Upload
others
View
2
Download
0
Embed Size (px)
Citation preview
B.Sc. Physics
Complete Notes of
MODERN PHYSICS
CHAPTER # 1: LIGHT AND QUANTUM PHYSICS
CHAPTER # 2: WAVE NATURE OF MATTER
CHAPTER # 3: NUCLEAR PHYSICS
CHAPTER # 4: ENERGY FROM NUCLEUS
B.Sc. Physics MODERN PHYSICS in Past Papers of University of
Sargodha
B.Sc. Physics, Paper C, Annual 2017
B.Sc. Physics, Paper C, Annual 2016
B.Sc. Physics, Paper C, Annual 2015
B.Sc. Physics, Paper C, Annual 2014
B.Sc. Physics, Paper C, Annual 2013
B.Sc. Physics, Paper C, Annual 2012
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
1 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
LIGHT AND QUANTUM PHYSICS \
The evidences in support of wave behavior of radiation are overwhelming. The radiations (including not only light but
all of electromagnetic radiations) show the phenomenon of reflection, refraction, interference, diffraction and
polarization, which can be understood by considering radiation as a wave.
In this chapter, we now move off in a new direction and consider experiments that can be understood only by making
quite a different assumption about electromagnetic radiation, namely, that it behave like a stream of particles.
49.1 Thermal Radiations
The radiations emitted by a body due to its temperature are called thermal radiations.
All bodies not only emit the thermal radiations, but also absorb these radiations from surroundings. If
the rate of emission of radiation is equal to the rate of absorption for a body, then the body is said to be in
thermal equilibrium.
The radiations emitted by a hot body depend not only on the temperature but also on the material of
which the body is made, the shape and the nature of the surface.
49.1.1 Cavity Radiator or the Black Body
A black body or cavity radiator is that which absorbs
approximately all radiations falling on it. So a black body has maximum
rate of emission and absorption of radiations.
A perfect black body does not exist. However a small hole in a
cavity whose inner wall are lamped black is the nearest approach to a
perfect black body.
For an ideal radiator (black body), the spectrum of the emitted
thermal radiation depends only on the temperature of radiating body and
not on the material, nature of the surface, size or shape of the body.
49.1.2 Radiant Intensity
Energy emitted per unit area per unit time over all the wavelengths, is called radiant intensity. It is
denoted by . Or
Power radiated per unit area over all the wavelengths is called radiant intensity.
49.1.3 Stephen-Boltzmann Law
The radiant intensity is directly proportional to the forth power of absolute temperature.
Mathematically,
where is a universal constant, called Stephen-Boltzmann constant. Its value is
.
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
2 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
49.1.4 Spectral Radiancy
Spectral radiancy of the black body is defined as the radiant intensity per unit wavelength at given
temperature. it is denoted by . Mathematically, it is described as:
This shows that the product of gives energy emitted per unit area per unit time over all the
wavelength lies in the range from to .
The energy emitted per unit area per unit time over all the wavelengths at a particular temperature is
obtained by integrating the equation (1), i.e.,
∫
49.1.5 The Wien Displacement Law
Statement. The wavelength for which the spectral radiancy becomes is inversely
proportional to the absolute temperature of the black body.
If is the wavelength corresponding to maximum spectral radiancy
for temperature , then the Wien displacement is described mathematically as:
The constant has the value of
Problem 1: What are the surface temperatures, radiant intensity and total radiated power of stars.
Sirius
Sun
Betelgeuse
Solution:
Surface Temperatures According to Wein’s Displacement Law:
Sirius
Sun
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
3 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
Betelgeuse
Radiant Intensity
By Stephan Boltzmann’s law:
Sirius
Sun
Betelgeuse
Total Radiated Power (L)
The total radiated power can be find out by expression:
Sun
Betelgeuse
The total radiated power of Betelgeuse is about 38000 times larger
49.1.6 Failure of Classical Physics to Solve the Problem of Energy Distribution along the Curve of Black
Body Radiation
The derivation of theoretical formula for distribution of spectral radiancy among various wavelengths has
remained an unsolved problem over a long period of time. On the basis classical physics, following two
formulas were derived to solve the problem of the energy-distribution along the curve of the black body
radiation.
Rayleigh-Jeans formula
Wien’s formula
49.1.7 Rayleigh-Jeans Formula
Rayleigh-Jeans derived a theoretical formula for the distribution of spectral radiancy among various
wavelengths on the basis of classical physics, which is given by:
Where k is the Boltzmann constant.
This formula was excellent for longer wavelengths but not good for shorter wavelengths.
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
4 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
48.1.8 Wien’s Formula
On the basis of analogy between the spectral radiancy curve and Maxwell speed distribution curve,
the Wien’s formula about spectral radiancy is described as
Where a and b are constant. Wien’s formula was in good agreement with the experimental curve for shorter
wavelength but not good for longer wavelengths.
Conclusion
Rayleigh-Jeans and Wien’s formulae were failed to solve the problem of distribution of spectral
radiancy among various wavelengths in cavity radiations because these formulae were based upon the
classical theory.
49.1.9 Success of Quantum Physics to Solve the Problem of Energy Distribution along the Curve of
Black Body Radiation
49.1.10 Max-Plank’s Quantum theory of Radiation
In 1900, Max-Planks gave the new concept about the nature of radiation, called Quantum theory of
radiation in which Planks assumed the discrete nature of radiation. He assumed the atoms of the cavity emit
and absorb radiation in the form of packet of energy, called quanta. The energy of each quanta is directly
proportional to the frequency:
Where h is the plank’s constant having the numerical value of .
In addition to this concept Max-Planks made the following assumption to derive his radiation law:
The atoms of the cavity behave like tiny harmonic oscillators.
The oscillators radiate and absorb energy only in the form of packets or bundles of electromagnetic
waves.
An oscillator can emit or absorb any amount of energy which is the integral multiple of .
Mathematically,
Where n is an integer.
Using these assumptions, Plank’s derived his radiation law given by:
Where and are the constant whose values can be chosen from the best fit of experimental curve. Within
two months, Plank’s succeeded to reform his law as:
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
5 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
49.1.11 Derivation of Rayleigh-Jeans Formula from Max-Plank’s Radiation Law
Plank’s radiation law approaches to Rayleigh-Jeans law at very long wavelengths. The Plank’s
radiation law is given by:
-------------- (1)
Putting
For a very long wavelengths i.e.,
And
Putting these values in equation (1), we get:
Back substituting the value of , we have
This is the Rayleigh-Jeans formula.
49.1.12 Derivation of Wien’s Formula from Max-Plank’s Law
Plank’s radiation law approaches to Wien’s formula at very short wavelength. The Plank’s radiation
law is given by:
Putting and
For very short wavelengths, i.e.,
So
Putting these values in equation (2), we have:
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
6 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
This is the Wien’s formula for spectral radiancy.
ءںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ےہ۔ ور ونسٹ اینپ یتمیق آرا رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ا ای لیم
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
49.2 Photo Electric Effect
The interaction between radiation and atoms of the
cavity lead to the idea of quantization of energy. It means that
energy can be emitted and radiated in the form of packets.
Photo electric effect is another example of interaction between
radiation and matter.
Definition: When a light of suitable frequency falls on a metal
surface, the electrons are emitted out. These electrons are called
photo electrons and this phenomenon is called photo electric
effect.
49.2.1 Experimental Set-up
The apparatus used to study the photo electric effect is shown in the figure. The light of a suitable
frequency falls on the metal surface, which is connected to the negative terminal of variable voltage source. If
the frequency is high enough, the electrons are emitted out from metal plate and accelerate towards anode.
These electrons are called photo electrons and current flows through circuit due to photo electrons is called
photo electric current. This phenomenon is called photo electric effect.
49.2.2 Maximum K.E of Photo Electrons
The maximum K.E of photo electrons can be measured by reversing the polarity of the battery. Now
the photo electric current will be reduced. The photo electric current does not drop to zero immediately
because the photo electrons emit from metal plate with different speeds. Some will reach the cathode even
though the potential difference opposes their motion. However if we make the reversed potential difference
large enough (called stopping potential) at which the photo electric current drops to zero. This potential
difference multiplied by the electronic charge gives the maximum kinetic energy of photo electrons.
Mathematically, the maximum kinetic energy of photo electrons is described as:
where is the stopping potential and is the charge of an electron.
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
7 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
49.2.2 Experimental Results
Photo electrons are emitted out from the given metal surface when the frequency of incident light is
equal to or greater than a critical value , called threshold frequency,
whatever the intensity of light may be.
Photo electric emission will not take place from a given metal surface if the
frequency of the incident light is less than the
threshold frequency whatever the intensity
of light may be.
Threshold frequency depends upon
the nature of the metal surface.
The energy of photo electrons
depends upon the frequency of incident
light and independent of the intensity of light.
The number of photo electrons emitted per second is directly
proportional to the intensity of light provided that the frequency of light
is equal to or greater than the threshold frequency.
49.2.4 Threshold Frequency
The frequency of the incident light required to remove least tightly bound electron from the metal
surface, is called threshold frequency.
49.2.5 Photo Electric Effect on the Basis of Classical Wave Theory
According to classical wave theory, the light consists of electromagnetic waves and their function is
to transfer energy from one place to another.
When light falls on metal surface, it transfer energy to the electrons continuously. When an electron
acquires sufficient energy, it escapes out the metal surface.
This theory successfully explains the emission electrons apparently, but this theory can’t explain the
three major features of photo electric effect.
The Intensity Problem
The Frequency Problem
Time Delay Problem
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
8 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
49.2.5.1 The Intensity Problem
According to classical wave theory, the light consists of oscillating electric and magnetic vector,
which increases in amplitude as the intensity of light beam is increased. Since the force applied to the
electrons is ‘ ’, therefore the kinetic energy of the electrons should also increased with the intensity of
light. However, the experimental results suggest that the K.E of electrons is independent of intensity of light.
49.2.5.2 The Frequency Problem
According to classical wave theory, the photo electric effect should occur for any frequency of light
provided that the incident light is intense enough to supply the energy needed to eject the photo electrons.
However, the experimental results show that there exists a critical frequency for each material. If the
frequency of the incident light is less than the photo electric effect does not occur, mo matter how much the
intensity of light is.
49.2.5.3 Time Delay Problem
The classical wave theory predicts that there must be a time interval between the incidence of light on
the metal surface and the emission of photo electrons. During this time, the electron should be absorbing
energy from the beam until it has accumulated enough energy to escape the metal surface. However the
experimental results show that there is no detectable time interval between the incidence of light and emission
of photo electrons provided that frequency of light is equal to or greater than the threshold frequency.
Conclusion
These three major features could not be explained on the basis of wave theory of light. However
Quantum light theory has successfully explained the photo electric effect which was proposed by the Einstein
in 1905.
49.2.6 Photons
In 1905, Einstein proposed quantum theory to explain the photo electric effect, according to which the
light consist of bundles or packets of energy, called photons. The energy E of a single photon is
where is the frequency of light and is the planks constant .
According to quantum theory, on photon of energy is absorbed by a single electron. If this energy is
greater than or equal to a specific amount of energy (called work function), then the electrons will be ejected,
otherwise not.
49.2.7 Work Function
The minimum amount of energy required to eject the electrons out of metal surface, is called work
function , which can be described as:
Here is the threshold or cur off frequency and is known as cut off wavelength.
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
9 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
49.2.8 Threshold Frequency or Cut Off Frequency
It is the minimum frequency of incident light at which the photoelectric effect takes place.
49.2.9 Einstein’s Photo Theory or Quantum Theory of Photoelectric Effect
When a incident light of suitable energy is exposed to the metal surface, then a part of this energy is
utilized in ejecting electron from metal surface and the excess energy ( ) becomes the kinetic energy of
photoelectrons. If the electrons does not lose any energy by the internal collision as it escapes from the metal,
then its energy will be maximum which can be described by the
formula:
As and
------------ (1)
(
)
From equation (1), it is clear that the stopping potential and
the frequency of light has a linear relationship and graph between these
quantities is a straight line.
Conclusion
In 1916, Millikan showed that Einstein’s equation agreed with experiments in every detail. Hence the
photon theory explains that, if the frequency of light is less than the threshold frequency , then no
photoelectrons will be emitted, how much the intensity of light may be.
If the frequency of light is equal to greater than cut off value , then weakest possible beam of light
can produce photo electric effect. Because the energy of one photon depends upon the frequency of light i.e.,
and not on the intensity of light.
Sample problem 6. Find the work function of sodium for which the threshold frequency is
.
Solution: Threshold frequency is
Work Function
As
Problem 29. An atom absorbs a photon having a wavelength 375 nm and immediately emits another
photon having wavelength 580 nm. What was the energy absorbed in this process?
Solution
Wavelength of incident photon
Wavelength of emitted photon
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
10 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
Energy Absorbed
(
) (
)
(
)
ءانبےن ےکےئل آپ یک دمد یک رضورت ےہ۔ںیمہ اس اکر ریخ وک رتہب ور ونسٹ اینپ یتمیق آرا رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ا ای لیم
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
www.facebook.com/HomeOfPhysics
Problem 35. (a) The energy needed to remove an electron from metallic sodium is 2.28 eV. Does the
sodium show photoelectric effect for red light with ? (b) What is the cur off wavelength for
photoelectric emission from sodium and to what color this wavelength corresponds?
Solution:
Wavelength of incident Photon
Work function
Energy of incident photon
As , so no photoelectric effect will take place.
(b) Cut off Wavelength
Work function
The cut off wavelength corresponds to green color.
