsur) (, 2 2 1 1 = + + 8S.ApinanEntropy balance + Energy balance Entropy balance + Energy balanceSystemmsysu1m1P1A1u2m2P2A2 H1H2UsysQWSV1V2From Entropy Balance From Entropy BalancedtS m dSTQS m S m sys systotal Gsur) (, 2 2 1 1 = + + dtS m dTWTQS m S m S T W sys syssurLSsurtotal G surr LS ) (2 2 1 1 , = + + = dt S m T dW S m S m T Q sys sys surrLS surr ) () ( 1 1 2 2 + = 9S.Apinan = + + + + + +insys sysSout dtU m dW Q gzuH m gzuH m ) ()2( )2( 2 2 From Energy Balance From Energy BalanceFrom Energy and Entropy Balance, at steady state From Energy and Entropy Balance, at steady state0 ) ( )2( )2( 1 1 2 2 2222 2 1211 1 = + + + + + + S LS surr W W S m S m T gzuH m gzuH m For only For only 1 1 input input 1 1 out put out put0 ) ( )2( 2= + A + A A A mWmWS T z guH S LSsurrVdP TdS dH + =And from0 )2( 2= + A A A mWmWz guP V S LSMechanical Energy Balance Mechanical Energy Balance10S.ApinanMechanical Energy Balance Mechanical Energy BalanceSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWSV1V2 = + + + + + + + +insys sysSout dtU m dW Q gzuPV U m gzuPV U m ) ()2( )2( 2 2 o oEnergy Balance Energy Balance11S.ApinanMechanical Energy Balance Mechanical Energy BalanceSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWSV1V2| | = + + + + + + +insys sysS out inout dtU m dW U U m Q gzuPV m gzuPV m ) () ( )2( )2( 2 2 o oQ TdS Q S m S m T W surr LS = ) ( 1 1 2 PdV dU TdS PdV TdS dU + = =| | dtU m dW U m Q V P m z guP V m sys sysS ) ()2( 2= + A + A + A +A+ A o12S.ApinanMechanical Energy Balance Mechanical Energy Balance| | dtU m dW U m Q V P m z guP V m sys sysS ) ()2( 2= + A + A + A +A+ A oFriction Heating Friction Heating Term Term Q PdV dU WLS + =dtU m dW W z guP V m sys sysS LS ) ()2( 2= + A +A+ A of LS gh m W = ||.|

\||.|

\|= =guDLfgDL fuhf242 2 22Re5 . 14269 . 0 ln(Re185 . 2269 . 0 ln 737 . 1 )`((

+ =D Df c cRe16= fRe < Re < 2000 2000Re > Re > 2000 2000f: Fanning friction factor13S.ApinanMechanical Energy Balance Mechanical Energy BalanceFor Incompressible fluid For Incompressible fluidf p h hguzgPguzgP+ + + = + +o o 2 222222111Balance Equation in Balance Equation in Differentiate form: in the Differentiate form: in the steady flow steady flow2105370 2105370 2105370 [email protected] Balance: Differentiate form Entropy Balance: Differentiate formSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWS0, = total Gsur S dTQ ddS m 16S.ApinanME MEBB Balance: Differentiate form Balance: Differentiate formSystemmsysu1m1P1A1u2m2P2A2H1H2UsysQWS0 ) ( = + + + S LS W d W d gdz udu VdP m 17Equation for solving engineering problem Equation for solving engineering problemS.ApinanMass Balance Mass BalancedtdmA u A u sys= 2 2 2 1 1 1 Entropy Balance Entropy BalancedtS m dSTQS m S m sys systotal Gsur) (, 2 2 1 1 = + + Mechanical Energy Balance Mechanical Energy Balance = + + + + + +insys sysS LSout dtU m dW W gzuPV m gzuPV m ) ()2( )2( 2 2 o oEnergy Balance Energy Balance = + + + + + +insys sysSout dtU m dW Q gzuH m gzuH m ) ()2( )2( 2 2 total G surr LS S T W , =There are There are 4 4 mains equation for solving the problems in addition to EOS. mains equation for solving the problems in addition to EOS. 18Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =There are There are 4 4 mains equation for solving the problems in addition to EOS. mains equation for solving the problems in addition to EOS. 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m Flow in various type of Units Flow in various type of Units2105370 2105370 2105370 [email protected] Throattling Process ProcessS.Apinan 21Throttling Process Throttling ProcessS.Apinan Throttling Throttling Orifice 111HuP222HuP1 21 21 2H H u u P P==~22Throttling Process: Orifice Throttling Process: OrificeS.Apinan111HuP222HuP1 21 21 2z z u u P P==

56Compressor: Isentropic Compressor: Isentropic S.ApinanMass Balance Mass Balance2 2 2 1 1 1 A u A u =Entropy Balance Entropy Balance02 2 1 1 = A = S S m S m Energy Balance Energy Balancemin , 1 2 ) ( sW H H m = Because of reversible process, the using equations are 3 equations. VdP WS =min ,Mechanical Energy balance Mechanical Energy balanceCompressor CompressorAdaibatic Adaibatic compression process compression processS.Apinan5758S.Apinan12112 ||.|

