CASE NO. 3089: LABORATORY DATA, QA CHECKLIST (DATA IS ... · A review of the laboratory raw data for case il Si^ S 'I has been completed by members of the Laboratory Section. Attached

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION VI

HOUSTON BRANCH

6608 HORNWOOD DRIVE

HOUSTON. TEXAS 77074

DATE: l l - S ^ ' 8 ^

SUBJECT: CLP Data Review'~,S^^L^'fi~Z^^—/-

FROM: /William Lag^fey, Chj.s'fHouston Branch (6Efr4l)

TO; Keith BradleyHazardous Waste Section (6ES-SH)

i".i^t l i ^ i " - )A review of the laboratory raw data for case il Si S 'I has been completedby members of the Laboratory Section. Attached please find copies of thereevant QC notices for the following samples.

INORGANIC: WS ^ / _/^JL°^

ORGANIC:

/ •^-S'S i> "•

Please call me if you have any questions regarding the data review.

Attachments

80417

C^^: Si\5 f^TfF- -/^f-; POT

fF •• ' .-TFA^fORGANIC QA CHEC./LIST

Contractor _Q(\L fil\L(\L____ Contract ?

Case Do. S(\ S I 3- S'S P

Site 1/g^rAC.

Matrix ^^"^g^-

Sample Mo. /^ 5'J'l")/

OVERALL COMt-iENTS (TO BE COI-iPLETED BY EPA PERSO;1?;EL)

Data Completeness __^ Acceptable__ Not Acceptable

Instruinsnt Tune y Acceptable___ Mot Acceptable

Hot Acceptable

Mot Acceptable

Mot Acceptable

Not Acceptable

Not Acceptable

Hot Acceptable

'V AcceptableChromatography

Blank Analysis

Matrix Spikes

Duplicates

Surrogate

Field Blank

t/ Acceptabie _

v^ Acceptable

j/ Acceptabi e _

v Acceptable^

^?^\ Acceptable _

OTHER COMMENTS OR CLARIFICATIONS

lA.r[,7£^ SA-MI^G-S /

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—f v n. i i t-i———r. ..______. <L.__^&/-42 ..___Q\:m__^cQfJ^^___^?^L_âQ2.

UNITED STATES ENVIRONMENTAL PROTECTION AGENCYREGION VI

HOUSTON BRANCH

6608 HORNWOOD DRIVE

HOUSTON. TEXAS 77074

DATE: //-^-

SUBJECT: CLE,Data Review

FROM: /William Lang^y, Chl-yHouston Branch (6ES-H)

TO: Keith BradleyHazardous Haste Section (6ES-SH)

A review of the laboratory raw data for case ii .î£:' J- 7 has been completedby members of the Laboratory Section. Attached please find copies of thereevant QC notices for the following samples.

INORGANIC:

SIC: D P D 0 L'/ / ^ '! -^ 0 ^-L'- u !^ (^rii\Û^;„e.}ORGANIC:

f7)' c ' v i . "[ l>r\.i

Please call me if you have any questions Tpparr'ir.c. i-ho ,'ara ,-ot^n,,

/ / ' r

Attachments / '^ >,' L / '

c^ ^^ ' ^c /fi7wi^r. ^-71 ^^(^L5\" '' (Tn 1'y T ORGAmC QA CHECKLIST / '

Contractor \-\ ^TÊTL'Tbl^ Contract p ^^-Cl- ^ I 3

Case Mo. "^QS'7_________ Matrix ______30( L___________

Site ^n^Tt\C ^[JFpS^r^ A ^ O / ^ /satnp1e r'0- ..PP <10^ / — . OFfG^/^^ (/tyc t .y ^ ^--1

\ > . ^ 7 ,

OVERALL COMMENTS (TO BE COMPLETED BY EPA PERSGÊL}

Data Completeness '^ Acceptable___ Mot Acceptable

Instrument Tuns i/' Acceptable__ Mot Acceptabi e

Chromatograph.y i^ Acceptable Hot Acceptable

Blank Analysis l^ Acceptable___ Mot Acceptable

Matrix Spikes v^ Acceptable___• Mot Acceptable

Duplicates j^ Acceptable___ Not Acceptable

Surrogate ' ' / Acceptable__ Mot Acceptable

Field Blank ^.^ Acceptable__ Hot Accept abTe

OTHER COMMEHTS 0° CLARIFICflTIOMS^ Sar C^'\\^\^ST^ AT7rKl4(•:D9 /^ Y GP^ 6^- H L

^ F/CL-P ^tfrKAc ^/2-(Nr$ftTc)-$£^ c^-wô^rs ,

CASE 3089- VERTACBatch no. 09ACT: AA71SF#: TFAH04Dioxin samples analyses from Hazelton LabsEPA_HOUSTOH 6ES-HL COMMEMTS

In the initial shipment of data from the lab, sample DF004105 showedthe highest level of 2,3,7,8-TCDD at 22.3ppb;duplicate analysis gave33-9 Ppb by peak height as reported by the lab ( 3 6 . 4 ppb by area )and was confirmed by partial scan analysis. Results of this duplic-ate analysis agreed to<50^ RPD as per Sect E5 of the contract,butnote that this was not one of the specified duplicates to be doneas per the packing list. The duplicate specified in the traffic formwas DF004112 and what appeared to be also marked DF004117. SMO hasbeen requested to try and find out why the lab did not do the specifiedsample duplicate , although duplicate analysis on the sample ofhighest concentration is a bonus.No other sample had^ppb,exclusive of the native spike,in this firstshipment. The lab stated that several samples,DF0041-13,-14,-l6 and-17 would require re-analysis with results to follow. One of thesesamples, DF 004116, showed^ 50ppb in early results.The resubmission report confirmed the high levels of TCDD in thesesamples;

DF 004116 had 119 ppbDF 004117 had 15.3 ppb.

Sample DF004114 had 30.9ppb TCDD but the surrogate recovery was out-side of acceptable limits; DF 004113 had analytical problems and theestimated max. concentration was 6 . 6 p p b .Final comment- The labs continue to receive, in error, an acetoneequipment rinsate sample. Conversation with EPA Project Officer(JoanFisk) on 11/19/ 4 confirms that this rinsate sample is suppose tobe trichloroethylene and not acetone.

M.L.HITTER6ES-HL11/19/8

UNITED S T A T E S ENVIRONMENTAL P R O T E C T I O N A G E N C Y6608 HORNVOOD DRIVE HOUSTON, TEMS 77074

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SOIL SURROGATE PERCENT RECOVERY SUMMARY

>. Ô^_________ Contract Laboratory V S "Tg<TT^ Contract No. IJÔh^WCaae No

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'.—!_ ; outside of QC limits

*»,ADVISORY LIMITS ONLY

•Comments: Q 'S*^- ^xK^t7 AA\kA>^ ^1 ) _

Vi>latiles:Scmi-Volatiles:Pisticides: •

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SOIL MATRIX SPIKE/MATBJ1X SPIKE DUPLICATE R E C O V E R Y

Case No.. Contractor —— Contract No..

Low Level, Medium Level.

wRPD

Con

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FRACTION

VOASMO

SAMPLE NO.

B/NSMO

SAMPLE NO.

ACIDSMO

SAMPLE NO.

PESTSMO

SAMPLE NO.

v^FRISKED VALUES AREpUTSIDE QC L^

: V O A s — — — — o u t o f . i - 1 ; outsB/N out o f ; outsACID——outo f^ - j——; oulslPEST 0 out of i-- ;\.gi .• outs

nmanta; • i

COMPOUND

1,1-DlcholoretneneTrichloroethernCMorobenieneTolutn»Bentene •1,2,4-TtlchlorobenzentActnaphtnene2,4 OinitrotoluentDi-n-ButylphthalalDPvr«ne • •N-Nitrosodl.n-Propylamlne1,4-OichlorobenienePenttchlorophenolPhenol '2-Chlorophenol4-Chloro-3-Methylphenol

Undane '•HeptachlorAldrin 'Dieldrin^[Endrin : 1

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;CONC. SPIKEi ADDED (ug)^ ....

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SAMPLERESULT

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1 RECOVERY:

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REAGENT BLANK SUMMARY

Contractor M5Lr^D^___l_____ Contract No. M^L^l^L

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SAS/Case: D'7'10 E

Batch # : 113

File name: HT011775A03 DMA # 03Date Analyzed: 09/05/B4 11:39ec column: CP 5IL 88Bottle date: 9/4/B4

CC ft 11775EPA Sample tt RB

ExtraClean-up

Yes

NetWeight(gms )10. 00

237B-TCDDCone.( p p b >ND

DetectLimit< p p b )

1. 630

Area(Height)320/322

< -——)

Area(Height)332/334

2. 70( 2.40)

SurrogatePercent'Accuracy205. 9 . ; , -

Area332

31568.

Area334

11712.

Area320

0.

Area322

Area257

Area32818000.

Height3325951.

Height334

5476.

BkGnd320

1215.

BkCnd322784.

MultipointRF-Native

0. 91

MultipointRF-Surr

1. 01

C1.3-TCDD eluted at scan_10B3The condition code is SU

REJECTED

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)SU - Surrogate '/. accuracy out of range

ND - Not DetectedFB - Field BlankP - Partial Scan

FORM 248-1

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COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM DflTA; HT011775A03 SCANS 1021 TO 114609/05/84 ll;39i80SAMPLE; 2 UL 11775 (C#£948-2 - RB ) 9/4/'84 OHA» 03COHDS.; CPSIL88 50M 0.23m ID 80<2)240<28C/MIN> CONTRACT MASSES 131MS Eft469 2378-TCDD <M/€ 332 - 1X-2378 - AS RETENTION MARKER) -^ ICfTFn

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1648.320.0361 0.50Q

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332.099± 0.500

14203.

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166016:56

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110017; 34

112017S54

114018; 13

COMPUCHEM LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA; HT011775A03 SCANS 1021 TO 114609/e5/84 11;39;80SAMPLE; 2 UL 11775 <C#2949-2- - RB ) 9/4/84 OUAt B3CONDS.; CPSIL88 50M 8.2311M ID 8e<2)24e<20C/MIH) CONTRACT MASSES 131MS EA* 13C12-2378-TCOO (INTERNAL STD)/'37CL4-237S-TCOD (SURROGATE STD) ^ ii-^TCn

REJLLILU

Lab: ConipuChem Labs

SAS/Case: 3089-05

Batch # : 113

File name: HT011023A03 OMA # 03Date Analyzed: 09/05/84 12:25GC column: CP SIL 88Bottle date: 9/4/84

CC « 11023EPA Sample « DF003713N

ExtraClean-up

Yes

NetWeight( g m s )10. 00

2378-TCDDCone.( p p b )0. 93

DetectLimit( p p b )-——

Area(H e i g h t )320/322

0. 78( 1 . 0 6 )

Area( H e i g h t )332/334

0. 74( 0. 78)

SurrogatePercentAccuracy

86. 3 - ,

0

Area332

262215.

Area334

355184.

Area320

45968.

Area322

5B7&8.

Area257

20504.

Area328

108144.107615.

Height33238545.

Height334

49536.

BkGnd320

B k G n d322

MultipointRF-Native

0, 91

MultipointRF-Surr

1 . 01

Comments : C13-TCDD eluted at scan 1342The condition code i^ÔK,

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)

OK - No errors found«->•• Corrected area 328 C328 10.009 X 322)3


FORM 248-1

COtlPUCHEM LABS 'RIC COtlPUCHEM DATA; HT011823A03 SCANS89/05/84 12;25:SBSAMPLE; 2 UL 11623 <C#3089"05 - DF003713N ) 9/4/84 OMfl# 03COHDS.; CP5IL88 50t1 e.23t1M ID 88<2)240<20C/MIN) CONTRACT MASSES 131M5 EA

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COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM DATA; HT811023A83 SCANS 1280 TO 1435e9/'85/'84 12; 25; 08SAMPLE; 2 UL. 11023 (C#3089-95 - OF983713N ) 9/'4/84 OMA# 83CONDS.; CPSIL88 5011 0.23(1(1 10 30<2)249<2aC/'MIN) CONTRACT MASSES 131MS EA» 13C12-2378-TCOD < INTERNAL STO)/'37CL4-2378-TCOO (SURROGATE STO>

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Lab: CompuChea LabsSAS/Case: 3089-05Batch # : 113

File name: HT010934A03 OUA « 03Date Analyzed: 09/05/84 14:46GC column: CP SIL 88Bottle date: 9/4/B4

CC # 10934EPA Sample # DF003704

ExtraClean—up

Yes

NetWeight( g m s )-t-OQfi.10,^

2378-TCDDCone.( p p b )ND

DetectLimit( p p b )

1. 9BO

Area( H e i g h t )320/322

( ——)

Area(Hei g h t )332/334

3. 20( 2. 76)

SurrogatePercent.Accuracy128. 3

n

Area332

390287.

Area334

121840.

Area320

70806.

Area322

13664.

Area257

0.

Area328

132752.132629. *

Height33250017.

Height334

18098.

BkGnd320

16223.

BkGnd322

3423.

MultipointRF-Native

0. 9 1

MultipointRF—Surr

1. 01

Comments : C13-TCDD e l u t e d at scan -1097The c o n d i t i o n code is IS

REJECTED

RB - Reagent BlarilN - Native TCDD SpikeD - Duplicate <Intralab>IS - 332/334 ion ratio out of range


*# Corrected area 328 C328 (0.009 X 322)3FORM 248-1

COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM DATA! HT010934d33 SCANS 1035 TO 116009/05/84 14:46(00SAMPLE; 2 UL 10934 (CK3089-05 - DF603704 ) 9/4/84 OMA# 03CONDS.s CPSIL88 50M 0.23MM ID 80(2)240(20C/MIN) CONTRACT MASSES 131MS EAt 13C12-2378-TCDD (INTERNAL STD)/37CL4-237S-TCDD (SURROGATE STD)

REJECTED20753.70806.42.8-1

3201

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19744.328.098

50560.332.Q99

1 0.508

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18944.