Problem 36: Find maximum kinetic energy in eV of photoelectrons if the work function of the material
is 2.33 eV and frequency of radiation is
Solution:
Work function
Frequency of incident photon
Maximum kinetic energy of Photoelectrons
The maximum kinetic energy of electrons can be find out by expression:
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
11 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
Now
Therefore,
Problem 38: light of wavelength 200 nm falls on an Aluminum surface. In Aluminum 4.2 eV is required
to remove an electron. What is:
a) Kinetic energy of fastest electron
b) Kinetic energy of slowest electrons
c) Find stopping potential
Solution:
(a)
(b)
The minimum K.E of photoelectrons is zero as it consumes all of its K.E in colliding with the atoms
of the metal.
(c)
As
Also
Therefore:
Problem 39: If the work function for the metal is . (a) What would be the stopping potential for
light having a wavelength of . (b) what would be the maximum speed of the emitted
photoelectrons at the metal surface?
Solution: (a)
(b)
As
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
12 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
√
√
ءںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ےہ۔ ور ونسٹ اینپ یتمیق آرا رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ا ای لیم
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
49.3 The Compton Effect
In 1923, Compton performed an experiment and he observed that the wavelength of X-rays changes
after scattering from a graphite target. Compton explained his experimental results postulating that the
incident X-rays beam consists of photons, and these photons experienced Billiard-Ball like collision with the
free electrons in the scattering target.
The experimental set-up for observing the Compton effect is shown in the figure below.
Compton effect can be explained by considering the elastic collision between X-ray photon and
electrons.
Consider an incident photon having energy and momentum
and
respectively. The
photon is scattered by a stationary electron along an angle with its regional direction, as shown in the figure.
The energy and momentum of the scattered photon are
and
respectively. The
rest mass energy of electron is , which is recoiled making an angle θ with the original direction of
incident photon.
During the elastic collision, both the energy and momentum remains conserved. So the energy
equation in this case is:
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
13 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
Dividing equation by ‘ ’, we get:
Squaring both sides of the equation,
(
)
(
)
--------- (1)
The conservation of momentum along the original direction of incident photon (along x-axis) is
Squaring both sides, we get:
--------- (2)
The conservation of momentum along the direction perpendicular to the original direction of photon
(y-axis) is:
Squaring both sides, we get:
--------- (3)
Adding equation (2) and (3)
--------- (4)
Subtracting equation (4) from equation (1), we get:
(
)
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
14 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
√
(
)
(
)
(
)
(
)
(
)
This is the expression of Compton shift, which shows consistency with experimental results. As collision is a
particle phenomenon, hence the particle nature of radiations was confirmed.
Sample Problem 8: X-rays with are scattered from a carbon target. The scattered
radiation is viewed at to the incident beam. (a) What is Compton shift ? What kinetic energy is
imparted to the recoiling electron?
Solution: (a)
(b) K.E imparted to electron
(
) (
)
Problem 51: A particular X-ray photon has a wavelength . Calculate the photon’s (a) energy
(b) frequency (c) the momentum
Solution: (a)
B. Sc. Physics (H.R.K) Chapter 49: Light and Quantum Physics (Edition 2015-16)
15 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected], www.facebook.com/HomeOfPhysics
(b)
(c)
Problem 55: Photon of wavelength are incident on free electrons. Find the wavelength of
photon that is scattered at from the incident direction? Do the same if the if the scattering angle is
.
Solution:
a) for
b) for
(a)
(b)
This result shows that as the angle of scattering increases, the wavelength of scattered photon also
increases.
ءےہ۔ںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ور ونسٹ اینپ یتمیق آرا رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ا ای لیم
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
16 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
In this chapter, we present experimental evidence supporting the claim that matter, long regarded as made up
of particles, has an equally convincing wave aspect. Heisenberg’s uncertainty principle will show us the limit
to which we can extend the concept of “particle” to into quantum mechanics.
We then introduce the Schrodinger’s equation, the fundamental equation to quantum mechanics, which deals
with the wave behavior of the particles.
THE WAVE NATURE OF MATTER
50.1 Dual Nature of Radiation
The electromagnetic radiations like light, X-rays etc., can produce the phenomenon of interference,
diffraction and polarization due to their wave nature. But under certain circumstances they can produce
photoelectric effect and Compton Effect which is the evidence of their particle nature. It means that
electromagnetic radiations have dual nature; wave as well as particle nature.
50.2 Dual Nature of Matter
In a similar way the particles like electrons, neutrons and protons etc. must have dual nature. If the
beam of electrons accelerated through a known potential difference ‘V’, is made to fall on a double slit and
after passing through the double slit, they are allowed to strike on a fluorescent screen. It has been observed
that pattern obtained on the screen is similar to the pattern of interference of light.
50.2.1 Double Slit Experiment
In Double slit experiment, a filament produces a spray of electrons which are accelerated through a
potential difference of about 50 kV. After passing through double slit, the electrons produce a visible
interference pattern on fluorescent screen, which can be photographed.
50.3 De Broglie Hypothesis
A wave is associated with every moving particle. Such a wave is called matter wave whose
wavelength can be find out by expression:
Where h is Plank’s constant, m is mass and v is velocity of moving object.
As the value of Plank’s constant is very small and is of the order of , the wavelength
associated with ordinary object (e.g., A moving tennis ball) is so small and is difficult to observe. But for the
small objects like electrons and neutron etc., the wave behavior of particles is dominant.
رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ ور ونسٹ ای لیم ءا ںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ےہ۔اینپ یتمیق آرا
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
17 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.4 The Davison-Germer Experiment
The De Broglie hypothesis was confirmed by Davison and Germer. The schematic diagram of
Davison and Germer experimental setup is shown in the figure.
The electrons from a heated filament F are accelerated
by an adjustable potential difference V. The beam of electrons is
allowed to fall on a nickel crystal. The diffracted beam of
electrons is detected by a movable detector at different values of
angles.
It is observed that there is a strong diffracted beam
obtained for and . This situation is
similar to the diffraction of light produced by the diffraction
grating.
In nickel crystal, the atoms are arranged in definite order; hence the crystal surface acts like a
diffraction grating. The first order maxima is obtained at an angle . The wavelength associated with
electrons can be determined by using the equation:
Here for the first order diffraction peak
Inter-planner spacing for nickel
Angle of diffraction
The wavelength of the matter wave, can be find out by using de Broglie hypothesis:
The kinetic energy of the electron is:
√
√
By putting the value of constants and , we have:
So, the value of de Broglie wavelength is in good agreement with the experimentally observed
wavelength associated with electrons.
50.5 G. P. Thomson Experiment
In 1927, G. P. Thomson (son of J. J. Thomson) performed an experiment and confirmed the de
Broglie equation of matter waves.
He obtained a fine beam of electrons accelerated through a potential difference of 15 kV and made it
to fall on a target which was not a single crystal, but it was made up of a large number of tiny, randomly
oriented crystallites (powdered aluminum).
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
18 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
A photographic plate was placed parallel to the target on which the diffraction pattern was obtained. It
was observed that the diffraction pattern of electrons was very similar to the diffraction of X-rays. As the
diffraction is a wave property, so the wave nature of electrons was confirmed experimentally.
