BC Science 10 unit 2 Review

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    The CHARGE of an ATOM = 0

    # Protons (+) = # Electrons (-)

    4.1 Atomic Theory and Bonding

    Atom Compound

    Composed ofProtons, Neutrons,and Electrons

    Different atoms arecalled elements

    A pure substancemade up of TWO or

    MORE ELEMENTS

    NaCl is a compound

    O2 is NOT a compound

    +

    ++

    Electrons: 1- charge

    Protons: 1+ charge

    Neutrons: NO charge

    ATOMIC # = # of Protons

    The mass of an atom= # PROTONS + # NEUTRONS(electrons have almost no mass)

    PROTONS + NEUTRONS + ELECTRONS

    = SUBATOMIC PARTICLES

    +

    METALS SEMI-

    METALS

    NON-METALS

    ATOMIC MASS =#Protons + #Neutrons

    Charge when an ion.*Atom has no charge

    ATOMIC # =# Protons

    * Atomic Mass should be rounded to nearest wholenumber EXCEPT when dealing with isotopes

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    Bohr Diagrams

    Electrons and Periods

    Forming Compounds

    Ionic Compounds

    Valence Shell Rule: 2:8:8 RULE

    Electrons are organized in shells:

    1st Shell: MAX 2 electrons2nd Shell: MAX 8 electrons

    3rd

    Shell: MAX 8 electrons

    As you move RIGHT, ONEMORE ELECTRON is added,until the outer SHELL is FULL(In this case 8 on outer shell)

    Period or ROW Far right column in this rowhas FULL SHELL, called aSTABLE OCTET

    Outer shell is calledthe VALENCE SHELL

    There are 2 types of compounds:

    1. Ionic 2. Covalent

    Formed from + and charged ions Involve TRANSFER of ELECTRONS Held together by IONIC BONDS

    Formed when 2 elements SHAREelectrons

    There are no IONS formed Held together by COVALENT BONDS

    Ionic compounds form from IONS:METAL ATOMS lose ELECTRONS to form a POSITIVE ION (CATION)NON-METAL ATOMS gain ELECTRONS to form a NEGATIVE ION (ANION)

    IONS are ATOMSthat have eitherGAINED or LOST

    ELECTRONS

    Charge of theion that forms:

    -1 for Chlorine

    Charge of the ionthat forms:+3 for Aluminum

    Metal: Cation (Positive)Non-Metal: Anion (Negative)

    Chlorine will GAIN 1 electron to form an ION Aluminum will LOSE 3 electrons to form an ION

    Family or COLUMN:#18 Noble Gases: FULL VALENCE SHELL

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    Ionic vs Covalent Compounds

    Lewis Diagrams

    Step 2 : Add any extra

    dots as pairs

    Some METALS can form MORE THAN ONE ion: called Multivalent

    Iron can form either:+3 charge OR +2 charge

    NON-METALS ARE NEVERMULTIVALENT

    Ionic

    Covalent (Molecular)

    Sodium has one electronon VALENCE shell. Itwants to lose this

    Chlorine needs ONEmore electron on its

    Valence shell to make 8.It wants to gain one

    1 2

    3

    SODIUM DONATES1 ELECTRON

    CHLORINE ACCEPTS1 ELECTRON

    SODIUM IONFORMED +1

    CHLRORINE IONFORMED -1

    SODIUM CHLORIDE FORMED

    Electrons are SHAREDbetween the Nitrogen atomand the 3 Hydrogen atoms

    NO electrons areTRANSFERRED

    NO IONS are formed

    Lewis diagram shows ONLY theVALENCE electrons (outer shell)

    Step 1: Draw 4 dots alone first

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    Lewis diagrams to show Ions and Ionic Compounds

    Lewis Diagram of Covalent Molecules

    Naming Simple Ionic Compounds

    Ionic Compound Formulas

    -Sodium loses its onlyouter valence electron;-Chlorine gains anelectron to fill in its last

    pair

    FLUORINE ATOM

    F

    8-

    FLUORINE ION

    F-

    Nitrogen has 5 VALENCEelectrons

    Nitrogen SHARES 3electrons with threehydrogen atoms. Thisleaves 2 electrons notpaired to anything

    Fluorine has oneunpaired electron.Each Fluorine shares itslone electron with theother lone electron.

