Challenges in the Electrical and Lighting Market final in the Electrical and... · Now a Strategic Business Unit of SABIC ... Potential Thermal Management solution ... Optical Properties

Challenges in the Electrical and Lighting Market

Solutions in SABIC Innovative Plastics

Hans-Otto Schlothauer October 2011

2

Agenda:

• SabicSabic Innovative Plastics Introduction

• Environment and PlasticsToxic freeRecycledSimplified process

• MaterialImproved flame retardant Thermal conductiveImproved weatherability

3

SABIC is a $40B Chemicals Industry Leader

SABIC (Saudi Basic Industries Company)

… established in 1976 to convert natural gas

feedstock into petrochemicals

A global company

– Operations in 100 countries

– 45+ state-of-the-art manufacturing facilities

– 30,000+ employees

Industry Recognition

– Fortune 500 and Fortune Most Admired

– 2006 Platts Petrochemical Company of the Year

A Materials Company Committed to Investing Globally

4

Chemicals PolymersFertilizersMetalsPerformance Chemicals

SABIC Innovative Plastics

Polycarbonate

Resin/Blends

782

Specialty Films &

Sheet

57

Polyphenylene

Oxide Blends

151

Styrenic Resins

(ABS-ASA)

221

Polybutylene

Terephtalate

156

Specialty

Compounding

69

Polyetherimide –

Polyimide

10

•Engineered

thermoplastics

Resins: PC, ABS, PBT,

PPO, PEI

•PP Compounds

•Sheet & film

•Olefins

•Oxygenates

•Aromatics

•Intermediates

•Gases

•Polyolefins

•PVC

•Polyester

•Steel

•Aluminum

•Ammonia

•Urea

•Phosphate

and liquid

fertilizers

•Catalyst

•Rubber

•Specialty

polymers

•Additives

•Elastomers

SABIC Sabic Innovative Plastics - One of the Six Strategic Business Units (Formerly GE Plastics)

A Materials Company Committed to Investing Globally

Now a Strategic Business Unit of SABIC… one of the world’s fastest growing global

petrochemical companies

5

Environment and Plastics

• Global Mega Trends

• Regulations

• Toxic free

• Recycled

• Simplified process

1980s 1990s 2000s 2010s….

Quality Globalization Internet Sustainability

……Sustainability and economic drivers are increasingly more intertwined…

7B 9B 0.8B 3B 1.5x 2.5x>$100 >$150 300M 600M

Global Mega Trends

6

To Address Issues of:

•Climate Change

•Resource Depletion

•Food and Water Shortage

•Toxicity Health Risk

•Energy Demand

•Ecological Destructions

Regulations, Standards & Voluntary Programs

Socio-Economic Pressures Driving Sustainability

Voluntary Eco Labels

NGO’s

Clean Production Action

Regulations and Executive Orders

REACH

OEM standards

Tyco

3MHP

Toyota

Nokia

Philips

Electrolux

Osram

CanonApple

7

8

Meets Requirements for

Bromine FR Free:

•no deca BDE•no TBBPA, other Br additives

Meets Requirements for

Non Halogen*:

RoHS compliant:• no penta/octa BDE• no Pb, Cd

*Non Halogen FR & Non PVC

Toxic free

Recycle of Plastics… One of the solutions to Sustainability

Transform

End-useMarkets

ReuseIn-House scraps

Reduce Incineration

Bio BasedPolymers

Minimize Land-Fill

ChemicalOrMechanicalRecycles

Post Consumer Waste

Post Industrial Waste

9

Valox iQ* PBT resin Chemical “Upcycle” process

vsTypical Post Consumer Recycle Process

High-end Plastic Parts

RegrindRe-compound

Heat history

Post Consumer PET

destined to landfillValox IQ* and Xenoy IQ* Resin

BDO

~2MM MT/yrto landfill

Chemical process

– Valox iQ* PBT is made in a chemical process by upcycling solid PET waste to PBT– Valox iQ* and Xenoy iQ* are drop in solutions for Valox* and Xenoy* products

– Post consumer recycle (PCR) typically involves regrinding part or runners and re-compounding in an extruder.