The wavelength of the matter waves associated with the electrons can be determined by using the
Bragg’s equation:
------------ (1)
Where d is the inter-planner spacing, is the glancing angle and m is the order of diffraction.
If V is the potential difference through which the electrons are accelerated, then the kinetic energy of
electrons is:
√
According to de Broglie hypothesis
√
√
G. P. Thomson observed that the de Broglie wavelength associated with moving electrons was good in
agreement with experimentally observed value, that was find out by using Bragg’s law.
The atomic structure of solids are studied the diffraction beam of electrons. The electrons are less
penetrating than X-rays, so the electrons are used to study the surface morphology of solids.
Sample problem 2: Calculate the de Broglie wavelength of (a) a virus particle of mass
moving at the speed of , and (b) an electron whose kinetic energy is .
Solution.
Mass of virus
Velocity
De Broglie Wavelength
( )
(b) Kinetic Energy of electron
√
De Broglie Wavelength
( )
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
19 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Problem 1. A bullet of mass 41 g travels at 960 m/s. what wavelength can we associate of the bullet not
reveal itself though diffraction effects?
Solution
Mass of bullet
Velocity of bullet
De Broglie Wavelength
( )
For diffraction condition:
Wavelength Size of diffracting aperture
As the wavelength of associated with bullet is very small, so diffraction effects of bullets can’t be revealed.
Problem 3: Calculate the wavelength of a 1 keV (a) electron (b) photon (c) neutron.
Solution: Kinetic Energy
De Broglie Wavelength
We know
( )
√ ( )
(a) For an electron
So
√ ( )
√
(b) For photon
(c) For neutron
So
√ ( )
√
Problem 4: The wavelength of yellow spectral emission line of sodium is . At what K.E would
an electron have same de Broglie wavelength?
Solution: Given wavelength
(a) For an electron
As we know:
√ ( )
( )
( )
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
20 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Problem 5: If the de Broglie wavelength of proton is 0.113 pm, (a) What is the speed of the proton and
(b) what electric potential would the proton have to be accelerated from rest to acquire this speed?
Solution
(a) Wavelength associated with proton
Velocity of proton
Mass of proton
As
(b) Electric Potential
For present case:
Problem 15: A neutron crystal spectrometer utilizes crystal planes of spacing in a
Beryllium crystal. What must be the Bragg’s angle so that only neutrons of energy are
reflected? Consider only fist order spectrum.
Solution:
Given Inter-planner spacing
Bragg’s Angle
Order of diffraction
Kinetic Energy
According to Bragg’s Law:
√
√
( )
Sample Problem 4. Thermal neutrons (293 K) coming out of a nuclear reactor fall on a crystal. The
spacing between the Bragg’s planes is . Find the most probable de Broglie wavelength in
the beam of these neutrons. (b) Find the Bragg’s scattering angle for the first order Bragg’s Diffraction.
Solution: (a) Boltzmann’s constant
Temperature
Order of diffraction
Inter-planner Spacing
√
√
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
21 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Now according to Bragg’s Law:
(
)
50.6 Waves and Particles
The evidence of the matter is wave like is very strong. On the other hand, the evidence that a matter is
particle like is equally as strong. In these situations, the description of wave as well as the particle nature of
matter has remained a challenge for the scientists.
One property that we like for the particles (even particles with the wave like nature) to have the ability
to be localized. For example, an electron in an atom of 0.1 nm diameter is localized in certain region of space.
On the other hand, a wave cannot be localized in space and time like a particle.
The amplitude of a matter wave carries information about the location of the particle. The wave has
the large amplitude where the particle is likely to be found, and it has the small amplitude where the particle is
unlikely to be found. If the wave has the constant amplitude throughout a given region of space, the particle is
equally likely to be found anywhere in that region. If the amplitude of the matter wave is zero in a specific
region, then the particle never found there.
50.7 Localizing Wave in Space
A wave packet is associated with a moving particle. Many waves adds up to make a wave packet of
length and adds to zero everywhere else. Thus for the present case, the particle is localized in space. The
particle is likely to be found in the region of size and unlikely to found outside that region.
This wave packet no longer contains a single wave number but rather a spread of wave numbers
centered about . Let is the rough measure of the spread of wave numbers. The product of and is
proves to be of the order of unity:
This expression tells that the smaller the value of , the larger must be the range of wave numbers .
Conversely, the narrower the spread in , the less localized the particle will be.
50.8 Localizing Wave in Time
A particle is localized in space as well as in time. So, the space variable x must be replaced by time
variable t (as the wavelength by the time period ). And the wave number must be replaced by the
angular frequency .
Similarly, the spread of wave number must be replaced by and the displacement by the
interval of time . So we have
It means that the product is of the order of unity.
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
22 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.9 Derivation of Heisenberg’s Uncertainty Relationship by Localization of Wave in Space
Consider a particle of mass m is moving along x-axis with velocity . By Localization of Wave in space, we
know:
( )
Where is the region in which the particle is likely to be found and is the rough measure of the spread of
wave numbers.
According to the de Broglie Hypothesis, the wavelength of the matter wave associated with moving
particle is described as:
Where h is the Plank’s constant and is the linear momentum of moving particle.
The angular wave number associated with this particle is described as:
(
)
The spread of wavenumber will be:
(
)
( )
Putting value of in equation (1), we get:
(
)
This is the expression of Heisenberg Uncertainty Relationship for the particle moving along x-axis. If
the motion of the particle depends upon the three coordinates x, y, z, the generalizing above relation, we have:
According to these relationships:
It is not possible to determine both the position and
the momentum of a particle with ultimate precision.
The width of the wave packet indicates the probable location of the particle, and is the range
in momentum.
It means that due to the wave nature, the exact position x of a particle cannot be determine, but it will
be in the range . Similarly, the true or exact momentum of the particle cannot be determined, but it will
be in the range of .
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
23 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.10 Derivation of Uncertainty Principle by Single-Slit Diffraction of Electron Experiment
Consider the experiment of diffraction of electrons by single slit. Let a beam of electrons moving with
speed passes through a single slit of width . The diffraction pattern is obtained on the screen B as shown
in the figure.
Due to the wave nature, the electron
beam bends on the either side of the central
point producing the diffraction pattern. Let
is the uncertainty in the component of
velocity along y- axis for the first minimum,
then we have
Consider the angle is very small, then
:
( )
In case of location of the first minimum of diffraction, we have:
Here m=1 and if is very small, then
( )
Comparing equation (1) and (2), we have:
According to the de Broglie hypothesis:
(
)
It means that, if the position of the particle is made more and more precise, the uncertainty in the
momentum of the particle increases and vice versa. On other words,
It is not possible to determine both the position and the momentum
of a particle with unlimited precision.
رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔ ور ونسٹ ای لیم ءا ںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ےہ۔اینپ یتمیق آرا
ہ رہش ٹنمن ڈرگی اکجل ون دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
24 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.11 The Energy-Time Uncertainty Relationship
The wave nature of a particle can be represented by the wave packet having angular frequency . So
the spread of angular frequency and the time interval are related as:
( )
According to Einstein’s photon equation is
where is frequency of photon.