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91776.

———11160 SCAH18:32 TIME

COriPUCHEM LABSCOMPUCHEM OATA; HT010934A33 SCANS 1035 TO 1160RIC + MASS CHROMATOGRAMS09/05/84 14i46!09SAMPLE! 2 UL 10934CONDS.i CPSIL88 50M 0.23MM469 2378-TCDD (M/E 332 -

<C#3089-05 - DF003704 ) 9/4./84 OMA» 03ID 80<2)240<20C/'MIN> CONTRACT MASSES 131MS EA13C-2378 - AS RETENTION MARKER)17; 20 REJECTED8194.

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^ a 70836.42.8-1 /i320

17:294272.

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21632.320.096

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5120.322.696

± 0.560——^————y"- ^-^'i ^ vy^r\n. ^

5856B.332.099

± 0.500———1—————,—————1—————,—————1

91776.

1123 1140 1160 SCAN17:54 18:13 18:32 TIME

Lafa: CompuChem LabsSAS/Case: 30B9-05Batch # : 113

File name: HT010959A03 DMA « 03Date Analyzed: 09/05/B4 15:40GC column: CP 5IL 88Bottle date: 9/4/84

CC # 10959EPA Sample ft DF003706

ExtraClean—up

Yes

NetWeight( g m s )10. 30

237B-TCDDCone.( p p b )0. 20

DetectLimit( p p b )———

Area( H e i g h t )320/322

0. 73( 0.80)

Area( H e i g h t )332/334

0. 79< 0.78)

SurrogatePercentAccuracy100. 0,.-0

Area332

il65020.

Area334

77946BO.

Area320

225112.

Area322

30752B.

Area257

90576.

Area328

2824150.2821390.

Height332

965632.

Height334

»123903

BkGnd320

BkGnd322

MultipointRF-Native

0. 91

MultipointRF-Surr

1 . 01

Comments: C13-TCDD eluted at sca-ri~l-337The c o n d i t i o n code is OK j

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)OK - No errors found»» Corrected area 328 [328 - (0.009 X 322)3


FORK 248-1

C011PUCHEM LABS 'RIC C011PUCHEM DATA; HT010959A03 SCANS 380 TO 180089/85/84 15848:00SAMPLE: 2 UL 10959 (Cft3089-05 - DF00370G ) 9/4/84 OMA# 03CONDS.; CPSIL&o 50M 0.23m ID 80(2)240<20C/MIN) CONTRACT MASSES 131MS EA

21; 22 2670590.

9:46

•^__23:2\ _ 25:24 28:10

6009; 35

8&012:47

108815; 59

120019;10

140022:22

160025:34

1800 SCAN28:45 TIME

COMPUCHEM LABS •RIC + MASS CHROMATOGRftMS COMPUCHEM DATA; HT810959A03 SCANS 1275 TO 140009/85/84 15:40;08SAMPLE; 2 UL 10959 <C«3089-85 - DF003706 ) 9/4/84 OUA# 03CONOS.; CPSIL88 5811 0.23m ID 80(2>240<20C/MIN) CONTRACT MASSES 131MS EA* 13C12-2378-TCDD <INTERNAL STD>/37CL4-2378-TCDD (SURROGATE STD>21; 24

34361,225112.2.8-, w^'

320 .

1 """" ' ""' 1 ' • ••"•" "1 "•"" ' " " " 1 '21:24393792.

31.8n 28^59-328

1 • 1 • 1 ' 1 '21; 229S5632.

77.9-, 61e502a-332

21:221239038.

108.0-, 779468a-334 .

21:222555930.

206.3n 17378500-RIC.

1 1 •" 1 " ' | " "•" ' ' " ] '1239 13B0 1320 134020:27 20:46 21:05 21:25

20:45 / \1614. / V

^4273. / "s

/Y/ \j \^ ± 0.5313

/ \ 22:08 334.108/ \ 2752. ± 0.590/ ' ^- ' 9120. • •

/Y

34889.320.096

± 0.580i • 1 • i

394240.328.698

± 0.5081 • 1 • 1

965632.332.093

1 1 1 1 1

1239038.

1 • 1 • i

2555900.

1368 1380 1400 SCAH21;44 22:03 22:22 TIME

COMPUCHEfl LABS

1.5-1257

3.6-i326

4.5i322

160.8-1332

264.7-1RIC

RICesêSAMFCONE469

1 '128820; 27

+ MASS CHROMATOGRAMS35^84 15;40!09'LE; 2 UL 10959]S.; CP5IL88 50M 0.23M

2378-TCDD (M/-E 332

20:451614.

• 4279.

23; 492089.78S3.

1

130920:46

132021:05

<C#3089-M ID 80<2>24- 13C-2378 -

-"T——"—r

85 - DF0937B60<20C/MIN) CO

AS RETENTION21:2413883.90576.

/\21; 2434361.225112.

/\21:2442672.307528.A,

21:22965632.

6165829.

/V21:22

2555900.17378580.

134021:25

COMPUCHEM DATA; HT010959A83 SCANS

) 9/4/-84 OMA* 03NTRACT MASSES 13111S EA

MARKER)

21:492112.

,. 13064.

i

^—^^^1366 138821:44 22:03

1275 TO 1400

14544.257,077

± 0,500

34888.320.096

± 0.508

43038.322.096

± 0.580,.„, „ -.,

965632.332.699

± 0.500

' 1

2555900.

, , , ^1480 SCAN22:22 TIME

Lab: CompuChein LabsSAS/Case: 2948-2Batch # : 113

File name: HR010983B03 OMA « 03Date Analyzed: 09/05/84 18:39GC column: CP SIL 88Bottle date: 9-4-84

CC « 10983EPA Sample « DF003709

ExtraClean-up

Yes

NetHeight( g m s )10. 10

2378-TCDDCone.( p p b )1. 30

DetectLimit( p p b )—

Area( H e i g h t )320/322

•e-fr4~,( 0 . 7 1 )


0, 77( 0. 7&)

SurrogatePercentAccuracy100. 6

Area332

153168.

Area334

199440.

Area320

33360.

Area322

52392.

Area257

13712.

Area328

72092.71621.

H e i g h t332

21950.

Height334

2B767.

BkGnd320

BkGnii322

MultipointRF-Native

0. 91

MultipointRF-Surr

1. 01

Comments : C13-TCDD eluted at scan 1340-The condition code is RA '/, , -

RE - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)

RA - 320/322 ion ratio out of range


** Corrected area 328 [328 (0.009 X 322)3FORM 248-1

COtlPUCHEII LABS 'RIC COMPUCHEM DATA; HR018983B03 SCANS 388 TO 1660BSêS^ 18:39:63SAMPLE; 2 UL 10983 <C#2948-2 - DF603709 ) 9-4-84 OMA# 03CONDS.; CPSIL88 SBM 0.23t1M ID 80<2)240<28C/MIN> CONTRACT MASSES 13111S EA

9!27 394752.

b;45

7:56f ; i s |

2l!2S

23;17 24s24

6009i35

see12:47

100015; 59

12UB19:10

148022; 22

1600 SCAN25:34 TIME

o 0COMPUCHEM LABS '

RIC + MASS CHRONATOGRAMS COMPUCHEM DATA; HR010983B03 SCAMS 1278 TO 140309/85/84 18;39;88SAMPLE; 2 UL 18983 <C#2948-2 - DFa93709 ) 9-4-84 OUA# 93CONDS.i CPSIL88 58M 0.23MM ID 80<2>240<28C/MIN> CONTRACT MASSES 131MS EA;»: 13C12-2378-TCDD (INTERNAL STO)/37CL4-2378-TCDD (SURROGATE STD)21:25

6185.33368.24.0-1

320

1 1 1 1

34.5-1328 .

l • ' '

77.7-1332

^,,.,...,.-,,,—i, , „ , , , , , , , ^ ,.„„....-.,.,„,..„„„-,.„„,„..,

160.0-i334 .

257.6-1RIC.

1288 1380 1320 1340 1360 138328:27 20:46 21

/ \\ ± 0.500

/ \ ± 0.500

^JviOO.

/\' ' 1 ' V .1-—— ..]>- r"

21; 259976.

?2092. 21;41/ ' \ 3146./ < , 12856./ ^-£^^:-^-^ ^^^21; 2421358.153168.

/V21;2328767.199440.

21; 2572996.539683.

/V .:05 21:25 21:44 22:03

7038.320.096

•

10192.328.698

± 0.500

22976.332.839

± 0.530" " " '"1

29568.334.190

76160.

1400 SCAN22:22 TIME

00

COriPUCHEM LABSCOMPUCHEM DATA: HR010983B83 SCANS 1278 TO 1403RIC + MASS CHROtlATOGRAMS09/65/84 18:39:00SAMPLE; 2 UL 10983CONDS.; CPSIL88 50M 0.23m469 2378-TCDD <M/E 332 -

<C»2948-2 - OF803709 ) 9-4-84 OMAtt 03ID 80<2>240<20C/MIN) CONTRACT MASSES 131MS EA13C-2378 - AS RETENTION MARKER)21:27

2672.13712.16.4-, J -

257

30.8-, 33^8-320

4l.4-i322

100.0-1

332 .

331.5-1RIC.

/ \.A^ / '*< ---'y\•-••-'\/-/' ^ \^ '' ^V^^V/^^Â-^/r ••———r— •••T- - T—-—-r -r-- -•I———r-" • ' r ""• • i

21:256185.

21:258665.52392.

21:2421950.153168.

/Y21:2572996.539683.

/V .

3768,257.077

———————— ± 0.580W/^—v^-s.• • ' • T--'-"" •T"

7088.320.096

± 0.503

9504.322.036

± 0.500

22976.332.099

± 0.500

——, |

76160.

SCANTIME

Lab: CompuCheffl LabsSAS/Case: 2948-2Batch « : 113

File name: HR011015B03 DMA « 03Date Analyied: 09/05/84 19:18CC column: CP SIL 88Bottle date: 9-4-84

CC ft 11015EPA Sample # DF003712

ExtraClean—up

Yes

NetWeight(gins )10. 00

2378-TCDDCone.< p p b )ND


3. 810

Area(He i g h t )320/322

/ ——— \


0. 33/ A "^ \

SurrogatePercentAccuracy

0. 0 '

Area3325376.

Area33416448.

Area320

0.

Area322

0.

Area257

Height3321648.

Height334

3105.

BkGnd3201471.

BkGnd322

1167.

MultipointRF-Native

0. 91

MultipointRF-Surr

1. 01

Comments - C13-TCDD e l u t e d at scai-l 1340The c o n d i t i o n code is SU'

REJECTED

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)SU - Surrogate 7. accuracy out of range


FORM 248-1

'•: '" " :; 0 0COMPUCHEM LABS •

RIC COMPUCHEM DATA; HR011015B03 SCAH5 300 TO 166009/65-'84 19; 188 00SflMPLE; 2 UL 11015 <C»2948-2 - DF003712 > 9-4-84 OWA# 03CONDS.s CPSIL88 50M 0.23M11 ID 80<2)240<20C-'MIN) CONTRACT MASSES 131(15 EA

9 27 372224.

QUJh-0LU—»LLJcc:

7:16'( . 8:53 U1^ 11:55 . 21:25 , 23:0924-09 ,JJt k '^^^^^^—i- U^—— . i ^Â^Ô^^^

6009:35

80012:47

100015:59'

12u019:10 22:22

1600 SCAN25(34 TIME

t- '; :•: • • 0 0

COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM DATAt HR011815B03 SCANS 1278 TO 1483BSêS^ 19;18i08SAMPLE: 2 UL 11015 (C»2948-2 - DF003712 ) 9-4-84 OMAtt 03CONDS.: CPSIL88 58M 8.23MM 'ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA , _» 13C12-2378-TCDD (INTERNAL STD)/'37CL4-2378-TCDD (SURROGATE STD) REJECTED

1B97.60.7-i 1 , . 4848^ . ^ 2224... ^'^l0" * r\ ^

^Â^^^^^^s^w"--/--^^•^vl.Ai321:^j --...—........i , 1 , 1 1 1 . -. 1-1— I;- i J^—„.—.—,-^•i.. _ ,.f^..^..j \p .^,11,,,.,. , _— f . 'û l f ' ' \f" \_ " ^ —" v___ • \—i • I.—.i.. .^..--.-. \- .1 f, 1 r\ A;t" ' \' . A ciiii

59.8-i328

A A •

^ A^^V-^^Â^^-^ AVv''\^V"^/'\J^^Âîm:

2192.328.098

CQQsJwW

72.1-332

21:251648.5376.

A 6|—————A-

2640.332.099

,1288 1300 1328 1340 1.363 1380 1400 SCAN20:27 20:46 21;05 21;25 21:44 22;03 22:22 TIME

^ c; . ••; 0 0

COMPUCHEM LABS 'RIC + MASS CHROtWrOGRAMS COMPUCHEM DATAi HR0U015B03 SCANS 1278 TO 140309/05/84 19!18i09SAMPLE; 2 UL 11815 <C»2948-2 - DF003712 > 9-4-84 OHA# 63CONOS.i CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA469 2378-TCDD <M/E 332 - 13C-2378 - AS RETENTION MARKER) -• ICPTFD

A A 1904'•>s^^\A—AS/\A/\A———————————————— 257.077'^VVV^ \ ^Â/^. . A A . ± 0.580

160.0-1322

22:011386.4256.

r\A.——/^——-^\3376.

322.836* 0.500

78.2-332

21:251648.5376. 2649.

332.899• A 0.500

284.4-1•RIC

9600.

