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Building the Biofuels Industry:
DOE efforts to Demonstrate and Deploy Integrated
BiorefineriesBrian Duff, Chief Engineer
DOE EERE Biomass Program
TAPPI/BioPRO
March 14, 2011
Energy Efficiency & Renewable Energy eere.energy.gov
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Building the Biofuels Industry
Goals, Vision, Mission
Importance of Biofuels
Biofuels Development Efforts at OBP
Efforts to Demonstrate and Deploy Integrated Biorefineries
Barriers to Biofuels Commercialization
Near Term Market Entry Opportunities
AGENDA
Energy Efficiency & Renewable Energy eere.energy.gov
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Department of Energy Priorities and Goals
Science & Discovery - Maintaining our leadership position
Economic Prosperity – Job Creation
Climate Change – GHG Reduction
Clean, Secure Energy – Energy Security
Advancing Presidential Objectives
Energy Efficiency & Renewable Energy eere.energy.gov
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Department of Energy Priorities and Goals
• Dramatically reduce dependence on foreign oil
• Promote the use of diverse, domestic and sustainable energy resource
• Establish a domestic bioindustry
• Reduce carbon emissions from energy production and consumption
Key Tenets of the Office of Energy Efficiency and Renewable Energy Strategic Plan:
Energy Efficiency & Renewable Energy eere.energy.gov
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Department of Energy Priorities and Goals
“A viable, sustainable domestic biomass industry that:
• produces renewable biofuels, bioproducts and biopower
• enhances U.S. energy security
• reduces our dependence on oil
• provides environmental benefits, including reduced greenhouse gas emissions, and
• creates economic opportunities across the nation.”
Vision of the Biomass Program
Energy Efficiency & Renewable Energy eere.energy.gov
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Department of Energy Priorities and Goals
“Develop and transform our renewable biomass resources into cost-competitive, high-performance
biofuels, bioproducts, and biopower through targeted research, development, demonstration, and deployment
supported through public and private partnerships.”
Mission of the Biomass Program
Energy Efficiency & Renewable Energy eere.energy.gov
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• At low % blends, refiners can
adjust operations to produce
suitable blendstocks• Ethanol, e.g., Vapor Pressure
• Biodiesel, e.g., Cold-Flow
• At higher % biofuel, displaced
hydrocarbons may be shifted to
less-valuable markets• Gasoline, e.g., to Cracker Feed
• Diesel, e.g., to Fuel Oil
• As crude is displaced as a source
of one product, there may be
shortfalls in other markets• Gasoline, e.g., Diesel & Jet
• Motor Fuels & Jet, e.g., chemicals
• Aromatics, e.g., hydrogen
Energy Security:Liquid Fossil Fuel Displacement
Source: Energy Information Administration, “Oil: Crude Oil and Petroleum Products Explained” and AEO2009, Updated February 2010, Reference Case.
In our fuels as in our schools, “drop-outs” are a problem!
Energy Efficiency & Renewable Energy eere.energy.gov
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0 5 10 15 20 25 30 35 40
2012
2015
2022
Renewable Fuel
Standard (RFS2)
Production Targets (Billions of Gallons)
Conventional (Starch) Biofuels
Biomass-based diesel
Cellulosic Biofuels
Other Advanced Biofuels
Advanced Biofuels(include cellulosic biofuels other
than starch-based ethanol)
EISA Mandated Biofuel Production Targets
15 BGY Cap on Conventional (starch) Biofuels
Energy Efficiency & Renewable Energy eere.energy.gov
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-40
-20
0
20
40
60
80
100
Gas Diesel Corn Ethanol Sugarcane Ethanol
Switchgrass Diesel
Stover Diesel Switchgrass TC Ethanol
Stover TC Ethanol
Switchgrass BC Ethanol
Stover BC Ethanol
g C
O2e p
er
MJ
Biofuel pathways with % reduction from baseline
EPA RFS2 CO2 e IntensityBiofuel lifecycle greenhouse gas emission reductions relative to petroleum fuels
Petroleum
Baseline
19%
61%
70%
91%
72%
93%
110% 130%
* TC = Thermochemical conversion | BC = Biochemical conversion
Source: EPA RFS2 Final Rule, March 26, 2010
Petroleum
Commercial Biomass
RD&D Biomass
Climate Change:
GHG Reduction
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
Economy
Why are Biofuels so Important?