The uncertainty in the frequency of the matter waves will be:
As
, put in equation (1):
(
)
This is another form of Uncertainty principle. It may be stated as:
It is not possible to determine both the energy and time co-ordinates with ultimate precision.
Problem 23: A nucleus in an excited state will return to its ground state, emitting a gamma ray in the
process. If its mean life time is 8.7 ps in a particular excited state of energy 13.2 MeV, find the
uncertainty in the energy of the corresponding emitted gamma-ray photon.
Solution:
By Heisenberg Uncertainty Principle:
Problem 25: A microscope using photons is employed to locate an electron in an atom within a distance
of 12 pm. What is the minimum uncertainty in the momentum of the electron located in this way?
Solution:
Now as
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
25 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Problem 26. Imagine playing a base ball in a universe where the planks constant is 0.60 J-s. what
would be the uncertainty in the position of a 0.5 kg base ball moving at 20 m/s with an uncertainty in
velocity is 1.2 m/s? Why would be hard to catch such a ball?
Solution:
Planks constant
Mass of the ball
Uncertainty in velocity
Now
The base ball will be in a region anywhere in a distance of 0.159 m=15.9 cm. so it will be hard to catch such a
ball.
Sample Problem 7: The rest mass energy of a massive particle is . The uncertainty of
measurement is only . What is the mean life interval between production and decay of this
particle?
Solution:
Sample Problem 6: (a) A free 10 eV electron moves in the x-direction with a speed of .
Assume that the speed can be measured to a precession of 1%. With what precision its position can be
simultaneously measured? (b) A golf ball has a mass of 45 g and a speed of 40 m/s, what you can
measure with a precision of 1%. What would be the uncertainty in its position?
Solution: Velocity of electron
Uncertainty in velocity
Now
(a) Mass of golf ball
Velocity of electron
Uncertainty in velocity
Now
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
26 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.12 The Wave Function
The wave nature of a particle can be represented by wave function , which is the function of space
and time co-ordinates. The behavior of the particle in terms of wave can be determined by knowing the wave
function for every point in the space and for every instant of time:
( )
Explanation
Consider a matter wave associated with a particle of mass travelling in the direction of increasing x
and on which no force acts, so called free particle. To describe the displacement associated with such a wave,
the American physicist Erwin Schrodinger introduced a quantity ( ) for such a free particle, called wave
function. The wave function for a free particle moving in the direction of increasing x is given by:
( ) ( )
Here is the amplitude of the wave, (
) is the wave number and ( ) is the angular
frequency. As this wave function contains the imaginary number ( √ ), so it a complex quantity.
Physical Interpretation of Wave Function
The physical interpretation of the wave function was given by the German Physicist Max Born. He
asserted that physical meaning should not be given to itself, but to the product of and its complex
conjugate . Specifically, Born postulated:
The product gives the probability that the particle
in question will be found between position and .
50.13 Schrodinger’s Equation
The Schrodinger equation is used to find out the expression of wave function of moving particle in a specific
direction. As it is described earlier, that a wave function is the function of both space and time variables. So
we can write the wave function for the particle moving along axis as:
( ) ( ) ( )
That is, the wave function of a particle can be described as the product of space dependent wave
function ( ) and time dependent wave function ( ). In the rest of the chapter we will focus our attention to
the space dependent portion of wave function.
Now the Schrodinger’s equation for a particle travelling in the direction is:
( )
( ) ( ) ( )
where is the total energy of the particle and ( ) is its potential energy.
50.14 Schrodinger’s Equation for a Free Particle
If the particle is a free particle, its potential energy ( ) is a constant which we can take to be zero
for all values of . The total energy E of the moving particle must be taken entirely kinetic. That is, in which
we must have
, in which is the momentum of the particle. With this assumption, the
Schrodinger’s equation becomes:
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
27 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
( )
( )
( )
( )
Put
--------------- (1), where is the wave number.
( )
( )
( )
( )
Putting
, we have:
( ) ( )
( ) ( )
The characteristic equation is described as:
√
The characteristic solution of this equation will be: ban
( ) ------------ (2)
As the particle is moving along positive x-direction, so the equation (2) will become:
( ) ------------ (3)
where A is the amplitude of the wave. The expression in equation (3) is wave function for the free particle
moving along direction.
Probability Density
For the free particle, the probability density P(x) is described as:
( ) [ ][ ]
Thus the probability density of a free particle is constant and is independent of or . Thus we conclude
that the particle can be find with equal probability, at any point along the x-directin from to .
Wave Number
From equation (1), we have
For the free particle, the total energy
, in which is the momentum of the particle.
( ⁄ )
Using de Broglie hypothesis, we have
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
28 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.15 Particle in a Well or One Dimensional Box
Let a particle of mass m is moving in a one-dimensional box of length . Consider that the particle
moves back and forth along x-axis between the perfectly hard and infinite high walls of the box, from
to , and no force acts on it during its motion. The particle suffers elastic collisions and its total energy
remains constant.
As there is no force acting on the particle, therefore
For convenience, we take the potential energy of the particle as zero, i.e., , inside the box. Since
the walls of the box are infinitely high, therefore the potential energy of the particle outside the box is infinite.
Since the particle cannot have an infinite amount of energy, so it cannot exist outside the box. Hence the wave
function of the particle ( ) is zero for and .
( )
( )
( )
( )
( )
( )
Put
--------------- (1)
( )
( )
Putting
, we have
( ) ( )
( ) ( )
For characteristic solution, we have:
√
The characteristic solution of this equation will be:
( )
( ) ( ) ( )
( ) ( ) ( ) --------- (2)
Let
Thus equation (2) will become:
( ) ---------- (3)
Where the constants A and B can be evaluated from the boundary conditions, which are:
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
29 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
(i) at
And (ii) at
Applying the 1st boundary condition, the equation (3):
Applying the 2nd
boundary condition:
, where n is an integer
----------- (4)
Thus equation (3) will become:
( )
----------- (5)
The solution of the wave function for the particle in a box, since we have not yet determined the
constant A. for this purpose, we make use of the normalization condition:
∫ | ( )|
For the present case:
∫| ( )|
∫ (
)
∫[ (
) ]
√
Thus the equation (4) will become:
( ) √
Energy of the particle in the Box
From equation (1) and (4), we have:
----------------- (6)
For ,
. Thus the equation (6) will become:
This shows that the particle in the box have discrete values. Hence, the energy of the particle in the box is
quantum box is quantized.
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
30 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
50.16 The Potential Step and Barrier Tunneling
When a particle is moving in a region of a constant potential suddenly comes across another region of
different constant potential, the common boundary of the two regions is
called potential step. In the figure, the height of the potential step is ,
say at . According to the classical physics, the particle coming from
region I, approach the potential barrier of potential step with energy,
and are slow down by the force
, so that the kinetic
energy is converted into potential energy. If the particles have sufficient
energy to overcome the barrier, then there will be total transmission. And
if , then the particles are stopped by the barrier and their motion will be reversed. In this case, there is
the total reflection of the beam.
