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BLACKDIAMOND

BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

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Page 1: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

BLACKDIAMOND

Page 2: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®
Page 3: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

1

Citadel Technologies ..........................2

DiamondWrap® .......................................4

DiamondWrap® Specialty Epoxies ........8

BlackDiamond® ...................................16

DiamondWrap® HP™ ............................20

DiamondWrap® SubSea™ ....................22

DiamaForce™ .......................................24

RhinoWrap® .........................................26

SLS-Series™ .......................................28

DiamaPro™ ..........................................34

DiamaCorr™ ........................................36

DiamaShield™ .....................................38

DiamaShoe™ ........................................40

Test Information ................................42

Appendix..............................................46

Engineering Assessment ...................49

Papers and Presentations ................52

© 1998, 2017 CTI Services LLC

Date of approval: May 5, 2017 V. 1

Page 4: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

CITADEL TECHNOLOGIES has been headquartered in Tulsa, OK, USA since 1994 and is the developer and manufacturer of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®, DIAMONDWRAP® HP™, DIAMONDWRAP® SUBSEA™, DIAMAFORCE™, RHINOWRAP®, and the SLS-SERIES™ of primers and coatings. They are the most extensively tested products on the market, and have been installed in over 50 countries.

As the best alternative to clamps and replacement, our products of carbon fiber and 100% solid epoxies are used to rehabilitate and restore original strength to damaged, corroded and eroded pipelines and pipe systems. DIAMONDWRAP® can also facilitate the repair of leaks, making these systems premier in the market of non-metallic repairs.

Our SLS-SERIES™ of coating system provides protection of surfaces for corrosion, erosion and harsh environments.

Citadel Technologies has developed fiberglass systems DIAMAPRO™, DIAMACORR™, DIAMASHIELD™ and DIAMASHOE™ to complement its carbon systems and provide corrosion and abrasion protection to new pipelines and pipe supports.

Citadel Technologies products are compliant with all major composite repair standards, including ASME PCC-2 and ISO-TS 24817. Our commitment to excellence assures that all systems are continually tested and reviewed using both in-house research, and independent labs, to insure that we maintain our leadership in the industry.

Citadel Technologies continually reviews and improves the effectiveness of its quality management system, and its efforts to meet its quality objectives, for the purpose of maintaining customer satisfaction. Citadel Technologies is certified by British Standard Institute (BSI) to the ISO 9001:2008.

If you are interested in additional information, please contact our authorized distributor in your area or our office in Tulsa, Oklahoma.

Regards,

Roger H. Walker, PEPresident

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Leaking or Corroded Piping System

s

www.cittech.com www.cittech.com2

Page 5: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Citadel Technologies ́products save time, labor and equipment costs. In most cases there is no plant downtime. Pipes can be wrapped while the line is in service, requiring no line evacuation, no welding of pipe, no need to cut the pipe, no heavy equipment handling requirements and no volatile compounds (VOCs).

• ASME PCC-2-2015 Post Construction Code Repair using Non-metallic Materials• ASME B31.4 Paragraph 451.6.2• ASME B31.8 Paragraph 851.42• ISO-TS 24817 – Composite repairs for pipe work – Qualification and design, installation, testing and inspection• NRF-030-PEMEX-2006 paragraph 8.4.2.4.6• NRF-0187-PEMEX-2007 paragraph 8.6.2.5• API 570 • CSA 2662-15 • DOT *

*Note: These standards do not endorse products, but sets forth regulations for non-metallic repairs in CFR Parts 192 and 195

Citadel Technologies engineering team can provide you the following:

• Technical Sessions to provide answers to your questions regarding composites.• Installation Training.• Inspector Training.• Impressive summary of the extensive testing performed.• Regularly scheduled training and certifications classes.

A Pipe Around a Pipe.

Oil and Gas Pipelines

Chemical Plants

Water/Wastewater Facilities

Refineries

Nuclear and Power Plants

Mining

Pulp and Paper Mills

Offshore/Marine Terminals

www.cittech.com www.cittech.com 3

Page 6: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

DIAMONDWRAP® is the premier carbon fiber wrap system used to rehabilitate and restore original operational strength to damaged, corroded and eroded piping systems. DIAMONDWRAP® is engineered to provide strength that enables a pipe to be restored to maximum allowable operating pressure (MAOP) without shutting down. The system is comprised of three components, each thoroughly and independently tested at both the university and international laboratory level. The first component is an epoxy primer, which ensures complete bonding and load transfer between the repair and the substrate. The second component and most unique feature of the DIAMONDWRAP® system, is its selection of bi-directional woven carbon-fiber materials, which provides reinforcement in the hoop and axial directions and is the strongest available non-metallic repair on the market. The third part of the binding force in the system is the polymeric epoxy resin, which allows for uniform loading throughout the entire wrap. For repairs that require surfaces to be modified (e.g.: heavy pitting or irregular shapes), the high modulus filler can be applied. These components form a composite system that is stronger than steel. The structural system forms a pipe around a pipe, and each successive wrap increases the pressure rating. Minimal creep ensures a long service life.

DIAMONDWRAP® requires an engineering assessment to compile service information such as substrate material, wall loss, operating temperature, pressure ranges and environment exposure. Citadel Technologies ́DIAMONDWRAP® Wizard© software analyzes this information to determine the number of wraps required for each pipe repair.

Because of its wet lay-up and low profile, DIAMONDWRAP® can be installed on tees, elbows and straight runs of pipe. It also works well in confined spaces and on irregular surfaces that require structural reinforcement or leak containment.

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Leaking or Corroded Piping System

s

www.cittech.com www.cittech.com4

Page 7: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

A Pipe Around a Pipe.

• Superior alternative to clamps.• Fits all pipe sizes.• Designed for use on straight length, elbows, tees, valves, fittings, vessels.• Compatible with carbon steel, stainless steel, alloys, PVC, fiberglass and more.• Accomodates high pressure with low profile.• Utilizes carbon fabric wrap (PAN-Polyacrylnitrile).• Highly corrosion resistant.• Long service life.• No VOCs.• Chemical resistant.• No hot works / No welding required.• Engineered solution.• Supplied as a complete kit.• Able to withstand high temperatures.• High strength.• Fast curing. • Extensively tested in labs and in the field.

Make it safely to the next turnaround or longer without an emergency plant shut down!

www.cittech.com www.cittech.com 5

Page 8: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

A Pipe Around a Pipe.

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Leaking or Corroded Piping System

s

Total Layers Normal Range (Typical) 2 to 6 (One Layer = One Ply) 2 to 6 (One Layer = One Ply)Cure Time Typically 5 Hours @ 25°C Typically 5 Hours @ 77°FMaximum Recommended Operating Temperature 82°C Standard 180°F StandardChemical Resistance Excellent ExcellentNominal Thickness 0.91 mm for 2 Ply BA Fabric to 0.036 in for 2 Ply BA Fabric to 2.74 mm for 6 Ply BA Fabric 0.108 in for 6 Ply BA FabricFabric PAN (Polyacrylnitrile) PAN (Polyacrylnitrile)Carbon Content by Volume 35% to 50% 35% to50%Glass Fiber Content by Volume 0% 0%Lap Sheer (Adhesive) Strength > 8,618 kPa @ 60°C > 1,250 PSI @ 140°FCompressive Strength of Putty 33,129 kPa @ 60°C 8,805 PSI @ 140°FHardness 78 to 84 (Shore D) 78 to 84 (Shore D)Linear Elastic Behavior 1.20% Strain to Failure 1.20% Strain to FailureElastic Modulus, Hoop Direction 3.47 x 107 kPa for BA 5.03 x 106 PSI for BAElastic Modulus, Axial Direction 3.16 x 107 kPa 4.59 x 106 PSITensile Strength, Hoop Direction 4.44 x 105 kPa 6.44 x 104 PSITensile Strength, Axial Direction 2.72 x 105 kPa 3.94 x 104 PSICoefficient of Thermal Expansion, Hoop Direction 2.52 x 10-5/ °C 1.4 x 10-5/ °FCoefficient of Thermal Expansion, Axial Direction 1.278 x 10-5/ °C 0.71 x 10-5/ °FDesign Stress, Hoop Direction 3.42 x 105 kPa 4.96 x 104 PSIDesign Stress, Axial Direction 2.09 x 105 kPa 3.03 x 104 PSIFatigue (cycle without failure - defect dependent) >100,000 cycles (0 -100% MAOP) >100,000 cycles (0 -100% MAOP) with up to 80% wall loss with up to 80% wall loss

www.cittech.com www.cittech.com6

Page 9: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

A Pipe Around a Pipe.

www.cittech.com www.cittech.com 7

Page 10: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

www.cittech.com www.cittech.com

Citadel Technologies is the industry leader in manufacturing specialty epoxies for use in specialized composite

wrap and coating applications. Citadel Technologies’ epoxies go unmatched in range, quality, and performance.

These specialty epoxies include three different High Temperature systems, and an Acid system designed for use

with harsh chemicals. Go where no other non-metallic composite wraps can go with these kits available from

Citadel Technologies!

DiamondWrap® High Temperature Ambient™ (HTA ™) Epoxy System

DiamondWrap® High Temperature 701™ (HT701 ™) Epoxy System

DiamondWrap® Ultra High Temperature™ (UHT ™) Epoxy System

DiamondWrap® Acid Epoxy System

ddd

8

Page 11: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

www.cittech.com www.cittech.com

ddd

High Teperature Environments

The DiamondWrap® High Temperature kits have been designed to be applied to pipes that operate above 82° C (180° F). Three different high temperature kits are available depending upon the conditions of the pipe and the application: High Temperature Ambient™ (HTA™), High Temperature 701™ (HT701™), Ultra High Temperature™ (UHT™).

This kit is designed to be used on pipes that operate at temperatures between 30° C and 149° C (86° F and 300° F). The DiamondWrap® High Temperature Ambient™ kit is formulated to set at temperatures of 30° C (86° F). Its slow set time is great for wrapping pipes while in service at elevated temperatures. It is also designed for pipes that operate at elevated temperatures, but will be wrapped while the line is out of service.

