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Eawag: Swiss Federal Institute of Aquatic Science and Technology Sandec: Sanitation, Water and Solid Waste for Development Carbonization research at Sandec Solid Waste Management Group Imanol Zabaleta

Carbonization research at Sandec Solid Waste Management ...web537.136.hosttech.eu/wordpress/wp-content/uploads/2016/...2015/11/25  · Nitrogen - Distribution of N between Process

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  • Eawag: Swiss Federal Institute of Aquatic Science and Technology

    Sandec: Sanitation, Water and Solid Waste for Development

    Carbonization research at Sandec Solid Waste Management Group

    Imanol Zabaleta

  • Outline

    1. Slow Pyrolysis -Tanzania 1. Horizontal Reactor

    2. Vertical Reactor

    2. Hydrothermal Carbonization - Switzerland 1. Energy efficiencies at mild conditions

    2. Nutrient balance

  • Construction and testing Horizontal reactor

    6

    1. pyrolysis drum 2. pipe for initial pyrolysis gases 3a. rotating knob

    Slow Pyrolysis in Tanzania – Phase I (2013-2014)

    3b. rotating and ejection handle 4. combustion chamber 5. brick kiln

    Externally heated

    Tested with different local biomass

  • 7

    Improving Energy efficiency of Horizontal reactor

    Slow Pyrolysis in Tanzania –Phase II

  • Constructing and testing a Vertical Reactor

    8

    Slow Pyrolysis in Tanzania –Phase II (2015)

    Simplification of “Abokobi Char Kiln”

  • 10

    Comparison of reactors

    Slow Pyrolysis in Tanzania –Phase II

    0%

    25%

    50%

    75%

    100%

    Cardboard (feedstock) horizontal kiln vertical kiln ARTI kiln

    Ash content Fixed carbon content Volatile content

    Cardboard H.R V.R.

    HHV [MJ / kgdb] 17.6 24.2 24.3

    ER1 [-] 0.67 1.49 𝐸𝑅 1 =𝐸.𝑐ℎ𝑎𝑟𝑐𝑜𝑎𝑙

    𝐸.𝑓𝑢𝑒𝑙

  • o Local Tanzanian student MSc thesis

    o Swiss Civil servant

    o Objectives:

    1. Improve energy efficiency

    2. Improve handling system of the reactor

    3. Test with two local feedstocks

    Optimization of Vertical reactor

    11

    Slow Pyrolysis in Tanzania –Phase III (2016)

  • o Hydrothermal Carbonization (HTC)

    Background

    12

    Hydrothermal Carbonization at mild conditions

    T 160-190oC

    P 20-30 bar

    RT 2 -10 hours

    Wet Biomass

    Gas

    Process Water

    Hydrochar.

  • Energy efficient– so what?

    15

    Hydrothermal Carbonization

    in the range of (roasted) biomass and peat

    similar characteristics to torrefied products (HHV: 20-24 MJ/kg, VM: 55-65%, FC:

    28-35%).

    Benefits over raw biomass: Homogenized, richer in carbon and energy density,

    hygroscopic and grindability characteristics

    Unsuitable for cooking

    stoves (too high VM)

    Suitable for combustion

    in industrial burners or

    incineration plants

  • Nitrogen - Distribution of N between Process Water and Hydrochar

    17

    Hydrothermal Carbonization

    60% of TN is mainly recovered in the Hydrochar

    Most of Water extractable as NO3.

    Phoshorus - Distribution of P between Process Water and Hydrochar

    50 – 70% of TP is mainly recovered in the Process Water

    50 – 70% of TP in hydrochar is Water extractable PO4.

  • Thank you for listening!

    [email protected]

    Questions?

    mailto:[email protected]:[email protected]