Quantum mechanically, for this potential step, we have the potential function as:
( )
( )
For the present case, the Schrodinger wave equation will be:
( )
( ) ( ) ( )
( )
[ ( )] ( )
( )
[ ( )] ( ) ---------------- (1)
Case-1.
Region-1
Let the particles with total energy E moves from region-I to region-II along x-axis. In region-I,
( ) . Therefore, the equation (1) will become:
( )
( )
Put
--------------- (2)
where is the wave number.
( )
( )
The characteristic solution of this equation will be:
( )
------------ (3)
The first and the second term of equation (3) represent the incident and reflected particles respectively.
Region-II
For region-II, ( ) . Therefore, the eqution (1) for the case of region-II will be:
( )
[ ] ( )
Put ( )
--------------- (4)
B. Sc. Physics (H.R.K) Chapter 50: The Wave Nature of Matter (Edition 2015-16)
31 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
where is the wave number.
( )
( )
The characteristic solution of this equation will be:
( )
------------ (5)
In equation (5), the first term represents the transmitted wave. And the second term represents a wave coming
from in the negative direction. Clearly, for , no particle can flow to region-I and D must be zero.
Therefore, the equation (5) becomes:
( )
------------ (6)
Case-2.
Region-I.
When is less than , then solution of Schrodinger wave equation for region-I is:
( )
( )
Put
------------ (7)
where is the wave number.
( )
( )
The characteristic solution of this equation will be:
( )
------------ (8)
The first and the second terms corresponds to the incident and reflected beams respectively.
Region-II.
When is less than , then solution of Schrodinger wave equation for region-II is:
( )
[ ] ( )
As , therefore the Schrodinger wave equation will become:
( )
[ ] ( )
Put ( )
--------------- (9)
where is the wave number.
( )
( )
The characteristic solution of this equation will be:
( )
------------ (10)
The first and the second terms corresponds to the incident and reflected beams respectively. The
equation (10) describes that there is always be a probability for a particle to move through a barrier.
ور ونسٹ ای لیم ءا ہںیمہ اس اکر ریخ وک رتہب انبےن ےکےئل آپ یک دمد یک رضورت ےہ۔اینپ یتمیق آرا رہش ٹنمن ڈرگی اکجل ون رکںی ای سیف کب اڈیسی رپ جیسیم رکںی۔دمحم یلع کلم، وگر
[email protected], www.facebook.com/HomeOfPhysics
mailto:[email protected]://www.facebook.com/HomeOfPhysics
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
32 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
NUCLEAR PHYSICS
Deep within the atom lies its nucleus, occupying only of the volume of the atom but providing most of its mass as well as
the force that holds it together.
In order to understand the structure of nucleus, our task becomes easier by many similarities between the study of atoms and
the study of nuclei. Both systems are governed by the laws of quantum mechanics. Like atoms, nuclei have excited states that
can decay to ground state through the emission of photons (gamma rays).
In this chapter we study the structure of nuclei and their constituents. We consider some experimental techniques for studying
their properties, and we conclude with a description of the theoretical basis for understanding the structure of nucleus.
54.1 Rutherford Experiment for the Discovery of the Nucleus
In 1897 J. J. Thompson discovered electrons. He also suggested a model of atom. According to his
model, an atom consisted equal amount of positive and negative charge. The positive charge of the atom was
considered to be spread out through the entire volume of the atom and electrons were thought to be distributed
throughout this volume like seeds embedded in a watermelon. Thompson‟s model of atom could not account
for the deflection of the particles passing near the surface of
the atom and particularly by the backward deflection of an
particle.
In 1911, Ernest Rutherford performed an experiment to
investigate the model of the atom. The apparatus consisted of a
source of particles, thin gold foil and a moveable detector.
A fine beam of high energy particles was made to fall on a
thin gold foil.
The scattered particles were detected at different
angle by a moveable detector. It was discovered that most of the
particles passed through the gold foil without any
deflection, or at very small angles of deflection. A very small fraction of particles were scattered through
large angles approaching 180˚.
A graph is plotted between the number of particles scattered and the scattering angle as shown in
the figure.
The results obtained were very surprising to Rutherford. He concluded that there is a very small
region inside an atom which is massive and whole mass of the atom is concentrated at this region which has
positive charge. This small region was give the name „nucleus‟. This is the reason why most of the
particles passed through the gold foil at small scattering angles. Only those particles could be deflected
through large angles which suffered head-on collision with the nuclei.
Therefore, according to Bohr and Rutherford, the model of atom may consist of a nucleus which is
massive and positive charged part, while the electrons are moving around the nucleus in allowed circular
orbits.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
33 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
54.2 Some Nuclear Properties
(i) Nuclear Systematic
Nuclei are made up of protons and neutrons. But these particles are not true elementary particles;
these are made up of other particles called quarks.
The number of protons in a nucleus is called the atomic number or charge number. It is represented by
Z. The number of neutrons is called the neutron number. It is represented by N. The total number of nucleon
is called the mass number. It is represented by .
The charge on one proton is , while the neutron is a neutral particle. The nuclei,
having same charge number Z but different mass number is called isotopes. The nuclei which are not stable,
used to emit , and rays are called radioactive nuclides.
(ii) The Nuclear Force
A nucleus is packed with protons and neutrons. As proton is a positively charged particle, so, there
must be electrostatic repulsion. But the nucleus is very much rigid and stable. So, there must be some other
force inside the nucleus which is responsible for the stability and rigidity of the nucleus. This force is called
Strong Nuclear Force.
The electrostatic force (Coulomb force) is a long range force, but the Strong Nuclear Force is a short
range force, having the range of . This force binds every nuclear pair: proton-proton, neutron-neutron
and proton-neutron pair with in the tiny nuclear volume. For the short range of the order of , the
coulomb force is much smaller than the Strong Nuclear Force. If the separation between the nucleons is
increased beyond , the strong nuclear force drops to zero rapidly, then the Coulomb‟s force of
repulsion will be able to break the nucleus.
(iii) Nuclear Radii
The Bohr radius is , while the radius of the nucleus is of the order of .
So, the nuclei are smaller than the atoms by a factor of . The size and structure of the nuclei can be studied
by scattering experiments using incident beam of high energy electrons.
The energy of incident electrons must be greater than 200 MeV. These
experiments measure the diffraction pattern diffraction pattern of the
scattered particles and of deduce the shape of the scattering object (the
nucleus). The nucleus does not have sharply defined surface, however
have a characteristic radius „R‟. the density has constant value inside
the nucleus, but it falls to zero through fuzzy surface zone. The mean
radius is given by:
Where A is the mass number and is a constant whose value is 1.2 fm. For example, the has the radius
.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
34 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
(iv) Nuclear Mass and Binding Energies
Atomic masses are measured in atomic mass units ( ). The atomic mass unit is defined as
times
the atomic mass of . Thus
One atomic mass unit „ ‟ is equivalent to the energy:
This means that we can write as .
