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Black carbon: Characterisation, measurement methods, and emission factors
Jana MoldanováIVL, Swedish Environmental Research Institute
Black carbon
Jana Moldanová, 2013-04-24
Definitions
Optical properties: Black carbon– Is formed by incomplete combustion of hydrocarbon
fuels, and is the most effective component of PM, by mass, at absorbing solar energy
– Mass of combustion-generated, sp2-bonded carbon that absorbs the same amount of light as the emitted particles. Absorption efficiency of the reference particles as 7 m2/g for 550-nm incident radiation (Bond 2004)
Thermal stability: Elemental carbon Structure: Soot Composition: Carbonaceous aerosol (includes OC)
Black carbon
Jana Moldanová, 2013-04-24
Definitions
Black carbon
Jana Moldanová, 2013-04-24
BC has a strong climate effect
Aamas et al., 2013
Black carbon
Jana Moldanová, 2013-04-24
BC sources - Europe
2. – non-industrial combustion4. – production processes9. – waste treatment and disposal10 – agriculture
van den Ggon, 2012
Black carbon
Jana Moldanová, 2013-04-24
BC sources - Global
Hendricks et al., 2013
BB for biomass burning, AWB for agricultural waste burning, AIRC for aviation, ANTH for other anthropogenic sources, VOLC for volcanoes and BIOG for biogenic sources.
Black carbon
Jana Moldanová, 2013-04-24
Spatial distribution of BC in fine PM
TRANSPHORM, van den Ghon, 2012
Black carbon
Jana Moldanová, 2013-04-24
Uncertainties in source strength
Kindbom in Hansson et al, 2012
Black carbon
Jana Moldanová, 2013-04-24
BC mixing – uncertainties in light absorption
Black carbon
Jana Moldanová, 2013-04-24
Measurement methods
Optical (BC)– in situ (Aethalometer)– filter analyses (Reflectande, trasmitance, Aethalometer,
MAAP)
Thermal (EC/OC)– NIOSH, Improve, EUCAARI, VDI
Photo-acoustic (measures heat generated by absorbed radiation)
Black carbon
Jana Moldanová, 2013-04-24
Optical Methods Sampling on filter matrix Measurement of modification of filter optical properties
by the sampled PM Assumption of Beer-Lambert law for data analyses Response depends on filter loading and interaction
between radiation, particles, and filter - requires corrections
Black carbon
Jana Moldanová, 2013-04-24
Multi-angle absorption photometer – both reflection and transmission – 2-stream model applied to evaluate results, no corrections
Optical Methods
Black carbon
Jana Moldanová, 2013-04-24
Thermal methods
Simple optical methods (oxidizing atmosphere, rizing T) Two-step methods (thermal pre-treatment to remove OC) Thermal-optical (optical correction for charring OC) Thermal stability and the optical correction can be
affected by presence of sulphate and metals in the PM
Black carbon
Jana Moldanová, 2013-04-24
Thermal-optical method
Black carbon
Jana Moldanová, 2013-04-24
Comparison of different optical and thermal methods (ship emissions)
PM1,
S1_
HFO
1%_
ME-
...
PM10
, S1_
HFO
1%_
ME.
..
TSP,
S1_
HFO
1%_
ME-
full
PM1,
S1_
HFO
1%_
ME.
..
PM10
, S1_
HFO
1%_
M...
TSP,
S1_
HFO
1%_
ME.
..
PM2.
5, S
2_H
FO1%
_ M
E...
PM10
, S2_
HFO
1%_
ME.
..
PM2.
5, S
2_H
FO0.
5%_
...
PM10
, S2_
HFO
0.5%
_ M
...
PM1,
S1_
MG
O_
AE
PM10
, S1_
MG
O_
AE
TSP,
S1_
MG
O_
AE
PM2.
5, S
2_M
GO
_ M
E-...
PM10
, S2_
MG
O_
ME-
...
0%
10%
20%
30%
40%
50%
60%
70% BC reflect.BC transmiss.EC
Different filter type for EC and BC
Black carbon
Jana Moldanová, 2013-04-24
Comparison EC/BC – typically in range 0.7-1.3
EPA, 2012
Black carbon
Jana Moldanová, 2013-04-24
Emission estimates From emission factors for EC/BC for individual sources
– Traffic: HDV wo DPF 45-150 mg/vkm, HDV w DPF 9-16 mg/vkm,PC w catalyst 1-2 mg/vkmPC petrol EURO 5+ 0.1-0.3 mg/vkmPC diesel EURO 5+ 0.1-1 mg/vkm
– Residential wood burning 0.043 – 3.5 g BC/kg wood (Kuipiainen & Klimont, 2007)
Samaras, 2012
Black carbon
Jana Moldanová, 2013-04-24
Emission estimates
From PM inventory and BC/PM ratio of the individual sources
Black carbon
Jana Moldanová, 2013-04-24
Emission estimates
From PM inventory and BC/PM ratio of the individual sources
TRANSPHORM, van den Ghon, 2012
Black carbon
Jana Moldanová, 2013-04-24
Emission factors for BC – effect of sampling
Figure 5 Composition of PM (as mg/m3 exhaust gas) collected on filters in the diluted and hot exhaust gas (Moldanová et al., 2009).
Black carbon
Jana Moldanová, 2013-04-24
<-------------- Residual fuel ---------> Dist. Fuel
PM composition profiles – ship emissions
Black carbon
Jana Moldanová, 2013-04-24
PM composition profiles – ship emissions
Volatility measured with online instruments (EEPS, GRIMM spectrometer, Thermodenuder)
Part of PM mass and PM number volatilized at 90ºC (Vol. 90), 150ºC (Vol. 150) and 300ºC (Vol. 300) in the thermodenuder and the non-volatile part (Nonvol.).
Black carbon
Jana Moldanová, 2013-04-24
PM composition – structure and composition of particles
STEM image of an agglomerate of soot-type particles from HFO combustion. Composition: C 77.1 wt%, N 15.7 wt% and O 6.9 wt% and traces of V, Ca and S (about 0.1 wt% of each element). b – Elemental composition map of V, Ca and S for the soot-type particles in a. c – Elemental composition of different particles with respect to N, V, and S.
a) b)c)
Black carbon
Jana Moldanová, 2013-04-24
PM composition – structure and composition of particles
STEM image of an agglomerate of soot-type particles from MGO combustion. b – Elemental composition map of S and Ca for the soot-type particles in a
Black carbon
Jana Moldanová, 2013-04-24
a - TEM picture of a small soot-type aggregate and its corresponding selected area electron diffraction (SAED) pattern, b - zoom on soot-type particles with dark dots and its associated SAED pattern
PM composition – structure and composition of particles
Black carbon
Jana Moldanová, 2013-04-24
Oxidation behaviour of PM (TSP in black and PM2.5 in red) sampled in a – HFO exhaust, b – MGO exhaust.
PM composition affects thermal stability
Black carbon
Jana Moldanová, 2013-04-24
Conclusions
Definition of BC is dependent of measurement technique used but also of impacts that are assumed (political definition)
Both optical and thermal methods give satisfactory results, impacts of PM composition on thermal methos need further consideration, further intercomparison of optical methods
Emission factors for BC and their variability with fuels, combustion conditions, technologies e.t.c. needs to be further developed
Consistency between PM and BC data important PM composition affect both measurement results and how the
particles behave in atmosphere (radiative properties, sink processes, health effects (?)
Relation between BC/EC emission at source and properties of these particles on mesoscale