_______,______V '^\._____A^ ,, rA_________A.^^^^\^--^ /\

1280 1300 1323 1340 1360 1380 1480 SCAN20:27 20;46 21:95 21;25 21:44 22:03 22:22 TIME

Lab: CompuChein Labs

SAS/Case: 294B-2

Batch tt : 113

File name: HR011064B03 DMA # 03Date Analyzed: 09/05/84 20:01ec column: CP SIL 8BBottle date: 9-4-84

CC « 11064EPA Sample « DF003717

Extra Net 2378-TCDD Detect Area Area SurrogateClean-up W e i g h t Cone. L i m i t ( H e i g h t ) ( H e i g h t ) Percent

( g m s ) ( p p b ) < p p b ) 320/322 332/334 Accuracy

Yes 10.30 -I—at)"" —— -Or-TCP 0.73 81.7^ [.-i ( t'^n < 0•7'?)

i—

Area Area Area Area Area Area332 334 320 322 257 328

B5952. 117664. 32024. 35536, 7816. 33912.33592. *

H e i g h t H e i g h t B k G n d BkGnd M u l t i p o i n t M u l t i p o i n t332 334 320 322 RF-Native RF-Surr

14235. 1B003. 0. 91 1. 01

Comments : C13-TCDD e lu ted at scan 1340The c o n d i t i o n c o d e is Rfii^~

-^L- ;

REJECTED

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)

RA - 320/322 ion ratio out of range** Corrected area 328 [328 - (0.009 X 322)3


FORM 246-1

0 0

COMPUCHEM LABSRIC COMPUCHEM DATAs HR011064B03 SCANS 300 TO 160009/05-'84 20; 01 seaSAMPLE; 2 UL 11064 <C»2948-2 - DF803717 ) 9-4-84 OWA» 03CONDS.s CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA9 27

6; 45

463840.

-,————j-400 6906:23 9:35 12:47

100015:59

12631S;10

140022:22

1680 SCAN25:34 TIME

- 0 0

37.4-1320 .

32.6-1328 .

82.3-1332 .

108.8-1334 .

259.6-1RIC.

1<•

RIC + ttflS09/05/84SAMPLES 2CONDS.t C» 13C12-2

^ v^vs^^/

-/•v,.,,,.^.-—.-,i^p-r^——^

21:2545881.v. ^/ \ 3968.

j -"-Y 23040.,

280 1308 1320 1340 1368 1380 1400 SCAN20:27 20:46 21:05 21s25 21;44 22;03 22;22 TIME

COMPUCHEM LABS •;S CHROriATOGRAMS COMPUCHEM DATAi HR011064B03 SCANS 1278 TO 143320:01:00

2 UL 11864 (C#2948-2 - DF003717 ) 9-4-84 OMA» 83:PSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA2376-TCDD <IHTERNAL STD)/37CL4-2378-TCDD (SURROGATE STD)

REJECTED32§24• 21;44 7024.

l\\. SSs m096^^ ^^-^'^^/ y^^v^..,^^ /v A * 8-500

21:265096.33912. 21s39r^, 1824.

J ^ 5632./ \ Â-s,'•••^•''•^•^^•^'•ÂA^V^1' ' i-\^^11 •K.,„ ,-«-„ j , , . . .^ V,, „ , , . , . , , , , , ,., „ . ,

21; 2414235.85952.

A21:2418063.117664.

/V

6128.328.098

t 0.500—— ^-^^^.^-^^

15456.332.899

± 0.500

18784.334.100

± 0.500

COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM OATAs HR8H064B03 SCANS 1278 TO 140309/65/84 20;01 seaSAMPLE; 2 UL 11064 <C#2948-2 - DF003717 ) 9-4-84 OMA» 03CONDS.i CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA469 2378-TCOO <M/E 332 - 13C-2378 - AS RETENTION MARKER)21:251672. REJECTED

21; 256852.^S24- 21;44

1723.^ 18248-t^Hî

7024.320.096

± 0.500

6656.322.6%

± 0.506

15456.332.899

± 0.500

48768.

1403 SCrtH22;22 TIME

Lab: CoflipuChem Labs

SAS/Case: 2948-2

Batch # : 1 1 3

File name: HR011106B03

Date Analyied: Ollc'S/S1-)

GC column: CP SIL SB

Bottle date: 9-4-B4

CC # 1 1 1 0 6

EPA Sample # DF003721 - " '

QUA « 03

-frr-0&-.s res^C-;50

ExtraClean-up

Yes

NetWeight(gms )10. 40

2378-TCDDCone.( p p b )ND


7. 790


( ——)


0. 00( 0.00)

SurrogatePerceo'tAccuracy

0. 0.

Q

Area332

0.

Area3346911.

Area320

Area322

0.

Area257

Area328

Height332

Height334

1945.

BkGnd320

1295.

Bk6nd322

912.

MultipointRF-Native

0. 91

MultipointRF-Surr

1. 01

Comments: C13-TCDD eluted at sca-n 1343The condition code is SO

\l '

REJECTED

RB - Reagent BlankN - Native TCDD SpikeD - Duplicate (Intralab)SU — Surrogate X accuracy out of range


FORM 248-1

00COMPUCHEM LABS •

RIC COMPUCHEM OATft; HR011106803 SCANS 388 TO 16&089/85/84 28;50:68SAMPLE; 2 UL 11106 <C»2948-2 - DF003721 ) 9-4-84 OMAtt 03CONDS.! CPSIL88 50M 0.23MM ID 60<2)240<20C/MIN) CONTRACT MASSES 131MS Eft9:27 364544.

0LU

5UJ3CH

5:45

10! 39 17:24

23' 08

^^^^&Â^

4006:23

6839:35

80012;47

160015:53

120819;18

140022:22

1608 SCAN25:34 TIME

COMPUCHEM LABS •RIC + MASS CHROMATOGRAMS COMPUCHEM DATA! HR811106B83 SCANS 1281 TO 146609/05/84 20:58:00SAMPLE; 2 UL 11106 <C»2948-2 - DF603721 ) 9-4-84 OUA» 03CONDS.: CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA ^,-,-^sl; 13C12-2378-TCDD < INTERNAL STO-WO^^Pe-TCDD <SURROGATE STD> REJECTED

ÂA^^^mA/V^\-WV^^-v^/VV^^^^MA

328.098

•v^—v-v^y^ ^/^^y^ ± e-500

21; 251945.£911. 2736.

334.100, * ^.f^.

_ _ _ _ _ _ _ _ K . A . _ r ^ ^ - ^_________»_______________A A 334.100

/VÂ^ VÂV ^--L-VV"^L--V^•vAA^^^^ ± 0-500It-....,, „ , .„,,...„.tt,..._..._———. ,.....„..———ii,,,...,,-,^—,., , , ....,,. . .,.-.—. ....„,.- 1 , 1 .,,.,,,i—..i.,,,,,,—.——.,in i——.Jt..^———l. ,.,.,.,————.,_- ...... i..,,,..-.—....., iK.i.i 1 1 ^

6656.

1300 1323 134020:46 21:05 2l!25

1368 13B0 1400 SCAN2l!44 22:03 22:22 TIME

•I' 9 8 \! O 0

COMPUCHEM LABS 'RIC + MASS CHROMATOGRAMS COMPUCHEM DATA; HR01110GB03 SCANS 1281 TO 146689/05/84 20:50:08SAMPLE; 2 UL 11106 <C»2948-2 - DF003721 ) 9-4-84 OUA» 03CONDS.; CPSIL88 50M 0.23m ID 88<2)240(20C/MIN) CONTRACT MASSES 131MS £A469 2378-TCDD <M/E 332 - 13C-2378 - AS RETENTION MARKER) pr ICPTFD

—————————————————————————A-»————————————/V\————————)./, A—A——————————————————————

Â/VsWVW^^r L^^'V W^^VMA•* 1 1 1 1 . .... .1. . . I t .V, .y Ui ., T..,,, ...I ....—. . . , - . . , , J,—- , , . . i . i , i i .1 I — . ,... — 1 1 . . 1 1 ...———t,.»,——.„ „ i ... i ..—. i ..^»——>..i.-^^Hi-^-iJt.-^.

1680.257.077V \A A——— 25?-077

V\A ± 0•5aa

p, 1552.v^^^W^^13%ssi...i- i .i...i- i . |H»...IMM —n.—<i ...l—«——.—ia.r 1 1 i ii-v.SwIMummw.^-wn , i i. . i 1 1 •11 1i... .... ..——...ll

2192.332.039± 8,500

6656.

1380 1328 134020;46 21:85 21:25

1360 1380 1480 SCAN21:44 22:03. 22;22 TIME

0 0

COMPUCHEH LAE:£MUSS SPECTRLH109-'i35^84 23:22 sen + 12:51SAMPLE; 41JL 11872

DATA: PCUllb72B21 ftlLT23 BASE 11/E; lb5RIC; 9£7£:S.-

165

173

193

169

235

155

1 215

!

161

1 1 1 III I 1• j i . 1 ^ 1 . . i i r i i

2k)7

221

278

243 2b4

. 1 . . 1 ll Ilil -d

'^2

.41

36S

blul l i 3 1 6 ! ! ! 3 3 61 1 ^ , 1 1 1 1 ll , ll

r- 2528

341' 1 ' ' '

10

Q '" 0 0

COMPUCHEM LABSMASS SPECTRUM09/85/64 23:22:B8 + 12;46SAMPLE; 4UL 11072#1821 - #1828 XI.00

DATA: PC011U72B21 #1821 BASE t'l/'E: 334RIC; 3728.

322334

187

213

223

328

278

257

199 233211

284

250175

2ub 299232

M'F 1fTl If.p - ni-t

MASS LIST09/05/B4 23:22:00 + 12:46SAMPLE: 4UL 11072#1021 - #1028 X I . 00

COMPUCHEM LABSDATA: PC011072B21 K1021 BASE M/E:

R I C :334

3728.

155 0. 00 M I N I M A336 * 0 M A X I M A

MASS 7. RA MASS

M I N INTEN:

7- RA

0. MAX INTEN: 251.

41. 046. 372. 39

56. 9715. 9427. 09

1. 2019. 920. 40

49. 4014. 342. 39

33. 471. 99

21. 1227. 49

6. 7731. OB11. 5511. 5557. 7711. 9550. 6011. 553. 592. 39

11. 168. 37

34. 663. 19

10. 7622. 31

5. 589. 968. 76

38. 2529. 0811. 55

1. 9947. 416. 77

31. 086. 371. 205. 5B9. 9&

11. 1613. 9415. 94

1. 20

298299300301302307316317319320322324326328329332334336

3.14.3.2.

1 1 .3.2.0.9.

76.9B.63.30.56.9.

82.100.38.

197419799559398016490135689796470025

COMPUCHEM LABSMASS CHROMATOGRAM COMPUCHEM DATAi HM84e90SAB3 SCANS 1248 TO 194Q89/81/84 8l27iB9SAMPLE! 2 UL < ISOMER MIX > OMft* 03CONOS.i CPSIL98 58M a.23MM ID e8<2)248<2BM1IN) COHTRACT MASSES 131MS EA469 2378 000 <M/E 332 - 13C-2378 - AS RETENTION MARKER)

^—^ £ > , f i ~ ? y /U(J ^ i • / ' ~ f131532.

319.500322.490

13OT'W.4C;

i4n'>i»y>

i sea^•^B 1600W814

180137fli43

198030121

SCANTIHE

9 P t7 0 0

COMPUCHEM LABS ' „RIC + MASS CHROMATOCRAMS COMPUCHEM MTAi m8409(M»»3 SCAMS 1278 TO 140309/93/84 8t27«W ' iSAMPLE! 2 UL ( ISOMER MIX > OMft» 83 : ' :

CONOS.l CPSIL88 SOM fl.2311f1 ID 88<2)248<2(>C/flIN) CONTRACT MASSES 131MS EA I» 13C12-2378-TCOO (INTERNAL STD)/37CL4-2378-TCOO (SURROGATE STp)

21«11 21.26 2li4^ :471 •q 49433. 31834.227917536. 3%B36. , . 283432.34.9-1 i 229776.

329 .

21«25 , I54813. i

3S.4-1 332413-328

79.5-1332 J

i • i • i ••

IW.e-i 948^1.334

' ' ' ' ' '

291.B-1 21illRieJ 137984.

•} 668544.• 1 -' 'Y

1288 13^ 1379'><».'»•» 'Wiê '»<.rm

A.,

/ V . * e•5M

, / \ t 9.SM

30583y w i \^ i * 0.5<»/ \

21i24120467.73^CT• 120832./ \ 332.B99/ '< t B.5M

21i24151687.

/ \

21l23443392.

29fl??99- 21845/ \ 15744B./ \ , 856960.

7 Y^ -r s,. . .1340•»» ,w

6.-^

1360 1389'>it<4 '• '??t(n

283432. fc^tÂi /\ t 53120./sA

"i';,' ,' '

i ' i '

1400 SCAN

320.096

5S424.328.098

152964.334.180

443392.

7?»'?7 TTMP

9 G h 0 0

COMPUCHEM LABSRIC * MASS CHROHATOGRAMS COMPUCHEM DATAi HK848905A03 SCANS 1278 TO 140389/93/84 8t27t80SAHPLEl 2 UL ( ISOMER MIX ) OMMt 03COHOS.i CPSIL88 SCH e.23MH ID 6e(2)24e<20yMIH) CONTRACT MASSES 131MS EA469 2.3,7,8-TCOO (QUATERNARY ION)

21111 21i26 21«*547153. 49433. 51834.229,776. 3BS936. , , 283432. ,53120.

21l2S443392.

1289^l* ^"»

-T1308''o. <r

21ill137984.668344.

1328T

138Q'>?•«'>

443392.

