Chapter 2 Periodic Table

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    Periodic Table

    Inside the Periodic Table

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    History of Periodic Table Came from the ideas of many

    scientists in the 18 th and 19 th centuries

    Observations grouping of properties predictions(hypothesis) of further

    experiments theories First introduced by Dmitri

    Ivanovitch Mendeleev in 1869

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    MendeleevsPeriodic Table

    Realized that if elements werearranged in order of increasingatomic mass certain properties

    were repeated Arranged the elements in

    horizontal rows in order of increasing atomic number

    Each time an element had similar properties to one before it, hestarted a new row under that

    preceding element

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    MendeleevsPeriodic Table

    Noticed to leave empty spaces toretain an order of arrangement of similar properties

    Realized that there were holes tobe filled by undiscoveredelements

    Law of chemical periodicity :properties of the elements areperiodic functions

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    H

    1

    Li7

    Be9.4

    F19

    B11

    N14

    C12

    O16

    Si

    28

    P

    31

    S

    32

    Cl

    35.5

    Mg

    24

    Na

    23

    Al

    27.3K

    39

    Ca

    40

    Mn

    55

    --

    44

    V

    51

    Ti

    48

    Cr

    52

    Fe56,Co59

    Ni 59,Cu63

    Zr

    90

    Nb

    94

    Mo

    96

    --

    100

    Sr

    87

    Rb

    85

    Yt

    88

    --72

    Br 80

    Zn65

    Cu63

    --68

    Se78

    As75

    Ru104,Rh104

    Pd105,Ag108

    R 2O R 2O6 R 2O7 RO 2 R 2O5 RO R 2O3

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    Pb207

    Bi208

    --Hg200

    Au199

    Tl204

    ?Ce140

    -- -- --Ba137

    Cs133

    ?Di138

    -- -- --?Er

    178

    Ta

    182

    ?La

    180

    W

    184

    --

    Th

    231

    -- U

    240

    ------ --

    Os195,Ir197Pt198,Au199

    -- -- ---- ---- --

    Sn

    118

    Sb

    122

    I

    127

    Cd

    112

    Ag

    108

    In

    113

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    Periodic Table Mosley noticed with electrons in a

    cathode ray tube that they emitted

    x-rays indicative of their atomic number Realized that the atomic

    properties are related to atomicnumber and not atomic mass asMendeleev thought

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    Periodic Table

    Elements are arranged so thatsimilar properties are in groups

    (vertical columns) Main group elements A group Transition elements B groups Periods horizontal rows

    (number from 1 starting H and He)

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    Periodic Table Divided into regions : metals,

    nonmetals, and metalloids Metals malleable, ductile,

    conduct electricity Nonmetals do not conduct

    electricity Metalloids some properties of

    metals and nonmetals (B, Si, Ge,As, Sb, Te)

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    Group 1A All called the alkali metals All are metals (except H) Form similar compounds with

    oxygen in the form of A 2O Solids at room temp, very reactive

    with water

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    Group IIA Called alkaline earth elements Composed of all metals Calcium very important element

    for our bones

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    Transition Elements

    All metals Have commercial uses Some are very well known and are

    expensive Gold, platinum, silver

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    Lanthanides and

    Actinides Two last rows of periodic table Some are radioactive

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    Group 3A

    Aluminum (Al) has many uses All are metals except boron which

    is a metalloid Boron is found as borax which is

    in many cleaning products

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    Group 4A Nonmetal Carbon (C) Metalloids silicon (Si) and

    germanium (Ge) Metals tin (Sn) and lead (Pb) By far C is the most important

    element in this Group

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    Carbon Allotropes element can exist in

    several different and very distinct

    forms Graphite and diamonds

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    Group 5A and 6A

    Most important elements arenitrogen (N) in 5A and oxygen (O)

    in 6A Sulfur has been known since

    ancient times as burning stone

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    Group 7A Referred to as Halogens F, Cl, Br, I exist as diatomic

    molecules (i.e. F 2, Cl 2, etc)

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    Group 8A

    Noble gases it was originallybelieved that none of these gases

    would react with other elements Sometimes called inert gases or

    rare gases

    He, Ne, Ar, Kr, Xe