\|=||.|

\| VVTT 11212||.|

\|=||.|

\|PPTT ||.|

\|=||.|

\|2112VVPPVPCC= From isentropic Ideal gas process From isentropic Ideal gas process 2 2 1 1 V P V P =o o2 2 1 1 V P V P =# # Polytropic Polytropic process processEntropy Balance Entropy Balance0 = dSCompressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluidQExample Example 77..9 9: Compressor : CompressorIf methane (assumed to be an ideal gas) is compressed adiabatically from 20 C and 140 kPa to 560 kPa, estimated the requirement and the discharge temperature of the methane. The compressor efficiency is 0.75.S.Apinan592 6 3 ,10 64 . 2 10 081 . 9 702 . 1 T TRC methane P + =dPPRdTTCdS P =dT C dH P=Example 7.9: Compressor Example 7.9: CompressorS.Apinan60) ( 1 2 min , 1 2 T T C W H H P s = = 11212||.|

\|=||.|

\|PPTT) 1 ( 1121 min , ||.|

\|= PPT C W P sFor CPis constant Example Example 77..9 9: Compressor : CompressorS.Apinan61Assume CPof methane constant at 38.5 J mol-1 K-1 =1.271 -mol J 3866 ) 1 ( 1121 min , = ||.|

\|= PPT C W P sHHWW isentropicsisentropic sAA= = ,q1mol J 7 . 5154 =SWK 42 . 393, 2 =isenTK 89 . 4262 = TProblem: Compressor Problem: CompressorS.Apinan62) ( 1 2 min , 1 2 T T C W H H P s = = 11212||.|

\|=||.|

\|PPTT) 1 ( 1121 min , ||.|

\|= PPT C W P sProvevpCCk = = R C C v p + = : Gas IdealExample Example 77..8 8: Compressor : CompressorSaturated vapor steam at 100 kPa (tsat = 99.63 C) is compressed adiabatically to 300 kPa. If the compressor efficiency is 0.75 what is the work required and what are the properties of the discharge stream?S.Apinan6364MINIMIZING THE COMPRESSOR WORK MINIMIZING THE COMPRESSOR WORKObviously one way of minimizing the compressor work is to approximatean internally reversible process as much as possible by minimizing theirreversibilities such as friction, turbulence, and nonquasi-equilibriumcompression. The extent to which this can be accomplished is limited byeconomic considerations. A second (and more practical) way ofreducing the compressor work is to keep the specific volume of the gasas small as possible during the compression process. This is done bymaintaining the temperature of the gas as low as possible duringcompression since the specific volume of a gas is proportional totemperature. Therefore, reducing the work input to a compressor requiresthat the gas be cooled as it is compressed.One common way of cooling the gas during compression is to use cooling jackets around the casing of the compressors.VdP WS =min ,65MINIMIZING THE COMPRESSOR WORK (ideal gas) MINIMIZING THE COMPRESSOR WORK (ideal gas)Isentropic (Pvk= constant) No cooling:Polytropic (Pvn= constant): Some coolingIsothermal (Pv = constant): Maximum cooling P-v diagrams of isentropic, polytropic, and isothermal compression processes between the same pressure limits. the area to the left of the process curve is the integral of v dP.When kinetic and potential energies are negligibleThe adiabatic compression (Pvk= constant) requires the maximum work and the isothermal compression (T = constant) requires the minimum. Why?66Multistage Compression with Multistage Compression with Intercooling IntercoolingIt is clear from these arguments that cooling a gas as it is compressed isdesirable since this reduces the required work input to the compressor. However,often it is not possible to have adequate cooling through the casing of thecompressor, and it becomes necessary to use other techniques to achieveeffective cooling. One such technique is multistage compression withintercooling, where the gas is compressed in stages and cooled between eachstage by passing it through a heat exchanger called an intercooler.67Multistage Compression with Multistage Compression with Intercooling IntercoolingThe gas is compressed in stages and cooled between each stage by passing it through a heat exchanger called an intercooler.P-v and T-s diagrams for a two-stage steady-flow compression process.68Multistage Compression with Multistage Compression with Intercooling IntercoolingTo minimize compression work during two-stage compression, the pressure ratio across each stage of the compressor must be the same. When this condition is satisfied, the compression work at each stage becomes identical, that is, wcomp I,in= wcomp II,in.The only variable in this equation is Px. The Px value that minimizes the total work is determined by differentiating this expression with respect to Px and setting the resulting expression equal to zero. It yields69Staged compression Staged compressionIn the case of centrifugal compressors, commercial designs currently do notexceed a compression ratio of more than a 3.5 to 10 in any one stage (for atypical gas). Since compression generates heat, the compressed gas is to becooled between stages making the compression less adiabatic and moreisothermal. The inter-stage coolers typically result in some partial condensationthat is removed in vapor-liquid separators.In the case of small reciprocating compressors, the compressor flywheel maydrive a cooling fan that directs ambient air across the intercooler of a two or morestage compressor.Because rotary screw compressors can make use of cooling lubricant to removethe heat of compression, they very often exceed a 9 to 10 compression ratio. Forinstance, in a typical diving compressor the air is compressed in three stages. Ifeach stage has a compression ratio of 7 to 1, the compressor can output 343times atmospheric pressure (7 x 7 x 7 = 343 atmospheres). (343 atm/34.8 MPa;5.04 ksi) NPPr / 1stage first in,stage last out,(((