1498'?'7.9-»

SCANTTMC

Ptrfor»anc» Chick Standard Diagnostics

File n«» : HK84090SA03

Input •can: 1340

Oiagnoctic Calculation Valu« Pass/Fall

C colu-n pTfor—noVall tV/Pfk for 2.3.7,8-l»o—r ( 1 4 . ) / < II1?. > .11X Pa««

ativ TCDD cass ratio320/322 ratio (0.&7-0.87) ( 305B3&.)/( 404912.) 0.7& Pa*s

S Resolut ion -y-323/322 ratio (0.07-0.20) ( 36S1B.)/( 404912.) 0.14 Pa»» ^

0

nt«rnal standard •ass ratio332/334 ratio (0.67-0.87) ( 739167. ) /( 940111.) 0.79 Pa»»

urrogate rcspons* factorRF •«• below («) 1.038HP averag* I.009RF / MP avj (+/- 10 X) 2.86 X Pa«»

» RF - (SOOt 352413. - (0.009X 404912.))) / (( 739167. + 9 4 0 1 1 1 . ) ( 1 0 0 ) )

A e 17 o oCOMPUCHEM LABS

MASS CHROMATOGRAM COMPUCHEM DATA; HM8409058B83SCANS 1237 TO 170809/05/84 17!i8;00SAMPLE; 2 UL < ISOMER MIX ) OUA» 03CONOS.: CPSIL68 50M 0.23m ID 80<2)240<20C/'MIN) CONTRACT MASSES 131MS EA469 2378-TCDO <M/E 332 - 13C-2378 - AS RETENTION MARKER)

2U43 152320.

319.500322.490

20801 -»a AC J "^^^SW ...

1360;a;46

140022:22

150023:58

160025:34

1760 SCAN27:10 TIME

COMPUCHEM LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA: NM8409050G03SCANS 1275 TO 1400es/es i7;i8:eeSAMPLEi 2 UL ( ISOMER MIX > OUA« 03CONDS.t CPSIL88 50M 0.23MM ID 80<2)240<20C/'MIN> CONTRACT MASSES 131MS EA» 13C12-2378-TCOO (INTERNAL STO>/'37CL4-2378-TCDO (SURROGATE STQ)

21:0846973.

35.7-1 231928.329

1 ' 1 • 1

34.2-1328 .

82.3-1332 .

21:22

100.8-1 97/2927-334 J

]I • i • l

282.8-RIC.

1280 1300 132010.17 '50..1C •11.fl^

A362,115.

..,„...—.,,„., r- —————,——,. ——..,.„—,

21; 08138772.728576.

-,,-^..,.,.,,, . , , , . - . . , ,, ...„„-.„,——.„ .- ..-..'' -,

21123 21^349423 53438.314566. , 327834. 54144./^/Y\/ ^^^1 i ^^^-

21:2450760.

21:22123777.770255.A-,150602.

i \j \ ^ ± 8.500

21:22428544.3826K0. 21:43

/ \ 156928. '/ \ , 977024.

1 ' 1 ' 1 "" '

1340 1360 1380?l»'?"? 21it4 2?:B3

320.0961 0.500

'

51776.328.098

1 0.308

'

124672.332.899

1 0.500

151552.334.100

428544.

11400 SCAN22:22 TIME

/. n i7 o oCOMPUCHEM LABS

RIC + MASS CHROMATOGRAMS09/05/84 17(18:00

COMPUCHEM DATAt, HM8409050B03SCANS 127S TO .1400

SAMPLE; 2 UL < ISOMER MIX ) OMA» 03CONDS.: CPSILB8 50M B.23MM ID 80<2)240<200MIN> CONTRACT MASSES 131MS EA469 2,3,7,8-TCDD (QUATERNARY ION) 21:43

53438.327834.

21i08 21:2349423.314566.46873.

21:22123777.770255. 124672.iee.0-

332 332.0991 0.500

21:22428544.3626170. 428544.

1400 SCAN22:22 TIME

PTforaance C h e c k Standard Diagnost ics

File name : W1S409050B03

Input scan: 1337

Diagnostic Calculation Value Pass/Fail

CC column performanceValley/Peak for Z, 3,7. B-isoaer ( 2 1 . ) / ( 108.) i9X Pass

Native TCDD mass ratio320/322 ratio (0.67-0.67) ( 314566.) / ( 41924B.) 0.75 Pass,.

MS R e s o l u t i o n 0323/322 ratio (0.07-0.20) ( 45440.)/t 41924B.) 0 .11 Passo

Internal s tandard mass ratio332/334 ratio (0.67-0.87) t 770255.)/( 972927.) 0.79 Pass

Surrogate response factorRF see below <») 1.027MP average I. 009RF / MP avg (+/- 10 y.) 1.81 X Pass

< RF = (500( 3&2115. - (0.009X 41924S. ) ) ) / « 770255. + 972927.)(100))

c /. P t7 0 0

COMPUCHEM LABS 'MASS CHROMATOGRAM COMPUCHEM DATA; HN840905B03 SCANS 1235 TO 160009/85/84 21:32:00SAMPLE! 2 UL < ISOMER MIX ) OUA# 03CONOS.: CPSIL88 50M 0.23MM ID 8a<2)240<20C/MIN> CONTRACT MASSES 131MS EA469 2378-TCDD <M/E 332 - 13C-2378 - AS RETENTION MARKER)2l!39 120576.

20:00

319.500322.498

125019:58

130020:46

135021:34

140022:22

145023; 10

150023:58

155024i46

1600 SCAM25:34 TIME

\7 0 0

COMPUCHEM LABS •RIC + MASS CNROMATOGRAMS COMPUCHEM DftTAt HN840905803 SCANS89/05/84 21:32;90SAMPLE! 2 UL < ISOMER MIX > ONAtt 03CONDS.i CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN> CONTRACT MASSES 131MS EAt 13C12-2378-TCOD (INTERNAL STO)/37CL4-2378-TCOD (SURROGATE STD)

21:04 21121 J1-40

32078. 34432. ww"36.6-1 177438. 233952. . , T^320. r\ f\^ /-y\

1. ' 1 ' 1 ' 1 ' 1 ' 121:2133847,

31.4-1 246656.328 .

1 '••" ' 1 • ' 1 , . . . . . . . , | , |21:1984303.

77.8n 53^19-332

21:19108023.

100.0-, 69W6-334

1 ' 1 ' 1 ' 1 • 1 ' 121820290494.

269.6-1RIC

1———j—————,—————j—————,—————j—————,—————j—————,—————j—————i—————j———1289 1300 1320 1340 1360 138028:27 20:46 21;05 2H25 21:44 22:03

/ <- / Y/ 1 \^.

/ \/ Y ^ ± 0.500

/ \ ' 334.100y^ ,2076960, 21:39

964fl /\ 116835.albia. / \ 7-?i7';i«K^ j \^3S^

1273 TO 1398

39872.320.096

1 0.500

'

34176.328.098

1 0.500

'

84608.332.099

168609.

± 0.500

'

293376.

SCANTIME

00

COMPUCHEM LABS 'RIC + MASS CHROMATOGRAMS COMPUCHEM DATA: HH840905B03 SCANS 1273 TO 139809/05/84 21132:00SAMPLE: 2 UL < ISOMER MIX ) OHA# 03CONDS.l CPSIL88 50M 0.23MM ID 80<2)240<20C/MIN) CONTRACT MASSES 131MS EA469 2,3.7,6-TCDD (QUATERNARY ION)

2l!04 21:21 Jig4832078. 34432. w'^177488. 233952. , 24b^7b• 39872.

320.996± 0.500

21:1984303.534319.108.0-1

33284608.

332.099± 0.500

21:20290494.2075960. 293376.

SCANTIME

Performance Check Standard DiagnosticsFile name : HN840905B03Input scan: 1335

Diagnostic Calculation Value Pass/FailGC column performance

Valley/Peak •for 2- 3- 7, 8-isomer ( 2 1 . ) / ( 105. ) 20X Pass

Native TCDD mass ratio320/322 ratio (0.67-0.87) < 233952. > / ( 290163.) 0.61 Pass

MS Resolution323/322 ratio <0.07-0.20) < 42888.)/( 290163.) 0.15 Passo

Internal standard mass ratio332/334 ratio (0.67-0.B7) ( 534319.)/< 6 9 7 4 9 6 . ) 0.77 Pass

Surrogate response factorRFMP averageRF / MP avg <+/- 10 X)

see belou) (*) 0. 9901. 0091.B7 7. Pass

RF = (500( 246656. - <0.009)< 2 9 0 1 6 3 . ) ) ) / ( ( 534319. + 6 9 7 4 9 6 . ) ( 1 0 0 ) >

signed

3UANTIT.-.TION REPORT FILE: TS840905A03

DATA: TS840905A03. TI09/05/84 9: 24: 00SAMPLE: 2 uL Std Lot C-031 (CC1 0.2 ng/rl) QUA* 03CONDS. : CPSILB8 50M 0.23MM ID 80(2)240(20C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST: 643

AMOUNT»AREA » REF.AMNT/<REF.AREA)* RESP.FACT)SESP. PAC. FROM LIBRARY ENTRY

NO1234S&

NO123436

MATE» 13» 13469469469•37C

M/E333334320322257328

CIS-237C-2, 3, 7

2378-T2,3- 7,1, 3. 7.

L-2. 3. 7

SCAN133613361338133813391338

fQ-

.8-CDI8-8-1.8-

T212121212121

TCDD-TCDDD (MTCDDTCDB-TCDD

IME212123232423

<IN(S

/E(SEITE.

(S

REF111111

TERNALECONDAR332 - 1CONJDARY.RTIARYiURROGAT

RRT1.0001.0001.0011.0011.0021. 001

STD)/37CY ION)3C-2378

ION)ION)E STANDA

METHA BBA BBA BBA BBA VBA BB

L4-2378-TCDD

- AS RETENTIC

AD)

AREA(HGHT)1938380.2449460.3S03S2.4S1784.193988.283416.

(SURRO&!

3N MAR KEF

yc-r/AMOUNT

SOO.OOO514-9fe2

19. 70219.84224. 0295. 9&4

iiTE' STt

0

l ^ /^ .

PC/ULPS/Ul-pe/ULPC/ULPG/ULPS/UL

0)

XT46.47.

1.1.2.0.

IDT104802832255

Input «can: 1336

DiagnoiticMS Sensitivity

Signal to Noil* ratio257 ion < > 2. 3 )322 ion < > 10.0 )

257/322 ratio (0.20-0.43)

Value

0. 43

Pass/Fail

Pay.

f!a^_Pass

Nativ TCDD respons» factorRPMP avragBRF / MP ava <+/- 10X)

0. 9140. 9140. 10 X Pass

Surrogate response factorRFW avrag*RF / MP avg

1.0611.0093.09 X

//, /^xsigned

o e 9 fr o o

15.4-1320..

11.6-1328 .

79.1-1332 .

160.0-1334

219.1-1R1C.

RIC + MASS CHROMffI89-'05/84 17(57(00SAMPLE: 2 ULCONOS.i CP5IL88 5(* 13C12-2378-TCDO

21:2295787.674215.

21:23289594.1566640.

1280 130026; 27 20:46

roGRAfisSTO LOT CCl

m 0.23MM ID 80(2)24(INTERNAL STDV37CL

132021:05

COtlPUCHEM

<CC1 08<200'MIN)4-2378-T(3)[

21:2513943.90880.

21:2510687.

i\21:2375997.534608.

1134(121:25

LABS 'COtlPUCHEM DA

2 NG/ML)CONTRACT MASSES

) (SURROGATE STD>

^^ .

^^-^

^—-

136021:44

TA: TS840905B023SCANS 1276

OMA« 03131HS EA

11232.328.098

± 0.500

1380. 22:03

TO 1401

14928.320.096t 0.500

76416.332.899

* 0.590""T

96640.334.1001 0.500

211712.

1400 SCAN22:22 TIME

I. 8 8 fr 00

C011PUCHEM LABSRIC + MASS CHROtlATOGRAMS COMPUCHEM DATA: TS840905B023SCAN5 1276 TO 148109/85/84 17;57;88SAMPLE: 2 UL STD LOT CC1 (CC1 8.2 NG/t1L> OUA« 83COHDS.l CPSIL8B 58M 0.23MM 10 88<2)248(28C/MIN> CONTRACT MASSES 131MS EA4S9 2378-TCDD <M.'E 332 - 13C-2378 - AS RETENTION MARKER)

21:243662.36112.8 r- Wlli.

.6-1 A."'I /X2l;2513343.

19.5i 30880-328 .

21:2516133.

22.2n 12^64-322

75997.100.8-, 534raB-332 .

1 ' ) . . . , . | . , . .., .. . , ..—.- i • • • | . r2li23209594.

277.1-, l566M0-RIC.

/ \y \s^ ± 8.588

/ \/ V.

/ \/ \^ ± 8.588

6544.257.877

± 8.588

14928.328.896

'

16992.322.096

X V 5v0

76416.332.899

211712.

QUANT I TAT I ON REPORT FILE: TS840905B023DATA: TS840905B023. TI09/05/84 17:57:00SAMPLE: S uL Std Lot CC1 (CC1 0.2 rig/mi) OWA# 03CONDS.: CPSIL8B 50M 0.23MM ID 80(2)240(20C/MIN> CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST: 802AMOUNT=AREA • REF.AMNT/(REF.AREA)* RESP.FACT)RESP. FAC. FROM LIBRARY ENTRYNO NAME1 * 13C12-237B-TCDD (INTERNAL STD)/37CL4-2378-TCDD (SURROCATE STD)2 » 13C-2*3.7.B-TCDD (SECONDARY IQN)3 469 2378-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 469 2,3.7,8-TCDD (SECONDARY ION)5 469 2.3.7,a-TCDD (TERTIARY ION)6 #37CL-2.3,7. 8-TCDD (SURROGATE STANDARD)

NO123456

M/E332334320322257328

SCAN133B13371340134013391340

TIME212151212121

232325252425

REF111111

1.0.1.1.1.1.

RRT000999001001001001

MEAAAAAA

STHBB3BBBBBBBBV

AREA(HGHT)534608.674215.90880.

127664-36112.72596.

