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®CBS 20 STANWIX STREET, 10TM FLOOR
Pll-I’SBURGH, PENNSYLVANIA 15222
November 23, 2015
To: DISTRIBUTION
Dorothy M. Alke ¯ Vice President, Environmental Projects
¯ 412.642.2562 Telephone
412.642.3014 Fax
Re-" First Quarter 2014 Groundwater.Investigation Plan for Operable Unit 2 Bennett’s Dump, Bloomington, Monroe County, Indiana
1.0 BACKGROUND
This report summarizes the results of groundwater, surface water, flow and water level monitoring work completed by CBS Corporation during the first quarter of 2014 at the Bennett’s Dump site. The work was performed for the purpose of assessing the feasibility of capturing PCB-contaminated shallow groundwater and to support the engineering design of an effective capture and treat system.
Monitoring activities in accordance with the December 2009 Final Bennett’s Dump Groundwater Investigation Plan for Operable Unit 2 (GWIP) were performed at surface water and groundwater locations including test pits, quarries, piezometers, monitoring wells, springs and streams as¯ summarized in Table 1.
The Bennett’s Dump Groundwater Investigation Plan comprises different monitoring schemes for the periods before and after construction of the Passive Quarry Drain. Pre-quarry drain construction monitoring activities were performed until completion of the quarry drain at the beginning of September 2010. The post-quarry drain monitoring program includes all of the locations and monitoring requirements .formerly prescribed by the Long Term Groundwater Monitoring Plan (LTGMP). Therefore, quarterly reporting under the GWIP will replace LTGMP reporting, pending the development and approval of a final LTGMP.
In November 2013, an Infiltration Galley for the recovery of shallow groundwater was installed in Bennett’s Dump site grid B13, as shown on Figure 1. A dry-season pilot test was conducted November 5-11, 2013 to evaluate the infiltration gallery’s potential for reducing migration of PCBs from the site into Stout’s Creek in the area downstream from Middle Spring. This was the initial stage of such testing. Results of the November 2013 initial stage pilot test were distributed by email to the parties on January 7, 2014.
November 23, 2015 Page 2
An extended, wet-season pilot test of the Infiltration Gallery was in preparation during March 2014, including baseline sampling at Stout’s Creek segment stations. Those activities are to be reported separately and are not included in this report.
2.0 SURFACE WATER MONITORING
The monitoring work described in this report was performed during January - March, 2014. This three month period constituted the first reporting quarter of 2014 for the Bennett’s Dump site.
Scope of Work
The scope of water sampling for January-MarCh 2014 comprised collecting samples at Stout’s Creek Upstream and Downstream stations, Middle Spring, Rusty Spring and Icebox Quarry. North Spring, Mid-North Spring and Mound Spring were not observed flowing during the first quarter.
Sample Collection and Handling
Samples at the spring and stream locations were collected by carefully filling a new disposable beaker. The water was transferred from the beaker into pre-cleaned amber glass 1-1iter bottles supplied by the analytical laboratory. Routine sampling parameters including temperature and conductivity were measured and recorded.
Samples were analyzed by Pace Analytical Lab of Indianapolis, Indiana. The samples were analyzed to a detection limit of 0.1 parts per billion (ppb) for all PCB parameters by EPA SW-846 method 8082. Beginning in April 2011, Stout’s Creek Downstream samples are analyzed to a detection limit of 0.01 ppb. Samples were also analyzed for total suspended solids (TSS) by method SM2540 D.
Quality Assurance
For quality assurance purposes a duplicate sample and a field blank were collected during each sampling event. All environmental and blank samples were labeled and logged onto a chain of custody form. The samples were stored and transported on ice in insulated coolers. Custody of the water samples was maintained by CBS until shipment to the analytical laboratory.
The field blank sample for 2014 first quarter GWI sampling was BD10770. PCBs were not detected in this sample.
Analgtical Results for Surface Water Samples
Field parameter measurements, PCB analytical results, and QA/QC results for surface water samples collected during this reporting period are reported in Tables 2 through 9. Each table summarizes historical groundwater monitoring data collected since the completion of Passive Quarry Drain in September 2010.
November 23, 2015 Page 3
Copies .of the chain of custody forms are provided in Appendix A. Copies of the certificates of analysis are provided in Appendix B. A validation summary for these samples appears in Appendix C. Copies of the field sampling data sheets are on file at PSARA’s Bloomington Branch Office.
3.0 FLOW AND WATER LEVEL MONITORING
The purpose of flow and water level monitoring is to evaluate site-specific data characterizing site hydrologic response under storm and non-storm conditions, and to evaluate correlations between PCB concentrations, spring flow and groundwater elevations. The goals are to assess the feasibility and support the engineering design of a system to capture and treat Middle Spring flows and nearby shallow groundwater.
Scope of Work
The scope of groundwater level and flow monitoring during this reporting period involved numerous manual measurements and observations, as well as the use of dedicated instrumentation to record water level and other parameters as summarized in Table 10. The instrument at Mound Spring was removed in the third quarter 2012, during an extended dry period, and will be re- installed if adequate .flow resumes.
The approximate locations of the stations are shown on Figure 1.
Flow and Water Level Plots
Middle Spring flowed throughout the first quarter. Mound Spring was not observed to flow during the January-March period. Therefore there are no plots of Mound Spring flow. Manual observations made at Mound Spring during the first quarter were added to the plots of Middle Spring flow.
Flow observations at on-site springs also are presented in Table 11. An Excel spreadsheet file, including water level and flow observation data, accompanies this report as an attached file: BD GWIP Water Level Observations with plots - Q1 2014.xlsx.
Quality Assurance
An instrument maintenance log for the Bennett’s Dump installations is provided in Appendix D. This log details the installation, re-indexing, and maintenance histories of the data logging equipment present at Bennett’s Dump during the reporting quarter.
November 23, 2015 Page 4
Crest Gauges
The purpose of the crest gauges at Middle Spring and Mound Spring is to provide an indication of maximum flow during each reporting period. Maximum recorded water levels and flows estimated from these data are presented in the instrument maintenance log in Appendix D. Manual observations during the First quarter are presented in Table 11. Mound Spring observations are :included on the Middle Spring flow plots.
Potentiometric Data
Potentiometric contours shown on Figure 1 were developed based on water level measurements taken on March 18, 2014. The specific water level measurement locations are listed in the table :insert on Figure 1.
If you have questions regarding the sampling and flow/water level monitoring activities or findings for this reporting period, please call Neill Vaughan at (812) 335-0424.
BP:15-(
Attachments
DISTRIBUTION Tom Alcamo, USEPA Region 5 Douglas Petroff, IDEM Simeon Baker, MCHD
CC:
John Langley, CBU Jeff Lifka, Tetra Tech John Bassett, AECOM Russ Cepko, CBS Mike Hessling, PSARA Patrick Kneip, PSARA Neill Vaughan, PSARA BP Files
List of Tables
1. Groundwater Investigation Plan Monitoring Requirements and Recommended Interim Plan
3.
4.
5.
6.
7.
8.
o
10.
11.
12.
