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A simpler and highly efficient protocol for the preparation of biodiesel from soap stock oil using BBSA catalyst Mehulkumar L. Savaliya, Bharatkumar Z. Dholakiya* Department of Applied Chemistry, S.V. National Institute of Technology (SVNIT), Ichchhanath, Surat-395007, Gujarat, India. * Corresponding Author. Tel +91-9428949595, E-mail address:[email protected], [email protected] -: Supporting information:- Figure S1. Reaction assembly for production of biodiesel from soap stock oil Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2015

biodiesel from soap stock oil using BBSA catalyst A

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Page 1: biodiesel from soap stock oil using BBSA catalyst A

A simpler and highly efficient protocol for the preparation of

biodiesel from soap stock oil using BBSA catalyst

Mehulkumar L. Savaliya, Bharatkumar Z. Dholakiya*

Department of Applied Chemistry, S.V. National Institute of Technology (SVNIT), Ichchhanath,

Surat-395007, Gujarat, India.

*Corresponding Author. Tel +91-9428949595, E-mail address:[email protected],

[email protected]

-: Supporting information:-

Figure S1. Reaction assembly for production of biodiesel from soap stock oil

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2015

Page 2: biodiesel from soap stock oil using BBSA catalyst A

Figure S2. (a) Stock oil and (b) Soap stock biodiesel

Figure S3. GC-FID chromatogram of soap stock biodiesel

Page 3: biodiesel from soap stock oil using BBSA catalyst A

RH2O

O

OH R

O

OH2 RC

O

CH3HO+

RC

O

CH3O

HR

C

O

CH3O

-

-H

+

H+

Figure S4. Proposed mechanism for esterification of free fatty acid to biodiesel

Figure S5. FT-IR spectrum of BBSA catalyst

Page 4: biodiesel from soap stock oil using BBSA catalyst A

Figure S6. X-ray diffractrogram of BBSA

Figure S7. BET isotherm of BBSA catalyst

Page 5: biodiesel from soap stock oil using BBSA catalyst A

Figure S8. FT-IR spectrum of soap stock oil

Figure S9. FT-IR spectrum of soap stock biodiesel

Page 6: biodiesel from soap stock oil using BBSA catalyst A

Figure S10. 1H NMR spectrum of soap stock oil

Figure S11. 1H NMR spectrum of synthesized soap stock biodiesel

Page 7: biodiesel from soap stock oil using BBSA catalyst A

Figure S12. 13C NMR spectrum of soap stock oil

Figure S13. 13C NMR spectrum of synthesized soap stock biodiesel