Glass Transition Temperature 171° C 340° FMaximum Recommended Operating Temperature 149° C 300° FRecommended Application Temperature Range* 25° C – 149° C 77° F – 300° FTensile Strength, Hoop Direction 576,719kPa 83,646 PSITensile Strength, Axial Direction 247,729 kPa 35,930 PSIElastic Modulus, Hoop Direction 49.1 x 106 kPa 7.13 x 106 PSIElastic Modulus, Axial Direction 23.8 x 106 kPa 3.46 x 106 PSINominal Thickness 1.016 mm (2 Ply) - 3.43 mm (6 Ply) 0.04 in (2 Ply) - 0.135in (6 Ply)Carbon Fiber % 35 - 50% 35 - 50%Glass Fiber % 0% 0%Resin Type 2 Part, 100% Solid Epoxy 2 Part, 100% Solid EpoxyLap Shear > 8,273.71 kPa >1,200 PSIHardness @ Full Cure 80 Shore-D 80 Shore-DPrimer Color Code Gray Gray

9

*Can only be installed at lower temperatures with special provisions. Minimum temperatures must be reached for these products to set and to cure. Contact Citadel Technologies for more information about special provisions, installation, cure times, and cure schedules.

High Temperature Ambient™ (HTA™)

Epoxy System

Page 12: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Leaking or Corroded Piping System

s

www.cittech.com www.cittech.com

The DiamondWrap® High Temperature kits have been designed to be applied to pipes that operate above 82° C (180° F). Three different high temperature kits are available depending upon the conditions of the pipe and the application:

High Temperature Ambient™ (HTA™), High Temperature 701™ (HT701™), Ultra High Temperature™ (UHT™).

The DiamondWrap® High Temperature 701™ kit has been designed to be applied on pipes that operate at temperatures up to 171º C (340º F). This kit has been formulated to cure at elevated temperatures, which allows it to be applied to pipes at elevated temperatures without the threat of reduced workability. To properly cure, these kits must be heated to at least 66º C (150º F) after installation, unless the pipe is operating above this temperature when the product is applied.

Glass Transition Temperature 196° C 385° FMaximum Recommended Operating Temperature 171° C 340° FRecommended Application Temperature Range* 25° C – 171° C 77° F – 340° FTensile Strength, Hoop Direction 576,719kPa 83,646 PSITensile Strength, Axial Direction 247,729 kPa 35,930 PSIElastic Modulus, Hoop Direction 49.1 x 106 kPa 7.13 x 106 PSIElastic Modulus, Axial Direction 23.8 x 106 kPa 3.46 x 106 PSINominal Thickness 1.016 mm (2 Ply) - 3,43 mm (6 Ply) 0.04 in (2 Ply) - 0.135in (6 Ply)Carbon Fiber % 35 - 50% 35 - 50%Glass Fiber % 0% 0%Resin Type 2 Part, 100% Solid Epoxy 2 Part, 100% Solid EpoxyLap Shear > 8,273.71 kPa >1,200 PSIHardness @ Full Cure 80 Shore-D 80 Shore-DPrimer Color Code Orange/Chocolate Orange/Chocolate

10

High Temperature 701™ (HT701™)

DiamondWrap High Temperature 701™ (HT701™) Epoxy System®

*Can only be installed at lower temperatures with special provisions. Minimum temperatures must be reached for these products to set and to cure. Contact Citadel Technologies for more information about special provisions, installation, cure times, and cure schedules.

Page 13: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

www.cittech.com www.cittech.com

The DiamondWrap® High Temperature kits have been designed to be applied to pipes that operate above 82°C (180°F). Three different high temperature kits are available depending upon the conditions of the pipe and the application: High Temperature Ambient™ (HTA™), High Temperature 701™ (HT701™), Ultra High Temperature™ (UHT™).

This system is pre-impregnated carbon fabric using Citadel Technologies’ DiamondWrap® Ultra-High Temperature™ epoxy system. This epoxy has been formulated to be applied to pipes operating at temperatures up to 288º C (550º F). Curing of this epoxy requires a minimum temperature of 149° C (300º F) either from the piping system itself, or with the addition of an external heat source.

Glass Transition Temperature 304° C 580° FMaximum Recommended Operating Temperature 288° C 550° FRecommended Application Temperature Range* 149° C – 232° C 300° F – 450° FTensile Strength, Hoop Direction 576,719 kPa 83,646 PSITensile Strength, Axial Direction 247,729 kPa 35,930 PSIElastic Modulus, Hoop Direction 49.1 x 106 kPa 7.13 x 106 PSIElastic Modulus, Axial Direction 23.8 x 106 kPa 3.46 x 106 PSINominal Thickness 1.016 mm (2 Ply) - 3.43 mm (6 Ply) 0.04 in (2 Ply) - 0.135in (6 Ply)Carbon Fiber % 35 - 50% 35 - 50%Glass Fiber % 0% 0%Resin Type 2 Part, 100% Solid Epoxy 2 Part, 100% Solid EpoxyLap Shear > 8,273.71 kPa >1,200 PSIHardness @ Full Cure 80 Shore-D 80 Shore-DPrimer Color Code Nearly Clear Nearly Clear

11

Ultra High Temperature™ (UHT™)High Temperature 701™ (HT701™)

DiamondWrap High Temperature 701™ (HT701™) Epoxy System

*Can only be installed at lower temperatures with special provisions. Minimum tempera-tures must be reached for these products to set and to cure. Contact Citadel Technolo-gies for more information about special provisions, installation, cure times, and cure schedules.

DiamondWrap Ultra High Temperature™ (UHT™) Epoxy System

Page 14: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Leaking or Corroded Piping System

s

www.cittech.com www.cittech.com

Glass Transition Temperature 121° C 250° FMaximum Recommended Operating Temperature 83° C 180° FRecommended Application Temperature Range 27° C – 60° C 80° F – 140° FTensile Strength, Hoop Direction 576,719 kPa 83,646 PSITensile Strength, Axial Direction 247,729 kPa 35,930 PSIElastic Modulus, Hoop Direction 49.1 x 106 kPa 7.13 x 106 PSIElastic Modulus, Axial Direction 23.8 x 106 kPa 3.46 x 106 PSINominal Thickness 1.016 mm (2 Ply) - 3,43 mm (6 Ply) 0.04 in (2 Ply) - 0.135in (6 Ply)Carbon Fiber % 35 - 50% 35 - 50%Glass Fiber % 0% 0%Resin Type 2 Part, 100% Solid Epoxy 2 Part, 100% Solid EpoxyLap Shear > 8,273.71 kPa >1,200 PSIHardness @ Full Cure 80 Shore-D 80 Shore-DPrimer Color Code Green Green

The DiamondWrap® Acid kit has been designed to be applied in areas, and on pipes, that contain harsh chemicals that will cause problems or deterioration in other epoxies. For a partial list of chemicals that are compatible with the Diamond Wrap® systems, please reference our Chemical Resistance Chart. If a specific chemical that you work with is not on this list, please contact Citadel Technologies for additional information and we will determine how the chemical will affect our system.

12

Page 15: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

www.cittech.com www.cittech.com

DiamondWrap® HTA™

DiamondWrap® Acid

after

before

13

Page 16: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

BLACKDIAMOND® is the premier carbon fiber wrap system used to rehabilitate and restore original operational strength to damaged, corroded and eroded pipelines. BLACKDIAMOND® is engineered to provide strength that enables a pipeline to be restored to maximum allowable operating pressure (MAOP) without shutting down. The system is comprised of three components, each thoroughly and independently tested at both the university and national laboratory level. The first component is an epoxy primer, which ensures complete bonding and load transfer between the repair and the substrate. The second component and most unique feature of the BLACKDIAMOND® system, is its bi-directional woven carbon-fiber material, which provides reinforcement in the hoop and axial directions and is the strongest available non-metallic repair on the market. The third component of the binding force in the system is the polymeric epoxy resin, which allows for uniform loading throughout the entire wrap. For repairs that require surfaces to be modified (e.g: heavy pitting), the high modulus filler can be applied. These components form a composite system that is stronger than steel. The structural system forms a pipe around a pipe, and each successive wrap increases the pressure rating. Minimal creep ensures a long service life.

BLACKDIAMOND® requires an engineering assessment to compile information such as substrate material, wall loss, operating temperature and pressure ranges. Citadel Technologies’ BLACKDIAMOND® Wizard© software analyzes this information to determine the number of wraps required for each pipeline repair.

Because of its wet lay-up and low profile, BLACKDIAMOND® can be installed on tees, elbows, straight runs of pipe. It also works will in confined spaces and on irregular surfaces that require structural reinforcement. The adhesive properties of the epoxy allow it to be applied to most substrates.

BLACKDIAMOND

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Corroded Piping System

s

www.cittech.com www.cittech.com14

Page 17: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

NOTE: BLACKDIAMOND® SYSTEM IS DESIGNED FOR INSTALLATION ON TRANSMISSON PIPELINES. BLACKDIAMOND® SYSTEM IS NOT INTENDED FOR USE ON A PIPELINE LEAK REPAIR.

LEAK REPAIR SHOULD BE CONDUCTED USING THE DIAMONDWRAP® LINE OF PRODUCTS.

• Superior alternative to clamps.• Fits all pipe sizes.• Designed for use on straight pipes, elbows, tees.• Compatible with carbon steel, stainless steel, alloys, PVC, fiberglass and more.• Accomidates high pressure with low profile.• Utilizes carbon faber wrap (PAN-Polyacrylnitrile).• Highly corrosion resistance.• Long service life.• No VOCs.• BLACKDIAMOND® 100% solids epoxy systems for chemical resistance.• No hot works / No welding required.• Engineered solution.• Supplied as a complete kit.• Able to withstand high temperatures.• High strength.• Fast curing. • Extensively tested in labs and in the field.