– PCR results in significant degradation (20%-30%) of product properties with every heat history

* Trademark of SABIC Innovative Plastics IP BV

Recycle process

10

iQ summary & New score-cards

PCR PETBottle

Re-Synthesis

(PET->PBT)

CompoundingInto:

Valox* iQXenoy* iQ

End-useApplications

Claims in ScorecardChemical Recycle Process (Up-cycling) •Scorecard… Good Reference

•Up-cycle from Post Consumer PET

Bottles to PBT Resin

–0.85 kg of PCR PET Utilization per 1kg

of iQ-PBT resin

–Contain Up to 60% of PCR%

(in iQ-PBT resin)

•“Drop-in” Performance as existing,

virgin PBT and PC/PBT

•CO2 & Energy Reduction vs. Crude-Oil

based PBT

–CO2: up to 34% reduction

–Energy: up to 47% reduction

Product Nam e

Description

Key Value proposition

Major Applications & Use s

Cradle-to-Gate M anufacturing DataVs compa rative product 1 Vs c omparativ e product 2

Valox iQ 195 Vs standard PBT Valox iQ 195 Vs Polyamide 6

GHG Emissions Reduction(%) 34 1

less than standard PBT 70 2

less than standard Polya mide 6Fos sil Fuel Energy Consumption

Reduction (%) 47 1 les s than standard PBT 58

2 les s than standard Polyamide 6

Claims

Greenhouse Ga s emission s

Energy Efficicency

Ma terial E ffectiveness

Ecolabelin g benefits

Green Chemis try

Key Contact Pe rsons

Produc t Marketing Leader

LCA and Proofs Leader

Toxic ity and Stewardsh ip LeadReferences

1 based on the Internal L ife Cycle Assessment da ta, Full ISO p eer review under progress2 Plas tics EUR (March 20 05), Ecoprofiles of the Eu ropean P latics Indus try, Polya mide (Nylon 6) ; www.plasticseu ro pe.org)

Elec trical & E lec tronics , autom otive, Consumer, In dustrial , Telecom, fo od contac t applications

Based on Novel chemical "up cycle " process, E lim inates post consum er sol id was te, E liminates p ost co nsum er solid was te, Red uced ene rg y consu mption ,

Reduced CO2 em iss ions, Delivers performance of virg in PBT ('D rop in solution")

Valo x iQ resin is based on nove l chem ica l "upcyc le" process utilizing post consum er PET solid waste, has s imilar engineerin g themo plastic property

performan ce, and e nables lower env ironme ntal im pact

Valo x iQ resin

Valox iQ resin is des igned to e mit app ro xim ately 35% less gree n house g ases com pared to tradit ional DMT based PBT. I f annual global PBT consumpt ion3)

(0 .7 MMT/yr, neat re sin bas is) were converted to Valox iQ, i t would avoid app ro xim ately 1.0 MMT /yr of green hou se gases equivalent to elim inating

approxim ately 500,000 passenger ve hicles on European road s per year

Valo x iQ resin is des igned to save appro xim ately 47% energy compa re d to traditio nal DMT base d PBT. If annual global PBT consumptio n3(0.7 MMT/yr, ne at

re sin bas is) were con verted to Valox iQ, i t would save ap proxim ately 5.2MM barrels of crude o il per year4

Valo x iQ resin is des igned to consum e 0.85kg (equivalent to 6 7 PET 0.5 liter water bottles ) o f Post consum er PET water bottles per Kg of Valox iQ res in

produced. If annual global PBT consump tion3 (0.7 MM T/yr, neat resin basis ) were converted to Valox iQ , it would elim inate/divert approx ima tely 0.6 MMT /yr PCR PET was te bottle s from landfi ll, equivalent to 2 34-fold le ngth of equ ator if al l such PCR PET bottles are linearly con nected.

Valo x iQ resin is des igned to contain up to 60% pos t consumer recycle content by weight. Use of Va lox iQ resin in perso nal com puter and industrial

applications m ay the pa rts to earn/qu alify up to 2 EPEAT (IEEE 1680.1) points

VALOX iQ resin series com ply with EU RoHS and w ith the Joint Indus try Guid e (JIG ), Global Auto motive Dec larable Subs tances Lis t (GADSL), and comes with FDA approval. VALOX iQ resin may also help you secure a voluntary ecolabel for your application. June 1, 2 010

Yasuhiro Sugawara, Tokyo C lub Build ing, 3-2-6 Kasum igaseki, Chiyoda -ku, Tokyo 100-001 3, JAPAN; Tel. +81-3-3593-473 5, Fax. +81-3-3593-4707 , Mobile.

