32
Chapter 1 INTRODUCTION AND Thermodynamics: An Engineering Approach, 6 th Edition Yunus A. Cengel, Michael A. Boles McGraw-Hill, 2008 BASIC CONCEPTS Mehmet Kanoglu Copyright © The McGraw-Hill Companies, Inc. Permission required for reproduction or display.

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Page 1: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Chapter 1

INTRODUCTION AND

Therm

odynamics: An Engineering Approach, 6thEdition

Yunus A. Cengel, Michael A. Boles

McGraw-Hill, 2008

INTRODUCTION AND

BASIC CONCEPTS

Mehmet Kanoglu

Copyright © The McGraw-Hill Companies, Inc. Perm

ission required for reproduction or display.

Page 2: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Objectives

•Id

entify

the u

niq

ue v

ocabula

ry a

ssocia

ted w

ith

therm

odynam

ics t

hro

ugh t

he p

recis

e d

efinitio

n o

f

basic

concepts

to form

a s

ound f

oundation f

or

the

develo

pm

ent

of th

e p

rincip

les o

f th

erm

odynam

ics.

•R

evie

w t

he m

etr

ic S

I and t

he E

nglis

h u

nit s

yste

ms.

•E

xpla

in t

he b

asic

concepts

of th

erm

odynam

ics s

uch

2

•E

xpla

in t

he b

asic

concepts

of th

erm

odynam

ics s

uch

as s

yste

m, sta

te, sta

te p

ostu

late

, equili

bri

um

,

pro

cess, and c

ycle

.

•R

evie

w c

oncepts

of te

mpera

ture

, te

mpera

ture

scale

s,

pre

ssure

, and a

bsolu

te a

nd g

age p

ressure

.

•In

troduce a

n intu

itiv

e s

yste

matic p

roble

m-s

olv

ing

techniq

ue.

Page 3: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

THERMODYNAMICS AND ENERGY

•Therm

odynamics

:T

he

scie

nce

of

energy.

•Energy:

Th

e a

bili

ty t

o c

au

se

ch

an

ge

s.

•T

he

na

me

therm

odynamics

ste

ms fro

m

the

Gre

ek w

ord

s therm

e (

he

at)

an

d

dynamis (

po

we

r).

•Conservation of energy principle

:D

uri

ng

an

in

tera

ctio

n, e

ne

rgy c

an

ch

an

ge

3

Du

rin

g a

n in

tera

ctio

n, e

ne

rgy c

an

ch

an

ge

fr

om

on

e fo

rm to

an

oth

er

bu

t th

e to

tal

am

ou

nt o

f e

ne

rgy r

em

ain

s c

on

sta

nt.

•E

ne

rgy c

an

no

t b

e c

rea

ted

or

de

str

oye

d.

•The first law of therm

odynamics

:A

n

exp

ressio

n o

f th

e c

on

se

rva

tio

n o

f e

ne

rgy

pri

ncip

le.

•T

he

fir

st la

w a

sse

rts th

at energy is a

th

erm

od

yn

am

ic p

rop

ert

y.

Energ

y c

annot

be c

reate

d

or

destr

oyed;

it c

an o

nly

change f

orm

s (

the f

irst la

w).

Page 4: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

•The second law of therm

odynamics:

It a

sse

rts th

at e

ne

rgy h

as quality

as

we

ll a

s quantity, a

nd

actu

al p

roce

sse

s

occu

r in

th

e d

ire

ctio

n o

f d

ecre

asin

g

qu

alit

y o

f e

ne

rgy.

•Classical therm

odynamics

:A

m

acro

sco

pic

ap

pro

ach

to th

e s

tud

y o

f th

erm

od

yn

am

ics th

at d

oe

s n

ot re

qu

ire

a

kn

ow

led

ge

of th

e b

eh

avio

r o

f in

div

idu

al p

art

icle

s.

Conserv

ation o

f energ

y

princip

le f

or

the h

um

an b

ody.

4

ind

ivid

ua

l p

art

icle

s.

•It p

rovid

es a

dir

ect a

nd

ea

sy w

ay to

th

e

so

lutio

n o

f e

ng

ine

eri

ng

pro

ble

ms a

nd

it

is u

se

d in

th

is te

xt.