=70Example: Multistage Compression Example: Multistage Compression71Example: Multistage Compression Example: Multistage Compression72Example: Multistage Compression Example: Multistage Compression73Example: Multistage Compression Example: Multistage Compression74Turbines and Compressors Turbines and CompressorsTurbine drives the electric generator In steam, gas, or hydroelectric power plants.As the fluid passes through the turbine, work is done against the blades, which are attached to the shaft. As a result, the shaft rotates, and the turbine produces work.Compressors, as well as pumps and fans, are devices used to increase the pressure of a fluid. Work is supplied to these devices from an external source through a rotating shaft.A fan increases the pressure of a gas slightlyand is mainly used to mobilize a gas. A compressor is capable of compressing the gas to very high pressures. Pumps work very much like compressors except that they handle liquids instead of gases.Energy balance for the compressor in this figure:S.Apinan75Example: Power Generation by a Steam Example: Power Generation by a Steam Turbine TurbineS.ApinanThe power output of an adiabatic steam turbine is 5 MW, and the inlet andthe exit conditions of the steam are as indicated in Figure.(a) Compare the magnitudes of h, ke, and pe.(b) Determine the work done per unit mass of the steam flowing throughthe turbine.(c) Calculate the mass flow rate of the steam.76Solution : Solution : Power Generation by a Steam Turbine Power Generation by a Steam TurbineS.Apinan77Solution : Solution : Power Generation by a Steam Turbine Power Generation by a Steam TurbineS.Apinan78Solution : Solution : Power Generation by a Steam Turbine Power Generation by a Steam TurbineS.Apinan79Pump PumpS.ApinanQHHWW isentropicsisentropic sAA= = ,q1 2 P P >80Pump: Isentropic Pump: Isentropic S.ApinanMass Balance Mass Balance2 2 2 1 1 1 A u A u =Entropy Balance Entropy Balance02 2 1 1 = A = S S m S m Energy Balance Energy Balancemin , 1 2 sW H H = Because of reversible process, the using equations are 3 equations. VdP WS =min ,Mechanical Energy balance Mechanical Energy balance81Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =There are 4 mains equation for solving the problems in addition to EOS. There are 4 mains equation for solving the problems in addition to EOS. 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m 82Pump PumpS.ApinanQHHWW isentropicsisentropic sAA= = ,q) ( 1 2 P P V Hisentropic = AdP T V dT C dH P ) 1 ( | + =VdP dTTCdS P| =83Isentropic Efficiencies of Compressors and Pumps Isentropic Efficiencies of Compressors and PumpsThe h-s diagram of the actual and isentropic processes of an adiabatic compressor.Compressors are sometimes intentionally cooled to minimize the work input.Isothermal efficiencyFor a pumpWhen kinetic and potential energies are negligibleCan you use isentropic efficiency for a non-adiabatic compressor? Can you use isothermal efficiency for an adiabatic compressor?84Example Example 77..10 10: Pump : PumpS.ApinanWater at 45 C and 10 kPa enters an adiabatic pump and is discharged at a pressure of 8600 kPa. Assume pump efficiency to be 0.75. Calculate the work of pump, the temperature change of water and the entropy change of water. Properties saturated water at 45 C: V = 1010 cm3kg-1, | = 425 x10-6K-1, Cp = 4.178 kJ kg-1K-1)85Example : Pump VS Compressor Example : Pump VS CompressorS.Apinan86Example : Pump VS Compressor Example : Pump VS CompressorS.Apinan87Example : Pump VS Compressor Example : Pump VS CompressorS.Apinan88Example : Pump VS Compressor Example : Pump VS CompressorS.Apinan89Mixing chambers Mixing chambersIn engineering applications, the section where the mixing process takes place is commonly referred to as a mixing chamber.The T-elbow of an ordinary shower serves as the mixing chamber for the hot- and the cold-water streams.Energy balance for the adiabatic mixing chamber in the figure is:10C60C43C140 kPaS.Apinan90Heat exchangers Heat exchangersHeat exchangers are devices where two moving fluid streams exchange heat without mixing. Heat exchangers are widely used in various industries, and they come in various designs.A heat exchanger can be as simple as two concentric pipes.Mass and energy balances for the adiabatic heat exchanger in the figure is:The heat transfer associated with a heat exchanger may be zero or nonzero depending on how the control volume is selected.S.Apinan91Pipe and duct Pipe and duct flow flowThe transport of liquids or gases in pipes and ducts is of great importance in many engineering applications. Flow through a pipe or a duct usually satisfies the steady-flow conditions.Heat losses from a hot fluid flowing through an uninsulatedpipe or duct to the cooler environment may be very significant.Pipe or duct flow may involve more than one form of work at the same time.Energy balance for the pipe flow shown in the figure isS.ApinanMore focus in the More focus in the Compressible fluid flow: Compressible fluid flow: Steady flow Steady flow2105370 2105370 2105370 [email protected] of compressible flow Processes of compressible flowS.ApinanThere are 3 main processes of compressible flowa. Isentropic flow through nozzlesb. Adiabatic friction flowc. Isothermal friction flowUsing 4 equations to solve the problemUsing 4 equations to solve the problemUsing 4 equations to solve the problem94Compressible fluids flow: Compressible fluids flow:S.Apinan-What is the relation between pressure and distance ?-What is the velocity different? -What is the density/ specific volume change with distance? 222HuP1A 2A0 = Q111HuP95Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =There are There are 4 4 mains equation for solving the problems in addition to EOS. mains equation for solving the problems in addition to EOS. 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m Compressible fluid flow: Compressible fluid flow: adiabatic steady flow adiabatic steady flow2105370 2105370 2105370 [email protected] fluids flow: adiabatic Compressible fluids flow: adiabaticS.Apinan222HuP1A 2A0 = Q111HuPMass Balance Mass BalanceEnergy Balance Energy Balance 0 = AdAuduVdVudu dH =2 1 z z =98S.ApinanWhy sonic velocity ?Why this value relate to the gas flow?How it relate to the gas flow ????Compressible fluids flow Compressible fluids flowIn incompressible flow, an increase in velocity is associated with adecrease in the cross-sectional area of the ductHowever, because of the compressibility, the flow behavior ofcompressible fluid is different from incompressible one. It could beexplained with the sonic velocity. Therefore, in the flow of compressiblefluid (mainly in gas), the velocity of fluids will be normally reportedthem comparing to the sonic velocity (mach number).99S.ApinanFor the compressible fluid, let consider the specific volume of fluid in the function of entropy and pressure: V=V(S,P)dPPVdSSVdVS P |.|