+81-90-262 6-9403, Mail : yasuhiro.sugawara@sabic -ip.com

Sreepa daraj Karanam , SABIC In novative Pla stics B.V., Technology, 1 P lasticsla an, 4612 PX, Bergen Op Zoom, Th e Nethe lands; Tel. +3 1-164-292056,

Fax:+3 1-164-292320, Em ail: s reepadaraj.karanam @ sabic -ip.co m

Els W e eg-Aerssens , Ph . D.; Produc t Ste ward for Base Res ins, Perfo rm ance Produ cts a nd SF&S, 1 Lexan Lane, Mt . Verno n, IN 47 620, U.S.A., Tel:+1 (513)

821-0518; Mob ile: +1 (513) 262-8522

Product Nam e

Description

Key Value proposition

Major Applications & Use s

Cradle-to-Gate M anufacturing DataVs compa rative product 1 Vs c omparativ e product 2

Valox iQ 195 Vs standard PBT Valox iQ 195 Vs Polyamide 6

GHG Emissions Reduction(%) 34 1

less than standard PBT 70 2

less than standard Polya mide 6Fos sil Fuel Energy Consumption

Reduction (%) 47 1 les s than standard PBT 58

2 les s than standard Polyamide 6

Claims

Greenhouse Ga s emission s

Energy Efficicency

Ma terial E ffectiveness

Ecolabelin g benefits

Green Chemis try

Key Contact Pe rsons

Produc t Marketing Leader

LCA and Proofs Leader

Toxic ity and Stewardsh ip LeadReferences

1 based on the Internal L ife Cycle Assessment da ta, Full ISO p eer review under progress2 Plas tics EUR (March 20 05), Ecoprofiles of the Eu ropean P latics Indus try, Polya mide (Nylon 6) ; www.plasticseu ro pe.org)

Elec trical & E lec tronics , autom otive, Consumer, In dustrial , Telecom, fo od contac t applications

Based on Novel chemical "up cycle " process, E lim inates post consum er sol id was te, E liminates p ost co nsum er solid was te, Red uced ene rg y consu mption ,

Reduced CO2 em iss ions, Delivers performance of virg in PBT ('D rop in solution")

Valo x iQ resin is based on nove l chem ica l "upcyc le" process utilizing post consum er PET solid waste, has s imilar engineerin g themo plastic property

performan ce, and e nables lower env ironme ntal im pact

Valo x iQ resin

Valox iQ resin is des igned to e mit app ro xim ately 35% less gree n house g ases com pared to tradit ional DMT based PBT. I f annual global PBT consumpt ion3)

(0 .7 MMT/yr, neat re sin bas is) were converted to Valox iQ, i t would avoid app ro xim ately 1.0 MMT /yr of green hou se gases equivalent to elim inating

approxim ately 500,000 passenger ve hicles on European road s per year

Valo x iQ resin is des igned to save appro xim ately 47% energy compa re d to traditio nal DMT base d PBT. If annual global PBT consumptio n3(0.7 MMT/yr, ne at

re sin bas is) were con verted to Valox iQ, i t would save ap proxim ately 5.2MM barrels of crude o il per year4

Valo x iQ resin is des igned to consum e 0.85kg (equivalent to 6 7 PET 0.5 liter water bottles ) o f Post consum er PET water bottles per Kg of Valox iQ res in

produced. If annual global PBT consump tion3 (0.7 MM T/yr, neat resin basis ) were converted to Valox iQ , it would elim inate/divert approx ima tely 0.6 MMT /yr PCR PET was te bottle s from landfi ll, equivalent to 2 34-fold le ngth of equ ator if al l such PCR PET bottles are linearly con nected.