(v) Nuclear Spin and Magnetism
Just like atoms, the nuclei have intrinsic angular momentum (nuclear spin) whose maximum value
along z-axis is
, where is total intrinsic angular momentum or nuclear spin quantum number.
In atomic magnetism, the Bohr magneton is given by:
Where is the mass of electron and T stand for tesla. Similarly for nuclear magneton , we have:
The magnetic moment of the heavier nuclei can be analyzed in terms of the magnetic moments of its
constituent protons and neutrons.
54.3 Binding Energy
It is the amount of energy required to tear a nucleus into its constituent nucleons. Or when nucleons
are fused to form a nucleus, then some energy is released which is called binding energy.
Example
The nucleus of Deuteron (a heavy hydrogen atom) consists of a protons and a neutron bounded
together by a strong nuclear force. The energy that we must add to deuteron to tear it apart in to its
constituent nucleons is called the energy. If , and are the masses of deuteron, neutron and proton
respectively, then according to the law of conservation of energy:
(
)
----------------- (1)
Here and
are the masses of the hydrogen and deuteron atom, respectively.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
35 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
[
] ---------------- (2)
In which,
.
As , and
. So by substituting the
values (2) and replacing by its equivalent , we find the binding energy to be:
.
54.3.1 Binding Energy per Nucleons
This is the binding energy of the deuteron. If the binding energy is divided by mass number A,
then binding energy per nucleon (
) is obtained. Figure show a graph between energy per nucleon (
) and
mass number A.
The (
) is high for middle mass nucleons. It means
that these nucleons are tightly bound and the nucleus
is much stable. The region of greatest stability
corresponds to mass number about 50 to 80.
The biding energy per nucleon curves drops at both
high and low mass numbers has the practical
consequence of the greatest importance. The dropping
of the binding energy curve at high mass numbers tells
us energy can be released in the nuclear fission of a
single massive nucleus into two smaller fragments.
The dropping of the binding energy curve at low mass
numbers tells us that energy will be released if the two nuclei of small mass numbers combined to form a
single middle mass nucleus. This process, the reverse of fission, is called nuclear fusion.
Sample problem 3. Find the total energy required to split into its constituent protons and
neutrons. (b) Find the energy per nucleon. The atomic mass of is
Solution. Number of proton (Atomic Number)
Atom Mass
Number of Neutrons (Neutron #)
Binding Energy
Mass Defect [ ]
Now
(b)Binding energy per Nucleon
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
36 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Problem. Find the energy per nucleon . The atomic mass of
is
Solution.
Number of proton (Atomic Number)
Atom Mass
Number of Neutrons (Neutron #)
Binding Energy
Mass Defect [ ]
Now
Binding energy per Nucleon
54.4 Radioactive Decay
The elements having charge number greater than 82, are not stable. They disintegrate and emit
particles or radiation spontaneously. Such elements are radioactive and this process of spontaneous emission
of particles or radiations is called radioactive decay or natural radioactivity.
Experiment
The radioactive sample is placed in a cavity in a lead block
above which a photographic plate is held. The whole apparatus is
placed inside a vacuum chamber, in which magnetic field is also
applied, as shown in the figure.
Three images are obtained on the photographic plate. It means
that three types of radiations are emitted by the radioactive sample,
which particles, particles and rays.
(i) particles
particles is a helium nucleus which consist of two protons and two neutrons. Its charge number is
2 and mass number is 4. It is highly ionizing particle, but its range is small. Emissions of particles from an
atom reduces its mass number A by four units and atomic number Z by two units. As a result, the product
element moves two places backward in the periodic table.
Explanation
The radionuclide decays spontaneously according to the scheme:
With the half life of . In this process, an energy of 4.27 MeV is emitted appearing
as the kinetic energy of the alpha particle and the recoiling residual nucleus
.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
37 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
In order to explain the alpha decay, a model is used in which the particle is assumed to be exist
preformed inside the nucleus before it escapes.
The figure shows the approximate potential energy function U(r) for the particle and the residual
nucleus as the function of their separation. It is a combination of a potential well associated with the
attractive strong nuclear force that acts in the nuclear interior ( ) and a Coulomb‟s potential associated
with the repulsive electrostatic force that acts between the two particles after the decay has occurred ( ).
The line that intersect the potential energy curve at point and , is the measure of emitted during
one alpha decay. The energy of 4.27 MeV is emitted appearing as the kinetic energy of the alpha particle
and the recoiling residual nucleus
.
The decay of the alpha particle is accompanied by the emission of energy. Now the question arises
that why did not decay shortly after they were created?
The answer to this question is given is background of the
potential barrier consideration. We can visualize this barrier as a
spherical shell whose inner radius is and whose outer radius is
, its volume being forbidden to the particle under the law of
classical physics.
But according to the quantum mechanics, there is a chance
of tunneling through barrier. It is this tunneling due to which an
alpha particle gets a chance to come out of nucleus. But its
probability is extremely little, (1 out of ). It is one about in
years. That is why nucleus has such long half life.
If energy of alpha particle is comparatively high, the potential barrier will be appear to it thinner and
lower. Hence in this case, tunneling will occur more readily, and half life is reduced considerably. For
example, alpha particle emitted by has energy of 6.81 MeV.
Sample problem 6. Find the energy released during the alpha decay of . The needed atomic masses
are
Solution.
The reaction equation is :
(ii) particles
A particle is a positive or negative electrons which is emitted from the nucleus of a radioactive
element. When a proton in the nucleus transforms into a neutron, a positive particles is emitted.
When a neutron inside a nucleus changes into protons, then negative particles are emitted:
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
38 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Emission of negative particles leaves the mass number of the product nucleus unchanged, but the
atomic number (charge number) increases by one unit. So the product element moves on place ahead in the
periodic table.
Similarly, emission of positive particles leaves the mass number of the product nucleus unchanged
but the atomic number (charge number) decreases by one unit. So the product element moves one place
backward in the periodic table.
Explanation: Emission of electron or a positron from a nucleus is known as beta decay. Beta particles don't
exist in nucleus. They are emitted as soon as they are formed by disintegration of a neutron or a proton in a
nucleus. The examples of beta decay are as follows:
Here and
are electron and positron.
The kinetic energy of beta particle does not remain constant, but it changes over a range as shown in the
figure. The maximum value of kinetic energy of the beta particle is 0.653 MeV, which is also the total
disintegration energy for the case of beta decay from Cu. The kinetic energy of the beta particle changes over
the range because the disintegration energy is shared by
beta particle and neutrino.
Beta particle is not emitted alone. But with
every beta particle another particle is emitted, called
neutrino. Total energy of beta particle and neutrino is
quantized. But the disintegration energy is shared by
the beta particle and neutrino in any proportion, i.e.,
beta particle may take any energy between 0 and maximum. The rest of energy is carried by neutrino. Thus
the above mentioned equations of beta decay take the modified form as given below:
̅
Here and ̅ are neutrino and anti-neutrino respectively. Neutrino is emitted with positron ( ) and
anti-neutrino is emitted with electron ( ). The neutrino and anti-neutrino are very light particles having no
charge and mass nearly of the order of
of mass of electron. So they interact with matter weakly and are
very difficult to detect.