\|cc+|.|

\|cc=Therefore Therefore????????Compressible fluids flow Compressible fluids flow100S.ApinanP P P STTVSV|.|

\|cc|.|

\|cc=|.|

\|ccFrom FromPTVV ((

cc= 1|TCTS PP =((

ccAND ANDP P CT VSV |=|.|

\|ccTherefore Therefore(Volume expansivity)Compressible fluids flow Compressible fluids flow101S.ApinanSVPV c |.|

\|cc = 2 2From physics: the speed of sound, From physics: the speed of sound, cc, in a fluid could be calculated from , in a fluid could be calculated from 22cVPVS =|.|

\|ccTherefore ThereforeCompressible fluids flow Compressible fluids flow102S.ApinanConsider the specific volume of fluid in the function of entropy and pressure: V=V(S,P)From FromdPcVdSCT VdVP 22 = |Therefore, Therefore, dPcVdSCTVdVP 2 = |Compressible fluids flow Compressible fluids flow103Compressible fluids flow: adiabatic Compressible fluids flow: adiabaticS.Apinan222HuP1A 2A0 = Q111HuPMass Balance Mass BalanceEnergy Balance Energy Balance0 = AdAuduVdVudu dH =2 1 z z =Compressible fluid Compressible fluid dPcVdSCTVdVP 2 = |104Compressible fluids flow: adiabatic Compressible fluids flow: adiabaticS.Apinan222HuP1A 2A0 = Q111HuPThe system is the adiabatic, The system is the adiabatic, there are the loss (irreversibility in the processSG,Total=02 1 z z =The entropy balance will not be used at this step. The entropy balance will not be used at this step. However, the fundamental relation will be used. However, the fundamental relation will be used. VdP TdS dH + =105S.ApinanThere are 4 equations with 6 differentials (dH, du, dV, dA, dSand dP). If we treats dS and dA as dependent. From Fromand and dPcVdSCTVdVP 2 = |0 = AdAuduVdVudu dH =VdP TdS dH + =Compressible fluids flow: adiabatic Compressible fluids flow: adiabatic Mass BalanceEnergy BalanceCompressible fluidFundamental Relation106S.ApinanTherefore Therefore VdP TdS udu + = 02 = AdAududPcVdSCTP|02 2 2 = + + AdAdPuVdSuTdPcVdSCTP|0 ) ( ) ( 2 2 2 = + +AdAdPcVuVdSCTuTP|0 ) 1 ( ) 1 ( 222 2= + + dAAuVdPcuTdSCuP|Compressible fluids flow: adiabatic Compressible fluids flow: adiabaticudu dH =VdP TdS dH + =107S.ApinanFrom From0 ) 1 ( ) 1 ( 222 2= + + dAAuVdPcuTdSCuP|When WhencuM =Mach Number Mach NumberTherefore Therefore0 ) 1 ( ) 1 ( 222= + + dAAuVdP M TdSCuP|Compressible fluids flow: adiabatic Compressible fluids flow: adiabatic108Compressible fluids flow: adiabatic Compressible fluids flow: adiabaticS.ApinanFrom Fromand andTherefore Therefore0 ) 1 ( ) 1 ( 222= + + dAAuVdP M TdSCuP|VdP TdS udu + = 0 ) )( 1 ( ) 1 ( 222= + + dAAuTdS udu M TdSCuP|0) 1 ( 1 22222= ||||.|

\|+dAM A uudu TdSMCuMP|109Compressible fluids flow: adiabatic Compressible fluids flow: adiabaticS.Apinan0) 1 ( 1 22222= ||||.|

\|+dxdAM A udxduudxdSTMCuMP|0 ) 1 ( ) 1 ( 222= + +dxdAAudxdPV MdxdSTCuP|Therefore, divide by Therefore, divide by dx dx0 > dx dSFor spontaneous process:(with irreversibility)110Compressible fluids flow: Pipe flow Compressible fluids flow: Pipe flowS.ApinandxdSMCuMTdxduu P||||.|