•Statistical therm

odynamics

:A

m

icro

sco

pic

ap

pro

ach

, b

ase

d o

n th

e

ave

rag

e b

eh

avio

r o

f la

rge

gro

up

s o

f in

div

idu

al p

art

icle

s.

•It is u

se

d in

th

is te

xt o

nly

in

th

e

su

pp

ort

ing

ro

le.

Heat flow

s in t

he d

irection o

f

decre

asin

g t

em

pera

ture

.

Page 5: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Application Areas of Therm

odynamics

5

Page 6: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

IMPORTANCE OF DIMENSIONS AND UNITS

•A

ny p

hysic

al q

ua

ntity

ca

n b

e c

ha

racte

rize

d b

y

dimensions

.

•T

he

ma

gn

itu

de

s a

ssig

ne

d to

th

e d

ime

nsio

ns

are

ca

lled

units

.

•S

om

e b

asic

dim

en

sio

ns s

uch

as m

ass m

, le

ng

th L

, tim

e t, a

nd

te

mp

era

ture

T a

re

se

lecte

d a

s primary

or fundamental

dimensions

, w

hile

oth

ers

su

ch

as v

elo

city V

, e

ne

rgy E

, a

nd

vo

lum

e V a

re e

xp

resse

d in

6

en

erg

y E

, a

nd

vo

lum

e V a

re e

xp

resse

d in

te

rms o

f th

e p

rim

ary

dim

en

sio

ns a

nd

are

ca

lled

secondary dimensions

, o

r derived

dimensions

.

•Metric SI system

:A

sim

ple

an

d lo

gic

al

syste

m b

ase

d o

n a

de

cim

al re

latio

nsh

ip

be

twe

en

th

e v

ari

ou

s u

nits.

•English system

:It h

as n

o a

pp

are

nt

syste

ma

tic n

um

eri

ca

l b

ase

, a

nd

va

rio

us u

nits

in th

is s

yste

m a

re r

ela

ted

to

ea

ch

oth

er

rath

er

arb

itra

rily

.

Page 7: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Some SI and English Units

Th

e S

I u

nit p

refixe

s a

re u

se

d in

all

bra

nch

es o

f e

ng

ine

eri

ng

.

Wo

rk =

Fo

rce

×D

ista

nce

1 J

= 1

N·m

1 c

al =

4.1

86

8 J

1 B

tu =

1.0

55

1 k

J

7T

he

de

fin

itio

n o

f th

e fo

rce

un

its.

1 B

tu =

1.0

55

1 k

J

Page 8: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

A b

ody w

eig

hin

g

60 k

gf

on e

art

h

will

weig

h o

nly

10

kgf on t

he m

oon.

Ww

eig

ht

mm

ass

ggra

vitational

accele

ration

8

The r

ela

tive m

agnitudes o

f th

e f

orc

e

units n

ew

ton (

N),

kilo

gra

m-f

orc

e

(kgf)

, and p

ound-f

orc

e (

lbf)

.

The w

eig

ht

of

a u

nit

mass a

t sea level.

Page 9: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Unity Conversion Ratios

All nonprimary units (secondary units) can be

form

ed by combinations of primary units.

Forc

e u

nits,

for

exam

ple

, can b

e e

xpre

ssed a

s

Dimensional homogeneity

All

equations m

ust

be d

imensio

nally

homogeneous.

9

They c

an a

lso b

e e

xpre

ssed m

ore

convenie

ntly

as unity conversion ratios

as

Unity c

onvers

ion r

atios a

re identically

equal to

1 a

nd

are

unitle

ss,

and t

hus s

uch r

atios (

or

their invers

es)

can b

e insert

ed c

onvenie

ntly into

any c

alc

ula

tion t

o

pro

perly c

onvert

units.

To b

e d

imensio

nally

hom

ogeneous,

all

the

term

s in a

n e

quation

must have t

he s

am

e u

nit.

Page 10: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

SYSTEMS AND CONTROL VOLUMES

•System

:A

qu

an

tity

of m

atte

r o

r a

re

gio

n

in s

pa

ce

ch

ose

n fo

r stu

dy.