Requirements
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Post-Quarry Drain PCB Results,
Icebox Quarry Water Samples
Stout’s Creek Upstream
Stout’s Creek Downstream
Mound Spring
Rusty Spring
Middle Spring
Mid-North Spring
Post-Quarry Drain PCB Results, North Spring
Flow and Water Level Monitoring, GWIP Stations
Flow Observations, On-Site Springs
Instrument Maintenance Log (Appendix D)
List of Figures and Plots
Figure 1 - Site Map with Monitoring and Sampling Locations, Potentiometric Surface Contours
Continuous Monitoring Plots Middle Spring Continuous Flow and Mound Spring Flow Observations, January 2014 Middle Spring Continuous Flow and Mound Spring Flow Observations, February 2014 Middle Spring Continuous Flow and Mound Spring Flow Observations, March 2014
Manual Monitoring Plots Bennett’s Dump On-Site Springs Flow and Rain, January 1 to March 31, 2014
Stout’s Creek Downstream Flow and Rain, January 1 to March 31, 2014 Bennett’s Dump Quarries and Pits, Observed Water Levels Bennett’s Dump Monitoring Wells, Observed Water Levels Bennett’s Dump Piezometers, Observed Water Levels
TABLES
Table 1. Groundwater Investigation Plan Monitoring Requirements
and Recommended Interim Plan Requirements
Bennett’s Dump, Bloomington, Monroe County, Indiana
Station
Middle Spring
Mound Spring
Middle Spring
Mound Spring
Rusty Spdng
Stout’s Creek Downstream
Stout’s Creek Upstream
North Spring
Mid-North Spring
Wedge Quan’y
Wedge South Quar~
Test Pit A
Test Pits 1,2,3,and 4
Downstream Quarry Drain
Outlet
Wedge Quarry
Icebox Quarry
Wedge Quarry
Wedge South Quan’y
Icebox Quarry
Test Pit A
Test Pit 4
PZ-H7
PZ-K9SW
PZ-I 11
PZ-LM5
MW-BC-10
MW-B 13
MW-C5
MW-C4A
MW-C3A
MW-I
MW-3
1VF~-6I
MW-6D
1 Frequency
2 weeks prior to drain construction
12 months after drain construction
Monthly after drain construction
or episodic so 12 samples collected
Every 2 weeks after drain construction"
Monthly after drain construction
Pre-drain construction - every rain event
Pnst-Drain construction - 5 rain events
Post-drain construction - 5 rain events
Once pre-drain c~nstruction.
After drain construction, if PCBs found
in downstream drain outlet then
individual components monthly
Monthly after drain construction
Every 2 weeks after drain construction
After one storm >I"
Quarterly after drain construction
Every 2 weeks before drain construction,
Monthly after drain construction
Every 2 weeks before drain construction,
Monthly after drain construction
Water Level or Flow
Measurement
¯ Hourly logging of flow, at V-notch weir
V-notch or visual flow estimate
Flow by velocity probe
Flow by velocity probe
Visual tlow estimate
V-notch or visual flow estimate
Water level
Weir, velocity probe or visual flow
estimation, depending upon
conditions
Hourly water level
Water level
Water level
Water level
Sample2
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
PCBs and TSS
Frequency of monitoring and sampling is quarterly, unless amended by approved Scopes of Work for other GWIP activities.
At time of PCB sample collection, also measure field parameters of conductivity and temperature. 3 Previous Interim recommendations anticipated the March 2012 pumping test and a follow-up pumping test, performed in March-April 2013.
Note: All monitoring requirements subject to change when a final revised LTGMP is developed.
3 Interim Recommendations
Continue Hourly logging
of flow
Monthly samples until test
starts then follow test schedule
Continue this schedule until test
starts, then follow test schedule.
Continue to Sample
Continue to Sample
Discontinue until LTGMON
Discontinue until LTGMON
Continue on monthly schedule
Discontinue until LTGMON
Continue
Continue this schedule
but only with Icebox and PZ-H7
Continue this schedule until test
starts then follow test schedule
but with additional wells and
piezorueters to be determined by
agreement and relevance to
each test.
Table 2. Post-Quarry Drain PCB Results Icebox Quarry
Bennett’s Dump, Bloomington, Indiana
Sampling PCBa, Data TSS, Conductivity, Temperature,
Sample ID Date ppb Validated? mg/L uS/cm °C
BD10772 18-Mar-14 < 0.10 Y < 1 215 6.3
BD10759 27-Dec-13 0.11 Y 3 213 4.2
BDI0679 17-Sep-13 < 0.10 Y 2 217 23
BD10625 13-Jun-13 < 0.10 Y 1 218 25.1
BD10500 19-Mar-13 < 0.10 Y 1 230 5.4
BD10439 19-Dee-12 < 0.10 Y 2 250 7.1
BD10425 20-Sep-12 < 0.10 Y < 1 241 21.9
BD10406 14-Jun-12 < 0.10 Y 1 263 20
BD10371 15-Mar-12 < 0.10 Y < 1 NR NR
BD10337 19-Dec-11 < 0.10 Y 1 264 7.1
BD10308 01-Sep-11 < 0.10 Y < 1 235 26.6
BD10301 17-Aug-ll < 0.10 Y 3 247 26.6
BD10302 17-Aug-11 < 0.10 Y 1 247 26.6
BD10300 30-Jul-ll <0.10 Y 9 231 31.1
BD10294 07-Jul-11 < 0.10. Y < 1 232 28
BD 10292 22-Jun- 11 < 0.10 Y 1 235 25.9
BD10283 31-May-ll < 0.10 Y 6 239 27.5
BD10236 02-Mar-11 < 0.10 Y < 1 250 6.6
BD10208 27-Oct-10 < 0.10 Y < 1 282 17.4
"Samples were analyzed to a detection limit of 0.1 parts per billion (ppb).
Table 3. Post-Quarry Drain PCB Results
Stout’s Creek Upstream
Bennett’s Dump, Bloomington, Indiana
Sample ID
BD10769
BD10682
BD10668
BD10640
BD10628
BD10618
BD10458
BD 10452
BD 10447
BD10436
BD 10432
BD 10428
BDI0423
BD10419
BD10414
BD10409
BD10401
BD10394
BD 10387
BD10380
BD10374
BD10368
BD10363
BD10355
BD 10349
BDI0341
BD10331
BD1032!
BD10315
BD10316(dup)
BD10315
BD 10316 (dup)
BD10312
BDI0305
BD10306 (dup)
BD10296
BD10285
BD 10277
BD10267
continued
Sampling
Date
18-Mar-14
28-Oct-13
19-Aug-13
15-Aug-13
29-Ju1-13
23-Apt-13
4-Mar- 13
25-Feb- 13
23-Jan- 13
12-Dec-12
16-Nov- 12
10-Oct-12
12-Sep-12
15-Aug-12
PCB~, Data TSS, Conductivity,
ppb
<o.01
<0.01
<0.01
<0.01
<0.01
< 0.01
< 0.Ol
<0.01
<0.01
<0.01
<0.01
<O.Ol
<0.01
<0.01
Validated?
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
mg/~
8
4
3
2
2
1
4
4
1
4
<1
4
2
3
uS/cm
672
472
479
499
539
634
690
719
651
586
573
619
597
493
Temperature,
oC
6
14.8
19.8
19.8
19.2
11.5
5.8
7.0
6.5
8.9
lO.8
14.9
20.2
22.6
19.9
17.4
17.9
14.2
13.7
13.3
12.5
12.3
9.9
8.4
7.6
7.0
9.3
12.9
16.6
I6.6
16.6
16.6
16.7
23.8
23.8
24.0
19.3
15.o
13.8
12-Jul-12
14-Jun-12
16-May-12
18-Apr- 12
02-Apr-12
27-Mar-12
19-Mar-12
15-Mar-12
12-Mar-12
05-Mar-12
20-Feb-12
25-Jan- 12
12-Dec-I I
11-Nov-11
12-Oct-11
12-Oct-I 1
12-Oct-11
12-Oct-11
15-Sep-11
18-Aug-11
18-Aug- 11
29-Jul-11
22-Jun-11
19-May- 11
05-May-11
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.01
<0.10
<0.01
<0.10
<0.I0
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
<0.10
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
<1 514
1 504
2 544
2 607
3 596
3 627
6 607
11 617
< 1 644
< 1 591
2 661
2 640
2 619
3 610
1 542
1 542
1 542
1 542
1 523
3 529
11 529
3 539
5 568
4 584
10 520
Flowb,
gaUmin
600
157
125
133
465
I2OO
620
530
51o
430
400
350
183
200
250
lOO
500
830
5o0
625
475
500
700
350
525
1450
720
380
14o
140
14o
140
70
100
100
lO6
630
565
2500
Table 3. Post-Quarry Drain PCB Results
Stout’s Creek Upstream
Bennett’s Dump, Bloomington, Indiana
Sample ID
BD 10255
BD 10245
BD10237
BD10227
BDI0217
BD 10218 (dup)
BD10213
BDI0207
BD 10202
Sampling
Date
14-Apr-ll
18-Mar-11
02-Mar-11
26-Jan-11
21-Dec-10
21-Dec-10
22-Nov-10
27-Oct-10
30-Sep-10
PCBa,
ppb
<0.10
<0.10
<0.10
<0.10
<0.10R
<0.10R
<0.10
<0.I0
<0.10
Data TSS, Conductivity,
Validated? mg/L uS/cm
Y 21 581
Y 17 661
Y 91 693
Y 4 785
Y 3 NR
Y 4 NR
Y 5 627
Y 4 655
Y 3 643
aSamples were analyzed to a detection limit of 0.01 parts per billion (ppb). Samples collected before 2012
were analyzed to a detection limit of 0.1 parts per billion (ppb).
bFlow estimate calculated from a set of flow velocity measurements.