    4.2 Names and Formulas of Compounds

    Ionic compounds: compounds composed of POSITIVE CATIONS and NEGATIVE ANIONS

    Ionic compounds are named

    using the IUPAC standard of naming:

    Sodium Chloride

    Metal :

    Always comes first Never ends in ide

    Non-Metal :

    Always comes last

    Ends in ide

    Na3P

    Subscript = # of Na ions in this compound

    When no subscript is writtenthe value is 1

    Na

    Na NaP

    Means THREE Naions bind toONE P ion

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    Writing Ionic Compound Formulas from Ions (SHORTCUT METHOD)

    Multivalent Ions

    Writing Formulas from Compound Names with Multi-Valent Ions

    Writing Names from Formulas (REVERSE of above)

    Polyatomic Ions

    Step 1: Write out ions

    Mg +2 with N-3

    Step 2: Cross Charge #s

    Mg +2 with N-3

    Step 3: Write newsubscripts

    Mg 3N2

    Step 4: ReduceSubscripts (if possible)

    Mg 3N2

    Mn+4 with 0-2 Mn+4 with 0-2 Mn2O4 MnO2

    When naming MULTIVALENT IONS you must indicate whichcharge of ion: e.g. Fe +3 would be Iron (III)

    In a compound containing Fe +3 you would name this:

    Iron (III) Oxide not Iron Oxide

    Some METALS can form more than onet e of ion = multi le char es

    Vanadium (IV) Oxide

    Step 1: Write out ions

    V +4 with O-2

    Step 2: Cross Charge #s Step 3: Write newsubscripts

    Step 4: ReduceSubscripts (if possible)

    V +4 with O-2 V 2O4 VO2

    VO2 Step 1: Uncross

    subscriptsStep 2: Write uncrossed

    numbers as charges

    Step 3: Fix the NON-METAL ion to its correct

    charge

    Step 4: Write the namesof the ions in your

    Formula Name

    VO2 V +2 with O-1 V +4 with O-2 (Oxygen must be doubled;so must Vanadium then)

    Vanadium (IV) Oxide

    Polyatomic ions are IONS MADE UP OF MORE THAN ONE TYPE OF ATOM:

    NO3-

    In the formula MgSO 4, to determine if you are dealing with a polyatomic ion look for a normal ionFIRST AND CIRCLE

    Mg SO 4 The remaining ion is not simple so it must be a Polyatomic Ion

    Made up of :ONE Nitrogen

    THREE Oxygens

    The entire thing has a TOTAL charge of -1

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    Naming Formulas Containing Polyatomic Ions

    Covalent Compounds

    Al (OH)3 Using methods above, we would see that there is:

    Name your compound using ions that it contains: Aluminum Hydroxide

    One Aluminum ION Three OH IONS

    Reminder that Aluminumdoes not need Roman

    Numerals

    OH- is not a regular ion so you mustuse the provided POLYATOMIC

    Naming sheet to name

    Covalent Compounds DO NOT have IONS: Naming is different from Ionic compounds

    Naming Rules:

    N2O = dinitrogen monoxideP4S10 = tetraphoshphorus decasulfide

    CO is NOT monocarbon monoxide:it is carbon monoxide

    There is no NO METAL,making this a

    COVALENT COMPOUND

    DO NOT REDUCE THE SUBSCRIPTS FOR

    COVALENT COMPOUNDS

    Covalent Compoundsare named accordingto their SUBSCRIPTS

    IDE endings are thesame for covalent

    EXCEPTION TO THE RULE:

    If the FIRST element is a ONE you DO NOT use MONO

    Formula Name

    CH4 methane

    NH3 ammonia

    H2 O water

    Some COVALENTCOMPOUNDS

    HAVE COMMON NAMES:

    CS2 P4O10

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    Chemical Reaction Structure

    Conservation of Mass in Chemical Change

    Writing and Balancing Chemical Equations (SIMPLE)