•Surroundings:T

he

ma

ss o

r re

gio

n

ou

tsid

e th

e s

yste

m

•Boundary

:T

he

re

al o

r im

ag

ina

ry s

urf

ace

th

at se

pa

rate

s th

e s

yste

m fro

m its

su

rro

un

din

gs.

•T

he

bo

un

da

ry o

f a

syste

m c

an

be

fixed o

r movable.

10

movable.

•S

yste

ms m

ay b

e c

on

sid

ere

d to

be

closed

or open.

•Closed system

(Control mass):

A fix

ed

am

ou

nt

of m

ass, a

nd

no

m

ass c

an

cro

ss

its b

ou

nd

ary

.

Page 11: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

•Open system

(control volume):

A p

rop

erl

y

se

lecte

d r

eg

ion

in

sp

ace

.

•It u

su

ally

en

clo

se

s a

de

vic

e th

at in

vo

lve

s

ma

ss flo

w s

uch

as a

co

mp

ressor,

tu

rbin

e, o

r n

ozzle

.

•B

oth

ma

ss a

nd

en

erg

y c

an

cro

ss th

e

bo

un

da

ry o

f a

co

ntr

ol vo

lum

e.

•Control surface

:T

he

bo

un

da

rie

s o

f a

co

ntr

ol

vo

lum

e. It c

an

be

re

al o

r im

ag

ina

ry.

11

An o

pen s

yste

m (

a

contr

ol volu

me)

with o

ne

inle

t and o

ne e

xit.

Page 12: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

PROPERTIES

OF A SYSTEM

•Property:

An

y c

ha

racte

ristic o

f a

syste

m.

•S

om

e fa

mili

ar

pro

pe

rtie

s a

re

pre

ssu

re P

, te

mp

era

ture

T, vo

lum

e

V, a

nd

ma

ss m

.

•P

rop

ert

ies a

re c

on

sid

ere

d to

be

e

ith

er intensive o

r extensive

.

12

eith

er intensive o

r extensive

.

•Intensive properties:

Th

ose

th

at

are

in

de

pe

nd

en

t o

f th

e m

ass o

f a

syste

m, su

ch

as te

mp

era

ture

, p

ressu

re, a

nd

de

nsity.

•Extensive properties:

Th

ose

w

ho

se

va

lue

s d

ep

en

d o

n th

e s

ize

—o

r e

xte

nt—

of th

e s

yste

m.

•Specific properties:

Exte

nsiv

e

pro

pe

rtie

s p

er

un

it m

ass.

Crite

rion t

o d

iffe

rentiate

inte

nsiv

e

and e

xte

nsiv

e p

ropert

ies.

Page 13: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Continuum

•M

att

er

is m

ade u

p o

f ato

ms t

hat

are

w

idely

spaced in t

he g

as p

hase.

Yet

it is v

ery

convenie

nt

to d

isre

gard

the

ato

mic

natu

re o

f a s

ubsta

nce a

nd

vie

w it as a

continuous,

hom

ogeneous m

att

er

with n

o h

ole

s,

that is

, a continuum

.

•T

he c

ontinuum

idealiz

ation a

llow

s u

s

to tre

at pro

pert

ies a

s p

oin

t fu

nctions

and t

o a

ssum

e t

he p

ropert

ies v

ary

continually

in s

pace w

ith n

o jum

p

13

continually

in s

pace w

ith n

o jum

p

dis

continuitie

s.

•T

his

idealiz

ation is v

alid

as long a

s

the s

ize o

f th

e s

yste

m w

e d

eal w

ith

is larg

e r

ela

tive t

o t

he s

pace

betw

een t

he m

ole

cule

s.

•T

his

is t

he c

ase in p

ractically

all

pro

ble

ms.

•In

this

text

we w

ill lim

it o

ur

consid

era

tion t

o s

ubsta

nces t

hat

can

be m

odele

d a

s a

continuum

.

