1
9 Appendix The purpose of this Appendix is to determine the per-unit- length parameters for tertiary circuits in Fig. 2 with the return path on the shield of the disturbing line. Writing Kirchhoffs law in the loop between the / and /th coaxials: AV Ax i= 0 Ij(x*Ax) V,(x*Ax) x* Ax Fig. 2 The per-unit-length equivalent circuit of tertiary circuits for Fig. 1 Noting that Itto = ~th After some manipulation, and comparing with eqn. 8, the per-unit-length parameters are given by: [R.]g = R si + R si L si - 2M tj -M fi -M ki Utilising Kirchhoffs current law for the /th conductor and ignoring the conductive losses, L(x + Ax)-L{x) , A \ -& ^ } = -ja>C Jr Vj(x + Ax) - t JuC n {Vj(x + Ax) - V,(x + Ax)} i=i This equation may be arranged to yield [C]JJ = C M +tcjk [C\jk = -Cjk fe=l Book review Crystalline electric field and structural effects in /-electron systems J.E. Crow, R.P. Guertin and T.W. Mihalisin (Eds.) Plenum Press, 1980, 638pp., $69.50 ISBN: 0-306-40443 The lanthanide (rare earth) series of elements with incomplete 4/ electron shells has provided physicists with an exciting variety of phenomena for investigation since the metals began to be available in reasonably pure form as a result of the work of Spedding and his group at Ames in the 1960s. In the follow- ing decade purity was further improved, and, as a result, ele- ments, alloys and compounds are now available in highly pure single-crystal form. Many of their striking properties arise from the fact that magnetic ordering due to indirect exchange coupling is found at sufficiently low temperatures in most lan- thanide systems. Additionally the crystalline electric field can cause splitting of the ionic ground state and give rise to a range of other effects, some of which manifest themselves by the strong directional dependence of physical properties. In parallel with, although a little behind, the work on lanthanides has been a corresponding investigation of the actinide series in which the 5/shell is being progressively filled. The properties of both lanthanides and actinides were dealt with at a con- ference in Philadelphia, the proceedings of which are pre- sented in the work under review. The report contains 63 papers, 25 of which were invited, and is a valuable survey of the state of the subject at the end of 1979. There is a good balance between review and original material and between experimental results and theory. Post- presentation discussions, apparently verbatim, are also included. Four major invited papers set the background in the first section, and these discuss the influence of crystal fields in determining magnetic properties and causing structural effects including phase transitions and magnetostrictive strains. The effect of pressure in changing lattice spacing and inducing mag- netic order is examined and the role of crystal fields in amorph- ous materials is briefly discussed. The remaining eight sections cover these and other topics in more detail. They include much of fundamental importance. Those interested in magnetoelastic and structural phenomena, neutron diffraction and magnetic excitations, intermediate or mixed valence systems, transport properties, including Kondo effect, and the coexistence of magnetic ordering and supercon- ductivity will all find papers of relevance. There is less of direct interest for readers seeking information about useful materials and applications. Those who persist will find some work on intermetallic compounds between rare earths (R) and transition metals (T) particularly those on the Laves phase RT 2 compo- sition of interest for the production of transducers. In addition work is reported on the RT S intermetallics, some of which are potential permanent magnet materials, on hydrogen adsorption and on rare earth garnets. Nevertheless the solid-state phycisist will experience more excitement than the engineer. W.D. CORNER 166 IEE PROC, Vol. 129, Pt. A, No. 3, MA Y 1982

Book review: Crystalline Electric Field and Structural Effects in f-Electron Systems

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Page 1: Book review: Crystalline Electric Field and Structural Effects in f-Electron Systems

9 Appendix

The purpose of this Appendix is to determine the per-unit-length parameters for tertiary circuits in Fig. 2 with the returnpath on the shield of the disturbing line. Writing Kirchhoffslaw in the loop between the / and /th coaxials:

AV—Ax i=0

Ij(x*Ax)

V,(x*Ax)

x* Ax

Fig. 2 The per-unit-length equivalent circuit of tertiary circuits forFig. 1

Noting that

Itto = ~th

After some manipulation, and comparing with eqn. 8, theper-unit-length parameters are given by:

[R.]g = Rsi + Rsi Lsi - 2Mtj

-Mfi -Mki

Utilising Kirchhoffs current law for the /th conductor andignoring the conductive losses,

L(x + Ax)-L{x) , A \-& ^ }— = -ja>CJr Vj(x + Ax)

- t JuCn{Vj(x + Ax) - V,(x + Ax)}i=i

This equation may be arranged to yield

[C]JJ = CM+tcjk [C\jk = -Cjkfe=l

Book reviewCrystalline electric field and structural effects in /-electronsystemsJ.E. Crow, R.P. Guertin and T.W. Mihalisin (Eds.)Plenum Press, 1980, 638pp., $69.50ISBN: 0-306-40443

The lanthanide (rare earth) series of elements with incomplete4 / electron shells has provided physicists with an excitingvariety of phenomena for investigation since the metals beganto be available in reasonably pure form as a result of the workof Spedding and his group at Ames in the 1960s. In the follow-ing decade purity was further improved, and, as a result, ele-ments, alloys and compounds are now available in highly puresingle-crystal form. Many of their striking properties arise fromthe fact that magnetic ordering due to indirect exchangecoupling is found at sufficiently low temperatures in most lan-thanide systems. Additionally the crystalline electric field cancause splitting of the ionic ground state and give rise to a rangeof other effects, some of which manifest themselves by thestrong directional dependence of physical properties. In parallelwith, although a little behind, the work on lanthanides hasbeen a corresponding investigation of the actinide series inwhich the 5/shell is being progressively filled. The propertiesof both lanthanides and actinides were dealt with at a con-ference in Philadelphia, the proceedings of which are pre-sented in the work under review.

The report contains 63 papers, 25 of which were invited,

and is a valuable survey of the state of the subject at the endof 1979. There is a good balance between review and originalmaterial and between experimental results and theory. Post-presentation discussions, apparently verbatim, are also included.

Four major invited papers set the background in the firstsection, and these discuss the influence of crystal fields indetermining magnetic properties and causing structural effectsincluding phase transitions and magnetostrictive strains. Theeffect of pressure in changing lattice spacing and inducing mag-netic order is examined and the role of crystal fields in amorph-ous materials is briefly discussed.

The remaining eight sections cover these and other topics inmore detail. They include much of fundamental importance.Those interested in magnetoelastic and structural phenomena,neutron diffraction and magnetic excitations, intermediate ormixed valence systems, transport properties, including Kondoeffect, and the coexistence of magnetic ordering and supercon-ductivity will all find papers of relevance. There is less of directinterest for readers seeking information about useful materialsand applications. Those who persist will find some work onintermetallic compounds between rare earths (R) and transitionmetals (T) particularly those on the Laves phase RT2 compo-sition of interest for the production of transducers. In additionwork is reported on the RTS intermetallics, some of which arepotential permanent magnet materials, on hydrogen adsorptionand on rare earth garnets. Nevertheless the solid-state phycisistwill experience more excitement than the engineer.

W.D. CORNER

166 IEE PROC, Vol. 129, Pt. A, No. 3, MA Y 1982