Composite WrapA Pipe Around a Pipe.

www.cittech.com www.cittech.com 15

Page 18: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

BLACKDIAMOND

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Corroded Piping System

s

Total Layers Normal Range (Typical) 2 to 6 (One Layer = One Ply) 2 to 6 (One Layer = One Ply)Cure Time Typically 5 Hours @ 25°C Typically 5 Hours @ 77°FMaximum Recommended Operating Temperature 82°C Standard 180°F StandardChemical Resistance Excellent ExcellentNominal Thickness 0.98 mm for 2 Ply to 0.039 in for 2 Ply to 2.93 mm for 6 Ply 0.116 in for 6 PlyFabric PAN (Polyacrylnitrile) PAN (Polyacrylnitrile)Carbon Content by Volume 35% to 50% 35% to 50%Glass Fiber Content by Weight 0% 0%Lap Sheer (Adhesive) Strength > 8,618 kPa @ 60°C > 1,250 PSI @ 140°FCompressive Strength of Putty 33,129 kPa @ 60°C 8,805 PSI @ 140°FHardness 78 to 84 (Shore D) 78 to 84 (Shore D)Linear Elastic Behavior 1.20% Strain to Failure 1.20% Strain to FailureElastic Modulus, Hoop Direction 6.70 x 107 kPa 9.72 x 106 PSIElastic Modulus, Axial Direction 1.47 x 107 kPa 2.13 x 106 PSITensile Strength, Hoop Direction 7.55 x 105 kPa 1.09 x 105 PSITensile Strength, Axial Direction 1.88 x 105 kPa 2.73 x 105 PSICoefficient of Thermal Expansion, Hoop Direction 2.52 x 10-5/ °C 1.4 x 10-5/ °FCoefficient of Thermal Expansion, Axial Direction 1.278 x 10-5/ °C 0.71 x 10-5/ °FDesign Stress, Hoop Direction 5.81 x 105 kPa 8.43 x 104 PSIDesign Stress, Axial Direction 1.44 x 105 kPa 2.10 x 104 PSIFatigue (cycle without failure - defect dependent) >100,000 cycles (0 -100% MAOP) >100,000 cycles (0 -100% MAOP) with up to 80% wall loss with up to 80% wall loss

www.cittech.com www.cittech.com16

Page 19: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Composite WrapA Pipe Around a Pipe.

www.cittech.com www.cittech.com 17

Page 20: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Corroded Piping System

s

DIAMONDWRAP® HP™ is the leading carbon fiber wrap system used to rehabilitate and restore original operational strength to dented, gouged, corroded and eroded pipelines. DIAMONDWRAP® HP™ is engineered to provide strength that enables a pipeline to be restored to maximum allowable operating pressure (MAOP) without shutting down. The system is comprised of three components, each thoroughly and independently tested at both the university and national laboratory levels. The first component is a solid epoxy primer, which ensures complete bonding and load transfer between the repair and the substrate. The second component and most unique feature of the DIAMONDWRAP® HP™ system, is its bi-directionally woven carbon-fiber material, which provides reinforcement in the hoop and axial directions, and is the strongest available non- metallic repair on the market. The third component of the binding force in the system is the polymeric epoxy resin, which allows for uniform loading throughout the entire wrap. For repairs that require surfaces to be modified (e.g: heavy pitting or irregular shapes), the high modulus filler can be applied. These components form a composite system that is stronger than steel. The structural system forms a pipe around a pipe, and each successive wrap increases the pressure rating. Minimal creep ensures a longer service life.

DIAMONDWRAP® HP™ requires an engineering assessment to compile information such as substrate material, wall loss, operating temperature and pressure ranges. Citadel Technologies’ DIAMONDWRAP® HP™Wizard© software analyzes this information to determine the number of wraps required for each pipeline repair.

Because of its wet lay-up and low profile, DIAMONDWRAP® HP™ can be installed on tees, elbows, straight runs of pipe, confined spaces and irregular surfaces that require structural reinforcement. The adhesive properties of the epoxy allow it to be applied to most substrates.

www.cittech.com www.cittech.com18

Page 21: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

• Superior alternative to clamps.• Fits all pipe sizes.• Designed for use on straight length, elbows, tees.• Compatible with carbon steel, stainless steel, alloys, PVC, fiberglass and more.• Accommodates High pressure – Low profile.• Utilizes carbon fabric wrap (PAN-Polyacrylnitrile).• Highly corrosion resistant.• Long service life.• No VOCs.• DIAMONDWRAP® HP™ 100% solids epoxy systems for chemical resistance.• No hot works / No welding required.• Engineered solution.• Supplied as a complete kit.• Able to withstand high temperatures.• High strength.• Fast curing.• Extensively tested in lab and the field.

Composite Wrap

NOTE: DIAMONDWRAP® HP™ SYSTEM IS DESIGNED FOR INSTALLATION ON TRANSMISSON PIPELINES. DIAMONDWRAP® HP™ SYSTEM IS NOT INTENDED FOR USE ON A PIPELINE LEAK REPAIR. LEAK REPAIR SHOULD BE CONDUCTED USING THE DIAMONDWRAP® LINE OF PRODUCTS.

A Pipe Around a Pipe.

www.cittech.com www.cittech.com 19

Page 22: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

Structural Carbon/Epoxy Rehab System for the Prevention and Repair of Corroded Piping System

s

Total Layers Normal Range (Typical) 2 to 7 (One Layer = One Ply) 2 to 7 (One Layer = One Ply)Cure Time Typically 5 Hours @ 25°C Typically 5 Hours @ 77°FMaximum Recommended Operating Temperature 82°C Standard 180°F StandardChemical Resistance Excellent ExcellentNominal Thickness 1.14 mm or 2 Ply to 0.045 in for 2 Ply to 4.00 mm for 7 Ply 0.158 in for 7 PlyFabric PAN (Polyacrilnitrile) PAN (Polyacrilnitrile)Carbon Content by volume 35% to 50% 35% to 50%Glass Fiber Content by Weight 0% 0%Lap Sheer (Adhesive) Strength > 8,618 kPa @ 60°C > 1,250 PSI @ 140°FCompressive Strength of Putty 33,129 kPa @ 60°C 8,805 PSI @ 140°FHardness 78 to 84 (Shore D) 78 to 84 (Shore D)Linear Elastic Behavior 1.20% Strain to Failure 1.20% Strain to FailureElastic Modulus, Hoop Direction 4.92 x 107 kPa 7.13 x 106 PSIElastic Modulus, Axial Direction 2.39 x 107 kPa 3.46 x 106 PSITensile Strength, Hoop Direction 5.77 x 105 kPa 8.36 x 104 PSITensile Strength, Axial Direction 2.48 x 105 kPa 3.59 x 104 PSICoefficient of Thermal Expansion, Hoop Direction 2.52 x 10-5/ °C 1.4 x 10-5/ °FCoefficient of Thermal Expansion, Axial Direction 1.278 x 10-5/ °C 0.71 x 10-5/ °FDesign Stress, Hoop Direction 4.44 x 105 kPa 6.44 x 104 PSIDesign Stress, Axial Direction 1.90 x 105 kPa 2.76 x 104 PSIFatigue (Cycles to failure - defect dependent) >100,000 cycles (0 -100% MAOP) >100,000 cycles (0 -100% MAOP) with up to 80% wall loss with up to 80% wall loss

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Composite WrapA Pipe Around a Pipe.

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www.cittech.com www.cittech.com

DESCRIPTION

DIAMONDWRAP® SUBSEA™ is the premier carbon fiber wrap system used to rehabilitate and restore original operational strength to damaged, corroded and eroded underwater piping systems. DIAMONDWRAP® SUBSEA™ is engineered to provide strength that enables a submerged pipe to be restored to maximum allowable operating pressure (MAOP) without shutting down. The system is comprised of three components, each thoroughly and independently tested at both the university and international laboratory level. The first component is an epoxy primer, which ensures complete bonding and load transfer between the repair and the substrate. The second component and most unique feature of the DIAMONDWRAP® SUBSEA™ system, is its selection of bi-directional woven carbon-fiber materials, which provides reinforcement in the hoop and axial directions and is the strongest available non-metallic repair on the market. The third component of the binding force in the system is the polymeric epoxy resin, which allows for uniform loading throughout the entire wrap. For repairs that require surfaces to be modified (e.g.: heavy pitting or irregular shapes), the high modulus filler can be applied. These components form a composite system that is stronger than steel. The structural system forms a pipe around a pipe, and each successive wrap increases the pressure rating. Minimal creep ensures a long service life.

DIAMONDWRAP® SUBSEA™ requires an engineering assessment to compile service information such as substrate material, wall loss, operating temperature, pressure ranges and environment exposure. Because of its wet lay-up and low profile, DIAMONDWRAP® SUBSEA™ can be installed on tees, elbows, straight runs of pipe, confined spaces and irregular surfaces that require structural reinforcement or leak containment. The adhesive properties of the epoxy allow it to be applied to most substrates. The epoxy must be mixed and applied above water before it is transported underwater to the site of the repair.

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www.cittech.com www.cittech.com

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SubSea™ Epoxy System

FEATURES AND CHARACTERISTICS

• Suitable for subsea pipelines, risers, and piping systems• Excellent adhesion to virtually any substrate• Straight length, elbows, tees, valves, fittings, vessels• Restores pipe strength to MAOP• Minimal creep ensures a long service life

DIAMONDWRAP® SUBSEA™ is compliant to DOT regulation, ASME B31, .8, .4, .G and PCC-2 Art 4.1, 4.2 and API 570. Please refer to API 570, Section 8.1.4 – Non-welding Repairs (On-Stream)

• No VOCs • Prevents future external corrosion• Strong chemical resistance• Supplied as a complete kit• Quick and easy installation

Total Layers Normal Range (Typical) 2 to 6 (One Layer = One Ply) 2 to 6 (One Layer = One Ply)Cure Time Minimum 24 Hours @ 25°C Minimum 24 Hours @ 77°FMaximum Recommended Operating Temperature 82°C 180°FChemical Resistance Excellent ExcellentNominal Thickness 0.91 mm for 2 Ply BA Fabric to 0.036 in for 2 Ply BA Fabric to 2.74 mm for 6 Ply BA Fabric 0.108 in for 6 Ply BA FabricFabric PAN (Polyacrylnitrile) PAN (Polyacrylnitrile)Carbon Content by Volume 35% to 50% 35% to 50%Glass Fiber Content by Volume 0% 0%Lap Sheer (Adhesive) Strength > 8,618 kPa @ 60°C > 1,250 PSI @ 140°FCompressive Strength of Putty 33,129 kPa @ 60°C 8,805 PSI @ 140°FHardness 78 to 84 (Shore D) 78 to 84 (Shore D)Linear Elastic Behavior 1.20% Strain to Failure 1.20% Strain to FailureElastic Modulus, Hoop Direction 3.47 x 107 kPa for BA 5.03 x 106 PSI for BAElastic Modulus, Axial Direction 3.16 x 107 kPa 4.59 x 106 PSITensile Strength, Hoop Direction 4.44 x 105 kPa 6.44 x 104 PSITensile Strength, Axial Direction 2.72 x 105 kPa 3.94 x 104 PSICoefficient of Thermal Expansion, Hoop Direction 2.52 x 10-5/ °C 1.4 x 10-5/ °FCoefficient of Thermal Expansion, Axial Direction 1.278 x 10-5/ °C 0.71 x 10-5/ °FDesign Stress, Hoop Direction 3.42 x 105 kPa 4.96 x 104 PSIDesign Stress, Axial Direction 2.09 x 105 kPa 3.03 x 104 PSI

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www.cittech.com www.cittech.com

DESCRIPTION

DIAMAFORCE™ is the premier carbon fiber reinforced polymer (CFRP) laminate designed for strengthening concrete, steel and masonry structures. DIAMAFORCE™ bonds to compromised structures as external reinforcement using Citadel Technologies’ high quality blend of two part epoxies.