Despite t

he larg

e g

aps b

etw

een

mole

cule

s,

a s

ubsta

nce c

an b

e t

reate

d a

s

a c

ontinuum

because o

f th

e v

ery

larg

e

num

ber

of

mole

cule

s e

ven in a

n

extr

em

ely

sm

all

volu

me.

Page 14: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

DENSITY AND SPECIFIC GRAVITY

Specific gravity:

The r

atio

of th

e d

ensity o

f a

substa

nce t

o t

he d

ensity o

f som

e s

tandard

substa

nce

at a s

pecifie

d t

em

pera

ture

(u

sually

wate

r at 4°C

).

Density

Specific weight:

The

weig

ht

of

a u

nit v

olu

me

of a s

ubsta

nce.

Specific volume

14

Density is

mass p

er

unit

volu

me;

specific

volu

me

is v

olu

me p

er

unit m

ass.

of a s

ubsta

nce.

Page 15: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

STATE AND EQUILIBRIUM

•T

herm

odynam

ics d

eals

with

equilibrium s

tate

s.

•Equilibrium

:A

sta

te o

f bala

nce.

•In

an e

quili

brium

sta

te there

are

no

unbala

nced p

ote

ntials

(or

drivin

g

forc

es)

within

the s

yste

m.

•Therm

al equilibrium

:If

the

tem

pera

ture

is t

he s

am

e t

hro

ughout

the e

ntire

syste

m.

A s

yste

m a

t tw

o d

iffe

rent

sta

tes.

15

•Mechanical equilibrium:

If there

is

no c

hange in p

ressure

at

any p

oin

t of th

e s

yste

m w

ith t

ime.

•Phase equilibrium:

If a

syste

m

involv

es t

wo p

hases a

nd w

hen t

he

mass o

f each p

hase r

eaches a

n

equili

brium

level and s

tays t

here

.

•Chemical equilibrium:

If the

chem

ical com

positio

n o

f a s

yste

m

does n

ot

change w

ith t

ime,

that

is,

no c

hem

ical re

actions o

ccur.

A c

losed s

yste

m r

eachin

g t

herm

al

equili

brium

.

A s

yste

m a

t tw

o d

iffe

rent

sta

tes.

Page 16: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

The State Postulate

•T

he n

um

ber

of pro

pert

ies

required t

o fix

the s

tate

of a

syste

m is g

iven b

y t

he state

postulate

:

�The state of a sim

ple

compressible system is

completely specified by

16

completely specified by

two independent,

intensive properties.

•Simple compressible

system:

If a

syste

m involv

es

no e

lectr

ical, m

agnetic,

gra

vitational, m

otion, and

surf

ace tensio

n e

ffects

.

Th

e s

tate

of

nitro

ge

n is

fixe

d b

y t

wo

in

de

pe

nd

en

t,

inte

nsiv

e p

rop

ert

ies.

Page 17: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

PROCESSES AND CYCLES

Process:

Any c

hange t

hat

a s

yste

m u

nderg

oes f

rom

one e

quili

brium

sta

te t

o

anoth

er.

Path

:T

he s

eries o

f sta

tes thro

ugh w

hic

h a

syste

m p

asses d

uring a

pro

cess.

To d

escribe a

pro

cess c

om

ple

tely

, one s

hould

specify t

he initia

l and f

inal sta

tes,

as w

ell

as t

he p

ath

it

follo

ws,

and t

he inte

ractions w

ith t

he s

urr

oundin

gs.

Quasistatic or quasi-equilibrium process:

When a

pro

cess p

roceeds in s

uch

a m

anner

that

the s

yste

m r

em

ain

s infinitesim

ally

clo

se t

o a

n e

quili

brium

sta

te

at all

tim

es.

17

Page 18: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

•P

rocess d

iagra

ms p

lott

ed b

y

em

plo

yin

g t

herm

odynam

ic p

ropert

ies

as c

oord

inate

s a

re v

ery

usefu

l in

vis

ualiz

ing t

he p

rocesses.

•S

om

e c

om

mon p

ropert

ies t

hat

are

used a

s c

oord

inate

s a

re t

em

pera

ture

T

, pre

ssure

P, and v

olu

me V (

or

specific

volu

me v

).