(iii) Rays
rays are not material particles but they are electromagnetic rays moving with the velocity of light.
These are the most energetic electromagnetic radiations having shortest wavelength and largest frequency.
ray can produce photoelectric effects, Compton effect and pair production. These radiations have largest
range. rays are emitted from the excited nuclei of radioactive elements.
Emission of rays does not change the mass number and atomic number of the product nucleus.
ray
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
39 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
54.5 Laws of Radioactivity and Half Lift of Radioactive Element
It is the time during which one half of the atoms of the parent element decay in to daughter element.
The half life of a radioactive element may vary from fraction of a second to millions of year.
The radioactive decay obeys the following two statistical laws:
The number of atoms that decay at any instant is proportional to the number of atoms present at that
instant.
No sample of radioactive element can ever completely decay in a finite time.
Let is the number of atoms initially present at time . Let N is the number of atoms at any time
t. If are the number of atoms decay during the interval of time , then the rate of decay
is directly
proportional to the number of atoms present. i.e.,
Where is the decay constant. It is the characteristics of radioactive element.
Initially at , there are radionuclide of parent element and N is the number of atoms at any time t.
Integrating above differential equation over appropriate limits, we have:
∫
∫
| | | |
(
)
---------------- (1)
This is known as radioactive decay law. It is clear from equation (1), that radioactivity follows an exponential
law and it takes an infinite time to decay a radioactive element completely.
When
, then
Putting values in equation (1), we have:
( )
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
40 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
(
)
This is the expression of half life of a radioactive element.
Question: Show that decay rate of radionuclide follows an exponential law.
Ans. The rate of decay (
) i.e., activity R can be find out by differentiating
the equation of law of radioactivity :
Where Decay rate at .
It is clear from equation that radioactive follows an exponential law and it takes an infinite time to
decay a radioactive element completely.
Problem 23. The half life of a radioactive isotope is 140 days. How many days would it take fit the
activity of the sample to fall to one forth of its initial decay rate?
Solution:
Law of radioactivity:
Problem 24. The half life of a particular radioactive isotope is 6.5 hr. if there are initially
of this isotope in a paricualr sample, how many atoms of this isotope remains after 26 hrs.
Solution:
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
41 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
As
Problem 25. A radioactive isotope of gold with a decay constant of . Calculate its: (a)
Half life (b) what fraction of the original will remain after three half lives? (c) After 10 days
Solution.
(a)
(b)
As
(c)
for
As
54.6 Mean Life of Radioactive Element
As the possible life of a radioactive element varies from 0 to , so the total life of all initially
present atoms in a given sample can be find out by the expression ∫
.
The mean or average life for a sample can be described by the expression:
∫
∫
∫
| |
Also,
as
Putting values in equation (1), we have:
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
42 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
∫ (
)
∫
∫
[|
|
∫
]
[
∫
] [
∫
]
∫
|
|
[ ]
[
]
[ ]
This is the expression of mean life of a radioactive element.
Question: Derive the relationship between Half Life and Mean Life of a radioactive element.
Ans. The half life and mean life of radioactive element is described by formulae
and
, respectively. Now,
This expression shows the mean life of a radioactive element is greater than its half life.
54.7 Units for Measuring Ionizing Radiation
Becquerel
SI unit of radioactivity is Becquerel. One Becquerel is one disintegration per second.
The Curie
The unit of activity or rate of decay of a radioactive source is Curie Ci. It is defined as the activity of
one gram of radium in equilibrium.
The Roentgen
It is the unit of exposure which may be defined as the exposure of beam of or to
produce , the air being dry and at standard temperature and pressure.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
43 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
The Rad
This is acronym for radiation absorbed dose and is a measure of the dose actually delivered to a
specified object. The specified part of a body (the hand, say) is said to have received and absorbed dose of 1
rad when have been delivered to it by ionizing radiation.
The rem
This is acronym for roentgen equivalent in man and is a measure of dose equivalent. The dose
equivalent (in rem) is found by multiplying the absorbed dose (in rad) by quality factor QF. According to the
recommendation of the National Council on Radiation Protection, no individual who is exposed to radiations
should receive a dose equivalent greater than 500 m rem (0.5 rem) in any one year.
54.8 Radioactive Dating
The age of a sample can be determined by radioactive dating. Suppose an initial radio nuclide I decays
to a final product F with a known half-life
At particular time , we start with initial nuclei with product (final) nuclei equal to zero. After
a time t, the initial nuclei at reduce to „ ‟ with the product (final) nuclei „ ‟, where .
To determine the age of radioactive sample we make use of exponential law of radioactivity:
where the decay constant
Taking logarithm on both sides, to the base e, we get:
(
)
(
)
(
)
(
)
Using formula of half life, we have :
(
)
Put
(
)
(
)
It is clear from expression that the age of radioactive sample can be determined by the ratio
. This
method can be used to determine the time since the formation of the solar system. Example include the ration
of to , to and to . The terrestrial rocks, moon rocks are analyzed by these
method, all seem to have common age of around year, which we take to be the age of our solar
system.
B. Sc. Physics (H.R.K) Chapter 54: Nuclear Physics (Edition 2015-16)
44 Muhammad Ali Malik, Whatsapp # +923016775811, [email protected] www.facebook.com/HomeOfPhysics
Sample Problem 9. In a sample of rock, the ratio of to nuclie is found to be 0.65. What is the
age of the rock? of is years.
Ratio =
(
)
54.9 Energy in Nuclear Reactions
A nuclear reaction can be represented by:
Here is the target nucleus, is the projectile nucleus, is the residual nucleus and is the emerging
nucleus. The projectile particle a may be charged particle which can be accelerated Van de Graph accelerator
or cyclone, or it may be a neutron from the nuclear reactor.
When the projectile particle penetrates a target nucleus, then a nuclear reaction takes place. The
reaction energy Q is defined as (rest mass energies)
------------- (1)
Here ,
,
If „ ‟ represents the kinetic energy, then the reaction energy „ ‟ is given by:
------------- (2)
Equation (1) and (2) are only valid, when Y and b are in their ground state.
Exothermic: If the reaction energy has positive value i.e., , then such nuclear reaction is known as
exothermic .
Endothermic: If the reaction energy Q is negative i.e., , then such a nuclear reaction is known as
endothermic. Such a reaction will not “go” unless a certain minimum kinetic energy (the threshold energy) is
carried into the system b the projectile. Its means that endothermic reaction needs some certain energy for its
performance.
Scattering: A nuclear reaction is called scattering, if the particles „a‟ and „b‟ are identical and so „X‟ and „Y‟
are also identical.
Elastic Scattering: If the kinetic energy of the system before the reaction is equal to the kinetic ener