R = Unusable; QA/QC data indicated significant deficiencies in the analytical data.
Temperature,
°C
12.5
9.2
7.7
4.6
6.2
6.2
14.5
18.0
21.7
Flowb,
gal/min
1200
8OO
1500
275
262
262
120
52
25
Table 4. Post-Quarry Drain PCB Results
Stout’s Creek Downstream
Bennett’s Dump, Bloomington, Indiana
Sample ID
BDI0767
BD10768b
BD10680
BD10681b
BD10626
BD 10627~
BDI0616
BD10617
BD10609
BDI0456
BD 10457b
BD10450
BDI0451~
BD10445
BD 10446b
BDI0434
BD 10435b
BD 10430
BDI0431~
BD 10426
BD 10427b
BDI0421
BD 10422b
BD10417
BD10418~
BD10416
BD10412
BD10413b
BD10411
BD 10407
BD10408~
BD10405
BD10399
~3~)1o4oob
BD10398
BD 10392
BD 10393~
BD10385
BD10386~
continued
Sampling
Date
18-Mar-14
18-Mar-14
28-Oct-13
28-Oct-13
29-Ju1-13
29-Ju1-13
23-Apr-13
23-Apr-13
22-Apr- 13
4-Mar-13
4-Mar- 13
25-Feb-13
25-Feb-13
23-Jan-13
23-Jan- 13
12-Dec-12
12-Dec-12
16-Nov-12
16-Nov-12
10-Oct-12
10-Oct-12
12-Sep-12
12-Sep-12
15-Aug-12
15-Aug-12
24-Ju1-12
I2-Jul-12
12-Jul-12
27-Jun-12
14-Jun-12
14-Jun-12
30-May-12
16-May-12
16-May-12
04-May- 12
18-Apr- 12
18-Apr- 12
02-Apt-12
02-Apr- 12
PCBa, Data TSS, Conductivity,
ppb
0.092
0.086
0.085
0.075
0.11
0.11
0.067
0.092
0.14
0.062
0.073
0.067
0.082
0.073 J
< 0.01 J
0.03
0.03
0.047
0.046
0.032
0.027
0.040
0.031
0.097
0.086
0.061
0.058
0.051
0.024
0.11
0.11
0.11
0.081
0.094
0.033
0.046
0.064
0.045
0.055
Validated?
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
mg/L
1
1
<I
1
3
3
2
2
4
2
3
2
2
1
2
2
2
-1
<1
2
2
I
1
<1
2
1
I
I
<1
2
3
I
2
2
<1
1
1
<1
<1
uS/cm
654
654
472
472
538
538
610
610
619
685
685
709
709
645
645 ~ i
570
570
569
569
614
614
569
569
497
497
486
509
509
490
509
509
522
547
547
581
850
608
594
594
Temperature,
°C
5.7
5.7
14.1
14.1
18.7
18.7
12.2
12.2
12.8
5.4
5.4
7,8
7.8
6.2
6.2
8.2
8.2
9.7
9.7
14.6
14.6
19.7
19.7
20
20
22.3
19.1
19.1
17.8
16.1
16.1
18.4
18.5
18.5
15.3
14.7
14.7
13.1
13.1
Flowe,
gagmin
600
6oo
157
157-
465
465
12oo
12oo
1475
620
620
530
530
51o
51o
430
430
400
400
350
350
200
200
2o0
200
270
250
250
16o
1oo
lOO
200
500
500
1000
850
850
500
5O0
Table 4. Post-Quarry Drain PCB Results
Stout’s Creek Downstream
Bennett’s Dump, Bloomington, Indiana
Sample ID
BD10384
BD10379
BD10378
BD10373
BD10366
BD10367b
BD10362
BD10361
BD10354
BD10348
BDI0347
BD 10340
BD10338
BD10330
BD10325
BD10320
BD10319
BDI0314
BD10319
BD10314
BD10313
BD10309
BDI0310b
BD10307
BD10303
BDI0295
BDI0293
BDI0287
BD10284
BD10279
BD10269
BD10270b
BD10252
BD10253b
BD10248
BD10248
BD 10242
BD10243b
BD10232
continued
Sampling PCBa, Data Date ppb Validated?
30-Mar-12
27-Mar- 12
22-Mar- 12
19-Mar-12
15-Mar-12
15-Mar-12
12-Mar-12
09-Mar-12
05-Mar-12
20-Feb- 12
07-Feb- 12
25-Jan- 12
05-Jan-12
12-Dec-11
02-Dec-11
11-Nov-11
25-Oct-11
12-Oct-11
25-Oct-11
12-Oct-11
30-Sep-11
15-Sep-11
15-Sep-11
0.069
0.046
0.038
0.062
0.032
0.030
0.038
0.042
0.089
0.II
0.11
0.036
0.052
0.038
0.081
0.097
0.067
0.063
0.067
0.063
0.063
0.093
0.081
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
TSS, Conductivity,
uS/cm
<1
<1
2
I
2
2
2
3
<I
1
2
2
<1
2
3
<1
<1
<I
<I
<1
6
2
2
607
614
581
597
623
623
642
657
589
650
629
636
628
614
628
607
623
544
623
544
614
524
524
Temperature, oC
12.6
14.6
13.2
14.3
13.1
13.1
10.4
9.6
9.0
8.2
8.3
6.8
8.5
9.5
10.7
12.7
16.2
16.4
16.2
16.4
16.4
14.9
14.9
01-Sep-11
18-Aug-11
29-Jul- 11
07-Jul-11
22-Jun-I 1
03-Jun-I I
19-Ma~-I 1
05-Ma)’-I 1
05-Ma~-I 1
14-Apr-11
14-Apr-11
3 l-Mar- 11
31-Mar- 11
18-Mar- 11
18-Mar- 11
02-Mar-11
0.068
0.031
0.13
0.097
0.044
Y
Y
Y
Y
Y
1
<1
2
1
4
523
526
532
535
566
0.085
0.095
<0.I0 R
<0.10 R
0.049
0.050
<0.10
<0.10
<0.I0
<0.I0
<0.10R
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
4
2
9
10
14
14
4
4
13
12
57
568
580
510
510 "
571
571
662
662
656
656
693
20.5
24.2
23.1
20.1
20.1
19.2
15.4
14.5
14.5
13.2
13.2
11.3
11.3
9.3
9.3
7.7
Flowe, gal/min
47O
625
45O
475
5OO
5OO
7O0
94O
35O
53O
97O
1550
66O
840 .
1600
38O
350 .
140
35O
140
350
57
57
55
95
85
275
59O
307
58O
2600
2600
1215
1215
326
326
800
8OO
1500
Table 4. Post-Quarry Drain PCB Results
Stout’s Creek Downstream
Bennett’s Dump, Bloomington, Indiana
Sample ID
BDI0233b
BD 10229
BD 10223
BD 10224b
BD 10222
BD10216
BD10214
BD10210
BD10211b
BD10209
BD10204
BD 10205b
BDI0203
BD10199
BD10200b
BD10198
aSamples were anal’
Sampling Date
02-Mar-11
09-Feb-11
26-Jan-I 1
26-Jan-I I
06-Jan-11
21-Dec-10
09-Dec-10
22-Nov- 10
22-Nov-10
10-Nov-10
27-Oct-I 0
27-Oct- 10
13-Oct-10
30-Sep-10
30-Sep-10
14-Sep-10
PCBa, Data
ppb Validated?