Security
Environment
www.navy.mil/
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
Energy Security:
o We import ~64% of our liquid fuels, often from countries who are
antagonistic towards the US
o We are a captive market dependent on countries we cannot rely on
National Security:
o We expend a significant amount of our military budget in funding and
personnel in activities directly related to maintaining our access to oil
o Our National Security is related to our Economy
Economic Security:
o Our dependence on oil and impact of oil prices acts like a throttle on
our economic engine
o The impact of rising oil prices reverberates through the economy,
raising the prices of goods and services and driving inflation
Biofuels: Why should we bother? SECURITY!
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
Trade Deficit
• We spend $400 billion/year on
imported oil, of which about $300B
finds its way into foreign treasuries
as profit: >$1 billion/day!!!!
Why should we bother? ECONOMICS!
www.census.gov
GDP: Rural Economic Development
and JOBS
• Creating 50-75 new direct jobs per
biorefinery
• Reinvigorating rural economies
• Creating major new energy crop
markets
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
The Environment!• Petroleum dependency contributes to anthropogenic
GHG emissions
• Rising levels of CO2 are decreasing the pH of our
oceans, potentially upsetting delicate and vital
ecosystems such as coral reefs
• Biofuels can reduce GHG and CO2 emissions up to
130%
• Biofuels can reduce risks & damages from oil
production/transport
Sustainability
• Many of our industrial practices are not sustainable
• Biofuels are renewable
• Production technologies and metrics are being
developed for sustainable biofuels production
Why should we bother?
Source: http://prasoondiwakar.com
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
QUALITY OF LIFE!
• Biofuels contribute to our economic prosperity
• As China and India continue to grow their
economies, the US will need to move away
from using 25% of every daily barrel of oil to
~10% or less , more reflective of our relative
populations
• To maintain our quality of life, we need to
develop new energy sources and renewable
bio-based analogs for petrochemical fuels and
products
Why should we bother?
Energy Efficiency & Renewable Energy eere.energy.gov
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The Importance and Relevance of Biofuels
Biofuels: Other Considerations
• Liquid fuels are a premium product application: we pay for energy density and
convenience. In the near term, biofuels are the only alternative that fits our
lifestyle
• Biomass is not unlimited: “Best Use of Biomass” dictates the highest value
product application
• Electricity generation has many other options: Hydro, Nuclear, Wind, Solar,
Geothermal, Wave, Ocean Thermal
• There is no other option for liquid transportation fuels besides biomass
• Electrifying the vehicle fleet does not address GHG issues unless generation
uses renewable, sustainable sources
• Ethanol is a “transition” fuel. The technologies being developed for ethanol are
being leveraged to other renewable liquid fuels: gasoline, diesel and jet fuel
• We need every arrow in our quiver, every tool in our box, and biofuels is one
Energy Efficiency & Renewable Energy eere.energy.gov
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Biofuels Development Efforts at the Biomass
Program of DOE
Energy Efficiency & Renewable Energy eere.energy.gov
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Biomass Program Mission, Objectives, Goals
Research, Development, and Demonstration
Integrated
BiorefineriesInfrastructure
Biochemical and
Thermochemical
Conversion
Feedstocks
Biopower
Biofuels
Bioproducts
Crosscutting Activities
Analysis; Sustainability; Partnerships, Communications, and Outreach
R&D Priorities• Achieving biofuel cost targets (modeled)
o <$2/gal for cellulosic ethanol;
o <$3 for cellulosic drop-ins
• Developing bio-power and bio-products for
important supporting roles
• Meeting the EISA Renewable Fuel Standard
• Investing to meet targets (~$200M/yr)
Moving Markets
• Close collaboration with USDA, EPA, DOD
• Pilot and commercial demonstrations
• Infrastructure for delivery (including fuel
dispensers)
• Subsidies and other policy drivers
Develop and transform our renewable and abundant biomass resources into cost
competitive, high performance biofuels, bioproducts, and biopower.
Energy Efficiency & Renewable Energy eere.energy.gov
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Strategic Focus: Biofuels
• Cellulosic Ethanol: Historically, the primary focus of the program has
been on the conversion of lignocellulosic biomass to fuel ethanol. This
work can be fully leveraged and applied to renewable hydrocarbon fuels.