\|+= 2221|dxdSMCuVTdxdP P||||.|

\|+ = 2211 |For flow in pipe: For flow in pipe: dA dA//dx dx = = 0 00 > dx dSFor spontaneous process (with irreversibility):Subsonic flow: M1P2< P1u2> u1P2> P1u2< u1However, for the supersonic flow is unstable in constant area pipe, the compression shock occurs results in increase in pressure and decrease in velocity to a subsonic value111SHOCK WAVES AND EXPANSION WAVES SHOCK WAVES AND EXPANSION WAVESFor some back pressure values, abrupt changes in fluid properties occur in a very thin section of a pipe under supersonic flow conditions, creating a shock wave. .Normal ShocksNormal shock waves: The shock waves that occur in a plane normal to the direction of flow. The flow process through the shock wave is highly irreversible.Schlieren image of a normal shock in a Laval nozzle. The Mach number in the nozzle just upstream (to the left) of the shock wave is about 1.3. Boundary layers distort the shape of the normal shock near the walls and lead to flow separation beneath the shock.S.Apinan112Example Example 77..1 1S.ApinanConsider the steady state, adiabatic, irreversible flow of an incompressible fluid in a horizontal pipe of constant cross-sectional area. Show thata. The velocity is constantb. The temperature increases in the direction of flowc. The pressure decreases in the direction of flow 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m Compressible fluid flow: Compressible fluid flow: Isentropic steady flow Isentropic steady flowcovergent covergent/divergent pipe /divergent pipe2105370 2105370 2105370 [email protected] NozzleS.Apinan111HuP222HuP1A 2ANozzle Process Nozzle Process--Change internal energy to kinetic energy Change internal energy to kinetic energy--usually operated usually operated isentropically isentropically1 21 21 21 2S S z z u u P P==> 1) can be accomplished only by attaching a diverging flow section to the subsonic nozzle at the throat (a convergingdiverging nozzle), which is standard equipment in supersonic aircraft and rocket propulsion.Convergingdiverging nozzles are commonly used in rocket engines to provide high thrust.S.Apinanu = cM=1 (Asterisk condition)123S.Apinan124Compressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluidS.ApinanMass Balance Mass Balance 0 = W 0 = Q 0 = AZ 0 = AS 222HuP111HuP0 = AdAuduVdVudu dH =Energy Balance Energy BalanceEntropy Balance Entropy Balance0 = dSMechanical Energy Balance Mechanical Energy Balanceudu VdP = VdP TdS dH + =We can use the fundamental relation instead of MEB125S.Apinan12112 ||.|

\|=||.|

\| VVTT 11212||.|

\|=||.|

\|PPTT ||.|

\|=||.|

\|2112VVPPVPCC= From isentropic Ideal gas process From isentropic Ideal gas process 2 2 1 1 V P V P =o o2 2 1 1 V P V P =# # Polytropic Polytropic process processEntropy Balance Entropy Balance0 = dSCompressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluid126S.ApinanCompressible fluid : Compressible fluid : They will be used when the mach number is used to They will be used when the mach number is used to present the velocity of fluid present the velocity of fluid0 = W 0 = Q 0 = AZ 0 = AS 222HuP111HuPdPcVVdV2 = cuM =Ideal gas and isentropic Ideal gas and isentropicSVPV c |.|

\|cc = 2 22 22V P c =VPVPS =|.|

\|cc 2 2 1 1 V P V P =Compressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluid22RT c =127For an ideal gasMach numberSpeed of soundThe Mach number can be different at different temperatures even if the velocity is the same.The speed of sound changes with temperature and varies with the fluid.Ma = 1 Sonic flowMa < 1 Subsonic flowMa > 1 Supersonic flowMa >> 1 Hypersonic flowMa ~ 1 Transonic flowS.ApinanTVPc |.|

\|cc = 2VRTP =PV RT c = =2128S.Apinan} = 2122122PPVdP u uP1 u1V1P2 u2V2} = 211 1112122 2PPdPP V Pu u ( )(((

||.|

\|= 112 1 12122 112PP V Pu uFrom Mechanical Energy Balance From Mechanical Energy BalanceCompressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluidudu VdP =129S.ApinanP1 u1V1P2 u2V2( )(((

||.|

\|= 112 1 12122 112PP V Pu uWhen u When u22reaches the speed of sound reaches the speed of soundSVPV c u |.|

\|cc = = 2 2 22 2 222 V P u =VPVPS =|.|

\|ccCompressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluid130S.ApinanP1 u1V1P2 u2V2) 1 (1212 ||.|

\|+= PP2 22 22 2 1 1 , 0 V P c u M u = = = =Compressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluid131Example: Isentropic of compressible fluid flow Example: Isentropic of compressible fluid flow S.ApinanAir enters a convergen-divergent nozzle at a temperature of 555.6 K and a pressure of 20 atm. The throat area is one-half that of the discharge of divergent section.a. Asterisk condition at the throat b. At M=0.8 in the throat what is pressure, temperature, velocity, specific volume ?Assume: Isentropic flow with air as the ideal gas with Mw = 29 g/gmol and = 1.420 atm555.6 K132Example: Isentropic of compressible fluid flow Example: Isentropic of compressible fluid flow S.Apinana. Asterisk condition at the throat 20 atm555.6 Ku1=0 m/sP2?? atmT2?? KM = 1) 1 (1212 ||.|

\|+= PP 2 2 1 1 V P V P =2 222 V P u =133Example: Isentropic of compressible fluid flow Example: Isentropic of compressible fluid flow S.Apinanb. At M=0.8 in the throat what is pressure, temperature, velocity, specific volume ?20 atm555.6 Ku1=0 m/sP2?? atmT2?? KM = 0.8Determine u Determine u22SVPV c |.|

\|cc = 2 22 22V P c =c u M / = Mc u =2From From134Example: Isentropic of compressible fluid flow Example: Isentropic of compressible fluid flow S.ApinanFrom From01 = uDetermine: P Determine: P22Then, Then, ( )(((

||.|

\|= 112 1 12122 112PP V Pu u) 1 (2122 ) 1 ( 2 ||.|

\|+ = M PP 2 2 1 1 V P V P =2 22V P c = Mc u =2How to derive this equation !!135Example Example 77. .3 3: Isentropic of compressible fluid : Isentropic of compressible fluid flow flow S.ApinanConsider the nozzle with the steam behave as an ideal gas flow calculatea. The critical pressure ratio and the velocity at the throatb. The discharge pressure for M = 2 at the nozzle exhaust700 kPa300 Cu1= 30 m/sGiven: = 1.4, Mw = 18P2kPaT2 Cu2= ?? m/sM =1 P3kPaT3 Cu3= ?? m/sM = 2136S.Apinan12112 ||.|