Valo x iQ resin is des igned to contain up to 60% pos t consumer recycle content by weight. Use of Va lox iQ resin in perso nal com puter and industrial

applications m ay the pa rts to earn/qu alify up to 2 EPEAT (IEEE 1680.1) points

VALOX iQ resin series com ply with EU RoHS and w ith the Joint Indus try Guid e (JIG ), Global Auto motive Dec larable Subs tances Lis t (GADSL), and comes with FDA approval. VALOX iQ resin may also help you secure a voluntary ecolabel for your application. June 1, 2 010

Yasuhiro Sugawara, Tokyo C lub Build ing, 3-2-6 Kasum igaseki, Chiyoda -ku, Tokyo 100-001 3, JAPAN; Tel. +81-3-3593-473 5, Fax. +81-3-3593-4707 , Mobile.

+81-90-262 6-9403, Mail : yasuhiro.sugawara@sabic -ip.com

Sreepa daraj Karanam , SABIC In novative Pla stics B.V., Technology, 1 P lasticsla an, 4612 PX, Bergen Op Zoom, Th e Nethe lands; Tel. +3 1-164-292056,

Fax:+3 1-164-292320, Em ail: s reepadaraj.karanam @ sabic -ip.co m

Els W e eg-Aerssens , Ph . D.; Produc t Ste ward for Base Res ins, Perfo rm ance Produ cts a nd SF&S, 1 Lexan Lane, Mt . Verno n, IN 47 620, U.S.A., Tel:+1 (513)

821-0518; Mob ile: +1 (513) 262-8522

•Scorecard shows all claims

Scorecard

0,

50,

100,

150,

200,

250,

300,

350,

400,

Valox 195 ValoxiQ 195

mP

t

Fossil fuelsMineralsLand useAcidif ication/ EutrophicationEcotoxicityOzone layerRadiation

Std PBT iQ PBT

Energy Consumption Reduction

11

12

Properties Regular PBT Valox iQ PBT Neat Resin

Tensile Stress at yield (Mpa) 54 50

Flexural Stress at 5% strain (Mpa) 85 82

Flexural Modulus (Mpa) 2500 2460

Notched Izod, 23 °C (J/m) 35 35

Specific gravity 1.31 1.31

Tc (°C) 164 170

Tm (°C) 225 220

HDT, 0.45 Mpa (°C) 155 150

Resin properties

*

* Typical values

Comparable properties

13

Material

• Improved flame retardant

• Thermal conductive

• Improved weatherability

• Up to 95% Light Reflectance• Up to UL 94 V0 at 1.5mm** • Improved UV behavior• Flow • Anti dust material available

14

Lexan* Polycarbonate resinsTransparent gradesDiffusion gradesSLX: Higher weatherabilityFR: FR transparent up to 1mmXHT: Higher heat stabilityFXD (Vfx): Diffusion

LNP*ThermocompPPA*based compounds

Soldering ability

Konduit*compounds

Potential Thermal Management solution

Potential materials for LED devices


Valox*resins/Lexan*resins

Non soldering

FR…A Unique Enabler

5VA clearV0 clear

Eco

High flow

Thinwall

• Standard PC type optical properties• Good practical impact strength• Heat resistance like PC• Flame resistance at thin walls-Clear UL94 5VA (3mm)-Clear & Diffusion UL94 V0 up to 1mm

• Almost limitless color capability• Compliance with ECO protocols**• UL746C f1 rating

• Thermal conductive up to 10W/m-K• Inherent electrical isolative • Pass 6KV breakdown test• Flame resistance UL94 V0 1.2mm**• Colors (white & dark gray & black)• Potential weight reduction• Design freedom

** (non-brominated, non-chlorinated and non phosphorus)

15

LUX9610 LUX9612 LUX9612 LUX9616 LUX9616 LUX9616

Thick. Item NA9E155T WH8E508X WH8E490x WH8E491x WH8E492x WH5E140X

3mm

%T 88.8 75 70 50 49 42.5

DLD (deg.) - 29 32 54 56 60

%Haze 1.1 99 99 99 99 99

2mm

%T 89.7 83 80 60 59 52

DLD (deg.) - 22 26 46 50 59

%Haze 0.6 98 98 99 99 99

1.5mm

%T 90.2 87 82 66 65 57.2

DLD (deg.) - 15 18 38 41 57

%Haze 0.6 96 96 98 99 99

1.0mm

%T 90.6 89 88.7 78.5 77 65

DLD (deg.) 8 11 25 30 50

%Haze 0.5 95 96 98 98 99

Optical Properties of Lexan*resin LUX961L

LUX-series from clear to diffusionProducts with broad optical properties suitable to cover LED diversified applications