AMOUNT500.000513.9SS18.53220. 33216.055

5. 540

XTOTPS/UL 46.54PG/UL 47.84PC/UL 1.72PG/UL I.89PG/UL 1.49PG/UL 0. 52

Input scan: 1338

DiagnosticMS Sensitivity

Signal to Noise ratio257 ion ( > 2. 5 )322 ion < > 10. 0 )

257/322 ratio (0.20-0.45)

Value

0. 28

Pass/Fail

Pass

Native TCDD response factorRFHP averageRF / MP avg (*/- 10X>

0. 9030. 9141. 20 V. Pass

Surrogate response factorRFMP averageRF / MP avg

0.9851.0092.42 X

^ fW signeac-o^ •

COHPUCHEH LABSRIC + IttSS CHROMATOGRAKS COMPUCHEM DATA) TS8499e5AB3 SCANS 1274 TO 139999/95/84 9)24108SAIfLEi 2 UL STO LOT C-831 <CCl 0.2 HG/tt.) OMAt 03CONOS.l CPS1L68 Sen B.2311H 10 6B<2)2W2eC/HIN) CONTRACT MASSES 131MS EA469 2378-TCDO (11^ 332 - 13C-2378 - f6 HETEWIOH HARKER)

2C318.9.9-1 19^8' 2684B.

^_____________S237 -1 / \ ^

17.4-,329 J

1——^————p-

22.4-,322 J

198.8-1

w}

271.5-1RICJ

' ' ' ' 21i33 ' '312(13.

. . . .7^ ,21)2366322.451784.

, , f\ ,2li21297798.1938S8a.

1 1 ' 2li21 ' ' ' 'B87424.

7^

51712.320.896t B.SM

66816.322.036* e.see

———l———,———

297964.332.B99t 0.598

- l— ,•-,-)——,

B89968.

1280 1380 1328 1340 1368 13882Bi27 28146 2ll85 21l25 • 21l44 22»83

SCANTIHE

0 0 4 8 8 5

COMPUCHEH LABSRIC + HASS CHROHftTOGRMB COMPUCHEM DftTfll T58489B»83 SCUMS 1274 TO 139989/83/84 9l24)00SAMPLE! 2 UL STD LOT C-851 <CC1 8.2 NG^L> OMA* 03COOS.) CPS1L88 SOI B.23HH 10 89<2)24B<2eC/t1IN) COHTRACT HASSES 131HS EA» 1X12-2378-TCDD <IHTERNftL STD)/37CL4-237e-TB)0 <SURfW»TE STO)

21l23S1283.

31712.13.4-320 _ 326. BX

i 9.W

——1—————————————————————————r,^——————————————————————————————46296.

l».7n 283416. ^^328 J / \ 328.838

1 / V , * e.3W

21(21237788.

•T_____^77.S-1 13WW. 237394,332 J / \ 332.B99

* 8.388

21)21384143.

IBB.B-334 J

384912.334.188* 8.388

21|21887424.

^_____________^210.

RIC.

1288 1308 1328 1348 1368 138828l27 29i46 ZllBS 21l23 21l44 22lB3

SCANTIME

0 0 4 8 8 4

~v

*» f

S3

A*-^

cxn

-fc

0 f

c. » So

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^»-i

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3 i

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^ 1 ^

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a r* ^ 0 «— ««

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«H

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t-, IT r -• r» ,1

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48

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^J 1 «4 1*1

t» •W -< n •t •* 0 -%

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*• »• •\» -• *» rw • *• •-• r*• 1 0 •« -» ,* 0 -» ;< w* w «0 < ^

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' n -• *• tT ^. r w m -< •w f* y ^ » — w ^ - "^

«J« n m r> » t — -• r* y r f 0 f - 0 0 - 3 w *-*

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<-' r1

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m0 f -» r» f* r* ?, 1

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•-» 0 u> u» *0 f rt — 3 0 - 1 •o no ^ t, ^

u» Ut m ir nr •»* K IT

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«-•

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S-~

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(» v» f•* 15 -» «-» f ,* 1 w •O (0

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^ •« tft

*0 • \ »\>r* 0 I • f* n* 0 -» • - •

» < r 'r f -a n f

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^ <-<

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rt r» -» .4 • t w I?»

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9 P S i7 0 0

COtlPUCHEtl LABSMASS SPECTRUMeg/es 17;34;00 + 8;56SAMPLE; 1UL 12486-7050»715 TO #716 SUMMED - tt945 X2.16

DATA; DH840935B21 #715 BASE M-'E; 198RICs 101376.

198

51

63' ' ' i '1 ' i ' i • i ' 1 •ll.

lie

i,,, 8.9 ,.9,9. Ll. . ...

1 1 7

• i ' i ' i • 1 ' i ' i ' i '

| 186

141 ,153 167 1731. « 1

1 '

255

206

224 244

^ 1 . 1 --I-.-T2 1 1 1.1, in. . . 237. 11 | i • i ' i ' i

275

1 , 265 .ill. 234

100 150 290 259

315 3?4 346 356 . 372 483 423

1ASS LIST39/05/84 17:34:00 + 8:563AMPLE: 1UL 12486-7050#715 TO #716 SUMMED - #945 X2.10

COMPUCHEM LABSDATA: DHB40905B21 # 715 BASE M/E: 19B

RIC: 101376.

50 0.00 M I N I M A444 # O MAXIMA

MASS 7. RA MASS

MIN INTEN:

7. RA MASS

0.

7. RA

MAX INTEN: 14864.

MASS 7. RA

9. 3538. 81

1. 650. 350. 200. 521. 630. 040. 32

45. 803. 096. 011. 84

44. 032. 66

. 1. 982. 632. 030. 060. 300. 220. 360. 172. 610. 691. 181. 420. 421 . 320. 820. 250. 23

14. 182. 44

31. 593. 560. 818.010. 72.0. 650. 750. 890. 20

48. 763. 08

17. 631. 000. 300. 200. 54

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24.6-1322 .

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1940 5CAH31(00 TIME

aUANTITATION REPORT FILE-. TSB40B20Be3

MTA. TBB40B20603. TI»8/ao/B4 iB:33.oeSAMPLE: 2 uL BTD LOT C-C51 (CC1 8.2 NO/MI.) OUA« 83:ONDS. •• CPSILBB BOM 6. 23MM ID BO(e)240(2eC/MIN) CONTRACT MASSES 131MB EASUBMITTED BY: 83 ANALYST: 643

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NO NAME1 • 13C12-237B-TCDD (INTERNAL STD)/37CL4-£37B-TCDD (SURROGATE STD)2 » 13C-2-3. 7»8-TCDD (SECONDARY ION)3 469 237B-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 469 2.3.7.B-TCDD (SECONDARY ION)5 469 2. 3. 7-8-TCDD (TERTIARY ION)6 #37CL-2, 3. 7.B-7CDD (SURROGATE STANDARD)

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M/E33233432032S25732B

SCANAB784.B78J.B80ABBe1BB61B79

TIME303030303030

606062620261

REF11111i

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77.6-1332 .

188.8-1334 .

348.4-1RIC.

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30:6141463.242768.->-» i .rt-.ba.27.1-1 /^

237 .

74.4-132B .

iee.e-i322.

91.2-1332.

489.3-1RIC.

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626364.3987440.

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AMOUNT-AREA • REF. AMNT/<REF. AREA)» RE9P. PACT)i£SP. FAC. FROM L-IBRARY ENTRY

NO NAMEA • 13C12-237B-TCDD (INTERNAL STD)/37CL4-237B-TCDD (SURROGATE STD)£ » J.3C-a 3. 7. 8-TCDD (SECONDARY ION)3 469 2378-TCDD <M/E 332 - A3C-237B - AS RETENTION MARKER)4 469 £,3.7.B-TCDD (SECONDARY ION)5 469 E.3<7,B-TCDD (TERTIARY ION)6 #37CL-2, 3. 7. B-TCDD (SURROGATE STANDARD)

NO1£3456

M/E33S33432032225735B

SCANA8771B77J.B791B79J.S791B79

TIME292930303030

5959ei&10101

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11294Ba.677775.930495.£42763.22B432.

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36.42.

6.7.5.0

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RESPONSE FACTOR OF BURBO&ATE « 0. 951

I- 0 6 17 0 0

COHFUCHEH LABSRIC + MASS CHROMflTOGRAMS COMPUCHEM DATA: TU840828C83 SCANS 1811 TO 193608/26/84 4:59:66SWLEi 2 UL STD LOT CC3 <CC3 5.6 HG/1-1L) OMH» 63COUDS.! CFSIL88 56(1 a.23MH ID 8fl<2)24e(29C/HIN) CONTRHCT riflSSES 131HS EA» IX12-2378-TCOO <IHTERHrtL STD)/37CL4-2378-TCDO (SURROGATE STD)

SSTSaS.108.0-328 .

12.6-1328 .

23.5-1332 .

30.6-1334.

341.4-1- RIC.

5362490.

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111277.652634.

A .29s55 '297773.1240368.

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29:533031036.18664700.

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1900 132038(21 30141

887808.320.696± e.see

111488.328.698

1 6.568

296384.332.699

± 6.566

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1 6.566

3631636.

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76.2-1328 ,

iee.e-i322 .

17.9-332

268.1-RIC.

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•29.55 •1165310.7631050.

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J&WM0*

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887868.320.096

1 0.500

1165310.322.095

1 0.300

208384.332.099

± 0.500

3031030.

1360 1920 SCHH38121 30t41 TIME

iUANTITATION REPORT FILE. TUB40B2eC03

OATA: TUB46B26C63. TI98/20/84 4:S9:B6SAMPLE: £ uL BTO LOT CC3 <CC3 S. 0 NO/MI.) OUA« 83;ONDS. : CPSILBB 56M 6. 23MM ID B0<2)24e(26C/MIIM) CONTRACT MASSES 131MS EASUBMITTED BY: 83 ANALYST: 619

AMOUNT-AREA • REF. AMNT/(REF. AREA)* RE9P. FACT)Ê9P. PAC. FROM LIBRARY ENTRY

NO NAME1 » 13C12-237B-TCDD (INTERNAL STD)/37CL4-237B-TCDD (SURROGATE STD)S » A3C-S. 3. 7. B-TCDD (SECONDARY ION)3 4&9 237B-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 4&9 2,3.7»B-TCDD (SECONDARY ION)5 4&9 E,3.7,B-TCDD (TERTIARY ION)6 #37CL-2-3. 7. B-TCDD (SURROGATE STANDARD)

NOXs345&

M/E3323343503S2257328

SCAN1B721B721B74187318741873

TIME292929292929

55555&555&55

REF111111

1.J-1.1.J-1.

RRT600600601601601601

MEAAAAAA

:THBBBEBBBBBBBV

AREA(H<;H11£403&51^3&9&a.5S&E490.7to3ie55.1920540.

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•) AMC560.537.471.4B2.3&B.21.

>LINT600B7331662&626466

PG/ULPG/ULPC/ULPC/ULPG/ULP6/UL

XI21.22.19.26.15.

6.

•OT605979274590

RESPONSE FACTDH OF NftTSVE TCDD • 6. B&l

REBPONSE FACTOH OF BUI»»tOI»ATE « 1. 024

f r O 6 17 00

COMPUCHEH LABSRIC + MASS CHROMATOGRfltIS COMPUCHEH DATA: TW40826C83 SCAMS 1820 TO 194588/28/84 7:86(86SAMPLEl 2 UL STD LOT CC4 <CC4 28. HG..-HL) OUA« 83COHOS.: CPSIL88 58H 6.23MM ID 88(2>246(28C/HIM) CONTRACT HfiSSES 131H5 EA» IX12-2378-TCOO (INTERNAL STD)/37CL4-2378-TCOO (SURROGATE 5TD>

30s 042289eea.13252788,188.e-i l^fw9•

329 .

30! 6331B56.

1.4-. lw56-328 .

38:82123155.

5.4. 73fl^332 .

i | i | ' 1 ' 1 " • • • i • • •38:82158631.

7.(H 97^71-334 .

————,————,————,————1————,————I————,————I————,————38:84

6887S58.297.3-1 4013^988.

RIC.

/ \ 38:58 , 326.696y \^/ S

/ ^

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' 1 ' 1 ' 1 ' ' 1 '

2289668.

2266. ±8.5887072.-1————'————1——

31744.328.898

± 8.588i • i

124168.332.699

1 9.386l b i

159488.334.188i 6.S68

l • i

6867550.

l ' lSCnHTIME

S 0 6 1 7 0 0

COHPUCHEM LAB?RIC * MASS CHROMATOGRAMS COMPUCHEM DATAl TU848820C83 SCflNS 1828 TO 194568/29/84 7(69(08SfiHPLEl 2 UL STD LOT CC4 <CC4 28. HG--ML) OHfi* 83CONDS.8 CPSIL88 5911 8.23HM ID 8a<2)248(2aC/HIH> COHTRflCT WSSES 131HS Efl469 2378-TCOD (tME 332 - IX-2378 - AS RETENTION MARKER)36:84

829877.4716798.27.4-1

237 .

75.6-1328.

100.8-1322.

4.1-1332.

224.9-,- RIC.

<\fwa».

A38:84

2283£6a.13252798.

A1 38:84

3826948.17417780.

/V1 ' 3aS82

123155.738216.

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829440.237.877

* 8.580

2289660.38i5fl 328.6962266. i 0.5087872.

3826940.38:48 322.6963768. i 8.36816928.' • •

124160.332.699

± 6.580

6867558.