•T

he p

refix iso-

is o

ften u

sed t

o

desig

nate

a p

rocess f

or

whic

h a

part

icula

rpro

pert

y r

em

ain

s c

onsta

nt.

•Isotherm

al process:

A p

rocess

18

•Isotherm

al process:

A p

rocess

during w

hic

h t

he t

em

pera

ture

T

rem

ain

s c

onsta

nt.

•Isobaric process:

A p

rocess d

uring

whic

h t

he p

ressure

P r

em

ain

s

consta

nt.

•Isochoric (or isometric) process:

A

pro

cess d

uring w

hic

h t

he s

pecific

volu

me v r

em

ain

s c

onsta

nt.

•Cycle

:A

pro

cess d

uring w

hic

h t

he

initia

l and f

inal sta

tes a

re identical.

The P

-V d

iagra

m o

f a c

om

pre

ssio

n

pro

cess.

Page 19: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

The Steady-Flow Process

•T

he term

steady

implie

s no

change w

ith tim

e.

The

opposite o

f ste

ady is

unsteady,

or transient.

•A

larg

e n

um

ber

of

engin

eering d

evic

es o

pera

te

for

long p

eriods o

f tim

e

under

the s

am

e c

onditio

ns,

and t

hey a

re c

lassifie

d a

s

steady-flow devices.

Du

rin

g a

ste

ad

y-

flo

w p

roce

ss,

flu

id

pro

pe

rtie

s w

ith

in

the

co

ntr

ol

vo

lum

e m

ay

ch

an

ge

with

19

steady-flow devices.

•Steady-flow process:

A

pro

cess d

uring w

hic

h a

flu

id

flow

s t

hro

ugh a

contr

ol

volu

me s

teadily

.

•S

teady-f

low

conditio

ns c

an

be c

losely

appro

xim

ate

d b

y

devic

es t

hat

are

inte

nded f

or

continuous o

pera

tion s

uch

as turb

ines,

pum

ps,

boile

rs,

condensers

, and h

eat

exchangers

or

pow

er

pla

nts

or

refr

igera

tion s

yste

ms.

po

sitio

n b

ut

no

t

with

tim

e.

Un

de

r ste

ad

y-f

low

co

nd

itio

ns,

the

ma

ss

an

d e

ne

rgy c

on

ten

ts o

f a

co

ntr

ol vo

lum

e

rem

ain

co

nsta

nt.

Page 20: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

TEMPERATURE AND THE ZEROTH LAW OF

THERMODYNAMICS

•The zeroth law of therm

odynamics:If tw

o b

od

ies a

re in

th

erm

al

eq

uili

bri

um

with

a th

ird

bo

dy, th

ey a

re a

lso

in

th

erm

al e

qu

ilib

riu

m w

ith

e

ach

oth

er.

•B

y r

ep

lacin

g th

e th

ird

bo

dy w

ith

a th

erm

om

ete

r, th

e z

ero

th la

w c

an

b

e r

esta

ted

as two bodies are in therm

al equilibrium if both have the

same temperature reading even if they are not in contact.

20

Tw

o b

od

ies r

ea

ch

ing

the

rma

l e

qu

ilib

riu

m

afte

r b

ein

g b

rou

gh

t

into

co

nta

ct in

an

iso

late

d e

nclo

su

re.

Page 21: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Temperature Scales

•A

ll te

mp

era

ture

sca

les a

re b

ase

d o

n

so

me

ea

sily

re

pro

du

cib

le s

tate

s s

uch

as

the

fre

ezin

g a

nd

bo

ilin

g p

oin

ts o

f w

ate

r:

the

ice point

an

d t

he

steam point.

•Ice point:

A m

ixtu

re o

f ic

e a

nd

wa

ter

tha

t is

in

eq

uili

bri

um

with

air

sa

tura

ted

w

ith

va

po

r a

t 1

atm

pre

ssu

re (

0°C

or

32

°F).

•Steam point:

A m

ixtu

re o

f liq

uid

wa

ter

an

d w

ate

r va

po

r (w

ith

no

air

) in

e

qu

ilib

riu

m a

t 1

atm

pre

ssu

re (

10

0°C

or

21

2°F

).