\|=||.|

\| VVTT 11212||.|

\|=||.|

\|PPTT ||.|

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\|2112VVPPVPCC= From isentropic Ideal gas process From isentropic Ideal gas process 2 2 1 1 V P V P =o o2 2 1 1 V P V P =# # Polytropic Polytropic process processEntropy Balance Entropy Balance0 = dSCompressible fluids flow: Isentropic flow of the Compressible fluids flow: Isentropic flow of the ideal gas fluid ideal gas fluid137Example Example 77. .3 3: Isentropic of compressible fluid : Isentropic of compressible fluid flow flow S.Apinan700 kPa300 Cu1= 30 m/sP2kPaT2 Cu2= ?? m/sM =1 P3kPaT3 Cu3= ?? m/sM = 212 ( )(((

||.|

\|= 112 1 12122 112PP V Pu uRT PV =) 1 (1212 ||.|

\|+= PP138Example Example 77. .3 3: Isentropic of compressible fluid : Isentropic of compressible fluid flow flow S.Apinan23 ( )(((

||.|

\|= 112 1 12122 112PP V Pu uRT PV =2 22V P c =2 22 2 2 22 V P M c M u = =Compressible fluid flow: Compressible fluid flow: Isothermal steady flow Isothermal steady flow2105370 2105370 2105370 [email protected] fluids flow: Isothermal Compressible fluids flow: IsothermalS.ApinanTemperature constant along the pipe Temperature constant along the pipeAs the similar way, using the balance equation to solve the problem. As the similar way, using the balance equation to solve the problem. Using the Re and moody chart to calculate the lost work. Using the Re and moody chart to calculate the lost work. 141Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =There are There are 5 5 mains equation for solving the problems in addition to EOS. mains equation for solving the problems in addition to EOS. 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m Compressible fluid Compressible fluiddPcVdSCTVdVP 2 = |They will be used when the velocity is in the form of mach number142Problem HW: Isothermal friction flow Problem HW: Isothermal friction flowS.ApinanAir at 1.7 atm gauge and 15 C enter a horizontal 75 mm steel pipe that is 70 m. long. The flow rate of the entering air q is 0.265 m3/s. Assuming isothermal flow, what is the pressure at the discharge end of the pipe and rate of heat transfer?Properties We take the properties of air to be = 1.4, Cp= 1.005 kJ/kg K, and R = 0.287 kJ/kg K. =0.0174 cP, Assume as the ideal gas1.7 atm15 Cu1P2?? atmT215 Cu2 = ??143Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =0 = AdAuduVdVmQ dudu dH= +0, = total GsurS dTQ ddS m 0 = + +mW dudu VdP LS2211VuVu= 0 ) ( = + + + S LS W d W d gdz udu VdP m 144Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.Apinanf LS gh m W =||.|

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\|= =guDLfgDL fuhf242 2 2|.|

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\|= =DdL uf gdhmW dfLS24 2Therefore02 2= + + dLDfuudu VdPFrom mass balanceconstant2211= = = =VuAmGVA uVA u 145Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.Apinanso02 2 2= + + dLDV fGudu VdPAnd From Ideal gas lawconstant2211= = = =VuAmGVA uVA u 02 22 = + + dLDfGVuduVdP02 22 2 = + + dLDfGG uududPRTP02 22= + + dLDfGuduG dPRTP146Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.Apinan02 22= + + dLDfGuduG dPRTP02) ln( ) (21 2122 2122 = + + D L fGuuG P PRTAnd From Ideal gas law and mass balance2211VuVu= 2 2 1 1 V P V P =and211 2PPu u =0044 . 0 , 00061 . 0 / , 10 8.56 Re S, kg/m 5 . 198 , cP 0174105 . 0 5 2= = = = = f D k G Re is constant ???? Prove !!147Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.Apinan||.|

\|+ = ) ln(22212 21 2PPDfLRT G P P0044 . 0 , 00061 . 0 / , 10 8.56 Re S, kg/m 5 . 198 , cP 0174105 . 0 5 2= = = = = f D k G K kJ/kg. 0.287 R K, 288 T m, 70 , kg/m.s 273578 kPa 578 . 273 atm 7 . 2 21 = = = = = = L P||.|