0.14 Y
<0.10 R Y
<0.10R Y
<0.10R Y
<0.10R Y
<0.10R Y
0.11 J Y
0.31K Y
0.26 K Y
< 0.37 K Y
< 0.55 K Y
< 0.55 K Y
0.16K Y
0.30 K Y
0.28 K Y
0.55 K Y
~ed to a detection limit of 0.01 parts per billion (ppb).
TSS, Conductivity, mg/L uS/cm
58 693
3 924
2 768
2 768
4 780
2 793
5 677
5 621
4 621
2 601
2 651
2 651
7 625
6 641
7 641
21 650
Samples collected before 2012
were analyzed to a detection limit of 0.1 parts per billion (ppb).
~Duplicate sample.
CFlow estimate calculated fyom a set of flow velocity measurements.
NR = Not reported.
J = Estimated value. The QA/QC data indicated an analytical bias.
K = Estimated value due to QA blank contamination
R = Unusable; QA/QC data indicated significant deficiencies in the analytical data.
Temperature,
OC
7.7
4.1
4.6
4.6
5.9
6.0
7.5
14.9
14.9
8.8
16.8
16.8
18.6
17.5
17.5
20.1
Flowe,
gal/min
1500
475
290
290
605
224
270
110
110
72
46
46
19
17
17
21
Table 5. Post-Quarry Drain PCB Results
Mound Spring
Bennett’s Dump, Bloomington, Indiana
Sample ID
NA
BD10760
NA
BDI0615
BD10602a
NA
NA
BD 10440
NA
NA
NA
NA
NA
NA
NA
NA
BD10343
NA
NA
NA
NA
NA
NA
NA
BD 10272
BDI0263
BD10261
BD10257
BD 10250
NA
BD 10240
NA
NA
NA
NA
NA
NA
PCBa,
Sampling Date ppb
18-Mar-14 -
27-Dec-13 0.51
29-Ju1-13 -
22-Apr- 13 0.57
19-Apr- 13 0.43
04-Mar- 13 -
25-Feb- 13 -
14-Jan- 13 0.66
12-Dec-12 -
16-Nov-12 -
10-Oct-12 -
12-Sep-12 -
15-Aug-I 2 -
07-Jul-12 -
15-Mar-12 -
20-Feb- 12 -
25-Jan-12 0.35
12-Dec-11 -
17-Nov-11 -
12-Oct-I 1 -
15-Sep-I I -
18-Aug-I I -
29-Jul-11 -
22-Jun-11 -
05-May-I 1 0.72
25-Apr-I 1 0.99
20-Apr-11 0.82
14-Apr-11 0.53
12-Apr-I I 0.56
18-Mar- 11 -
07-Mar-11 .0.58
02-Mar-11 -
26-Jan-I 1 -
21-Dec-10 -
22-Nov- l 0 -
27-Oct-10 -
30-Sep-10 -
Data TSS,
Validated? mg!L
Y 1
Y <1
Y 3
Y 1
Y <1
Y <1
Y <1
Y I
Y <1
Y 1
Y 2
~arts per billion (ppb).
Conductivity, uS/cm
470
521
717
496
630
471
457
505
511
518
520
Samples were analyzed to a detection limit of 0.1
~Flow estimated using V-notch weir, unless otherwise noted.
¢Flow estimated visually.
dSample collected post-storm, since Mound Sp. now flows only in ephemeral, very wet conditions.
NR = Not reported.
Temperature,
oC
9.9
14.7
8.7
8.6
6.5
12.7
" 10.9
9.9
16.2
9.8
8.9
Flowb,
gal/min
0.4
DRY
1
3
DRY
DRY
6.8
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
0.25
DRY
DRY
DRY
DRY
DRY
DRY
DRY
13,4
29
18
0.4
12
DRY
2e
DRY
DRY
DRY
DRY
DRY
DRY
Table 6. Post-Quarry Drain PCB Results
Rusty Spring Bennett’s Dump, Bloomington, Indiana
Sample ID
BD10773
NA
NA
NA
BD10461
NA
NA
NA
NA
NA
NA
NA
NA
BD10~9
BD 10~ $2
BD10~46
BD10~6
BD 10~28
NA
NA
NA
NA
NA
BDI0291
BD 10274
NA
NA
BD10241
NA
NA
NA
NA
NA
NA
Sampling Date
18-Mar-14
28-Oct-13
29-Ju1-13
22-Apr-13
04-Mar-I 3
25-Feb-I 3
23 -Jan- 13
12-Dec-12
16-Nov-12
10-Oct-12
12-Sep-12
15-Aug-12
07-Jul-12
05-Mar-12
20-Feb-12
25-Jan-12
12-Dec-11
06-Dec-11
12-Oct-I 1
12-Oct-I 1
15-Sep-I 1
18-Aug-11
29-Jul-11
22-Jun-I 1
05-May-I I
14-Apr-I 1
18-Mar-11
07-Mar- 11
02-Mar-11
26-Jan-11
21-Dec-10
22-Nov- 10
27-Oct- 10
30-Sep-10
PCBa,
ppb
2.9
4.2
4.5
3.3
3.8
4.0
4.6
6.2
3.5
3.5
Data
Validated?
¥
Y
Y
Y
Y
Y
Y
Y
Y
Y
TSS, mg/L
160
6
10
<1
2
1
2
Conductivity,
uS/cm
567
692
672
672
710
756
778
623
538
628
Temperature,
oC
6,8
9.5
8.6
8.6
9.1
12.0
11.4
16.0
11.6
7.9
Flowb,
gal!min
0.4
DRY
DRY
DRY
0.1
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
0.5
0.3
1.5
1.5
2.5
DRY
DRY
DRY
DRY
DRY
1.5
7
DRY
DRY
3
DRY
DRY
DRY
DRY
DRY
DRY
Samples were analyzed to a detection limit of 0.1 parts per billion (ppb).
bFlow estimated visually.
J = Estimated value. The QA/QC data indicated an analytical bias.
Table 7. Post-Quarry Drain PCB Results
Middle Spring
Bennett’s Dump, Bloomington, Indiana
Sample ID
BI)10771
BD 10731
BD 10629
BD10624
BD10614
BD10460
BD10454
BD10449
NA
NA
NA
NA
NA
NA
BD10382
BD10376
BD10370
BD10364
BD10360
BD10356
BD10357 (dup)
BD10350
BD10351 (dup)
BD10344
BD10345 (dup)
BDI0333
BD10334 (dup)
BD10327
NA
NA
NA
NA
NA
BD10288
BD10289 (dup)
BD10281
BD10282 (dup)
BD 10273
BD10258
continued
Sampling Date
18-Mar-14
8-Nov- 13
29-Jul- 13
23-Apt-13
22-Apr-13
4-Mar-13
25-Feb- 13
23 -Jan- 13
12-Dec-12
16-Nov-12
10-Oct-12
12-Sep-12
15-Aug-12
07-JuM2
27-Mar-12
19-Mar-12
15-Mar-12
12-Mar- 12
06-Mar-12
05-Mar- 12
05-Mar- 12
20-Feb- 12
20-Feb- 12
25-Jan-12
25-Jan-12
, 12-Dec-11
12-Dec- 11
06-Dec-I 1
17-Nov-11
12-Oct-11
15-Sep-11
18-Aug-11
29-Jul-11
22-Jun-11
22-Jun-I 1
19-May-I 1
19-May-I 1
05-May-11
14-Apr-11
PCBa,
ppb
4.3
2.0
5.4
4.6
4.3
4.6
4.6
5.8
3.0
3.5
3.8
4.6
3.6
4.2
4.2
4.2
4.4
4.8
4.7
6.4
6.6
7.7
4.8
4.6
4.5
4.8
4.8
4.4
Data
Validated?