    4.3 Chemical Equations

    Word Equation: nitrogen monoxide + oxygen nitrogen dioxide

    Symbolic Equation: 2NO + O 2 2NO2

    Reactants Products

    Coefficients are number placed in front of a FORMULA

    Conservation of Mass states that mass is conserved in a chemical reaction

    TOTAL MASS REACTANTS = TOTAL MASS PRODUCTS

    Step 1: Write out Word Equation: Iron + Bromine Iron (III) Bromide

    Step 2: Write out Skeleton Equation with ions: Fe + Br 2 Fe+3 + Br-

    Step 3: Write out Skeleton Equation: Fe + Br2 FeBr 3

    Step 4: Balance the equation by adding 2 Fe + 3 Br2 2 FeBr 3 COEFFICIENTS

    2 Irons 2 Irons3 x 2 =6

    Bromines

    2 x 3 =6

    Bromines

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    Writing and Balancing Polyatomic Equations

    Acids and Bases Core Ideas

    Acid BasepH value 0 to less than 7 More than 7 to 14Corrosive? YES YES Taste SOUR BITTERReact with metals? YES NO

    pH Indicators

    Step 1: Tin(IV) Nitrite + Potassium Phosphate Potassium Nitrite + Tin (IV) Phosphate

    Step 2: Sn+4 NO2- + K+ PO4

    -3 K+ NO2- + Sn+4 PO4

    -3

    Step 3: Sn(NO 2)4 + K3PO4 KNO2 + Sn3(PO 4)4

    Step 4: 3 Sn(NO 2)4 + K3 PO4 3 K NO2 + Sn3(PO 4)4

    Step 5: 3 Sn(NO 2)4 + K3 PO4 3 KNO2 + Sn3(PO 4)4

    Step 6: 3 Sn(NO 2)4 + 4 K3 PO4 12 KNO2 + Sn3(PO 4)4

    Use SHORT CUT RULE

    (SHOWN PREVIOUSLY )

    Treat each POLYATOMICION AS A GROUP

    Four NO2 One PO4 One NO2 Four PO4

    Balance Metals

    HINT: When balancing equations with OXYGEN and HYDROGEN,balance the CARBON first, then hydrogen, then oxygen

    5.1 Acids and Bases

    Acids DONATE H+ ionsBases ACCEPT H+ ions

    pH Scale

    0 to less than 7 =ACID More than 7 to 14 = BASE

    7= NEUTRAL

    Phenolphthalein: COLORLESS TO PINK from 8.2-10.0Bromothymol blue: YELLOW TO BLUE from 6.0-7.6

    See DATA BOOKLET

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    Naming Acids

    Naming Bases

    Acid versus Bases (In solution)

    Core Concepts

    Normal : Hydrogen Chlor ide becomes Hydrochlor ic Acid

    Special : Hydrogen Carbon ate becomesCarbon ic Acid

    Hydrogen Sulf ite becomesSulfur ous Acid

    HCl Hydrogen Chloride HCl (aq) Hydrochloric Acid Aqueous (aq)(in solution)

    Dry

    IDE turns into IC

    ATE turns into IC but NO hydro

    ITE turns into OUS

    Bases are H+ acceptors; usually have an OH on the right side of their formula

    Caustic: a solution made from very reactive bases (e.g. concentrated Sodium Hydroxide)

    NaOH Sodium HydroxideCa(OH) 2 Calcium HydroxideNH4OH Ammonium Hydroxide

    More H+

    than OH-

    ACIDS H

    +

    = OH-

    NEUTRAL More OH

    -than H

    +

    BASES

    Pure water has the same amount of H+ and OH- ions :MEANING there are NO EXTRA H + ions or OH - ions

    H+ + OH- H2O

    Since ACIDS and BASESproduce IONS

    they CONDUCT ELECTRICITY

    5.2 Salts

    Salt: Contain a positive ion (from a base) and a negative ion (from an acid ) e.g. NaCl

    ACID + BASE SALT + WATER Na + OH- H+ Cl-

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    Acid/Base Neutralization