\|+ = )273578ln( 213 . 8 5 . 198 288 287 2 27357822 22PPatm 26 . 12 = P148Example: Compressible flow, Rayleigh flow Example: Compressible flow, Rayleigh flowS.ApinanAir enters a rectangular duct at T1 = 300 K, P1 = 420 kPa, and Ma1 = 2. Heat is transferred to the air in the amount of 55 kJ/kg as it flows through the duct. Disregarding frictional losses, determine the temperature and Mach numberat the duct exit. Assumption: associated with Rayleigh flow (i.e., steady one-dimensional flow of an ideal gas with constant properties through a constant cross-sectional area duct with negligible frictional effects) , Properties We take the properties of air to be = 1.4, Cp= 1.005 kJ/kg K, and R = 0.287 kJ/kg K. 149Equation for solving engineering problem: Steady Equation for solving engineering problem: Steady flow flowS.ApinanMass Balance Mass BalanceEntropy Balance Entropy BalanceMechanical Energy Balance Mechanical Energy BalanceEnergy Balance Energy Balancetotal G surr LS S d T W d , =There are 5 mains equation for solving the problems in addition to EOS. There are 5 mains equation for solving the problems in addition to EOS. 0 = AdAuduVdV0 ) ( = + + SW d Q d gdz udu dH m 0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m Compressible fluid Compressible fluiddPcVdSCTVdVP 2 = |They will be used when the velocity is in the form of mach number150Solution : Compressible flow, Rayleigh flow Solution : Compressible flow, Rayleigh flowS.Apinanm/s 4 . 694 u m/s 2 . 347 12= = = = = Mc c RT PV c FromP1 = 420 kPaT1 = 300 KMa1 = 2T2, Ma2q = 55 kJ/kgEnergy balance21 122 2 u H u HmQq + = =Mass balance22112 2 2 1 1 1 0VuVuA u A u = = Compressible fluid udu dHmQ d+ =0 = AdAuduVdV151Solution : Compressible flow, Rayleigh flow Solution : Compressible flow, Rayleigh flowS.ApinanEntropy balance:) ( 1 2 S S mTQsur = EOS:22 211 1TV PTV P=Mechanical Energy Balance0, = total GsurS dTQ ddS m 0 ) ( = + + + S LS W d W d gdz udu VdP m udu VdP =152HW: Isothermal friction flow HW: Isothermal friction flowS.ApinanAir at 25 C enter a section of 2-in. Schedule 40 steel pipe at a gauge pressure of 310 kN/m2and flow rate of 1200 kg/h. Assuming isothermal flow, what is the pressure drop in 60 m of pipe ?Compressible fluid flow: Compressible fluid flow: adiabatic steady flow adiabatic steady flow2105370 2105370 2105370 [email protected] fluids flow: Compressible fluids flow: Adaibatic AdaibaticS.ApinanTemperature not constant along the pipe Temperature not constant along the pipeAs the similar way, using the balance equation to solve the problem. As the similar way, using the balance equation to solve the problem. Using the Re and moody chart to calculate the lost work. Using the Re and moody chart to calculate the lost work. Because the temperature is not constant, the Re numbers is also not Because the temperature is not constant, the Re numbers is also not constant. However, it is not different so much along the pipe. The average constant. However, it is not different so much along the pipe. The average Re could be used. Furthermore, Re could be used. Furthermore, for M< for M dx dSFor spontaneous process (with irreversibility):Subsonic flow: M1P2< P1u2> u1P2> P1u2< u1However, for the supersonic flow is unstable in constant area pipe, the compression shock occurs results in increase in pressure and decrease in velocity to a subsonic value157S.ApinanReference Reference1. Thermodynamics an Engineering Approach, Y. A. engel and M. A. Boles, 6thed., 20082. Introduction to Chemical Engineering Thermodynamics, 6th Edition, J. M. Smith, H. C. Van Ness and M. M. Abbott, McGraw-Hill, 20013. , , .. 25384. Chemical Engineering Thermodynamics I: .. 5. Chemical Engineering Thermodynamics I: .. 6. Unit Operations of Chemical Engineering, 7thedition, W.L. McCabe, J.C. Smith and P. Harriott158Stagnation Properties Stagnation PropertiesStagnation (or total) enthalpyStatic enthalpy: the ordinary enthalpy hSteady flow of a fluid through an adiabatic duct.Energy balance (with no heat or work interaction, no change in potential energy) S.ApinanDuring a stagnation process, the kinetic energy of a fluid is converted to enthalpy, which results in an increase in the fluid temperature and pressure. The properties of a fluid at the stagnation state are called stagnation properties (stagnation temperature, stagnation pressure, stagnation density, etc.). The stagnation state is indicated by the subscript 0.159The actual state, actual stagnation state, and isentropic stagnation state of a fluid on an h-s diagram.Isentropic stagnation state: When the stagnation process is reversible as well as adiabatic (i.e., isentropic).The stagnation processes are often approximated to be isentropic, and the isentropic stagnation properties are simply referred to as stagnation properties. When the fluid is approximated as an ideal gas with constant specific heatsT0is called the stagnation (or total) temperature, and it represents the temperature an ideal gas attains when it is brought to rest adiabatically.The term V2/2cpcorresponds to the temperature rise during such a process and is called the dynamic temperature.S.Apinan160DUCT FLOW WITH HEAT TRANSFER AND DUCT FLOW WITH HEAT TRANSFER AND NEGLIGIBLE FRICTION (RAYLEIGH FLOW) NEGLIGIBLE FRICTION (RAYLEIGH FLOW)So far we have limited our consideration mostly to isentropic flow (no heat transfer and no irreversibilities such as friction). Many compressible flow problems encountered in practice involve chemical reactions such as combustion, nuclear reactions, evaporation, and condensation as well as heat gain or heat loss through the duct wall. Such problems are difficult to analyze exactly since they may involve significant changes in chemical composition during flow, and the conversion of latent, chemical, and nuclear energies to thermal energy. A simplified model is Rayleigh flow.Rayleigh flows: Steady one-dimensional flow of an ideal gas with constant specific heats through a constant-area duct with heat transfer, but with negligible friction. S.Apinan161Quiz III: Compressible fluid flow Quiz III: Compressible fluid flowS.ApinanHelium expands in a nozzle from 1 MPa, 500 K, and negligible velocity to 0.1 MPa. Calculate the throat and exit areas for a mass flow rate of 0.25 kg/s, assuming the nozzle is isentropic. Assume: He as the ideal gas with the properties of R = 2.0769 kJ/kg.K, Cp = 5.1926 kJ/kg.K, = 1.667. 