DIAMAFORCE™ integrates proprietary products with specialty engineering services to improve, protect, and enhance infrastructure. DIAMAFORCE™ repairs deterioration or damage and enhances structures in order to extend life or comply with change of use requirements. For new construction, DIAMAFORCE™ improves the performance, protects and extends the life of structures, as well as corrects construction defects.

DIAMAFORCE™ can be used to increase the strength of existing beams, slabs, walls, columns and connections. Building strengthening applications typically include seismic retrofit; strengthening due to corrosion, change of use, or in some cases, the correction of an existing defect due to a construction or design error.

DIAMAFORCE™ is ideal for industrial structure strengthening because of its high strength-to-weight ratio and ease of installation. DIAMAFORCE™ can be installed with minimal impact to the operations of the structure and is easily installed around existing equipment and instrumentation. DIAMAFORCE™ can be used to encapsulate, seal and protect other repairs.

There are many drivers for increasing or restoring the structural capacity of structures, including code changes, changes in use (which increase service loads), deficiencies within the structure caused by errors in design or construction, or loss of capacity due to deterioration. Regardless of the need, DIAMAFORCE™ and Citadel Technologies can assist in the development and implementation of value-added structural upgrade and strengthening solutions.

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Engineered Rehabilitation for Deteriorating Structures

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Cure Time (typical at 25° C) (hr) 4.5 Approx. 4.5 Approx. 4.5 Approx.Maximum Operating Temperature (°F) 82° C (180° F) 82° C (180° F) 82° C (180° F)Fabric Orientation +/- 45° 0°/90° 0°Nominal thickness (in) .045 (1ply) (1.1 mm) .023 (1ply) (0.58 mm) .040 (1ply) (1 mm)Lap Shear strength to concrete Concrete failure Concrete failure Concrete failureHardness Shore D 78 to 84 78 to 84 78 to 84Linear elastic behavior 9.38% strain 1.27% strain 1.89% strainElastic Modulus Hoop direction (ksi) 709** (48,883 bar) 7130 (491,596 bar) 9900Elastic Modulus Axial direction (ksi) 709*** (48,883 bar) 3,460 (238,558 bar) 0Tensile Strength (ksi) Hoop 9.1** (627 bar) 83.6 (5,764 bar) 132.3 (9,121 bar)Tensile Strength (ksi) Axial 9.1*** (627 bar) 35.9 (2,475 bar) 0

Property Bi-Axial (+/-45º)

Bi-Directional (0/90º)

Uni-Directional

*Depends on specifications **Strength in the +45° direction ***Strength in the -45° direction

Structural Reinforcement

TYPICAL APPLICATIONS

• Structural external reinforcement• Flexural and shear reinforcement• Bridge and column repair• Seismic retrofitting• Concrete pipe supports• Piers, pilings, platforms and towers• Concrete and/or steel columns, beams and slabs• Preventative maintenance• Seal and protect existing repairs• Design/construction deficiencies • Load increases• Repair damaged structures

BENEFITS

• No VOCs• Applicable in damp and wet environments• Very high strength, light weight and low profile• Long shelf life when stored properly• Repair spalls to original geometries • Long term solution• Repair without taking structure out of service• Corrosion resistant• Quick installation with no heavy equipment necessary• Good high and low temperature properties• Ambient cure• Designed according to ACI 440

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RHINOWRAP® is a hybrid carbon fiber and fiberglass composite wrap system used to rehabilitate and restore strength to low pressure, low risk corroded and eroded piping systems. RHINOWRAP® is engineered to provide strength that enables a pipe to be restored to normal operating pressure without shutting down.

The system is comprised of two components, each thoroughly and independently tested at both the university and national laboratory levels. The first component and most unique feature of the RHINOWRAP® system, is its hybrid bi-directionally woven carbon/fiberglass material, which provides reinforcement in the hoop and axial directions and is the strongest low risk non-metallic repair on the market. The second component of the binding force in the system is the polymeric epoxy resin, which allows for uniform loading throughout the entire wrap.

As a flexible wet lay-up system, RHINOWRAP® can be installed on tees, elbows, and straight runs of pipe. This flexible system is also easily applied in confined spaces and on irregular surfaces that require structural reinforcement or leak containment. The adhesive properties of the epoxy allow it to be applied to most substrates. Each kit is designed to cover a specific square footage amount with 4 options of cloth width.

• Superior alternative to clamps.• Fits all pipe sizes.• Designed for use on straight length, elbows, tees.• Compatible with carbon steel, stainless steel, alloys, PVC, fiberglass and more.• Low profile. • Designed for pressures up to 150 PSI.• Online training on www.rhinowraponline.com• Utilizes carbon fabric wrap (PAN-Polyacrylnitrile) and

Fiberglass.• Highly corrosion resistance.• Long service life.• RHINOWRAP® 100% solids epoxy systems for chemical resistance. • No VOCs. • No hot works / No welding required. • Supplied as a complete kit. • Fast curing. • Extensively tested in lab and the field.

Carbon Fiber and Fiberglass Hybrid Com

posite Wrap

www.rhinowraponline.com

NOTE: RHINOWRAP® SYSTEM IS DESIGNED FOR LOWER RISK: Low pressure (up to 10 Bar/150PSI) and low temperatures (up to 50°C/122°F). For questions regarding pressures and temperatures exceeding the above, please contact us.

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Tensile Strength 164,661 kPa 23,882 PSIModulus 12.3 x 106 kPa 17.8 x 105 PSIStrength per layer per inch 1.290 kPa/ply/mm 475 PSI/ply/inLinear elastic behavior 1.64% strain to failure 1.64% strain to failureCure Time 8 hours @ 25°C 8 hours @ 77°FTg, Glass Transition Temp. 100°C 212°FNominal thickness per ply 0.51054 mm 0.0201 inCarbon fiber content 30 - 50% 30 - 50%Glass fiber content 50 - 70% 50 - 70%Lap Shear strength >6894.76 kPa >1,000 PSIHardness 78 to 84 (Shore D) 78 to 84 (Shore D)

Each kit may be used on a wide variety of pipe diameters with easy installation. However, when wrapping around elbows or tees, the following recommendations should be followed to insure proper application.

Pipe Diameter Range Recommended Metric System English System Kit 203.2 mm < 8 Pol. RW-2-5 152.4 -355.6 mm 6 – 14 in RW-4-10 254 - 406.4 mm 10 – 16 in RW-6-15 355.6 mm > 14 in RW-12-20

• Using the RW-12-20 kit, you could wrap approximately 3 linear feet on a 24” pipe with 4 layers of material.• Using the RW-6-15 kit, you could wrap approximately 3.5 linear feet on a 16” pipe with 4 layers of material.• Using the RW-4-10 kit, you could wrap approximately 5.5 linear feet on a 6” pipe with 4 layers of material.• Using the RW-2-5 kit, you could wrap approximately 5.5 linear feet on a 3” pipe with 4 layers of material.

Alternatively, if you only needed 2 layers of material for corrosion prevention or external repair with no through-wall defect, you could double these lengths/area coverages.

A Pipe Around a Pipe.

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Description

Citadel Technologies SLS-Series™ of epoxies and coatings have been tested on various applications for more than 20 years. The epoxy system can be tailored to a customer’s specific needs.

Possible Applications for the SLS-Series™

Applicator Network

Citadel Technologies has a network of qualified applicators to assist with projects. We choose only the most experienced, safety oriented and quality driven applicators to join our network.

Ultra-Build Epoxy Lining System

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• Deep Shaft and Tunnel Lining • Waste Water Systems• Sewer, Lift Stations and Clarifiers • Tanks and Towers • Piping Systems • Fan Systems • Cooling lines • Cooling Towers

• Refineries • Gas and Electric Industry• Transmission lines • Power Plants• Nuclear Plant • Beverage and Food • Chemical Plants • Corroded Substrates

• Steam Plants • Pumps• Schools, Prisons, and Hospitals• Cruise ships • Marine • Off Shore Platforms • Mines • Washdown and Finishing Plants

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Designed Solutions

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PRODUCT NAME

CHEMICAL CONCEN- TRATION

Water DetergentBacteriaDetergent

Alkalis Sodium Hydroxide AmmoniaAmmonia Hydroxide

Inorganic Acids

10%20%36%

5%10%

10%10%

10%30%

50%98%

20%

Sulfuric Acid

Organic Acids Acetic Acid

Buteric Acid

AlcoholsEthanol Methanol

Organic Solvents AcetoneButyl AcetateCellusolve

Gasoline JP–4 MEK

Toluene

Chlorinated SolventsMethylene Chloride

Trichloroethylene

Hydraulic Fluids

ExcellentExcellentExcellent Excellent

Excellent

ExcellentExcellentExcellentExcellentExcellentExcellentExcellentExcellentExcellentExcellent

ExcellentExcellentExcellent

PoorPoor

ExcellentExcellent

PoorExcellent

Poor

Excellent

ExcellentExcellentExcellentExcellent

Excellent

ExcellentFairPoorGoodPoorPoor

ExcellentGoodPoor

PoorPoorPoor

PoorPoor

ExcellentExcellent

PoorExcellent

Poor

Excellent

SLS-30™

ExcellentExcellent Excellent Excellent

Excellent

Excellent

PoorPoor

ExcellentExcellent

PoorExcellent

Poor

Excellent

SLS-70™SLS-60™

Chromic AcidHydrochloric Acid

Phosphoric Acid

Nitric Acid

50%30%

10%

SLS-Series™ Chemical Resistance

NOTE: This chart is provided as a general reference guide relating to chemical resistance characteristics. It is based on ambient temperature. Characteristics will vary with increased temperature, pressure, and percent of concentration of the chemical identified.