P v

ers

us T p

lots

of

the

exp

eri

me

nta

l

da

ta o

bta

ine

d

fro

m a

co

nsta

nt-

vo

lum

e g

as

the

rmo

me

ter

usin

g fo

ur

diffe

ren

t g

ase

s

at

diffe

ren

t (b

ut

low

) p

ressu

res.

21

•Celsius scale

:in

SI

un

it s

yste

m

•Fahrenheit scale

:in

En

glis

h u

nit

syste

m

•Therm

odynamic temperature scale

:A

te

mp

era

ture

sca

le th

at

is in

de

pe

nd

en

t o

f th

e p

rop

ert

ies o

f a

ny s

ub

sta

nce

.

•Kelvin scale

(SI)

Rankine scale

(E)

•A

te

mp

era

ture

sca

le n

ea

rly id

en

tica

l to

th

e K

elv

in s

ca

le is th

e ideal-gas

temperature scale

. T

he

te

mp

era

ture

s

on

th

is s

ca

le a

re m

ea

su

red

usin

g a

co

nsta

nt-

vo

lum

e g

as t

he

rmo

me

ter.

A c

on

sta

nt-

vo

lum

e g

as t

he

rmo

me

ter

wo

uld

rea

d -

27

3.1

5°C

at

ab

so

lute

ze

ro p

ressu

re.

Page 22: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Com

parison o

f

tem

pera

ture

scale

s.

22

•T

he r

efe

rence t

em

pera

ture

in t

he o

rigin

al K

elv

in s

cale

was t

he ice point,

273.1

5 K

, w

hic

h is t

he t

em

pera

ture

at

whic

h w

ate

r fr

eezes (

or

ice m

elts).

•T

he r

efe

rence p

oin

t w

as c

hanged t

o a

much m

ore

pre

cis

ely

repro

ducib

le

poin

t, the triple point

of

wate

r (t

he s

tate

at w

hic

h a

ll th

ree p

hases o

f w

ate

r

coexis

t in

equili

brium

), w

hic

h is a

ssig

ned t

he v

alu

e 2

73.1

6 K

.

Com

parison o

f

magnitudes o

f

various

tem

pera

ture

units.

Page 23: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

PRESSURE

Pressure

:A

norm

al fo

rce e

xert

ed

by a

flu

id p

er

unit a

rea

68 k

g136 k

g

Afe

et=

300cm

2

0.2

3 k

gf/

cm

20.4

6 k

gf/

cm

2

23

The n

orm

al str

ess (

or

“pre

ssure

”) o

n t

he

feet of a c

hubby p

ers

on is m

uch g

reate

r

than o

n t

he f

eet of

a s

lim p

ers

on.

Som

e

basic

pre

ssure

gages.

0.2

3 k

gf/

cm

20.4

6 k

gf/

cm

2

P=

68/3

00=

0.2

3 k

gf/

cm

2

Page 24: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

•Absolute pressure

:T

he

actu

al p

ressu

re a

t a

giv

en

po

sitio

n. It is

me

asu

red

re

lative

to

ab

so

lute

va

cu

um

(i.e

., a

bso

lute

ze

ro p

ressu

re).

•Gage pressure

:T

he

diffe

ren

ce

be

twe

en

th

e a

bso

lute

pre

ssu

re a

nd

th

e lo

ca

l a

tmo

sp

he

ric p

ressu

re. M

ost p

ressu

re-m

ea

su

rin

g d

evic

es a

re

ca

libra

ted

to

re

ad

ze

ro in

th

e a

tmo

sp

he

re, a

nd

so

th

ey in

dic

ate

ga

ge

p

ressu

re.

•Vacuum pressures

:P

ressu

res b

elo

w a

tmo

sp

he

ric p

ressu

re.

Thro

ughout

this

text,

the

pre

ssure

P

24

pre

ssure

P

will

denote

absolute

pressure

unle

ss

specifie

d

oth

erw

ise.