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
y .
Y
Y
Y
Y
Y
Y
Y
Y
Y
TSS,
mg/L
1
<1
<1
1
<1
<1
<1
5
2
1
1
2
<1
1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
<1
1
<1
Conductivity,
uS/cm
474
570
515
534
533
585
560
595
563
573
569
564
576
579
579
577
577
584
584
594
594
618
515
515
470
470
405
486
Temperature,
deg C
~ 8.1
lO.2
15.1
10.5
11
9.3
10.0
10.3
14.3
18.8
16.3
13.4
10.2
10.6
10.6
10.I
10.I
10.8
10:8
12.2
12.2
12.7
15.3
15.3
13.2
13.2
13.7
11.6
Flowb,
gal/min
3.4
0.l
5
8.3
9
6.4
2.3
4
DRY
DRY
DRy
DRY
DRY
DRY
0.1
NR
0.3
16
0.1
1.9
1.9
4
4
10.5
10.5
6
6
12
DRY
DRY
DRY
DRY
DRY
4
4
4
4
16
12
Table 7. Post-Quarry Drain PCB Results
Middle Spring
Bennett’s Dump, Bloomington, Indiana
Sample ID
BDI0247
BD10235
BD10226
BD 10221
NA
NA
NA
NA
Samples were anal’
bFlow estimated usin
Sampling Date
18-Mar- 11
02-Mar- 11
26-Jan-I 1
28-Dec- 10
21 -Dec- 10
22-Nov-10
27-Oct-10
30-Sep-10
PCBa, Data
ppb Validated?
6.0 Y
9.1 Y
9.2 Y
8.1 Y
,zed to a detection limit of 0.1 parts per billion (ppb.
V-notch weir, unless otherwise noted.
TSS, mg/L
<1
<I
<1
<1
Conductivity,
uS/cm
506
542
583
NR
Temperature,
deg C
10.5
9.4
9.6
Flowb,
gal/min
8.3
10.5
2.3
0.5
DRY
DRY
DRY
DRY
Table 8. Post-Quarry Drain PCB Results
Mid-North Spring
Bennett’s Dump, Bloomington, Indiana
Sample ID
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
BD10275
BD10266
BDI0265
BDI0262
BD10259
NA
NA
NA
NA
NA
NA
NA
Sampling Date
18-Mar-14
28-Oct-13
29-Ju1-13
23-Apr-13
4-Mar-13
25-Feb-13
23-Jan-13
12-Dec-12
16-Nov-12
10-Oct-12
12-Sep-12
15 -Aug- 12
07-Jul-12
15-Mar-12
20-Feb-12
25-Jan-12
12-Dec- 11
17-Nov- 11
12-Oct-11
15-Sep-i i
18-Aug- 11
29-Jul-11
22-Jun-11
05-May-11
03-May-I 1
27-Apr- 11
25 -Apr- 11
20-Apt- 1 l
18-Mar- 11
02-Mar- 11
26-Jan-11
21-Dec-10
22-Nov-10
27-Oct- 10
30-Sep-10
PCBa,
ppb
0.45
0.41
0.25
0.38
0.21
Data TSS, mgn
8
1
2
"4
3
Conductivity, Temperature,
°C
15.4
14.8
14.9
13.8
10.9
Validated?
Y
Y
Y
Y
Y
uS/cm
273
297
277
284
341
Samples were analyzed to a detection limit of 0.1 parts per billion (ppb).
bFlow estimated using V-notch weir.
CFIow estimated visually.
Flow,
gal/min
I)RY
DRY
DRY
DRY
DRY
DRY
DRY
DRY¢
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
3.5b
2~
4.5b
0.2b
DRY
DRY
DRY
DRY
DRY
DRY
DRY
Table 9. Post-Quarry Drain PCB Results
North Spring
Bennett’s Dump, Bloomington, Indiana
Sample ID
NA
NA
NA
BD 10601
BDI0493
BD 10455
BD10441
NA
NA
NA
NA
NA
NA
NA
NA
BD10339
NA
BD10326
NA
NA
NA
NA
NA
NA
BD 10276
BD 10264
BD 10260
BD10251
BD 10249
NA
BD10239
NA
BDI0231
BD 10230
NA
NA
NA
NA
NA
Sampling Date
18-Mar-14
28-Oct-13
29-Jul- l 3
19-Apr-13
18-Mar-13
27-Feb-l 3
14-Jan-13
I2-Dec-12
16-Nov-12
10-Oct-12
12-Sep-12
15-Aug-12
07-Jul-12
15-Mar-12
20-Feb-12
19-Jan-12
12-Dec-1 I
06-Dec-11
17-Nov-11
12-Oct-11
15-Sep-11
18-Aug-I 1
29-Jul-11
22-Jun-11
05-May-I I
25-Apr-I 1
20-Apr-I 1
12-Apr- 11
05-Apr-I 1
18-Mar-11
07-Mar- 11
02-Mar-11
28-Feb-11
22-Feb-11
26-Jan-11
21-Dec-10
22-Nov- 10
27-Oct- 10
30-Sep-I0
PCBa,
ppb
4
6.5
6.1
4.9
4.8
5.5
4.0
5.2
5.7
5.6
4.9
6.9
6.0
6.1
Data
Validated?
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Samples were analyzed to a detection limit of 0.1 parts per billion (ppb).
bFlow estimated visually.
TSS,
mg/L
8
13
8
2
3
8
7
4
7
5
13
4
7
2
Conductivity,
uS/cm
507
522
559
595
583
614
442
43l
422
447
458
452
482
475
Temperature,
oC
9.8
7.7
7.8
8.9
9.9
11.8
11.3
11.0
10.5
lO.1
9.4
8.6
8.7
7.5
Flowb,
gal/min
DRY
DRY
DRY
6
3
3
3
DRY
DRY
DRY
DRY
DRY
DRY
DRY
DRY
1
DRY
3
DRY
DRY
DRY
DRY
DRY
DRY
2
8
8
4
1.5
DRY
5
DRY
2
2
DRY
DRY
DRY
DRY
DRY
Table 10. Flow and Water Level Monitoring GWIP Stations
Bennett’s Dump Bloomington, Monroe County, Indiana
Monitoring Station Parameter Instrumentation
V-notch weir and Crest Gauge Middle Spring Water level/flow
Level logging transducer
Mid-North Spring Water level/flow V-notch weir and Crest Gauge
Mound Spring Water level/flow
North Spring Flow
Stout’s Creek Flow
Downstream
Stout’s Creek Upstream Flow
V-notch weir and Crest Gauge
Level logging transducer
None
Flow velocity meter
Flow velocity meter
Quarry Drain Outlet Flow Weir or Flow Velocity Meter
Icebox, Wedge & Wedge South Quarries
Water Level Staff gauge
Pit A (surrogate for Test Pits 1-4)
Monitor Wells & piezometers
(see Table 1)
Water Level
Water Level
Depth-to-water meter
Depth-to-water meter
Table 11. Flow Observations
On-Site Springs
Bennett’s Dump, Bloomington, Indiana
Observation Date
3/31/2014
3/18/2014
2/21/2014
1/30/2014
12/27/2013
12/23/2013
12/16/2013
11/8/2013
11/5/2013
10/28/2013
9/23/2013
9/3/2013
8/23/2013
8/15/2013
7/29/2013
6/28/2013
5/22/2013
4/22/2013
4/15/2013
4/8/2013
3/26/2013
3/19/2013
3/18/2013
3/12/2013
3/4/2013
2/27/2013
2/25/2013
1/30/2013
1/23/2013
1/14/2013
1/11/2013
12/12/2012
11/16/2012
10/10/2012
9/28/2012