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Ultra-Build Epoxy Lining System

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* available in 2:1 and 3:1 ratios

For industrial and aqueous service where strength and corrosion resistance are most critical.

• Waste Collection Systems • Cooling Water Lines • Sewers • Slurry Tanks• Lift Stations • Vaults • Waste Treatment Facilities • Rehabilitation • New Construction • Manholes

SLS-30™ is a two-component, 100% solids, no VOC epoxy system. It has been designed to provide the greatest structural strength and chemical resistance of any product in its class.

SLS-30™ provides both a structural, cured-in-place lining and a chemical protective barrier in one quick application. It can be applied to both old and new bricks, concrete and steel at a thickness of 40 mls. to over 275 mils.

SLS-30™ can be applied at all ambient temperature ranges; however, care must be taken not to apply over frost or active leaks. It must also be noted that when applied to very cold surfaces, set and cure times will be greatly increased. As with any cured in-place system that requires a good bond, the substrate must be free from all dirt, oil, grease, and rust.

Description Metric English

Mix Ratio (Resin/Hardner) 2.5:1* 2.5:1*

Combined Wt. Per Gallon 4.38 kg / gal. 9.6lbs / gal.

Pot Life (100 g mass) 12 min @ 25°C 12 min @ 77°F

Set Time 3.0 hrs @ 3.0 hrs @ 2.54 mm @ 25°C 100 mils @ 77°F

Hardness 78-84 (Shore D) 78-84 (Shore D)

Compressive Strength 93,080 kPa 13,500 PSI

Compressive Str. Ult. 151,600 kPa 22,000 PSI

Tensile Strength 59,300 kPa 8,600 PSI

Tensile Elongation, % (resin) >3.5 >3.5

Tensile Modulus 3.24 x 106 kPa 4.7 x 105 PSI

Flexural Strength 97,500 kPa 142,00 PSI

Flexural Modulus 3.5 x 106 kPa 5.0 x 105 PSI

Taber Abrasion 30mg 30mg

Adhesion (Concrete) Substrate Failure Substrate Failure

Adhesion (Steel) 1.2 kPa 1,200 PSI

Description Metric English

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Tensile Strength / Elongation ASTM D638Flexural Strength ASTM D790Hardness, Shore D ASTM D2260Solids by Volume (%) ASTM D2369Weight per Gallon ASTM D1475Flash Point TOC ASTM D1310Dry Time ASTM D1650Chemical Resistance (30 Days) ASTM D543Chemical Resistance Flexural Strength (180 Days) ASTM D790Compressive Strength ASTM D695Freeze-Thaw UL 76-63Adhesion ASTM D3983Taber Abrasion, CS-17 Wheel ASTM D4064, 1 Kg Load/1,000 cycles

Metric System English System

Pot Life (100 g mass) 11 min 5 sec @ 25 ° C 11 min 5 sec @ 77 ° FSet Time 2 hrs 47 min @ 2.54 mm @ 25°C 2 hrs 47 min @100 Mils @ 77°FHardness 78-84 (Shore D) 78-84 (Shore D)Compressive Strength 91,650 kPa 13,292 PSICompressive Strength Ult. 151,600 kPa 22,000 PSITensile Strength 60,000 kPa 8,695 PSITensile Modulus 3.24 x 106 kPa 4.7 x 105 PSIFlexural Strength 102,700 kPa 14,893 PSIFlexural Modulus 3.5 x 106 kPa 5.0 x 105 PSITaber Abrasion 30 mg 30 mgAdhesion (Concrete) Substrate Failure Substrate FailureAdhesion (Steel) 1.2 kPa 1,200 PSI

Designed Solutions

www.cittech.com www.cittech.com

Sulfuric Acid, 20% 1.402%Sodium Hydroxide, 5% 0.91%Ammonium Hydroxide, 5% 0.995%Nitric Acid, 1% 1.301%

Ferric Chloride, 1% 1.227%Sodium Hypochlorite, 1% 1.100%Distilled Water 1.015%Toluene 1.205%

% Weight Gain % Weight Gain

31

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Ultra-Build Epoxy Lining System

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DESCRIPTION: A 3.5:1 ratio, Ultra High Build epoxy system formulated for spraying or hand application. Use with 3.5:1 ratio proportional equipment or by hand.

CHARACTERISTICS: Formulated to produce excellent bond and chemical resistance to the host substrate. The ability to apply higher buildup per pass.

APPLICATION: Our experienced team will assist in qualifying your existing equipment or offering carefully calibrated equipment for use with the SLS Series product line. The epoxy component utilizes a 3.5:1 ratio by volume. The SLS Series is only applied to qualified applicators or consultants within in the Citadel Technologies Network.

ADVANTAGES:

HANDLING: There is no special safety or handling procedure beyond those published on the MSDS.

• Ultra High Build Capability • Onsite Technical Consultants • No VOCs • Harsh Chemical Environments and Substrates• Excellent adhesion to steel and concrete • Extensively tested by Citadel Technologies

LIQUID PROPERTIES

Color GreenPot Life (100 g mass@ 77F) 12 mins Set Time (100 mils @ 77F ) 3.0 HoursMix Ratio 3.5:1 Combined Weight 9.6 lbs/gals

PHYSICAL PROPERTIES (1/8” Casting or 125 Mils Casting)

Hardness 78-84 (Shore D) Tensile Strength (ASTM D638) 8,600.00 PSITensile Modulus (ASTM D638) 4.7 x 105 PSI Tensile Elongation @Break >3.5 Taber Abrasion (ASTM D4064) 30 mg

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Designed Solutions

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DESCRIPTION: A 4.3:1 ratio, Ultra High Build epoxy system formulated for spraying or hand application. Use with 4.3:1 ratio proportional equipment or by hand.

CHARACTERISTICS: Formulated to produce excellent bond and chemical resistance to the host substrate. The ability to apply higher buildup per pass.

APPLICATION: Our experienced team will assist in qualifying your existing equipment or offering carefully calibrated equipment for use with the SLS Series product line. The epoxy component utilizes a 4.3.1 ratio by volume. The SLS Series is only applied by qualified applicators or consultants within in the Citadel Technologies Network.

ADVANTAGES:

HANDLING: There is no special safety or handling procedure beyond those published on the MSDS.

• Applied to corroded substrates above 180F • Formulated to set at higher temperatures • No VOCs • Excellent adhesion to steel and concrete • High Chemical resistance

LIQUID PROPERTIES

Color TaupePot Life (100 g mass@ 77F) 12 mins Set Time (100 mils @ 77F ) 3.0 HoursMix Ratio 4.3:1 Combined Weight 9.6 lbs/gals

PHYSICAL PROPERTIES (1/8” Casting or 125 Mils Casting)

Hardness 78-84 (Shore D) Tensile Strength (ASTM D638) 8,600.00 PSITensile Modulus (ASTM D638) 4.7 x 105 PSI Tensile Elongation @Break >3.5 Adhesion (Concrete) (ASTMD3983) Substrate FailureAdhesion (Steel) (ASTMD3983) 1,200 PSI

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Description

DIAMAPRO™ is the premier fiberglass composite wrap system engineered to rehabilitate and restore strength to corroded and eroded piping systems. With DIAMAPRO™, Citadel Technologies has paired fiberglass fabric with its high tech custom epoxies and subjected it to the same rigorous quality control seen in all of Citadel Technologies’ products.

Installation is quick, cost effective, environmentally friendly, making DIAMAPRO™ the right choice for your pipe repair needs. With its flexibility, DIAMAPRO™ can be installed on tees, elbows, straight pipes, flanges and valves alike. DIAMAPRO™ is able to restore a pipe to maximum allowable operating pressure (MAOP) without shutting down. DIAMAPRO™ is fast curing with no VOCs, no hot work/welding required and complies with ASME PCC-2 Article 4.1, making DIAMAPRO™ a superior alternative to clamps.

Compared to traditional methods of repair, DIAMAPRO™ is less expensive, less time consuming, and not as labor intensive. DIAMAPRO™ has the added value of no service interruptions while avoiding any emissions from vented or damaged pipes, which reduces safety risks.

DIAMAPRO™ is available in bulk for easy storage and emergency situations.

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Fiberglass Composite Repair System

TYPICAL APPLICATIONS

• Emergency repair solution• Adds strength to existing piping• Designed to extend life of pipe to next turnaround

opportunity• Fast and effective repairs

• Impact protection• Installation on elbows, tees and complex geometries• Quick installation with no heavy equipment necessary• Industries include transmission pipelines, refineries,

chemical plants, power plants, and more

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Superior Pipe Restoration

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Properties ENGLISH METRIC

Total layers 2-14* 2-14*Cure Time (typical at 25oC)(hr) 4.5 Approx. 4.5 Approx.Maximum Operating Temperature (°F) 180˚F 82˚CChemical Resistance (pH range) 2 to 12 2 to 12Nominal Thickness (in) .06 (2ply) – .44 (14ply) 1.5-11 mmLap Shear Strength @ 140 ̊F (Adhesive) 2,000 PSI 137 barHardness Shore D 78 to 84 78 to 84Linear Elastic Behavior 1.80% strain 1.80% strainElastic Modulus Hoop Direction (Msi) 1.2 82,737 barTensile Strength Hoop Direction (ksi) 16.4 1,131 barMeets Requirements of ASME PCC-2, ISO/TS 24817 Yes Yes

BENEFITS

• Tested and designed according to ASME PCC-2 Article 4.1 (Nonmetallic repair standard for High Risk Applications)

• Applicable in damp and wet environments• No VOCs• Fiberglass reinforcing material (2, 4, 6, 12-inch

wide fabrics)• 100% Solids epoxies formulated and tested by

Citadel Technologies • Strong chemical resistance• UV Resistant

• Engineered Solution according to customer’s stock levels

• Long shelf life when stored properly• Restores strength to corroded and eroded piping

systems• Purchased in bulk quantities instead of kits: Rolls

of fiberglass and bottles of epoxy• Fast curing – Leaking pipes can be quickly

returned to service• No hot works/welding required

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Description

DIAMACORR™ is a two-component coating and lining system, which includes 100% solids epoxy and bi-directional fiberglass fabric. It provides high-strength corrosion and chemical protection. DIAMACORR™ offers excellent low-temperature performance and is available with high-temperature epoxies. Installation is quick, cost effective, and environmentally friendly. DIAMACORR™ is designed to be applied over steel, concrete, or masonry. Use DIAMACORR™ to protect your new piping, or extend the service life of existing systems. DIAMACORR™ HT™ can be installed on piping systems that operate up to 149°C (300°F). DIAMACORR™ does not require a hot works permit to install. DIAMACORR™ 701™ can be installed on piping systems that operate up to 170 ̊C (340 ̊F).