UL yellow card V0 @ 1.5mm at all colors; RTI 125/115/125C


16

EXRL0847/63 EXRL0847/63 EXRL0847/63 EXRL0847/63 EXRL0863

Thick. Item WH8E508X WH8E490x WH8E491x WH8E492x WH5E140X

3mm

%T 75 71 50 49 44

DLD (deg.) 29 32 54 56 60

%Haze 99 99 99 99 99

2mm

%T 83 81 62 60 52

DLD (deg.) 22 26 46 50 59

%Haze 98 98 99 99 99

1.5mm

%T 86 83 68 66 57

DLD (deg.) 15 18 38 41 57

%Haze 96 96 98 99 99

1.0mm

%T 89 88.7 79 78 65

DLD (deg.) 8 11 25 30 50

%Haze 95 96 98 98 99

Optical Properties of Lexan* resin EXRL0847 & EXRL0863 � LUX2114 & LUX2614

LUX-series Products with broad optical properties suitable to cover LED diversified applications


UL yellow card V2 @ 0.75mm / GWFI 850C

17

Optical Properties of Lexan EXRL0706 & EXRL0747

thickness Item NA8E061T WH8F013X WH7E317X WH6E305X WH5E143X WH4E202X

3.0mm

Transmission% 88.6 77.7 68.1 52.3 47.8 42.2

DLD 25.6 33.2 50 57.2 59.8

Haze% 1.2 97.7 99 99.2 99.2 99

2.0mm

Transmission% 89.8 84.7 79 64.6 58.8 50.5

DLD 18.1 25.1 42.3 52.1 58.8

Haze% 0.8 97.3 98.7 99 99.3 99

1.5mm

Transmission% 90.2 87.7 83.5 73 67.5 56

DLD 12.4 17.9 32.8 47.1 57.3

Haze% 0.7 95.8 97.7 98.6 99 99

1.0mm

Transmission% 90.6 89.4 87.6 81.3 76.5 63.7

DLD 7.1 12.7 19.8 30.5 53

Haze% 0.7 94.3 96.8 98.2 98.6 98.9

UL Yellow Card: 5VA @ 3mm nature & all colorsV0 up to 1.0mm nature & all colorsf1 outdoor rating (all color)


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LNP* Konduit* Compounds

Konduit* Compounds are compounds that exhibit superior thermal conductive performance. The unique feature of this compound is its ability to fulfill the requirements needed for the LED Lighting heat sink and driver housing applications.

• Available in black, gray or white colors

• Thermal conductivity up to 10W/mK (electrical isolative)

• Thermal conductivity up to 15W/mK (electrical conductive)

Features & Potential Benefits in LED Socket:

� Reduce working temperature by metal+plastics hybrid design - increase operating efficiency and life span

� Inherent electrical isolative – pass 6KV breakdown test

� Comply with safety regulations like Underwriter’s Laboratory (UL)

� Design freedom of injection molding

� Better productivity compare to die-cast Al

� Potentially system cost reduction through improved productivity

� Eliminate painting process with PX09322


19

Ko

nd

uit

®C

om

po

un

ds

(Da

rk c

olo

r)

[email protected], K=2.6-10 W/m-K

[email protected], K=2.1-8.1 W/m-K

PX10321

PX10322

[email protected], K=1.7-5 W/m-K


PA6 based

PX10323 [email protected], K=3.5-15 W/m-K

0X10324 [email protected], K=3.5-15 W/m-K

Electrically conductive

PPS based

PX08321

PX08322

Ko

nd

uit

®C

om

po

un

ds

(Lig

ht

colo

r)


PX11311

PX09322


[email protected], K=1.5-6 W/m-K PA6 based

OX11312 [email protected], K=1.4-4.5 W/m-K

OX11314 [email protected], K=1.8-6.5 W/m-K

PPS based

PX11313

LNP Konduit* compound product tree


20

Lexan Copolymers – Portfolio Look

Clarity Impact Colors

Unique Product Attributes expand Polycarbonate Performance to New Applications

SLX

Weatherable

+

XHT

HeatResistance

+

HFD

SuperiorFlow

+CFR

FlameResistance

+

EXL

Low TempImpact

+

FST

FlameSmokeToxicity

+ DMX

ScratchResistance

+

21

UV weathering• Clarity, color and gloss• Toughness• Chemical resistance• Eliminates UV coating• Diffuse lighting

How can Lexan* SLX resins serve you?