9/14/2012
9/7/2012
8/15/2012
7/24/2012
continued
Mound
Spring a
0
0
0
0
0.4
31.7
0
0
0
0
0
0
0
0
0
0
0
5.6
0
0
0
0
0
0
0
0
0
0
0
7
0
0
0
0
0
0
0
0
0
Middle
Spring a
3.4
3.4
10.5
3.4
10
18.4
0.8
0.1
0
0
0
0
0
0
5.5
5.5
4.8
9.4
1.5
0.3
1.9
3.7
4.0
0.8
6.4
7.3
2.3
7.3
4
13.1
7.3
0
0
0
0
0
0
0
0
Mid-North Spring a
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
North
Spring
0
0
0
0
0
3
0
0
0
0
0
0
0
0
0
0
0
0.1
0
0
0
1.5
3
0
0
3
o
0.5
0
3
0
0
0
0
0
0
0
0
0
Rusty b
Spring
0.4
Nil
0
0
0
0
0
0
0
0
0
0
NR
NR
0
0
0
0
0
0
0
0.1
0
0
NR
0
0
0
0
0
0
0
0
0
0
0
Table 11. Flow Observations
On-Site Springs
Bennett’s Dump, Bloomington, Indiana
Observation Date
7/12/2012
7/10/2012
6/27/2012
6/14/2012
5/30/2012
5 / 17/2012
5/4/2012
4/18/2012
4/2/2012 c
3/27/2012 c
3/19/2012 c
3/15/2012 ~
3/5/2012
2/29/2012
2/20/2012
2/10/2012
2/7/2012
1/25/2012
1/18/2012
1/12/2012
12/30/2011
12/19/2011
12/12/2011
12/5/2011
12/2/2011
11/30/2012
11/23/2011
11/17/2011
11/15/2011
11/14/2011
1 I/4/2011
10/22/2011
10/12/2011
10~4/2011
9/30/2011
9/30/2011
9/26/2011
9/15/2011
9/8/2011
continued
Mound Middle Mid-North North
Spring a Spring a Spring a Spring b
0
0
0
0
0
0
0
0
0
o
o
.o
o
o
0
o
0
0.3
0
0
0
o
0
0
0
0
o
0
0
0
0
o
0
0
0
0
0
0
0
0
0
o.o
o.o
0.7
4.8
2.8
2.8
0.0
0.12
o.15
0.3
1.9
2.8
4.0
6.4
8.3
10.5
9.4
4
6.4
6.4
6
11.8
5.5
lO.5
1.9
0
o
o
0
o
0
0
0
0
0
0
0
o
0
0
0
0
0
o
0
0
o
o
0
0
o
0
0
0
0
0
o
o
0
0
0
0
o
o
0
o
0
o
o
0
0
0
0
0
0
0
0
0
0
0
o
0
0
0
o
0
o
o
0
o
0
0
o
5
0
0
0
0
3
o
1
o
o
o
0
o
0
o
0
0
0
0
0
0
Rusty
Spring b
0
0
0
0
0.25
1.25
1
0.5
0
0
0
0.05
0.5
0.5
0.3
1
1
1.5
1
0.1
0.25
1.5
2.5
0.5
2.5
1
0
0
0
0
0
0
0
0
0
0
0
0
Table 11. Flow Observations
On-Site Springs
Bennett’s Dump, Bloomington, Indiana
Observation
Date
9/1/2011
8/26/2011
8/18/2011
8/9/2011
8/5/2011
7/29/2011
7/15/2011
7/7/2011 "
7/1/2011
6/24/2011
6/22/2011
6/16/2011
6/14/2011
6/3/2011
5/28/2011
5/19/2011
5/6/2011
5/5/2011
4/25/2011
4/20/2011
4/14/2011
4/i2/2011
4/5/2011
3/31/2011
3/25/2011
3/I 8/2011
3/I 1/2011
3/7/2011
3/2/2011
2/28/2011
2/22/2011
2/18/2011
2/9/2011
2/4/2011
1/26/2011
1/21/2011
1/4/2011
12/28/2010
12/23/2010
continued
Mound
Spring a
0
0
0
0
0
0
0
.0
0
0
0
0
0
0
0
0
6.8
13.4
28
32
0.4
11.5
0
0
0
0
2
2
0
0
.0
0
0
0
0
0
0
0
0
Middle Spring a
0
0
0
0
0
0
0
1.9
1.5
3.4
4
3.4
1.9
3.4
6
7.3
13.1
16
18
16
11.8
14.5
8.3
6.4
7.3
8.3
12
lO.5
14.5
12
1.9
2.3
3.4
3.4
0.5
0.4
Mid-North Spring a
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
3.5
¯ 3.5
4.5
0.2
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
North
Spring b
0
0
0
0
0
0
0
0
0
0
0
1
0
0
0
0
1
2
8
0
4
1.5
0
0
0
0
5
0
2
2
0
0
0
0
0
0
0
0
Rusty
Spring b
0
0
0
0
0
0
0
0
0.1
0.5
1.5
1
0
0
0
1.5
NR
7
0
NR
0
0
0
0
0
0
0
3
0
0
0
0
0
0
0
Table 11. Flow Observations On-Site Springs
Bennett’s Dump, Bloomington, Indiana
Observation Mound Middle Mid-North North Rusty
Date spring a Spring a Spring a Spring b Spring b
12/21/2010 0 0 0 0 0
12/9/2010 0 0 0 0 NR
11/30/2010 0 0 0 0 0
11/22/2010 0 0 0 0 0
11/12/2010 0 0 0 0 NR
10/27/2010 0 0 0 0 0
10/15/2010 0 0 0 0 NR
9/30/2010 0 0 0 0 0
9/15/2010 0 0 0 0 NR
aFlow estimated using V-notch weir.
bFlow estimated visually.
Pump test in progress.
NR - Not Recorded
FIGURES
V-notch Weir
MW-3
I~ 24" Corrugated Plastic ’Drain Pil~.
Surface Water
Stout’s Creek Up Strum Sample Location
PZ-F4 GP-3 GP-11
P~-Itl
Inffitretion Gellery
C~ntrol Point
BD383
3101113.17 3100947.82 3100498.00
3100847.59 3101022.15 3100682.89 3101020.78
1436411.88 143560~34 1436414.92 1435678.11 1435455.55 143634~42
~ 18. am4
stature
,RY A
Intermittent Overflow Discharge from Quarter
Mile Quarry Complex
QuarTY Drain \Ouffall
Quarry Drain Weir Plate
I~ 11/18/14 - 0~.17pm T~ t~t0Ofl
/
[] Survey Control Point
~i~:. Piezometer Location
//~ Stream Gauging and
Sampling Point
~ Staff Gauge
(~ Springs
Test Pit Potentiometric Surface Contour on March 18, 2014
CBS Corporation
CONTINUOUS MONITORING PLOTS
25
20
Middle Spring Continuous Flow and Mound Spring Flow Observations
January 2014
5
I
1-Jan 6-Jan 11-Jan 16-Jan 21 -Jan 26-Jan 31 -Jan
2014
5.0
4.0
0.0
Middle Spring Flow ¯ Middle Sp obs. ¯ Rain Events [] Mound Sp obs. --Cumulative Rain
25
20
Middle Spring Continuous Flow and Mound Spring Flow Observations
February 2014
5
0 1-Feb 21 -Feb 6-Feb 11-Feb 16-Feb 26-Feb
2014
5.0
4.0
3.0 .__.
1.0
0.0
Middle Spring Flow ¯ Middle Sp obs. ¯ Rain Events [] Mound Sp obs. Cumulative Rain
25
2O
0 1-Mar
Middle Spring Continuous Flow and Mound Spring Flow Observations
March 2014
6-Mar 11-Mar 16-Mar 21 -Mar 26-Mar 31 -Mar
2014
5.0
4.0
3.0 ~~
1.0
0.0
Middle Spring Flow ¯ Middle Sp obs ¯ Rain Events n Mound Sp obs --Cumulative Rain
MANUAL MONITORING PLOTS
L_
o o o 00 ~ ~
(wriSt) ~o1:1
o o
(saq:~u!) u!e~! a^p, elnLun3 AIq~,uolN
I
(rude) ~o1:1
0
f::: .--.