Installation Method

• Execute surface preparation• The substrate must be free of rust, oil, grease, salt, or any other source of contamination• Recommend near white surface to provide anchor profile• Pour hardener into resin and mix for approximately one to two minutes until mixture is homogenous• Apply mixed epoxy saturant to DIAMACORR™ reinforcing fiber• Apply reinforcing fiber to pipe at a 50% spiral overlap for the length of pipe to be wrapped• Allow sufficient time for product to cure in ambient temperatures• Minimum 74HSD

Corrosion Protection: 12” OD 26m length

Corrosion Protection: 30” OD 24m length Corrosion Protection: 20” OD 52m length

Corrosion Protection: 20” OD 52m length

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Coating and Lining System

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Coating and Lining System

www.cittech.com www.cittech.com 37

Features and Characteristics

• Bi-directional fiberglass fabric• Suitable for protecting piping, pipelines, tanks, miscellaneous pressure vessels, welds, and structures• Excellent adhesion to virtually any substrate• Adds strength to existing piping or structure• UV resistant• Abrasian resistant• Long term durability • No VOCs • Excellent low temperature performance• Prevents future external corrosion• Strong chemical resistance• No hot works permits• No installation training required• Industries of typical use include: petroleum, refineries, pipelines, chemical plants, offshore platforms,

pulp and paper mills

Properties DIAMACORR™ DIAMACORR™HT™ DIAMACORR™701™

Pot life 45 min @ 25° C (77° F) 60 min at 25° C (77° F) Indefinite @ 25° C (77° F)

Set Time 1 hour @ 25° C (77° F) 3 hours @ 25° C (77° F) 2 hours 20 min @ 135° C (275° F)

Mix Ratio Pre-poured Pre-poured Pre-poured

Operating Temperature Range -60° C to 82° C (-77° F to 180° F) -60° C to 149° C (-77° F to 300° F) -60° C to 171° C (-77° F to 340° F)

Application Temperature Range 10° C to 60° C (50° F to 140° F) 10° C to 107° C (50° F to 225° F) 10° C to 135° C (50° F to 275° F)*

UV Protection Yes Yes Yes

Abrasion Resistance Yes Yes Yes

Colors Resin = Off White Resin = Light Tan Resin = Light Yellow

Hardener = Maroon Hardener = Maroon Hardener = Maroon

Mixed = Dark White Mixed = Tan Mixed = Amber

Shelf Life 2 years minimum 2 years minimum 2 years minimum

Chemical Resistance Excellent Excellent Excellent

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Description

DIAMASHIELD™ is designed to protect field joints and thrust bore pipes from the highly abrasive environments. DIAMASHIELD™’s abrasion resistant composite coating system is beneficial when applied to operations such as horizontal directional drilling (HDD) or thrust boring. Once installed, Citadel Technologies’ high quality composite coating system adds thickness to the pipe or field joint to combat potential scratches and coating defects that may occur during dragging or directional drilling.

DIAMASHIELD™ is composed of three different components: an epoxy polymeric matrix that is reinforced with a fiberglass mat, and a two-part 100% solids epoxy topcoat. Together, the composite and epoxy topcoat combine to provide optimal abrasion resistance and thickness build-up to achieve superior results on field joints and thrust bore pipes.

Features and Characteristics

• Excellent abrasion resistance for protecting coated pipes subjected to horizontal directional drilling and thrust boring• Economically builds abrasion resistant coating thickness on field joints• Excellent adhesion to virtually any substrate• UV Resistant• No VOCs• High performance in low temperatures• Prevents external corrosion• Strong chemical resistance• No hot works permits • Applicable operations include HDD, thrust bore, field joints, pipelines, etc.• No hot works permits

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Coating and Lining System

www.cittech.com www.cittech.com 39

Properties DIAMASHIELD™

Pot life 45 min @ 25°C (77°F) Set Time 1 hour @ 25°C (77°F) Mix Ratio Pre-poured Operating Temperature Range -60°C to 82°C (-77°F to 180°F) Application Temperature Range 10°C to 60°C (50°F to 140°F) UV Protection Excellent Abrasion Resistance Excellent Colors Resin = Tan Hardener = Maroon Shelf Life 2 years minimum 2 years minimum

0

3

6

9

12

15

18

21

24

27

30

33

10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220

Cure-T

ime P

redic

tio

n (hours)

Cure Temperature (oF)

Cure-Time Predictions vs Temperature

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Description

DIAMASHOE™ is a manufactured two-component fiber- reinforced polymer (FRP) pipe support system, which includes 100% solids epoxy and fiberglass fabric.

Use DIAMASHOE™ as a high-strength method to protect and extend the life of your new or existing piping from abrasion and corrosion typically associated with metal pipe supports.

DIAMASHOE™, in combination with Citadel Technologies’ SLS-Series™, is an economic and light weight alternative to metal pipe supports. Installation is quick, cost effective, and environmentally friendly. DIAMASHOE™ can be applied to steel, concrete, or any other substrate.

www.cittech.com www.cittech.com40

Abrasion-Resistant Pipe Support System

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Abrasion-Resistant Pipe Support System

www.cittech.com www.cittech.com 41

Features and Characteristics • Suitable for protecting piping, pipelines, and welds • Light weight – does not add weight to the pipe• High compressive strength• Increased bond strength vs. metal pipe support• UV resistant• Long term durability• Prevents future external corrosion on the pipe and does not corrode once installed• Abrasion-resistant• No hot works permits for installation• Industries include transmission pipelines, refineries, chemical plants, power plants, and more

Properties DIAMASHOE™

Thickness 6.3mm to 9.5mm (1/4” to 3/8”)Operating Temperature Range -60°C to 82°C (-77°F to 180°F)Application Temperature Range 10°C to 60°C (50°F to 140°F)UV Protection YesAbrasion Resistance YesColor Desert Sand

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Ultra-Build Epoxy Lining System

s

The University of Tulsa and Citadel Technologies conducted independent rupture tests per ASME PCC-2 Section 4.1, Appendix III. The results are shown for repairs with a maximum of 6 layers of carbon on the repair when the pipe was repaired with no internal pressure applied. Both defects were 6 inches long, and the patch defect was 6”x6” in area.

Defect Type Wall Loss ksi (MPa) ksi (MPa) No Flaw N/A 6.65 45.85 N/A N/A Axi- 50% 4.35 29.99 6.35 43.78 Symmetrical 80% 1.88 12.96 5.12 35.3 Square, 50% 4.4 30.34 6.25 43.09 Patch-shaped 80% 1.88 12.96 5.25 36.2

No Repair Repaired

Failure Pressure

Fatigue tests were performed by the University of Tulsa on pressure vessels to determine the effectiveness of repairs made using a carbon/epoxy composite material system. The carbon/epoxy system is intended to repair externally damaged or corroded steel pipe. Six-inch nominal diameters by five feet long pressure vessels were constructed from A-106 Grade B steel for test purposes. Defects were machined into the outer surface of each pressure vessel to determine limitations of the carbon /epoxy repair system. Unrepaired pipes were cycled to determine a base number of maximum operating cycles. Remaining vessels were wrapped and then cyclically pressurized until a leak in the system was detected. The repaired vessels were compared to un-repaired vessels with equal size defects to determine the effectiveness of the repair. Results indicate there was a substantial increase in the performance of the pipe.

Repair None Repaired Defect 1.125” x 5.19” 1.25” x 2.75” 1.125” x 5.19” 1.125” x 5.19” Wall Loss 80% 80% 70% 80% Cycles 3 Infinite Infinite Infinite

Test Information

www.cittech.com www.cittech.com

1Ksi = 1.000 PSI ou 70,30 Kgl/cm2 ou 68,94 Bar

42

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The University of Tulsa performed cathodic disbondment testing. Cathodic disbondment tests were conducted on A-106 Grade B steel pipes on which carbon- fiber-reinforced polymeric wraps were installed. The composite wraps are part of system used to repair externally damaged or corroded steel pipes. To stimulate a corrosive environment, pipes coated with the composite wraps were submerged in an electrolyte consisting of potable water, sodium chloride, sodium sulfate and sodium carbonate. Holidays or breaks in the composite wrap were produced, exposing electrolyte. Test results indicate the carbon-fiber-reinforced polymeric repair system exhibits no disbondment.

Galvanic Corrosion tests were performed by the University of Tulsa using composite panels joined in conjunction with dissimilar metals. The test results showed no corrosion attributed to Galvanic Corrosion.

Room temperature, coupon testing was performed at the University of Tulsa. Specimens were tested using an in-situ creepture fixture. The test was done at 77% (UTS), and the results were recorded for a 1350-hour test period. The creep testing supports the fact that carbon-fiber composites are resistant to creep and creep rupture under ambient conditions. The level of creep in the tests was small enough to extrapolate that the material would not fail at 77% (UTS) load during its lifetime.

Test Information

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Chemical Resistance for Standard Epoxies

30 Days Exposed

Water No effect Sulfuric Acid,20% No effect Sodium Hydroxide,50% No effect Ammonium Hydroxide,5% No effect Nitric Acid,1% No effect Sodium Hypochlorite(Bleach) No effect Ferric Chloride,1% No effect Detergent Solution No effect Gasoline No effect Tolune No effect

Citadel Technologies’ standard epoxy is designed for operating temperatures up to 82°C (180°F). This system is blended to withstand a wide range of chemicals including: caustic, 20% sulfuric acid, 20% hydrochloric acid, water, brine, detergents, toluene, gasoline, and other weak acids and solvents. It is not intended for concentrated Strong Acids, Organic Acids, Strong Solvents (MEK, Acetone, Alcohol). For these stronger chemical concentrations, please consult Citadel Technologies and consider the use of Citadel Technologies’ Acid epoxy system.