UV weathering


PotentialApplications:

Outdoor / Street Lighting applications

Lexan* SLX resin UV PC resin

As molded:

In hot chamberfor 2900 hours:175W MH lamp

120oC on the refractor

55oC ambient

UV PROTECTIVE LAYER

Lexan SLX resin

UV light

Xenon Arc Weathering –transparent colors –: YI and Haze#

Lexan* SLX Resins - Lower Haze and Yellowness After UV Exposure

0

2

4

6

8

10

0 2000 4000

Hours

Delt

a Y

I

0

5

10

15

20

25

0 2000 4000

HoursH

aze (

%)

Lexan* UV PC resin

Lexan* SLX resin T3 (SLXxy7zT)

ISO-4892-2A protocol~1800 hours = 1 yr Florida exposure

This information should be used as indicative only. The true performance can only be determined under conditions as in the final application.

# Optical data shown in presentation apply to transparent materials.

22

Lexan* SLX vs. UV Stabilised PC Resin –transparent colors –

Modified G26 protocol3000 kJ/m2 = ~1 year Florida exposure

Ductile

Brittle

0

20

40

60

80

0 10000 20000 30000

Exposure energy (kJ/m2)

Impact Energy (J)

Lexan SLX25x1T

Lexan* UV-stab

PC resin

This information should be used as indicative only. The true performance can only be determined under conditions as in the final application.

Xenon Arc Exposure

Lexan SLX Resin: Better Retention of Colour, Transparency, Ductility than standard UV PC Resin

23

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THE MATERIALS, PRODUCTS AND SERVICES OF SABIC INNOVATIVE PLASTICS HOLDING BV, ITS SUBSIDIARIES AND AFFILIATES (“SELLER”), ARE SOLD SUBJECT TO SELLER’S STANDARD CONDITIONS OF SALE, WHICH CAN BE FOUND AT http://www.sabic-ip.comAND ARE AVAILABLE UPON REQUEST. ALTHOUGH ANY INFORMATION OR RECOMMENDATION CONTAINED HEREIN IS GIVEN IN GOOD FAITH, SELLER MAKES NO WARRANTY OR GUARANTEE, EXPRESS OR IMPLIED, (i) THAT THE RESULTS DESCRIBED HEREIN WILL BE OBTAINED UNDER END-USE CONDITIONS, OR (ii) AS TO THE EFFECTIVENESS OR SAFETY OF ANY DESIGN INCORPORATING SELLER’S PRODUCTS, SERVICES OR RECOMMENDATIONS. EXCEPT AS PROVIDED IN SELLER’S STANDARD CONDITIONS OF SALE, SELLER SHALL NOT BE RESPONSIBLE FOR ANY LOSS RESULTING FROM ANY USE OF ITS PRODUCTS OR SERVICES DESCRIBED HEREIN. Each user is responsible for making its own determination as to the suitability of Seller’s products, services or recommendations for the user’s particular use through appropriate end-use testing and analysis. Nothing in any document or oral statement shall be deemed to alter or waive any provision of Seller’s Standard Conditions of Sale or this Disclaimer, unless it is specifically agreed to in a writing signed by Seller. No statement by Seller concerning a possible use of any product, service or design is intended, or should be construed, to grant any license under any patent or other intellectual property right of Seller or as a recommendation for the use of such product, service or design in a manner that infringes any patent or other intellectual property right.

SABIC Innovative Plastics is a trademark of Sabic Holding Europe BV


Disclaimer

Documents

Challenges in the Electrical and Lighting Market final in the Electrical and... · Now a Strategic Business Unit of SABIC ... Potential Thermal Management solution ... Optical Properties