Page 25: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Variation of Pressure with Depth

Wh

en

th

e v

ari

atio

n o

f d

en

sity

with

ele

va

tio

n is k

no

wn

25

Fre

e-b

ody d

iagra

m o

f a r

ecta

ngula

r

fluid

ele

ment

in e

quili

brium

.

The p

ressure

of

a f

luid

at

rest

incre

ases w

ith d

epth

(as a

result o

f added w

eig

ht)

.

Page 26: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

In a

room

fill

ed w

ith

a g

as,

the v

ariation

of pre

ssure

with

heig

ht

is n

eglig

ible

.

Pre

ssure

in a

liq

uid

at re

st in

cre

ases

linearly w

ith

dis

tance f

rom

the

free s

urf

ace.

26

free s

urf

ace.

The p

ressure

is t

he

sam

e a

t all

poin

ts o

n

a h

orizonta

l pla

ne in

a g

iven f

luid

regard

less o

f

geom

etr

y, p

rovid

ed

that th

e p

oin

ts a

re

inte

rconnecte

d b

y

the s

am

e f

luid

.

Page 27: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Pascal’s law

:T

he

pre

ssu

re a

pp

lied

to

a

co

nfin

ed

flu

id in

cre

ase

s th

e p

ressu

re

thro

ug

ho

ut b

y th

e s

am

e a

mo

un

t.

Th

e a

rea

ra

tio

A2/A

1is

ca

lled

th

e ideal mechanical

advantage

of th

e h

yd

rau

lic

lift.

27

Liftin

g o

f a

la

rge

we

igh

t

by a

sm

all

forc

e b

y th

e

ap

plic

atio

n o

f P

asca

l’s

law

.

lift.

Page 28: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

The Manometer

Measuring t

he

pre

ssure

dro

p a

cro

ss

a flo

w s

ection o

r a f

low

devic

e b

y a

diffe

rential

manom

ete

r.

It is c

om

monly

used t

o m

easure

sm

all

and

modera

te p

ressure

diffe

rences. A

manom

ete

r

conta

ins o

ne o

r m

ore

flu

ids s

uch a

s m

erc

ury

, w

ate

r,

alc

ohol, o

r oil.

28

In s

tacked-u

p f

luid

layers

, th

e

pre

ssure

change a

cro

ss a

flu

id layer

of density ρ

and h

eig

ht h is ρ ρρρgh

.

The b

asic

manom

ete

r.

Page 29: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Other Pressure Measurement Devices

•Bourdon tube:C

on

sis

ts o

f a

ho

llow

me

tal tu

be

be

nt

like

a h

oo

k w

ho

se

en

d is c

lose

d a

nd

co

nn

ecte

d t

o a

dia

l in

dic

ato

r n

ee

dle

.

•Pressure transducers

:U

se

va

rio

us te

ch

niq

ue

s

to c

on

ve

rt t

he

pre

ssu

re e

ffe

ct

to a

n e

lectr

ica

l

effe

ct

su

ch

as a

ch

an

ge

in

vo

lta

ge

, re

sis

tan

ce

,

or

ca

pa

cita

nce

.

•P

ressu

re tra

nsd

uce

rs a

re s

ma

ller

an

d f

aste

r,

an

d th

ey c

an

be

mo

re s

en

sitiv

e, re

liab

le, a

nd

pre

cis

e th

an

th

eir

me

ch

an

ica

l co

un

terp

art

s.

29

Various t

ypes o

f B

ourd

on t

ubes u

sed

to m

easure

pre

ssure

.

pre

cis

e th

an

th

eir

me

ch

an

ica

l co

un

terp

art

s.

•Strain-gage pressure transducers:

Wo

rk b

y

ha

vin

g a

dia

ph

rag

m d

efle

ct

be

twe

en

tw

o

ch

am

be

rs o

pe

n t

o t

he

pre

ssu

re in

pu

ts.

•Piezoelectric transducers

:A

lso

ca

lled

so

lid-

sta

te p

ressu

re t

ran

sd

uce

rs,

wo

rk o

n t

he

pri

ncip

le th

at

an

ele

ctr

ic p

ote

ntia

l is

ge

ne

rate

d in

a c

rysta

llin

e s

ub

sta

nce

wh

en

it

is s

ubje

cte

d t

o

me

ch

an

ica

l p

ressu

re.