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Tests involving dents and gouges were performed both by the University of Tulsa and by Stress Engineering. The results of this test program, along with supporting data from other studies on these repair systems, confirm the validity of this repair system for repair of dents and pipes with gouges. The reinforcement provided by the carbon fiber/epoxy composite repair system provides a significant increase to the fatigue life of un-repaired mechanically damaged pipes.

Composite Repairs Made While The Pipe is Pressurized

Testing was conducted on Citadel Technologies’ carbon composite products by wrapping defective pipe while under internal pressure loading. Test pipes with flaws varying from 20% to 75% wall loss were wrapped while the pipe was operating at MAOP. The pipes were then cycled between 50 PSI and MAOP. After inspection indicated that there was no de-lamination, the pipes were pressured to rupture. No differences were noted to those pipes that were wrapped at zero pressure. This testing shows that defects may be repaired without reducing the pipeline pressure prior to wrapping.

If you would like more detailed information regarding these, or other, test programs, please contact Citadel Technologies and request a copy of the Citadel Technologies Technical Product Guide.

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APPENDIX

Transmission Line Under certain conditions Preferred Preferred

Facilities “In Plant” Lines Preferred Under certain conditions Under certain conditions

External Corrosion Yes Yes Yes

Internal Corrosion Per Design Per Design No (Length of repair life determined by rate of internal corrosion) (Length of repair life determined by rate of internal corrosion)

Thru Wall Defect Up to 1” hole (larger w/ plug) No No

Dents Yes Yes Yes

Wrinkle Bends Yes Yes Yes

Weld Yes Yes Yes

Bending Yes Yes Yes

Axial Loads Yes Yes Yes

Pipe Material Bonds well to most metals and plastics with the exception of polypropylene and polyethylene = Bonds well to most metals and plastics with the exception of polypropylene and polyethylene

Pipe Size No limit No limit No limit

Straight Pipe No limits in continuous length No limits in continuous length No limits in continuous length

Elbow Yes Yes Yes

Tee Yes Yes Yes

Valve Heads Yes Yes Yes

Other configurations Yes Yes Yes

Maximum RecommendedOperating TemperaturePressure No limit No limit No limit

Chemical Compatibility Excellent Excellent Excellent

For strong acids and solvents consult Citadel Technologies For strong acids and solvents consult Citadel Technologies

Standard ASME PCC-2, 4.1 ASME PCC-2, 4.1 ASME PCC-2, 4.1

82°C (180°F) Standard149°C (300°F) HTA™

171°C (340°F) HT701™288°C (550°F) UHT™ (*)

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Citadel Technologies Carbon Fiber Composite Wrap Product Guide

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APPENDIX

Transmission Line Under certain conditions Preferred Preferred

Facilities “In Plant” Lines Preferred Under certain conditions Under certain conditions

External Corrosion Yes Yes Yes

Internal Corrosion Per Design Per Design No (Length of repair life determined by rate of internal corrosion) (Length of repair life determined by rate of internal corrosion)

Thru Wall Defect Up to 1” hole (larger w/ plug) No No

Dents Yes Yes Yes

Wrinkle Bends Yes Yes Yes

Weld Yes Yes Yes

Bending Yes Yes Yes

Axial Loads Yes Yes Yes

Pipe Material Bonds well to most metals and plastics with the exception of polypropylene and polyethylene = Bonds well to most metals and plastics with the exception of polypropylene and polyethylene

Pipe Size No limit No limit No limit

Straight Pipe No limits in continuous length No limits in continuous length No limits in continuous length

Elbow Yes Yes Yes

Tee Yes Yes Yes

Valve Heads Yes Yes Yes

Other configurations Yes Yes Yes

Maximum RecommendedOperating TemperaturePressure No limit No limit No limit

Chemical Compatibility Excellent Excellent Excellent

For strong acids and solvents consult Citadel Technologies For strong acids and solvents consult Citadel Technologies

Standard ASME PCC-2, 4.1 ASME PCC-2, 4.1 ASME PCC-2, 4.1

82°C (180°F) Standard149°C (300°F) HTA™

171°C (340°F) HT701™288°C (550°F) UHT™ (*)82°C (180°F) Standard

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Citadel Technologies ́epoxy products have a minimum shelf life of more than two (2) years when stored in a dry place at room temperature and sealed in the original unopened container.

BlackDiamond® System stored over 5 years has been tested with no measurable change in characteristics.

Typically stabilizing the resin system temperature between 20°C and 30°C (68°F -86°F) is recommended. This provides the best viscosities and pot life for ease of installation. Note that some environmental and operating conditions and temperatures can change this recommendation. Our engineering staff will provide you with any recommended changes.

The epoxy systems are 100% solids. Each system is manufactured for specific applications for installation on systems where hydrocarbons and high operating temperatures are a critical factor.

APPENDIX

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Product Care

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APPENDIX

Engineering Assessment

www.cittech.com

OWNER/OPERATOR:

Plant&Contact:

City/State/Country:

Phone/Email:

CONTRACTOR/INSTALLER:

Contractor&Contact:

City/State/Country:

Phone/Email:

PLANT/INFORMATION COMPONENT

Crude&Oil Refinery Pipe

Chemical DOT&Pipeline Elbow

Water Gas&Processing Tee

Other Other

EXISTING/CONDITION/OF/COMPONENT://(mark/all/that/apply) PIPE/SPECIFICATIONS

Not&Leaking Pinhole&Leak&E&hole&size: Diameter:

Seam&Leak Internal&Corrosion&E&Contents&of&line: Grade:

Crack Schedule:

External&Corrosion Length&of&flaw:

%&WALL&LOSS Type&of&Steel:

TEMPERATURE LINE/PRESSURE

Low: °F Min: PSI

Constant: °F Operating: PSI

Max: °F Max: PSI

Emergency/Repair?&(Y/N)

Line/temperature/can/be/lowered/or/raised/during/maintenance/to:Low: °F Max: °F

Surface/Preparation/available?

Minimum/available/space/for/the/repair/(If&less&than&1&meter&surrounding):Above: Around:&

Conditions/at/the/time/of/repairPipe&temperature: °F Ambient&temperature: °F

What/is/anticipated/service/life/of/the/repair/system? Months Years

Date/of/Approval:/August/13,/2012

Repair&Qty:

FORTENGT001/ENGINEERING/ASSESSMENT/FORM"

Uncontrolled*when*printed Version:/7

Below:

Wrap/Line/while/in/Service?&(Y/N):

Repair&Length:

Repair&Qty:

QMS Document

Internal(use(only:Case&Number:

PLEASE/ATTACH/ALL/DRAWINGS,/SKETCHES,/PICTURES,/AND/OR/SCHEMATICS/TO/THIS/FORM

Page/1/of/1

Repair&Description:

49

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Sample DiamondWrap® Wizard Calculation

APPENDIX

6430 S. 39th W. Ave Tulsa, Oklahoma 74132 Phone: 918.584.2220 Fax: 918.584.2221

#XXXXX3/5/2009

Kit = Standard

Material Specifications:

(3) DW-1204 Kits

Each kit will supply

Owner contact Diamond Wrap®ContactMaterial Type - Carbon Steel ASTM A106 Gr. B

From Engineering Assessment

Pipe Diameter - 12 inOperating Pressure - 150 psiDesign Pressure - 225 psi

Current Wall Thickness - 0 in

External Defects - Corrosion. Internal Defects - Corrosion.

Application - Plants

XXX Refinery Maintenance Contracting

Joe Engineer Joe Wrap

XYZ Fixit Rd.123 Refinery Dr.

Houston, TX Houston, TX

[email protected] [email protected]

Minimum Yield Strength - 35000 psi

Phone: 555-555-2181

Fax:

Phone: 555-555-1812

Fax:

0.064 (Using Design Conditions)0.051 (Using Operating Conditions)

= 4 wraps of BA cloth

Operating Temperature - 100 FDesign Temperature - 180 F

Design repair thickness (t_repair) = 0.027 in Tensile modulus for the composite laminate in the circumferential direction (Ec):

Operating: 3784491 psiDesign : 3736230 psi

External Pipe Diameter(D) = 12.75 inInternal Pressure(P) = 150 psi (Operating) , 225 psi (Design)SMYS (Specified Minimum Yield Strength) (s) = 35000 psiMinimum remaining wall thickness of the pipe (ts) = 0 inAllowable circumferential strain ( ) = 0.50% (operating) and 0.60% (design)Ply or layer thickness of the composite repair material (t_layer) = 0.018 in

Wrap calculations have taken into consideration all information provided on the engineering report and are subject to CitadelTechnologies' terms and conditions.