' l y 1SCANTIME

1UANTITATION REPORT FILE: TVB40B20C03

lATA. TVB40B20Ce3. TI38/20/84 7:®0:00SAMPLE: 2 L)L BTD LOT CC4 (CC4 20. MB/ML) OUAtt 6330NDS. : CPSILBB 50M 0. 23MM ID 80(2)240(20C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST-. &A9

•tMOUNT-AREA • REF. AMNT/(REF. AREA)» REBP. PACT)ÊSP. FAC. FROM LIBRARY ENTRY

NO NAME1 •» 13C12-237B-TCDD (INTERNAL STD)/37CL4-S?37B-TCDD (SURROGATE STD)£ » A3C-S, 3. 7. 8-TCDD (SECONDARY ION)3 469 237B-7CDD (M/E 332 - 130-2378 - AS RETENTION MARKER)4 4&9 2.3.7<B-TCDD (SECONDARY ION)5 4&<? 2.3.7.B-TCDD (TERTIARY ION)6 »37CL-£<3>7. B-TCDD (SURROGATE STANDARD)

NO123456

M/E33233432032S25732B

BCAN1BB01BBOABB21B821B821881

TIME30: ®238: 8230:0430:0438:0430:03

REF11A111

1.1.1.A.J-J-

RRTeeeeoeeeleeleeieei

METHA BBA BBA BBA BBA BBA BB

AREA<Hi;H730216.973271.

13252705174177CO

4716790170456

T) AMOUNT500. 000543. 215

197B. 5302030. B501535. 290

9. 523

PC/ULPC/ULPG/ULPG/ULPG/ULPG/UL

XTOT7. 58B. £3

29. 9930. 7823. 27

0. 14

0. 900RESPONSE FACTOR OF NATZVE TCDD

L 0 6 1 7 0 0

COHPUCHEH LABSRIC •i' MASS CHROMATOCRAMS COMPUCHEH DATA: 114840820083 SCANS 1620 TO 194588/28/84 7(55:99SflUPLEl 2 UL STD LOT CC5 (CC5 48. NG/HL) 014A« 83COHOS.; CPSIL88 58H 8.23m 10 88(2>248(28C/HIN) CONTRACT MASSES 131HS EA» 13C12-2378-TCOD (INTERNAL STD)/37CL4-2378-TCDD (SURROGATE STD)

38:1)44837858.30273388.180.8-, ^ .

328.

62366.l.3-i 37^2'

328 .

130677.2.7-, 85a664'

332.

170858.3.3-1

334

38:84 •14155700.

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A 30(27 38»44 320.0365376. 3848. i 0.500

' ' ' 38803

/ V' ' 38^82

i 0.500

' ' ' ' 38^82

1111050.

A/ \ 38t38 38s42/ ^ 11320. 18368.

4857850.

• 21856. • • 14848.l • 1 • 1

63168.328.098

t 0.500i • l • l

130608.332.099

1 1 1 1 1

171520.334.100

1 0.500i • l • l

14155700.

• .1152&. 42112. •

8 0 6 17 0 0

COHPUCHEH LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA: TM848820C83 SCANS 1828 TO 194508/28/64 7;55«eeSAMPLEl 2 UL STO LOT CCS <CC8 48. HC/HL) WH« 63COHDS.s CPSIL88 5uH a.23t1H ID aa<2)24u(2uC/HIH> CONTRACT MASSES 131HS EA469 2378-TCOO (M/E 332 - 13C-2378 - AS RETENTION MARKER)36:84

1763329.10730106.28.6-1

257.

30! 644857858.

77.e-, 3e2^300-328 .

6387836.ifle.e-i 395^-322

36:62139877.

2.1-1332

' ' ' ' 36;6414155786.

IDi-OUllW.

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36:64

7V856664.

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2646.3248.

30(275376.

. 21856.

30; 235632.20992. .

'

30137

36(443840.

. . 14848.

36(426513.

• 25(52. , •

'

1763320.257.677t 6.568

——,——

4857856.326.696t 6.566

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6367830.322.696

1 6.566

'

136688.332.699t 6.560

'

224.4-1RIC.

• 18'x

26.CW

—————,—————p1840•X»'-M

.ISga 1886 1900'>a.<*i io»(»'» •w.'?i

36l3611526.

•lt52&,

36l4216368.42112. •

1926'W»4l

19400<<MI

14155766.

SCAHTTNC

8UANTITATION REPORT FILE-. TWB46e£®C®3

DATA; TUB40BS0Ce3. TIee/20/84 7;B5 00SAMPLE: £ uL BTD LOT CC5 <CC5 40 us/MI.) OUA« 03CONDS. : CPSILB8 .50M C. 23MM ID B0(2)240(eeC/MIN) CONTRACT MASSES 1.31MS EASUBMITTED BY: 63 ANALYST: 619

AMOUNT-AREA * REF. AMNT/(REF. AREAX RE9P. FACT)RESP. PAC. FROM LIBRARY ENTRY

NO NAME1 * 13C12-237B-TCDD <INTERNAL STD)/37CL4-S37B-TCDD (SURROGATE STD)£ » 13C-a 3. 7. 8-TCDD (SECONDARY ION)3 469 2378-TCDD (M/E 332 - 13C-237S - AS RETENTION MARKER)4 469 2.3,7.6-TCDD (SECONDARY ION)5 469 £.3>7.e-TCDD (TERTIARY ION)6 #37CL-£. 3. 7, B-TCDD (SURROGATE STANDARD)

NOAS345&

M/E332334320322257328

SCAN1B8B1B801882188218821881

TIME303030393030

020504849403

REF111111

1.1.1.1.1.1.

RRT600000001001001601

METHA BBA 89A BBA BBA BBA BB

AREA<HGHfe5B&M.

111105030B73300.3'?5B54eO,1.0730103.

37B032.

T) AMOUNT500. 000532. 314

3879. 6203962. 010299B. 090

1B. 130

PC/ULPC/ULPG/ULPG/ULPG/ULPG/UL

XTOT4. 214. 48

35. 6333. 32as. 21

6. 15

0. B90RESPONSE FACTOR OF NATIVE TCDD

0 !- 6 17 0 0

Cuf'tFUCHEH LABSRIC + MASS CHROMftTOGRflMS CQMPUCHEM DATA: TS848821C83 SCANS 1811 TO 193688/21/84 3;58s885fiHPL£» 2 UL STD LOT CCl (CCl 8.2 HC.-11L> OHM 83COHDS.t CFSIL88 58(1 8.23m ID 88(2>248(2aC/HlM) COMTRflCT MASSES 131HS Efl» IX12-2378-TCDO (INTERNHL STD)/37CL4-2378-TCDD <Sl)RROGATE STD)

21845.128832.14.5-

328 .

12.1-1328 .

77.8-1332 .

108.8-1334 .

217.8-BIC.

l^Wl^.

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17045.9^104.

1 ' 1 ' ' 2a;55 '116260.728831./V

1——^——,————,——1——^——-}==—r

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' ' ' ' 29855323627.2170618.r^-

1820 1848 I860 1888M«(« '^»94 WH3 38192

*

t

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l ' •"' ' • """"' I1 ' "" """••••I---"1960 192038121 38(41

21856.328.896

8.588

18288.328.898

8.588

116864.332.899

8.588

158272.334.188

8.588

326144.

SCAHTIME

I- I. 6 17 0 0

COHFUCHEM LABSRIC + MASS CHROMftTOGRftMS COMPUCHEM DATA: TS840821C63 SCANS 1811 TO 193668/21/84 3:58888SMHFLE; 2 UL STD LOT CCl <CCl 6.2 NG/HU OHH» 62COWS.: CF5ILS8 56H 6.23HH ID 86<2>246(2aC/HIH) COHTRHCT MASSES 131HS EM469 2378-TCDO <H/E 332 - 1X-2378 - ftS RETEHTION MMRKER)

29s567199.35856.7.(H

257 .

l8.7-|326 .

25.1-1322 .

196.6-332 .

279.1-1RIC.

d3ii3b.

.. ...... ..A1 ' ^ 1 '29s56 ' -r

21645.128632.

A.29(5628251.176968.

/V' ' 29s55 '

116266,728831.

^\—,————^ v ,29t55323627.2176616.

, , , . , A, ,1820 1846 I860 1S86'x»«W ?q»?4 ?9i43 3ft«fl?

8224.2S7.677

t 6.568

21856.326.6961 6.566

29344.322.696

t 6.366

116864.332.699

t 6.566

326144.

1906 1920 SCHH39«?1 38(41 TIME

SUANTITATION REPORT FILE: TSB40B21C03

3ATA: TBB4eB21Ce3. TI1B/S1/B4 3-SB.08SAMPLE: £ "L Bro LOT CC1 (CC1 0. 3 NG/MI.) OUA« 83:ONDS. : CPSIL88 50M 8. 23MM ID 8e(£)24e<20C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST; 619

AMOUNT-AREA » REF. AMNT/(REF. AREA)* RESP. FACT)lESP. FAC. FROM LIBRARY ENTRY

NO NAMEA • A3CA2-2378-TCDD (INTERNAL STD)/37CL4-S37B-TCDD (SURROCATE STD)2 » 13C-2. 3*7>8-TCDD (SECONDARY ION)3 469 E378-TCDD (M/E 332 - 13C-2378 - AS RETENTION MARKER)4 4fe9 2.3.7.B-TCDD (SECONDARY ION)5 4&9 2.3-7.8-TCDD (TERTIARY ION)6 »37CL-£, 3.7. B-TCDD (SURROGATE STANDARD)

NO12345&

M/E3323343503ZS2573SB

SCAN1B73187218741B7418741874

TIME£9:5529:55S9:5fc29:5fc29:5629:5&

REF111111

1.8.1.1.1.1.

RRT006999001001001001

MEAAAAAA

rwBBBBBBBBBBBB

AREA(H(SHT)728B31.952231.128832.1709&B.35856.99184

AMC500.532.19.19.11.5.

>UNTeeo481150972693547

PS/ULPC/ULPG/ULPC/ULPG/ULPG/UL

XI45.4B.

1.1.1.6.

•OT929876838751

RESPONSE FACTOB OF NATIVE TCDD • 0. BB9

RE6PDN6E FACTOR OF SURRO&ATK K 6. 9&7

£ ^ 6 17 00

COWUCHEH LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA! 11840820803 SCANS 1817 TO 1942eS/28/84 19;23;euSAMPLEl 2 UL STD LOT C-652 <CC2 1.6 HG/HL) OHntt 63COHD5.; CPSILSe 58H 8.23HH ID 8a(2)24a(2flC/HIM) CONTRACT MASSES 131HS EA» 13C12-2378-TCOO (INTERNAL STDV37CL4-2378-TCDO (SURROGATE STD)

39:01326144.

71.4-1 ^ r ^ '326 J / \ 36; 38 328.8961 / \ 2341. * e.see

| ^/ '<^1 ' 1 ' 1 ' 3a«ei

101986.22.5-, 6S^1-328 J / \

1 ^ \^' ' 38808

365284.88.2-1 226^648.332

l—p-.———,—————j—————,—————1—————,—————j—————p38sS@456261.

l88.«H 29^478-334 .

—1————i————|————'————1————•————1————r38261

1722366.377.1-, "T28"-- / \n / \ eeei.

1828 1846 1868 16S6WtW 2Si24 29(43 38102

/ \ 38i26 332.933/ \^ 3llfl. i 8.580

/ \7 \^

i ' i ' i ' i !

326144.

7136. •l • l • i

182656.328,838

1 8.588——,„ .p. .-r -..-.. —————r—-"——(-

366884.

, 8394, . I . ,

456784.334.180

1 0.588————^————,————,—————,————y-

1722368.39i41

29824.

1^0 1928 1948 SCHH30121 38(41 31(88 TIME

17 ^ 6 1 7 0 0

COHFUCHEH LABS"RIC + MASS CHRQMATOGRAMS COMPUCHEM DATAt 11848820893 SCANS 1817 TO 194268/28/84 19:23(00SAMPLE! 2 UL STD LOT C-052 <CC2 1.0 HG/ML) OUH» 83COMD3.; CFSIL88 50M 0.23m ID e0<:2:»240(20C.-11IH> COHTRRCT MASSES 131MS En469 2378-TCOO <M/E 332 - 13C-2378 - AS RETENTION MARKER)

38; 82128248.741391.27.7-1

2S7 .

75. M-328 ..

100.8-1322 .| / v^ f;448. •

84.2-1332.

396.2-1-RIC.

1 •" ' 1 '

2685536.

, . ,

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, . , , A,1826 1546•MfW Ms?4

1

'

••"""1 ••••••"•"

1860•?<<«43

f41J3t.

30:01326144.

30101434688.2708676.

A38;e8365284.2265040.

30(011722360.

, , .„„, , , ,1986 1300 1320'Wifl?

—"——1—————'—————1—————'

36:392541.7136. •

30:283403.

30(263110.8384,

301416601.29824.—————,——————,————a£Û————,

30121 30(41

120448.2S7.677

t 0.500, ,-.,.„?-

326144.320.696t 6.566

1———r

434688.322.096

t 6.5661

366080.332.699

1 0.566i |-

1722366.

1946 SCAH31100 TIME

OUANTITATION REPORT FILE-. TTB40B20B03DATA-. TTB40B20B03. TI6B/20/B4 19:23.80SAMPLE: S uL STD LOT €-052 (CC2 1. 0 MS/MI.) OUAtt 93CONDS. : CPSILB8 50M 0. 23MM ID B6(£)240(20C/MIN) CONTRACT MASSES A31MS EASUBMITTED BY: 03 ANALYST: &43

AMOUNT-AREA « REF. AMNT/(REF. AREA)* RESP. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAMEA » A3C12-237B-TCDD (INTERNAL 5TD)/37CL4-237B-TCDD (SURROGATE STD)2 » 13C-2. 3. 7. B-TCDD (SECONDARY ION)3 469 237B-TCDD <M/E 332 - A3C-237B - AS RETENTION MARKER)4 469 £.3. 7. B-TCDD (SECONDARY ION)5 469 2, 3.7, B-TCDD (TERTIARY ION>6 #37CL-2.3,7, B-TCDD (SURROGATE STANDARD)

10Jl23456

M/E33233432832225732B

SCANAB7B1B7BAB791B79J.B801B79

TIME303030383030

000601018261

REP1A1AAA

A.A.A.A.A.A.