• Alternative Light-Duty and Diesel Replacement Fuels: Over past few
years, Biomass Program has expanded its technology portfolio to include
the production of renewable hydrocarbon fuels from lignocellulosic
biomass, including renewable gasoline, diesel and jet fuel, which will be
required to meet the EISA goal.
FeedstockProduction
FeedstockLogistics
BiofuelsProduction
BiofuelsDistribution
BiofuelsEnd Use
Energy Efficiency & Renewable Energy eere.energy.gov
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R E
F I N
I N
G
Focus of Biomass Conversion RD&D
Integrated Biorefineries
FeedstockProduction& Logistics
• Energy crops
• Forest Residue
• Agricultural Residue
• Algae
Ethanol
Butanol
Olefins
Gasoline
Diesel
Others
Feed Products
Lignin(for power)
Thermochemical Conversion
FastPyrolysis
Gasification Syngas Fischer TropschAlcohol Synthesis
Liquid
Bio-oilZeolite Cracking
Hydrogenolysis
Upgrading
Enzymatic Hydrolysis
Sugars Fermentation
Biochemical Conversion
Lipid (Oil) Extraction
Algal
Oil
Transesterification
Fractionation
Energy Efficiency & Renewable Energy eere.energy.gov
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Recovery Act Funding and InitiativesBiomass R&D and Demonstration Projects - $800 Million
$509M Pilot and Demonstration-Scale BiorefineriesValidate technologies for integrated production of advanced
biofuels, products, and power to enable financing and replication.
DOE recently selected
- 14 pilot-scale projects for up to $25M each
- 4 demonstration-scale projects for up to $50M
$81M Commercial-Scale BiorefineriesIncrease in funding for prior awards; one project
Expedite construction; accelerate commissioning and start-up
$107M Fundamental Research$24M: Integrated Process Development Unit
$5M: Sustainability research with the Office of Science
$34M: Advanced Biofuels Technology Consortium
$44M: Algal Biofuels Consortium to accelerate demonstration
$20M Ethanol Infrastructure ResearchOptimize flex-fuel vehicles operating on E85
Evaluate impacts of intermediate blends on conventional vehicles
Upgrade existing infrastructure for compatibility with E85
$13.5M NREL Integrated Biorefinery Research Facility
expand the pretreatment capacity
$69.5M SBIR and Program Direction
Energy Efficiency & Renewable Energy eere.energy.gov
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Biomass Program Demonstration
and Deployment Activities in Support of
Integrated Biorefineries
Energy Efficiency & Renewable Energy eere.energy.gov
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Integrated Biorefineries andMajor Research Thrusts
• 29 R&D, pilot, demonstration, and commercial-
scale projects selected to validate IBR
technologies: 2,12,9,6• Diverse feedstocks represented
• Multiple transportation fuels and bio-based
products
• Fundamental Research• Drop-in biofuels consortium
• Algae consortia (4)
• Deployment • Expansion of Integrated Biorefinery Research
facility at NREL
• Integrated Process Development Unit to reduce
cost of feedstocks logistics
Energy Efficiency & Renewable Energy eere.energy.gov
23For more information visit:
http://www.eere.energy.gov/biomass/integrated_biorefineries.html
Biomass Program‟s Integrated Biorefinery
Project Portfolio
Energy Efficiency & Renewable Energy eere.energy.gov
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Integrated Biorefinery Pathways
Feedstock Conversion Intermediate Conversion Product Partner
Energy Efficiency & Renewable Energy eere.energy.gov
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Integrated Biorefinery Pathways
Feedstock Conversion Intermediate Conversion Product Partner
Energy Efficiency & Renewable Energy eere.energy.gov
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Barriers to Commercialization
Energy Efficiency & Renewable Energy eere.energy.gov
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Challenges for the Demonstration
and Deployment of IBRs
Energy Efficiency & Renewable Energy eere.energy.gov
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Barriers exist throughout the value chain:Feedstock:
Who‟s going to invest in planting a new crop when
there‟s no plant to take it to?
Financing/Capital: Who‟s going to finance a plant when there‟s no
feedstock to supply it?