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Sample DiamondWrap® Wizard Calculation

APPENDIX

Engineering Assessment – Concrete

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Date ofPresentation / Publication

Engineer Presenting / Submitting Material Type of Presentation / Publication Type of Presentation / Publication

19-Apr-99 Roger Walker and Wes Rowley Technical paper 7th International Conference on Nuclear Engineering Tokyo, Japan Use of Structural Lining Systems

2-Apr-00 Roger Walker and Wes Rowley Technical paper 8th International Confernce on Nuclear Engineering Baltimore, MD Use of Reinforced Epoxy as a Structural Lining System

24-Jul-00 Roger Walker and Wes Rowley Technical paper EPRI Service Water System Reliability Improvement Seminar Branson, MO A Case Study for Service Water System Degradation and Repair

2-Apr-01 Roger Walker and Wes Rowley Technical paper and presentation 9th International Conference on Nuclear Engineering Nice, France Non-metallic Structural Wrap Systems for Pipe

4-Apr-04 Technical paper Cathodic-Disbondment Testing of Carbon-fiber/Epoxy Composite Wraps on Steel Piping

1-Jan-06 Goertzen, Mike Kessler Technical Journal Submission Material Science and Engineering A Creep behavior of carbon fiber/epoxy matrix composites

1-Jan-07 Goertzen, Mike Kessler Technical Journal Submission Composites Part B: Engineering Dyanmic mechanical analysis of carbon/epoxy composites for structural pipeline repair

1-Jan-08 Josh Duell, Jeff Wilson, Mike Kessler Technical paper International Journal of Pressure Vessels and Piping Analysis of a carobn composite overwrap pipeline repair system

22-Apr-09 Roger Walker and Jesse French Technical paper 4th Pipeline Technology Conference 2009 Hannover, Germany Validation Testing of Composite Repair Systems for Pipes and Pipelines

1-Jan-10 Thomas Rehberg, Michael Schad and Matt Green Magazine publication Pipeline Technology Magazine Non-Metallic Composite Repair Systems for Pipes and Pipelines

14-Feb-10 Matt Green, Michael Keller, Roger Walker Technical paper and presentation 13th Middle East Corrosion Conference and Exhibition Kingdom of Bahrain The Effects of Internal Pressure of a Pipeline During Application of a Nonmetallic Composite Repair

18-Jul-11 Tim Mally Technical paper and presentation ASME PVP Baltimore, MD Underwater Testing of a Typical Ambient-Cure Epoxy Resin for Composite Repairs

26-May-11 Amanda Hawkins Technical presentation and demo to pipeline end user group Southern Gas Association Workshop Houston, TX Technical Specifications of Citadel Technologies' repair systems

1-Feb-12 Mike Keller, Brad Jellison, Travis Ellison Technical paper Composites Part B: Engineering Moisture effects on the thermal and creep performance of carbon fiber/epoxy composites for structural pipeline repair

1-Feb-12 Amanda Hawkins Magazine publication North American Oil and Natural Gas Pipeline Journal NA The Evolution of Composite Repair Industry

1-Apr-12 Amanda Hawkins Magazine publication North American Oil and Natural Gas Pipeline Journal NA Summary of CTI and business

7-Mar-12 Amanda Hawkins Technical paper and presentation CGA Excavation Safety Conference and Expo 2012 Las Vegas, NV Importance of analyzing, reporting, and repairing pipelines damaged during excavation

12-Mar-12 Amanda Hawkins Technical paper and presentation NACE 2012 Salt Lake City, UT Composite Repair of Pipelines with Axial Flaws

3-May-12 Amanda Hawkins Technical presentation and demo to pipeline end user group Southern Gas Association Workshop Houston, TX Technical Specifications of Citadel Technologies' repair systems

16-Jul-12 Tim Mally Technical paper and presentation ASME PVP Toronto, Canada "Empirical Estimation of the Abrasion Endurance Life of Epoxy Coatings for

16-Jul-12 David Gribble Technical paper and presentation ASME PVP Toronto, Canada Applications on Transmission Pipelines"

24-Aug-12 Tim Mally, Allison Johnston, Molly Chann, Roger Walker, Michael Keller

Technical paper Composite Structures Initial Quantification Of The Effect of Ambient Humidity On The Strength Of Non-Metallic Repairs Of Piping And Pressure Vessels

27-Aug-12 Amanda Hawkins Technical/non-technical presentation to pipeline professionals Tulsa Pipeline Expo Educational Session Tulsa, OK Performance of a Carbon-Fiber/Epoxy Composite for the Underwater Repair of Pressure Equipment

24-Sep-12 David Gribble Technical paper and presentation ANNA 2012 Toronto, Canada

Tim Mally Technical Journal Submission NA Initial Observation Of The Effects of Nitrogen Based Chemicals On Non-Metallic Repairs Of Piping And Pressure Vessels

1-Sep-13 Tim Mally Technical paper and presentation ASME PVP France Underwater Testing of a Typical Ambient-Cure Epoxy Resin for Composite Repairs

28-Aug-13 Amanda Hawkins Educational session presentation Tulsa Pipeline Expo Educational Session Tulsa, OK The Effects of Different Types of Surface Preparation on Lap Shear Strength of a Typical Ambient Cured Carbon Fiber Composite Repair System

1-Sep-13 Tim Mally Technical paper and presentation ASME PVP Tulsa, OK Composite Repairs: Not just a 'temporary repair'

28-Aug-13

15-Maz

Amanda Hawkins Educational session presentation Tulsa Pipeline Expo Educational Session Composite Repairs: Not just a 'temporary repair'

Engineering Papers and Presentations

15-Mar-15

Summer 2015

Tim Mally

Amanda Hawkins, Bradford Johnson Technical paper and presentation

Magazine publication

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Event / Journal Location Type of Presentation / Publication

19-Apr-99 Roger Walker and Wes Rowley Technical paper 7th International Conference on Nuclear Engineering Tokyo, Japan Use of Structural Lining Systems

2-Apr-00 Roger Walker and Wes Rowley Technical paper 8th International Confernce on Nuclear Engineering Baltimore, MD Use of Reinforced Epoxy as a Structural Lining System

24-Jul-00 Roger Walker and Wes Rowley Technical paper EPRI Service Water System Reliability Improvement Seminar Branson, MO A Case Study for Service Water System Degradation and Repair

2-Apr-01 Roger Walker and Wes Rowley Technical paper and presentation 9th International Conference on Nuclear Engineering Nice, France Non-metallic Structural Wrap Systems for Pipe

4-Apr-04 Technical paper Cathodic-Disbondment Testing of Carbon-fiber/Epoxy Composite Wraps on Steel Piping

1-Jan-06 Goertzen, Mike Kessler Technical Journal Submission Material Science and Engineering A Creep behavior of carbon fiber/epoxy matrix composites

1-Jan-07 Goertzen, Mike Kessler Technical Journal Submission Composites Part B: Engineering Dyanmic mechanical analysis of carbon/epoxy composites for structural pipeline repair

1-Jan-08 Josh Duell, Jeff Wilson, Mike Kessler Technical paper International Journal of Pressure Vessels and Piping Analysis of a carobn composite overwrap pipeline repair system

22-Apr-09 Roger Walker and Jesse French Technical paper 4th Pipeline Technology Conference 2009 Hannover, Germany Validation Testing of Composite Repair Systems for Pipes and Pipelines

1-Jan-10 Thomas Rehberg, Michael Schad and Matt Green Magazine publication Pipeline Technology Magazine Non-Metallic Composite Repair Systems for Pipes and Pipelines

14-Feb-10 Matt Green, Michael Keller, Roger Walker Technical paper and presentation 13th Middle East Corrosion Conference and Exhibition Kingdom of Bahrain The Effects of Internal Pressure of a Pipeline During Application of a Nonmetallic Composite Repair

18-Jul-11 Tim Mally Technical paper and presentation ASME PVP Baltimore, MD Underwater Testing of a Typical Ambient-Cure Epoxy Resin for Composite Repairs

26-May-11 Amanda Hawkins Technical presentation and demo to pipeline end user group Southern Gas Association Workshop Houston, TX Technical Specifications of Citadel Technologies' repair systems

1-Feb-12 Mike Keller, Brad Jellison, Travis Ellison Technical paper Composites Part B: Engineering Moisture effects on the thermal and creep performance of carbon fiber/epoxy composites for structural pipeline repair

1-Feb-12 Amanda Hawkins Magazine publication North American Oil and Natural Gas Pipeline Journal NA The Evolution of Composite Repair Industry

1-Apr-12 Amanda Hawkins Magazine publication North American Oil and Natural Gas Pipeline Journal NA Summary of CTI and business

7-Mar-12 Amanda Hawkins Technical paper and presentation CGA Excavation Safety Conference and Expo 2012 Las Vegas, NV Importance of analyzing, reporting, and repairing pipelines damaged during excavation

12-Mar-12 Amanda Hawkins Technical paper and presentation NACE 2012 Salt Lake City, UT Composite Repair of Pipelines with Axial Flaws

3-May-12 Amanda Hawkins Technical presentation and demo to pipeline end user group Southern Gas Association Workshop Houston, TX Technical Specifications of Citadel Technologies' repair systems

16-Jul-12 Tim Mally Technical paper and presentation ASME PVP Toronto, Canada "Empirical Estimation of the Abrasion Endurance Life of Epoxy Coatings for

16-Jul-12 David Gribble Technical paper and presentation ASME PVP Toronto, Canada Applications on Transmission Pipelines"

24-Aug-12 Tim Mally, Allison Johnston, Molly Chann, Roger Walker, Michael Keller

Technical paper Composite Structures Initial Quantification Of The Effect of Ambient Humidity On The Strength Of Non-Metallic Repairs Of Piping And Pressure Vessels

27-Aug-12 Amanda Hawkins Technical/non-technical presentation to pipeline professionals Tulsa Pipeline Expo Educational Session Tulsa, OK Performance of a Carbon-Fiber/Epoxy Composite for the Underwater Repair of Pressure Equipment

24-Sep-12 David Gribble Technical paper and presentation ANNA 2012 Toronto, Canada

Tim Mally Technical Journal Submission NA Initial Observation Of The Effects of Nitrogen Based Chemicals On Non-Metallic Repairs Of Piping And Pressure Vessels

1-Sep-13 Tim Mally Technical paper and presentation ASME PVP France Underwater Testing of a Typical Ambient-Cure Epoxy Resin for Composite Repairs

28-Aug-13 Amanda Hawkins Educational session presentation Tulsa Pipeline Expo Educational Session Tulsa, OK The Effects of Different Types of Surface Preparation on Lap Shear Strength of a Typical Ambient Cured Carbon Fiber Composite Repair System

1-Sep-13 Tim Mally Technical paper and presentation ASME PVP Tulsa, OK Composite Repairs: Not just a 'temporary repair'

28-Aug-13

15-Maz

Amanda Hawkins Educational session presentation Tulsa Pipeline Expo Educational Session Composite Repairs: Not just a 'temporary repair'

Engineering Papers and Presentations

World Pipelines

ASME PVP

World Composite Comfort: Economically Restoring Pipeline Integirty One Bend at a TimeElevated Temperature Lap Shear Testing of a Carbon Fiber Epoxy Compostie Repair System 53

Page 56: BLACKDIAMOND - aea-global.comaea-global.com/sites/default/files/Citadel Info Book English- 2017.pdf · of carbon composite repair systems. Our products include DIAMONDWRAP®, BLACKDIAMOND®

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