    Oxides Reacting with water

    Acids and Metals

    Core Ideas

    3 H2SO4 + 2 Al(OH) 3 Al2(SO4)3 + 6 H2O

    ACID BASE SALT WATER

    Metal Oxides react with water to form a BASE

    Non-Metal Oxides react with water to form an ACID SO2(g) + H 2O --> H 2SO3 (aq)

    Na 2O(s) + H2 2O --> 2 NaOH (aq)

    An oxide is a compound with a METAL or NON-METAL with OXYGEN

    Acids will react with METALS to form a SALT and HYDROGEN GAS

    Na 2O(s) + H 2O --> 2 NaOH (aq)

    2 HCL (aq) + Mg (s) --> MgCl 2 (aq) + H 2 (g)

    5.3 Organic Compounds

    Organic: Compounds that contain CARBON

    Inorganic: Compounds that do NOT contain CARBON (exceptions are: CO 2 + CO + CO3-2 + Carbides)

    Carbon has 4electrons in its valence shell

    Carbon forms4 COVALENT BONDS

    Carbides are IONIC compounds thathave CARBON as a NON-METAL:

    e.g. Al 4C3

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    Hydrocarbon examples

    Alcohol examples

    Reaction Types

    HYDROCARBONS:Organic compoundthat only contains

    CARBON andHYDROGEN

    ALCOHOLS:Organic compoundthat only contains

    CARBON, HYDROGEN,& OXYGEN

    6.1 Types of Chemical Reactions

    Synthesis:

    Decomposition:

    A + B C

    2 Na + Cl2 2 NaCl

    AB A + B

    2 NaCl 2 Na + Cl2

    2 Na + Cl2 2 Na+ and 2 Cl -

    ATOM ATOM ION ION

    2 Na+ and 2 Cl - 2 Na + Cl2ION ION ATOM ATOM

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    Single Replacement VS Double Replacement Reactions

    Neutralization Reaction Combustion Reaction

    2Al + 3CuCl2 3Cu + 2AlCl3 Pb(NO3)2 + 2NaI 2NaNO3 + PbI2 M NM M NM M M

    SINGLE REPLACEMENTA METAL CAN SWITCH WITH A METAL

    ORA NON-METAL WITH A NON-METAL

    Remember:A METAL forms + IONS

    NON-METAL forms - IONS

    DOUBLE REPLACEMENTION switches with a ION

    AND- ION switches with a - ION

    ACID + BASE SALT + WATER

    H2SO4 + Ca(OH)2 CaSO4 + 2 HOH

    H+ + OH- H2O (HOH)

    HYDROCARBON + O2 CO2 + H2O

    CH4 + 2 O2 CO2 + 2 H2O

    SUGARS such as Glucose (C 6H12O6)will also undergo combustion

    6.2 Factors Affecting the Rate of Chemical Reactions

    Rate of Reaction: How quickly or slowly reactants turn

    into products

    Every chemical reaction occurs at a certain RATE

    4 things AFFECT REACTION RATE: 1. Temperature2. Concentration3. Surface Area

    4. Presence of a Catalyst

    1. Temperature

    Temp = Reaction Rate

    2. Concentration

    Concentration = Reaction Rate

    Increased temp. means an increase in KINETICENERGY = More particles colliding

    Increased conc. means that there are moremolecules in a solution to collide with one another

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    Core Ideas

    Isotopes

    3. Surface Area

    Surface Area = Reaction Rate

    4. Catalysts

    Surface area is a measure of how much areaof an object is exposed

    The greater the surface area the more of asolid is available to react

    A substance that speeds up the rate of a chemicalreaction

    Catalysts LOWER the energy needed to breakbonds for a reaction to occur

    Catalysts are not used up in a chemical reaction

    Biological Catalysts are called ENZYMES

    Catalysts allow REACTANTS to better line up andproperly collide making a reaction easier to occur

    7.1 Atomic Theory, Isotopes, Radioactive Decay

    Radioactivity: release of HIGH ENERGY PARTICLE OR WAVES

    Natural Background Radiation: radiation that occurs in our environment. This radiationhas the potential to interact with ATOMS creating IONS