162The effects of back pressure on the flow through a convergingdiverging nozzle.When Pb= P0(case A), there will be no flow through the nozzle. 1. When P0> Pb> PC, the flow remains subsonic throughout the nozzle, and the mass flow is less than that for choked flow. The fluid velocity increases in the first (converging) section and reaches a maximum at the throat (but M < 1). However, most of the gain in velocity is lost in the second (diverging) section of the nozzle, which acts as a diffuser. The pressure decreases in the converging section, reaches a minimum at the throat, and increases at the expense of velocity in the diverging section.Converging Converging Diverging Nozzles Diverging NozzlesS.ApinanPPbb= Exit pressure = Exit pressure1632. When Pb= PC, the throat pressure becomes P* and the fluid achieves sonic velocity at the throat. But the diverging section of the nozzle still acts as a diffuser, slowing the fluid to subsonic velocities. The mass flow rate that was increasing with decreasing Pbalso reaches its maximum value.3. When PC> Pb> PE, the fluid that achieved a sonic velocity at the throat continues accelerating to supersonic velocities in the diverging section as the pressure decreases. This acceleration comes to a sudden stop, however, as a normal shock develops at a section between the throat and the exit plane, which causes a sudden drop in velocity to subsonic levels and a sudden increase in pressure. The fluid then continues to decelerate further in the remaining part of the convergingdiverging nozzle. Converging Converging Diverging Nozzles Diverging NozzlesS.Apinan1644. When PE> Pb > 0, the flow in the diverging section is supersonic, and the fluid expands to PFat the nozzle exit with no normal shock forming within the nozzle. Thus, the flow through the nozzle can be approximated as isentropic. When Pb= PF, no shocks occur within or outside the nozzle. When Pb< PF, irreversible mixing and expansion waves occur downstream of the exit plane of the nozzle. When Pb> PF, however, the pressure of the fluid increases from PFto Pbirreversibly in the wake of the nozzle exit, creating what are called oblique shocks.Converging Converging Diverging Nozzles Diverging NozzlesS.Apinan165SHOCK WAVES AND EXPANSION WAVES SHOCK WAVES AND EXPANSION WAVESFor some back pressure values, abrupt changes in fluid properties occur in a very thin section of a convergingdiverging nozzle under supersonic flow conditions, creating a shock wave. We study the conditions under which shock waves develop and how they affect the flow.Normal ShocksNormal shock waves: The shock waves that occur in a plane normal to the direction of flow. The flow process through the shock wave is highly irreversible.Schlieren image of a normal shock in a Laval nozzle. The Mach number in the nozzle just upstream (to the left) of the shock wave is about 1.3. Boundary layers distort the shape of the normal shock near the walls and lead to flow separation beneath the shock.166Compressible fluids flow: Feature Compressible fluids flow: FeatureCompressible flows can have features that do not occur in low-speed flows. For example, shock waves and expansion waves can occur in supersonic flows. Another important phenomenon that can occur due to compressibility is choking, where the mass flow rate through a duct system may be limited as a result of the Mach number being equal to 1 at some point in the flow. Another effect of compressibility is associated with the acceleration of a gas flow through a duct. In incompressible flow, an increase in velocity is associated with a decrease in the cross-sectional area of the duct, this in fact being true as long as M < 1. However, when M > 1, that is, when the flow is supersonic, the opposite is true; that is, an increase in the velocity is associated with an increase in the cross-sectional area. Therefore, in order to accelerate a gas flow from subsonic to supersonic velocities in a duct, it is necessary first to decrease the area and then, once the Mach number has reached 1, to increase the area, that is, to use a so-called convergent-divergent nozzle. An example is the nozzle fitted to a rocket engine. S.Apinan167Compressible fluids flow: Choke flow Compressible fluids flow: Choke flowFluid flow through a restricted area whose rate reaches a maximum when the fluid velocity reaches the sonic velocity at some point along the flow path. The phenomenon of choking exists only in compressible flow and can occur in several flow situationsChoked flow can occur through a convergent flow area or nozzle attached to a hugereservoir. Flow exits the reservoir through the nozzle if the back pressure is less than thereservoir pressure. When the back pressure is decreased slightly below the reservoirpressure, a signal from beyond the nozzle exit is transmitted at sonic speed to thereservoir. The reservoir responds by sending fluid through the nozzle. Further, themaximum velocity of the fluid exists at the nozzle throat where the area is smallest.When the back pressure is further decreased, fluid exits the reservoir more rapidly.Eventually, however, the velocity at the throat reaches the sonic velocity. Then the fluidvelocity at the throat is sonic, and the velocity of the signal is also sonic. Therefore, furtherdecreases in back pressure are not sensed by the reservoir, and correspondingly will notinduce any greater flow to exit the reservoir. The nozzle is thus said to be choked, and themass flow of fluid is a maximum. See also Mach number; Nozzle; Sound; Supersonicdiffuser.Through varying Through varying--area duct area ductS.Apinan168Compressible fluids flow: Choke flow Compressible fluids flow: Choke flowChoked flow can also occur through a long constant-area duct attached to areservoir. As fluid flows through the duct, friction between the fluid and the ductwall reduces the pressure acting on the fluid. As pressure is reduced, other fluidproperties are affected, such as sonic velocity, density, and temperature. Themaximum Mach number occurs at the nozzle exit, and choked flow results whenthis Mach number reaches.With friction With frictionS.ApinanWith heat addition With heat additionA reservoir with a constant-area duct attached may also be considered in the case that the flow through the duct is assumed to be frictionless but heat is added to the system along the duct wall.