Page 30: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

THE BAROMETER AND ATMOSPHERIC PRESSURE

•A

tmospheric p

ressure

is m

easure

d b

y a

devic

e c

alle

d a

barometer;

thus,

the

atm

ospheric p

ressure

is o

ften r

efe

rred t

o a

s t

he barometric pressure

.

•A

fre

quently u

sed p

ressure

unit is t

he standard atm

osphere

, w

hic

h is d

efined a

s

the p

ressure

pro

duced b

y a

colu

mn o

f m

erc

ury

760 m

m in h

eig

ht

at

0°C

Hg

=

13,5

95 k

g/m

3)

under

sta

ndard

gra

vitational accele

ration (g = 9

.807 m

/s2).

The length

or

the

cro

ss-s

ectional are

a

30

The b

asic

baro

mete

r.

cro

ss-s

ectional are

a

of th

e t

ube h

as n

o

effect on t

he h

eig

ht

of th

e f

luid

colu

mn o

f

a b

aro

mete

r,

pro

vid

ed t

hat th

e

tube d

iam

ete

r is

larg

e e

nough t

o

avoid

surf

ace t

ensio

n

(capill

ary

) effects

.

Page 31: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

PROBLEM-SOLVING TECHNIQUE

•S

tep 1

: P

roble

m S

tate

ment

•S

tep 2

: S

chem

atic

•S

tep 3

: A

ssum

ptions a

nd A

ppro

xim

ations

•S

tep 4

: P

hysic

al Law

s

•S

tep 5

: P

ropert

ies

•S

tep 6

: C

alc

ula

tions

31

•S

tep 6

: C

alc

ula

tions

•S

tep 7

: R

easonin

g,

Verification,

and D

iscussio

n

EES (Engineering Equation Solver)

(Pro

no

un

ce

d a

s e

ase

):

EE

S is a

pro

gra

m th

at so

lve

s s

yste

ms o

f lin

ea

r o

r n

on

line

ar

alg

eb

raic

or

diffe

ren

tia

l e

qu

atio

ns n

um

eri

ca

lly. It h

as a

la

rge

libra

ry o

f b

uilt

-in

th

erm

od

yn

am

ic p

rop

ert

y fu

nctio

ns a

s w

ell

as

ma

the

ma

tica

l fu

nctio

ns. U

nlik

e s

om

e s

oftw

are

pa

cka

ge

s, E

ES

do

es n

ot so

lve

en

gin

ee

rin

g p

rob

lem

s; it o

nly

so

lve

s th

e e

qu

atio

ns

su

pp

lied

by th

e u

se

r.

Page 32: Chapter 1 INTRODUCTION AND - yildiz.edu.tryildiz.edu.tr/~atayil/Ch1.pdf · ... An Engineering Approach, 6 Chapter 1 INTRODUCTION AND th ... macroscopic approach to the study of thermodynamics

Summary

•T

herm

odynam

ics a

nd e

nerg

y

�A

pp

lica

tio

n a

rea

s o

f th

erm

od

yn

am

ics

•Im

port

ance o

f dim

ensio

ns a

nd u

nits

�S

om

e S

I a

nd

En

glis

h u

nits,

Dim

en

sio

na

l h

om

og

en

eity,

Un

ity c

on

ve

rsio

n r

atio

s

•S

yste

ms a

nd c

ontr

ol volu

mes

•P

ropert

ies o

f a s

yste

m

•D

ensity a

nd s

pecific

gra

vity

•S

tate

and e

quili

brium

32

•S

tate

and e

quili

brium

�T

he

sta

te p

ostu

late

•P

rocesses a

nd c

ycle

s

�T

he

ste

ad

y-f

low

pro

ce

ss

•T

em

pera

ture

and t

he z

ero

th law

of th

erm

odynam

ics

�T

em

pe

ratu

re s

ca

les

•P

ressure

�V

ari

atio

n o

f p

ressu

re w

ith

de

pth

•T

he m

anom

ete

r and t

he a

tmospheric p

ressure

•P

roble

m s

olv

ing t

echniq

ue