(:U) uo!~,eAal3
F:&
APPENDIX A
Chain-of-Custody Records
01102348
2
3
4
5
6
7
8
9
1(
1:
CHAIN-OF-CUSTODY / Analytical Request Document 7he Chain-of-Custody Is a LEGAL DOCUMENT~ ,NJ relevant fields must be completed accurately.
project Name:
P~oJect Numbec
^i Section D Matrix Codes A _
~1 COLLECTED Requk~dC]ient In/omla~on MATRIX / CODE
Odnking Water OW Water W’F ]~ 0 I Waste WaterPmduc,
W~N Soil/Send SL
eL SAMPLE ID
Sample IDs MUST BE UNIQUE Tlssue TS 0
~ ~ DATE "r Z Z = 0 = Pace Project No./Lab I.D.
ADDITIONAL COMMENTS ACCEPTED BY I AFFIUATION SAMPLE CONDITIONS
SAMPLER NAME AND SIGNATURE
DATE Signed
F-ALL-Q-020rev,07, 15-May-2007
APPENDIX B
Certificates of Analysis
/_....~ace AnalyticaF
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Oompleted
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11749
PO Number
BL-0396
Sampled
18-MAR-14 10:00
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER 20 STANWIX STREET 10TH FLOOR PITTSBURG, PA 15222-1384
CLIENT ID: BD10767
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION DATA PACKAGE #: 66021
MATRIX: WT
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWIX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
Parameter Result Det. Limit Units
INITIAL WEIGHT OR VOLUME 2000 mL
_ EINALvoLuME :::: : :
Parameter Result Det. Limit Units
PCB AROCLOR 1016 BDL 0.01 ug/L
,PcB ARocLon1221 ’ ’ : PCB AROCLOR 1232 0.092 0.01 ug/L
PCB AROCLOR 1242 : BDL ’~ ...... ’ . 0.01 ug/L =’
PCB AROCLOR 1248 BDL 0.01 ug/L
=PCBAROCLOR1254 : ’ ’ ..... I " ] ’:’ " .... BDL , ¯ 0.01, ug!L :: ’: .
PCB AROCLOR 1260 BDL 0.01 ug/L
SUMMATION OF AROCLORS : : :
Aroclor pattern is degraded
Page 1 of 2
~ace Analytical °
Sample lD: AAl1749 BD10767
TOTAL sUSPENDED sOLIDS DRIED AT 103~105 DEGREES CSM2540 O 19TH ED i. " : NELAC:Y
Parameter Result Det. Limit Units
SUSPENDED SOLIDS I1 I 1 I mg/L
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical
Pace Analytica! Services,
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Lab ID
AA1175O
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER
20 STANWIX STREET
10TH FLOOR PITTSBURG, PA 15222-1384
CLIENT ID: BD10768 MATRIX TYPE: NON-SPECIFIC WATER
SUBMITTER: 2226 - CBS CORPORATION DATA PACKAGE #: 66021 MATRIX: WT
LOCATION: BENNETT’S DUMP
26-MAR-14
Printed
27-MAR-14
Bill To
BETH STEIGERWALD
CBS CORPORATION
Completed PO Number
BL-0396
Sampled
18-MAR-14 10:00
20 STANWlX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
PCB SEPARATORY FUNNEL LIQUID-LIQUID EXTRACTION SW846-3510C i :
. ~nalyst:.CiHIPSKiND ~ ii i i : ~ A~’~iysis Datei21’MAR~i4 ~ instrUme~i PREP’ ~::
Parameter Result Det. Limit
INITIAL WEIGHT OR VOLUME 2000
FINAL VOLUME 1
~ PCB AROCLORS BY GAS CHROMATOGRAPHY/ECD SW846;8082A ......... ¯
:Test: P230.11o
Units
rnL
rnL
NELAC:Y
Analyst: C:::HIPSKIND : , ; : ....... Analysfs Date:21-MAR,14 1:6:20 . Instrument: GC/ECD ; Test: O301,7.0,
: Prep: POB SEPARAToRY FUnnEL. LIQUID:LIQ0iD:EXTRA~i0~:S~846:3516~ P230.ii~ :
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATE RECOVERY
DECACHLOROBIPHENYL(DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL
0.086
BDL
BDL
BDL
52.0
Det. Limit
0.01
0.01
0.01
0.01
0.01
0.01
0.01
0.01
Units
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
% Rec
0.086 0.01 ug/L
Aroclor pattern is degraded
Page 1 of 2
~ace Analytical~
Pace Analytical Services, Inc.
Sample lD: AAl1750 BD10768
TOTAL SUSPENDED SOLIDS DRIED AT 103’105. DEGREES C SM2540 DI:i9TH ED ’~’ i NE[_AC:Y :
Parameter Result Det. Limit Units
SUSPENDED SOLIDS I1 I 1 I mg/L
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace AnalyticaF Pace Analytical Services, Inc.
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11751
PO Number
BL-0396
Sampled
18-MAR-14 10:15
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET 10TH FLOOR PITTSBURG, PA 15222-1384
CLIENT ID: BD10769
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021
MATRIX: WT
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
Parameter
1Result i Det. Limit Urn~i~s ,,
INITIAL WEIGHT OR VOLUME 2000 mL
FINAL VOLUME ~ i i~: ’ .....
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221’
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
,PCB AROCLOR 1262
SURROGATE .:RECOVERY
DECACHLOROBIPHENYL; (DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL :: :: : ::
BDL
BDL
BDL
BDL
BDL
BDL
66.0
BDL
Det. Limit
0.01
’ : O~Ol
0.01
0.01
Units
ug/L
ug/L’
ug~L ug/E
0.01 ug/L
0.01 ug/_L
0.01 ug~L
% Rec
0.01 ug/L.
Page 1 of 2
~ace Analytical °
Sample ID: AAl1751 BD10769
TOTAL SUSPENDEDISOLIDS IDRIED AT103.4 05 ~DEGR EE~ ~i SM2540 D 19THED ’ ~ :: :~’ i: NELAC:Y i
Parameter Result Det. Umit Units
SUSPENDED SOLIDS
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25~MAR-14
Page 2 of 2
~ace Analytical Pace Analytlc~l Services, Inc.
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11752
PO Number
BL-0396
Sampled
18-MAR-14 10:20
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
CLIENT ID: BD10770
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021
MATRIX: BD
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR
PITTSBURGH, PA 15222
Sample Description
Parameter
FINAL VOLUME
Units
m L
mk
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATERECOVER¥:
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
62.0
BDL
Det. Limit
DECAGHLOROBIPHENYL (DCB)
SUMMATION OF AROCLORS
Units
0.10 ug/L
0.10 :ug/L
0.10 ug/L
0.10 Ug/L
0.10 ug/L
0,10: ugiL
0.10 ug/L
0.10 ug/L
% Rec
0.10 ug/L
Page 1 of 2
, . ~ace Analytical~
Sample lD: AAl1752 BD10770
TOTAL: SUSPENDED SOLIDS DRIED AT 103’105 DEGREESiC SM2540 D 19~HED . :i, ~::, i~;~:, N ELAC:¥1 ~
Parameter Result Det. Limit Units / SUSPENDED SOLIDS L BDL [ 1 ~ rng/L /
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical°
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11753
PO Number
BL-0396
Sampled
18-MAR-14 10:25
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
CLIENT ID: BD10771
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021 MATRIX: BD
LOCATION: BENNETT’S DUMP
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWIX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
Parameter
INITIAL WEIGHT OR VOLUME
FINAL VOLUME
1000 mL
5
Prepi PCBSEPARATORY :FUN:NEE LiQUID~LIQUi6 ExTRACTIoN Sw846-35i00 P230!.110 : ::: ’:.: i i: .::: : :::::::
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR :1242
PCB AROCLOR 1248
PCB AROCLOR 1254
PCB AROCLOR 1260
PCB ARO(~LOR 1262
SURROGATE RECOVERY
DECACHLOROBIPHENYL (DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL
BDL
BDL
4.3
’BDL
BDL
BDL
94.0
4.3
Det. Limit Units
0.10 ug/L
0.10 ug/L
0.10 ug/L
0.10 Ug/L
0.10 ug/L
~0.10~ :ug/L.