Who‟s going to finance a plant when the Conversion
Technology can‟t get a performance guarantee?
Product Off-take: Who‟s going to finance a plant when the longest off-take
contract you can get is 2-3 years?
Challenges for the Demonstration
and Deployment of IBRs
Energy Efficiency & Renewable Energy eere.energy.gov
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Conversion Technology Development
Market Surety
Project Financing
Challenges for the Demonstration
and Deployment of IBRs
Energy Efficiency & Renewable Energy eere.energy.gov
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Conversion Technology Development
Challenges for the Demonstration
and Deployment of IBRs
Technology developers must contend with the “Valley of Death”
between bench scale reduction to practice and true
commercial production.
Conversion Technologies must be scaled up to generate the
engineering data required for plant construction
Conversion Technologies must be validated at scale to obtain
engineering data and support project financing
Energy Efficiency & Renewable Energy eere.energy.gov
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Market Surety
Challenges for the Demonstration
and Deployment of IBRs
The price of oil fluctuates dramatically and therefore there
is no surety in the off-take product price for the
renewable analogs
Federal incentive policies and market mandates are subject
to change and expiration, and there is no surety that they
will cover the tenor of the loan
Market Surety can be increased through
consistent public policy
Energy Efficiency & Renewable Energy eere.energy.gov
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Project Financing
Challenges for the Demonstration
and Deployment of IBRs
The lack of a performance guarantee can be addressed
through the federal loan guarantee programs
Feedstock supply chain issues can be addressed through
programs like the USDA‟s Biomass Crop Assistance
Program (BCAP)
Project financing can be improved through financial
assistance programs and capital construction tax
incentive programs
Product off-take supply issues can be addressed with
programs like the Cellulosic Biofuels Reverse Auction
Energy Efficiency & Renewable Energy eere.energy.gov
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Investing across the value chain
What‟s the Biomass Program Doing
to Address these Barriers?
• Feedstock & Feedstock Logistics
• Conversion: expanding beyond ethanol;
leveraging investments
• Demonstration and Deployment Projects
• Infrastructure Development for Mid-Level Blends
• Fuel Certification
Energy Efficiency & Renewable Energy eere.energy.gov
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Working with Stakeholders to Access Capital
and Secure Project Financing
What‟s the Biomass Program Doing
to Address these Barriers?
Financial/Market:
Financial assistance programs
LGP – DOE and USDA
Interagency collaborations: USDA – BCAP; EPA
– markets; DOD – potential off-take partner
Market development: RFS2, reverse auction,
off-take contract opportunities with industry
Energy Efficiency & Renewable Energy eere.energy.gov
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Near-Term Market Entry Opportunities
Challenges for the Demonstration
and Deployment of IBRs
Energy Efficiency & Renewable Energy eere.energy.gov
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Potential Near-term Market Entry Opportunities:
Market Entry Opportunities
• Breweries
• P&P plants – fuels, chemicals, power
• Oilseed crushers/processors
• Corn dry mills – fuels, chemicals
• Petrochemical Refineries – fuels, chemicals, power
• MRFs & Landfills – fuels, chemicals, power
• WWTP – fuels, chemicals, power
• Pharmaceutical and contract fermentation
operations
Energy Efficiency & Renewable Energy eere.energy.gov
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Focus on P&P Mills as a Market Entry Point –
Matching Barriers to Opportunities:
Market Entry Opportunities
• Feedstock Supply:
• Already been doing it for 100+ years
• Infrastructure already exists
• Relationships already in place
• Documented historical supply
• Documented cost history
• Sustainable practices already demonstrated
• Multiple opportunistic feedstocks already on or near site:
Hog fuel, Black Liquor, Green Liquor, Sludges
Energy Efficiency & Renewable Energy eere.energy.gov
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Focus on P&P Mills as a Market Entry Point –
Matching Barriers to Opportunities:
Market Entry Opportunities
• Technology:
• Derivative of existing P&P unit operations
• Staff already up to speed with most unit operations
• Sites already developed: permit facilitation, etc.