RRTeeo000001001001001

MEAAAAAA

ETHBBBBBBBBBBBB

AREA(HGHT)2£&504<5£937476.?0B553e.270B&76.741391.&54&71.

AMt500.52B.100.101.77.11.

>UNT00055A376B1679B792

PC/ULPG/ULPC/ULPC/ULPG/ULPC/UL

XI37.40.7.7.5.0.

•OT87036071B9B9

RE&PONtE rACTOR OF NATXVE TCDD « 0. 921

RESPONSE FACTOR OP BUmtD&ATE « 1. 009

9 I- 6 17 00

COHPUCHEH LASSRIC + MASS CHROMflTOGRfiMS COHPUCHEH DATAi 10846820883 SCANS 1816 TO 194188/2B/84 29i21i8aSAMPLE; 2 UL STO LOT 0-653 (CC3 5.8 HC/ML) OMft» 83COHDS.; CP5IL88 58(1 8.23ftf1 10 88<2)248(2aC/HlH) CONTRACT MASSES 131HS Eft» IX12-2378-TCDO (INTERNAL STD>/37a.4-2378-TCOD (SURROGATE STD)

30:01557117.35ob4rf8»189.8-1 •syaû.

328

3080163844.

11.4. W-328

1 I.- ." | . . . i • i • | ' | • | • 129858122892.

21.9-1332 .

23;53153937.

27.8-, 995^-334.

38:681855488.

332.5. 123^1M•RIC.

A 38;383587.

^ -— 6224.1—.——,——,—————.—————,—————|—————r- i———,——-as^.————.———a-,————.————

29»32 / \,% / Y * t'-508

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793624.

A.y^

29t32 / \ .2848. • / \19688, . y v^

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63368.328.893

122368.332.099

1 0.S00i r

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1 0.500

1855480.

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27.5-1237 .

78.3-1326.

100.01

322 .

17.2-1332 .

261.1-1.RIC

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1 ' ' ' ' |29; 38122892..J ^

1840•XI. 1A

1

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18id

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(CC3 5.e<2flC/HlN>t6 RE7ENTI

30! [email protected].

A30161557117.3566439.A30:01716656.4580068.

38:66 • i • 11855468.12362100.

1888•Wfflf

LAB5COMPUCHEM DATA: TU840828B03 SCANS

6 HG'HL) OMn» 63CONTRflCT HASSES 131HS EHOH MARKER)

^-

30:363507.

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„.„..,..„.„...,..„,.,.„,,„.,. ......,..,„ ...,j....,..,,, „ „1986 1926ia.?f »»-<i

1816 TO 1341

195584.257.B77

1 a.SBU

558686.326.696i 6.566

710656.322.696i 6.566

T—————..-.,..

122368.332.699i 6.S60

1855486.

• 11940 SCAHlltBfl TIMF

3UANTITATION REPORT FILE. TUe40B20B03

3ATA; TUB40B20B03. TI96/20/B4 £8:21:00SAMPLE •• £ uL BTD LOT C-0S3 (CC3 5. 0 NO/MI.) OUA« 83CONDS. : CPBILB3 50M 8. 23MM ID 80(2)240(S0C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 63 ANALYST: 643

AMOUNT-AREA « REF. AMNT/(REF. AREA)* RE8P. FACT)RESP. FAC. FROM LIBRARY ENTRY

NO NAME1 » A3C12-237B-TCDD (INTERNAL STD)/37CL4-S37B-TCDD (SURROGATE STD)2 • 13C-S-3-7, B-TCDD (SECONDARY ION)3 469 237B-TCDD (M/E 332 - 13C-237B - AS RETENTION MARKER)4 469 2,3.7.8-TCDD (SECONDARY ION)5 4&9 2.3-7.B-TCDD (TERTIARY ION)6 »37CL-2, 3.7.B-TCDD (SURROGATE STANDARD)

W1Z3456

M/E33233432032225732B

SCAN1B761B771B79AB79AB791B79

TIME292930303030

585901010101

REF111A11

1.1.1.1.1.1.

RRT000001002003002002

MEAAAAAA

£THBBBBBBBBBBBB

AREA(H£m793&24.995B71.

35064384F.Be060.121B553417671

•> AMt500.511.4B1.491.364.21.

)UNT000420&5B355944471

PS/ULPC/ULPG/ULPG/ULPG/ULPG/UL

XI21.21,20.20.15.

0.

roT095732723991

RESPONSE FACTOR OF- NATTVE TCDD = 0. 903

RE&ÔNSE FACTOR OF EUBBD&ATE " 1. 0S1

6 I 6 17 0 0

COMFUCHEH LABSRIC * MASS CHROMATOGRAMS COHPUCHEM DATfti TV84fl82fl8a3 SCANS 1815 TO 194088./28/84 21i89i60SAMPLE! 2 UL STO LOT C-854 <CC4 28. NG/HL) (MM 83CONDS.; CFSIL8S 58H 8.23MH ID S8(2)248<28C-'HIN) CONTRACT MASSES 131HS EA» 13C12-2378-TCOO (INTERNAL STD)/37CL4-2378-TCOO (SURROGATE STD)

29(593317738.18462300.100.0-1

326.

t.3-i328.

5.0-332.

6.5-1334 .

299.3-1RIC.

7V1 29<59'

42911.234448.

Al——,————,————|————,————,————p--———1—^—^—29s58165675.

K

/ ^• • • ' • '29^^ '

214972.1271738.

' ' ' ' * 29:5999267&S.

55752800•

1820 1846 I860 1888'WfO'i '».'>d •»t>,4'» 'Wl<V>

3U;316460.

24960.———,—————,————,————

"•r"" "" ' •"""""• i """""

i • «

38:31 3014213568. 15323.

• • 33824. ^7872.1968 192030171 30i4t

3317758.326.896

t 6.566• 1

43648.328.898

i 8.588-,————|

166400.332.899

i 0.900,„, ,

215296.334.188

i 0.580

• 1

9928788.

1948 SCAH31)88 TIME

0 3 6 17 0 0

COHPUCHEH LAGSRIC * MASS CHROMATOCRAMS COMPUCHEH OATAl TU840820803 SCANS 1815 TO 194068^28/84 2l:89!flflSMHPLEI 2 UL STD LOT 0-654 (CC4 29. HG/HL) OMfl» 83CONOS.8 CPSIL88 56H 8.23HH ID 80(2)246(26C/HIN;i COHTRACT MASSES 131MS Efl469 2378-7COO <M-'E 332 - 1X-2378 - ftS RETENTION MARKER)

368091144830.6471610.26.2-

2S7 .

76.e-329

'

198.8. 243^M•322 .

3.8-1332 .

227.4-1• RIC.

btfioio.

A' ' ' 29i59

3317750.18462360.

A29; 59

4366336.

7\^23s58165675.S65647.

A' " ' ' 29:59'

9926768.59752880.

/ \1 1 \ 'Mi 51

^ V , . . 33824.---1" -••""r— •••• • • • ••••"r • • --r-- • | • •r i ^••""" ,1820 1848 I860 lS»aWiW ?9i?4 yfi43 36i62

* i1 ' 1 ' I

38l316400.

, 2-f^W-

38:323968.

• • • 11328.

1 i

13568.l •

196630121

1144830.257.677i 6.569

3317750.326.696i 6.560

1 ' 1

4366330.36i53 322.6964764. ±6.566

• 11392.

166466.332.699i 0.566

9928766.39i4215323.47872. •„ ,l.,i,.,,,,,,,, .........,;.....

1920 1946 SCflU30(41 31(66 TIME

3UANTITATION REPORT FILE; TVB4®B2eB03

3ATA: TVB4e82Mie3. TI&B/20/84 ei:e9-.eoSAMPLE: £ uL BTD LOT C-®54 (CC4 SB. NO/NI.) OUA« ®3;ONDS. : CPSIL98 58M ®. 23MM ID 86 (2) 248000/HIM) CONTRACT MASSES 131MS EASUBMITTED BY; 03 ANALYST: 643

AMOUNT-AREA » REF. AMNT/<REF. AREA)» RE9P. FACT)i£SP. FAC. FROM LIBRARY ENTRY

NO NAME1 * 13C12-2378-TCDD (INTERNAL STD)/37CL4-?37B-TCDD (SURROGATE STD)2 • A3C-2. 3. 7>S-TCDD (SECONDARY ION)3 4&9 2378-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 469 2.3.7.8-TCDD (SECONDARY ION)5 469 2.3,7.8-TCDD (TERTIARY ION)6 »37CL-2<3<7. B-TCDD (SURROGATE STANDARD)

NO123456

M/E33233432032225732B

SCAN187618761877187718781877

TIME292929293029

585B59599059

REF111111

JL1.1.1.1.1.

RRTeeeeee001eei801eel


AREA(HCH965647.

1P71730.iB4&23ea24379106.

6471610234448.

T) AMOUNT500. eee536. 744

20B4. 2BO2149. 5801592. 9M

9. 985

PC/ULPG/ULPG/ULPC/ULPG/ULPC/UL

XTOT7. 277. B1

30. 3231. 2723. 1B0. 14

RESPONSE FACTDB OF NATIVE TCDD « ®. 957

Z 2 6 t? 0 0

CQHPUCHEH LflBSRIC * MASS CHROMATOGRftMS COMPUCHEH DATA: TM840821C83 SCANS 1817 TO 194208/21/84 Qi19(00SAMPLE) 2 UL STD LOT CC5 (CC5 48. H6.--HL) OHH» 63COHOS.i CPSIL88 Sflt'l e.23MH ID S8<2)246<2eC/HIN) COHTRflCT HASSES 131H5 Efl» 1X12-2378-TCDD (INTERNAL STD>/37CL4-2378-TCDO <SURROGftTE 5TD)3a;ei

£676478.40759000.iee.0-i

328.

l.3-i328 ..

2.6.332.

3.3i334 .

247.4-1RIC.

wfwaaa.A1 1 1 1 1 • 36,91 1

8367S.513392.A

' 1 29S59175765.1075426.

1 ' ' 29sS9'221591.1384310.

A' ' 30.'@8

16515866.114766030.

/V

30:288966.39046. i———,—————,—————,———

1 "•"" ••.••""••"-•"••i---'

3Qi 2818944.81928. •

6676470.320.B96

1 0.500

fUCAfl0^000.

328.698i 0.500

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176640.332.099i 0.500

, , „ „ , , , , ,

222208.334.100

1 0.500

16515000.36! 516464.15488.

C 2 6 17 0 0

COHFUCHEH LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA; TM84B821C03 SCANS 1817 TO 19426S/21/84 6:19:00SAMPLE: 2 UL STD LOT CC5 <CC5 48. HG/HL) OHA» 63COHOS.: CFSIL88 50H a.23t1H ID 80(2)246<2eC/HIN) CONTRACT MASSES 131MS EA469 2378-TCDO <H/E 332 - 13C-2378 - AS RETEHTION MARKER)36801

2441216.14680100.no i HboUHW.28.7-, ^/V30:01

££76478.78.4-, 48?%09•"1 /V

38:01S5l9£78.

100.6-1322.

29:59175765.

2.1-1332

1 ' •" • • " 1 i i . | - i38seel65l5uuu.

iQt a 114766000,l-M.ll-l /-~\

-RIU / \

1828 1840 1860 1880•tO,OS 'XI.'>4 •>a.4'» VrW>

53152700.

„.,-————,„,———.,„„.., .„.,...„ r. ....,,—..,.....,..,-,-Z,,,.—. -.'•'-m^—.

1875420.

/\\

--

1

1

1

1900W.91

30:2889£0.39048.

30; 2810715.35456..

30:2818944.

1320 1940•Vim WfM TIHF

38! 382288.

j^——————————^

30(567602.

. . .20309.

i • l

30:516464.15488.

2441210.257.677

1 B.5M

6676470.320.696t 0.306

8519670.322.696t 6.366

176640.332.699t 6.560

16515666.

5CAH

KIANTITATION REPORT FILE; TWB48B21C83

1ATA; TUB48B51C83. TI?B/2i/B4 e:i9;eeSAMPLE: E uL BTO LOT CC5 <CC5 48. MS/ML) OMAtt 03;ONDS. : CPSILBS S8M 0. 23MM ZD 8e(2)240(28C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY; ®3 ANALYST: 619

AMOUNT-AREA « REP. AMhST/(REF. AREA)* RESP. FACT)V.SP. FAC. FROM LIBRARY ENTRY

NO NAME1 » A3C12-237B-TCDD (INTERNAL STD)/37CL4-£37B-"TC:DD <BURROGATE STDiS * A3C-2. 3. 7. B-TCDD (SECONDARY ION)3 469 2379-TCDD <M/E 332 - 13C-2378 - AS RETENTION MARKER)4 469 2.3-7,6-TCDD (SECONDARY ION)B 469 2,3.7. B-TCDD (TERTIARY ION)6 #37CL-2, 3-7, 8-TCDD (SURROGATE STANDARD)

NO1S3456

M/E33233432032225732B

SCAN1B771B77AB79•1.B791B791B79

TIME292930303830

5959ei818181

REF111111

1.1.1.1.1.1.

RRT000008001881801081

MEAAAAAA

STHB6BBBBBBBBBB

AREACHC107542a.1384318

40759003.5315270814&B8100.

513392.

AMC580.B24.

4131.420B.3244.

19.

HJNT888621730090490476

PG/ULPG/ULPC/ULPC/ULPG/ULPG/UL

XI3.4.

32.33.25.8.