    1. Electromagnetic Radiation: (energy waves) RADIO WAVES to GAMMA WAVES

    2. High energy particles: ALPHA and BETA PARTICLES

    Two types of Radiation

    Discovered by Roentgen and later Marie Curie

    that uranium caused photographic plates todarken: this led to the discovery of what she

    called RADIOACTIVITY

    Isotope: the SAME particular element but with a DIFFERENT ATOMIC MASS

    Note that the ATOMIC MASSlisted is the AVERAGE mass forALL the K atoms in nature:SOME ARE HEAVIER than 39

    but the AVERAGE K weighs

    39.1 AMU

    POTASSIUM has 3 isotopes:K-39 K-40 K-41 19 P 19 P 19 P

    20 N 21 N 22 N

    ONLY THE # OF NEUTRONS ISDIFFERENT Some ISOTOPES are RADIOACTIVE and

    undergo DECAY

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    Radiation Types

    Core Ideas

    Electromagnetic Radiation

    The more frequent(compressed) the energy

    waves are the moreENERGY they carry

    GAMMA RAYS are highenergy destructive

    waves released bycertain radioactive

    ATOMS

    Radioactive Decay: these include ALPHA and BETA particles

    Positively Charged Same as a helium nucleus

    Low-penetration

    Negatively Charged Same as an electron

    Higher-penetration

    Alpha Beta

    BOTH ARE EJECTED FROM A NUCLEUS DURINGRADIOACTIVE DECAY

    MASS is conserved meaningit is the SAME on both SIDES

    of ARROW

    Bottom #s = CHARGES

    NO CHARGE or MASS ARE WAVES not particles HIGHEST-penetration

    Gamma

    7.2 Half Life

    Radiocarbon Dating: determining the age of an object by measuring the amount of Carbon-14 remaining

    Half Life: The amount of time it takes for HALF of the nuclei in a sample to decay(THIS IS A CONSTANT)

    At start: 100%1 st Half-life 50%2nd Half-life 25%3 rd Half-life 12.5%

    The time it TAKES toget to each half life is

    specific for eachradioactive atom

    Parent Daughter

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    Using a Decay Curve

    Core Ideas

    You can use this graph tofind out HOW much PARENTis left at ANY point in time

    (even between half lives)

    Remember:

    Parent % + Daughter % = 100% Use this scale to read

    what % is remaining

    Use this scale toread how much

    time has passed

    7.3 Nuclear Reactions

    Nuclear Fission VS Nuclear Fusion The splitting APART of a BIGGERnucleus into 2 SMALLER NUCLEI,

    LOTS OF ENERGY, andSUBATOMIC PARTICLES

    The fusion of 2 SMALLER NUCLEI(JOIN TOGETHER) to make aBIGGER NUCLEUS, LOTS OFENERGY, and SUBATOMICPARTICLES

    FORMS A BIGGER NUCLEI:MUST BE FUSION

    FORMS 2 SMALLER NUCLEI:MUST BE FISSION

    ENERGY ENERGY

    During FISSION a smallerparticle such a NEUTRON (n )may be fired at a the LARGERNUCLEUS to break it apart

    Remember, MASS is conserved: This means that the MASS of the LEFT SIDE of the

    reaction = MASS of the RIGHT SIDE

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    Chain Reaction: One nuclear reaction initiates the next reaction

    In Canada, we use CANDU reactors, which are safe yet efficient system to generatingelectricity .HOWEVER, this FISSION reactor produces radioactive waste that must be isolated safely forthousands of years

    SUN: The sun is a giant FUSION REACTOR:

    Must be controlled:

    In a NUCLEAR REACTOR certain materials are used to control therelease of NEUTRON which are the BULLETS that are released by aREACTION and TRIGGER the next reaction(SEE ABOVE)

    Scientists are looking for ways to create FUSION nuclear reactorsThese usually produce wastes that are NOT radioactive

    Heaver isotopeof Hydrogen:Deuterium

    High pressure in the sun FUSES the 2HYDROGEN NUCLEI together