• Opportunities to reduce cost by co-location and shared
labor
• Option to reduce cost of operation and generate new
revenues
• Technology/business model readily replicated in other
mills
Energy Efficiency & Renewable Energy eere.energy.gov
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Focus on P&P Mills as a Market Entry Point –
Matching Barriers to Opportunities:
Market Entry Opportunities
• Product Off-take/Financing:
• Power contract with mill or grid provides reliable, long-
term off-take potential
• Co-location diversifies the product slate
• Mills can bring equity in form of equipment and site
• Mills bring operating cash flow that contributes to
successful financing potential
Energy Efficiency & Renewable Energy eere.energy.gov
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Focus on P&P Mills as a Market Entry Point –
Existing Examples:
Market Entry Opportunities
Tembec, Témiscaming, QC
• The only known pulp mill in North America that
currently produces ethanol.
• The company ferments spent sulfite liquor (wood
hydrolysates) with yeast
• Tembec produces 15 million liters per year (4
mmgy) of alcohol, most of which goes to the food
and beverage market.
Energy Efficiency & Renewable Energy eere.energy.gov
41
Focus on P&P Mills as a Market Entry Point –
Existing Examples:
Market Entry Opportunities
SEKAB AB, Domsjö, Sweden
• SEKAB has been producing ethanol from black
liquor since the „40s
• The company supplies over 90% of the Swedish
market through Brazilian imports and is ramping up
its own lignocellulosic ethanol technology
Energy Efficiency & Renewable Energy eere.energy.gov
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Highlighting Three P&P Projects in the
Biomass Program Portfolio
Challenges for the Demonstration
and Deployment of IBRs
Energy Efficiency & Renewable Energy eere.energy.gov
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Projects in the Biomass Program
Portfolio
Flambeau River Biofuels
• Site : Park Falls, WI
• Objective: Build and operate a 1000 ton-per-day Integrated
Biorefinery for production of renewable diesel at an Existing
Pulp and Paper Mill
• Supporting Pilot Data: 1000+ hours of pilot plant operation in
Raleigh, North Carolina
• Feedstock(s): Woody Biomass
• Technology: Thermochemical gasification with Fischer-
Tropsch
• Products: 18 MGPY Renewable Diesel and Olefins Waxes
Energy Efficiency & Renewable Energy eere.energy.gov
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Projects in the Biomass Program
Portfolio
NewPage Corporation: Project Independence
• Site : Wisconsin Rapids, WI
• Objective: Build and operate a 500+ ton-per-day Integrated
Biorefinery for production of renewable diesel at an Existing
Pulp and Paper Mill
• Supporting Pilot Data: 1000+ hours of pilot plant operation in
Raleigh, North Carolina
• Feedstock(s): Mill Residues and un-merchantable wood
• Technology: Thermochemical gasification with Fischer-
Tropsch
• Products: 8.2 MGPY Renewable FT Liquids
Energy Efficiency & Renewable Energy eere.energy.gov
45
Projects in the Biomass Program
Portfolio
Red Shield Acquisition – Old Town Mill
• Site : Old Town, ME
• Objective: Construct an Integrated Biorefinery that will
extract hemicelluloses from wood chips to make biofuel and
other specialty chemicals at an existing pulp mill.
• Feedstock(s): Pentose sugars from wood hydrolyzate
• Technology: Biochemical – Fermentation
• Products: 1.5 MGPY Biobutanol; 2.2 MGPY Acetic Acid
Energy Efficiency & Renewable Energy eere.energy.gov
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Challenges for the Demonstration
and Deployment of IBRs
The Mission is not over ; What‟s still to be done:
• Continue to foster new feedstock production methods
• Continue to develop feedstock collection, preprocessing and
supply logistics
• Demonstrate technology readiness and reliability
• Continue to develop market outlets and long-term contract
options
• Invest in pioneer plants to reduce technical risk and
demonstrate financing mechanisms
• Develop metrics and methods to document technology
sustainability and LCA/GHG benefits
• Develop sustainable public policy
Energy Efficiency & Renewable Energy eere.energy.gov
47
Secretary of Energy Steven Chu :
"Developing the next generation of biofuels is key to our effort to end our dependence on foreign oil and address the climate crisis -- while creating millions of new jobs that can't be outsourced. With American investment and ingenuity -- and resources grown right here at home -- we can lead the way toward a new green energy economy."
Challenges for the Demonstration and
Deployment of IBRs