•OT961572326915

RE&PONSE FACTOR OP NATIVE TCDD 8. 954

COHPUCHEH LfiBSRIC * WSS CHROMATOGRftMS COMPUCHEM DATA: TA848821B83 SCANS 1816 TO 194168/21/S4 16:03iW5nWl£t 2 UL STD LOT C-651 <ttl 8.2 HG-'HL) OHH« 83COM05.; CFSILS8 SBM e.23m ID 8a(2>24e<2BC/riIH> CONTRACT MASSES 131HS Eftt IX12-2378-TCDD (INTERtW- 5TD)/'37a-4-2378-TC[0 (SURROGATE STO)

30)6227265.

15.8-1 l'??<"9•

/V' 1 l . 1—————, 1 \ f \ i • | 1

30:0119169.

18.9-, „ . l24^28-328 .

29(59147769.

79.8-, l81^-332.

29; 59186598.

lee.e-. 124X3e•334 .

1 i 1 i 1 i | . 1 i30:60489362.

218.8-, 3<M9MB-• RIC. / \

1829 1840 1866 1888 1900^ " • ' • f t - ^ , " , r t . »^ <" -^rt. rt^ *»0»'>1

29:14 / V2263. / \8968- / Y^

J ^—,•——1—————•—————1—————•—————1—————r^-——i——-—=¥— . ., - -r-

/ \ 36l25/ \ 2688./ \>s-^ 6168.

28128.328.896i 8.566

i • i

26448.328.098i 6.586

148224.332.699t 6.566

•"•••••"" •""i"- ---•.•--••—r

187648.334.166

± 6.5661 k———^H^W^^^ .

416624.

„ , „„„„„ ,,„..„.„.„„„ , ,.,,,,,, .1528 1940 SCAN111. ^ t Ot.ftrt TTMC

9 Z 6 V 0 0

COHFUCHEH LMBSRIC * MftSS CHROMATOGRftMS COMPUCHEM DATfti TA840821B03 SCANS 1616 TO 194168/21/84 16:03:08SflMPLE; 2 UL STD LOT 0-851 <CC1 9.2 HG41D OHfit 83COH05.; CFSIL8S 501-1 8.23HH ID Su<2)248<2eC/HIH) COHTRnCT HASSES 13116 EH469 2378-TCOD (H/E 332 - 13C-2378 - MS RETENTION MARKER)

38; 629636.52336.7.1-.

'1

19.6-1328 .

25.4-1322 .

109.0-1332.

277.0-1RIC.

B^JJB.

/\3888227285.174080.

/V3820137324.235896.

/V1 1 1 29s53

147769.1818798.

1 ' 1 ' ' ' 38;88489362.3049840.

/V.1826 1840 1868 188829i0S 29t24 29(43 30102

10496.257.677i 6.586

28128.326.696i 6.566

37632.322.696i 6.506

148224.332.699

t 6.566

416624.

1900 1928 1940 SCAH30(21 30*41 31(00 TIME

'UANTITATION REPORT FILE. TA840B21B03

-ATA: TAB40B21B03. TI.B/21/B4 i6-.e3-.e0•AMPLE; £ uL BTD LOT C-B51 <CC1 0.2 KG/MI-) OUAtt 03:ONDS. : CPSILBB 50M B. 23MM ID Be<£)24e(SOC/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST; 643

.MOUNT-AREA » REF. AMNT/(REF. AREA)* RESP. FACT)<ESP. FAC. FROM L-IBRARY ENTRY

NO NAME1 » A3C12-237B-TCDD (INTERNAL STD)/37CL4-£37B-TCDD (SURROCATE STD)£ « 13C-2. 3. 7, B-TCDD (SECONDARY ION)3 469 S378-TCDD (M/E 332 - J.3C-237B - AS RETENTION MARKER)4 469 &3.7.6-TCDD (SECONDARY ION)5 469 S. 3, 7. B-TCDD (TERTIARY ION)6 »37CL-S. 3. 7. B-TCDD (SURROGATE STANDARD)

NO1S3456

M/E3323343503222573SB

SCAN1B77AB771B801B79AB8B1B79

TIME292930303030

595905010201

REF111111

1.1.1.1.1.1.

RRTeeeeeeeesoeiwsMl

MEAAAAAA

STHBBBBBBBBBBBE;

AREA(HGHT)101B798.1249030.

1740Ba.E35096.S233&.

1S45SB.

AMC500.499.IB.19.12.

4.

)UNToee6636276472109B7

PC/ULPC/ULPG/ULPG/ULPG/ULPC/UL

VI47.47.1.1.1.0.

'OT393677B61647

REBÔNRE rACTon OF' NftTTve TCDD •i 0. 902

ReePDNfE FACTOR or- BUBRDGATE = 6. B99

8 2 6 1 7 0 0

COt'lPUCHEH LABSRIC + MASS CHROtlATOGRAHS COMPUCHEM DATA; TT840821C83 SCANS 1885 TO 1938e8--21/84 5:64t08SAHPLE» 2 UL STD LOT CC2 tCC2 1.6 HG.41L> OUA« 03CONDS.; CF51L68 SflH 6.23(111 ID 86(2)24a(2aC/HlH) COHTftACT MASSES 13K1S EA» 13C12-2378-TCDD < INTERNAL STD^ya^-ZBPB-TCDO (SURROGATE STD)

29:51174336.1158370. 174336.74.8-1

328 .

25.9-1328 .

78.4-1332.

188.8-1334 .

383.8-1 6208^58.:RIC.

——,————1————,————,——

" ^.L--JJU--J-M-1' i ^ n

1h i ii i l l ii i i i^————^———————w—— ^

11303.U.

/\1 \J v-

29s 51537e<».364111.

/Y29»se182232.1233148.

,/V,29:58232868.1496968.

/Y29:56894976.

174336.326,896i e.see

—,———,———,———,———,

68288.328.B98

1 0.560

182784.332.633

t e.-XM

233216.334.160i 8.500

—F-————.————,——-i—i i

894976.

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<a3yaw NoiiHaiaa'svszK-oel - ?ec 3/M> croi-szet R91'"3 SHiet S3SSVH 13WUH03 (NIU--M;)9t-?(.3)e? 01 HUC.T.'B M9S SSIIS'D "SON03£8 »WIO <1H.-3N B't SOT) ZOO lOI OIS T) S «3TdHyS

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004929

3UANTITATION REPORT FILE; TTB4&B21CB3OATA; TTB46B21CB3. TZ6B/21/B4 5: M-. 60SAMPLE: 2 uL STD LOT CC2 <CC2 1.0 NO/ML) OWAd 03tWOS. •• CP5IL8B BBM 0. 23MM ID 60(2)240(200/MIN) CONTRACT MASSES 131MS EABUBMITTED BY: 03 ANALYST; 619

AMOUNT-AREA • REF. AMNT/<REF. AREA)* RESP. FACT)RESP. PAC. FROM LIBRARY ENTRY

NO NAME :1 » 13C12-237B-TCDD (INTERNAL STD>/37CL4-S37B-T?:DD (SURROGATE STD)2 • 13C-& 3. 7, B-TCDD (SECONDARY ION)3 4&9 e378-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 4&9 S.3.7.B-TCDD (SECONDARY ION)5 4&9 2.3.7.8-TCDD (TERTIARY ION)6 #37CL-2-3.7. 6-TCDD (SURROGATE STANDARD)

NO12345&

M/E332334320322257326

SCAN1867AB671B&B1B6S1B&81B&B

TIME292929292929

5056B1515151

REF111111

1.1.1.1.1.1.

RRT880oeeeeieeieeieei

MEAAAAAA

ETHBBBBBBBBBBBB

AREA(H(;HT)1E33146.149&9ea.115B978.14&1248.

3BB175.3&4111.

AMOUNT500. eeo494. 731102. 459100. B9074. B1912. 646

PC/UL :PG/UL :PC/ULPG/ULPG/ULPG/UL

XTOT»B. 911B. 507. 977. B55. B28. 94

RESPONSE FACTOR OF NATIVK TCDD • ®. 959

RE&PON&E FACTOR OF SLWROBATE B 1. 071

COHPUCHEH LABSRIC + MASS CHROMATOGRrtMS COMPUCHEM DATA! TU848821C83 SCANS 1819 TO 193588/21/84 5s47:eeSAHFLEl 2 UL STO LOT CC3 <CC3 S.fl HG.--NL> OHH« 83CONOS.; CPSIL88 5eM 0.23MM ID 8e<2)24a(2flC/HIN) CONTRfiCT UnSSES 131MS Eft» 1X12-2378-TCDO (INTERNA. STD)/37CL4-2378-TCDO (SURROGATE STO>

2646618.Iflfl.Bn 14w88e-328 .

23i55298533.

U.3. 1676218-328 .

' ' ' ' 1 29«54 '526336.

19.9-, 388\85a•332 .

1 1 1 • • 2^3 '673936,

25.7. 39^638-334 .

29;55883897B.

333.7-, 5e6^0a•. RIC.

"

1626 1848 I860 1880WfW '^«?4 29»43 3C«(»?

A 3fl!33 328.8964845. i 8.588

>-- • • • 18£56. . .

/Y

/V/ \y ^

A 3fls33

. ^l ' I ' i ' i

2646818.

239888.328.898t 8.588

i i i | i

526336.332.893i 8.588

1 . 1 ;

679336.334.188t 8.588

(

8838978.

9813.• • • 35712. '.,..,.....,..,..,..,,..,,, .. -. •-lAi..,-,,,,————r

1966 1920 SCHHWi?) 30>41 TIHE

Z £ 6 t7 0 0

COHPUCHEM LABSRIC + MftSS CHROMftTQGRftMS COMPUCHEM DATft; TU840821C03 SCAMS 1818 TO 193568/21/84 Si47(09SAMPLE! 2 UL STD LOT CC3 <CC3 3.9 HG/HL> OHA» 83COHOS.s CPSIL88 50H 6.23HH 10 80(2>246(26C/MIN) CONTRACT MASSES 131MS EA469 2378-TCDO (M/E 332 - 13C-2378 - AS RETENTION MARKER)29:55

982144.5164920.26.0-1

237.

76.4-1326 .

00.01322 .

15.2-1332 ,

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aib43û.

/ Y' • i • i ^^ •2646016.14904000.

/V'—————————-s.^—3465210.19371888.

A' ' ' 23;54

526336.3081850.

/ V1 . 1 1 1 ' . )29s55

8836976.50687200.

A1826 1849 1866 188829805 29(24 29i43 30102

38(334845.

• • • 18656. • •—i—————|————i-'—'"——|—————i—

30:454123.

, • , • i I™ .

36(339813.

• • 35712....,, .,„„„....,., . .....,..- .faL——.,........,„., ,...-

1966 192930(21 36i41

902144.257.677t 6.56Q

2646610.326.096i 0.566

3465216.322.696

1 6.506

526336.332.699

t 6.506

8836976.

SCANTIME

aUAHTIT^TION REPORT FILE; TUB40B21C03

3ATA: TUB40B21C03. TI98/21/84 B:47:003AWLE; 2 uL STD LOT CC3 (CC3 5. 0 NC/MI.) OUA« 03;ONDS. : CPSILBB SOM 8. 23MM ID BO<2)24e<20C/MIN) CONTRACT MASSES 131MS EASUBMITTED BY: 03 ANALYST: &19

AMOUNT-AREA • REF. AMNT/CREF. AREA)* RESP. FACT)ÊSP. PAC. FROM LIBRARY ENTRY

NO NAME1 » 13C12-2378-TCDD (INTERNAL STD)/37CL4-£37B-TCDD <SURROGATE STD)S » 13C-2. 3»7>S-TCDD (SECONDARY ION)3 4&9 S378-TCDD <M/E 332 - 13C-237B - AS RETENTION MARKER)4 469 a.3-7.B-TCDD (SECONDARY ION)5 4&9 2,3,7.B-TCDD < TERTIARY ION)6 #37CL-2, 3. 7. B-TC&D (SURROGATE STANDARD)

NO123456

M/E335334328322257328

SCAN1B711B7CAB721B721B721B72

TIME292929292929

545355555555

REP111111

1.8.1.1.1.1.

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AREA<^GH13081050.3913&38.

149040CO.i9y7ieea,

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RESPONSE F-ACTOR OF NATIVE TCDD - 0. 9BO

RESPONSE FACTOR OF BUKRO&ATE " 1. 073

t ?£ 6 17 00

COHPUCHEH LABSRIC * MftSS CHROMATOGRflMS COMPUCHEM OftTfts TU840821C83 SCANS 1814 TO 1939e8/2l/84 6:4lt6CSflHPLE; 2 UL STD LOT CC4 <CC4 28. NG/HL) OHflt 83COHDS.s CPSIL88 SflH a.23HH 10 8fl<2)24a<29C/HIN> CONTRACT HflSSES 131HS Efl» 1X12-2378-TCDO (INTERNAL STD)/37CL4-2378-TCOO (SURROGftTE STD)

23t5*6496258.SS2^5688- 6496258.iee.8-1

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1 1 1 1 1 29^ . • . • 1 •332396.2048346.

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A1S26 1849 1860 1880WtfG ?«1»?4 '?<^;43 30se?

1

30:2626624.

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85564.328.698

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15.7-1329

49.2-1328 .

83.9-1222 .

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8.5-i326 .

44.2-i328

84.1-,232 .

166.0"iS34 .

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21s30 ' '46660.

282^76. 42240.

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COHPUCHEH LABSRIC + MASS CHROMATOGRAMS COMPUCHEM DATA: HT010918C03 SCANS 1284 TO 140908/38/84 2;11808SAMPLES 2 UL 19918 <0»ie9 - DF003702 ) 8-28-84 OUA# 83COHOS.s CPSIL88 5011 8.23m ID 8e<2)24e<20C.41IN) COHTRflCT TOSSES 131MS EM469 2378-TCDO <M/E 332 - 13C-2378 - AS RETENTION MARKER)

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Documents

CASE NO. 3089: LABORATORY DATA, QA CHECKLIST (DATA IS ... · A review of the laboratory raw data for case il Si^ S 'I has been completed by members of the Laboratory Section. Attached