0.10 ug/L
0.10 ug/L
% Rec
0..10 uglL
Aroclor 1248 is degraded.
Page 1 of 2
~ace AnalyticaF
Sample lD: AAl1753 BD10771
TOTAL SUSPENDED SOI3DS DRIED AT
Parameter Result Det. Limit Units
SUSPENDED SOLIDS
Sample Comments
AMENDED REPORT - CBB - 27-MAR-14 : summation amended
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical~
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST. INDIANAPOLIS, IN 46231 (317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11754
PO Number
BL-0396
Sampled
18-MAR-14 10:45
Report To
RUSS CEPKO CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET 10TH FLOOR PITTSBURG, PA 15222-1384
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWIX STREET 10TH FLOOR PITTSBURGH, PA 15222
Sample Description
CLIENT ID: BD10772
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021 MATRIX: BD
LOCATION: BENNETT’S DUMP
Parameter
INITIAL WEIGHT OR VOLUME
FINAL VOLUME
Result
1000
5
Det. Limit Units
mL
mL
Prep: PCB SEPARATORY FUNNEL LIQUiD:LIQUi:~ ~XTRACTIoN sW8~4643510C P230H io ,::-::: .... ::::i
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242
PCB AROCLOR 1248
’PCB AROCLOR 1254
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATE RECOVERY
DECACHLOROBIPHENYL (DCB)
SUMMATION OF AROCLORS
Result
BDL
BDL
BDL
BDL
BDL
BDL
BDL
BDL
84.0
BDL
Det. Limit Units
0.10 ug/L
0.10 :ug/k
0.10 ug/L
0.10 ug!L
0.10 ug/L
o.io ugiL 0.10 ug/L
0.10 ug/L
% Rec
0.10 ug/L
Page 1 of 2
~ace AnalyticaF
Parameter Result
SUSPENDED SOLIDS - BDL
Sample Comments
Sample lD: AAl1754 BD10772
: ~e~t:: G40318i0:
Det. Limit Units I
I i I mglL I
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
Page 2 of 2
~ace Analytical
Pace Analytical
Service Location
PACE ANALYTICAL SERVICES, INC. 7901 W. MORRIS ST.
INDIANAPOLIS, IN 46231
(317)243-8304
CERTIFICATE OF ANALYSIS Received
19-MAR-14
Completed
26-MAR-14
Printed
27-MAR-14
Lab ID
AA11755
PO Number
BL-0396
Sampled
18-MAR-14 10:30
Report To
RUSS CEPKO
CBS CORP - NATIONAL CITY CENTER 20 STANWlX STREET
10TH FLOOR
PITTSBURG, PA 15222-1384
Bill To
BETH STEIGERWALD CBS CORPORATION 20 STANWlX STREET 10TH FLOOR
PITTSBURGH, PA 15222
Sample Description
CLIENT ID: BD10773
MATRIX TYPE: NON-SPECIFIC WATER SUBMITTER: 2226 - CBS CORPORATION
DATA PACKAGE #: 66021 MATRIX: BD,
LOCATION: BENNETT’S DUMP
Parameter
INITIAL WEIGHT OR VOLUME
FINAL VOLUME
Result
1000
5
Det. Limit Units
Parameter
PCB AROCLOR 1016
PCB AROCLOR 1221
PCB AROCLOR 1232
PCB AROCLOR 1242 ’
PCB AROCLOR 1248
PCB AROCLOR t 254 ....
PCB AROCLOR 1260
PCB AROCLOR 1262
SURROGATE RECOV:ERY, .....
DECACHLOROBIPH ENYL (DCB)
SUMMATION OF AROCLORS ...... :
Aroclor pattern is degraded
Result
BDL
BDL
2.9
BDL
BDL
BDL
BDL
92.0
2.9
Det. Limit Units
0.10. ug/L
.0.10: U~/L .....
0.10 ug/L
0.10 uglL
0.10 ug/L
0.10 ug/L 0.10 ug/L
’% Rec
0:i:0i’ug/L :
Page 1 of 2
,~ace Analytical ° Pace Analytical Services, Inc.
Sample lD: AAl1755 BD10773
Parameter Result Det. Limit Units I
SUSPENDED SOLIDS ~ 2 t 1 ~ mg/L J
Sample Comments
BDL Below Detection Limit
Sample was received on ice at temperature 2.8 C. Sample chain of custody number 1771728.
This Certificate shall not be reproduced, except in full, without the written approval of the lab. The sample results relate only to the analytes of interest tested or to the sample as received by the lab. Pace Analytical Services, INC. certifies that the test results indicated as NELAP (National Environmental Laboratory Accreditation Program) accredited (Yes for NELAP) meet all requirements of NELAP and Kansas (KDHE) unless otherwise explained or justified as to the the exact nature of the deviations. KS ELAP / NELAP Accreditation # E-10177 Indiana SDWA C-49-01
Approved by: CHRISTOPHER BOYLE 25-MAR-14
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APPENDIX C
Data Validation
Validation Results March 18, 2014
Bennett’s Dump SDG #66021
Groundwater Monitoring Samples
1. Validation of the following samples has been completed:
BD10767 to BD10773
Validation was performed per the requirements forlevel 4 data in the project QAPjP. This includes a check for; Holding Time, Calibration, Blank Contamination, Precision, Accuracy, and Accuracy of Nominal Reporting Limits against method requirements.
Based on this review no data qualifications are recommended.
The QAPjP requires an assessment of the overall data quality with respect to Precision, Accuracy, Representativeness, Completeness and Comparability (PARCC).
o Precision and accuracy: Precision and accuracy were accessed by reviewing the lab performance on lab spiked samples, lab spike duplicates and field duplicates. All requirements were met.
o Representativeness: The representativeness requirement involves an assessment of the field sampling and lab analytical techniques. The field sampling locations and techniques as well as lab procedures were in accordance with the approved sampling plan and QAPjP. Therefore the representativeness requirements were met.
o Completeness: The completeness goal for the project was for all project data to be 90% accepted. Completeness is calculated by dividing the total number of acceptable analyses by the total performed. An acceptable analysis is defined as one that conformed to QC protocols and is not rejected. All these analyses were accepted. The project completeness goal has been met to date.
O Comparability: All the samples taken, analyzed and validated by CBS were ¯ taken by CBS or it’s contractors sampling crews using the same procedures as previous samples at this location. These samples were analyzed by Heritage Labs. Care should be taken when attempting to trend Heritage sample results with other labs using slightly different procedures. Overall these results should be directly comparable to other Heritage lab results from these locations.
Overall, the main objective of the sampling event was to determine if PCBs are present at a concentration of. 1 ppb or more (!).0] ppb for Stout’s Creek ])ownstream, SCD and Upstream, SCIJ-).. This data is of sufficient quality to satisfy this goal.
O:~LEA~EnvironmentalkBloomington\SHAREDIRkBP validation~reports\validation report -BD Mar 18, 2014.doc 9/2/14
APPENDIX D
Instrument Maintenance Log
Bennett’s Dump InStrument Maintenance Log First Quarter 2014
Office Rain Gauge: Instrument
HOBO
#9928483
Mound Sp.: Instrument
Crest gauge
Middle Spring: Instrument
In-Situ LevelTROLL #303381
Crest gauge
Date
1/1/2014 to
3/31/2014
1/1/2014 to 3/31/2014
2/18/2014 2/21/2014 3/26/2014
1/13/2014 2/4/2014 2/18/2014 3/5/2014 3/19/2014
2/18/2014 2/21/2014 3/26/2014
Action
Normal function.
Not instrumented, Manually observed due to infrequent and short-duration flow.
0.33 feet 0.32 feet 0 feet
No re-indexing needed. Re-indexed by 0.001 ft. Re-indexed by 0.019 ft. Re-indexed by 0.003 ft. Re-indexed by 0.004 ft.
0.33 feet 0.21 feet 0.165 feet